EP1700903B1 - Method for eliminating corrosion stains caused by acid foodstuffs from marble surfaces - Google Patents
Method for eliminating corrosion stains caused by acid foodstuffs from marble surfaces Download PDFInfo
- Publication number
- EP1700903B1 EP1700903B1 EP05425308A EP05425308A EP1700903B1 EP 1700903 B1 EP1700903 B1 EP 1700903B1 EP 05425308 A EP05425308 A EP 05425308A EP 05425308 A EP05425308 A EP 05425308A EP 1700903 B1 EP1700903 B1 EP 1700903B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- marble
- mixture
- polishing
- buffer
- onto
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Not-in-force
Links
- 239000004579 marble Substances 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract description 17
- 239000002253 acid Substances 0.000 title claims description 9
- 230000007797 corrosion Effects 0.000 title claims description 7
- 238000005260 corrosion Methods 0.000 title claims description 7
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims abstract description 39
- 238000005498 polishing Methods 0.000 claims abstract description 18
- 239000000203 mixture Substances 0.000 claims abstract description 16
- 235000006408 oxalic acid Nutrition 0.000 claims abstract description 12
- 239000000428 dust Substances 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000004744 fabric Substances 0.000 claims description 6
- 238000004140 cleaning Methods 0.000 claims description 3
- 238000001035 drying Methods 0.000 claims description 2
- 238000009499 grossing Methods 0.000 claims description 2
- 239000007921 spray Substances 0.000 claims description 2
- 239000000126 substance Substances 0.000 description 4
- 230000003245 working effect Effects 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000008030 elimination Effects 0.000 description 2
- 238000003379 elimination reaction Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 235000015203 fruit juice Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/14—Fillers; Abrasives ; Abrasive compositions; Suspending or absorbing agents not provided for in one single group of C11D3/12; Specific features concerning abrasives, e.g. granulometry or mixtures
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/049—Cleaning or scouring pads; Wipes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
-
- C11D2111/24—
-
- C11D2111/44—
Definitions
- the invention refers to a method to eliminate the stains onto the marble surfaces, generally level, without shift said surfaces. This avoids the use of a smoothing mill that, to eliminate the stain, works as far as the no eaten into layer with the actuation of a subsequent buffing.
- the stains that form onto the marble surfaces for different causes are eliminated only actuating the removal of the plane and its transport in a worker in marble workshop.
- the stain or the stains are eliminated using specific machinery having the characteristic to eliminate all the marble superficial layer, also the no stained parts, and then a buffing is actuated.
- surfaces not mobile like floors or stairs, or surfaces not easy to be dismounted machines to be transported are used that actuate the same working of the machines present in the workshops.
- Aim of the present invention is to create a method to eliminate the stains onto the marble surface without the necessity to remove the marble plane of the interested surface, without the use of specific machinery and with workings to be actuated to persons not skilled in this field. It is known that the stains formation is frequently due to the acid substances or similar absorption. Infact, also only for having placed an ash-try with dirty under border, for example dirty of fruitjuice or any other acid substance, onto a marble plane , the absorption generated the stain. Also the presence of acid substances onto a floor, onto a wall or onto stairs, if not immediately cleaned, generate stains to be eliminated only with particular workings.
- FIG. 1 is perspective view of a component used in the invented method.
- Figure 2 is transversal section view of a buffer to be used with the mixture to be used for giving again to the marble the original polishing.
- the invented method uses a polishing buffer 1 with under abrasive sheets 2, or part with abrasive dust, and a second spongy buffer 3.
- a mixture 4 consists of oxalic acid in grain 5 of a diameter from four millimetres to eight millimetres and, in the same quantity, to this mixture is added other milled oxalic acid 6 having a dimension smaller of the grains 5 but not in dust.
- This second milled oxalic acid 6 has so the dimension of coarse sand.
- This mixture that to treat a corrosion stain left to something with a dimension of a glass bottom, is composed of about ten grams of oxalic acid in grain, of about ten grams of milled oxalic acid and of about five grams of polishing dust, is the fundamental element to bring the marble to the original conditions.
- the working method provides a first cleaning phase of the surface 8 to treat, using a neuter deterging distributed with a spray, with subsequent rinsing with water by means of sponge and with drying actuated with a felt cloth. After about a hour, with the marble surface dry so that the stain of acid substance is visible, the abrasive polishing buffer 1 is used.
- the stain to be eliminated is wet with a little quantity of water and so to form a water thin layer covering the same stain.
- the abrasive polishing buffer 1 is used making rotating movements onto the surface to be treated for about one minute.
- the water is coloured of the marble colour to confirm the reactions of the material to the proceeding.
- the marble surface is cleaned with a dry cloth. In this phase the treated marble surface must be opaque and uniform, with the sign of the stain.
- the surface must be wet again with a thin layer water and must be used again the abrasive polishing buffer 1 with the modes previous described.
- the mixture 4 adding a water drop.
- the marble surface is cleaned with a dry cloth, with the corrosion stain not more present.
- the mixture 4 is used again the mixture 4 by means of the spongy buffer 3 with the same modes and so till the complete elimination of the opaque parts.
- a marble polish without frustrate the invented polishing method. The described method so eliminates the stains onto all kinds of marbles with results equal to the particular known workings.
Abstract
Description
- The invention refers to a method to eliminate the stains onto the marble surfaces, generally level, without shift said surfaces. This avoids the use of a smoothing mill that, to eliminate the stain, works as far as the no eaten into layer with the actuation of a subsequent buffing. Currently, infact, the stains that form onto the marble surfaces for different causes are eliminated only actuating the removal of the plane and its transport in a worker in marble workshop. In this seat the stain or the stains are eliminated using specific machinery having the characteristic to eliminate all the marble superficial layer, also the no stained parts, and then a buffing is actuated. For surfaces not mobile, like floors or stairs, or surfaces not easy to be dismounted machines to be transported are used that actuate the same working of the machines present in the workshops. But these machines need skilled workers for their use and also voltages generally not present in the house electric connection. Aim of the present invention is to create a method to eliminate the stains onto the marble surface without the necessity to remove the marble plane of the interested surface, without the use of specific machinery and with workings to be actuated to persons not skilled in this field. It is known that the stains formation is frequently due to the acid substances or similar absorption. Infact, also only for having placed an ash-try with dirty under border, for example dirty of fruitjuice or any other acid substance, onto a marble plane , the absorption generated the stain. Also the presence of acid substances onto a floor, onto a wall or onto stairs, if not immediately cleaned, generate stains to be eliminated only with particular workings. In this situation the aesthetic damage on these surfaces remains till the total buffing of the same surface is actuated with high costs that justify said working only in the case of more stains or when the stains and the wear and tear suggested the total sanding with abrasive and the subsequent buffing.
US 145971 ,US 370551 andUS 5 490 883 all describe a method for cleaning a marble surface by applying an aqueous solution comprising oxalic acid. The invented method permits, instead, to actuate the immediate elimination of the formed stain onto the marble and the reinstatement of the original lucid layer. The advantages coming from the invented method so essentially consist in the fact to eliminate the stain quickly and to not must use particular machinery and skilled persons with the relative costs, this with a final result equal to the one obtained with the workings known in the prior art and without removing the stained surface. The invented method is following described in the particulars and in the drawings of table 1 which show a working example.Figure 1 is perspective view of a component used in the invented method.Figure 2 is transversal section view of a buffer to be used with the mixture to be used for giving again to the marble the original polishing. The invented method uses a polishing buffer 1 with under abrasive sheets 2, or part with abrasive dust, and asecond spongy buffer 3. Onto saidspongy buffer 3 is placed amixture 4 consists of oxalic acid ingrain 5 of a diameter from four millimetres to eight millimetres and, in the same quantity, to this mixture is added other milledoxalic acid 6 having a dimension smaller of thegrains 5 but not in dust. This second milledoxalic acid 6 has so the dimension of coarse sand. To all this mixture at the end is added, in quantity like the middle of one of the two components already used, amarble polishing dust 7, known in the art with commercial name "potè polishing dust". This mixture, that to treat a corrosion stain left to something with a dimension of a glass bottom, is composed of about ten grams of oxalic acid in grain, of about ten grams of milled oxalic acid and of about five grams of polishing dust, is the fundamental element to bring the marble to the original conditions. The working method provides a first cleaning phase of thesurface 8 to treat, using a neuter deterging distributed with a spray, with subsequent rinsing with water by means of sponge and with drying actuated with a felt cloth. After about a hour, with the marble surface dry so that the stain of acid substance is visible, the abrasive polishing buffer 1 is used. The stain to be eliminated is wet with a little quantity of water and so to form a water thin layer covering the same stain. Indicatively for a stain left to a glass about twenty-five grams of water are used, the abrasive polishing buffer 1 is used making rotating movements onto the surface to be treated for about one minute. During the action of the buffer onto the stain the water is coloured of the marble colour to confirm the reactions of the material to the proceeding. After about a minute the marble surface is cleaned with a dry cloth. In this phase the treated marble surface must be opaque and uniform, with the sign of the stain. In the case that the stain or part of the same are still present, the surface must be wet again with a thin layer water and must be used again the abrasive polishing buffer 1 with the modes previous described. Onto the opaque stain formed onto the treated marble is then placed, by means of thespongy buffer 3, themixture 4 adding a water drop. Then are actuated, with strong wiping, circular movements onto the opaque part for about two minutes. At the end of this working the marble surface is cleaned with a dry cloth, with the corrosion stain not more present. In the case that opaque parts still are present, is used again themixture 4 by means of thespongy buffer 3 with the same modes and so till the complete elimination of the opaque parts. To have a marble surface with bigger lucidity is then used a marble polish without frustrate the invented polishing method. The described method so eliminates the stains onto all kinds of marbles with results equal to the particular known workings.
Claims (4)
- Method to eliminate localized stains from corrosion due to acid foodstuffs or similar onto marble surfaces, providing to eliminate the stains without the necessity to remove said surfaces and without using particular machines for smoothing and polishing said surfaces, characterized in the fact to use a polishing buffer (1) with under abrasive sheets (2) and a second spongy buffer (3) having a mixture (4) consists of oxalic acid in grain (5) of a diameter from four millimetres to eight millimetres and, in the same quantity, to have added other milled oxalic acid (6) having a dimension smaller of the grains (5) but not in dust, and that to this mixture is added, in quantity like the middle of one of the two components already used, a marble polishing dust (7), and that the components of the mixture are mixing.
- Method to eliminate localized stains from corrosion due to acid foodstuffs or similar onto marble surfaces, as per claim 1, characterized in that it provides a first cleaning phase of the surface (8) to treat, using a neuter deterging distributed with a spray, with subsequent rinsing with water by means of sponge and with drying actuated with a felt cloth; and that, after about a hour, the abrasive polishing buffer (1) is used making rotating movements and pressure onto the marble stain wet with a little quantity of water; and that after to have cleaned the marble surface with a dry cloth having an opaque and uniform surface without stain, onto the opaque part is placed the spongy buffer (3) with the mixture (4) adding a water drop; and that strong wiping with circular movements are actuated for about two minutes and at the end a dry cloth is passed so having a surface without stain and polished.
- Method to eliminate localized stains from corrosion due to acid foodstuffs or similar onto marble surfaces, as per claim 2, characterized in that in the case that the stain is still present the polishing is actuated again adding the mixture (4) onto the opaque parts by the spongy buffer (3) and repeating the work.
- Method to eliminate localized stains from corrosion due to acid foodstuffs or similar onto marble surfaces, as per claim 1, characterized in that the polishing is actuated with a spongy buffer having a mixture (4) consists of oxalic acid in grain (5) of a diameter from four millimetres to eight millimetres and, in the same quantity, to milled oxalic acid (6) not in dust and to marble polishing dust (7) in quantity like the middle of one of the two components already used and that said mixture is mixed.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE602005012793T DE602005012793D1 (en) | 2005-03-06 | 2005-03-06 | Process for removing stains caused by corrosion by acidic foods of marble surfaces |
AT05425308T ATE423187T1 (en) | 2005-03-06 | 2005-03-06 | METHOD FOR REMOVAL STAINS CAUSED BY CORROSION BY ACIDIC FOODS FROM MARBLE SURFACES |
EP05425308A EP1700903B1 (en) | 2005-03-06 | 2005-03-06 | Method for eliminating corrosion stains caused by acid foodstuffs from marble surfaces |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05425308A EP1700903B1 (en) | 2005-03-06 | 2005-03-06 | Method for eliminating corrosion stains caused by acid foodstuffs from marble surfaces |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1700903A1 EP1700903A1 (en) | 2006-09-13 |
EP1700903B1 true EP1700903B1 (en) | 2009-02-18 |
Family
ID=34943190
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP05425308A Not-in-force EP1700903B1 (en) | 2005-03-06 | 2005-03-06 | Method for eliminating corrosion stains caused by acid foodstuffs from marble surfaces |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP1700903B1 (en) |
AT (1) | ATE423187T1 (en) |
DE (1) | DE602005012793D1 (en) |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US145971A (en) * | 1873-12-30 | Improvement in processes for cleaning marble, granite | ||
US370551A (en) * | 1887-09-27 | Process of cleaning the surfaces of stone | ||
US5490883A (en) * | 1994-06-16 | 1996-02-13 | The Servicemaster Company, L.P. | Solution and method for cleaning marble surfaces |
US6251808B1 (en) * | 1997-10-22 | 2001-06-26 | Illinois Tool Works, Inc. | Metal and fiberglass cleaning and polishing article |
US5962001A (en) * | 1997-11-03 | 1999-10-05 | Illinois Tool Works, Inc. | Disinfecting and sanitizing article |
-
2005
- 2005-03-06 DE DE602005012793T patent/DE602005012793D1/en not_active Expired - Fee Related
- 2005-03-06 EP EP05425308A patent/EP1700903B1/en not_active Not-in-force
- 2005-03-06 AT AT05425308T patent/ATE423187T1/en not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
ATE423187T1 (en) | 2009-03-15 |
EP1700903A1 (en) | 2006-09-13 |
DE602005012793D1 (en) | 2009-04-02 |
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