EP1806163A1 - Zusammensetzung zur dauerhaften Verformung des menschlichen Haares - Google Patents

Zusammensetzung zur dauerhaften Verformung des menschlichen Haares Download PDF

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Publication number
EP1806163A1
EP1806163A1 EP06025295A EP06025295A EP1806163A1 EP 1806163 A1 EP1806163 A1 EP 1806163A1 EP 06025295 A EP06025295 A EP 06025295A EP 06025295 A EP06025295 A EP 06025295A EP 1806163 A1 EP1806163 A1 EP 1806163A1
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EP
European Patent Office
Prior art keywords
hair
composition
composition according
concentration
calculated
Prior art date
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Granted
Application number
EP06025295A
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English (en)
French (fr)
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EP1806163B1 (de
Inventor
Jonathan Dr. Wood
Bernd Dr. Nöcker
Sandra Schmelz
Britta Punsch
Jörg Schneider
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Kao Germany GmbH
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KPSS Kao Professional Salon Services GmbH
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Priority to EP06025295A priority Critical patent/EP1806163B1/de
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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/35—Ketones, e.g. benzophenone
    • A61K8/355—Quinones
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/04—Preparations for permanent waving or straightening the hair

Definitions

  • the present invention concerns a composition for the permanent shaping of human hair used both for the permanent waving of human hair with an excellent waving effect as well as for the straightening of curled hair.
  • thioglycolic acid also in form of the salts thereof, in particular its ammonium salt, although numerous other thio compounds have been proposed for this purpose, which, however, mostly did not succeed.
  • compositions containing thioglycollates are customarily applied at a pH-value between 7 and 10, in particular 8.5 and 9.5.
  • compositions vary in their waving and/or straightening performance and, therefore, there is still need for further improvement.
  • the present invention starts from the task of providing a composition for the permanent shaping of human hair with excellent waving and straightening performance. Hair waved or straightened with composition disclosed herein looks and feels natural upon touching by hand.
  • the first object of the present invention is a composition for permanent shaping and/or straightening hair based on at least one reducing agent, which further comprises at least one ubichinone of the formula where n is a number between 1 and 10.
  • Preferred ubichinones are the ones where n is a number between 6 and 10 and especially preferred is Ubichinone 50 where n is 10, also known as Coenzyme Q10.
  • Ubichinones have been used in cosmetic compositions. Such compositions have been disclosed for example in EP 751 762 B1 for hair conditioning compositions in combination with retinols, in DE 199 26 167 A1 and DE 199 26 168 A1 for hair styling compositions, DE 199 26 170 A1 for cleansing preparations and in DE 199 26 156 A1 for hair conditioning compositions. Furthermore, in EP 1232 741 A1 the use of ubichinones in hair colouring compositions is disclosed.
  • Concentration of at least one ubichinone of the above formula in permanent shaping compositions of the present invention is from 0.0001 to 1%, preferably from 0.0002 to 0.75%, more preferably from 0.0002 to 0.5% and most preferably from 0.0005 to 0.5% by weight, calculated to total composition.
  • the permanent waving compositions according to the invention comprises at least one reducing compound.
  • Preferred are thioglycolic acid and thiolactic acid as well as the salts thereof, in particular the ammonium and ethanolamine salts.
  • Further useful thio compounds are in particular cysteine or the hydrochloride thereof, homocysteine, cysteamine, N-acetyl cysteine, thioglycerol, ethanediol monothioglycollate, 1.2-propyleneglycol monothioglycollate (see also WO-A 93/1791 ), 1-3-propanediol monothioglycollate or the isomer mixture resulting therefrom, 1.3-butanediol and 1.4-butanediol monothioglycollate and the isomer mixtures therefrom, polyethylene glycol, such as di-, tri- and tetraethyleneglycol monothioglycollates, glyce
  • inorganic reducing sulfur compounds such as sodium hydrogen sulfite is basically also possible.
  • the total reduction agent content in the compositions according to the invention customarily amounts from 2.5 % to about 15 % by weight, calculated to total composition as free thioglycolic acid as reference substance.
  • the waving compositions containing reducing agents can, if necessary, comprise alkalizing agents. Their quantity is dependent on the reducing agent and the desired pH-value of the composition.
  • Reducing agent compositions preferably contain about 0.1 % to about 5%, in particular about 0.5% to about 2.5% by weight thereof, calculated to the total composition.
  • Alkalizing agents preferred within the scope of the invention are ammonium carbamate, ammonia and/or ammonium(bi)carbonate, and triethanolamine. It is desirable to adjust the pH-value between about 6.5 and 10.5, preferably about 7 to 9.5.
  • the shaping compositions according to the invention are suited for use both for the permanent waving, i.e. curling of human hair and for the straightening, i.e. smoothing thereof.
  • the viscosity best suited for the permanent waving compositions according to the invention proved to be in the range of about 500 to 10,000 mPa.s, preferably about 1,000 to about 5,000 mPa.s, measured at 20°C in a Brookfield viscosimeter (no. 5 spindle), whereas the viscosity suited for the straightening compositions is preferably higher in a range up to about 50,000 mPa.s, preferably up to 30,000 mPa.s measured at 20°C in a Brookfield viscosimeter (no. 5 spindle).
  • the viscosity is adjusted by addition of the appropriate amounts of thickening agents known per se, such as cellulose derivatives. Thickening may as well be realised by formulating a composition in form of an emulsion with the use of C 10 -C 22 -fatty alcohols, in admixture with long mono alkyl chain quaternary ammonium surfactants.
  • the permanent waving compositions according to the present invention preferably comprise surfactants selected from anionic, nonionic, cationic and amphoteric ones. Their proportion ranges from about 0.05 % to about 10%, in particular from about 0.1 % to about 5 % by weight, calculated to total composition.
  • Suitable anionic surfactants are especially the known alkyl ether sulfates and carboxylic acids, in particular in form of their alkali salts, as well as protein fatty acid condensates.
  • Suitable nonionic surfactants which are preferred within the scope of the invention, are in particular C 8 -C 18 -fatty alcohol polyglycol ethers, fatty acid polyglycol esters, fatty acid alkanolamides, amineoxides, and especially C 8 -C 18 -alkyl polyglucosides.
  • amphoteric surfactants such as the known alkyl betaines, alkyl amido betaines, and alkyl amphoacetates.
  • permanent shaping compositions comprise at least one cationic surfactant according to general formula where R 1 s a saturated or unsaturated, branched or non-branched alkyl chain with 8-22 C atoms or R 5 CO NH (CH 2 ) n where R 5 is saturated or unsaturated, branched or non-branched alkyl chain with 7-21 C atoms and n has typical value of 0 - 4 or R 6 CO O (CH 2 ) n where R 6 is saturated or unsaturated, branched or non-branched alkyl chain with 7-21 C atoms and n has typical value of 0 - 4, and R 2 is a hydrogen, saturated or unsaturated, branched or non-branched alkyl chain with 1-22 C atoms or R 5 CO NH (CH 2 ) n where R 5 is saturated or unsaturated, branched or non-branched alkyl chain with 7-21 C atoms and n has typical value of 0 - 4 or R
  • Concantration of at least one cationic surfactant is in the range from 0.05 % to 5 %, preferably 0.1 % to 2.5 % by weight, calculated to total composition.
  • Suitable long-chain quaternary ammonium compounds which can be used alone or in admixture are in particular cetyl trimethyl ammonium chloride, dimethyl dicetyl ammonium chloride, trimethyl cetyl ammonium bromide chloride, stearyl trimethyl ammonium chloride, dimethyl stearyl benzyl ammonium chloride, benzyl tetradecyl dimethyl ammonium chloride, dimethyl dihydrogenated tallow ammonium chloride, lauryl pyridinium chloride, lauryl dimethyl benzyl ammonium chloride, lauryl trimethyl ammonium chloride, tris-(oligooxyethyl) alkyl ammonium phosphate, cetyl pyridinium chloride, etc.
  • the compositions comprise at least one cationic polymer.
  • cationic polymers listed under the generic name "Polyquaternium” and "Quaternium” in the CTFA International Cosmetic Ingredient Dictionary. Examples are Polyquaternium 6, Polyquaternium 7, Polyquaternium 10, Polyquaternium 11, Polyquaternium 16, Polyquaternium 22 and Polyquaternium 28, Polyquaternium 39, Quaternium-8, Quaternium-14, Quaternium-15, Quaternium-18, Quaternium-22, Quaternium-24, Quaternium-26, Quaternium-27, Quaternium-30, Quaternium-33, Quaternium-53, Quaternium-60, Quaternium-61, Quaternium-72, Quaternium-78, Quaternium-80, Quaternium-81, Quaternium-81, Quaternium-82, Quaternium-83 and Quaternium-84.
  • the cationic polymers also include the quaternized products of graft polymers from organopolysiloxanes and polyethyl oxazolines described in EP-A 524 612 and EP-A 640 643 .
  • Concantration of one or more cationic polymers is in the range from 0.05 % to 5 %, preferably 0.1 % to 2.5 % by weight, calculated to total composition.
  • Permanent shaping compositions of present invention can comprise additionally at least one organic solvent.
  • Suitable organic solvents are 2-methyl-1,3-propanediol, mono and dialcohols or the ethers thereof, in particular mono-C 1 -C 3 -alkyl ether, ethanol, n-propanol, isopropyl alcohol, 1-methoxypropanol, 1-ethoxypropanol and ethoxydiglycol, diols and their esters 1,3- and 1,4-butanediol, diethyleneglycol and the monomethyl and monoethyl ether thereof, dipropylene glycol and the monomethyl and monoethyl ether thereof, glycerol, hexanetriol, ethyl carbitol, benzyl alcohol, benzyloxy ethanol, propylene carbonate, N-alkyl pyrrolidone, and urea or their mixture preferably in an amount from about 0.1 % to 10 % by weight
  • Permanent shaping composition of the present invention can comprise further ceramide type of compound with the general formula where R 7 and R 8 are independent from each other alkyl- or alkenyl group with 10 to 22 carbon atoms, R 9 is alkyl or hydroxyl alkyl with 1 to 4 carbon atoms group and n is a number between 1 to 6, preferably 2 or 3.
  • Preferred compound according to the above chemical structure is cetyl-PG-hydroxyethylpalmitamide.
  • sterols especially the phytosterols as preferred hair restructuring agents.
  • Especially preferred ones are of plant origin for example ergosterol, sitosterol, stigmasterol, fucosterol, brassicasterol, fungisterol, campesterol, zymosterol, ascosterol, cerevisterol, episterol, faecosterol, spinasterol.
  • phytosterols the ones found in "Avocadin" which is the unsaponified fraction of the avocado oil is more preferred.
  • fatty acids of C10 to C22 may be incorporated into the compositions of the present invention at a concentration of preferably 0.01 to 2.5% by weight calculated to total composition.
  • Another preferred compound in the permanent shaping composition of the present invention is silicone compounds and especially aminated silicones such as amodimethicone available from for example Dow Corning under the brand names Dow Corning 949 Emulsion and Dow Corning 2-8194. Concentration of silicones, especially amodimethicone, is in the range of 0.05 to 2.5%, preferably 0.1 to 1% by weight calculated to total composition.
  • one or more natural oil component may be incorporated into the compositions of the present invention. Suitable are such as olive oil, almond oil, avocado oil, wheatgerm oil, ricinus oil or their mixture. Concentration of these natural oil ingredients should be 0.01 to 2.5%, preferably 0.01.to 1%, more preferably 0.05 to 0.5% by weight, calculated to total composition.
  • compositions used according to the invention can naturally comprise all the substances customarily found in permanent shaping compositions, a list of which will not be given here, and are preferably present as solutions, gels with a higher or lower viscosity, emulsions or creams. They can be single-phase products or compositions packed into separate packaging which are united upon application, as they are disclosed, for example, in DE-C 43 04 828 .
  • Composition of the present invention is used in a process for permanent waving wherein hair is washed or shampooed first and wound on the curlers, subsequently a reducing agent comprising composition with at least one ubichinone is applied onto hair and after 1 to 45 min, preferably 1 to 30 min of processing time, depending on the hair strength, rinsed off from hair with tap water and an oxidizing composition comprising at least one oxidizing agent, preferably hydrogen peroxide or sodium bromate at a concentration of 0.5 to 10% by weight calculated to total of oxidizing composition, is applied onto hair and left on the hair 1 to 20 min and rinsed off and curlers removed from hair. In cases where additional conditioning composition is required this may as well be applied.
  • the curlers are removed after rinsing off the reducing agent and before applying the oxidizing egent.
  • an intermediate treatment composition is applied onto hair and without rinsing off but after removing the excess amount of intermediate treatment with a towel, oxidizing composition is applied and at the end of the processing they are rinsed off from hair and criers are removed from hair. It has further been found out that the use of ubichinone in the intermediate treatment composition in the same concentration range as disclosed above for the reducing composition improves the permanent shaping of hair as well in terms of curl appearance and natural look and feel of hair.
  • permanent shaping of hair is carried our with a process wherein hair is washed or shampooed first and subsequently a reducing agent comprising composition is applied onto hair and after 1 to 45 min, preferably 1 to 30 min of processing time, depending on the hair strength, rinsed off from hair with tap water and an intermediate treatment composition comprising at least one ubichinone of the formula above and magnesium sulfate at a concentration of 2 to 15% by weight is applied and without rinsing off an oxidizing composition comprising at least one oxidizing agent, preferably hydrogen peroxide or sodium bromate at a concentration of 0.5 to 10% by weight calculated to total of oxidizing composition, is applied onto hair and left on the hair 1 to 20 min and rinsed off. In cases where additional conditioning composition is required this may as well be applied.
  • the intermediate treatment composition has a pH value between 2.5 to 6, preferably 3 to 5.5 and most preferably 3 to 5.
  • a straightening process may also be carried out in a different process wherein hair is washed and/or shampooed and dried and reducing composition comprising at least one ubichinone is applied onto dry hair and processed for 5 to 60 min, preferably 5 to 45 min and rinsed off with water and dried and the dry hair physically straighten with hot iron at a temperature of 130 to 210°C and subsequently an oxidizing composition comprising at least one oxidizing agent, preferably hydrogen peroxide or sodium bromate at a concentration of 0.5 to 10% by weight calculated to total of oxidizing composition, is applied onto hair and left on the hair 1 to 20 min and rinsed off.
  • oxidizing composition comprising at least one oxidizing agent, preferably hydrogen peroxide or sodium bromate at a concentration of 0.5 to 10% by weight calculated to total of oxidizing composition
  • Ammonium thioglycolate (60%) 21.3 (% by wt. Ammonium hydrogen carbonate 5.0 1,3- butylene gylcol 3.0 Amodimethicone 0.2 PEG-40-Hydrogenated castor oil 0.7 Polyquaternium-7 0.5 Perfume 0.4 Coenzyme Q10 0.04 Ammonia, 25% ad pH 8.3 Water ad 100.0
  • Ammonium thioglycollate (60%) 15.0 (% by wt.) Ammonium hydrogen carbonate 2.5 Ceteth-20 0.7 Tallow trimonium chloride 0.1 1,3- butylene gylcol 0.5 Polyquaternium-6 1.5 Amodimethicone 0.2 Coenzyme Q10 0.1 Oleic acid 0.05 Perfume 0.4 Ammonia, 25% ad pH 8.0 Water ad 100.0
  • the permanent wave achieved with this composition was similar to the one obtained with the composition according to Example 1.
  • Ammonium thioglycollate (60%) 0.9 (% by wt.) Cystein hydrochloride 5.7 Ammonium hydrogen carbonate 1.5 Acetylcystein 0.7 Cetrimonium chloride 0.1 1,3- butylene gylcol 0.5 Polyquaternium-39 1.5 Amodimethicone 0.2 Coenzyme Q10 0.1 Oleic acid 0.05 Perfume 0.4 Ammonia, 25% ad pH 9.8 Water ad 100.0
  • the permanent wave achieved with this composition was similar to the one obtained with the composition according to Example 1.
  • a permanent waving product consisting of two Compositions A and B, filled into a two-chamber packaging the chambers of which were kept separate until application, was prepared by destruction of the separating wall and applied onto human hair rolled onto curlers. The hair was rinsed after about fifteen minutes processing and neutralized for about five minutes with a 2.5 % H 2 O 2 neutralizer composition, rinsed again, shampooed and dried. An expressive, even, intensive permanent wave was obtained. An identical treatment which had no Ubichinone showed a visibly inferior wave.
  • Composition A A:
  • Ammonium hydrogen carbonate 4.5 (g) Polyquaternium -6 1.0 PEG-65-Hydrogenated castor oil 0.8 Isopropyl alcohol 1.5 Ethoxydiglycol 2.0 Cocoamidopropyl betaine 1.0 Perfume 0.3 Coenzyme Q10 0.05 Turbidifying agent 0.5 Ammonia, 25% ad pH 8.4 Water ad 72.0
  • Composition B is a composition of Composition B:
  • a permanent waving product filled into a two-chamber package was prepared in analogy to Example 3:
  • Composition A A:
  • Ammonium hydrogen carbonate 3.5 (g) Polyquaternium -11 0.5 Ethanol 0.5 1-Methoxypropanol 1.0 Cocoamidopropyl betaine 1.0 PEG-25-glyceryl cocoate 0.8 Coenzyme Q10 0.1 Oleic acid 0.05 Perfume 0.3 Turbidifying agent 0.5 Ammonia, 25% ad pH 8.3 Water ad 72.0
  • Composition B is a composition of Composition B:
  • a product with a pH-value of 7.4 was obtained by admixture of the Compositions immediately prior to application. After application onto dyed hair as described in Example 3, this mixture resulted in an expressive permanent wave, which had not effect whatever on the color gloss and color intensity.
  • Ammonium thioglycollate 70% 15.0 (g) Ammonium hydrogen carbonate 4.5 PEG-40-Hydrogenated castor oil 0.7 C 12 -C 18 -Fatty alcohol mixture 3.5 Cetrimonium chloride 2.0 Amodimethicone 0.05 2-Methyl-1.3-propanediol 0.5 Polyquaternium -28 0.1 Coenzyme Q10 0.1 Perfume 0.3 Ammonia, 25% ad pH 8.0 Water ad 100.0
  • the above composition had a pH of 4.10.
  • This composition constitutes an effecting smoothing composition for kinky hair.

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  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Emergency Medicine (AREA)
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EP06025295A 2005-12-16 2006-12-07 Zusammensetzung zur dauerhaften Verformung des menschlichen Haares Active EP1806163B1 (de)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP06025295A EP1806163B1 (de) 2005-12-16 2006-12-07 Zusammensetzung zur dauerhaften Verformung des menschlichen Haares

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP05027635A EP1797861A1 (de) 2005-12-16 2005-12-16 Zusammensetzung zur dauerhaften Verformung des menschlichen Haares
EP06025295A EP1806163B1 (de) 2005-12-16 2006-12-07 Zusammensetzung zur dauerhaften Verformung des menschlichen Haares

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EP1806163A1 true EP1806163A1 (de) 2007-07-11
EP1806163B1 EP1806163B1 (de) 2011-10-05

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EP06025295A Active EP1806163B1 (de) 2005-12-16 2006-12-07 Zusammensetzung zur dauerhaften Verformung des menschlichen Haares

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EP (2) EP1797861A1 (de)
AT (1) ATE527026T1 (de)
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Cited By (4)

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DE102007005335A1 (de) * 2007-02-01 2008-08-07 Beiersdorf Ag Lichtschutzzubereitung mit einer Kombination von Mikropigmenten
DE102007005336A1 (de) * 2007-02-01 2008-08-07 Beiersdorf Ag UV-Filterkombination mit Piperazinderivaten
DE102007005334A1 (de) * 2007-02-01 2008-08-07 Beiersdorf Ag Piperazinderivate in diolhaltigen kosmetischen Zubereitungen
WO2011067112A2 (de) 2009-12-04 2011-06-09 Henkel Ag & Co. Kgaa Verwendung von coenzym q10 und/oder dessen derivaten in verfahren zur permanenten haarumformung

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EP1797861A1 (de) 2005-12-16 2007-06-20 KPSS-Kao Professional Salon Services GmbH Zusammensetzung zur dauerhaften Verformung des menschlichen Haares
EP2011478A1 (de) * 2007-06-26 2009-01-07 KPSS-Kao Professional Salon Services GmbH Zusammensetzung zur dauerhaften Verformung des menschlichen Haares
EP2011479A1 (de) * 2007-06-26 2009-01-07 KPSS-Kao Professional Salon Services GmbH Zusammensetzung zur dauerhaften Verformung des menschlichen Haares
EP2011543A1 (de) 2007-06-26 2009-01-07 KPSS-Kao Professional Salon Services GmbH Zusammensetzung zur dauerhaften Verformung des menschlichen Haares
EP2022535A1 (de) * 2007-08-07 2009-02-11 KPSS-Kao Professional Salon Services GmbH Zusammensetzung zur dauerhaften Verformung des menschlichen Haares
EP2022470A1 (de) * 2007-08-07 2009-02-11 KPSS-Kao Professional Salon Services GmbH Färbemittelzusammensetzung
EP2022468A1 (de) * 2007-08-07 2009-02-11 KPSS-Kao Professional Salon Services GmbH Zusammensetzung zur Haarkonditionierung
EP2177204A1 (de) 2008-10-20 2010-04-21 KPSS-Kao Professional Salon Services GmbH Färbemittelzusammensetzung
EP2177203A1 (de) * 2008-10-20 2010-04-21 KPSS-Kao Professional Salon Services GmbH Haarfärbezusammensetzungen und Zusammensetzung zur dauerhaften Verformung von Haaren
EP2177202A1 (de) * 2008-10-20 2010-04-21 KPSS-Kao Professional Salon Services GmbH Färbemittelzusammensetzung
EP2177206A1 (de) * 2008-10-20 2010-04-21 KPSS-Kao Professional Salon Services GmbH Zusammensetzung zur dauerhaften Verformung des menschlichen Haares
EP2177205A1 (de) * 2008-10-20 2010-04-21 KPSS-Kao Professional Salon Services GmbH Zusammensetzung zur dauerhaften Verformung des menschlichen Haares
EP2177245A1 (de) * 2008-10-20 2010-04-21 KPSS-Kao Professional Salon Services GmbH Zusammensetzung zur dauerhaften Verformung des menschlichen Haares
EP2191863A1 (de) * 2008-11-26 2010-06-02 KPSS-Kao Professional Salon Services GmbH Zusammensetzung zur dauerhaften Verformung des menschlichen Haares
EP2332515A1 (de) 2009-12-09 2011-06-15 KPSS-Kao Professional Salon Services GmbH Verfahren zur dauerhaften Verformung des menschlichen Haares
JP6025103B2 (ja) * 2013-06-06 2016-11-16 山栄化学株式会社 パーマネントウェーブ用第２剤及びパーマネントウェーブ用剤
US9095518B2 (en) 2013-08-01 2015-08-04 Liqwd, Inc. Methods for fixing hair and skin
EP2857003A1 (de) * 2013-10-02 2015-04-08 The Procter and Gamble Company Haarpflegezusammensetzung mit Ammoniumthioglycolat und/oder Ammonium-Thiolactat
EP3285733B1 (de) 2015-04-24 2019-10-23 Liqwd, Inc. Verfahren zur behandlung von relaxtem haar
KR101697967B1 (ko) * 2016-04-01 2017-01-19 우상호 점착기능이 향상된 조성물 및 퍼머 방법
US9872821B1 (en) * 2016-07-12 2018-01-23 Liqwd, Inc. Methods and formulations for curling hair

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US20070141005A1 (en) 2007-06-21
US7850953B2 (en) 2010-12-14
EP1797861A1 (de) 2007-06-20
AU2006246481B2 (en) 2012-09-06
EP1806163B1 (de) 2011-10-05
AU2006246481A1 (en) 2007-07-05
US8889111B2 (en) 2014-11-18
ATE527026T1 (de) 2011-10-15
US20110044926A1 (en) 2011-02-24

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