EP1797168A1 - Liquid composition - Google Patents

Liquid composition

Info

Publication number
EP1797168A1
EP1797168A1 EP05761375A EP05761375A EP1797168A1 EP 1797168 A1 EP1797168 A1 EP 1797168A1 EP 05761375 A EP05761375 A EP 05761375A EP 05761375 A EP05761375 A EP 05761375A EP 1797168 A1 EP1797168 A1 EP 1797168A1
Authority
EP
European Patent Office
Prior art keywords
bottle
oil
bleaching composition
bleaching
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP05761375A
Other languages
German (de)
French (fr)
Other versions
EP1797168B1 (en
Inventor
D. Reckitt Benckiser Produktions GmbH FREGONESE
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Reckitt Benckiser NV
Original Assignee
Reckitt Benckiser NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=33042401&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP1797168(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Reckitt Benckiser NV filed Critical Reckitt Benckiser NV
Priority to PL05761375T priority Critical patent/PL1797168T3/en
Publication of EP1797168A1 publication Critical patent/EP1797168A1/en
Application granted granted Critical
Publication of EP1797168B1 publication Critical patent/EP1797168B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions

Definitions

  • the present invention relates to a liquid detergent composition.
  • Detergent compositions are well known. Typical detergent compositions include a source of active oxygen. For example, peroxygen compounds are often included in detergent compositions to improve their stain-removing properties.
  • Peroxygen compounds are relatively unstable and tend to decompose on storage. Thus, bleaching compositions containing such compounds tend to lose their bleaching power during storage. Additionally bleaching compositions are usually quite aggressive to other more sensitive components of a detergent formulation (e.g. enzymes) and need to be kept separate therefrom
  • a multi-chamber bottle comprising in one chamber a bleaching composition and in another chamber a bleach sensitive formulation, the viscosity of the bleaching composition being controlled by an admixture of a thickener and a hydrocarbon, and the density of the bleaching composition being controlled by the presence of an ionic salt.
  • the viscosity of the contents of the bleaching formulation containing chamber has been found to remain constant even with prolonged storage.
  • the bleaching composition comprises phthalimidoperhexanoic acid (PAP) as the bleaching component (e.g. as available from Solvay Solexis) .
  • PAP phthalimidoperhexanoic acid
  • the PAP is supplied as a stable water suspension at, for example, a concentration of 17%.
  • the PAP suspension comprises from 10-50% of the bleaching composition, more preferably from 20-40% and most preferably about 30%.
  • the PAP preferably has a particle size of about 50 ⁇ m.
  • the hydrocarbon component of the bleaching composition comprises paraffin (Ci 5 -C 24 ) .
  • the paraffin content of the bleaching composition is about 2%.
  • the thickener of the bleaching composition is cellulose based, e.g. a xanthan gum (e.g. as available from Monsanto, US or ADM US) .
  • the xanthan gum content of the bleaching composition is about 0.5%.
  • the ionic salt present in the bleaching composition is present in an amount of from 3-35%, more preferably from 5 to 20% and most preferably about 10%.
  • the ionic salt is sodium sulphate.
  • the contents of the multi-chamber bottle are intended to be used as a detergent in an automatic washing machine, e.g. an automatic dishwasher.
  • an automatic dishwasher detergent formulation As such the combined composition formed by combining the contents of the chambers of the bottle generally comprises an automatic dishwasher detergent formulation
  • the detergent most preferably comprises an automatic dishwasher detergent.
  • automatic dishwasher detergent examples include conventional detergents, and the ⁇ 2-in-l' and ⁇ 3- in-1' variants.
  • the detergent formulation typically comprises one or more of the following components; builder, co-builder, surfactant, bleach activator, bleach catalyst, enzyme, polymer, dye, pigment, fragrance, water and organic solvent.
  • fragrance and enzyme may be bleach sensitive and thus may be confined to the bleach sensitive chamber of the bottle.
  • compositions Being intended to be placed in a bottle the composition are most preferably liquid.
  • the liquid compositions are preferably aqueous.
  • the bottle is twin-chambered.
  • the bleaching composition was stored (storage conditions set out in the table below) and its viscosity was measured after time. The results are in the table below
  • the viscosity of a comparative composition (without paraffin oil) was also measured.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Jellies, Jams, And Syrups (AREA)

Abstract

A multi-chamber bottle comprises in one chamber a bleaching composition and in another chamber a bleach sensitive formulation. The viscosity of the bleaching composition is controlled by an admixture of a thickener and a hydrocarbon. The density of the bleaching composition is controlled by the presence of an ionic salt.

Description

Liquid Composition
The present invention relates to a liquid detergent composition.
Detergent compositions are well known. Typical detergent compositions include a source of active oxygen. For example, peroxygen compounds are often included in detergent compositions to improve their stain-removing properties.
Peroxygen compounds, however, are relatively unstable and tend to decompose on storage. Thus, bleaching compositions containing such compounds tend to lose their bleaching power during storage. Additionally bleaching compositions are usually quite aggressive to other more sensitive components of a detergent formulation (e.g. enzymes) and need to be kept separate therefrom
Separation in solid formulations is straightforward and may be achieved by the use of multi-phase solids such as multi layer tablets wherein one layer contains a bleach and another layer contains a bleach sensitive component such as an enzyme.
Separation in liquids is more difficult. One way to achieve this separation is by the use of a multi-chamber bottle with one chamber of the bottle containing a bleaching formulation and another chamber containing a bleach sensitive formulation. However, a recognised problem with the use of multi- chamber bottles is the difficulty that can be experienced trying to achieve equal / appropriate discharge of each of the chambers so that the right amount of composition from each chamber is dispensed into the washing machine.
It is an object of the present invention to obviate / mitigate the problems outlined above.
According to the present invention, there is provided a multi-chamber bottle comprising in one chamber a bleaching composition and in another chamber a bleach sensitive formulation, the viscosity of the bleaching composition being controlled by an admixture of a thickener and a hydrocarbon, and the density of the bleaching composition being controlled by the presence of an ionic salt.
Surprisingly it has been found that by using the viscosity and density controlling agents above, equal / appropriate release of each of the formulations may be achieved over time (i.e. over prolonged storage / transportation) and throughout the use of the bottle. Without wishing to be bound by theory it is proposed that the even discharge of the two formulations from the bottle of the present invention arises from a firm control of their relative pourability (a function of viscosity (η) and density (δ) ) .
Also the viscosity of the contents of the bleaching formulation containing chamber has been found to remain constant even with prolonged storage. Generally the bleaching composition comprises phthalimidoperhexanoic acid (PAP) as the bleaching component (e.g. as available from Solvay Solexis) .
Usually the PAP is supplied as a stable water suspension at, for example, a concentration of 17%. Usually the PAP suspension comprises from 10-50% of the bleaching composition, more preferably from 20-40% and most preferably about 30%.
The PAP preferably has a particle size of about 50 μm.
Preferably the hydrocarbon component of the bleaching composition comprises paraffin (Ci5-C24) .
Generally the paraffin content of the bleaching composition is about 2%.
Preferably the thickener of the bleaching composition is cellulose based, e.g. a xanthan gum (e.g. as available from Monsanto, US or ADM US) .
Generally the xanthan gum content of the bleaching composition is about 0.5%.
Preferably the ionic salt present in the bleaching composition is present in an amount of from 3-35%, more preferably from 5 to 20% and most preferably about 10%.
Most preferably the ionic salt is sodium sulphate. A-
Generally the contents of the multi-chamber bottle are intended to be used as a detergent in an automatic washing machine, e.g. an automatic dishwasher. As such the combined composition formed by combining the contents of the chambers of the bottle generally comprises an automatic dishwasher detergent formulation
Accordingly the detergent most preferably comprises an automatic dishwasher detergent. Examples of which include conventional detergents, and the λ2-in-l' and λ3- in-1' variants.
The detergent formulation typically comprises one or more of the following components; builder, co-builder, surfactant, bleach activator, bleach catalyst, enzyme, polymer, dye, pigment, fragrance, water and organic solvent.
Of these components it will be appreciated that some (e.g. fragrance and enzyme may be bleach sensitive) and thus may be confined to the bleach sensitive chamber of the bottle.
Being intended to be placed in a bottle the composition are most preferably liquid. The liquid compositions are preferably aqueous.
Generally the bottle is twin-chambered.
The invention will now be described with reference to the following non-limiting examples. Example 1
The following bleach containing and bleach sensitive compositions were prepared.
Bleach Containing
Bleach Sensitive
The bleaching composition was stored (storage conditions set out in the table below) and its viscosity was measured after time. The results are in the table below
The viscosity of a comparative composition (without paraffin oil) was also measured.
The results are in the table below.
2% of paraffin oil in the bleach formulation is enough to keep the viscosity within a very narrow range.

Claims

1. A multi-chamber bottle comprising in one chamber a bleaching composition and in another chamber a bleach sensitive formulation, the viscosity of the bleaching composition being controlled by an admixture of thickener and a hydrocarbon, and the density of the bleaching composition being controlled by the presence of an ionic salt.
2. A bottle as in claim 1, where in the bleaching composition comprises phthalimidoperhexanoic acid (PAP) as the bleaching component.
3. A bottle as in claim 2, wherein the PAP comprises about 30% of the bleaching composition.
4. A bottle as in claim 1, 2 or 3, wherein the hydrocarbon component of the bleaching composition comprises paraffin.
5. A bottle as in claim 4, wherein the paraffin content of the bleaching composition is about 2%.
6. A bottle as in any one of the preceding claims, wherein the thickener of the bleaching composition is cellulose based, e.g. a xanthan gum.
7. A bottle as in claim 6, wherein the xanthan gum content of the bleaching composition is about 0.5%.
8. A bottle as in claim 7, wherein the ionic salt present in the bleaching composition is present in an amount of about
10%.
9. A bottle as in claim 8, wherein the ionic salt is sodium sulphate.
10. A bottle as in any one of the previous claims wherein a composition (the bleach containing and / or the bleach sensitive composition) includes a hydrophobic component having a density of from 0.6-1 gram/cm3, more preferably 0.7-0.92 grams cm3, more preferably 0.75-0.92 grams cm3, more preferably 0.8-0.92 grams cm3, more preferably 0.85-0.92 grams cm3, and most preferably from 0.85-0.87 grams cm3.
11. A bottle in accordance with claim 10, wherein the viscosity of the hydrophobic component is less than 300 cp, more preferably between 50- 250 cp, more preferably between 75 to 150 cp, and most preferably from 95-100 cp.
12. A bottle in accordance with claim 10 or 11, wherein the hydrophobic component is a hydrocarbon oil, an edible oil, or a mixture thereof.
13. A bottle in accordance with claim 12 wherein the oil is olive oil, sunflower oil, ,maize oil, rape oil, soya oil, peanut oil, meadowfoam seed oil, linseed oil, walnut oil, sesame oil, thistle oil or a mixture thereof.
14. A bottle in accordance with claim 13, wherein the hydrophobic component is a paraffin oil, e.g. squalene.
15. Use of the bottle as in any one of claims 1 to 14 in an automatic dishwashing process.
EP05761375A 2004-08-20 2005-07-22 Liquid composition Expired - Lifetime EP1797168B1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
PL05761375T PL1797168T3 (en) 2004-08-20 2005-07-22 Liquid composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0418625A GB2417250A (en) 2004-08-20 2004-08-20 Multi-chamber bottle containg a liquid detergent composition
PCT/GB2005/002870 WO2006018596A1 (en) 2004-08-20 2005-07-22 Liquid composition

Publications (2)

Publication Number Publication Date
EP1797168A1 true EP1797168A1 (en) 2007-06-20
EP1797168B1 EP1797168B1 (en) 2008-07-02

Family

ID=33042401

Family Applications (1)

Application Number Title Priority Date Filing Date
EP05761375A Expired - Lifetime EP1797168B1 (en) 2004-08-20 2005-07-22 Liquid composition

Country Status (13)

Country Link
US (1) US20080269098A1 (en)
EP (1) EP1797168B1 (en)
CN (1) CN101006168A (en)
AT (1) ATE399850T1 (en)
AU (1) AU2005273764B2 (en)
BR (1) BRPI0514434A (en)
CA (1) CA2577506A1 (en)
DE (1) DE602005007921D1 (en)
ES (1) ES2306178T3 (en)
GB (1) GB2417250A (en)
PL (1) PL1797168T3 (en)
WO (1) WO2006018596A1 (en)
ZA (1) ZA200701047B (en)

Families Citing this family (12)

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DE102005054565A1 (en) * 2005-11-14 2007-05-16 Henkel Kgaa Oxidizing agent containing fragrant consumer products
ATE444350T1 (en) * 2006-08-23 2009-10-15 Mifa Ag Frenkendorf LIQUID BLEACH COMPOSITION
US8338352B2 (en) * 2007-05-07 2012-12-25 Ecolab Usa Inc. Solidification matrix
US8759269B2 (en) * 2007-07-02 2014-06-24 Ecolab Usa Inc. Solidification matrix including a salt of a straight chain saturated mono-, di-, and tri- carboxylic acid
US8138138B2 (en) * 2008-01-04 2012-03-20 Ecolab Usa Inc. Solidification matrix using a polycarboxylic acid polymer
US8772221B2 (en) 2008-01-04 2014-07-08 Ecolab Usa Inc. Solidification matrices using phosphonocarboxylic acid copolymers and phosphonopolyacrylic acid homopolymers
US8198228B2 (en) * 2008-01-04 2012-06-12 Ecolab Usa Inc. Solidification matrix using an aminocarboxylate
DE102009046217A1 (en) * 2009-10-30 2011-05-12 Henkel Ag & Co. Kgaa Liquid machine dishwashing detergent
US8530403B2 (en) * 2009-11-20 2013-09-10 Ecolab Usa Inc. Solidification matrix using a maleic-containing terpolymer binding agent
US20110124547A1 (en) * 2009-11-23 2011-05-26 Ecolab Inc. Solidification matrix using a sulfonated/carboxylated polymer binding agent
GB2496132A (en) * 2011-10-31 2013-05-08 Reckitt Benckiser Nv Pthalimidopercaproic acid sugar suspension
PL2794836T3 (en) 2011-12-22 2016-12-30 Detergent composition comprising glutamic-n,n-diacetate, water and bleaching agent

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US4606775A (en) * 1984-04-05 1986-08-19 Purex Corporation Automatic dishwasher in a dual functioning system
GB8910725D0 (en) * 1989-05-10 1989-06-28 Unilever Plc Bleach activation and bleaching compositions
EP0435379A3 (en) * 1989-12-22 1991-07-31 Akzo N.V. Suspension, coating, agglomeration and uses of imidoperoxycarboxylic acids
US5824630A (en) * 1993-07-16 1998-10-20 The Procter & Gamble Company Machine dishwashing composition containing oxygen bleach and paraffin oil and nitrogen compound silver tarnishing inhibitors
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Also Published As

Publication number Publication date
BRPI0514434A (en) 2008-06-10
EP1797168B1 (en) 2008-07-02
US20080269098A1 (en) 2008-10-30
GB2417250A (en) 2006-02-22
ATE399850T1 (en) 2008-07-15
ZA200701047B (en) 2008-08-27
CN101006168A (en) 2007-07-25
AU2005273764B2 (en) 2011-03-24
GB0418625D0 (en) 2004-09-22
PL1797168T3 (en) 2008-12-31
WO2006018596A1 (en) 2006-02-23
DE602005007921D1 (en) 2008-08-14
ES2306178T3 (en) 2008-11-01
AU2005273764A1 (en) 2006-02-23
CA2577506A1 (en) 2006-02-23

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