EP1704898A1 - Oxidation protection of a cosmetic composition with rice germ oil - Google Patents

Abstract

Cosmetic composition comprises rice germ oil.

Description

The present invention relates to the protection of cosmetic formulations against oxidative degradation and thus protected preparations.
Oxidation-sensitive preparations in the sense of the present specification are oils sensitive to oxidation, especially vegetable oils which have a high proportion of unsaturated fatty acids. This is characterized in particular by the iodine number. For the purposes of the invention, an oxidation-sensitive oil is an oil having an iodine value greater than 80. Further oxidation-sensitive substances in the context of the invention are plant extracts, the extracts of the plant families of Nymphaeaceae, Nelumbonaceae, Fabaceae and / or Leguminosae being particularly preferred.

State of the art

In cosmetic formulations containing water, vegetable oils or active ingredients are often used to give the product a nourishing effect. For this purpose, vegetable oils are often used with a high proportion of unsaturated fatty acids, as they are very close to the natural skin lipids in structure and composition and are very well absorbed by the skin. The more unsaturated units present in an oil, the greater its tendency to spoil by oxidative processes. In cosmetic products, this often leads to undesirable color and odor impairments.
So far, these vegetable oils are stabilized by additional stabilizers (such as BHT, propyl gallate, tocopherol acetates, EDTA, IDS, UV filters, benzophenones, etc.) in the formulation. Many of these substances are problematic and also cause considerable additional costs.

A particular challenge is to find an alternative route to the long-term stabilization of this formulation containing vegetable oils.

invention

It has now been found that the serious disadvantages of the prior art, in particular the lack of color and oxidation stability can be avoided by cosmetic preparation containing rice germ oil. Thus, odor impairments and quality reductions of cosmetic preparations are overcome in a manner not foreseeable by the skilled person.
Cosmetic preparations with oxidation-sensitive ingredients are surprisingly stabilized by the skilled person by the addition of rice oil (Oryza sativa). In particular, this is surprising since the rice oil itself is an unsaturated oil. Rice oil-containing preparations are suitable both as leave-on products such as emulsions, body oils, etc., and as rinse-off products such as shower and bath products, shampoos, etc. These are characterized by being able to meet consumer expectations to a great extent and thereby have a significant market significance.
It is preferred if the content of rice germ oil 0.05 to 6 wt.%, Particularly preferably 0.2 to 5 wt.%, Very particularly preferably 0.5 to 2 wt.% Is.
It is preferred if in addition an oxidation-sensitive substance is included.
It is further preferred if the oxidation-sensitive substance is present in concentrations of at least 0.1% by weight, more preferably 0.5% by weight, very preferably 1% by weight, very preferably 5% by weight. It is preferred if the oxidation-sensitive substance has an iodine number of at least 80. It is further preferred if the oxidation-sensitive substance contains an oxidizable vegetable oil or a plant extract, particularly preferably extracts of the plant families of the Nymphaeaceae, Nelumbonaceae, Fabaceae and / or Leguminosae. It is preferred if preparation at least 1 wt.%, Particularly preferably more than 2 wt.% Surfactant substance, most preferably with an HLB value between 3.8 to 8 or greater than 10, very exceptionally particularly preferably between 5 and 7 or greater than 12 contains.

It is preferred if the surface-active substance is selected from the group of ethoxylated fatty alcohol derivatives having a C chain length greater than 10 and a mean degree of ethoxylation between 2 and 75, more preferably between 2 and 39, most preferably between 2 and 5.

• (a) 1 - 25 Gew.% eines oder mehrerer Alkyl- und/oder Alkylethersulfate,
• (b) 0,1 -20 Gew.% N-Acylglutamat,
• (c) wobei der Gehalt an freien Fettsäuren in den Zubereitungen geringer als 3 Gew.% bevorzugt geringer als 2 Gew. % besonders bevorzugt bis zu 1 Gew.%, aber in allen Fällen mindestens 0,2 Gew.% beträgt,

enthält.
Weiter ist es bevorzugt, wenn die Zubereitung einen Lipidanteil von mindestens 5 Gew.%, bevorzugt mindestens 10 Gew.%, besonders bevorzugt mindestens 15 Gew.% aufweist.
Durch weitere Zugabe geringer Mengen von Oryzanol wird ein synergistischer Effekt erzielt der sich in überraschender Weise sogar zu Stabilisierung besonders oxidationsempfindlicher Substanzen eignet.
Daher ist es bevorzugt, wenn die Zubereitung zusätzlich mehr als 0,007 Gew.% Oryzanol, bevorzugt mehr als 0,01 Gew.% Oryzanol enthält.
Die Erfindung umfasst auch die Verwendung von erfindungsgemäßen Zubereitungen zur Körperpflege und/oder Körperreinigung.
Das Weglassen eines einzelnen Bestandteile beeinträchtigt die einzigartigen Eigenschaften der Gesamtzusammensetzung. Daher sind alle angegebenen Bestandteile der erfindungsgemäßen Zubereitungen zwangsläufig erforderlich, um die Erfindung auszuführen.It is further preferred if anionic surfactants, particularly preferably alkyl and / or alkyl ether sulfates, in proportions of from 2 to 25% by weight, preferably from 3 to 20% by weight and particularly preferably from 7.5 to 15% by weight, are present as surface-active substances.
It is further preferred if it contains further anionic, amphoteric or nonionic surfactants of 1-15% by weight, particularly preferably 3-10% by weight and very particularly preferably 4-7% by weight.
It is preferred if they

• (a) 1 to 25% by weight of one or more alkyl and / or alkyl ether sulfates,
• (b) 0.1-20% by weight of N-acyl glutamate,
• (c) wherein the content of free fatty acids in the preparations is less than 3% by weight, preferably less than 2% by weight, more preferably up to 1% by weight, but in all cases at least 0.2% by weight,

contains.
It is further preferred if the preparation has a lipid content of at least 5% by weight, preferably at least 10% by weight, particularly preferably at least 15% by weight.
By further addition of small amounts of oryzanol, a synergistic effect is achieved, which is surprisingly even suitable for stabilizing particularly oxidation-sensitive substances.
Therefore, it is preferred if the preparation additionally contains more than 0.007% by weight of oryzanol, preferably more than 0.01% by weight of oryzanol.
The invention also encompasses the use of preparations according to the invention for personal care and / or body cleansing.
The omission of a single component affects the unique properties of the overall composition. Therefore, all stated constituents of the preparations according to the invention are necessarily required to carry out the invention.

Advantageous embodiments

• anionische Tenside,
• kationische Tenside,
• amphotere Tenside und
• nichtionische Tenside.

Anionische Tenside weisen als funktionelle Gruppen in der Regel Carboxylat-, Sulfat- oder Sulfonatgruppen auf. In wäßriger Lösung bilden sie im sauren oder neutralen Milieu negativ geladene organische Ionen. Kationische Tenside sind beinahe ausschließlich durch das Vorhandensein einer quarternären Ammoniumgruppe gekennzeichnet. In wäßriger Lösung bilden sie im sauren oder neutralen Milieu positiv geladene organische lonen. Amphotere Tenside enthalten sowohl anionische als auch kationische Gruppen und verhalten sich demnach in wäßriger Lösung je nach pH-Wert wie anionische oder kationische Tenside. Im stark sauren Milieu besitzen sie eine positive und im alkalischen Milieu eine negative Ladung. Im neutralen pH-Bereich hingegen sind sie zwitterionisch, wie das folgende Beispiel verdeutlichen soll: RNH₂ ⁺CH₂CH₂COOH X^- (bei pH=2) X^- = beliebiges Anion, z.B. Cl^- RNH₂ ⁺CH₂CH₂COO^- (bei pH=7) RNHCH₂CH₂COO^- B⁺ (bei pH=12) B⁺ = beliebiges Kation, z.B. Na⁺ Preparations according to the invention preferably contain surfactants. Surfactants are amphiphilic substances that can dissolve organic, nonpolar substances in water. Due to their specific molecular structure with at least one hydrophilic and one hydrophobic part of the molecule, they provide for a lowering of the surface tension of the water, the wetting of the skin, the facilitation of dirt removal and dissolution, a gentle rinsing and, as desired, for foam regulation.
The hydrophilic portions of a surfactant molecule are usually polar functional groups, for example -COO ^- , -OSO ₃ ^2- , -SO ₃ ^- , while the hydrophobic parts are usually nonpolar hydrocarbon radicals. Surfactants are generally classified according to the nature and charge of the hydrophilic part of the molecule. Here four groups can be distinguished:

• anionic surfactants,
• cationic surfactants,
• amphoteric surfactants and
• nonionic surfactants.

Anionic surfactants generally have carboxylate, sulfate or sulfonate groups as functional groups. In aqueous solution they form negatively charged organic ions in an acidic or neutral medium. Cationic surfactants are almost exclusively characterized by the presence of a quaternary ammonium group. In aqueous solution, they form positively charged organic ions in an acidic or neutral environment. Amphoteric surfactants contain both anionic and cationic groups and behave accordingly in aqueous solution depending on the pH as anionic or cationic surfactants. They have a positive charge in a strongly acidic environment and a negative charge in an alkaline environment. In the neutral pH range, however, they are zwitterionic, as the following example is intended to illustrate: RNH ₂ ⁺ CH ₂ CH ₂ COOH X ^- (at pH = 2) X ^- = any anion, eg Cl ^- RNH ₂ ⁺ CH ₂ CH ₂ COO ^- (at pH = 7) RNHCH ₂ CH ₂ COO ^- B ⁺ (at pH = 12) B ⁺ = any cation, eg Na ⁺

Typical of non-ionic surfactants are polyether chains. Nonionic surfactants do not form ions in an aqueous medium.

A. Anionic surfactants

1. 1. Acylglutamate, beispielsweise Natriumacylglutamat, Di-TEA-palmitoylaspartat und Natrium Caprylic/ Capric Glutamat,
2. 2. Sarcosinate, beispielsweise Myristoyl Sarcosin, TEA-lauroyl Sarcosinat, Natriumlauroylsarcosinat und Natriumcocoylsarkosinat,

Carbonsäuren und Derivate, wie

1. 1. Carbonsäuren, beispielsweise Laurinsäure, Aluminiumstearat, Magnesiumalkanolat und Zinkundecylenat,
   Sulfonsäuren und Salze, wie

1. 1. Acyl-isethionate, z.B. Natrium-/ Ammoniumcocoyl-isethionat,
2. 2. Alkylsulfonate, beispielsweise Natriumcocosmonoglyceridsulfat, Natrium C_12-14 Olefin-sulfonat, Natriumlaurylsulfoacetat und Magnesium PEG-3 Cocamidsulfat,
3. 3. Sulfosuccinate, beispielsweise Dioctylnatriumsulfosuccinat, Dinatriumlaurethsulfosuccinat, Dinatriumlaurylsulfosuccinat, Dinatriumundecylenamido-MEA-Sulfosuccinat und PEG-5 Laurylcitrat Sulfosuccinat.

sowie
Schwefelsäureester, wie

1. 1. Alkylethersulfat, beispielsweise Natrium-, Ammonium-, Magnesium-, MIPA-, TIPA-Laurethsulfat, Natriummyrethsulfat und Natrium C_12-13-Parethsulfat,
2. 2. Alkylsulfate, beispielsweise Natrium-, Ammonium- und TEA-Laurylsulfat.

Advantageously used anionic surfactants are
Acylamino acids (and their salts), such as

1. 1. acylglutamates, for example sodium acylglutamate, di-TEA-palmitoylaspartate and sodium caprylic / capric glutamate,
2. 2. sarcosinates, for example myristoyl sarcosine, TEA lauroyl sarcosinate, sodium lauroyl sarcosinate and sodium cocoyl sarcosinate,

Carboxylic acids and derivatives, such as

1. 1. carboxylic acids, for example lauric acid, aluminum stearate, magnesium alkoxide and zinc undecylenate,
   Sulfonic acids and salts, such as

1. 1. acyl isethionates, eg sodium / ammonium cocoyl isethionate,
2. 2. alkyl sulfonates, for example sodium coconut monoglyceride sulfate, sodium C _12-14 olefin sulfonate, sodium lauryl sulfoacetate and magnesium PEG-3 cocamide sulfate,
3. 3. Sulfosuccinates, for example dioctyl sodium sulfosuccinate, disodium laureth sulfosuccinate, disodium lauryl sulfosuccinate, disodium undecylenamido MEA sulfosuccinate and PEG-5 lauryl citrate sulfosuccinate.

such as
Sulfuric acid esters, such as

1. 1. alkyl ether sulfate, for example sodium, ammonium, magnesium, MIPA, TIPA laureth sulfate, sodium myreth sulfate and sodium C _12-13 pareth sulfate,
2. 2. Alkyl sulfates, for example sodium, ammonium and TEA lauryl sulfate.

B. Cationic surfactants

1. 1. Alkylamine,
2. 2. Alkylimidazole,
3. 3. Ethoxylierte Amine und
4. 4. Quaternäre Tenside.
5. 5. Esterquats

Advantageously to use cationic surfactants

1. 1. alkylamines,
2. 2. alkylimidazoles,
3. 3. Ethoxylated amines and
4. 4. Quaternary surfactants.
5. 5. Esterquats

Quaternary surfactants contain at least one N atom covalently bonded to 4 alkyl and / or aryl groups. This results in a positive charge regardless of the pH. Advantageous quaternary surfactants are alkylbetaine, alkylamidopropylbetaine and alkylamidopropylhydroxysulfaine. Cationic surfactants can furthermore preferably be chosen, for the purposes of the present invention, from the group of quaternary ammonium compounds, in particular benzyltrialkylammonium chlorides or bromides, such as benzyldimethylstearylammonium chloride, furthermore alkyltrialkylammonium salts, for example cetyltrimethylammonium chloride or bromide, alkyldimethylhydroxyethylammonium chlorides or bromides, dialkyldimethylammonium chlorides or bromides, alkylamidethyltrimethylammonium ether sulfates Alkylpyridinium salts, for example lauryl or cetylpyrimidinium chloride, imidazoline derivatives and compounds having a cationic character such as amine oxides, for example alkyldimethylamine oxides or alkylaminoethyldimethylamine oxides. Cetyltrimethylammonium salts are particularly advantageous to use.

C. Amphoteric surfactants

1. 1. Acyl-/dialkylethylendiamin, beispielsweise Natriumacylamphoacetat, Dinatriumacylamphodipropionat, Dinatriumalkylamphodiacetat, Natriumacylamphohydroxypropylsulfonat, Dinatriumacylamphodiacetat und Natriumacylamphopropionat,
2. 2. N-Alkylaminosäuren, beispielsweise Aminopropylalkylglutamid, Alkylaminopropionsäure, Natriumalkylimidodipropionat und Lauroamphocarboxyglycinat.

Advantageously used amphoteric surfactants

1. 1. acyl / dialkylethylenediamine, for example sodium acylamphoacetate, disodium acylamphodipropionate, disodium alkylamphodiacetate, sodium acylamphohydroxypropylsulfonate, disodium acylamphodiacetate and sodium acylamphopropionate,
2. 2. N-alkylamino acids, for example aminopropylalkylglutamide, alkylaminopropionic acid, sodium alkylimidodipropionate and lauroamphocarboxyglycinate.

D. Nonionic surfactants

1. 1. Alkohole,
2. 2. Alkanolamide, wie Cocamide MEA/ DEA/ MIPA,
3. 3. Aminoxide, wie Cocoamidopropylaminoxid,
4. 4. Ester, die durch Veresterung von Carbonsäuren mit Ethylenoxid, Glycerin, Sorbitan oder anderen Alkoholen entstehen,
5. 5. Ether, beispielsweise ethoxylierte/propoxylierte Alkohole, ethoxylierte/ propoxylierte Ester, ethoxylierte/ propoxylierte Glycerinester, ethoxylierte/ propoxylierte Cholesterine, ethoxylierte/ propoxylierte Triglyceridester, ethoxyliertes propoxyliertes Lanolin, ethoxylierte/ propoxylierte Polysiloxane, propoxylierte POE-Ether und Alkylpolyglycoside wie Laurylglucosid, Decylglycosid und Cocoglycosid.
6. 7. Polyglycerinester, Diglycerinester, Monoglycerinester
7. 8. Methylglucosester, Ester von Hydroxysäuren

Advantageously used nonionic surfactants are

1. 1. Alcohols,
2. 2. alkanolamides, such as cocamide MEA / DEA / MIPA,
3. 3. amine oxides, such as cocoamidopropylamine oxide,
4. 4. Esters formed by esterification of carboxylic acids with ethylene oxide, glycerol, sorbitan or other alcohols,
5. 5. Ethers, for example ethoxylated / propoxylated alcohols, ethoxylated / propoxylated esters, ethoxylated / propoxylated glycerol esters, ethoxylated / propoxylated cholesterols, ethoxylated / propoxylated triglyceride esters, ethoxylated propoxylated lanolin, ethoxylated / propoxylated polysiloxanes, propoxylated POE ethers and alkyl polyglycosides such as lauryl glucoside, decyl glycoside and cocoglycoside.
6. 7. Polyglycerol esters, diglycerol esters, monoglycerol esters
7. 8. Methyl glucose esters, esters of hydroxy acids

bei welcher X und Y unabhängig voneinander gewählt werden aus der Gruppe H (Wasserstoff) sowie der verzweigten und unverzweigten Alkylgruppen, Acylgruppen und Alkoxygruppen mit 1 - 24 Kohlenstoffatomen, p eine Zahl von 0 - 200 darstellt, q eine Zahl von 1 - 40 darstellt, und r eine Zahl von 1 - 100 darstellt.It is also advantageous to use a combination of anionic and / or amphoteric surfactants with one or more nonionic surfactants. The following surfactants have proved to be particularly advantageous for use: sodium acylglutamate, sodium lauroyl sarcosinate, sodium isethionate, disodium laurylsulfosuccinate, sodium laureth sulfate, sodium parethsulfate, alkylamidopropylbetaine, sodium alkylamphodiacetate, alkylpolyglycosides, such as laurylglucoside, decylglycoside and cocoglycoside.
Emulsifiers may be added to the preparations according to the invention. According to the invention, the silicone emulsifiers can advantageously be selected from the group of the alkyl methicone copolyols and / or alkyl dimethicone copolyols, in particular from the group of compounds which are characterized by the following chemical structure:

in which X and Y are independently selected from the group H (hydrogen) and the branched and unbranched alkyl groups, acyl groups and alkoxy groups having 1 to 24 carbon atoms, p is a number from 0 to 200, q represents a number from 1 to 40, and r represents a number from 1 to 100.

An example of silicone emulsifiers which are particularly advantageous for the purposes of the present invention are dimethicone copolyols which are sold under the trade names ABIL® EM 90, ABIL® EM 97 and ABIL® B 88183.

• Sorbitanstearat, Sorbitanoleat, Lecithin, Glyceryllanolat, Lanolin, mikrokristallines Wachs (Cera microcristallina) im Gemisch mit Paraffinöl (Paraffinum liquidum), Ozokerit, hydriertem Ricinusöl, Glycerylisostearat, Polyglyceryl-3-Oleat, Wollwachssäuregemische, Wollwachsalkoholgemische, Pentaerythrithylisostearat, Polyglyceryl-3 Diisostearat, Sorbitan Oleat im Gemisch mit hydriertem Ricinusöl, Bienenwachs (Cera alba) und Stearinsäure, Natriumdihydroxycetylphosphat im Gemisch mit Isopropylhydroxycetylether, Methylglucosedioleat, Methylglucosedioleat im Gemisch mit Hydroxystearat und Bienenwachs, Mineralöl im Gemisch mit Petrolatum und Ozokerit und Glyceryloleat und Lanolinalkohol, Petrolatum im Gemisch mit Ozokerit und hydriertem Ricinusöl und Glycerylisostearat und Polyglyceryl-3-oleat, PEG-7-hydriertes Ricinusöl, Sorbitanoleat im Gemisch mit PEG-2-hydriertem Ricinusöl, Ozokerit und hydriertem Ricinusöl, Sorbitanisostearat im Gemisch mit PEG-2-hydriertem Ricinusöl, Polyglyceryl-4-isostearat, Polyglyceryl-4-isostearat, Hexyllaurat, Acrylat/ C_10-30-Alkylacrylat-Crosspolymer, Sorbitanisostearat, Poloxamer 101, Polyglyceryl-2-dipolyhydroxystearat, Polyglyceryl-3-Diisostearat, Polyglyceryl-4-dipolyhydroxystearat, PEG-30-dipolyhydroxystearat, Diisostearoylpolyglyceryl-3-diisostearat, Polyglyceryl-2-dipolyhydroxystearat, Polyglyceryl-3-dipolyhydroxystearat, Polyglyceryl-4-dipolyhydroxystearat, Polyglyceryl-3-dioleat.

The one or more W / O emulsifiers are preferably selected according to the invention from the following group:

• Sorbitan stearate, sorbitan oleate, lecithin, glyceryl lanolate, lanolin, microcrystalline wax (Cera microcristallina) in admixture with paraffin oil, ozokerite, hydrogenated castor oil, glyceryl isostearate, polyglyceryl-3-oleate, wool wax acid mixtures, wool wax alcohol mixtures, pentaerythritol isostearate, polyglyceryl-3 diisostearate, sorbitan Oleat in a mixture with hydrogenated castor oil, beeswax (Cera alba) and stearic acid, Natriumdihydroxycetylphosphat in admixture with isopropyl hydroxycetyl ether, methyl glucose dioleate, methyl glucose dioleate in admixture with hydroxystearate and beeswax, mineral oil in admixture with petrolatum and ozokerite and glyceryl oleate and lanolin alcohol, petrolatum in admixture with ozokerite and hydrogenated Castor oil and glyceryl isostearate and polyglyceryl-3-oleate, PEG-7 hydrogenated castor oil, sorbitan oleate mixed with PEG-2-hydrogenated castor oil, ozokerite and hydrogenated castor oil, sorbitan isostearate in admixture with PEG-2-hydrogenated castor oil, polyglyc eryl 4-isostearate, polyglyceryl 4-isostearate, hexyl laurate, acrylate / C _10-30 alkyl acrylate crosspolymer, sorbitan isostearate, poloxamer 101, polyglyceryl-2-dipolyhydroxystearate, polyglyceryl-3-diisostearate, polyglyceryl-4-dipolyhydroxystearate, PEG-30 dipolyhydroxystearate, diisostearoylpolyglyceryl-3-diisostearate, polyglyceryl-2-dipolyhydroxystearate, polyglyceryl-3-dipolyhydroxystearate, polyglyceryl-4-dipolyhydroxystearate, polyglyceryl-3-dioleate.

The emulsifiers are advantageously selected from the group of sorbitan esters and sucrose esters, in particular the branched and unbranched alkyl esters and alkenyl esters having carbon chains of 4 to 24 carbon atoms, preferably sorbitan stearate, sorbitan oleate, glyceryl sorbitan stearate, sucrose monostearate, sucrose monolaurate, sucrose palmitate.

gekennzeichnet sind, wobei R' einen verzweigten oder unverzweigten Acylrest mit 6 - 14 Kohlenstoffatomen darstellt. Vorteilhaft wird R' gewählt aus der Gruppe der unverzweigten Acylreste.Advantageously, the emulsifiers can be selected from the group of monoglycerol monocarboxylic monoesters, in particular those which by the structures

wherein R 'represents a branched or unbranched acyl radical having 6-14 carbon atoms. Advantageously, R 'is selected from the group of unbranched acyl radicals.

The acids underlying these esters are the hexanoic (Caproic acid) (R '= - C ₅ H ₁₁ ), heptanoic (Enanthic acid) (R '= -C ₆ H ₁₃ ), octanoic (Caprylic) (R '= -C ₇ H ₁₅ ), nonanoic (Pelargonic acid) (R '= -C ₈ H ₁₇ ), decanoic (Capric acid) (R '= -C ₉ H ₁₉ ), undecanoic (R '= -C ₁₀ H ₂₁ ), 10-undecenoic (Undecylenic) (R '= -C ₁₀ H ₁₉ ), dodecanoic (Lauric acid) (R '= -C ₁₁ H ₂₃ ), tridecanoic (R '= -C ₁₂ H ₂₅ ), tetradecanoic (Myristic) (R '= -C ₁₃ H ₂₇ ),

Advantageously, the emulsifiers can also be selected from the group of di- and triglycerol monocarboxylic monoesters. According to the invention, the di- or triglycerol units of the monocarboxylic acid monocarboxylic acid monocarboxylic acid esters or triglycerol monocarboxylic acid monesters according to the invention are present as linear, unbranched molecules, ie "monoglycerol molecules" etherified via the respective OH groups in the 1- or 3-position.

wobei R" einen Kohlenwasserstdffrest, vorteilhaft einen verzweigten oder unverzweigten Alkyl- oder Alkenylrest von 5 bis 17 C-Atomen darstellt.The monocarboxylic acid monoesters according to the invention are preferably characterized by the following structure:

where R "is a Kohlenwasserstdffrest, advantageously a branched or unbranched alkyl or alkenyl radical of 5 to 17 carbon atoms.

wobei R"' einen Kohlenwasserstoffrest, vorteilhaft einen verzweigten oder unverzweigten Alkyl- oder Alkenylrest Alkylrest von 5 bis 17 C-Atomen darstellt.The monocarboxylic acid esters of triglycerin according to the invention are preferably characterized by the following structure:

wherein R "'represents a hydrocarbon radical, preferably a branched or unbranched alkyl or alkenyl radical alkyl radical of 5 to 17 carbon atoms.

The acids underlying these esters are the hexanoic (Caproic acid) (R "or R"'= -C ₅ H ₁₁ ), heptanoic (Enanthic acid) ' (R "or R"'= -C ₆ H ₁₃ ), octanoic (Caprylic) (R "or R '" = -C ₇ H ₁₅ ), nonanoic (Pelargonic acid) (R "or R '" = -C ₈ H ₁₇ ), decanoic (Capric acid) (R "or R"'= -C ₉ H ₁₉ ), undecanoic (R "or R '" = -C ₁₀ H ₂₁ ), 10-undecenoic (Undecylenic) (R "or R"'= -C ₁₀ H ₁₉ ), dodecanoic (Lauric acid) (R "or R"'= -C ₁₁ H ₂₃ ), tridecanoic (R "or R '" = -C ₁₂ H ₂₅ ), tetradecanoic (Myristic) (R "or R '" = -C ₁₃ H ₂₇ ), pentadecanoic (R "or R '" = -C ₁₄ H ₂₉ ), Hexadecansäure (Palmitic acid) (R "or R"'= -C ₁₅ H ₃₁ ), heptadecanoic (Margaric) (R "or R '" = -C ₁₆ H ₃₃ ), octadecanoic (Stearic acid) (R "or R '" = -C ₁₇ H ₃₅ ).

R "and R" 'are particularly favorably selected from the group of the unbranched alkyl radicals with odd C numbers, in particular with 9, 11 and 13 C atoms.

Also advantageous triglyceryldüsostearat (nomenclature analog CTFA: polyglyceryl-3-diisostearat), isostearyl diglycerylsuccinate, Diglycerylsesquüsostearat (nomenclature analog CTFA: polyglyceryl-2-sesquüsostearat), triglycerylpolyhydroxystearate (nomenclature analog CTFA: polyglyceryl-2-polyhydroxystearat).

Likewise particularly advantageous, the emulsifier or emulsifiers are selected from the group of mono-, oligo and polyethoxylated compounds, in particular polyethoxylated monohydric or polybasic alcohols or fatty acids, for example ceteareth-20, PEG-20-glyceryl stearate, steareth-20, PEG-20 Stearate, PEG-30 stearate, PEG-40 stearates, PEG-40 castor oil, PEG-1-glycerol sorbitan oleostearate, PEG-7 hydrogenated castor oil, PEG-40 sorbitan peroleate, PEG-45 dodecyl glycol copolymer.

Preparations according to the invention preferably contain polar oils as lipids. Polar oils are, for example, those from the group of lecithins and fatty acid triglycerides, namely the triglycerol esters of saturated and / or unsaturated, branched and / or unbranched alkanecarboxylic acids having a chain length of 8 to 24, in particular 12 to 18, carbon atoms. The fatty acid triglycerides can be selected, for example, advantageously from the group of synthetic, semi-synthetic and natural oils, such as olive oil (iodine number 77-90), sunflower oil (iodine number 122-138), soybean oil (iodine number 124-132), peanut oil (iodine number 85-105 ), Rapeseed oil (iodine number 95-120), almond oil (iodine number 93-106), palm oil, coconut oil, castor oil (iodine number 82-90), wheat germ oil (iodine value 125-135), grape seed oil 125-142), safflower oil (iodine value 86-119) , Evening primrose oil (iodine number 145-162), macadamia nut oil (iodine value 74-76) and the like.
Particularly advantageous polar lipids in the context of the present invention are all native lipids, such as. B. Olive oil (iodine number 77-90), sunflower oil (iodine number 122-138), soybean oil (iodine number 124-132), peanut oil (iodine number 85-105), rapeseed oil (iodine number 95-120), almond oil (iodine number 93-106), Palm oil, coconut oil, castor oil (iodine value 82-90), wheat germ oil (iodine number 125-135), grape seed oil 125-142), thistle oil (iodine value 86-119), evening primrose oil (iodine number 145-162), macadamia nut oil (iodine value 74-76), corn oil (Iodine number 103-130), avocado oil (iodine value 80-95) and the like and those listed below. Manufacturer trade name INCI name Condea chemistry Isofol 14T Butyl Decanol (+) Hexyl Octanol (+) Hexyl Decanol (+) Butyl Octanol Lipochemicals INC. / USA (Induchem) Lipovol MOS-130 Tridecyl Stearate (+) Tridecyl Trimellitate (+) Dipentaerythrityl Hexacaprylate / Hexacaprate Huels CONDEA chemistry Miglyol 840 Propylene Glycol Dicaprylate / Dicaprate Goldschmidt Tegosoft SH Stearyl heptanoate Henkel Cognis Cetiol B Dibutyl adipate Condea Augusta SPA Cosmacol ELI C12-13 alkyl lactates Henkel Cognis Myritol 331 Cocoglycerides Unichema Prisorine 2041 GTIS Triisostearin

durch Oxidation eines Alkohols zu einem Aldehyd, durch Aldol-Kondensation des Aldehyds, Abspaltung von Wasser aus dem Aldol- und Hydrierung des Allylaldehyds. Guerbetalkohole sind selbst bei niederen Temperaturen flüssig und bewirken praktisch keine Hautreizungen. Vorteilhaft können sie als fettende, überfettende und auch rückfettend wirkende Bestandteile in Haut- und Haarpflegemittein eingesetzt werden.
Die Verwendung von Guerbet-Alkoholen in Kosmetika ist an sich bekannt. Solche Species zeichnen sich dann meistens durch die Struktur

aus. Dabei bedeuten R₁, und R₂ in der Regel unverzweigte Alkylreste.
Erfindungsgemäß vorteilhaft werden der oder die Guerbet-Alkohole gewählt aus der Gruppe, bei denen
R₁ = Propyl, Butyl, Pentyl, Hexyl, Heptyl oder Octyl und
R₂ = Hexyl, Heptyl, Octyl, Nonyl, Decyl, Undecyl, Dodecyl, Tridecyl oder Tetradecyl.
Erfindungsgemäß bevorzugte Guerbet-Alkohole sind das 2-Butyloctanol - es hat die chemische Struktur

und ist beispielsweise unter der Handelsbezeichnung Isofol® 12 von der Gesellschaft Condea Chemie GmbH erhältlich - und das 2-Hexyldecanol - es hat die chemische Struktur

und ist beispielsweise unter der Handelsbezeichnung Isofol® 16 von der Gesellschaft Condea Chemie GmbH erhältlich. Auch Mischungen von erfindungsgemäßen Guerbet-Alkoholen sind erfindungsgemäß vorteilhaft zu verwenden. Mischungen aus 2-Butyloctanol und 2-Hexyldecanol sind beispielsweise unter der Handelsbezeichnung Isofol® 14 von der Gesellschaft Condea Chemie GmbH erhältlich.Furthermore, the oil phase may advantageously be selected from the group of dialkyl ethers, the group of saturated or unsaturated, branched or unbranched alcohols. It is particularly advantageous if the oil phase contains or consists entirely of C _12-15 -alkyl benzoate.
Furthermore, the oil phase can be advantageously selected from the group of Guerbet alcohols. Guerbet alcohols are named after Marcel Guerbet, who first described their production. They arise according to the reaction equation

by oxidation of an alcohol to an aldehyde, by aldol condensation of the aldehyde, elimination of water from the aldol and hydrogenation of allyl aldehyde. Guerbet alcohols are fluid even at low temperatures and cause virtually no skin irritation. Advantageously, they can be used as greasing, overfatting and also moisturizing ingredients in skin and hair care.
The use of Guerbet alcohols in cosmetics is known per se. Such species are usually characterized by the structure

out. R ₁ and R _{2 are} generally unbranched alkyl radicals.
Advantageously according to the invention, the Guerbet alcohol or alcohols are selected from the group in which
R ₁ = propyl, butyl, pentyl, hexyl, heptyl or octyl and
R ₂ = hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl or tetradecyl.
Guerbet alcohols preferred according to the invention are the 2-butyloctanol - it has the chemical structure

and is available, for example, under the trade name Isofol® 12 from Condea Chemie GmbH - and 2-hexyldecanol - it has the chemical structure

and is available, for example, under the trade name Isofol® 16 from Condea Chemie GmbH. Mixtures of Guerbet alcohols according to the invention are also advantageously usable according to the invention. Mixtures of 2-butyloctanol and 2-hexyldecanol are available, for example, under the trade name Isofol® 14 from Condea Chemie GmbH.

Particularly advantageous lipids in the context of the present invention are the substances listed below: Manufacturer trade name INCI name Stearinerie Dubois Fils DUB VCI 10 Isodecyl Neopentanoate Henkel Cognis Cetiol SN Cetearyl Isononanoate Unichema isopropyl palmitate isopropyl palmitate Henkel Cognis Eutanol G octyldodecanol Bayer AG, Dow Corning Silicone oil VP 1120 Phenyl trimethicone Henkel Cognis isopropyl Isopropyl stearate WITCO, Goldschmidt Finsolv TN C12-15 alkyl benzoates Dr. Straetmans Dermofeel BGC Butylene Glycol Caprylate / Caprate Unichema Huels Miglyol 812 Caprylic / Capric Triglycerides

Non-polar oils are, for example, those which are selected from the group of branched and unbranched hydrocarbons and waxes, in particular Vaseline (petrolatum), paraffin oil, squalane and squalene, polyolefins and hydrogenated polyisobutenes. Among the polyolefins, polydecenes are the preferred substances. Manufacturer Trade name Trade name INCI name Neste PAO NV polydecenes (Lief. Hansen & Rosenthal) Nexbase 2006 FG EC petroleum chemistry (supplier Bayer AG) Solvent ME Isohexadecane DEA mineral oil (Lief. Hansen & Rosenthal) Pioneer 2076 Mineral oil Tudapetrol DEA mineral oil (Lief. Hansen & Rosenthal) Pioneer 6301 Mineral oil Tudapetrol EC petroleum chemistry GmbH isoeicosane isoeicosane DEA mineral oil (Lief. Hansen & Rosenthal) Pioneer 2071 Mineral oil Tudapetrol Henkel Cognis Cetiol CC Dicaprylyl carbonates Henkel Cognis Cetiol OE Dicaprylyl ether Unichema Estol 1540 EHC Octyl Cocoate

Fat and / or wax components which can advantageously be used according to the invention can be selected from the group of vegetable waxes, animal waxes, mineral waxes and petrochemical waxes. Favorable according to the invention are, for example, candelilla wax, carnauba wax, Japan wax, esparto grass wax, cork wax, guaruma wax, rice germ oil wax, sugar cane wax, berry wax, ouricury wax, montan wax, jojoba wax, shea butter, beeswax, shellac wax, spermaceti, lanolin (wool wax), crepe fat, ceresin, ozokerite (earth wax). , Paraffin waxes and micro waxes, provided that the conditions required in the main claim are met.

It may also be advantageous to choose the oil phase of the preparations according to the invention partially or completely from the group of cyclic and / or linear silicones, which are also referred to in the present disclosure as "silicone oils". Such silicones or silicone oils may be present as monomers, which are typically characterized by structural elements, as follows:

Silicone oils are high molecular weight synthetic polymeric compounds in which silicon atoms via oxygen atoms chain and / or net-like linked and the remaining valences of silicon by hydrocarbon radicals (usually methyl, more rarely ethyl, propyl, phenyl groups, etc.) are saturated ,

wobei die Siliciumatome mit gleichen oder unterschiedlichen Alkylresten und/oder Arylresten substituiert werden können, welche hier verallgemeinernd durch die Reste R₁ - R₄ dargestellt sind (will sagen, daß die Anzahl der unterschiedlichen Reste nicht notwendig auf bis zu 4 beschränkt ist). m kann dabei Werte von 2 - 200.000 annehmen.As linear silicones having several siloxy units which are advantageously used according to the invention, they are generally characterized by structural elements as follows:

wherein the silicon atoms can be substituted with identical or different alkyl radicals and / or aryl radicals, which are here generalized by the radicals R ₁ - R ₄ (to say that the number of different radicals is not necessarily limited to 4). m can assume values of 2 - 200,000.

werden auch als Polydimethylsiloxan bzw. Dimethicon (INCl) bezeichnet. Dimethicone gibt es in verschiedenen Kettenlängen bzw. mit verschiedenen Molekulargewichten. Dimethicone unterschiedlicher Kettenlänge und Phenyltrimethicone sind besonders vorteilhafte lineare Silikonöle im Sinne der vorliegenden Erfindung. Hersteller Handelsname NCI-Name Wacker Wacker Silikonöl AK 100 Polydimethylsiloxan Dow Corning Dow Corning Fluid 245 Cyclopentasiloxan Dow Corning Dow Corning Fluid 345 Cyclomethicone Systematically, the linear silicone oils are called polyorganosiloxanes; the methyl-substituted polyorganosiloxanes, which are the quantitatively most important compounds of this group and are characterized by the following structural formula

are also referred to as polydimethylsiloxane or dimethicone (INCl). Dimethicones are available in different chain lengths or with different molecular weights. Dimethicone different chain length and phenyltrimethicones are particularly advantageous linear silicone oils in the context of the present invention. Manufacturer trade name NCI Name brave Wacker silicone oil AK 100 polydimethylsiloxane Dow Corning Dow Corning Fluid 245 cyclopentasiloxane Dow Corning Dow Corning Fluid 345 Cyclomethicone

wobei die Siliciumatome mit gleichen oder unterschiedlichen Alkylresten und/oder Arylresten substituiert werden können, welche hier verallgemeinernd durch die Reste R₁ - R₄ dargestellt sind (will sagen, daß die Anzahl der unterschiedlichen Reste nicht notwendig auf bis zu 4 beschränkt ist). n kann dabei Werte von 3/2 bis 20 annehmen. Gebrochene Werte für n berücksichtigen, daß ungeradzahlige Anzahlen von Siloxylgruppen im Cyclus vorhanden sein können.Cyclic silicones which are advantageously used in accordance with the invention are generally characterized by structural elements as follows

wherein the silicon atoms can be substituted with identical or different alkyl radicals and / or aryl radicals, which are here generalized by the radicals R ₁ - R ₄ (to say that the number of different radicals is not necessarily limited to 4). n can assume values of 3/2 to 20. Broken values for n take into account that odd numbers of siloxyl groups may be present in the cycle.

Advantageously, phenyltrimethicone is chosen as the silicone oil. Other silicone oils, for example dimethicone, phenyldimethicone, cyclomethicone (octamethylcyclotetrasiloxane), for example hexamethylcyclotrisiloxane, polydimethylsiloxane, poly (methylphenylsiloxane), cetyldimethicone, behenoxydimethicone, are to be used advantageously in the context of the present invention.

The preparations according to the invention may furthermore comprise cosmetic adjuvants conventionally used in such preparations, for example preservatives, perfumes, substances for preventing foaming, foam stabilizers, Dyes, pigments, which have a coloring effect, thickeners, surface-active substances, emulsifiers, softening, moistening and / or moisturizing substances, moisturizing agents, film formers, fats, oils, waxes, alcohols, polyols and their toxicologically tolerated ethers and esters, branched and / or unbranched hydrocarbons, other antioxidants, stabilizers, pH regulators, bodying agents, bactericides, deodorants, antimicrobials, antistatic agents, UV absorbers, complexing and sequestering agents, pearlescing agents, polymers, electrolytes, organic solvents, silicone derivatives, plant extracts, vitamins and / or other active ingredients or other conventional ingredients of a cosmetic or dermatological formulation. Also solubilizers, eg for incorporation of hydrophobic components such as perfume preparations may be included.

The total amount of the excipients is for example 0.001 to 15 wt .-%, preferably 0.01 to 10 wt .-%, each based on the total weight of the preparation.
The amount of thickening agent is for example 0.05 to 5.0 wt .-%, preferably 0.1 to 3.0 wt .-%, in particular 0.15 to 2.0 wt .-%, each based on the total weight of Preparation.

The following examples are intended to illustrate the present invention without limiting it. Unless indicated otherwise, all amounts, proportions and percentages are based on the weight and the total amount or on the total weight of the preparations.

It is possible in all cases in individual cases that the above-mentioned concentration data are slightly exceeded or fallen short of and yet preparations according to the invention are obtained. This is not unexpected by those skilled in the art given the wide variety of suitable components of such formulations, so that he knows that in such overrun or underrun the soil of the present invention is not left.

The following examples are intended to illustrate the present invention without limiting it. The numerical values in the examples are percentages by weight, based on the total weight of the respective preparations.
To determine the iodine number, the method "iodine number according to Wijs" (cyclohexane / glacial acetic acid method) is used.

Examples O / W emulsion with rice oil and oryzanol

1 2 3 4 5 Glycerylsterat 1.0 --- - 0.5 0.25 Polyethylene glycol (40) stearate 10.0 --- 1 5 --- Triglycerinmethylglucosedistearat --- 5.5 --- --- 2.5 sorbitan --- 1.5 2 --- --- cyclomethicone 12.5 5 --- 10.0 3 dimethicone 5.0 13.0 3.0 10.0 15.0 cetyl alcohol 2 --- 3 1 --- stearyl --- 1 --- 1 --- Cetylstearylalkohol --- --- 1 1 --- C13-16 isoparaffin 0.5 1 3 2.0 --- Mineral oil 0.5 1.0 6.0 3.0 --- Perfume q, s, q, s, q, s, q, s, q, s, methylparaben 0.4 0.1 0.05 0.3 0.4 Propylparaben 0.3 0.4 0.25 0.15 --- Grapeseed oil 0.1 0.25 0.5 plant extracts 0.5 0.01 Evening primrose oil 0.2 0.5 0.25 jojoba oil 1.0 0.2 glycerin 5 10 10 15 7.5 oryzanol 0,025 00:05 00:25 00:03 Charming germ oil 5 0.5 0.2 1 0.75 water ad 100 ad 100 ad 100 ad 100 ad 100 6 7 8th 9 10 polyethylene glycol stearyl ether (21) 1 - 2.5 2 1.5 polyethylene glycol stearyl ether (2) 1 - 5.5 3 7.5 cetearylglucoside --- 8th --- --- --- cyclomethicone 12.5 15 28.0 25.0 17.5 dimethicone 5.0 13.0 5.0 12.0 15.0 behenyl 3 2 --- 1 --- stearyl 3 2 --- 2 --- Cetylstearylalkohol 3 4 --- --- 2 hydrogenated polyisobutene 0.5 0.75 1.0 2.0 0.25 octyldodecanol 0.5 1.0 0.75 3.0 0.25 Mineral oil 5 10 15 3 7.5 glycerin 5 10 15 3 7.5 panthenol 0.5 1.0 0.75 0.25 0.1 Perfume q, s, q, s, q, s, q, s, q, s, methylparaben 0.4 0.1 0.05 0.3 0.4 Propylparaben 0.3 0.4 0.25 0.15 --- modified starch 0.5 --- --- 0.15 - Grapeseed oil 0.1 0.25 0.5 almond oil 0.5 0.01 Evening primrose oil 0.2 0.5 jojoba oil 1.0 0.2 0.1 oryzanol 0025 00:01 0.2 Rice bran oil 5 0.5 0.2 1 0.75 water ad 100 ad 100 ad 100 ad 100 ad 100 11 12 13 14 15 Glycerylsteratcitrat 1.0 0.5 0.1 0.5 0.3 Polyethylene glycol (20) cetearylether 10.0 1.0 5 - - Triglycerinmethylglucosedistearat --- --- --- --- 2.5 cyclomethicone - --- - 1 - dimethicone 0.5 3.0 0.75 1.5 0.2 behenyl 1 --- 2 1 0.2 dicaprylyl 3 5 10 15 5 stearyl --- --- --- 1 0.2 Cetylstearylalkohol --- --- 1 1 0.2 tocopherol 0.5 0.5 0.75 0.25 0.1 octyldodecanol 0.5 --- 0.75 3.0 0.25 panthenol 0.5 --- 0.75 0.25 0.1 Carbomer 0.05 0.35 0.15 0.1 --- Perfume q, s, q, s, q, s, q, s, q, s, Caprylic / Capric triglyceride 1 5 3 5 10 methylparaben 0.4 0.3 0.05 0.3 0.4 Propylparaben 0.3 --- 0.25 0.15 --- Iodopropynyl butylcarbamate. --- --- 0.05 --- 0.1 phenoxyethanol --- 0.5 --- 0.15 --- sorbitol 10 --- - 5 --- butylene --- --- --- 5 10 propylene glycol --- --- 10 5 --- Grapeseed oil 0.1 0.25 0.5 almond oil 0.5 0.01 Evening primrose oil 0.2 0.5 jojoba oil 1.0 0.2 0.1 plant extracts 0.1 0.15 0.3 glycerin --- 7.5 --- --- --- oryzanol 00:05 00:01 00:25 00:03 Rice bran oil 5 0.5 0.2 1 0.75 water ad 100 ad 100 ad 100 ad 100 ad 100 16 17 18 19 20 Glycerylsteratcitrat 1.0 0.75 0.1 0.5 0.3 Polyethylene glycol (20) cetearylether 1.0 --- 2 1.5 - Triglycerinmethylglucosedistearat --- 5.5 --- --- 2.5 cyclomethicone 2 4 6 1 3 dimethicone - 0.5 0.75 --- --- behenyl 1 --- 2 1 0.2 stearyl --- 1 --- 1 0.2 Cetylstearylalkohol --- --- 1 1 0.2 mineral oil 0.5 0.75 1.0 2.0 0.25 octyldodecanol 0.5 1.0 0.75 3.0 0.25 panthenol 0.5 1.0 0.75 0.25 0.1 Carbomer 0.05 0.1 0.15 0.1 --- Perfume q, s, q, s, q, s, q, s, q, s, dicaprylyl 3 5 10 15 5 tocopherol 0.5 1.0 0.75 0.25 0.1 Caprylic / Capric triglyceride 1 2 3 5 10 methylparaben 0.4 0.1 0.25 0.3 0.4 Phenonip 0.3 0.4 0.25 0.15 --- modified starch --- 2.5 --- 0.15 --- Grapeseed oil 0.1 0.25 0.5 almond oil 0.5 0.01 plant extracts 0.3 0.4 Evening primrose oil 0.2 0.5 jojoba oil 1.0 0.2 0.1 glycerin 3 5 8th 12 10 oryzanol 0025 00:01 00:03 Rice bran oil 5 0.5 0.2 1 0.75 water ad 100 ad 100 ad 100 ad 100 ad 100

WO / emulsions

1 2 3 4 5 Triglycerindiisostearat 1.0 0.5 0.25 2.0 3.0 Diglycerindipolyhydroxystearat 1.0 1.5 1.75 3.0 2.0 paraffin oil 12.5 10.0 8.0 5.0 17.5 vaseline 8.0 6.0 5.0 12.0 2.5 hydrogenated coconut glycerides 2.0 1.0 2.5 5.0 0.25 oleate 0.5 0.75 1.0 2.0 0.25 octyldodecanol 0.5 1.0 0.75 3.0 0.25 aluminum stearate 0.4 0.3 0.6 1.0 0.05 dicaprylyl 0.1 0.05 0.15 0.5 1.0 hydrogenated castor oil 0.5 0.75 1.0 2.5 5.0 magnesium sulfate 0.5 0.6 0.5 0.7 1.0 glycerin 3.0 5.0 10.0 15.0 1.5 citric acid 0.2 0.1 0.2 0.3 1.0 sodium citrate 0.4 0.2 0.4 0.6 2.0 Grapeseed oil 0.1 0.25 0.5 almond oil 0.5 0.01 Evening primrose oil 0.2 0.5 plant extracts 1.0 0.2 0.1 Perfume q, s, q, s, q, s, q, s, q, s, ethanol 2.0 --- 5.0 --- --- Caprylic / capric 2.0 2.5 3.0 5.0 0.5 potassium sorbate 0.4 0.15 0.05 0.3 0.4 benzyl alcohol 0.3 0.4 0.25 0.15 --- Dehydroacetic acid, Na salt --- --- 0.05 --- 0.1 orizanol 0025 00:05 00:01 00:25 00:03 Rice bran oil 5 0.5 0.2 1 0.75 water ad 100 ad 100 ad 100 ad 100 ad 100

W / S emulsions

11 12 13 14 15 Cetyl PEG / PPG-10/1 dimethicone 1.0 --- - 3.0 5.0 Cylomethicone + PEG / PPG-18/18 dimethicone 10.0 12.5 15.0 - - cyclomethicone 12.5 15 18.0 25.0 17.5 dimethicone 5.0 13.0 5.0 12.0 15.0 hydrogenated polyisobutene 0.5 0.75 1.0 2.0 0.25 octyldodecanol 0.5 1.0 0.75 3.0 0.25 panthenol 0.5 1.0 0.75 0.25 0.1 sodium chloride 2.0 0.6 2.5 0.7 1.0 glycerin 3.0 5.0 10.0 15.0 1.5 lactic acid 0.2 --- 1.75 0.3 1.0 sodium lactate 0.4 --- 3.5 0.6 2.0 Grapeseed oil 0.1 0.25 0.5 almond oil 0.5 0.01 Evening primrose oil 0.2 0.5 plant extracts 0.2 0, 5 jojoba oil 1.0 0.2 0.1 Perfume q, s, q, s, q, s, q, s, q, s, potassium sorbate 0.4 0.1 0.05 0.3 0.5 C5 cyclomethicone 1.0 --- 7.0 --- --- iodopropynylbutylcarbamate --- --- 0.05 --- 0.1 orizanol 0025 00:05 00:01 00:25 00:03 Rice bran oil 5 0.5 0.2 1 0.75 water ad 100 ad 100 ad 100 ad 100 ad 100

W / O emulsions,

21 22 23 24 25 PEG-22 dodecyl glycol copolymer 5.0 1.5 0.25 --- 3.0 PEG-45 dodecyl glycol polymer 1.0 1.5 1.75 3.0 - paraffin oil 12.5 10.0 8.0 5.0 17.5 isopropyl 8.0 6.0 5.0 12.0 2.5 hydrogenated coconut glycerides 2.0 1.0 2.5 5.0 0.25 Evening primrose oil 0.5 0.75 1.0 2.0 0.25 octyldodecanol 0.5 1.0 0.75 3.0 0.25 aluminum stearate 0.4 0.3 0.6 1.0 0.05 dicaprylyl 0.1 0.05 0.15 0.5 1.0 hydrogenated castor oil 0.5 0.75 1.0 2.5 5.0 magnesium sulfate 0.5 0.6 0.5 0.7 1.0 glycerin 3.0 5.0 10.0 15.0 1.5 citric acid 0.2 0.1 0.2 0.3 1.0 Perfume q, s, q, s, q, s, q, s, q, s, 1,3 butylene glycol 2.0 --- 5.0 --- --- Caprylic / capric 2.0 2.5 3.0 5.0 0.5 benzyl alcohol --- --- --- 1.0 0.75 potassium sorbate 0.4 0.15 0.05 0.3 0.4 plant extracts 0.2 0.3 orizanol 0025 00:05 00:01 00:25 00:03 Reiskeimlöl 5 0.5 0.2 1 0.75 water ad 100 ad 100 ad 100 ad 100 ad 100

W / O emulsions,

26 27 28 29 30 Polyglyceryl-2 dipolyhydroxystearate 3.0 --- 0.25 --- 3.0 Polyglyceryl-3 diisostearate 1.0 3.5 1.75 2.5 - PEG-40 sorbitan isostearate --- 2.5 0.5 3.5 3.0 paraffin oil 12.5 10.0 8.0 5.0 17.5 isopropyl 8.0 6.0 5.0 12.0 2.5 hydrogenated coconut glycerides 2.0 1.0 2.5 5.0 0.25 isopropyl palmitate 0.5 1.0 0.75 3.0 0.25 dicaprylyl 0.1 0.05 0.15 0.5 1.0 potassium sorbate 0.05 0.1 0.5 0.75 0.25 hydrogenated castor oil 0.5 0.75 1.0 2.5 5.0 Talc, micronized 0.5 1.0 --- 0.25 0.1 plant extracts 0.2 0.3 Grapeseed oil 0.1 0.25 0.5 almond oil 0.5 0.01 Evening primrose oil 0.2 0.5 jojoba oil 1.0 0.2 0.1 orizanol 0025 00:05 00:01 00:25 00:03 Rice bran oil 5 0.5 0.2 1 0.75 water ad 100 ad 100 ad 100 ad 100 ad 100

Bath Care Formulations: The following substances were used:

Polyacrylat:

Carbopol ETD 2020, Noveon

Acrylates Copolymer:

Carbopol Aqua SF-1 Polymer, Noveon

Natriumlaurethsulfat:

Hier wurde Texapon N 70 von der Firma Cognis verwendet.
Gleiche Ergebnisse werden auch mit den Rohstoffen Genapol LRO Paste von Clariant und Emal 270 D/B von Kao erzielt.

Cocamidopropylbetain:

Tego-Betain F 50, Goldschmidt

Natrium Myristylethsulfat:

Texapon K 14 Spezial 70%, Cognis

Alkylpolyglucosid:

Hier kam Plantacare 2000 UP der Firma Cognis zum Einsatz. Ähnliche Ergebnisse werden auch mit Plantacare 1200 UP ebenfalls von Cognis erreicht.

Natriumcocoylglutamat:

Plantapon ACG-35, Cognis

Natrium Cocoamphoacetat:

Rewoteric AM C, Goldschmidt Rewo

PEG-7 Glyceryl Cocoate

Tegosoft GC von Goldschmidt kommt hier zum Einsatz. Auch Cetiol HE von Cognis und Glycerox HE B von Croda können eingesetzt werden.

PEG-40 hydriertes Ricinusöl:Emulgin HRE, Cognis
PEG-200 hydriertes Glycerylpalmitat: Rewoderm LI 520-70, Goldschmidt Rewo
PEG-90 Glyceryl Isostearat: Oxetal VD 92, Zschimmer&Schwarz

polyacrylate:

Carbopol ETD 2020, Noveon

Acrylates copolymer:

Carbopol Aqua SF-1 polymer, Noveon

Sodium Laureth Sulfate:

Here, Texapon N 70 was used by Cognis.
The same results are achieved with the raw materials Genapol LRO Paste from Clariant and Emal 270 D / B from Kao.

cocamidopropyl:

Tego-Betain F 50, Goldschmidt

Sodium myristylethsulfate:

Texapon K 14 Special 70%, Cognis

Alkylpolyglucosid:

Plantacare 2000 UP from Cognis was used here. Similar results are also achieved with Plantacare 1200 UP also from Cognis.

sodium cocoyl:

Plantapon ACG-35, Cognis

Sodium cocoamphoacetate:

Rewoteric AM C, Goldschmidt Rewo

PEG-7 glyceryl cocoate

Tegosoft GC from Goldschmidt is used here. Cetiol HE from Cognis and Glycerox HE B from Croda can also be used.

PEG-40 hydrogenated castor oil: Emulgin HRE, Cognis
PEG-200 hydrogenated glyceryl palmitate: Rewoderm LI 520-70, Goldschmidt Rewo
PEG-90 Glyceryl Isostearate: Oxetal VD 92, Zschimmer & Schwarz

The contents given in the recipe are the active contents of the respective raw materials .

to shower

1 2 3 4 5 Sodium laureth sulfate 11.0 5.0 9.5 9.5 8.5 Sodium myrethsulfate 3.0 cocoamidopropyl 3.5 4.5 3.0 3.5 4.0 sodium cocoyl 1.5 1.5 2.5 2.5 Decyl glucosides 1.5 PEG-40 hydrogenated castor oil 0.5 0.5 0.5 0.5 0.5 PEG-7 glyceryl cocoate 2.0 2.3 2.0 1.5 glycerin 0.5 1.0 PEG-200 hydrogenated glyceryl palmitate 0.5 0.5 0.1 0.3 PEG-90 glyceryl isostearate 0.3 0.5 PEG-120 methyl glucose dioleate 0.2 Grapeseed oil 0.1 0.5 0.1 almond oil 0.1 0.25 Evening primrose oil 0.25 Rice bran oil 0.25 0.2 0.5 0.75 1.0 jojoba oil 0.2 0.25 Laureth-2 0.1 0.1 sodium chloride 1.0 1.0 2.0 1.0 1.0 Trisodium EDTA 0.2 0.2 0.2 Tetrasodium imminodisuccinate 0.8 Polyquaternium-10 0.2 0.2 Guar hydroxypropyl trimonium chlord 0.3 Benzophenone-4 0.1 0.1 Glycol distearate 0.6 glycerin 0.3 Laureth-4 0.3 Styrene / acrylate copolymer 1.0 1.0 Alcohol denate. 1.0 plant extracts 0.2 oryzanol 0.05 0.1 0.5 preservatives q.s. q.s. q.s. q.s. q.s. dyes q.s. q.s. q.s. q.s. q.s. citric acid q.s. q.s. q.s. q.s. q.s. Perfume q.s. q.s. q.s. q.s. q.s. water ad ad ad ad ad

Exfoliating products

Surfactant-containing emulsion:

6 7 8th 9 10 11 sodium laureth sulfate 11.0 6.0 - 8.0 - - cocamidopropyl - 3.5 - 2.0 2.0 4.0 Sodium myristylethsulfate - - 6.0 - 7.0 7.0 alkylpolyglucosides - 2.5 - - 2.0 - polyacrylate 0.5 0.4 0.5 0.6 0.3 0.4 PEG-7 glyceryl cocoate - - 1.0 1.0 - - paraffin oil 34.5 30.0 45,00 40.0 25.0 35.0 Grapeseed oil 8.4 12.0 - 5.0 15.0 10.0 almond oil - 1.0 - 1.0 - 1.0 Rice bran oil 2.5 0.5 0.1 0.25 0.3 5.0 jojoba oil - 0.5 1.0 - 1.0 - oryzanol 0.05 0.1 0.5 0.1 dimethicone 0.5 - 1.0 0.5 - - Stearin alcohol - - - 0.5 - - Lanolin alcohol 0.3 - - - - - dyes - 0.1 - - 0.1 - effect pigments 0.1 0.2 - - - rice bran 0.1 0.5 0.2 glycerin - 0.2 - 0.5 - - oryzanol 0.1 0.05 0.2 0.1 plant extracts 0.1 0.2 0.3 methylparaben 0.4 0.3 0.1 0.3 0.2 0.4 Ethylparaben 0.1 - 0.1 - 0.1 - Propylparaben 0.2 0.2 0.1 0.2 0.2 0.2 Butylparaben 0.1 - 0.1 - 0.1 - Isobutylparaben 0.1 - 0.1 - 0.1 - polyethylene 0.2 2.0 5.0 phenoxyethanol 0.6 0.6 0.5 0.6 0.5 0.6 Butylhydroxyethanol 0.1 0.1 0.1 0.1 0.1 - NaOH q.s. q.s. q.s. q.s. q.s. q.s. Perfume 1.2 0.8 1.5 1.0 1.2 1.0 water ad 100 ad 100 ad 100 ad 100 ad 100 ad 100

The ground soap noodles are dosed with the color slurry and the other components in a conventional soap mixer (screw mixer with perforated screen), homogenized by repeated mixing, discharged via an extruder, cut and processed in the usual way to pieces.

Claims (14)

Cosmetic preparation containing rice germ oil. Preparation according to claim 1, characterized in that the content of rice germ oil from 0.05 to 6 wt.%, Preferably 0.2 to 5 wt.%, Particularly preferably 0.5 to 2 wt.% Is. Preparation according to one of the preceding claims, characterized in that additionally an oxidation-sensitive substance is contained. Preparation according to one of the preceding claims, characterized in that the oxidation-sensitive substance is present in concentrations of at least 0.1% by weight, preferably 0.5% by weight, particularly preferably 1% by weight, very particularly preferably 5% by weight. Preparation according to one of the preceding claims, characterized in that the oxidation-sensitive substance has an iodine value of at least 80. Preparation according to one of the preceding claims, characterized in that the oxidation-sensitive substance contains an oxidizable vegetable oil or a plant extract, particularly preferably extracts of the plant families of Nymphaeaceae, Nelumbonaceae, Fabaceae and / or Leguminosae. Preparation according to one of the preceding claims, characterized in that it contains at least 1 wt.%, Preferably more than 2 wt.% Surfactant, preferably with an HLB value between 3.8 to 8 or greater than 10, more preferably between 5 and 7 or greater 12 contains. Preparation according to one of the preceding claims, characterized in that the surface-active substance from the group of ethoxylated fatty alcohol derivatives with a C chain length greater than 10 and a mean degree of ethoxylation between 2 and 75, preferably between 2 and 39, more preferably between 2 and 5 is selected. Preparation according to one of the preceding claims, characterized in that they are surface-active substances anionic surfactants, particularly preferably alkyl and / or alkyl ether in proportions of 2-25 wt.%, Preferably 3-20 wt.% And particularly preferably 7.5-15 % By weight. A preparation according to claims 7 to 9, characterized in that it contains further anionic, amphoteric or nonionic surfactants of 1-15% by weight, preferably 3-10% by weight and more preferably 4-7% by weight. Preparation according to one of the preceding claims, characterized in that they (a) 1 to 25% by weight of one or more alkyl and / or alkyl ether sulfates, (b) 0.1-20% by weight of N-acylglutamate, (c) wherein the content of free fatty acids in the preparations is less than 3% by weight, preferably less than 2% by weight, more preferably up to 1% by weight, but in all cases at least 0.2% by weight, contains. Preparation according to one of the preceding claims, characterized in that it has a lipid content of at least 5 wt.%, Preferably at least 10 wt.%, Particularly preferably at least 15 wt.% Has. Preparation according to one of the preceding claims, characterized in that it additionally contains more than 0.007 wt.% Oryzanol, preferably more than 0.01 wt.% Oryzanol. Use of preparations according to one of the preceding claims for personal care and / or body cleansing.