EP1743124B1 - Industrial water preheater - Google Patents
Industrial water preheater Download PDFInfo
- Publication number
- EP1743124B1 EP1743124B1 EP02807300A EP02807300A EP1743124B1 EP 1743124 B1 EP1743124 B1 EP 1743124B1 EP 02807300 A EP02807300 A EP 02807300A EP 02807300 A EP02807300 A EP 02807300A EP 1743124 B1 EP1743124 B1 EP 1743124B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- stabilizer
- valve
- water
- stub
- pipe
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24D—DOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
- F24D17/00—Domestic hot-water supply systems
- F24D17/0078—Recirculation systems
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F24—HEATING; RANGES; VENTILATING
- F24D—DOMESTIC- OR SPACE-HEATING SYSTEMS, e.g. CENTRAL HEATING SYSTEMS; DOMESTIC HOT-WATER SUPPLY SYSTEMS; ELEMENTS OR COMPONENTS THEREFOR
- F24D17/00—Domestic hot-water supply systems
- F24D17/0073—Arrangements for preventing the occurrence or proliferation of microorganisms in the water
Definitions
- the subject of the utility model is a hot water heater fed with heating water from the gas and oil boilers, which are adapted to cooperate with the usual low temperature boilers in the field of heat supply.
- Ru 55 852 a domestic water heater is known, which is fed with heating water from the systems in the boiler or heating oil heated boiler houses and is equipped with a plate heat exchanger consisting of some plate heat exchange.
- the heat exchange kit is installed in the hot water outlet collector through connections and is connected to a stabilizer which in turn is connected to the cold water collector by a spigot and circulating pump with an external circulation line and a spigot, check valve and internal recirculation pump.
- the existing of some plate heat exchanger heat exchange kit is connected to the Schuwasserspeisetechnisch. (Further hot water preheaters are from the patent applications DE 10036452A . DE 3836523A and WO 9529127A known.)
- the domestic water heater which according to the utility model contains a heat exchange set composed of some plate heat exchangers installed in the cold water collector and in the hot water outlet collector and connected to the heating water supply pipe, is characterized by having a mixing unit comprising a thermostatic valve, an outlet collector Control thermometer for monitoring of the warm Hot water with a temperature of + 60 ° C and a thermometer for circulation of hot domestic water with a temperature of + 55 ° C.
- the mixing unit is connected to the stabilizer through a spout and a conduit of elevated temperature water.
- the stabilizer is hydraulically connected through the plate heat exchange kit with a safety valve and with an expansion vessel from the cold water side.
- the preheater according to this utility model contains some design solutions and technological solutions that protect against the formation of bacterial flora, and especially against the emergence of strains of Legionnaires' disease bacteria whose intensive development takes place in temperatures of 20 ° C to 55 ° C.
- the mixing unit used with a thermostatic mixing valve allows preservation in the stabilizer of the elevated temperature of + 70 ° C and after mixing allows feeding into the acceptance system of the water with the required temperature of + 60 ° C. Because only stainless steel is used in plant design, deposits of sediment and limestone sediments are limited, as well as a periodic increase of hot water temperature up to + 80 ⁇ 90 ° C and complete elimination of legionnaires' disease bacteria in the preheater.
- the preheater is also completely adapted to the cooperation with condensing boilers of high technical efficiency. This guarantees very favorable cooling of the heating water by approx. + 35 ° C, because the prerequisite for condensation formation in the condensing boilers of the gas and oil boiler house is the constant maintenance of the return temperature below + 57 ° C. Achieving such temperatures in the previously used, equipped with tubular heating capacity and fürellevor Suitem is difficult and does not guarantee the complete condensation conditions.
- the hot water heater is connected by a shut-off valve 2 to the plant 1 supplying the heating water from the gas and oil boiler house.
- the plate heat exchange set 9 is connected to the line leading from the shut-off valve 2 by feed pump 3 with control gauge 4 , check valve 5 , control thermometer 6 with capillary 6a , control gauge 7 and by automatic vent 8 .
- the plate heat exchange set 9 is through line 10a , 11 11a control thermometer with capillary 11a , control gauge 12 and shut-off valve 13 with the Return water system 10, wherein the plate heat exchanger set 9 is fed by the plant 1 and with a heating water pipe and the return water is led out of the heat exchanger set 9 through the conduit 10a into the return water system 10th
- the plate heat exchange set 9 is connected by shut-off valve 15 , filter sludge trap 16 , control gauge 17 on the bypass line of the filter sludge trap 16 , check valve 18 , expansion vessel 19 and safety valve 20 with the cold water system 14 .
- the plate heat exchanger set 9 is connected through line 21 and nozzle 22 to the stabilizer 23 and the stabilizer 23 is connected through outlet nozzle 24, line 25 and 25a with the mixing unit Zm.
- the mixing unit cm is with an associated cold water line 33 thermostatic direct effect valve 26 as well as output collector 27 with a built-in sensor 28 of the servo motor 29 for control of the thermostatic valve 26, with control thermometer 34 on the line 30 and with thermometer 37a on line 37 for circulation of the equipped warm hot water.
- the line 30 is connected to the outlet port 31 and the shut-off valve 32 for shutting off the hot service water with the required operating temperature of + 60 ° C.
- the circulation line 35 is connected through shut-off valve 36 , line 37 , circulation pump 38 and pressure line 39 to the lower port 40 of the stabilizer 23 .
- the outlet connector 41 of this stabilizer is connected on the other hand by the associated pump 42 for internal circulation, as well as by non-return valve 43 and pressure line 43 to the cold water system fourteenth
- the stabilizer 23 is equipped with inspection nozzle 44 , pressure gauge 45 and nozzle 46 , and in the bottom of the stabilizer, a nozzle 47 is installed with emptying and desludging valve 48 , wherein the inspection nozzle 44 , the lower nozzle 40 and the outlet nozzle 41 lie in a plane, which passes through axes of these nozzles.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
- Control Of Steam Boilers And Waste-Gas Boilers (AREA)
- Details Of Fluid Heaters (AREA)
- Resistance Heating (AREA)
- Cookers (AREA)
- Cereal-Derived Products (AREA)
- Materials For Medical Uses (AREA)
- Jellies, Jams, And Syrups (AREA)
- Instantaneous Water Boilers, Portable Hot-Water Supply Apparatuses, And Control Of Portable Hot-Water Supply Apparatuses (AREA)
- Domestic Hot-Water Supply Systems And Details Of Heating Systems (AREA)
Abstract
Description
Der Gegenstand des Gebrauchsmusters ist ein Brauchwasservorwärmer, der mit Heizwasser aus den Gas- und Ölkesseln gespeist wird, die an Zusammenarbeit mit den in der Femwärmeversorgung üblichen Niederparameterkesseln angepasst sind.The subject of the utility model is a hot water heater fed with heating water from the gas and oil boilers, which are adapted to cooperate with the usual low temperature boilers in the field of heat supply.
Aus der polnischen Beschreibung des Gebrauchsmusters Nr. Ru 55 852 ist ein Brauchwasservorwärmer bekannt, der mit Heizwasser aus den Systemen in den mit Gas oder Heizöl beheizten Kesselhäusern gespeist wird und mit einem aus einigen Plattenwärmetauscher bestehenden Plattenwärmetauschersatz ausgerüstet ist. Der Wärmetauschersatz ist durch Anschlüsse in den Warmwasserauslaufkollektor eingebaut und ist mit einem Stabilisator verbunden, der wiederum durch einen Stutzen und eine Umlaufpumpe mit einer Leitung für äußere Zirkulation sowie durch einen Stutzen, einen Rückschlagventil und eine Pumpe für innern Umlauf mit dem Kaltwasserkollektor verbunden ist. Der aus einigen Plattenwärmetauscher bestehende Wärmetauschersatz ist an die Heizwasserspeiseleitung angeschlossen.
(Weitere Brauchwasservorwärnier sind aus den Patentanmeldungen
(Further hot water preheaters are from the patent applications
Auf dem Boden des gleichzeitigen Stands der Technik entstand die Aufgabe, eine Konstruktion des Brauchwasservorwärmers mit einer Schutzmaßnahme gegen Entstehung von Stämmen der Legionärskrankheitsbakterien zu schaffen sowie entsprechende Lösungen für Beseitigung der Temperaturaufschichtung des Warmwassers und für Erhalten der Wassertemperatur im Stabilisatorbehälter von +60°C auf der ganzen Behälterhöhe einzuführen.
Der ausarbeitete Vorwärmer soll darüber hinaus der Zusammenarbeit mit den Kondensationskesseln vom hohen technischen Wirkungsgrad angepasst werden.On the basis of the contemporary state of the art the task arose to create a construction of the hot water heater with a protective measure against formation of strains of Legionnaires' disease bacteria and solutions for eliminating the temperature stratification of the hot water and for maintaining the water temperature in the stabilizer tank of + 60 ° C on the to introduce the entire container height.
The elaborated preheater will also be adapted to the cooperation with the condensing boilers of high technical efficiency.
Der Brauchwasservorwärmer, der dem Gebrauchsmuster gemäß einen Wärmetauschersatz enthält, der aus einigen in den Kaltwasserkollektor und in den Warmwasserausgangskollektor eingebauten sowie an die Heizwasserspeiseleitung angeschlossenen Plattenwärmetauschem zusammengesetzt ist, charakterisiert sich dadurch, dass er eine Mischeinheit besitzt, die ein thermostatisches Ventil, einen Ausgangskollektor, ein Kontrollthermometer für Überwachung des warmen Brauchwassers mit der Temperatur von +60°C und ein Thermometer für Zirkulation des warmen Brauchwassers mit der Temperatur von +55°C enthält. Die Mischeinheit ist durch einen Auslaufstutzen und eine Leitung mit Wasser mit erhöhter Temperatur mit dem Stabilisator verbunden. Der Stabilisator ist durch den Plattenwärmetauschersatz mit einem Sicherheitsventil und mit einem Ausdehnungsgefäß von der Kaltwasserseite hydraulisch verbunden.The domestic water heater, which according to the utility model contains a heat exchange set composed of some plate heat exchangers installed in the cold water collector and in the hot water outlet collector and connected to the heating water supply pipe, is characterized by having a mixing unit comprising a thermostatic valve, an outlet collector Control thermometer for monitoring of the warm Hot water with a temperature of + 60 ° C and a thermometer for circulation of hot domestic water with a temperature of + 55 ° C. The mixing unit is connected to the stabilizer through a spout and a conduit of elevated temperature water. The stabilizer is hydraulically connected through the plate heat exchange kit with a safety valve and with an expansion vessel from the cold water side.
Der diesem Gebrauchsmuster gemäß ausgeführte Vorwärmer enthält einige Konstruktionslösungen sowie technologische Lösungen, die vor Entstehung der Bakterienflora, und besonders vor Entstehung von Stämme der Legionärskrankheitsbakterien schützen, deren intensive Entwicklung in Temperaturen von 20°C bis 55°C erfolgt.
Die eingesetzte Mischeinheit mit einem thermostatischen Mischventil ermöglicht Erhaltung im Stabilisator der erhöhten Temperatur von +70°C sowie nach Vermischen erlaubt Zuführung in die Abnahmeanlage des Wassers mit der erforderlichen Temperatur von +60°C.
Weil bei Anlagenausführung ausschließlich nichtrostender Stahl eingesetzt wird, ist die Ablagerung von Kesselstein und Sedimenten mit Legionärskrankheitsbakterien begrenzt sowie ist periodische Erhöhung der Warmwassertemperatur bis zum +80÷90°C und damit vollständige Liquidation der Legionärskrankheitsbakterien in der Vorwärmeranlage möglich.
Der Vorwärmer ist auch völlig der Zusammenarbeit mit den Kondensationskesseln vom hohen technischen Wirkungsgrad angepasst. Das garantiert sehr günstige Abkühlung des Heizwassers um ca. +35°C, weil die Voraussetzung für Kondensationsentstehung in den Kondensationskesseln des Gas- und Ölkesselhauses die ständige Erhaltung der Rücklauftemperatur unterhalb von +57°C ist. Erzielung solcher Temperaturen in den bisher angewandten, mit Rohrheizschlangen ausgerüsteten Kapazitäts- und Durchlaufvorwärmem ist erschwert und gewährleistet die völlige Kondensationsbedingungen nicht.The preheater according to this utility model contains some design solutions and technological solutions that protect against the formation of bacterial flora, and especially against the emergence of strains of Legionnaires' disease bacteria whose intensive development takes place in temperatures of 20 ° C to 55 ° C.
The mixing unit used with a thermostatic mixing valve allows preservation in the stabilizer of the elevated temperature of + 70 ° C and after mixing allows feeding into the acceptance system of the water with the required temperature of + 60 ° C.
Because only stainless steel is used in plant design, deposits of sediment and limestone sediments are limited, as well as a periodic increase of hot water temperature up to + 80 ÷ 90 ° C and complete elimination of legionnaires' disease bacteria in the preheater.
The preheater is also completely adapted to the cooperation with condensing boilers of high technical efficiency. This guarantees very favorable cooling of the heating water by approx. + 35 ° C, because the prerequisite for condensation formation in the condensing boilers of the gas and oil boiler house is the constant maintenance of the return temperature below + 57 ° C. Achieving such temperatures in the previously used, equipped with tubular heating capacity and Durchlaufvorwärmem is difficult and does not guarantee the complete condensation conditions.
Der Gegenstand des Gebrauchsmusters ist auf der beiliegenden Zeichnung näher dargestellt.The subject of the utility model is shown in more detail on the accompanying drawing.
Wie auf der Zeichnung vorgestellt ist, ist der Brauchwasservorwärmer durch ein Absperrventil 2 an die das Heizwasser aus Gas- und Ölkesselhaus zuführende Anlage 1 angeschlossen. An die Leitung, die vom Absperrventil 2 durch Beschickungspumpe 3 mit Kontrollmanometer 4, Rückschlagventil 5, Kontrollthermometer 6 mit Kapillare 6a, Kontrollmanometer 7 und durch selbsttätigen Entlüfter 8 führt, ist der Plattenwärmetauschersatz 9 angeschlossen. Der Plattenwärmetauschersatz 9 ist durch Leitung 10a, Kontrollthermometer 11 mit Kapillare 11a, Kontrollmanometer 12 und Absperrventil 13 mit der Rücklaufwasseranlage 10 verbunden, wobei der Plattenwärmetauschersatz 9 durch die Anlage 1 und Leitung mit Heizwasser beschickt wird und das Rücklaufwasser aus dem Wärmetauschersatz 9 durch die Leitung 10a in die Rücklaufwasseranlage 10 geführt wird. Der Plattenwärmetauschersatz 9 ist durch Absperrventil 15, Filter-Schlammfang 16, Kontrollmanometer 17 auf der Bypassleitung des Filter-Schlammfangs 16, Rückschlagventil 18, Ausdehnungsgefäß 19 und Sicherheitsventil 20 mit der Kaltwasseranlage 14 verbunden.
Der Plattenwärmetauschersatz 9 ist durch Leitung 21 und Stutzen 22 mit dem Stabilisator 23 verbunden, und der Stabilisator 23 ist durch Auslaufstutzen 24, Leitung 25 und 25a mit der Mischeinheit Zm verbunden. Die Mischeinheit Zm ist mit einem mit Kaltwasserleitung 33 verbundenen thermostatischen Direktwirkungsventil 26 sowie mit Ausgangskollektor 27 mit einem eingebauten Fühler 28 des Stellmotors 29 für Steuerung des thermostatischen Ventils 26, mit Kontrollthermometer 34 auf der Leitung 30 und mit Thermometer 37a auf der Leitung 37 für Zirkulation des warmen Brauchwassers ausgerüstet. Die Leitung 30 ist mit dem Auslaufstutzen 31 und mit dem Absperrventil 32 für Absperrung des warmen Brauchwassers mit der erforderlichen Betriebstemperatur von +60°C verbunden. Die Zirkulationsleitung 35 ist durch Absperrventil 36, Leitung 37, Umlaufpumpe 38 und Druckleitung 39 mit dem unteren Stutzen 40 des Stabilisators 23 verbunden. Der Auslaufstutzen 41 dieses Stabilisators ist dagegen durch die angeschlossene Pumpe 42 für inneren Umlauf sowie durch Rückschlagventil 43 und Druckleitung 43a mit der Kaltwasseranlage 14 verbunden. Der Stabilisator 23 ist mit Revisionsstutzen 44, Manometer 45 und Stutzen 46 ausgerüstet, und im Boden des Stabilisators ist ein Stutzen 47 mit Entleerungs- und Entschlammventil 48 installiert, wobei der Revisionsstutzen 44, der unteren Stutzen 40 und der Auslaufstutzen 41 in einer Ebene liegen, die durch Achsen dieser Stutzen durchgeht.As shown in the drawing, the hot water heater is connected by a shut-off
The plate
- 1. Heizwasserzufiihranlage1. Heizwasserzufiihranlage
- 2. Absperrventil2nd shut-off valve
- 3. Beschickungspumpe3. Feed pump
- 4. Kontrollmanometer4. Control gauge
- 5. Rückschlagventil.5. Check valve.
- 6. Kontrollthermometer6. Control thermometer
- 6a. Kapillare6a. capillary
- 7. Kontrollmanometer7. Control gauge
- 8. Entlüfter8. deaerator
- 9. Plattenwärmetauschersatz9. Plate heat exchange kit
- 10. Rücklaufwasseranlage10. Return water system
- 11. Kontrollthermometer11. Control thermometer
- 11a. Kapillare11a. capillary
- 12. Kontrollmanometer12. Control gauge
- 13. Absperrventil13. shut-off valve
- 14. Kaltwasseranlage14. cold water system
- 15. Absperrventil15. shut-off valve
- 16. Filter-Schlammfang16. Filter sludge trap
- 17. Kontrollmanometer17. Control gauge
- 18. Rückschlagventil18. Check valve
- 19. Ausdehnungsgefäß19. Expansion vessel
- 20. Sicherheitsventil20. Safety valve
- 21. Leitung21st line
- 22. Stutzen22nd neck
- 23. Stabilisator23. Stabilizer
- 24. Auslaufstutzen24. outlet pipe
- 25. Leitung25th line
- 25a. Leitung25a. management
- 26. thermostatisches Ventil26. thermostatic valve
- 27. Ausgangskollektor27th exit collector
- 28. Fühler28th sensor
- 29. Stellmotor29th actuator
- 30. Leitung30th line
- 31. Auslaufstutzen31. outlet pipe
- 32. Absperrventil32nd stop valve
- 33. Kaltwasserleitung33. cold water pipe
- 34. Kontrollthermometer34. Control thermometer
- 35. Zirkulationsleitung35th circulation pipe
- 36. Absperrventil36th stop valve
- 37. Leitung für Zirkulation des warmen Brauchwassers37. Circulation for the circulation of hot domestic water
- 38. Umlaufpumpe38. circulation pump
- 39. Druckleitung39th pressure line
- 40. unterer Stutzen des Stabilisators40th lower neck of the stabilizer
- 41. Auslaufstutzen41. spout
- 42. Pumpe des inneren Umlaufs42. Pump of the internal circulation
- 43. Rückschlagventil43. Check valve
- 44. Revisionsstutzen44. Inspection nozzle
- 45. Manometer45. Pressure gauge
- 46. Stutzen46. neck
- 47. Stutzen mit Entleerungsventil47. Connecting piece with drain valve
- 48. Entleerungs- und Entschlammventil48. Emptying and desludging valve
- Zm - MischeinheitZm - mixing unit
Claims (1)
- A consumable water preheater with a heat exchanger unit (9), consisting of two or several plate heat exchangers which comprises a mixing unit (Zm), equipped with a thermostatic valve and an adjustable servo-motor for its control. It is significant thereof, that a heat exchanger unit (9), consisting of two or several plate heat exchangers, is connected with a cool water collecting pipe (14) and with heating water outlet collecting pipes (1,10) of hot usable water as well as with a hot water supply conduit (21). The mixing unit consists of: an outlet collecting pipe (27) with a built-in sensor (28) of the servo-motor (29) for control of a thermostatic mixing valve (26); a check thermometer (34) on a conduit (30) and a thermometer (37a) are placed on a circulation conduit of hot usable water A mixing unit (Zm) is connected with the stabilizer (23) by means of conduits (25a), (25) and a stub pipe (24) In a stabilizer (23) tank casing an inspection stub pipe (44), an outlet stub pipe (41) and a stabilizer lower stub pipe (40) are installed; at the same time stub pipes (41) and (44) are placed in the same surface, which goes through axes of these stub pipes and in the bottom of the stabilizer (23) tank, there is installed a stub pipe (47) with a drain and desludging valve (48) ; at the same time the stabilizer (23) is hydraulically connected through a plate heat exchanger unit (9) with a safety valve (20) and an expansion tank (19) of cool water.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL113164U PL62235Y1 (en) | 2002-04-12 | 2002-04-12 | Utility water heater |
PCT/PL2002/000068 WO2003091631A1 (en) | 2002-04-12 | 2002-09-10 | Industrial water preheater |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1743124A1 EP1743124A1 (en) | 2007-01-17 |
EP1743124B1 true EP1743124B1 (en) | 2008-02-20 |
Family
ID=19949424
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02807300A Expired - Lifetime EP1743124B1 (en) | 2002-04-12 | 2002-09-10 | Industrial water preheater |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP1743124B1 (en) |
AT (1) | ATE386908T1 (en) |
DE (1) | DE50211760D1 (en) |
PL (1) | PL62235Y1 (en) |
WO (1) | WO2003091631A1 (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2492763A (en) * | 2011-07-09 | 2013-01-16 | Christopher Paul Done | Use of hot air in a loft to heat water |
FR3019631B1 (en) * | 2014-04-04 | 2019-05-17 | Etablissements Charot | METHOD AND UNIT FOR REGULATING A HOT WATER PRODUCTION PLANT |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ATE100781T1 (en) * | 1987-10-23 | 1994-02-15 | Vaillant Gmbh | DEVICE TO PREVENT THE OCCURANCE OR. THE REPRODUCTION OF MICROLIFE IN PROCESSED WATER. |
AU4914793A (en) * | 1992-10-20 | 1994-05-05 | Australian Warm Water Systems Pty. Ltd. | Water treatment apparatus |
US5701387A (en) * | 1994-12-19 | 1997-12-23 | Mcgugan; Colin A. | Storage tank water heater tempering system |
AT409033B (en) * | 1999-07-30 | 2002-05-27 | Stampfer & Boeckl Gmbh Ingenie | HEATING SYSTEM |
RU55852U1 (en) | 2006-03-31 | 2006-08-27 | Открытое акционерное общество "Татнефть" им. В.Д. Шашина | PIPE FOLDING DEVICE |
-
2002
- 2002-04-12 PL PL113164U patent/PL62235Y1/en not_active IP Right Cessation
- 2002-09-10 AT AT02807300T patent/ATE386908T1/en not_active IP Right Cessation
- 2002-09-10 WO PCT/PL2002/000068 patent/WO2003091631A1/en active IP Right Grant
- 2002-09-10 DE DE50211760T patent/DE50211760D1/en not_active Expired - Fee Related
- 2002-09-10 EP EP02807300A patent/EP1743124B1/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
WO2003091631A1 (en) | 2003-11-06 |
ATE386908T1 (en) | 2008-03-15 |
EP1743124A1 (en) | 2007-01-17 |
PL113164U1 (en) | 2002-10-07 |
PL62235Y1 (en) | 2006-05-31 |
DE50211760D1 (en) | 2008-04-03 |
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