EP1797239A1 - Apparatus for loosening the fibres of a raw tissue web and corresponding method - Google Patents

Apparatus for loosening the fibres of a raw tissue web and corresponding method

Info

Publication number
EP1797239A1
EP1797239A1 EP04790182A EP04790182A EP1797239A1 EP 1797239 A1 EP1797239 A1 EP 1797239A1 EP 04790182 A EP04790182 A EP 04790182A EP 04790182 A EP04790182 A EP 04790182A EP 1797239 A1 EP1797239 A1 EP 1797239A1
Authority
EP
European Patent Office
Prior art keywords
roller
rollers
pair
tissue web
protuberances
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP04790182A
Other languages
German (de)
French (fr)
Other versions
EP1797239B1 (en
Inventor
Heinz-Jürgen Müller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Essity Germany GmbH
Original Assignee
SCA Hygiene Products GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SCA Hygiene Products GmbH filed Critical SCA Hygiene Products GmbH
Publication of EP1797239A1 publication Critical patent/EP1797239A1/en
Application granted granted Critical
Publication of EP1797239B1 publication Critical patent/EP1797239B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • D21F11/14Making cellulose wadding, filter or blotting paper

Definitions

  • the present invention relates to an apparatus for loosening the fibres of a raw tissue web before converting to the tissue product and to a corresponding method.
  • a raw tissue web is a continuous tissue paper and tissue paper is defined as a soft absorbent paper having a low basis weight.
  • tissue paper is defined as a soft absorbent paper having a low basis weight.
  • the total basis weight of multiple-ply tissue products is preferably equal to a maximum of 65 g/m2, more preferably to a maximum of 50 g/m ⁇ .
  • Its density is typically below 0.6 g/cm ⁇ , preferably below 0.30 g/cm 3 and more preferably between 0.08 and 0.20 g/cm 3 .
  • tissue is distinguished from paper production by the its extremely low basis weight and its much higher tensile energy absorption index (see DIN EN 12625-4 and DIN EN 12625-5) .
  • Paper and tissue paper also differ in general with regard to the modulus of elasticity that characterizes the stress-strain properties of these planar products as a material parameter.
  • a tissue's high tensile energy absorption index results from the outer or inner creping.
  • the former is produced by compression of the paper web adhering to a dry cylinder as a result of the action of a crepe doctor or in the latter instance as a result of a difference in speed between two wires ("fabrics") .
  • fabrics two wires
  • Moist tissue paper webs are usually dried by the so-called Yankee drying, the through air drying (TAD) or the impulse drying method.
  • the fibers contained in the tissue paper are mainly cellulosic fibres, such as pulp fibers from chemical pulp (e.g. Kraft sulfite and sulfate pulps) , mechanical pulp (e.g. ground wood) , thermo mechanical pulp, chemo-mechanical pulp and/or chemo-thermo mechanical pulp (CTMP) . Pulps derived from both deciduous (hardwood) and coniferous (softwood) can be used. The fibers may also be or include recycled fibers, which may contain any or all of the above categories.
  • chemical pulp e.g. Kraft sulfite and sulfate pulps
  • mechanical pulp e.g. ground wood
  • thermo mechanical pulp chemo-mechanical pulp and/or chemo-thermo mechanical pulp
  • CMP chemo-thermo mechanical pulp
  • Pulps derived from both deciduous (hardwood) and coniferous (softwood) can be used.
  • the fibers may also be or include recycled fibers, which may contain any or
  • the fibers can be treated with additives - such as fillers, softeners, such as quaternary ammonium compounds and binders, such as conventional dry-strength agents or wet-strength agents used to facilitate the original paper making or to adjust the properties thereof.
  • additives such as fillers, softeners, such as quaternary ammonium compounds and binders, such as conventional dry-strength agents or wet-strength agents used to facilitate the original paper making or to adjust the properties thereof.
  • the tissue paper may also contain other types of fibers, e.g. regenerated cellulosic fibres or synthetic fibers enhancing, for instance, strength, absorption, smoothness or softness of the paper.
  • Tissue paper may be converted to the final tissue product in ⁇ many ways, for example, by embossing or laminating it into a multi-ply product, rolled or folded.
  • raw tissue web in sense of the present invention it is meant the web discharged from the paper making machine before it is converted to the tissue product as before-mentioned.
  • the fibres are arranged in a substantially oriented manner and the dried fibres form a fibre composite, namely the raw tissue web.
  • the fibres in the raw tissue web leaving the paper-making machine are as previously mentioned substantially- oriented in the machine direction of the paper-making machine, as it is also depicted in Fig. 5A, which schematically shows a raw tissue web after leaving the papermaking machine and before being treated by method of the present invention.
  • Such a raw tissue web or tissue paper, respectively is depending on its basis weight relatively stiff and inflexible.
  • the basic idea of the present invention is to loosen at least the fibres of the raw tissue web located in the surface region/-s of the tissue web so as to increase the softness on the surface of the raw tissue web and to break up the inflexible fibre composite of the raw tissue web, which is both achieved in that the raw tissue web is flexed in the machine direction and/or cross to the machine direction (cross-machine direction) .
  • the flexing for example could be compared (merely for the sake of explanation of the invention) with pulling the raw tissue web over an edge under tension, whereby the fibres on the surface of the tissue web opposite to the surface facing the edge are raised.
  • the apparatus comprises a first pair of rollers and/or a second pair of rollers.
  • the first pair of rollers defines a first nip for introducing the tissue web, the first nip being at least as large as the thickness of the tissue web.
  • the tissue web is introduced into the first nip in a machine direction preferably under tension.
  • the tissue web is not compressed or calendared in the nip.
  • the first nip equals the thickness of the tissue web or is slightly larger.
  • One roller of the first pair of rollers has protuberances extending about the entire circumference of the roller and separated from each other in the longitudinal direction of the roller.
  • the longitudinal direction of the roller is meant to be the direction parallel to the center axis of the roller.
  • the other roller of the first pair of rollers is formed complementary to the one roller thereof.
  • the other roller has protuberances extending about the entire circumference of the roller and being separated from each other in the longitudinal direction of the roller.
  • the rollers are arranged so that the protuberances of the one roller engage with regions separating adjacent protuberances of the other roller, etc.
  • the apparatus of the present invention may alternatively or additionally comprise a second pair of rollers defining a second nip for introducing the tissue web, the second nip being at least as large as the thickness of the tissue web.
  • the second nip is defined and configured similar or equal to the first nip.
  • one roller of the second pair of rollers has protuberances being at least separated in a direction of the circumference of the roller.
  • protuberances in the form of columns or knobs having e.g. a rounded head are distributed about the circumference of the roller and separated from each other.
  • the other roller of the second pair of rollers is also complementary to the one roller thereof. That is, the other roller is also configured to have protuberances being at least separated from each other in a direction of the circumference of the roller and both rollers are arranged so that the protuberances engage portions between two protuberances of the other roller adjacent in a direction of the circumference of the roller.
  • the web introduced into the nip dimensioned as aforesaid in context with the first pair of rollers is flexed in the cross- machine direction.
  • the web is flexed about an axis or a plurality of axis perpendicular to the machine direction or in parallel with the cross-machine direction.
  • the arrangement of the apparatus according to the present invention enables to loosen the fibres at least on one surface of a tissue web so as to increase the softness of the surface/-s of the tissue web as well as the flexibility.
  • the protuberances of the one roller of the first pair of rollers are separated by means of grooves extending about the entire circumference of the one roller and being complementary to the protuberances.
  • This arrangement leads to an improved intermeshing between the two rollers and therefore, a more uniform flexing of the tissue web. This in turn leads to a more uniform flexibility and softness of the tissue web.
  • the protuberances of the one roller of the second pair of rollers can be separated by means of grooves at least between the protuberances, the grooves extending in the longitudinal direction of the one roller and being complementary to the protuberances.
  • the grooves are at least complementary to the two protuberances separated by the groove.
  • the protuberances of the one roller of the second pair of rollers are separated in the longitudinal direction, so that the roller somewhat looks like an alternate arrangement of gear wheels and spacers on a common axis.
  • a pair of calander rollers for calandering the tissue web after flexing and to improve its visual appearance.
  • the protuberances on the one roller of the first pair of rollers are helically formed, being divided in the center of the roller as seen in the width direction of the center axis of the roller, the two parts running away from each other to the left side of the roller and to the right side of the roller, respectively, in the longitudinal direction of the roller.
  • the roller is composed of two helically formed protuberances divided in the middle of the longitudinal direction of the roller.
  • At least one of the rollers of the first and/or second pair of roller is heated.
  • the protuberances and/or grooves of the one roller of the first and/or second pair of rollers and preferably also of the other roller are rounded.
  • the protuberances have the dimensions of for example a micro-embossing used in converting.
  • the protuberances of the one roller of the first and/or second pair of rollers have a width parallel to the width of the roller of approximately 0.2 to 1.0 mm and a height perpendicular to the width of approximately 0.2 to 1.0 mm.
  • the dimensions of the first pair of rollers and second pair of rollers is the same.
  • the width of the protuberances equals the height of the protuberances.
  • the present invention also provides a method for loosing the fibres of a raw tissue web, the method comprising the steps of introducing the tissue web into a first nip as described above and flexing the tissue web in the machine direction in the first nip.
  • the method may alternatively or additionally comprise the step of introducing the tissue web into a second nip similar to the one described above and flexing the tissue web in the cross-machine direction in the second nip.
  • the method of the present invention also comprises the step of calandering the tissue web at least subsequent the first and/or second flexing.
  • Fig. 1 shows schematically the apparatus according to one embodiment of the present invention
  • Fig. 2 shows the section A of Fig. 1 in an enlarged scale, wherein the two rollers of the second pair of rollers is depicted;
  • Fig. 3 shows a side view of the first pair of rollers shown in Fig. 1 in an enlarged scale
  • Fig. 4 shows a cross section of the first pair of rollers perpendicular to the longitudinal direction of the one roller and the other roller;
  • Fig. 5A and Fig. 5B show the raw tissue web being discharged from the paper making machine before the process of the present invention (Fig. 5A) and after the process of the present invention (Fig. 5B) .
  • an apparatus comprising a first pair of rollers and a second pair of rollers.
  • the first pair of rollers is located downstream the second pair of rollers in the machine direction MD.
  • the second pair of rollers can be located downstream the first pair of rollers in the machine direction.
  • the first pair of rollers has a first roller 3 and a second roller 4.
  • the second pair of rollers has a first roller 5 and second roller 6. All rollers 3 to 6 are disposed with their axis of rotation or center axis, respectively in parallel with a raw tissue web 7 and transverse to the machine direction (in cross-machine direction) .
  • the tissue web is transported preferably under tension in the machine direction.
  • the first pair of rollers defines between the first roller 3 and the second roller 4 a first nip 8. Similar, the first roller 5 and the second roller 6 of the second pair of rollers 2, define a second nip 9. As shown in Fig. 1, the raw tissue web 7 (hereinafter tissue web 7) is transported in the machine direction.
  • Fig. 2 shows the second pair of rollers including the first roller 5 and the second roller 6.
  • the tissue web 7 is introduced into the second nip 9 and being transported in the machine direction MD.
  • the first roller 5 of the second pair of rollers comprises protuberances 10 extending in the longitudinal direction of the roller 5, i.e. in parallel to the center axis.
  • the protuberances 10 on the roller 5 are separated to each other by a groove 11 also extending in the longitudinal direction of the roller 5.
  • the protuberances 10 could additionally be separated from each other in the longitudinal direction so that the roller would look similar to an alternate arrangement of gear wheels and spacers on a common axis.
  • the second roller 6 of the second pair of rollers is configured complementary to the roller 5 as it is depicted in Fig. 2.
  • the protuberances 10 of the roller 5 engage with grooves 11 of the roller 6 and vice versa. Consequently, if the tissue web 7 is passed through the second nip 9 in the machine direction, the tissue web is flexed about an axis in the cross machine direction, i.e. perpendicular to the machine direction.
  • the first pair of rollers 1 is depicted by a side view in enlarged scale in Fig. 3 and in a cross section perpendicular to the longitudinal direction (longitudinal cross section) of the two rollers in Fig. 4.
  • the first roller 3 of the first pair of rollers 1 has protuberances 12 extending about the entire circumference of the roller 3 and grooves 13 separating the protuberances 12 from each other in the longitudinal direction of the roller 3, the grooves 13 also extending about the entire circumference of the roller 3.
  • the second roller 4 of the first pair of rollers 1 is configured complementary to the first roller 3.
  • the second roller 4 also has protuberances 12 and grooves 13, wherein the protuberances 12 of the second roller 4 mesh with grooves 13 of the first roller 3 and vice versa. Consequently, and as depicted in Fig. 4 the tissue web 7 is flexed about an axis in parallel with the machine direction, which in Fig. 4 runs perpendicular to the drawing sheet. Please note that in Fig. 4 only half of the first roller 3 and the second roller 4 is depicted and the axes 14 and 15 represent the symmetry axis of the respective rollers.
  • the protuberances 10 and 12 of the first and second pair of rollers preferably have a width W of between app. 0,2 and 1,0 mm and a height H of between app. 0,2 and 1,0 mm. More preferred the height H equals the width and the protuberances of the first pair of rollers have substantially the same dimensions as of the second pair of rollers.
  • first nip 8 and the second nip 9 are configured as schematically depicted in the figures so as to be not smaller than the thickness of the tissue web 7.
  • the dimension of the nips 8 and 9 is configured to be equal to the thickness or the tissue web 7 or slightly larger. This leads to the fact that the raw tissue web 7 introduced in the first and second nip 8, 9 is not damaged, no pattern is formed on the tissue web and the visual appearance is not inferred. To say it in other words, the tissue web is not calandered or compressed in the nips 8 and 9.
  • Common thicknesses of raw tissue are approximately 150 to 400 ⁇ m, preferably 200 to 350 ⁇ m for TAD-Tissues, and approximately 80 to 200 ⁇ m, preferably 100 to 150 ⁇ m for tissues of the conventional drying method (Yankee-drying) . These data always refer to the thickness of one ply.
  • a tissue web is comprised of a plurality of fibres upon being discharged from the paper making machine.
  • the plurality of fibres are all oriented substantially in the machine direction MD as shown in Fig. 5A.
  • the fibres 16 at least in the outer surface regions are raised so as to stand up and being not oriented in the machine direction MD anymore.
  • the fibres 16 are also raised on the outer surfaces and are not oriented in the machine direction anymore, but parallel or angular to the cross machine direction.
  • tissue product final tissue product
  • the tissue web 7 produced by the present invention can be converted in any manner as it is known to the skilled person.

Landscapes

  • Paper (AREA)

Abstract

Apparatus for loosening the fibers (16) raw tissue web (7) before converting to the tissue product, the apparatus comprising: a first pair of rollers (1) defining a first nip (8) for introducing the tissue web (7), the first nip being at least as a large as the thickness of the tissue web, one roller (3) of the first pair of rollers having protuberances (12) extending about the entire circumference of the roller and being separated from each other in the longitudinal direction of the roller, the other roller (4) of the first pair of rollers being formed complementary to the one roller thereof, so that the tissue web is flexed in the machine direction (MD); and/or a second pair of rollers (2) defining a second nip (9) for introducing the tissue web (7), the second nip being at least as large as the thickness of the tissue web, one roller (5) of the second pair of rollers having protuberances (10) being at least separated in a direction of the circumference of the roller, the other roller (6) of the second pair of rollers being formed complementary to the one roller thereof, so that the tissue web is flexed in the cross-machine direction (CD). Further the present invention also suggests a corresponding method.

Description

Apparatus for loosening the fibres of a raw tissue web and corresponding method
Field of the invention
The present invention relates to an apparatus for loosening the fibres of a raw tissue web before converting to the tissue product and to a corresponding method.
A raw tissue web is a continuous tissue paper and tissue paper is defined as a soft absorbent paper having a low basis weight. One generally selects a basis weight of 8 to 30 g/m^, especially 10 to 25 g/m^ per ply. The total basis weight of multiple-ply tissue products is preferably equal to a maximum of 65 g/m2, more preferably to a maximum of 50 g/m^ . Its density is typically below 0.6 g/cm^, preferably below 0.30 g/cm3 and more preferably between 0.08 and 0.20 g/cm3.
The production of tissue is distinguished from paper production by the its extremely low basis weight and its much higher tensile energy absorption index (see DIN EN 12625-4 and DIN EN 12625-5) . Paper and tissue paper also differ in general with regard to the modulus of elasticity that characterizes the stress-strain properties of these planar products as a material parameter.
A tissue's high tensile energy absorption index results from the outer or inner creping. The former is produced by compression of the paper web adhering to a dry cylinder as a result of the action of a crepe doctor or in the latter instance as a result of a difference in speed between two wires ("fabrics") . This causes the still moist, plastically deformable paper web to be internally broken up by compression and shearing, thereby rendering it more stretchable under load than an uncreped paper.
Moist tissue paper webs are usually dried by the so-called Yankee drying, the through air drying (TAD) or the impulse drying method.
The fibers contained in the tissue paper are mainly cellulosic fibres, such as pulp fibers from chemical pulp (e.g. Kraft sulfite and sulfate pulps) , mechanical pulp (e.g. ground wood) , thermo mechanical pulp, chemo-mechanical pulp and/or chemo-thermo mechanical pulp (CTMP) . Pulps derived from both deciduous (hardwood) and coniferous (softwood) can be used. The fibers may also be or include recycled fibers, which may contain any or all of the above categories. The fibers can be treated with additives - such as fillers, softeners, such as quaternary ammonium compounds and binders, such as conventional dry-strength agents or wet-strength agents used to facilitate the original paper making or to adjust the properties thereof. The tissue paper may also contain other types of fibers, e.g. regenerated cellulosic fibres or synthetic fibers enhancing, for instance, strength, absorption, smoothness or softness of the paper.
Tissue paper may be converted to the final tissue product in ■many ways, for example, by embossing or laminating it into a multi-ply product, rolled or folded.
As raw tissue web in sense of the present invention it is meant the web discharged from the paper making machine before it is converted to the tissue product as before-mentioned.
Background of the invention
In the paper-making machine, the fibres are arranged in a substantially oriented manner and the dried fibres form a fibre composite, namely the raw tissue web. In the conventional art, the fibres in the raw tissue web leaving the paper-making machine are as previously mentioned substantially- oriented in the machine direction of the paper-making machine, as it is also depicted in Fig. 5A, which schematically shows a raw tissue web after leaving the papermaking machine and before being treated by method of the present invention.
Such a raw tissue web or tissue paper, respectively is depending on its basis weight relatively stiff and inflexible.
Summary of the invention
Consequently, it is the technical problem underlying the present invention to provide an apparatus and a method which are capable to increase the flexibility and decrease the stiffness of a raw tissue web before converting to the final tissue product.
This technical problem is solved by an apparatus having the features of claim 1 and a method having the features of claim 9.
The basic idea of the present invention is to loosen at least the fibres of the raw tissue web located in the surface region/-s of the tissue web so as to increase the softness on the surface of the raw tissue web and to break up the inflexible fibre composite of the raw tissue web, which is both achieved in that the raw tissue web is flexed in the machine direction and/or cross to the machine direction (cross-machine direction) . The flexing for example could be compared (merely for the sake of explanation of the invention) with pulling the raw tissue web over an edge under tension, whereby the fibres on the surface of the tissue web opposite to the surface facing the edge are raised.
This basic idea of the present invention is achieved according to the present invention by an apparatus for loosening the fibres of a raw tissue web before converting to the tissue product, wherein the apparatus comprises a first pair of rollers and/or a second pair of rollers. The first pair of rollers defines a first nip for introducing the tissue web, the first nip being at least as large as the thickness of the tissue web. In the apparatus according to the present invention, the tissue web is introduced into the first nip in a machine direction preferably under tension. As the nip is at least as large as the thickness of the tissue web, the tissue web is not compressed or calendared in the nip. Preferably", the first nip equals the thickness of the tissue web or is slightly larger. In any case, the dimensions of the nip have to be determined so that the tissue web is still flexed as described in the following while not being compressed. One roller of the first pair of rollers has protuberances extending about the entire circumference of the roller and separated from each other in the longitudinal direction of the roller. The longitudinal direction of the roller is meant to be the direction parallel to the center axis of the roller. The other roller of the first pair of rollers is formed complementary to the one roller thereof. In other words, also the other roller has protuberances extending about the entire circumference of the roller and being separated from each other in the longitudinal direction of the roller. However, the rollers are arranged so that the protuberances of the one roller engage with regions separating adjacent protuberances of the other roller, etc. (i.e. both rollers mesh) This arrangement enables that the tissue web transported through the nip of the first pair or rollers being dimensioned as aforesaid is flexed in the machine direction. That is, the tissue web introduced in the nip is flexed about an axis or a plurality of axis in parallel with the machine direction. Furthermore, the apparatus of the present invention may alternatively or additionally comprise a second pair of rollers defining a second nip for introducing the tissue web, the second nip being at least as large as the thickness of the tissue web. In particular, the second nip is defined and configured similar or equal to the first nip. Furthermore, one roller of the second pair of rollers has protuberances being at least separated in a direction of the circumference of the roller. In other words, protuberances in the form of columns or knobs having e.g. a rounded head are distributed about the circumference of the roller and separated from each other. The other roller of the second pair of rollers is also complementary to the one roller thereof. That is, the other roller is also configured to have protuberances being at least separated from each other in a direction of the circumference of the roller and both rollers are arranged so that the protuberances engage portions between two protuberances of the other roller adjacent in a direction of the circumference of the roller. By this arrangement, the web introduced into the nip dimensioned as aforesaid in context with the first pair of rollers is flexed in the cross- machine direction. In other words, the web is flexed about an axis or a plurality of axis perpendicular to the machine direction or in parallel with the cross-machine direction.
The arrangement of the apparatus according to the present invention enables to loosen the fibres at least on one surface of a tissue web so as to increase the softness of the surface/-s of the tissue web as well as the flexibility.
Preferably, the protuberances of the one roller of the first pair of rollers are separated by means of grooves extending about the entire circumference of the one roller and being complementary to the protuberances. This arrangement leads to an improved intermeshing between the two rollers and therefore, a more uniform flexing of the tissue web. This in turn leads to a more uniform flexibility and softness of the tissue web.
Similar, the protuberances of the one roller of the second pair of rollers can be separated by means of grooves at least between the protuberances, the grooves extending in the longitudinal direction of the one roller and being complementary to the protuberances. The grooves are at least complementary to the two protuberances separated by the groove. Thereby, a similar effect can be achieved as it has been pointed out above.
Preferably, the protuberances of the one roller of the second pair of rollers are separated in the longitudinal direction, so that the roller somewhat looks like an alternate arrangement of gear wheels and spacers on a common axis.
Preferably, there is arranged downstream the first and/or the second pair of rollers, a pair of calander rollers for calandering the tissue web after flexing and to improve its visual appearance.
According to another embodiment of the present invention the protuberances on the one roller of the first pair of rollers are helically formed, being divided in the center of the roller as seen in the width direction of the center axis of the roller, the two parts running away from each other to the left side of the roller and to the right side of the roller, respectively, in the longitudinal direction of the roller. In other words, the roller is composed of two helically formed protuberances divided in the middle of the longitudinal direction of the roller. Thus, the web is pulled by one helical portion to the one side and by the other helical portion to the opposite side, so that the web does not move perpendicular to the machine direction but is somewhat extended in the cross-machine direction.
Preferably, and to increase the aforementioned effect of the present invention at least one of the rollers of the first and/or second pair of roller is heated.
Furthermore, in order not to damage the tissue web and in order not to leave some kind of embossing on the tissue web after being discharged from the apparatus of the present invention, the protuberances and/or grooves of the one roller of the first and/or second pair of rollers and preferably also of the other roller are rounded.
For this reason, it is also preferable that the protuberances have the dimensions of for example a micro-embossing used in converting. Preferably, the protuberances of the one roller of the first and/or second pair of rollers have a width parallel to the width of the roller of approximately 0.2 to 1.0 mm and a height perpendicular to the width of approximately 0.2 to 1.0 mm. Preferably, the dimensions of the first pair of rollers and second pair of rollers is the same. Furthermore, it is also preferred that the width of the protuberances equals the height of the protuberances.
In addition, the present invention also provides a method for loosing the fibres of a raw tissue web, the method comprising the steps of introducing the tissue web into a first nip as described above and flexing the tissue web in the machine direction in the first nip. Furthermore, the method may alternatively or additionally comprise the step of introducing the tissue web into a second nip similar to the one described above and flexing the tissue web in the cross-machine direction in the second nip.
Preferably, the method of the present invention also comprises the step of calandering the tissue web at least subsequent the first and/or second flexing.
Brief description of the drawings
In the following, the present invention is described in more detail referring to a preferred exemplary embodiment of the present invention and the accompanying drawings, in which: Fig. 1 shows schematically the apparatus according to one embodiment of the present invention;
Fig. 2 shows the section A of Fig. 1 in an enlarged scale, wherein the two rollers of the second pair of rollers is depicted;
Fig. 3 shows a side view of the first pair of rollers shown in Fig. 1 in an enlarged scale;
Fig. 4 shows a cross section of the first pair of rollers perpendicular to the longitudinal direction of the one roller and the other roller;
Fig. 5A and Fig. 5B show the raw tissue web being discharged from the paper making machine before the process of the present invention (Fig. 5A) and after the process of the present invention (Fig. 5B) .
Description of the preferred embodiment of the invention
Referring to Fig. 1, an apparatus according to one exemplary embodiment of the present invention is shown comprising a first pair of rollers and a second pair of rollers. In the shown embodiment the first pair of rollers is located downstream the second pair of rollers in the machine direction MD. However, alternatively also the second pair of rollers can be located downstream the first pair of rollers in the machine direction. The first pair of rollers has a first roller 3 and a second roller 4. Similar, the second pair of rollers has a first roller 5 and second roller 6. All rollers 3 to 6 are disposed with their axis of rotation or center axis, respectively in parallel with a raw tissue web 7 and transverse to the machine direction (in cross-machine direction) . The tissue web is transported preferably under tension in the machine direction. The first pair of rollers defines between the first roller 3 and the second roller 4 a first nip 8. Similar, the first roller 5 and the second roller 6 of the second pair of rollers 2, define a second nip 9. As shown in Fig. 1, the raw tissue web 7 (hereinafter tissue web 7) is transported in the machine direction.
In Fig. 2 the section A in Fig. 1 is depicted in an enlarged scale. Thus, Fig. 2 shows the second pair of rollers including the first roller 5 and the second roller 6. The tissue web 7 is introduced into the second nip 9 and being transported in the machine direction MD. The first roller 5 of the second pair of rollers comprises protuberances 10 extending in the longitudinal direction of the roller 5, i.e. in parallel to the center axis. The protuberances 10 on the roller 5 are separated to each other by a groove 11 also extending in the longitudinal direction of the roller 5. In an alternative embodiment the protuberances 10 could additionally be separated from each other in the longitudinal direction so that the roller would look similar to an alternate arrangement of gear wheels and spacers on a common axis.
The second roller 6 of the second pair of rollers is configured complementary to the roller 5 as it is depicted in Fig. 2. In other words, the protuberances 10 of the roller 5 engage with grooves 11 of the roller 6 and vice versa. Consequently, if the tissue web 7 is passed through the second nip 9 in the machine direction, the tissue web is flexed about an axis in the cross machine direction, i.e. perpendicular to the machine direction.
The first pair of rollers 1 is depicted by a side view in enlarged scale in Fig. 3 and in a cross section perpendicular to the longitudinal direction (longitudinal cross section) of the two rollers in Fig. 4. The first roller 3 of the first pair of rollers 1 has protuberances 12 extending about the entire circumference of the roller 3 and grooves 13 separating the protuberances 12 from each other in the longitudinal direction of the roller 3, the grooves 13 also extending about the entire circumference of the roller 3. As best viewed in Fig. 4, the second roller 4 of the first pair of rollers 1 is configured complementary to the first roller 3. That is, the second roller 4 also has protuberances 12 and grooves 13, wherein the protuberances 12 of the second roller 4 mesh with grooves 13 of the first roller 3 and vice versa. Consequently, and as depicted in Fig. 4 the tissue web 7 is flexed about an axis in parallel with the machine direction, which in Fig. 4 runs perpendicular to the drawing sheet. Please note that in Fig. 4 only half of the first roller 3 and the second roller 4 is depicted and the axes 14 and 15 represent the symmetry axis of the respective rollers.
The protuberances 10 and 12 of the first and second pair of rollers preferably have a width W of between app. 0,2 and 1,0 mm and a height H of between app. 0,2 and 1,0 mm. More preferred the height H equals the width and the protuberances of the first pair of rollers have substantially the same dimensions as of the second pair of rollers.
Furthermore, the first nip 8 and the second nip 9 are configured as schematically depicted in the figures so as to be not smaller than the thickness of the tissue web 7. Preferably, the dimension of the nips 8 and 9 is configured to be equal to the thickness or the tissue web 7 or slightly larger. This leads to the fact that the raw tissue web 7 introduced in the first and second nip 8, 9 is not damaged, no pattern is formed on the tissue web and the visual appearance is not inferred. To say it in other words, the tissue web is not calandered or compressed in the nips 8 and 9. Common thicknesses of raw tissue are approximately 150 to 400 μm, preferably 200 to 350 μm for TAD-Tissues, and approximately 80 to 200 μm, preferably 100 to 150 μm for tissues of the conventional drying method (Yankee-drying) . These data always refer to the thickness of one ply. By flexing the tissue web 7 in the first nip 8 and the second nip 9 in the machine direction and the cross machine direction the softness and flexibility of the tissue web 7 is increased compared to a tissue web from a conventional paper making machine.
The effect achieved by the apparatus and the method of the present invention will be explained in the following with reference to Figs. 5A and 5B. A tissue web is comprised of a plurality of fibres upon being discharged from the paper making machine. The plurality of fibres are all oriented substantially in the machine direction MD as shown in Fig. 5A. After the web is flexed in the second nip 9, the fibres 16 at least in the outer surface regions are raised so as to stand up and being not oriented in the machine direction MD anymore. Furthermore, by flexing the tissue web 7 in the first nip 8 the fibres 16 are also raised on the outer surfaces and are not oriented in the machine direction anymore, but parallel or angular to the cross machine direction. Consequently, by means of the apparatus of the present invention and the method of the present invention the softness and the flexibility of the tissue web is increased. However, it is to be expected that the rigidity of the tissue web 7 is reduced compared to the tissue web shown in Fig. 5A being discharged from the conventional paper making machine. In contrast, it is to be expected that the absorbency is increased. Consequently, it will be preferable for a tissue product (final tissue product) to be comprised of one ply manufactured by the apparatus or the method of the present invention and another ply being manufactured in a conventional manner, so that the conventional ply increases the rigidity of the overall product, whereas the new and inventive ply according to the present invention increases softness and flexibility of the overall product . Furthermore, it is to be noted that the tissue web 7 produced by the present invention can be converted in any manner as it is known to the skilled person.
It is to be understood that the present invention has been explained by means of the embodiment shown in the figures for the purpose of explaining the principles of the invention only and the detailed description is not to be considered as limiting the scope of the invention to this embodiment, but the scope of the invention is defined by the appended claims. In fact, various modifications and variations will be apparent to the skilled person.

Claims

1. Apparatus for loosening the fibers (16) of a raw tissue web (7) before converting to the tissue product, the apparatus comprising: a first pair of rollers (1) defining a first nip (8) for introducing the tissue web (7) , the first nip being at least as a large as the thickness of the tissue web, one roller (3) of the first pair of rollers having protuberances (12) extending about the entire circumference of the roller and being separated from each other in the longitudinal direction of the roller, the other roller (4) of the first pair of rollers being formed complementary to the one roller thereof, so that the tissue web is flexed in the machine direction
(MD) ; and/or a second pair of rollers (2) defining a second nip (9) for introducing the tissue web (7) , the second nip being at least as large as the thickness of the tissue web, one roller
(5) of the second pair of rollers having protuberances (10) being at least separated in a direction of the circumference of the roller, the other roller (6) of the second pair of rollers being formed complementary to the one roller thereof, so that the tissue web is flexed in the cross-machine direction (CD) .
2. Apparatus according to claim 1, wherein the protuberances (12) of the one roller of the first pair of rollers (1) are separated by means of grooves (13) extending about the entire circumference of the one roller and being complementary to the protuberances (12) .
3. Apparatus according to claim 1 or 2, wherein the protuberances of the one roller (5) of the second pair of rollers (2) are separated by means of grooves (11) at least between the protuberances (10) , the grooves extending in the longitudinal direction of the one roller and being at least complementary to the two protuberances (10) separated by the groove.
4. Apparatus according to any one of the preceding claims, wherein the protuberances (10) of the one roller (5) of the second pair of rollers (2) are separated in the longitudinal direction.
5. Apparatus according to any one of the preceding claims, further comprising a pair of calander rollers downstream of the first (1) and/or the second (2) pair of rollers.
6. Apparatus according to any one of the preceding claims, wherein the protuberances on the one roller (3) of the first pair of rollers (1) are helically formed, being divided in the center of the roller as seen in a width direction of the center axis of the roller, the two parts running away from each other to the left side of the roller and to the right side of the roller, respectively, in the longitudinal direction of the roller.
7. Apparatus according to any one of the preceding claims, wherein at least one of the rollers (3, 4, 5, 6) of the first
(1) and/or second (2) pair of rollers is heated.
8. Apparatus according to any one of the preceding claims, wherein the protuberances (10, 12) and/or grooves (11, 13) of the one roller (3, 5) of the first (1) and/or second (2) pair of rollers are rounded.
9. Apparatus according to any one of the preceding claims, wherein the protuberances (10, 12) of the one roller (3, 5) of the first (1) and/or second (2) pair of rollers have a width parallel to the width of the roller of approximately 0.2 to 1.0 mm and a height perpendicular to the width of approximately 0.2 to 1.0 mm.
10. Apparatus according to claim 9, wherein the width of the protuberances (10, 12) equals the height of the protuberances
(10, 12) .
11. Method for loosening the fibers (16) of a raw tissue web (7) , the method comprising the steps of:
Introducing the tissue web (7) into a first nip (8) formed by a first pair of rollers without compressing the tissue web between the rollers, one roller (3) of the first pair of rollers being formed by arranging protuberances (12) extending about the entire circumference of the roller and being separated in the longitudinal direction of the one roller, the other roller (4) being complementary to the one roller;
Flexing the tissue web in the machine direction (MD) in the first nip (8) ; and/or
Introducing the tissue web (7) into a second nip (9) formed by a second pair of rollers (2) without compressing the tissue web between the rollers, one roller (5) of the second pair of rollers being formed arranging protuberances (10) being separated in the direction of the circumference of the one roller, the other roller (6) being complementary to the one roller;
Flexing the tissue web (7) in the cross-machine (CD) direction in the second nip (9) .
12. Method according to claim 11, further comprising the step of calandering the tissue web (7) at least subsequent step of first and/or second flexing.
EP04790182A 2004-10-07 2004-10-07 Apparatus for loosening the fibres of a raw tissue web and corresponding method Expired - Lifetime EP1797239B1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/EP2004/011225 WO2006037365A1 (en) 2004-10-07 2004-10-07 Apparatus for loosening the fibres of a raw tissue web and corresponding method

Publications (2)

Publication Number Publication Date
EP1797239A1 true EP1797239A1 (en) 2007-06-20
EP1797239B1 EP1797239B1 (en) 2009-01-21

Family

ID=34959004

Family Applications (1)

Application Number Title Priority Date Filing Date
EP04790182A Expired - Lifetime EP1797239B1 (en) 2004-10-07 2004-10-07 Apparatus for loosening the fibres of a raw tissue web and corresponding method

Country Status (5)

Country Link
EP (1) EP1797239B1 (en)
AT (1) ATE421612T1 (en)
DE (1) DE602004019257D1 (en)
ES (1) ES2319773T3 (en)
WO (1) WO2006037365A1 (en)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4236963A (en) * 1978-11-21 1980-12-02 Beloit Corporation Apparatus for texturing untextured dry tissue web
CA2101865C (en) * 1993-04-12 2007-11-13 Richard Joseph Kamps Method for making soft tissue
EP1232854B2 (en) * 2001-02-16 2008-07-09 The Procter & Gamble Company Method of making a thick and smooth embossed tissue

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO2006037365A1 *

Also Published As

Publication number Publication date
ES2319773T3 (en) 2009-05-12
WO2006037365A1 (en) 2006-04-13
ATE421612T1 (en) 2009-02-15
DE602004019257D1 (en) 2009-03-12
EP1797239B1 (en) 2009-01-21

Similar Documents

Publication Publication Date Title
De Assis et al. Understanding the effect of machine technology and cellulosic fibers on tissue properties–A review
US6348131B1 (en) Multi-ply embossed absorbent paper products
US7037406B2 (en) Cross-machine direction embossing of absorbent paper products having an undulatory structure including ridges extending in the machine direction
US5164045A (en) Soft, high bulk foam-formed stratified tissue and method for making same
US7731819B2 (en) Method of making creped towel and tissue incorporating high yield fiber
KR100303605B1 (en) Soft tissue
US8012309B2 (en) Method of making wet embossed paperboard
US8647105B2 (en) Embossing system and product made thereby with both perforate bosses in the cross machine direction and a macro pattern
US6455129B1 (en) Single-ply embossed absorbent paper products
US10344432B2 (en) Absorbent paper product and method for manufacturing such absorbent paper product
HU218422B (en) Apparatus used in manufacturing a cellulosie fibrous structure and cellulosic fibrous structure made thereon
WO2009077001A1 (en) Method for pulp preparation and pulp treatment and a paper, especially a tissue paper
WO2008003343A1 (en) Method of making an absorbent structure as a multi layer paper, especially a tissue paper
WO2014049839A1 (en) Facial tissue product, and method for producing same
JP2014073420A (en) Toilet paper product
MXPA05004184A (en) Fabric with three vertically stacked wefts with twinned forming wefts.
EP1797239B1 (en) Apparatus for loosening the fibres of a raw tissue web and corresponding method
JP5495459B1 (en) Manufacturing method of toilet paper products
EP1099539B1 (en) Multi-ply/single ply embossed absorbent paper products
WO2023214114A1 (en) Boosting the cross-machine direction shrinkage and extensibility of a fiber product
WO2020229737A1 (en) Fiber formulation, its use and method for making it
KR20090019793A (en) Multi-layer woven creping fabric

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20070301

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PL PT RO SE SI SK TR

DAX Request for extension of the european patent (deleted)
17Q First examination report despatched

Effective date: 20080215

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: SE

Ref legal event code: TRGR

REF Corresponds to:

Ref document number: 602004019257

Country of ref document: DE

Date of ref document: 20090312

Kind code of ref document: P

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2319773

Country of ref document: ES

Kind code of ref document: T3

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090121

NLV1 Nl: lapsed or annulled due to failure to fulfill the requirements of art. 29p and 29m of the patents act
PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090121

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090121

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090121

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090622

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090121

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090121

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090121

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090121

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090121

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090121

26N No opposition filed

Effective date: 20091022

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090421

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20091030

Year of fee payment: 6

Ref country code: ES

Payment date: 20091016

Year of fee payment: 6

Ref country code: FI

Payment date: 20091021

Year of fee payment: 6

Ref country code: SE

Payment date: 20091026

Year of fee payment: 6

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20091028

Year of fee payment: 6

Ref country code: IT

Payment date: 20091013

Year of fee payment: 6

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20091031

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20091031

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20091031

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090422

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20091007

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20091007

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20101007

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090722

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20101102

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20110630

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20101007

Ref country code: FI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20101007

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090121

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 602004019257

Country of ref document: DE

Effective date: 20110502

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20101008

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20090121

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20090917

Year of fee payment: 6

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20111118

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20101007

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20101008

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110502