EP1815113A1 - Oxidation catalyst and particulate filter - Google Patents
Oxidation catalyst and particulate filterInfo
- Publication number
- EP1815113A1 EP1815113A1 EP05809778A EP05809778A EP1815113A1 EP 1815113 A1 EP1815113 A1 EP 1815113A1 EP 05809778 A EP05809778 A EP 05809778A EP 05809778 A EP05809778 A EP 05809778A EP 1815113 A1 EP1815113 A1 EP 1815113A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- exhaust gas
- oxidation
- particulate filter
- oxidation catalyst
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/10—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
- F01N3/18—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control
- F01N3/20—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by methods of operation; Control specially adapted for catalytic conversion ; Methods of operation or control of catalytic converters
- F01N3/2053—By-passing catalytic reactors, e.g. to prevent overheating
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N13/00—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
- F01N13/009—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N13/00—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
- F01N13/011—Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more purifying devices arranged in parallel
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/023—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles
- F01N3/0231—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters using means for regenerating the filters, e.g. by burning trapped particles using special exhaust apparatus upstream of the filter for producing nitrogen dioxide, e.g. for continuous filter regeneration systems [CRT]
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/02—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust
- F01N3/021—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters
- F01N3/033—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices
- F01N3/035—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for cooling, or for removing solid constituents of, exhaust by means of filters in combination with other devices with catalytic reactors, e.g. catalysed diesel particulate filters
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
- F01N3/0814—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents combined with catalytic converters, e.g. NOx absorption/storage reduction catalysts
Definitions
- the invention relates to a method for operating an exhaust gas purification system with a particle filter switched on in an exhaust gas line for separating soot from the exhaust gas of a self-igniting internal combustion engine and with an oxidation catalytic converter upstream of the particle filter for removing the particle collected in the particle filter soot.
- the oxidation catalyst is used for converting hydrocarbon and carbon monoxide into water and carbon dioxide, while a particle filter arranged downstream of the oxidation catalyst is used for the separation of the carbon black from the exhaust gas stream.
- a temperature increase of the exhaust gas is achieved. This temperature is further increased by a post-injection of fuel.
- a method for controlling the post-injection depending on the oxidation catalyst and the loading state of the particulate filter is specified.
- the invention is based on the object of specifying a method for operating an exhaust gas purification system and a corresponding device with which the total emissions of an internal combustion engine are reduced.
- This object is achieved in that the oxidation rate of the oxidation dationskatalysators variable and / or the oxidation catalyst from the exhaust line can be suppressed.
- the function of the oxidation catalytic converter is therefore to increase the exhaust gas temperature by the oxidation of hydrocarbons (exothermic catalytic converter). This provides a contribution to the required exhaust gas temperature for the periodic regeneration of the particulate filter with O 2 contained in the exhaust gas. Since the elevated temperature should prevail only during the phase of regeneration in the exhaust system, the oxidation catalyst is suppressed from the exhaust line and displayed again.
- the oxidation rate can therefore be varied between no oxidation and maximum oxidation, or the oxidation catalyst can be bypassed, for example, by way of a bypass line.
- the variable activity of the oxidation catalyst is used to dampen the activity of the oxidation catalyst outside the regeneration phases of the particulate filter. As a result, unwanted side reactions, such as those of NO to NO 2 and of SO 3 to SO 4 avoided or reduced.
- the exhaust gas temperature is variable by a controlled operation of the oxidation catalyst upstream pilot burner, in particular can be increased.
- the exhaust gas temperature can be additionally increased, in particular in operating states in which the previously described measures of increasing the temperature (for example, at low partial load) are insufficient.
- the pilot burner is always used only at maximum effective oxidation catalyst.
- the exhaust gas emitted by an internal combustion engine 1 is supplied to an oxidation catalytic converter 3 via an exhaust gas line 2a, flows through it and is supplied to a particle filter 4 via further exhaust gas lines 2b, 2c.
- This particle filter 4 is designed as a discontinuously regenerating particle filter 4, that is to say that the (soot) particles which have been filtered out of the exhaust gas are burnt off discontinuously. This burning off takes place in the particle filter 4 by increasing the exhaust gas temperature to about 600 ° C.
- This increase in the exhaust gas temperature is achieved by oxidizing oxidation of CO and HC to H 2 O and CO 2 in the oxidation catalyst.
- the oxidation rate of the oxidation catalytic converter can be varied and / or the oxidation catalytic converter can be suppressed from the exhaust gas line.
- a bypass line 2e exists, via which the Oxidations ⁇ catalyst is bypassed controlled.
- a further oxidation catalyst 3a may optionally be used in the bypass line 2e, which has a different tuning and reduces other emissions in the exhaust gas, for example HC, CO, HC particles.
- the exhaust-gas temperature can also be varied, in particular increased, by a controlled operation of a pilot burner arranged upstream of the oxidation catalytic converter.
- the exhaust gas temperature can be additionally increased, in particular in operating states in which the previously described measures for increasing the temperature (for example, at low partial load) are insufficient.
- the control of the oxidation rate and / or the suppression and superimposition takes place, for example, by sensor-appropriate detection of suitable parameters (engine speed, injection quantity). genute, load values, exhaust gas temperature, nitrogen dioxide concentration) and / or the use of electronic controls using Verwen ⁇ stored memory maps.
- suitable parameters engine speed, injection quantity
- Verwen ⁇ stored memory maps As an alternative to the bypass line 2e, the carbon monoxide emission of the internal combustion engine can be controlled by tuning the fuel injection, since this in turn directly influences the conversion of nitrogen monoxide to nitrogen dioxide.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Exhaust Gas After Treatment (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Lighting Device Outwards From Vehicle And Optical Signal (AREA)
- Processes For Solid Components From Exhaust (AREA)
Abstract
Description
Claims
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102004057434A DE102004057434A1 (en) | 2004-11-27 | 2004-11-27 | Oxidation catalyst and particle filter |
PCT/EP2005/012557 WO2006056432A1 (en) | 2004-11-27 | 2005-11-24 | Oxidation catalyst and particulate filter |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1815113A1 true EP1815113A1 (en) | 2007-08-08 |
EP1815113B1 EP1815113B1 (en) | 2010-02-10 |
Family
ID=35686483
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP05809778A Not-in-force EP1815113B1 (en) | 2004-11-27 | 2005-11-24 | Method for operating an exhaust gas purification system |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP1815113B1 (en) |
AT (1) | ATE457415T1 (en) |
DE (2) | DE102004057434A1 (en) |
WO (1) | WO2006056432A1 (en) |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS61112716A (en) * | 1984-11-08 | 1986-05-30 | Mitsubishi Motors Corp | Diesel particulate collector |
JP2712783B2 (en) * | 1990-08-10 | 1998-02-16 | トヨタ自動車株式会社 | Exhaust gas purification device for internal combustion engine |
JP3089989B2 (en) * | 1995-05-18 | 2000-09-18 | トヨタ自動車株式会社 | Diesel engine exhaust purification system |
JP3250645B2 (en) * | 1995-05-24 | 2002-01-28 | 日野自動車株式会社 | Exhaust gas purification equipment |
DE19533355A1 (en) * | 1995-09-08 | 1997-03-13 | Wilfried Faerber | Treating exhaust gases containing e.g. soot particles |
DE10043613A1 (en) * | 2000-08-02 | 2002-02-14 | Fev Motorentech Gmbh | Filter arrangement, used for cleaning exhaust gases from IC engines, comprises porous particle filter body having catalytically active coating, oxidation catalyst, and adjusting element for adjusting feeds |
JP3758617B2 (en) * | 2002-07-12 | 2006-03-22 | トヨタ自動車株式会社 | Exhaust gas purification device for internal combustion engine |
DE10241065A1 (en) * | 2002-09-05 | 2004-03-11 | Robert Bosch Gmbh | Process and assembly to reduce automotive particle and nitrogen oxides emissions, has catalytic converter operating in parallel with plasma reactor |
JP4045935B2 (en) * | 2002-11-25 | 2008-02-13 | 三菱ふそうトラック・バス株式会社 | Exhaust gas purification device for internal combustion engine |
-
2004
- 2004-11-27 DE DE102004057434A patent/DE102004057434A1/en not_active Withdrawn
-
2005
- 2005-11-24 WO PCT/EP2005/012557 patent/WO2006056432A1/en active Application Filing
- 2005-11-24 DE DE502005009005T patent/DE502005009005D1/en active Active
- 2005-11-24 AT AT05809778T patent/ATE457415T1/en active
- 2005-11-24 EP EP05809778A patent/EP1815113B1/en not_active Not-in-force
Non-Patent Citations (1)
Title |
---|
See references of WO2006056432A1 * |
Also Published As
Publication number | Publication date |
---|---|
EP1815113B1 (en) | 2010-02-10 |
WO2006056432A1 (en) | 2006-06-01 |
DE502005009005D1 (en) | 2010-03-25 |
ATE457415T1 (en) | 2010-02-15 |
DE102004057434A1 (en) | 2006-06-08 |
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