EP1778028A1 - Powdered sweetener for human nutrition - Google Patents

Powdered sweetener for human nutrition

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Publication number
EP1778028A1
EP1778028A1 EP05760847A EP05760847A EP1778028A1 EP 1778028 A1 EP1778028 A1 EP 1778028A1 EP 05760847 A EP05760847 A EP 05760847A EP 05760847 A EP05760847 A EP 05760847A EP 1778028 A1 EP1778028 A1 EP 1778028A1
Authority
EP
European Patent Office
Prior art keywords
sweetener
nhdc
mixture
vanillin
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP05760847A
Other languages
German (de)
French (fr)
Inventor
Denis Felisaz
Nathalie Sinet
Carole Thieblemont
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Pancosma SA
Original Assignee
Pancosma SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Pancosma SA filed Critical Pancosma SA
Priority to EP05760847A priority Critical patent/EP1778028A1/en
Publication of EP1778028A1 publication Critical patent/EP1778028A1/en
Withdrawn legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
    • A23L27/30—Artificial sweetening agents
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs

Definitions

  • the present invention relates to a powdered sweetener for human nutrition with a sensory character bringing it closer to the taste of sugar.
  • Table sugar consisting mainly of sucrose or sucrose, is the most popular sweetener for its taste properties but is rich in calories. In many food products, we therefore seek to replace it with sweeteners or sweeteners less rich in calories whose sensory character is similar to the taste of sugar.
  • powdered sweeteners for human consumption are composed of a statistical mixture of several powders of very different particle sizes, namely sweeteners of a relatively coarse particle size and mixed with a potentiator in the form of a powder. much finer.
  • the sweetener that is, the sweet flavoring agent, is usually saccharin or sodium or calcium saccharinate, sometimes other intense sweeteners of natural or artificial origin.
  • the role of the potentiator is twofold. First, as its name indicates, it has the effect of prolonging the perception of the sweet taste which, in its absence, would be too fleeting. a good potentiator, such as those used conventionally, can increase the sweet perception over time by about 50 to 80%. The other effect of the potentiator, and not least, is to mask the secondary or parasitic flavors of the sweetener, for example to mask the bitter and metallic taste of saccharin or its sodium and calcium salts.
  • sweetener to designate the sweetener / potentiator mixture that is the subject of the invention, as well as the corresponding traditional products that will serve as a comparison, while we will use the expression "sweetening formulation" or
  • sweetening premix when the sweetener itself is dispersed in a carrier. This sweetening formulation, a sort of condiment such as salt or pepper, will then be incorporated into the final food.
  • Traditional sweeteners are statistical mixtures of one or more sweeteners and one or more potentiators which, as already indicated above, the particle sizes are very different. Despite the care that can be brought to their realization, it can only result in mixtures with a high degree of heterogeneity.
  • EP928564 proposes a process for the preparation of human food powder sweetener comprising the preparation of a mixture in solution of a sweetener and a potentiator, and then the spraying of this mixture by atomizing drying to obtain a powder.
  • the powder sweetener thus obtained is in the form of an intimate mixture whose sweetener / potentiator distribution is substantially homogeneous, non-statistical, and whose proportion of the sweetener relative to the potentiator is substantially constant and equal to one particle of powder to another.
  • sweetener compositions in which the sweetener is selected from the group consisting of sodium or calcium saccharinates, saccharin, aspartame, acesulfame, cyclamates and stevioside, and mixtures thereof, and the potentiator is chosen from the group comprising thaumatin, neohesperidin dihydrochalcone (NHDC), glycyrrhizin, and mixtures thereof, the sweetener / potentiator proportion being between 99.95 / 0.05 and 85/15, in parts by weight.
  • NHDC neohesperidin dihydrochalcone
  • glycyrrhizin glycyrrhizin
  • These sweetener compositions provide significant progress over traditional sweetener compositions because they provide a consistent taste for the sweetening formulations obtained by dispersing them on a support.
  • the compositions disclosed by this document have a sensory character quite far from the taste of sugar.
  • the present invention is based on the surprising discovery that for some sweeteners a potentiator comprising a mixture of NHDC and a vanilla flavor in appropriate proportions gives the sweetness sensory character closer to the taste of sugar.
  • the invention relates to a human food powder sweetener in the form of an intimate mixture whose sweetener / potentiator distribution is substantially homogeneous, non-statistical, and whose proportion of the sweetener relative to the potentiator is the the
  • the sweetener is selected from sodium saccharinate, calcium saccharinate, saccharin and a mixture of these substances
  • the potentiator is a mixture of NHDC and a vanilla flavor
  • the amounts of the sweetener and the mixture of NHDC and a vanilla flavor are chosen so as to impart to the sweetness sensory character closer to the taste of sugar.
  • the sweetener of the invention has a sensorial character close to sugar, in particular a long-lasting sweetness with roundness and sensation in the mouth and absence of astringency or metallic or bitter aftertaste.
  • the vanilla-type aroma can be vanillin, that is to say 3-methoxy-4-hydroxybenzaldehyde, generally obtained by extraction from vanilla beans or 'by synthesis from guaiacol by condensation or lignin , ethyl-vanillin, that is to say 3-ethoxy-4-hydroxybenzaldehyde, present in the pods of certain varieties of Tahitian vanilla and usually obtained by synthesis very similar to that used for vanillin, or a another derivative of vanillin that has similar aromatic power.
  • the vanilla flavor is selected from vanillin and ethyl vanillin, vanillin being particularly preferred.
  • the weight ratio between the amounts of NHDC and vanillin is generally from 6 to 1.0, preferably from 2.5 to 1.5, in particular from 2 to , 2 to 1.8.
  • vanilla flavor is ethylvanillin
  • NHDC and vanillin are in general from 24 to 2.5, preferably from 10 to 3, in particular from 6 to 4.
  • An interesting sweetener is that which comprises, by weight, 97.6 to 99.5% sodium saccharinate, 0.40 to 2.0% NHDC and 0.10 to 0.80% aroma. vanilla type.
  • compositions of such a sweetener that are particularly interesting on the sensory level are those which comprise, by weight:
  • the sweetener powder according to the invention has a particle size of between 10 and 130 ⁇ m, with a substantially Gaussian distribution.
  • the powdered sweetener according to the invention may also contain other ingredients in small amounts, such as flavor enhancers, sodium glutamate, and nucleotides (sodium inosinate and guanylate), ethyl malol and maltol. These ingredients are part of the "micro-ingredients" that can enter the intermediate formulation of the food or premix that may also contain emulsifiers gelling, antioxidants the
  • preservatives dyes. These latter substances are generally calculated to be present at a rate of 5 to 10 kg per tonne in the final feed.
  • the powdered sweetener according to the invention can be prepared very simply, according to a well-known technology in human nutrition and in the technology of aroma production, by "micronisation”, that is to say by atomization and drying of a liquid mixture, sprayed in a suitable apparatus.
  • This apparatus may take the form of a tower in which the liquid mixture is admitted to the top by a nozzle or a turbine, the atomized powder obtained being collected at the base of the tower.
  • the tower may be filled with an inert gas to prevent oxidation phenomena.
  • the sweetener powder according to the invention can be used in two ways in the human diet. Firstly, in a conventional manner, the sweetener according to the invention may be dispersed on a support of the dextrose, silica or starch type, for example in the proportion of 10 to 75 parts by weight of sweetener for 90 to 25 parts by weight of support. On the basis of the usual values, this allows to constitute a final feed at an average dose of 300 to 3,000 g / t, preferably I 1 650 g / t, which corresponds to an amount of sweetener of order of 150 to 500 g / t and a potentiator of 0.15 to 15 g / t based on the average dose of 65O g / t.
  • the sweetener according to the invention is perfectly homogeneous and the particle size of this sweetener is sufficiently fine, there will obviously be no difficulty in obtaining a carrier-based sweetening formulation, and then a final food, too. perfectly homogeneous.
  • sweeteners are firstly dairy products such as flavored yogurt, flavored milks, ice cream, fresh or frozen desserts, puddings, mousses and creams; then powdered products, including creams, cocoa, flavored drinks, desserts and ices; non-alcoholic beverages, for example, fruit-based beverages, milk-based beverages, tonics, Cola-type beverages, alcoholic beverages such as ciders, dark beers, wine beverages; and also confectionery, acidulous, jams, chewing gums, pastries, sweets and chocolates, cereals, ice cream cones, mayonnaise, sauces, salads, snacks, soups, as well as non-caloric table sweeteners.
  • dairy products such as flavored yogurt, flavored milks, ice cream, fresh or frozen desserts, puddings, mousses and creams
  • powdered products including creams, cocoa, flavored drinks, desserts and ices
  • non-alcoholic beverages for example, fruit-based beverages, milk-based beverages, tonics, Cola-type beverages,
  • Figures 1 to 4 represent the "spider web” (cobwebs), results of quantitative descriptive sensory analysis (QDA) according to the AFNOR standard NF V 09-016 for, respectively,
  • a sodium saccharinate solution A is prepared by introducing 900 liters of water into a tank, heating to 60 ° C., then slowly adding 1000 kg of sodium saccharinate and stirring the solution for 30 minutes until the complete dissolution (the solution becomes transparent).
  • Solution B is poured slowly into solution A.
  • Rotational speed of the turbine atomization 15,000 revolutions / min, at 2O 1 OOO revolutions / min, the turbine can be replaced with an atomizing nozzle.
  • a sweetener according to the invention is thus obtained in the form of a homogeneous fine powder having a particle size with a substantially Gaussian distribution of between 10 and 130 ⁇ m with an average of 48.5 ⁇ m and comprising around 75,000,000 particles or grains per gram. This powder is soluble in water.
  • sweeteners according to the invention and the comparative sweeteners of the same composition but with no vanilla-type flavor were dissolved in Evian neutral water so as to have a sucrose equivalent of 5% and compared to sucrose solutions. 5% by a committee of 3 people chosen for their ability to identify and evaluate taste properties.
  • Sucrants 2 and 6 are those which are the closest to sucrose solutions.
  • Sucrose 2 according to the invention, sucrose, and three conventional intense sweeteners, namely sodium saccharinate, aspartame, acesulfame K have been dissolved in Evian-type water and subjected to descriptive quantitative sensory analysis tests of AFNOR Standard NF V 09-016.
  • three conventional intense sweeteners namely sodium saccharinate, aspartame, acesulfame K have been dissolved in Evian-type water and subjected to descriptive quantitative sensory analysis tests of AFNOR Standard NF V 09-016.
  • This test consists of the assignment by a committee of 8 people chosen for their ability to identify and evaluate taste properties, for each of these substances, grades of 0 to 5 for each of 9 sensory characteristics important for the taste.
  • Figure 1 is the "spider web" for sodium saccharin, aspartame, acesulfame K, sweetener 2 and sucrose.
  • Figure 2 is the "spider web" for sodium saccharin, sweetener 2 and sucrose.
  • Figure 3 is the "spider web" for aspartame, sweetener 2 and sucrose
  • Figure 4 is the "spider web" for Acesulfame K, the sweetening 2 and sucrose.
  • the sweetener of the invention has sensory characteristics that are much closer to the taste of sugar than comparison sweeteners, in particular a long-lasting sweetness with roundness and sensation in the mouth and absence of astringency or metallic or bitter aftertaste.
  • Figure 2 shows that sodium saccharin has a little more astringency and metallic taste, and less caramel taste, vanilla taste, roundness, mouthfeel, duration of sweetness and length. in the mouth than the sweetener of the invention.
  • Figure 3 shows that aspartame has more astringency and metallic taste, and less roundness, sensation in mouth, duration of sweetness and length in the mouth than the sweetener of the invention, and n has no caramel taste or vanilla taste. It tastes very far from that of sugar.
  • Figure 4 shows that acesulfame K has more astringency, less caramel taste, a little less roundness, mouthfeel and duration of sweetness than the sweetener of the invention.

Abstract

The invention concerns a powder sweetener for human food in the form of an intimate mixture whereof the sweetener/flavour enhancer distribution is substantially homogeneous, non-statistic, and whereof the proportion of sweetener relative to the flavour enhancer is substantially constant and equal in each particle. The invention is characterized in that the sweetener is selected among sodium saccharinate, calcium saccharinate, saccharine, and a mixture of those substances, and the flavour enhancer comprises a mixture of NHDC and a vanilla-type flavour, the amounts of sweetener and of the mixture of NHDC with a vanilla-type flavour being selected so as to provide the sweetener a sensory character close to the taste of sugar. The invention also concerns a method for preparing said sweetener and a granulated food formulation containing same.

Description

SUCRANT EN POUDRE POUR ALIMENTATION HUMAINE POWDER SUCKER FOR HUMAN FEEDING
La présente invention se rapporte à un sucrant en poudre pour alimentation humaine avec un caractère sensoriel le rapprochant du goût du sucre.The present invention relates to a powdered sweetener for human nutrition with a sensory character bringing it closer to the taste of sugar.
Le sucre de table, essentiellement constitué de sucrose ou saccharose, est l'édulcorant le plus apprécié pour ses propriétés gustatives mais il est riche en calories. Dans de nombreux produits pour alimentation humaine, on cherche donc à le remplacer par des sucrants ou édulcorants moins riches en calories dont le caractère sensoriel se rapproche du goût du sucre.Table sugar, consisting mainly of sucrose or sucrose, is the most popular sweetener for its taste properties but is rich in calories. In many food products, we therefore seek to replace it with sweeteners or sweeteners less rich in calories whose sensory character is similar to the taste of sugar.
Traditionnellement, les sucrants en poudre pour l'alimentation humaine sont composés d'un mélange statistique de plusieurs poudres de granulométries très différentes, à savoir d'édulcorants d'une granulométrie relativement grossière et mélangée à un potentiateur se présentant sous forme d'une poudre beaucoup plus fine. L'édulcorant, c'est-à-dire l'agent qui apporte le goût sucré est habituellement de la saccharine ou du saccharinate de sodium ou de calcium, parfois d'autres édulcorants intenses d'origine naturelle ou artificielle.Traditionally, powdered sweeteners for human consumption are composed of a statistical mixture of several powders of very different particle sizes, namely sweeteners of a relatively coarse particle size and mixed with a potentiator in the form of a powder. much finer. The sweetener, that is, the sweet flavoring agent, is usually saccharin or sodium or calcium saccharinate, sometimes other intense sweeteners of natural or artificial origin.
Le rôle du potentiateur est double. D'abord, comme son nom l'indique, il a comme effet de prolonger la perception du goût sucré qui, en son absence, serait trop fugitive. un bon potentiateur, tels que ceux utilisés classiquement, permet d'augmenter la perception sucrée dans le temps d'environ 50 à 80 %. L'autre effet du potentiateur, et non des moindres, est de masquer les goûts secondaires ou parasites de l'édulcorant, par exemple de masquer le goût amer et métallique de la saccharine ou de ses sels de sodium et de calcium. Afin de lever toute ambiguïté dans la terminologie utilisée ci-après, nous utiliserons le terme de "sucrant" pour désigner le mélange édulcorant/potentiateur, objet de l'invention, ainsi que les produits traditionnels correspondants qui serviront de comparaison, tandis que nous utiliserons l'expression "formulation sucrante" ouThe role of the potentiator is twofold. First, as its name indicates, it has the effect of prolonging the perception of the sweet taste which, in its absence, would be too fleeting. a good potentiator, such as those used conventionally, can increase the sweet perception over time by about 50 to 80%. The other effect of the potentiator, and not least, is to mask the secondary or parasitic flavors of the sweetener, for example to mask the bitter and metallic taste of saccharin or its sodium and calcium salts. In order to eliminate any ambiguity in the terminology used hereinafter, we will use the term "sweetener" to designate the sweetener / potentiator mixture that is the subject of the invention, as well as the corresponding traditional products that will serve as a comparison, while we will use the expression "sweetening formulation" or
"prémélange sucrant", lorsque le sucrant proprement dit est dispersé dans un support. Cette formulation sucrante, en quelque sorte un condiment comme le sel ou le poivre, sera ensuite incorporée dans l'aliment final."sweetening premix", when the sweetener itself is dispersed in a carrier. This sweetening formulation, a sort of condiment such as salt or pepper, will then be incorporated into the final food.
Les sucrants traditionnels sont des mélanges statistiques d'un ou plusieurs édulcorants et d'un ou plusieurs potentiateurs dont, comme déjà indiqué plus haut, les granulométries sont très différentes. Malgré le soin que l'on peut apporter à leur réalisation, il ne peut en résulter que des mélanges présentant une forte hétérogénéité.Traditional sweeteners are statistical mixtures of one or more sweeteners and one or more potentiators which, as already indicated above, the particle sizes are very different. Despite the care that can be brought to their realization, it can only result in mixtures with a high degree of heterogeneity.
Cette très forte hétérogénéité peut entraîner des variations dans le profil du goût sucré des aliments, une bouchée pouvant présenter un goût sucré à peine perceptible, tandis que la bouchée suivante peut être, elle, trop sucrée voire amère et métallique par suite des difficultés à masquer l'arrière-goût de la saccharine, en dépit de la présence du potentiateur, lorsque celle-ci est en trop forte concentration. Les formulations sucrantes à base de sucrants grossiers ne donnent ainsi que modérément satisfaction.This very high heterogeneity can lead to variations in the profile of the sweet taste of food, a bite that can have a sweet taste barely perceptible, while the next bite can be too sweet or bitter and metallic due to difficulties to hide the aftertaste of saccharin, despite the presence of the potentiator, when it is in too high concentration. The sweetening formulations based on coarse sweeteners thus give only moderately satisfaction.
Pour résoudre ce problème, la demande de brevetTo solve this problem, the patent application
EP928564 propose un procédé de préparation de sucrant en poudre pour alimentation humaine comprenant la préparation d'un mélange en solution d'un édulcorant et d'un potentiateur, puis la pulvérisation de ce mélange par atomisation séchage pour obtenir une poudre. Le sucrant en poudre ainsi obtenu se présente sous forme d'un mélange intime dont la répartition édulcorant/potentiateur est sensiblement homogène, non statistique, et dont la proportion de l'édulcorant par rapport au potentiateur est sensiblement constante et égale d'une particule de poudre à l'autre. Ce document propose différentes compositions de sucrant en poudre dans lesquelles l'édulcorant est choisi dans le groupe comprenant les saccharinates de sodium ou de calcium, la saccharine, l'aspartame, 1 'acésulfame, les cyclamates et le stévioside, et leurs mélanges, et le potentiateur est choisi dans le groupe comprenant la thaumatine, la néohespéridine dihydrochalcone (NHDC) , la glycyrrhizine, et leurs mélanges, la proportion édulcorant/potentiateur étant comprise entre 99,95/0,05 et 85/15, en parties pondérales. Ces compositions de sucrant apportent un progrès important par rapport aux compositions de sucrant traditionnelles car elles apportent un goût constant aux formulations sucrantes obtenues en les dispersant sur un support. Toutefois les compositions divulguées par ce document ont un caractère sensoriel assez éloigné du goût du sucre.EP928564 proposes a process for the preparation of human food powder sweetener comprising the preparation of a mixture in solution of a sweetener and a potentiator, and then the spraying of this mixture by atomizing drying to obtain a powder. The powder sweetener thus obtained is in the form of an intimate mixture whose sweetener / potentiator distribution is substantially homogeneous, non-statistical, and whose proportion of the sweetener relative to the potentiator is substantially constant and equal to one particle of powder to another. This document proposes various powdered sweetener compositions in which the sweetener is selected from the group consisting of sodium or calcium saccharinates, saccharin, aspartame, acesulfame, cyclamates and stevioside, and mixtures thereof, and the potentiator is chosen from the group comprising thaumatin, neohesperidin dihydrochalcone (NHDC), glycyrrhizin, and mixtures thereof, the sweetener / potentiator proportion being between 99.95 / 0.05 and 85/15, in parts by weight. These sweetener compositions provide significant progress over traditional sweetener compositions because they provide a consistent taste for the sweetening formulations obtained by dispersing them on a support. However, the compositions disclosed by this document have a sensory character quite far from the taste of sugar.
La présente invention est fondée sur la découverte surprenante que pour certains édulcorants un potentiateur comprenant un mélange de NHDC et d'un arôme de type vanille dans des proportions appropriées confère au sucrant un caractère sensoriel le rapprochant du goût du sucre.The present invention is based on the surprising discovery that for some sweeteners a potentiator comprising a mixture of NHDC and a vanilla flavor in appropriate proportions gives the sweetness sensory character closer to the taste of sugar.
L' invention concerne un sucrant en poudre pour alimentation humaine se présentant sous forme d'un mélange intime dont la répartition édulcorant/potentiateur est sensiblement homogène, non statistique, et dont la proportion de l'édulcorant par rapport au potentiateur est l'l'The invention relates to a human food powder sweetener in the form of an intimate mixture whose sweetener / potentiator distribution is substantially homogeneous, non-statistical, and whose proportion of the sweetener relative to the potentiator is the the
sensiblement constante et égale d'une particule de poudre à l'autre, caractérisé en ce que l'édulcorant est choisi parmi le saccharinate de sodium, le saccharinate de calcium, la saccharine et un mélange de ces substances, et le potentiateur est un mélange de NHDC et d'un arôme de type vanille, les quantités de l'édulcorant et du mélange de NHDC et d'un arôme de type vanille étant choisies de façon à conférer au sucrant un caractère sensoriel le rapprochant du goût du sucre.substantially constant and equal from one powder particle to another, characterized in that the sweetener is selected from sodium saccharinate, calcium saccharinate, saccharin and a mixture of these substances, and the potentiator is a mixture of NHDC and a vanilla flavor, the amounts of the sweetener and the mixture of NHDC and a vanilla flavor are chosen so as to impart to the sweetness sensory character closer to the taste of sugar.
Le sucrant de l'invention possède un caractère sensoriel proche du sucre, en particulier un goût sucré de longue durée avec rondeur et sensation en bouche et absence d'astringence ou d'arrière-goût métallique ou amer.The sweetener of the invention has a sensorial character close to sugar, in particular a long-lasting sweetness with roundness and sensation in the mouth and absence of astringency or metallic or bitter aftertaste.
L'arôme de type vanille peut être la vanilline, c'est-à-dire le 3-méthoxy-4-hydroxybenzaldéhyde, en général obtenue par extraction de gousses de vanille ou ' par synthèse à partir du gaïacol par condensation ou de la lignine, éthyl-vanilline, c'est-à-dire le 3-éthoxy-4- hydroxybenzaldéhyde, présente dans les gousses de certaines variétés de vanille de Tahiti et habituellement obtenue par voie de synthèse très proche de celle utilisée pour la vanilline, ou un autre dérivé de la vanilline qui a un pouvoir aromatique semblable. De préférence l'arôme de type vanille est choisi parmi la vanilline et éthyl-vanilline, la vanilline étant particulièrement appréciée.The vanilla-type aroma can be vanillin, that is to say 3-methoxy-4-hydroxybenzaldehyde, generally obtained by extraction from vanilla beans or 'by synthesis from guaiacol by condensation or lignin , ethyl-vanillin, that is to say 3-ethoxy-4-hydroxybenzaldehyde, present in the pods of certain varieties of Tahitian vanilla and usually obtained by synthesis very similar to that used for vanillin, or a another derivative of vanillin that has similar aromatic power. Preferably the vanilla flavor is selected from vanillin and ethyl vanillin, vanillin being particularly preferred.
Lorsque l'arôme de type vanille est la vanilline, le rapport, en poids, entre les quantités de NHDC et de vanilline est en général de 6 à 1,0, de préférence de 2,5 à 1,5, en particulier de 2,2 à 1,8.When the vanilla flavor is vanillin, the weight ratio between the amounts of NHDC and vanillin is generally from 6 to 1.0, preferably from 2.5 to 1.5, in particular from 2 to , 2 to 1.8.
Lorsque l'arôme de type vanille est 1' éthylvanilline, le rapport, en poids, entre les quantités l'When the vanilla flavor is ethylvanillin, the ratio, by weight, between the amounts the
de NHDC et de vanilline est en général de 24 à 2,5, de préférence de 10 à 3, en particulier de 6 à 4.NHDC and vanillin are in general from 24 to 2.5, preferably from 10 to 3, in particular from 6 to 4.
Un sucrant intéressant est celui qui comprend, en poids, de 97,6 à 99,5 % de saccharinate de sodium, de 0,40 à 2,0 % de NHDC et de 0,10 à 0,80 % d'arôme de type vanille.An interesting sweetener is that which comprises, by weight, 97.6 to 99.5% sodium saccharinate, 0.40 to 2.0% NHDC and 0.10 to 0.80% aroma. vanilla type.
Des exemples de compositions d'un tel sucrant particulièrement intéressants au plan sensoriel sont celles qui comprennent, en poids :Examples of compositions of such a sweetener that are particularly interesting on the sensory level are those which comprise, by weight:
- de 97,6 à 99,5 % de saccharinate de sodium, de 0,4 à 2,0 % de NHDC et de 0,1 à 0,4 % d'éthylvanilline, en particulier de 98,8 % de saccharinate de sodium, 1,0 % de NHDC et 0,2% d' éthylvanilline, etfrom 97.6 to 99.5% of sodium saccharinate, from 0.4 to 2.0% of NHDC and from 0.1 to 0.4% of ethylvanillin, in particular of 98.8% of sodium saccharinate, sodium, 1.0% NHDC and 0.2% ethylvanillin, and
- de 97,7 à 99,3 % de saccharinate de sodium, de 0,40 à 1,5 % NHDC et de 0,30 à 0,80 % de vanilline, en particulier 98,5 % de saccharinate de sodium, 1,0 % de NHDC et 0,5 % de vanilline.from 97.7 to 99.3% of sodium saccharin, from 0.40 to 1.5% of NHDC and from 0.30 to 0.80% of vanillin, in particular 98.5% of sodium saccharinate, 0% NHDC and 0.5% vanillin.
De préférence, le sucrant en poudre selon l'invention a une granulométrie comprise entre 10 et 130 μm, avec une répartition sensiblement gaussienne.Preferably, the sweetener powder according to the invention has a particle size of between 10 and 130 μm, with a substantially Gaussian distribution.
Le sucrant en poudre selon invention peut contenir également d'autres ingrédients en petites quantités, tels que des exhausteurs de goût, glutamate de sodium, et nucléotides (inosinate et guanylate de sodium) , éthylmaltol et maltol. Ces ingrédients font partie des "micro-ingrédients" qui peuvent entrer dans la formulation intermédiaire de l'aliment ou prémix qui peut contenir aussi des émulsifiants gélifiants, antioxydants l'The powdered sweetener according to the invention may also contain other ingredients in small amounts, such as flavor enhancers, sodium glutamate, and nucleotides (sodium inosinate and guanylate), ethyl malol and maltol. These ingredients are part of the "micro-ingredients" that can enter the intermediate formulation of the food or premix that may also contain emulsifiers gelling, antioxidants the
conservateurs, colorants. Ces dernières substances sont généralement calculées pour être présentes à raison de 5 à 10 kg par tonne dans l'aliment final.preservatives, dyes. These latter substances are generally calculated to be present at a rate of 5 to 10 kg per tonne in the final feed.
Le sucrant en poudre selon 1 ' invention peut être préparé très simplement, selon une technologie bien connue en alimentation humaine et dans la technologie de fabrication des arômes, par "micronisation", c'est-à-dire par atomisation et séchage d'un mélange liquide, pulvérisé dans un appareil approprié. Cet appareil peut prendre la forme d'une tour dans laquelle le mélange liquide est admis au sommet par une buse ou une turbine, la poudre atomisée obtenue étant récoltée à la base de la tour. Dans certains cas, si cela s'avère nécessaire, la tour peut être remplie d'un gaz inerte pour éviter les phénomènes d'oxydation.The powdered sweetener according to the invention can be prepared very simply, according to a well-known technology in human nutrition and in the technology of aroma production, by "micronisation", that is to say by atomization and drying of a liquid mixture, sprayed in a suitable apparatus. This apparatus may take the form of a tower in which the liquid mixture is admitted to the top by a nozzle or a turbine, the atomized powder obtained being collected at the base of the tower. In some cases, if necessary, the tower may be filled with an inert gas to prevent oxidation phenomena.
Le sucrant en poudre selon l'invention peut être utilisé de deux façons dans l'alimentation humaine. D'abord, d'une façon classique, le sucrant selon l'invention peut être dispersé sur un support du type dextrose, silice ou amidon par exemple à raison de 10 à 75 parties pondérales de sucrant pour 90 à 25 parties pondérales de support. Sur la base des valeurs usuelles, cela va permettre de constituer un aliment final à une dose moyenne de 300 à 3'000 g/t, de préférence I1650 g/t, ce qui correspond à une quantité d'édulcorant de l'ordre de 150 à 5OO g/t et de potentiateur de 0,15 à 15 g/t sur la base de la dose moyenne de l'65O g/t. Il faut bien comprendre que, puisque le sucrant selon l'invention est parfaitement homogène et que la granulométrie de ce sucrant est suffisamment fine, il n'y aura évidemment aucune difficulté à obtenir une formulation sucrante sur support, puis un aliment final, eux aussi parfaitement homogènes.The sweetener powder according to the invention can be used in two ways in the human diet. Firstly, in a conventional manner, the sweetener according to the invention may be dispersed on a support of the dextrose, silica or starch type, for example in the proportion of 10 to 75 parts by weight of sweetener for 90 to 25 parts by weight of support. On the basis of the usual values, this allows to constitute a final feed at an average dose of 300 to 3,000 g / t, preferably I 1 650 g / t, which corresponds to an amount of sweetener of order of 150 to 500 g / t and a potentiator of 0.15 to 15 g / t based on the average dose of 65O g / t. It should be understood that, since the sweetener according to the invention is perfectly homogeneous and the particle size of this sweetener is sufficiently fine, there will obviously be no difficulty in obtaining a carrier-based sweetening formulation, and then a final food, too. perfectly homogeneous.
Les principaux domaines d'application concernés par les sucrants sont d'abord les produits laitiers tels que yogourts aromatisés, laits aromatisés, glaces, desserts frais ou congelés, poudings, mousses et crèmes ; ensuite les produits en poudre, notamment les crèmes, cacao, boissons aromatisées, desserts et glaces ; les boissons non alcoolisées, par exemple les boissons à base de fruits, les boissons à base de lait, les toniques, les boissons de type Cola, les boissons alcoolisées telles que cidres, bières brunes, boissons à base de vin ; et aussi les confiseries, les acidulés, les confitures, les gommes à mâcher (chewing- gums) , les pâtisseries, les bonbons et les chocolats, les céréales, les cônes de glace, les mayonnaises, les sauces notamment de salades, les snacks, les soupes, ainsi que les édulcorants non-caloriques de table.The main areas of application concerned by sweeteners are firstly dairy products such as flavored yogurt, flavored milks, ice cream, fresh or frozen desserts, puddings, mousses and creams; then powdered products, including creams, cocoa, flavored drinks, desserts and ices; non-alcoholic beverages, for example, fruit-based beverages, milk-based beverages, tonics, Cola-type beverages, alcoholic beverages such as ciders, dark beers, wine beverages; and also confectionery, acidulous, jams, chewing gums, pastries, sweets and chocolates, cereals, ice cream cones, mayonnaise, sauces, salads, snacks, soups, as well as non-caloric table sweeteners.
D'autres particularités et avantages de l'invention apparaîtront à la lecture de la description qui va suivre, à caractère illustratif et non limitatif. Cette description sera lue en référence aux Figures 1 à 4.Other features and advantages of the invention will become apparent on reading the description which follows, illustrative and not limiting. This description will be read with reference to Figures 1 to 4.
Les Figures 1 à 4 représentent les "spider web" (toiles d'araignée), résultats de l'analyse sensorielle quantitative descriptive (QDA) selon la norme AFNOR NF V 09-016 pour, respectivement,Figures 1 to 4 represent the "spider web" (cobwebs), results of quantitative descriptive sensory analysis (QDA) according to the AFNOR standard NF V 09-016 for, respectively,
-le saccharinate de sodium, l'aspartame, l'acésulfame K, le sucrant 2 et le sucrose ;sodium saccharin, aspartame, acesulfame K, sweetener 2 and sucrose;
le saccharinate de sodium, le sucrant 2 et le sucrose ;sodium saccharin, sweetener 2 and sucrose;
l'aspartame, le sucrant 2 et le sucrose ; etaspartame, sweetener 2 and sucrose; and
l'acésulfame K, le sucrant 2 et le sucrose. l'acesulfame K, sweetener 2 and sucrose. the
1) Préparation de sucrants selon invention1) Preparation of sweeteners according to the invention
On prépare une solution A de saccharinate de sodium en introduisant 900 litres d'eau dans une cuve, en chauffant jusqu'à 600C, puis en ajoutant lentement 1000 kg de saccharinate de sodium et en agitant la solution pendant 30 minutes jusqu'à la dissolution complète (la solution devient transparente ) .A sodium saccharinate solution A is prepared by introducing 900 liters of water into a tank, heating to 60 ° C., then slowly adding 1000 kg of sodium saccharinate and stirring the solution for 30 minutes until the complete dissolution (the solution becomes transparent).
Parallèlement, dans une petite cuve remplie de 100 litres d'eau chauffée jusqu'à 7O0C, on ajoute lentement le NHDC, l'arôme de type vanille, en quantités correspondant à la composition désirée pour le sucrant en préparation, puis on laisse dissoudre le produit pendant 30 minutes sous agitation.At the same time, in a small tank filled with 100 liters of water heated to 70 ° C., the NHDC, the vanilla flavor, is slowly added in amounts corresponding to the desired composition for the sweetener in preparation and is then left dissolve the product for 30 minutes with stirring.
On verse la solution B lentement dans la solution A.Solution B is poured slowly into solution A.
Lorsque la solution obtenue devient transparente, on procède à l'opération d'atomisation-séchage (spray-drying) dans une tour dont les conditions de travail sont les suivantes:When the solution obtained becomes transparent, the spray-drying operation is carried out in a tower whose operating conditions are as follows:
Température de la solution : 600CTemperature of the solution: 60 0 C
Température d'air entrée : 19O0CInlet air temperature: 19O 0 C
Température d'air sortie : 1000CExhaust air temperature: 100 0 C
Vitesse de rotation de la turbine d' atomisation : 15'000 tours/min, à 2O1OOO tours/min, la turbine pouvant être remplacée par une buse d'atomisation.Rotational speed of the turbine atomization: 15,000 revolutions / min, at 2O 1 OOO revolutions / min, the turbine can be replaced with an atomizing nozzle.
On obtient ainsi un sucrant selon l'invention, se présentant sous forme d'une poudre fine homogène ayant une granulométrie à répartition sensiblement gaussienne comprise entre 10 et 130 μm avec une moyenne de 48,5 μm et comprenant autour de 75 '000 '000 particules ou grains par gramme. Cette poudre est soluble dans l'eau.A sweetener according to the invention is thus obtained in the form of a homogeneous fine powder having a particle size with a substantially Gaussian distribution of between 10 and 130 μm with an average of 48.5 μm and comprising around 75,000,000 particles or grains per gram. This powder is soluble in water.
On a ainsi réalisé les sucrants en poudre suivants, selon les potentiateurs utilisés et leur proportion exprimée en valeurs pondérales.The following powder sweeteners were thus produced, according to the potentiators used and their proportion expressed in weight values.
SUCRANTS SELON L'INVENTION 1 à 7SUCKERS ACCORDING TO INVENTION 1 to 7
2) Préparation de sucrants comparatifs2) Preparation of comparative sweeteners
On utilise le procédé de préparation décrit ci-dessus mais avec une solution B ne contenant que du NHDC. The preparation method described above is used but with a solution B containing only NHDC.
l'the
SUCRANTS COMPARATIFS 1 à 2COMPARATIVE SUCRANTS 1 to 2
3) Test gustatif de comparaison avec le sucrose pour les sucrants de invention et les sucrants comparatifs3) Taste comparison test with sucrose for inventive sweeteners and comparative sweeteners
Les sucrants selon l'invention et les sucrants comparatifs de même composition mais sans arôme de type vanille ont été dissous dans de l'eau neutre de type Evian de façon à avoir un équivalent .en sucrose de 5% et comparés à des solutions de sucrose de 5% par un comité de 3 personnes choisies pour leur aptitude à identifier et évaluer des propriétés gustatives .The sweeteners according to the invention and the comparative sweeteners of the same composition but with no vanilla-type flavor were dissolved in Evian neutral water so as to have a sucrose equivalent of 5% and compared to sucrose solutions. 5% by a committee of 3 people chosen for their ability to identify and evaluate taste properties.
Cette comparaison a permis de montrer pour tous les sucrants de l'invention testés un caractère sensoriel proche du goût du sucre, avec, par rapport aux sucrants comparatifs, la suppression du goût métallique ou amer et une augmentation de la sensation en bouche et de la durée du goût sucré.This comparison made it possible to show, for all the sweeteners of the invention tested, a sensory character close to the taste of sugar, with, compared with the comparative sweeteners, the suppression of the metallic or bitter taste and an increase in the sensation in the mouth and the duration of sweet taste.
Les sucrants 2 et 6 sont ceux.qui sont les plus proches des solutions de sucrose.Sucrants 2 and 6 are those which are the closest to sucrose solutions.
4) Test d'analyse sensorielle quantitative descriptive (QDA)4) Quantitative Descriptive Sensory Analysis Test (QDA)
Le sucrant 2 selon l'invention, le sucrose, et trois édulcorants intenses conventionnels, à savoir le saccharinate de sodium, l'aspartame, l'acésulfame K ont été mis en solution dans de l'eau de type Evian et soumis aux tests d'analyse sensorielle quantitative descriptive de la Norme AFNOR NF V 09-016.Sucrose 2 according to the invention, sucrose, and three conventional intense sweeteners, namely sodium saccharinate, aspartame, acesulfame K have been dissolved in Evian-type water and subjected to descriptive quantitative sensory analysis tests of AFNOR Standard NF V 09-016.
Ce test consiste en l'attribution par un comité de 8 personnes choisies pour leur aptitude à identifier et évaluer des propriétés gustatives, pour chacune de ces substances, de notes de 0 à 5 pour chacune de 9 caractéristiques sensorielles importantes pour le goût.This test consists of the assignment by a committee of 8 people chosen for their ability to identify and evaluate taste properties, for each of these substances, grades of 0 to 5 for each of 9 sensory characteristics important for the taste.
Ces notes sont introduites dans le logiciel Tastel qui fournit pour chaque substance un graphe dénommé "spider web " (toile d'araignée) représentant les notes moyennes attribuées pour ces caractéristiques sensorielles selon 9 axes : "bitter" (amertume) , "astringent" (astringence) ,These notes are introduced in the Tastel software which provides for each substance a graph called "spider web" (spider's web) representing the average scores attributed for these sensory characteristics according to 9 axes: "bitter" (bitterness), "astringent" ( astringency),
"metallic" (goût métallique), "caramel-like", (goût de caramel) , "vanilla-like" (goût de vanille) , "long lasting""metallic", "caramel-like", (caramel taste), "vanilla-like" (vanilla flavor), "long lasting"
(longueur en bouche, mesurée par chronomètre) , "duration of the sweetening intensity" (durée de l'intensité sucrante, mesurée par chronomètre) , "mouth feeling" (sensation en bouche : si saveurs partout dans la bouche, bonne sensation en bouche ; si saveurs uniquement sur une zone précise de la langue, sensation en bouche faible ou inexistante) et(length in the mouth, measured by stopwatch), "duration of the sweetening intensity" (duration of the sweetness, measured by stopwatch), "mouth feeling" (mouthfeel: if flavors all over the mouth, good feeling in mouth if flavors only on a specific area of the tongue, low or no sensation in the mouth) and
"full-taste" (rondeur : équilibre des saveurs en bouche) ."full-taste" (roundness: balance of flavors in the mouth).
La Figure 1 est le "spider web" pour le saccharinate de sodium, l'aspartame, l'acésulfame K, le sucrant 2 et le sucrose .Figure 1 is the "spider web" for sodium saccharin, aspartame, acesulfame K, sweetener 2 and sucrose.
La Figure 2 est le "spider web" pour le saccharinate de sodium, le sucrant 2 et le sucrose.Figure 2 is the "spider web" for sodium saccharin, sweetener 2 and sucrose.
La Figure 3 est le "spider web" pour l'aspartame, le sucrant 2 et le sucroseFigure 3 is the "spider web" for aspartame, sweetener 2 and sucrose
La Figure 4 est le "spider web" pour le l'acésulfame K, le sucrant 2 et le sucrose.Figure 4 is the "spider web" for Acesulfame K, the sweetening 2 and sucrose.
On constate sur la Figure 1 que le sucrant de l'invention a des caractéristiques sensorielles beaucoup plus proches du goût du sucre que les édulcorants de comparaison, en particulier un goût sucré de longue durée avec rondeur et sensation en bouche et absence d' astringence ou d' arrière- goût métallique ou amer.It can be seen in FIG. 1 that the sweetener of the invention has sensory characteristics that are much closer to the taste of sugar than comparison sweeteners, in particular a long-lasting sweetness with roundness and sensation in the mouth and absence of astringency or metallic or bitter aftertaste.
La Figure 2 montre que le saccharinate de sodium a un peu plus d' astringence et de goût métallique, et moins de goût caramel, de goût de vanille, de rondeur, de sensation en bouche, de durée de l'intensité sucrante et de longueur en bouche que le sucrant de l'invention.Figure 2 shows that sodium saccharin has a little more astringency and metallic taste, and less caramel taste, vanilla taste, roundness, mouthfeel, duration of sweetness and length. in the mouth than the sweetener of the invention.
La Figure 3 montre que l'aspartame a plus d' astringence et de goût métallique, et moins de rondeur, de sensation en bouche, de durée de l'intensité sucrante et de longueur en bouche que le sucrant de l'invention, et n'a aucun goût caramel ou goût de vanille. Il a un goût très éloigné de celui du sucre.Figure 3 shows that aspartame has more astringency and metallic taste, and less roundness, sensation in mouth, duration of sweetness and length in the mouth than the sweetener of the invention, and n has no caramel taste or vanilla taste. It tastes very far from that of sugar.
La figure 4 montre que l'acésulfame K a plus d' astringence, moins de goût de caramel, un peu moins de rondeur, de sensation en bouche et de durée de l'intensité sucrante, que le sucrant de l'invention. Figure 4 shows that acesulfame K has more astringency, less caramel taste, a little less roundness, mouthfeel and duration of sweetness than the sweetener of the invention.

Claims

l'l'l'l'REVENDICATIONS the the the the CLAIMS
1. Sucrant en poudre pour alimentation humaine se présentant sous forme d'un mélange intime dont la répartition édulcorant/potentiateur est sensiblement homogène, non statistique, et dont la proportion de édulcorant par rapport au potentiateur est sensiblement constante et égale d'une particule de poudre à l'autre, caractérisé en ce édulcorant est choisi parmi le saccharinate de sodium, le saccharinate de calcium, la saccharine, et un mélange de ces substances, et le potentiateur comprend un mélange de NHDC et d'un arôme de type vanille, les quantités de édulcorant et du mélange de NHDC et d'un arôme de type vanille étant choisies de façon à conférer au sucrant un caractère sensoriel le rapprochant du goût du sucre.1. Powdered sweetener for human food in the form of an intimate mixture whose sweetener / potentiator distribution is substantially homogeneous, non-statistical, and whose proportion of sweetener relative to the potentiator is substantially constant and equal to one particle of powder to the other, characterized in that sweetener is selected from sodium saccharinate, calcium saccharinate, saccharin, and a mixture of these substances, and the potentiator comprises a mixture of NHDC and a vanilla flavor, the amounts of sweetener and the mixture of NHDC and a vanilla flavor are chosen so as to give the sweetness a sensory character bringing it closer to the taste of sugar.
2. Sucrant selon la revendication 1, caractérisé en ce que l'arôme de type vanille est choisi parmi la vanilline et éthylvanilline. 2. Sugar according to claim 1, characterized in that the vanilla flavor is selected from vanillin and ethyl vanillin.
3. Sucrant selon la revendication 2, caractérisé en ce que l'arôme de type vanille est la vanilline, et le rapport, en poids, entre les quantités de NHDC et de vanilline est de 2,5 à 1,5, en particulier de 2,2 à 1,8.3. Sugar according to claim 2, characterized in that the vanilla flavor is vanillin, and the ratio, by weight, between the amounts of NHDC and vanillin is 2.5 to 1.5, in particular of 2.2 to 1.8.
4. Sucrant selon la revendication 2, caractérisé en ce que l'arôme de type vanille est l'éthylvanilline, et le rapport, en poids, entre les quantités de NHDC et de vanilline est de 10 à 3, en particulier de 6 à 4.4. Sugar according to claim 2, characterized in that the vanilla flavor is ethylvanillin, and the ratio, by weight, between the amounts of NHDC and vanillin is from 10 to 3, in particular from 6 to 4 .
5. Sucrant selon l'une des revendications précédentes, caractérisé en ce qu'il comprend, en poids, de 97,6 à 99,5 % de saccharinate de sodium, de 040 à 2,0 % de NHDC et de 0,10 à 0,80 % d'arôme de type vanille.5. Sugar according to one of the preceding claims, characterized in that it comprises, by weight, 97.6 to 99.5% of sodium saccharinate, 040 to 2.0% of NHDC and 0.10 at 0.80% vanilla flavor.
6. Sucrant selon la revendication 5, caractérisé en ce qu'il comprend, en poids, de 97,6 à 99,5 % de saccharinate de sodium, de 0.4 à 2.0 % de NHDC et de 0,1 à 0,4 % d'éthylvanilline.6. Sugar according to claim 5, characterized in that it comprises, by weight, from 97.6 to 99.5% of sodium saccharinate, 0.4 to 2.0% NHDC and 0.1 to 0.4% ethylvanillin.
7. Sucrant selon la revendication 5, caractérisé en ce qu'il comprend, en poids, de 97,7 à 99,3 % de saccharinate de sodium, de 0,40 à 1,5 % NHDC et de 0,30 à 0, 80 % de vanilline.7. Sugar according to claim 5, characterized in that it comprises, by weight, 97.7 to 99.3% sodium saccharinate, 0.40 to 1.5% NHDC and 0.30 to 0 , 80% vanillin.
8. Sucrant selon la revendication 7, caractérisé en ce qu'il comprend, en poids, 98,5 % de saccharinate de sodium, 1,0 % de NHDC et 0,5 % de vanilline. 8. Sugar according to claim 7, characterized in that it comprises, by weight, 98.5% sodium saccharinate, 1.0% NHDC and 0.5% vanillin.
9. Procédé de préparation d'un sucrant selon l'une des revendications précédentes, caractérisé en ce qu'on prépare un mélange en solution d'un édulcorant choisi parmi le saccharinate de sodium, le saccharinate de calcium, la saccharine, et un mélange de ces substances et d'un potentiafeur comprenant un mélange de NHDC et d'un arôme de type vanille, puis qu'on pulvérise ce mélange par atomisation séchage pour obtenir une poudre.9. Process for the preparation of a sweetener according to one of the preceding claims, characterized in that a solution mixture of a sweetener selected from sodium saccharinate, calcium saccharinate, saccharin and a mixture is prepared. of these substances and a potentiafeur comprising a mixture of NHDC and a vanilla flavor, and then spray this mixture by spray drying to obtain a powder.
10. Formulation alimentaire sucrante en granulés, caractérisé en ce qu'elle comprend un sucrant selon l'une des revendications 1 à 8 dispersé sur un support du type dextrose, silice ou amidon à raison de 10 à 75 parties pondérales de sucrant pour 90 à 25 parties pondérales de support. 10. Food formulation sweetening granules, characterized in that it comprises a sweetener according to one of claims 1 to 8 dispersed on a support of the type of dextrose, silica or starch at a rate of 10 to 75 parts by weight of sweetener for 90 to 25 weight parts of support.
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US9101160B2 (en) 2005-11-23 2015-08-11 The Coca-Cola Company Condiments with high-potency sweetener
EP1815754B1 (en) 2006-02-02 2009-04-15 Pancosma S.A. Sweetener for animal feeding
US8017168B2 (en) 2006-11-02 2011-09-13 The Coca-Cola Company High-potency sweetener composition with rubisco protein, rubiscolin, rubiscolin derivatives, ace inhibitory peptides, and combinations thereof, and compositions sweetened therewith
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