EP1716407A1 - Dispositif et procede de determination de la composition chimique de matieres solides, liquides ou gazeuses - Google Patents

Dispositif et procede de determination de la composition chimique de matieres solides, liquides ou gazeuses

Info

Publication number
EP1716407A1
EP1716407A1 EP05700034A EP05700034A EP1716407A1 EP 1716407 A1 EP1716407 A1 EP 1716407A1 EP 05700034 A EP05700034 A EP 05700034A EP 05700034 A EP05700034 A EP 05700034A EP 1716407 A1 EP1716407 A1 EP 1716407A1
Authority
EP
European Patent Office
Prior art keywords
plasma
laser light
optical components
laser
radiation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP05700034A
Other languages
German (de)
English (en)
Inventor
Johann Gruber
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Innsitec Laser Technologies GmbH
Original Assignee
Innsitec Laser Technologies GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Innsitec Laser Technologies GmbH filed Critical Innsitec Laser Technologies GmbH
Publication of EP1716407A1 publication Critical patent/EP1716407A1/fr
Withdrawn legal-status Critical Current

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Classifications

    • G—PHYSICS
    • G01—MEASURING; TESTING
    • G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
    • G01N21/71—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light thermally excited
    • G01N21/718—Laser microanalysis, i.e. with formation of sample plasma

Definitions

  • the subject of the invention is a device for determining the chemical composition of solid, liquid or gaseous substances, in particular metal melts, by means of laser-induced plasma spectroscopy.
  • the invention further relates to a method for determining the chemical composition of solid, liquid or gaseous substances, in particular metal melts, by laser-induced plasma spectroscopy, laser light being directed onto a surface of the solid or liquid substance or via a focusing device along a first optical axis directed into the gaseous substance and a plasma is ignited there and the radiation emitted by the plasma is spectrally analyzed to determine the chemical composition.
  • LIPS Laser-induced plasma spectroscopy
  • composition of a substance For example, the chemical composition of a molten metal located in a metallurgical vessel and, if appropriate
  • Changes in the composition of the melt can in principle be determined or tracked quickly. Since the measurements can be carried out directly on or in the case of a gas in the substance to be examined, it is not necessary to take a sample. Therefore, with this spectroscopic method, substances of all physical states can be investigated without any significant loss of material.
  • a known device for performing laser-induced plasma spectroscopy comprises a laser source for generating laser light and a focusing device with which the generated laser light is focused, for example, on a metal melt to be examined in the form of a laser spot. If the power of the laser light focused on the material reaches a threshold value, material is evaporated on the surface of the molten metal in the area of the laser spot and a plasma is ignited. This plasma emits electromagnetic radiation, which is characteristic of the chemical composition of the molten metal at the location of the laser spot. With a suitable analysis device, which is another component of such devices, a qualitative and quantitative spectral analysis, the radiation emitted by the plasma are carried out and so a chemical composing Obergurig ⁇ be errriittelt.
  • additional optical components can be provided which guide laser light to the material or emitted plasma light to the analysis device.
  • the laser beam diameter or the power density of the laser light on the examined sample is constant during a measurement. If the laser light output is not constant, the plasma properties are influenced, which can lead to considerable variations in the analysis results and the reproducibility is negatively influenced.
  • a main source of error for incorrect measurement results is a variation in the distance from the focusing device to the substance or material to be examined. If this distance changes, the laser light output on a surface or in the material also changes, which can result in the falsification of analysis results.
  • US Pat. No. 4,986,658 proposes to use a diode laser and a phototransistor which cooperates with it to determine a distance between a focusing device and a metal melt in a Ll PS device.
  • Laser light is directed or directed by the diode laser at an angle of incidence onto the metal surface, reflected by it and fed to the phototransistor.
  • the stated distance should be determinable from the intensity of the reflected laser light measured with the phototransistor.
  • a disadvantage of this method is, however, that when the melt surface moves, the incident laser light is reflected in different directions in an uncontrolled manner and consequently does not reach the phototransistor as desired and required.
  • the object of the invention is to eliminate these disadvantages and to provide a device of the type mentioned at the outset with which changes in a distance from sample material to focusing device can be observed quickly, reliably and in a simple manner and with high accuracy. It is also the object of the invention to provide a method of the type mentioned at the outset with which changes in a distance from sample material to focusing device can be determined quickly, reliably and in a simple manner with high accuracy.
  • a position-sensitive detector according to the invention for radiation emitted by the plasma does not require any further devices for distance measurement, especially no further lasers used specifically for distance measurement, and the device is therefore of a simpler design than known devices can be.
  • the position-sensitive detector is a photodiode array or a line-scan camera system, because such detectors are robust and can be used in a small design and can thus contribute to a space-saving construction of a device.
  • Optical components of a device according to the invention advantageously comprise mirrors and / or prisms in order to guide laser light from the laser onto or into a substance to be examined.
  • laser light can be guided over long distances without a high divergence of the laser light occurring and / or large intensity losses.
  • the polarization of the light can be lost when the laser light is guided via glass fiber optics.
  • radiation emitted by the plasma can be fed to the analysis device via the optical components.
  • Laser light and emitted radiation can then be directed via the same optical components and there is little expenditure on optical components.
  • laser light can be conducted from the laser to the sample and emitted radiation from the plasma to the analysis device along a first optical axis by means of optical components and, on the other hand, radiation emitted with the same optical components can be fed to a position-sensitive detector along a second optical axis
  • lasers and examination units can be at a safe distance be arranged to the measuring location or to the sampling point, which is of great advantage particularly when using a device according to the invention in the metallurgical industry.
  • an antireflection layer With regard to a loss-free conduction of laser light from the laser onto or into a sample, it has proven to be very expedient if at least some of the optical components are provided with an antireflection layer. Otherwise, there will be losses due to reflections if laser light is incident vertically on optical components. In particular if a large number of optical components are provided, the losses resulting therefrom can be considerable, for example in the air and when laser light is incident vertically on an optical component made of glass, back reflections of about 4% in each case. Antireflection layers now largely prevent laser light from coupling back into the laser source. It goes without saying that in a very favorable embodiment, all optical components are provided with an anti-reflective layer. In this context, it is particularly advantageous if an antireflection layer consists of a layer which is transparent to radiation in the wavelength range from 120 nm to 1500 nm, because in this case the same optical components can also be used to conduct plasma-emitted radiation.
  • prisms made of calcium fluoride have proven particularly useful for guiding light. Fluoride compounds with sufficient transparency down to the UV range of up to 120 nanometers can be deposited easily and with high optical quality on prisms made of this material.
  • An advantage of a deposition of fluorides on calcium fluoride is that a great adhesive strength of the deposited layer and a high thermal and mechanical stability of prisms overall can be achieved with these material pairs.
  • the optical components have at least one mirror provided with a dielectric layer and a metallic coating, laser light on the one hand and on the other hand with the aid of the dielectric layer radiation emitted by the plasma can be effectively directed in any direction with the aid of the metallic coating.
  • a mirror is advantageously provided with a metallic coating on one surface and with a dielectric layer on an opposite surface, the dielectric layer and the parts of the mirror located between the surfaces in the
  • Wavelength ranges from 120 nm to 1500 nm are transparent. Such a design prevents the dielectric layers from splintering in the event of temperature fluctuations, which, if a dielectric layer is applied directly to a metallic layer, can occur because of significantly different coefficients of thermal expansion of the layers. If a device according to the invention is to be used to control metallurgical processes, it is advantageous if at least some of the optical components and the focusing device are arranged in an arm which has a cavity. The optical components are thus protected from dust and dirt in a simple manner.
  • a high degree of flexibility in the conduction of laser light and at most radiation emitted by the plasma is achieved if the arm has segments which can be displaced and / or rotated relative to one another.
  • the arm has one or more joints and a mirror or prism is provided at the respective joint points for deflecting laser light or emitted radiation.
  • the focusing device is movable, in particular displaceable.
  • a control device is provided for a movement of the focusing device depending on a position or intensity of the emitted radiation measured by the position-sensitive detector or depending on a spectrum measured by the analysis device. This configuration makes it possible to keep the laser power on or in the sample constant during a measurement.
  • the device has a correction device for setting a beam diameter of laser light.
  • Control device for automatic adjustment of the beam diameter depending on a position measured by the position sensitive detector or intensity of the emitted radiation or as a function of a spectrum measured by the analysis device offers the advantage of controlled constant laser power on or in the sample during a measurement.
  • the optical components form a first light guide system and further optical components form at least one second light guide system, the device having a light switch through which laser light and / or emitted radiation can pass through the respective light guide systems or from the light guide systems of the analysis device and / or can optionally be fed to the detector.
  • chemical analyzes can be carried out quickly at different locations, which can be very important, in particular, for seamless process control.
  • the same laser source and the same analysis device or the same position-sensitive detector can be used regardless of the measurement location. Equipment expenditure is therefore minimized.
  • the procedural aim of the invention is achieved in that, in a method of the type mentioned at the outset, the intensity of radiation emitted by the plasma is measured in a position-sensitive manner on a second optical axis that differs from the optical axis of the laser light, and from this a distance of the focusing device from the surface of the fixed or liquid substance or a position of the plasma in the gaseous substance is determined.
  • the method also enables position changes to be determined very precisely. This applies in particular if a device as described above is used to carry out the method.
  • an optical path from the plasma to a position-sensitive detector can be one or more meters. Small changes in the position of the plasma then result in large shifts in the detector. In other words: a measurement is made with particular accuracy.
  • a further advantage of a method according to the invention is given in that changes in a plasma position can be observed with little outlay on equipment, because emissions of the plasma which is anyway necessary for analyzing a chemical composition are used.
  • An advantage lies in particular in the fact that a method according to the invention can also be used in the investigation of metallic melts, in which conventional methods of distance measurement are unreliable or not applicable.
  • the distance of the focusing device from the surface of the solid or liquid substance or from the plasma in the gaseous substance is continuously determined and automatically regulated.
  • Beam diameter of the laser light is regulated.
  • changes in the distance from the plasma to the focusing device and the associated changes in the laser power on the sample can be compensated for by widening or narrowing the laser beam. Since a variation of the laser beam diameter is possible immediately after the laser light emerges from the laser source, the laser light output can be far from that Sampling point can be easily readjusted.
  • the focusing device located near the sample can be kept stationary.
  • the laser light and the emitted radiation are guided at least partially over the same optical components.
  • devices such as the laser source, analysis device and detector can be set up at a safe distance from the measuring location. This also enables simple maintenance or, if necessary, repair of the facilities mentioned.
  • incident laser light is scanned over the surface or guided over a surface.
  • an average value is obtained when determining a chemical composition, for example of a metal melt, and measurement falsifications, which are caused by inhomogeneities on the melt surface, are reduced.
  • Scanning can be carried out in a simple manner by rotating a mirror or prism in the beam path, as a result of which the laser light changes its direction.
  • Figure 1a is a schematic representation of a device according to the invention
  • Figure 1 b an arm for beam guidance
  • Figure 1c is a schematic representation of the discovery of a
  • Figure 2 shows a coated prism
  • Figure 3a shows a mirror coated on one side.
  • Figure 3b shows a mirror coated on both sides
  • Figure 4 shows a beam switch with several arms for beam guidance
  • FIG. 5a shows a jet switch with a swivel joint 5b shows the jet switch from FIG. 5a in a side view
  • FIG. 1a shows an embodiment of a device 1 according to the invention, which is particularly suitable for examining metallic melts.
  • FIG. 1 a shows a laser source 11 suitable for generating high-energy laser light 41.
  • the laser source 11 can be a pulsed Nd: YAG laser, the 1064 nm laser line of which is used in the further course of the measurement.
  • the laser light 41 strikes a diverging lens 14, which is arranged in the beam path in front of other optical components and with which the beam parameters such as diameter and divergence of the laser light can be adjusted by shifting.
  • the laser light 41 then passes through a beam guidance system 2, which is subdivided into a plurality of segments which can be displaced and / or rotated relative to one another, and strikes a focusing device 15, with which it is focused or focused on a surface 31 of a sample 3.
  • the plasma 31 ignited on the sample 3 emits characteristic radiation 51, which is guided over the beam guidance system 2 and along the same optical axis 4 as the laser light 41 and is fed to an analysis device 12 with the aid of a transparent mirror 17.
  • the analysis device 12 can be, for example, a commercially available wavelength-dispersive spectrometer. Emitted radiation is guided along a second optical axis 5 to a converging lens 16 and directed onto a position-sensitive detector 13.
  • the parts of the device 1 lying within a housing area 6 can be accommodated in a single housing and can thus be operated far from the sample 3 to be examined and, if necessary, serviced.
  • the radiation guidance system 2 is shown in more detail in one embodiment in FIG. 1b.
  • Individual arm segments 21 are connected to form an arm which is hollow on the inside and inside which laser light 41 and radiation 51 emitted by a plasma can be conducted.
  • the arm segments 21 have an axis of rotation A, A 'or A "about which they can be rotated relative to one another.
  • Prisms 22 are located at intersections of the axes of rotation A, A' and A" and each rotate with an arm segment 21.
  • extendable and retractable segments can of course also be provided in order to bring an arm closer to a sample 3.
  • FIG. 1c The effects of a change in position of a plasma 32 are shown in FIG. 1c. If, at the start of a measurement, a plasma 32 is ignited on a surface of a molten metal 81 by a laser beam 41 incident along an optical axis, this emits radiation, which is focused along a second optical axis by means of a lens onto a position-sensitive detector 13, such as a photodiode array, and is detected there with photodiode 13a. If a level of the molten metal 81 now rises during a measurement, an emission of the plasma 32 ′ results in a signal at the photodiode 13b.
  • a position-sensitive detector 13 such as a photodiode array
  • FIG. 2 shows an embodiment of a prism 22 as it is advantageously used in a device according to the invention.
  • the prima 22 has a prism base body 22a made of calcium fluoride (CaF 2 ) which is transparent to both laser light and radiation 51 emitted by a plasma 32.
  • Anti-reflective coatings 22b made of a fluoride are applied to the prism base body 22a and reduce the proportion of reflected laser light 41. Among other things, this can prevent significant portions of laser light 41 from being coupled back into the laser 11, which can lead to damage or even render the laser 11 unusable.
  • FIGS. 3a and 3b show mirrors 23 which are particularly suitable for use in a device according to FIG. 1.
  • a mirror 23 has a mirror base body 23a, on which a metallic coating 23b for reflecting radiation 51 emitted by the plasma is applied.
  • a dielectric coating 23c is applied to the metallic coating 23b, which effectively reflects laser light 41, but is transparent to emitted radiation 51.
  • FIG. 3b An alternative arrangement of coatings on the mirror base body 23a is shown in FIG. 3b. In this alternative, they are metallic
  • Coating 23b on one side of the mirror base body 23a and a dielectric coating 23c applied on an opposite side This proves to be an advantage when a device 1 according to the invention is used at high temperatures, for example when determining the chemical composition of a molten steel.
  • Metallic coating 23b and dielectric coating 23c, which have significantly different coefficients of thermal expansion, are then insulated from one another. Therefore, the metallic coating 23b can expand with increasing temperature without influencing the dielectric coating 23b.
  • a jet switch 7, its mode of operation and various configurations are illustrated in FIGS. 4 to 6.
  • laser light can be fed from a device through a beam splitter 7 to different beam arms 2, 2 ', 2 ", which guide the laser light to metal melts 81, 81', 81" located in metallurgical vessels 8, 8 ', 8 "
  • Plasma emissions can also be directed to a device 1 via beam arms 2 and beam splitter 7 and analyzed there.
  • a prism 22 is provided in the beam splitter 7, which can be rotated about an axis A and thus can feed light to different beam arms 2 or can feed light from individual beam arms 2 to a device 1.
  • a beam splitter 7 can also have a linearly displaceable prism 22 with which individual beam arms 2 can be used to supply or remove light.

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  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Plasma & Fusion (AREA)
  • Optics & Photonics (AREA)
  • Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Investigating, Analyzing Materials By Fluorescence Or Luminescence (AREA)

Abstract

L'invention concerne un dispositif et un procédé de détermination de la composition chimique de matières solides, liquides ou gazeuses, notamment de fontes métalliques, par spectroscopie au plasma produit par laser. L'invention vise à permettre l'observation rapide, fiable, simple et précise de variations d'un écart entre l'échantillon (3) et un dispositif de focalisation (15) de lumière laser, notamment dans le cas de fontes métalliques, et donc à éliminer des erreurs de mesure. A cet effet, le dispositif selon l'invention comporte une source laser (11) destinée à la production de lumière laser, des composants optiques éventuels (22), un dispositif de focalisation destiné à guider la lumière laser sur une surface de la matière solide ou liquide ou dans la matière gazeuse, afin d'y amorcer un plasma, un dispositif d'analyse (12) destiné à déterminer la composition chimique de la matière par analyse spectrale du rayonnement émis par le plasma, et un détecteur sensible à la position (13) destiné à détecter le rayonnement émis par le plasma. Selon ledit procédé, la lumière laser et le rayonnement plasma émis pour la détermination de la composition chimique sont guidés le long d'un premier axe optique (4) et le rayonnement plasma supplémentaire nécessaire à la détermination de l'écart est guidé le long d'un deuxième axe optique (5), différent du premier, vers le détecteur sensible à la position.
EP05700034A 2004-02-18 2005-02-14 Dispositif et procede de determination de la composition chimique de matieres solides, liquides ou gazeuses Withdrawn EP1716407A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
AT2592004A AT500029B1 (de) 2004-02-18 2004-02-18 Vorrichtung und verfahren zur bestimmung der chemischen zusammensetzung von festen, flüssigen oder gasförmigen stoffen
PCT/AT2005/000049 WO2005078416A1 (fr) 2004-02-18 2005-02-14 Dispositif et procede de determination de la composition chimique de matieres solides, liquides ou gazeuses

Publications (1)

Publication Number Publication Date
EP1716407A1 true EP1716407A1 (fr) 2006-11-02

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EP05700034A Withdrawn EP1716407A1 (fr) 2004-02-18 2005-02-14 Dispositif et procede de determination de la composition chimique de matieres solides, liquides ou gazeuses

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EP (1) EP1716407A1 (fr)
AT (1) AT500029B1 (fr)
WO (1) WO2005078416A1 (fr)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101915753B (zh) * 2010-07-30 2013-05-29 浙江师范大学 基于遗传神经网络的激光诱导击穿光谱定量分析方法
BE1022447B1 (fr) * 2013-12-05 2016-04-06 Centre De Recherches Metallurgiques Asbl Dispositif de focalisation d'un faisceau laser par camera (ii)
DE102019106765B4 (de) * 2019-03-18 2020-11-26 Thyssenkrupp Ag Verfahren zur Präparation und Analyse einer Probe eines metallischen Werkstoffs
CN112255205A (zh) * 2020-09-23 2021-01-22 菲兹克光电(长春)有限公司 一种基于激光诱导等离子体谱的鉴伪文检系统及方法

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Publication number Priority date Publication date Assignee Title
US4774403A (en) * 1987-03-30 1988-09-27 Harvey Industries, Inc. Triangulation-type position measuring device
US6008897A (en) * 1999-01-19 1999-12-28 National Research Council Of Canada Method and apparatus for materials analysis by enhanced laser induced plasma spectroscopy
AT409553B (de) * 2000-09-28 2002-09-25 Voest Alpine Ind Anlagen Vorrichtung zur chemischen analyse von materialproben sowie metallurgisches gefäss hierfür
EP1223423A3 (fr) * 2001-01-16 2004-01-28 National Research Council of Canada Procédé et dispositif pour spectroscopie amplifiée au plasma produit par laser utilisant des impulsions laser avec des longueurs d'onde mélangées
US6741345B2 (en) * 2001-02-08 2004-05-25 National Research Council Of Canada Method and apparatus for in-process liquid analysis by laser induced plasma spectroscopy
US6909505B2 (en) * 2002-06-24 2005-06-21 National Research Council Of Canada Method and apparatus for molten material analysis by laser induced breakdown spectroscopy

Non-Patent Citations (1)

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See references of WO2005078416A1 *

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Publication number Publication date
AT500029B1 (de) 2006-11-15
AT500029A1 (de) 2005-10-15
WO2005078416A1 (fr) 2005-08-25

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