EP1700903B1 - Procédé d'elimination des tâches de corrosion à cause des produits alimentaires acides ou des produits similaires des surfaces de marbre - Google Patents

Procédé d'elimination des tâches de corrosion à cause des produits alimentaires acides ou des produits similaires des surfaces de marbre Download PDF

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Publication number
EP1700903B1
EP1700903B1 EP05425308A EP05425308A EP1700903B1 EP 1700903 B1 EP1700903 B1 EP 1700903B1 EP 05425308 A EP05425308 A EP 05425308A EP 05425308 A EP05425308 A EP 05425308A EP 1700903 B1 EP1700903 B1 EP 1700903B1
Authority
EP
European Patent Office
Prior art keywords
marble
mixture
polishing
buffer
onto
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Not-in-force
Application number
EP05425308A
Other languages
German (de)
English (en)
Other versions
EP1700903A1 (fr
Inventor
Massimo Piraccini
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
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Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to AT05425308T priority Critical patent/ATE423187T1/de
Priority to EP05425308A priority patent/EP1700903B1/fr
Priority to DE602005012793T priority patent/DE602005012793D1/de
Publication of EP1700903A1 publication Critical patent/EP1700903A1/fr
Application granted granted Critical
Publication of EP1700903B1 publication Critical patent/EP1700903B1/fr
Not-in-force legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/14Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/049Cleaning or scouring pads; Wipes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/06Powder; Flakes; Free-flowing mixtures; Sheets
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/001Softening compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/26Organic compounds containing oxygen
    • C11D7/265Carboxylic acids or salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces
    • C11D2111/24Mineral surfaces, e.g. stones, frescoes, plasters, walls or concretes
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/40Specific cleaning or washing processes
    • C11D2111/44Multi-step processes

Definitions

  • the invention refers to a method to eliminate the stains onto the marble surfaces, generally level, without shift said surfaces. This avoids the use of a smoothing mill that, to eliminate the stain, works as far as the no eaten into layer with the actuation of a subsequent buffing.
  • the stains that form onto the marble surfaces for different causes are eliminated only actuating the removal of the plane and its transport in a worker in marble workshop.
  • the stain or the stains are eliminated using specific machinery having the characteristic to eliminate all the marble superficial layer, also the no stained parts, and then a buffing is actuated.
  • surfaces not mobile like floors or stairs, or surfaces not easy to be dismounted machines to be transported are used that actuate the same working of the machines present in the workshops.
  • Aim of the present invention is to create a method to eliminate the stains onto the marble surface without the necessity to remove the marble plane of the interested surface, without the use of specific machinery and with workings to be actuated to persons not skilled in this field. It is known that the stains formation is frequently due to the acid substances or similar absorption. Infact, also only for having placed an ash-try with dirty under border, for example dirty of fruitjuice or any other acid substance, onto a marble plane , the absorption generated the stain. Also the presence of acid substances onto a floor, onto a wall or onto stairs, if not immediately cleaned, generate stains to be eliminated only with particular workings.
  • FIG. 1 is perspective view of a component used in the invented method.
  • Figure 2 is transversal section view of a buffer to be used with the mixture to be used for giving again to the marble the original polishing.
  • the invented method uses a polishing buffer 1 with under abrasive sheets 2, or part with abrasive dust, and a second spongy buffer 3.
  • a mixture 4 consists of oxalic acid in grain 5 of a diameter from four millimetres to eight millimetres and, in the same quantity, to this mixture is added other milled oxalic acid 6 having a dimension smaller of the grains 5 but not in dust.
  • This second milled oxalic acid 6 has so the dimension of coarse sand.
  • This mixture that to treat a corrosion stain left to something with a dimension of a glass bottom, is composed of about ten grams of oxalic acid in grain, of about ten grams of milled oxalic acid and of about five grams of polishing dust, is the fundamental element to bring the marble to the original conditions.
  • the working method provides a first cleaning phase of the surface 8 to treat, using a neuter deterging distributed with a spray, with subsequent rinsing with water by means of sponge and with drying actuated with a felt cloth. After about a hour, with the marble surface dry so that the stain of acid substance is visible, the abrasive polishing buffer 1 is used.
  • the stain to be eliminated is wet with a little quantity of water and so to form a water thin layer covering the same stain.
  • the abrasive polishing buffer 1 is used making rotating movements onto the surface to be treated for about one minute.
  • the water is coloured of the marble colour to confirm the reactions of the material to the proceeding.
  • the marble surface is cleaned with a dry cloth. In this phase the treated marble surface must be opaque and uniform, with the sign of the stain.
  • the surface must be wet again with a thin layer water and must be used again the abrasive polishing buffer 1 with the modes previous described.
  • the mixture 4 adding a water drop.
  • the marble surface is cleaned with a dry cloth, with the corrosion stain not more present.
  • the mixture 4 is used again the mixture 4 by means of the spongy buffer 3 with the same modes and so till the complete elimination of the opaque parts.
  • a marble polish without frustrate the invented polishing method. The described method so eliminates the stains onto all kinds of marbles with results equal to the particular known workings.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Finish Polishing, Edge Sharpening, And Grinding By Specific Grinding Devices (AREA)

Claims (4)

  1. Procédé d'élimination des tâches de corrosion à cause de produits alimentaires acides ou des produits alimentaires acides out des produits similaires des surfaces de marbre qui prévoit l'élimination des tâches sans devoir déplacer les surfaces et sans employer des outillages spécifiques pour polir et cirer dites surfaces, caractérisée par le fait qu'on va employer un bourrelet abrasif à même de polir (1) doué de feuilles abrasifs au dessous (2) et un deuxième bourrelet spongieux (3) qui contient un mélange (4) composé par acide oxalique en grains (5) dont le diamètre est de quatre a huit millimètres et, en la même quantité on va employer d'autre acide oxalique haché (6) dont la dimension est plus petite que les grains (5) mais ce n'est pas de poudre, et que à dit mélange on va ajouter en une quantité correspondant a la moitié d'un de deux composantes employés, une poudre à même de polir les surfaces telles que le marbre (7), et que tout en mélangeant les composantes.
  2. Procédé d'élimination des tâches de corrosion à cause de produits alimentaires acides ou des produits alimentaires acides out des produits similaires des surfaces de marbre, selon la revendication 1, caractérisée par le fait que dit procédé envisage d'abord une phase initiale de nettoyage de la surface (8) à traiter, en utilisant un détergent neutre distribué grâce a vaporisateur, suivi per un rinçage d'eau à l'aide d'une éponge et séchage obtenu par l'emploi d'un drap de feutre; et que, après une demi-heure environ, le bourrelet abrasif (1) est employé en faisant des mouvements circulaires et en exercant une pression sur la tâche du marbre imbibée d'une petite quantité d'eau; et que après avoir nettoyé la surface du marbre avec un tissue sec obtenant ainsi une surface opaque et uniforme sans tâches, sur la zone opaque on va placer le bourrelet abrasif spongieux (3) tout en unissant le mélange (4) et en ajoutant une goutte d'eau, et que on procedéra a frotter de manière énergique grâce à des mouvements circulaires de presque deux minutes et que, une fois accomplie cette procedure on passera un drap sec tout en obtenant une surface parfaitement polie et sans tâches.
  3. Procédé d'élimination des tâches de corrosion à cause de produits alimentaires acides ou des produits alimentaires acides out des produits similaires des surfaces de marbre, selon la revendication 2, caractérisée par le fait, au cas où la tâche subsiste encore il est toutefois possible de polir en ajoutant le mélange (4) sur les zones opaques à l'aide du bourrelet spongieux (3) et en répetant l'operation.
  4. Procédé d'élimination des tâches de corrosion à cause de produits alimentaires acides ou des produits alimentaires acides out des produits similaires des surfaces de marbre, selon la revendication 1, caractérisée par le fait que, on peut polir la surface à l'aide d'un bourrelet spongieux imbibé d'un mélange (4) fait de acide oxalique en grains (5) ayant un diamètre de quatre à huit millimetres et, en la même quantité, de acide oxalique haché mais pas en poudre (6) et d'une poudre à même de polir la marbre (7) dans une quantité correspondant à la moitié d'un de deux composantes déjà employés et tout en employant le mélange.
EP05425308A 2005-03-06 2005-03-06 Procédé d'elimination des tâches de corrosion à cause des produits alimentaires acides ou des produits similaires des surfaces de marbre Not-in-force EP1700903B1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
AT05425308T ATE423187T1 (de) 2005-03-06 2005-03-06 Verfahren zum entfernen von flecken verursacht durch korrosion durch säurehaltige lebensmittel von marmoroberflächen
EP05425308A EP1700903B1 (fr) 2005-03-06 2005-03-06 Procédé d'elimination des tâches de corrosion à cause des produits alimentaires acides ou des produits similaires des surfaces de marbre
DE602005012793T DE602005012793D1 (de) 2005-03-06 2005-03-06 Verfahren zum Entfernen von Flecken verursacht durch Korrosion durch säurehaltige Lebensmittel von Marmoroberflächen

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP05425308A EP1700903B1 (fr) 2005-03-06 2005-03-06 Procédé d'elimination des tâches de corrosion à cause des produits alimentaires acides ou des produits similaires des surfaces de marbre

Publications (2)

Publication Number Publication Date
EP1700903A1 EP1700903A1 (fr) 2006-09-13
EP1700903B1 true EP1700903B1 (fr) 2009-02-18

Family

ID=34943190

Family Applications (1)

Application Number Title Priority Date Filing Date
EP05425308A Not-in-force EP1700903B1 (fr) 2005-03-06 2005-03-06 Procédé d'elimination des tâches de corrosion à cause des produits alimentaires acides ou des produits similaires des surfaces de marbre

Country Status (3)

Country Link
EP (1) EP1700903B1 (fr)
AT (1) ATE423187T1 (fr)
DE (1) DE602005012793D1 (fr)

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US145971A (en) * 1873-12-30 Improvement in processes for cleaning marble, granite
US370551A (en) * 1887-09-27 Process of cleaning the surfaces of stone
US5490883A (en) * 1994-06-16 1996-02-13 The Servicemaster Company, L.P. Solution and method for cleaning marble surfaces
US6251808B1 (en) * 1997-10-22 2001-06-26 Illinois Tool Works, Inc. Metal and fiberglass cleaning and polishing article
US5962001A (en) * 1997-11-03 1999-10-05 Illinois Tool Works, Inc. Disinfecting and sanitizing article

Also Published As

Publication number Publication date
ATE423187T1 (de) 2009-03-15
EP1700903A1 (fr) 2006-09-13
DE602005012793D1 (de) 2009-04-02

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