EP1682288B1 - Method and device for applying an adjustable tensile-stress distribution, in particular in the edge regions of cold-rolled metal strips - Google Patents

Method and device for applying an adjustable tensile-stress distribution, in particular in the edge regions of cold-rolled metal strips Download PDF

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Publication number
EP1682288B1
EP1682288B1 EP04764552A EP04764552A EP1682288B1 EP 1682288 B1 EP1682288 B1 EP 1682288B1 EP 04764552 A EP04764552 A EP 04764552A EP 04764552 A EP04764552 A EP 04764552A EP 1682288 B1 EP1682288 B1 EP 1682288B1
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EP
European Patent Office
Prior art keywords
strip
edge
edges
rolling
tensile stress
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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EP04764552A
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German (de)
French (fr)
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EP1682288A2 (en
Inventor
Hans-Peter Richter
Hartmut Pawelski
Ludwig Weingarten
Thorsten Bode
Jürgen Klöckner
Ralf Ohrndorf
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SMS Siemag AG
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SMS Siemag AG
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B37/00Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
    • B21B37/28Control of flatness or profile during rolling of strip, sheets or plates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B37/00Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
    • B21B37/28Control of flatness or profile during rolling of strip, sheets or plates
    • B21B37/30Control of flatness or profile during rolling of strip, sheets or plates using roll camber control
    • B21B37/32Control of flatness or profile during rolling of strip, sheets or plates using roll camber control by cooling, heating or lubricating the rolls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B45/00Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
    • B21B45/02Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for lubricating, cooling, or cleaning
    • B21B45/0203Cooling
    • B21B45/0209Cooling devices, e.g. using gaseous coolants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B45/00Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
    • B21B45/02Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for lubricating, cooling, or cleaning
    • B21B45/0269Cleaning
    • B21B45/0275Cleaning devices
    • B21B45/0278Cleaning devices removing liquids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/40Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling foils which present special problems, e.g. because of thinness
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B13/00Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories
    • B21B13/14Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories having counter-pressure devices acting on rolls to inhibit deflection of same under load; Back-up rolls
    • B21B13/142Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories having counter-pressure devices acting on rolls to inhibit deflection of same under load; Back-up rolls by axially shifting the rolls, e.g. rolls with tapered ends or with a curved contour for continuously-variable crown CVC
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B27/00Rolls, roll alloys or roll fabrication; Lubricating, cooling or heating rolls while in use
    • B21B27/06Lubricating, cooling or heating rolls
    • B21B27/10Lubricating, cooling or heating rolls externally
    • B21B2027/103Lubricating, cooling or heating rolls externally cooling externally
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B27/00Rolls, roll alloys or roll fabrication; Lubricating, cooling or heating rolls while in use
    • B21B27/02Shape or construction of rolls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B27/00Rolls, roll alloys or roll fabrication; Lubricating, cooling or heating rolls while in use
    • B21B27/06Lubricating, cooling or heating rolls
    • B21B27/10Lubricating, cooling or heating rolls externally
    • B21B27/106Heating the rolls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B37/00Control devices or methods specially adapted for metal-rolling mills or the work produced thereby
    • B21B37/28Control of flatness or profile during rolling of strip, sheets or plates
    • B21B37/44Control of flatness or profile during rolling of strip, sheets or plates using heating, lubricating or water-spray cooling of the product
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B39/00Arrangements for moving, supporting, or positioning work, or controlling its movement, combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
    • B21B39/02Feeding or supporting work; Braking or tensioning arrangements, e.g. threading arrangements
    • B21B39/08Braking or tensioning arrangements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B45/00Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
    • B21B45/02Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for lubricating, cooling, or cleaning
    • B21B45/0239Lubricating
    • B21B45/0245Lubricating devices
    • B21B45/0248Lubricating devices using liquid lubricants, e.g. for sections, for tubes
    • B21B45/0251Lubricating devices using liquid lubricants, e.g. for sections, for tubes for strips, sheets, or plates

Definitions

  • the invention relates to a method for applying a controllable tensile stress distribution, especially in the edge regions during cold rolling of metal strips, in order to reduce the risk of too high tensile structure and band edge cracks with the adverse consequence of production-reducing band breaks, and to improve the strip surface and its flatness even at relatively higher Tape speed and to reduce Bandbeklan, according to the preamble of claim 1 (see, eg JP-A-62142011 ).
  • the invention also relates to an apparatus for carrying out the method, according to the preamble of claim 5.
  • Process is collected before the nip and separated again. This makes it possible to produce the emulsion or dispersion, which is introduced into the nip, time and again with a certain concentration before moving into the nip.
  • the focus of this invention is the actual production of the emulsion and the separation of the involved media.
  • the document EP 1 188 494 A1 describes a belt scraper, belt scraper method, rolling mill and rolling method. To improve the productivity of a cold rolling device, this was provided with a belt scraper.
  • the document EP 0 672 471 B1 discloses a method and apparatus for rolling ribbons.
  • rollers wear-resistant at least in one of its end regions with enlarged radii running rollers are shifted from each other so that the rolled strip in its width in each case with areas of smaller radius in contact, and that with increasing heating and with thermal crowning by opposing displacement of the rollers Regions of their larger radius are pushed over edge regions of the rolled strip.
  • edge area elevations of the strip which would occur due to the rising thermal crowning, are eliminated.
  • the document DE 199 08 743 A1 discloses a method and an apparatus for drying and keeping dry, in particular cold strip in the outlet area of cold rolling and strip lines.
  • drying and keeping dry particular of rolled strips it is known by a partitioning the dry area of the finished rolled strip from the wet room of Separate rolling stand.
  • a non-contact seal between the foreclosure and the tape by an air cushion-like compressed gas cushion and a slit flow is proposed so as to apply compressed gas from a plurality of nozzles from Blasdüsenangn at right angles from above and below the tape surfaces. This measure prevents penetration of rolling oil or even emulsion at high belt speeds of over 1000 m / min, irrespective of the bandwidth, and achieves non-contact belt drying.
  • the document DE 101 31 369 A1 discloses a method and apparatus for cooling and / or lubricating rolls, in particular the work rolls of a rolling stand and a rolled strip conveyed between and conveyed through these rolls, using water in the form of sprays as cooling medium and spray oil, oil-air mixture or oil -Water mixture, as a lubricant.
  • a combined use of supercooling of the belt and roll surface and the roll lubrication on the scaffold inlet side is proposed by the two media - water or lubricant - the rolls or the strip fed separately and to different application sites of the rolling surface be applied.
  • the European patent EP 0 672 471 B1 discloses a method and apparatus for rolling belts with axially displaceable rollers.
  • the method is characterized in that low-wear, executed with at least at one of its end portions with enlarged radii rollers are shifted against each other such that the rolled strip is in its width in each case with areas of smaller radius in contact and that with increasing heating and with thermal crowning By oppositely moving the rollers and areas of the rollers with a larger radius are pushed over edge regions of the rolled strip.
  • This method is used to counteract the annoying, thermal crowning effect simply and inexpensively, in order to make rolling plans more free.
  • the U.S. Patent 5,943,896 discloses a method for influencing the contour of a rolled strip in the edge region.
  • each work roll has a smaller diameter portion at one end than at the other end thereof, the smaller end portion being shorter than the large diameter portion across the width of the work roll.
  • the diameter of the work roll linearly changes from the small diameter to the larger diameter.
  • the two superposed rollers are arranged so that the thinner end of the one roller is opposite to the thicker end of the other roller.
  • the Japanese godparent application JP 05050122 discloses an apparatus and method for realizing a sharply separated heat transfer between different temperature ranges on the surface of a work roll.
  • the Japanese application 03297507 discloses a method for detecting the occurrence of stresses in the edge regions of a rolled strip and an extension to prevent the edge areas. For this purpose, it is proposed to apply a cold coolant in the region of the center of the rolled strip, that is to say not in its edge regions, and at the same time to apply a warm coolant in the edge regions and outside thereof.
  • German patent application DE 31 144 87 A1 discloses a method and apparatus for roll tempering in cold rolling mills.
  • a roll area which lies outside the strip edge and adjoins directly to the strip edge be tempered by applying heated lubricant.
  • a relatively sharp borderline between hot and cold lubricant jet is set. The position of this boundary line should coincide with the position of the band edge.
  • the invention is in the cold rolling, especially in the aluminum industry, but occasionally in the steel and non-ferrous metal area, the task of further reducing the resulting during thin rolling strip edges and near-edge long strip fibers and tape cracks on To further save edgebandings and thereby further improve the quality and quantity of application.
  • This object is achieved by the method claimed in claim 1.
  • This method is characterized in that the strip edges are influenced by "hot edge spray", in particular by zonewise spraying of rolling oil at different temperatures, and in the Work rolls in the Beriech the band edges a special finish is used, which is suitable for partial buildup of material in the prestretch, the material structure in subsequent stitches leads to a longer band edge and counteracts the risk of high Gebupes.
  • An embodiment of the method according to claim 1 provides that an increased diameter decrease of the work rolls is made at the edge region due to partial increase in diameter during their shaping by means of inductive heating.
  • the strip tension distribution is changed by a concave bendable or curved guide roller such that the tape tension is reduced at the strip edges and increased in the center of the strip.
  • Another embodiment of the device advantageously includes a convexly bendable in the belt running direction or curved steering roller in an arrangement between two guide rollers for changing the tensile stress distribution of a strip before its entry into a rolling stand.
  • the device is further configured by the fact that they are on the inlet side of a rolling mill means for direct additive application, in particular on the rolled strip z. B. for lubricating oil with relatively high viscosity, and on the outlet side of the work rolls means for bale cooling of the work rolls and preferably additional lubricant removal means which spray the rolled strip with preference from both the tape top and from the underside of the band with the attributable spray media.
  • the device according to the invention has a device which removes coolant in the outlet side of the scaffold.
  • FIG. 1 shows a part of a device for applying a controllable tensile stress distribution, in particular in edge regions during cold rolling of metal strips, with in at least two separate zones 10, 10 'existing spray nozzle assemblies 11, 11' with connections to separate Sprühstoffzu exiten 19, 19 'to different zones 10, 10th
  • a partial inductive heating of the work roll in a conventional manner.
  • FIG. 2 shows a pair of work rolls 12, 12 ', each having in one end a special grinding 13, 13' with increases in diameter in the end regions for extending the strip edges to be rolled with simultaneous reduction of tensile stresses and reduction of long strip fibers.
  • FIG. 5 shows a side view of an inventive system, with a decoiler on the left side and a Aufrollhaspel on the right and guide means for the rolled strip 16 in the direction of belt 14 and means 21 for direct application of lubricant with viscosity or additive on the band inlet side and means 22 for bale cooling the outlet side work rolls and means 23 for the outlet side lubricant removal.
  • a material build-up at the strip edge during the pre-stitching and correspondingly a material removal at the strip edge during the finishing passes is achieved with the aid of an additive direct application in the inlet side and roll cooling in the outlet side.

Abstract

The invention relates to a method and a device for applying an adjustable tensile-stress distribution, in particular in the edge regions during the cold-rolling of metal strips ( 16 ), in particular metal foil, in order to reduce the risk of an excessive build-up of tension and cracks at the edges of the strip, which can lead as a negative consequence to cracks in the strip and to a reduction in production, and in order to improve the surface of the strip and its planarity, even for a relatively high strip displacement speed, and also to reduce strip trimming widths. To achieve these aims, at least one or a combination of two of the following measures are implemented: a) separation of lubrication and cooling of the working rolls by lubricating on the run-in side and cooling on the discharge side, b) additional influencing of the strip edges using a hot edge spray", in particular by spraying ( 21 ) rolling oil with differing temperatures in zones, c) use of a special cross-sectional configuration of the working rolls ( 12, 12 ') in the vicinity of the strip edges, which creates a partial material build-up during the blooming pass, said build-up forming a longer strip edge with subsequent passes, thus counteracting the risk of an excessive build-up of tensile stress.

Description

Die Erfindung betrifft ein Verfahren zum Aufbringen einer regelbaren Zugspannungsverteilung, insbesondere in den Kantenbereichen beim Kaltwalzen von Metallbändern, zwecks Verringerung der Gefahr eines zu hohen Zugaufbaus und Bandkantenrissen mit der nachteiligen Folge von produktionsmindernden Bandrissen, sowie zur Verbesserung der Bandoberfläche und ihrer Planheit auch bei relativ höherer Bandlaufgeschwindigkeit und zur Reduzierung von Bandbesäumbreiten, gemäß dem Oberbegriff des Anspruchs 1 (siehe z.B. JP-A-62142011 ). Die Erfindung betrifft auch eine Vorrichtung zur Durchführung des Verfahrens, gemäß dem Oberbegriff des Anspruchs 5.The invention relates to a method for applying a controllable tensile stress distribution, especially in the edge regions during cold rolling of metal strips, in order to reduce the risk of too high tensile structure and band edge cracks with the adverse consequence of production-reducing band breaks, and to improve the strip surface and its flatness even at relatively higher Tape speed and to reduce Bandbesäumbreiten, according to the preamble of claim 1 (see, eg JP-A-62142011 ). The invention also relates to an apparatus for carrying out the method, according to the preamble of claim 5.

Aus dem Dokument EP 0 054 172 A2 ist ein Verfahren bekannt, bei dem zum spannungsfreien Walzen von Kaltband der Reibwert zwischen den Bandoberflächen und den Walzenballen-Mantelflächen durch Beaufschlagung mit Walzschmiermittel beeinflusst wird. Diese wird dabei in Abhängigkeit von hinter dem letzten Gerüst in Querrichtung des Bandes liegenden Zonen ermittelten partiellen Zugspannungen zugeführt. Dabei wird Grundöl dem Walzschmiermittel vor dem Einlauf des Bandes in den Walzspalt in durch die ermittelten partiellen Zugspannungen bestimmten Mengen und in örtlich begrenzten Bereichen unmittelbar auf die Bandoberflächen aufgetragen. Ziel dieser Maßnahme ist es, die Schmierbestandteile lokal auf Streifen des zu walzenden Bandes aufzubringen, um durch die lokal verbesserte Schmierung die dortige Walzkraft zu senken und damit auch die lokale Abplattung der Walze zu verringern. Weiterhin wird die in die Walze eingebrachte Reibungswärme an diesen Stellen reduziert.From the document EP 0 054 172 A2 a method is known in which for the tension-free rolling of cold strip, the coefficient of friction between the strip surfaces and the roll barrel lateral surfaces is influenced by the application of rolling lubricant. This is supplied as a function of located behind the last framework in the transverse direction of the belt zones determined partial tensile stresses. Here, base oil is applied to the rolling lubricant before the inlet of the strip in the nip in determined by the determined partial tensile stresses and in localized areas directly on the belt surfaces. The aim of this measure is to locally apply the lubricating components on strips of the strip to be rolled in order to reduce the local rolling force by the locally improved lubrication and thus also to reduce the local flattening of the roller. Furthermore, the friction heat introduced into the roll is reduced at these points.

Aus dem Dokument EP 0 367 967 B1 ist ein Verfahren und eine Vorrichtung bekannt, bei der die Konzentration einer Emulsion aus Walzöl gezielt beeinflusst und die Emulsion bzw. Dispersion nach Austritt aus dem Walzspalt bzw.From the document EP 0 367 967 B1 a method and a device is known in which the concentration of an emulsion of rolling oil specifically influenced and the emulsion or dispersion after exiting the nip or

Ablauf vor dem Walzspalt aufgefangen und wieder getrennt wird. Hiermit wird es möglich, die Emulsion bzw. Dispersion, die in den Walzspalt eingebracht wird, immer wieder mit bestimmter Konzentration zeitgerecht vor Einzug in den Walzspalt herzustellen. Der Schwerpunkt dieser Erfindung liegt in der aktuellen Herstellung der Emulsion und der Trennung der beteiligten Medien.Process is collected before the nip and separated again. This makes it possible to produce the emulsion or dispersion, which is introduced into the nip, time and again with a certain concentration before moving into the nip. The focus of this invention is the actual production of the emulsion and the separation of the involved media.

Das Dokument EP 1 188 494 A1 beschreibt eine Bandabstreifvorrichtung, Bandabstreifmethode, Walzgerüst und Walzverfahren. Zur Verbesserung der Produktivität einer Kaltwalzeinrichtung wurde diese mit einem Bandabstreifer versehen.The document EP 1 188 494 A1 describes a belt scraper, belt scraper method, rolling mill and rolling method. To improve the productivity of a cold rolling device, this was provided with a belt scraper.

Beim Hochgeschwindigkeitswalzen von mehr als 700 m/min, welches mit konventionellen Abstreiferrollen oder Rohr-Abstreifer nicht ausführbar war, wurde die Produktivität der Kaltwalzeinrichtung und die Oberflächenqualität eines Bandes durch Hinzufügen der Abstreifvorrichtung wesentlich verbessert.In high-speed rolling of more than 700 m / min, which was not feasible with conventional scraper rollers or tube scrapers, the productivity of the cold rolling device and the surface quality of a strip were significantly improved by adding the scraper.

Das Dokument EP 0 672 471 B1 offenbart ein Verfahren und eine Vorrichtung zum Walzen von Bändern. Als Walzen werden verschleißarme, mit mindestens in einem ihrer Endbereiche mit vergrößerten Radien ausgeführte Walzen derart gegeneinander verschoben, dass das Walzband in seiner Breite jeweils mit Bereichen des geringeren Radius in Kontakt stehen, und dass mit zunehmender Erwärmung und mit thermischer Bombierung durch gegensinniges Verschieben der Walzen Bereiche ihres größeren Radius über Randbereiche des Walzbandes geschoben werden. Dadurch wird erreicht, dass die Randbereich-Überhöhungen des Bandes, die durch die steigende thermische Bombierung eintreten würden, beseitigt werden.The document EP 0 672 471 B1 discloses a method and apparatus for rolling ribbons. As rollers wear-resistant, at least in one of its end regions with enlarged radii running rollers are shifted from each other so that the rolled strip in its width in each case with areas of smaller radius in contact, and that with increasing heating and with thermal crowning by opposing displacement of the rollers Regions of their larger radius are pushed over edge regions of the rolled strip. As a result, it is achieved that the edge area elevations of the strip, which would occur due to the rising thermal crowning, are eliminated.

Das Dokument DE 199 08 743 A1 offenbart ein Verfahren und eine Vorrichtung zum Trocknen und Trockenhalten von insbesondere Kaltband im Auslaufbereich von Kaltwalz- und Bandanlagen. Bei der Trocknung und dem Trockenhalten insbesondere von gewalzten Bändern ist es bekannt, durch eine Abschottung den Trockenbereich des fertiggewalzten Bandes vom Feuchtraum des Walzgerüstes zu trennen. Hierzu wird eine berührungslose Abdichtung zwischen der Abschottung und dem Band durch ein luftkissenähnliches Druckgaspolster sowie eine Spaltströmung vorgeschlagen, um so Druckgas aus einer Vielzahl von Blasdüsen aus Blasdüsenleisten im rechten Winkel von oben und unten auf die Bandoberflächen aufzubringen.
Durch diese Maßnahme wird auch bei hohen Bandgeschwindigkeiten über 1000 m/min unabhängig von der Bandbreite eine Durchdringung von Walzöl oder auch Emulsion mit Erfolg verhindert und eine berührungslose Bandtrocknung erreicht.
The document DE 199 08 743 A1 discloses a method and an apparatus for drying and keeping dry, in particular cold strip in the outlet area of cold rolling and strip lines. In the drying and keeping dry particular of rolled strips, it is known by a partitioning the dry area of the finished rolled strip from the wet room of Separate rolling stand. For this purpose, a non-contact seal between the foreclosure and the tape by an air cushion-like compressed gas cushion and a slit flow is proposed so as to apply compressed gas from a plurality of nozzles from Blasdüsenleisten at right angles from above and below the tape surfaces.
This measure prevents penetration of rolling oil or even emulsion at high belt speeds of over 1000 m / min, irrespective of the bandwidth, and achieves non-contact belt drying.

Das Dokument DE 101 31 369 A1 offenbart ein Verfahren und eine Vorrichtung zum Kühlen und / oder Schmieren von Walzen, insbesondere der Arbeitswalzen eines Walzgerüstes und eines zwischen diesen Walzen gewalzten und hindurch geförderten Walzbandes unter Verwendung von Wasser in Form von Sprühstrahlen als Kühlmedium und Sprühöl, Öl-Luft-Gemisch oder Öl-WasserGemisch, als Schmiermittel. Zur Verbesserung der Schmier- und Kühlwirkung wird ein kombinierter Einsatz von Unterkühlung der Band- und Walzenoberfläche sowie der Walzenschmierung auf der Gerüsteinlaufseite vorgeschlagen, indem die beiden Medien - Wasser bzw. Schmiermittel - den Walzen bzw. dem Walzband getrennt zugeführt und an unterschiedliche Auftragsstellen der Walzoberfläche aufgetragen werden. Für Wasser bzw. Schmiermittel sind jeweils separate Vorratsbehälter sowie getrennte Zuführungen zu den Sprühbalken für Wasser und zu den Sprühbalken für das Schmiermittel vorgesehen. Mit großem Vorteil ergibt sich hieraus eine optimale Nutzung von jeweils Schmier- oder Kühlwirkung der beiden Medien Wasser und Schmiermittel und damit zugleich eine Senkung des Kraft- und Arbeitsbedarfes, bedingt durch minimierte Reibwerte an den Walzen. Die geschliffene Oberfläche der Walze hält selbst bei höchsten Beanspruchungen stand. Die bisher beobachteten Materialabschälungen an den Walzen werden unterbunden. Die Oberfläche des gewalzten Bandes bleibt optimal glatt, Zundereinschlüsse und Rattermarken auf der Bandoberfläche sind eliminiert.The document DE 101 31 369 A1 discloses a method and apparatus for cooling and / or lubricating rolls, in particular the work rolls of a rolling stand and a rolled strip conveyed between and conveyed through these rolls, using water in the form of sprays as cooling medium and spray oil, oil-air mixture or oil -Water mixture, as a lubricant. To improve the lubricating and cooling effect, a combined use of supercooling of the belt and roll surface and the roll lubrication on the scaffold inlet side is proposed by the two media - water or lubricant - the rolls or the strip fed separately and to different application sites of the rolling surface be applied. For water or lubricant separate reservoirs and separate feeds to the spray bar for water and to the spray bar for the lubricant are provided. With great advantage, this results in an optimal use of each lubricating or cooling effect of the two media water and lubricant and thus at the same time a reduction in force and labor requirements, due to minimized friction coefficients on the rollers. The ground surface of the roller withstands even the highest demands. The previously observed Materialabschälungen on the rollers are suppressed. The surface of the rolled strip remains optimally smooth, scales and chatter marks on the strip surface are eliminated.

Die europäische Patentschrift EP 0 672 471 B1 offenbart ein Verfahren und eine Vorrichtung zum Walzen von Bändern, mit axial verschiebbaren Walzen. Das Verfahren ist dadurch gekennzeichnet, dass verschleißarme, mit mindestens an einem ihrer Endbereiche mit vergrößerten Radien ausgeführte Walzen derart gegeneinander verschoben werden, dass das Walzband in seiner Breite jeweils auch mit Bereichen mit geringerem Radius in Kontakt steht und dass mit zunehmender Erwärmung und mit thermischer Bombierung durch gegensinniges Verschieben der Walzen auch Bereiche der Walzen mit größerem Radius über Randbereiche des Walzbandes geschoben werden. Dieses Verfahren dient dazu, dem störenden, thermischen Bombierungseffekt einfach und kostengünstig entgegenzuwirken, um Walzpläne freier gestalten zu können.The European patent EP 0 672 471 B1 discloses a method and apparatus for rolling belts with axially displaceable rollers. The method is characterized in that low-wear, executed with at least at one of its end portions with enlarged radii rollers are shifted against each other such that the rolled strip is in its width in each case with areas of smaller radius in contact and that with increasing heating and with thermal crowning By oppositely moving the rollers and areas of the rollers with a larger radius are pushed over edge regions of the rolled strip. This method is used to counteract the annoying, thermal crowning effect simply and inexpensively, in order to make rolling plans more free.

Das US Patent 5,943,896 offenbart ein Verfahren zum Beeinflussen der Kontur eines gewalzten Bandes im Randbereich. Für diesen Zweck wird vorgeschlagen, continuously variable crown CVC-Arbeitswalzen mit einem speziellen unsymmetrischen Schliff zu verwenden. Gemäß diesem Schliff weist jede Arbeitswalze an ihrem einen Ende einen Bereich mit einem kleineren Durchmesser auf als an ihrem anderen Ende, wobei der Bereich mit dem kleineren Ende über die Breite der Arbeitswalze gesehen, kürzer ist als der Bereich mit dem großen Durchmesser. In einem Übergangsbereich geht der Durchmesser der Arbeitswalze z.B. linear von dem kleinen Durchmesser auf den größeren Durchmesser über. Während des Walzbetriebs sind die beiden übereinander angeordneten Walzen so angeordnet, dass das dünnere Ende der einen Walze jeweils dem dickeren Ende der anderen Walze gegenüber steht.The U.S. Patent 5,943,896 discloses a method for influencing the contour of a rolled strip in the edge region. For this purpose it is proposed to use continuously variable crown CVC work rolls with a special unsymmetrical cut. According to this finish, each work roll has a smaller diameter portion at one end than at the other end thereof, the smaller end portion being shorter than the large diameter portion across the width of the work roll. In a transition region, for example, the diameter of the work roll linearly changes from the small diameter to the larger diameter. During the rolling operation, the two superposed rollers are arranged so that the thinner end of the one roller is opposite to the thicker end of the other roller.

Die japanische Patenanmeldung JP 05050122 offenbart eine Vorrichtung und ein Verfahren zum Realisieren eines scharf getrennten Wärmeübergangs zwischen verschiedenen Temperaturbereichen auf der Oberfläche einer Arbeitswalze.The Japanese godparent application JP 05050122 discloses an apparatus and method for realizing a sharply separated heat transfer between different temperature ranges on the surface of a work roll.

Die japanische Anmeldung 03297507 offenbart ein Verfahren, um das Auftreten von Spannungen in den Randbereichen eines gewalzten Bandes und eine Verlängerung der Randbereiche zu verhindern. Zu diesem Zweck wird vorgeschlagen, im Bereich der Mitte des gewalzten Bandes, also nicht in dessen Randbereichen ein kaltes Kühlmittel aufzubringen und gleichzeitig in den Randbereichen sowie außerhalb derselben ein warmes Kühlmittel aufzubringen.The Japanese application 03297507 discloses a method for detecting the occurrence of stresses in the edge regions of a rolled strip and an extension to prevent the edge areas. For this purpose, it is proposed to apply a cold coolant in the region of the center of the rolled strip, that is to say not in its edge regions, and at the same time to apply a warm coolant in the edge regions and outside thereof.

Die deutsche Offenlegungsschrift DE 31 144 87 A1 offenbart ein Verfahren und eine Vorrichtung zur Walzentemperierung in Kaltwalzwerken. Um das Auftreten von hohen Kantenspannungen beim Walzen von Feinbändern und Folien zu vermeiden wird vorgeschlagen, dass ein Walzenbereich, der außerhalb der Bandkante liegt und sich unmittelbar an die Bandkante anschließt durch Aufbringen von erwärmtem Schmiermittel temperiert wird. Es wird eine relativ scharfe Grenzlinie zwischen warmem und kaltem Schmiermittelstrahl eingestellt. Die Lage dieser Grenzlinie soll mit der Lage der Bandkante zusammenfallen.The German patent application DE 31 144 87 A1 discloses a method and apparatus for roll tempering in cold rolling mills. In order to avoid the occurrence of high edge tensions during rolling of fine strips and films, it is proposed that a roll area which lies outside the strip edge and adjoins directly to the strip edge be tempered by applying heated lubricant. A relatively sharp borderline between hot and cold lubricant jet is set. The position of this boundary line should coincide with the position of the band edge.

Schließlich ist es aus der gattungsbildenden japanischen Patentanmeldung JP 62142011 bekannt, Kühlung und Schmierung von Arbeitswalzen zu trennen, indem auf der Eingangsseite lediglich Walzöl und auf der Ausgangsseite lediglich Kühlmittel aufgebracht wird. Auf diese Weise wird die Kontur eines gewalzten Metallbandes verbessert.Finally, it is from the generic Japanese patent application JP 62142011 Known to separate cooling and lubrication of work rolls by applying only rolling oil on the input side and only coolant on the output side. In this way, the contour of a rolled metal strip is improved.

Ausgehend vom vorgenannten Stand der Technik liegt der Erfindung im Kaltwalzbereich, insbesondere in der Aluminium-Industrie, fallweise aber auch im Stahlbereich und NE-Metall-Bereich, die Aufgabe zugrunde, die beim Dünnwalzen entstehenden strammen Bandkanten und randnahen langen Bandfasern sowie Bandrisse weiter zu reduzieren, Besäumungen weiter einzusparen und dadurch die Qualität sowie die Quantität beim Ausbringen weiter zu verbessern.Based on the above-mentioned prior art, the invention is in the cold rolling, especially in the aluminum industry, but occasionally in the steel and non-ferrous metal area, the task of further reducing the resulting during thin rolling strip edges and near-edge long strip fibers and tape cracks on To further save edgebandings and thereby further improve the quality and quantity of application.

Diese Aufgabe wird durch das in Patentanspruch 1 beanspruchte Verfahren gelöst. Dieses Verfahren ist dadurch gekennzeichnet, dass die Bandkanten durch "Hot Edge Spray", insbesondere durch zonenweises Aufsprühen von Walzöl mit unterschiedlichen Temperaturen, beeinflusst werden und bei den Arbeitswalzen im Beriech der Bandkanten ein spezieller Schliff verwendet wird, der zum partiellen Materialaufbau beim Vorstich geeignet ist, wobei der Materialaufbau bei nachfolgenden Stichen zu einer längeren Bandkante führt und der Gefahr eines hohen Zugaufbaues entgegenwirkt.This object is achieved by the method claimed in claim 1. This method is characterized in that the strip edges are influenced by "hot edge spray", in particular by zonewise spraying of rolling oil at different temperatures, and in the Work rolls in the Beriech the band edges a special finish is used, which is suitable for partial buildup of material in the prestretch, the material structure in subsequent stitches leads to a longer band edge and counteracts the risk of high Zugaufbaues.

Mit Hilfe der erfindungsgemäßen Maßnahmen wird nachweisbar die Bandrissgefahr durch Bandkanteneinrisse deutlich verringert und zusätzlich die Bandoberfläche verbessert.With the aid of the measures according to the invention, the risk of ligament tear is clearly reduced by band edge tears and, in addition, the strip surface is improved.

Durch regelbare Zugspannungsverteilung, insbesondere im Bandkantenbereich wird ein höherer Materialdurchsatz unter Reduzierung von Nebenzeiten bei erhöhter Arbeitsgeschwindigkeit problemlos erreicht. Dazu werden insgesamt die Planheiten deutlich verbessert, die Produktion gesteigert und Walzöl-Umlaufmengen reduziert.By adjustable tension distribution, especially in the band edge area, a higher material throughput is easily achieved while reducing non-productive times at an increased operating speed. Overall, the flatness is significantly improved, production increased and rolling oil circulation volumes reduced.

Eine Ausgestaltung des Verfahrens nach Anspruch 1 sieht vor, dass eine vermehrte Durchmesserabnahme der Arbeitswalzen an den Kantenbereich infolge partieller Durchmessererhöhung während deren Formgebung mittels induktiver Erwärmung vorgenommen wird.An embodiment of the method according to claim 1 provides that an increased diameter decrease of the work rolls is made at the edge region due to partial increase in diameter during their shaping by means of inductive heating.

Weiterhin kann von der Maßnahme Gebrauch gemacht sein, dass die Bandzugspannungsverteilung durch eine konkav biegbare bzw. gebogene Umlenkrolle derart geändert wird, dass die Bandzugspannung an den Bandkanten verringert und in der Bandmitte erhöht wird.Furthermore, it can be made use of the measure that the strip tension distribution is changed by a concave bendable or curved guide roller such that the tape tension is reduced at the strip edges and increased in the center of the strip.

Und schließlich kann von der weiteren Maßnahme Gebrauch gemacht sein, dass bei Vorstichen Material an den Bandkanten durch "Edge Sprays" mit Schmiermittel von relativ höherer Viskosität aufgebaut wird.Finally, use may be made of the further measure that, in the case of pre-stitches, material is built up at the edge of the strip by means of "edge sprays" with lubricant of relatively higher viscosity.

Die oben genannte Aufgabe wird weiterhin durch eine Vorrichtung zum Aufbauen einer regelbaren Zugspannungsverteilung mit den Merkmalen des Anspruchs 5, gelöst. Die mit dieser Vorrichtung verbundenen Vorteile sind zuvor bei dem erfindungsgemäßen Verfahren beschrieben worden.The above object is further achieved by a device for establishing a controllable tensile stress distribution with the features of claim 5. The with this device Associated advantages have been previously described in the inventive method.

Eine weitere Ausgestaltung der Vorrichtung beinhaltet vorteilhafterweise eine in Bandlaufrichtung konvex biegbare bzw. gebogene Lenkrolle in Anordnung zwischen zwei Führungsrollen zur Veränderung der Zugspannungsverteilung eines Bandes vor dessen Einlauf in ein Walzgerüst.Another embodiment of the device advantageously includes a convexly bendable in the belt running direction or curved steering roller in an arrangement between two guide rollers for changing the tensile stress distribution of a strip before its entry into a rolling stand.

In Ergänzung hierzu ist die Vorrichtung weiterhin dadurch ausgestaltet, dass sie auf der Einlaufseite eines Walzgerüstes Mittel zur Additiv-Direktauftragung, insbesondere auf das Walzband z. B. für Schmieröl mit relativ hoher Viskosität, und auf der Auslaufseite der Arbeitswalzen Mittel zur Ballenkühlung der Arbeitswalzen und bevorzugt zusätzliche Mittel zur Schmiermittelentfernung besitzt, die das Walzband mit Vorzug sowohl von der Bandoberseite als auch von der Bandunterseite her mit den zuordenbaren Sprühmedien besprühen.In addition to this, the device is further configured by the fact that they are on the inlet side of a rolling mill means for direct additive application, in particular on the rolled strip z. B. for lubricating oil with relatively high viscosity, and on the outlet side of the work rolls means for bale cooling of the work rolls and preferably additional lubricant removal means which spray the rolled strip with preference from both the tape top and from the underside of the band with the attributable spray media.

Und schließlich besitzt die Vorrichtung nach der Erfindung eine Einrichtung, welche Kühlmittel in der Auslaufseite des Gerüstes entfernt.And finally, the device according to the invention has a device which removes coolant in the outlet side of the scaffold.

Weitere Einzelheiten, Merkmale und Vorteile der Erfindung ergeben sich aus der nachstehenden Erläuterung eines in den Zeichnungen schematisch dargestellten Ausführungsbeispieles.Further details, features and advantages of the invention will become apparent from the following explanation of an embodiment schematically illustrated in the drawings.

Es zeigen:

Figur 1
eine Vorrichtung für "Hot Edge Spray" an der Walzenkante
Figur 2
einen Spezialschliff für Arbeitswalzen
Figur 3
In Seitenansicht eine konvex biegbare bzw. gebogene Lenkrolle
Figur 4
Die Draufsicht auf die Lenkrolle gem. Fig. 3
Figur 5
In Seitenansicht eine erfindungsgemäße Anlage mit Direktauftragung von Schmiermittel auf das Walzband, auslaufseitiger Walzenkühlung und Schmiermittelentfernung.
Show it:
FIG. 1
a device for "hot edge spray" on the roll edge
FIG. 2
a special grinding for work rolls
FIG. 3
In side view a convex bendable or curved steering roller
FIG. 4
The top view of the steering role gem. Fig. 3
FIG. 5
In side view, a plant according to the invention with direct application of lubricant to the rolled strip, outlet side roll cooling and lubricant removal.

Figur 1 zeigt einen Teil einer Vorrichtung zum Aufbringen einer regelbaren Zugspannungsverteilung, insbesondere in Kantenbereichen beim Kaltwalzen von Metallbändern, mit in wenigstens zwei getrennten Zonen 10, 10' vorhandenen Sprühdüsenanordnungen 11, 11' mit Anschlüssen an getrennte Sprühmittelzuführungen 19, 19' an unterschiedliche Zonen 10, 10' jeder Arbeitswalze 12. Darüber hinaus besteht die Möglichkeit einer partiellen induktiven Erwärmung der Arbeitswalze in an sich bekannter Art. FIG. 1 shows a part of a device for applying a controllable tensile stress distribution, in particular in edge regions during cold rolling of metal strips, with in at least two separate zones 10, 10 'existing spray nozzle assemblies 11, 11' with connections to separate Sprühmittelzuführungen 19, 19 'to different zones 10, 10th In addition, there is the possibility of a partial inductive heating of the work roll in a conventional manner.

Figur 2 zeigt ein Paar Arbeitswalzen 12, 12', die jeweils in einem Endbereich einen Spezialschliff 13, 13' mit Durchmesservergrößerungen in den Endbereichen zur Verlängerung der zu walzenden Bandkanten unter gleichzeitigem Abbau von Zugspannungen und Reduktion langer Bandfasern aufweisen. FIG. 2 shows a pair of work rolls 12, 12 ', each having in one end a special grinding 13, 13' with increases in diameter in the end regions for extending the strip edges to be rolled with simultaneous reduction of tensile stresses and reduction of long strip fibers.

Die Figuren 3 und 4 zeigen gemeinsam in Seitenansicht und in Draufsicht eine Anordnung zur Verlängerung der Zugspannungsverteilung über die Bandbreite bei Fertigstichen. Dies wird erreicht durch einen variablen Umschlingungswinkel W bei Banddicken: 1 - 6 µm mit W = 60 - 90 ° 8 - 20 µm mit W = 45 - 60 ° > 20 µm W = 45 ° und darüber bei Metallfolien W = 15 - 20 ° The FIGS. 3 and 4 show together in side view and plan view of an arrangement for extending the tensile stress distribution over the bandwidth in ready-stitching. This is achieved by a variable wrap angle W at strip thicknesses: 1 - 6 μm with W = 60 - 90 ° 8-20 μm with W = 45 - 60 ° > 20 μm W = 45 ° and above in the case of metal foils W = 15 - 20 °

Figur 5 zeigt in Seitenansicht eine erfindungsgemäße Anlage, mit einer Abrollhaspel auf der linken Seite und einer Aufrollhaspel auf der rechten Seite sowie Führungsmittel für das Walzband 16 in Bandlaufrichtung 14 sowie Mittel 21 zur Direktauftragung von Schmiermittel mit Viskosität bzw. Additiv auf der Bandeinlaufseite sowie Mittel 22 zur Ballenkühlung der auslaufseitigen Arbeitswalzen und mit Mitteln 23 zur auslaufseitigen Schmiermittelentfernung. Damit wird ein Materialaufbau an der Bandkante während der Vorstiche und entsprechend ein Materialabbau an der Bandkante während der Fertigstiche mit Hilfe einer Additiv-Direktauftragung in der Einlaufseite und Walzenkühlung in der Auslaufseite erreicht. FIG. 5 shows a side view of an inventive system, with a decoiler on the left side and a Aufrollhaspel on the right and guide means for the rolled strip 16 in the direction of belt 14 and means 21 for direct application of lubricant with viscosity or additive on the band inlet side and means 22 for bale cooling the outlet side work rolls and means 23 for the outlet side lubricant removal. Thus, a material build-up at the strip edge during the pre-stitching and correspondingly a material removal at the strip edge during the finishing passes is achieved with the aid of an additive direct application in the inlet side and roll cooling in the outlet side.

BezugszeichenlisteLIST OF REFERENCE NUMBERS

10, 10'10, 10 '
Sprühzonespray zone
11, 11'11, 11 '
Sprühdüsenanordnungspray nozzle
12, 12'12, 12 '
Arbeitswalzenstrippers
14.14th
BandlaufrichtungTape direction
15.15th
Lenkrollecastor
16.16th
Bandtape
17.17th
Führungsrolleleadership
19. 19'19. 19 '
SprühmittelzuführungSprühmittelzuführung
20.20th
Walzgerüstrolling mill
21.21st
Additiv-AuftragungAdditive-application
22.22nd
BallenkühlmittelBall coolant
23.23rd
SchmiermittefentfernungSchmiermittefentfernung

Claims (8)

  1. Method for applying a regulable tensile stress distribution particularly in the edge regions during the cold rolling of metal strips, for the purpose of reducing a risk of excessive build-up of tensile stress and the risk of strip edge cracks, which can have the negative consequence of strip breakages and thus reduced production, and for the purpose of improving the strip surface and its flatness, even at relatively high strip running speed and of reducing strip trimming widths, wherein the method comprises the following step:
    a) separation of lubricant and cooling of work rolls by lubrication at the run-in side and cooling at the runout side,
    and is further characterised by the following additional measures:
    b) influencing of the strip edges by hot edge spray particularly by zonal spraying of rolling oil at different temperatures, and
    c) use of a special cross-sectional configuration of the work rolls in the region of the strip edges for partial material build-up during the roughing pass, which leads to a longer strip edge in subsequent passes and counteracts the risk of build up of a high tensile stress.
  2. Method according to claim 1 or 2, characterised in that a greater diameter reduction of the work rolls is undertaken at the edge regions due to partial diameter increase during shaping by inductive heating.
  3. Method according to claim 1 or 2, characterised in that the strip tensile stress distribution is varied by a concavely bendable or bent deflecting roll in such a way that the strip tensile stress is reduced at the edges of the strip and increased in the centre of the strip.
  4. Method according to one or more of claims 1 to 3, characterised in that in roughing passes, material is built up at the edges of the strip by edge sprays with lubricants of relatively high viscosity.
  5. Device for developing an regulable tensile stress distribution, particularly in edge regions during the cold rolling of metal strips, preferably for performance of the method according to the preceding claims, wherein the device comprises at least one spray nozzle system (11, 11') on the run-in side for applying lubricant and means for cooling the barrels of the work rolls on the runout side; characterised in that
    at least two of the spray nozzle systems (11, 11') with connections for separate spray medium feeds (19, 19') are present for spraying the lubricant in the form of rolling oil at different temperatures in different zones (10, 10') of each work roll (12); and that
    each of the work rolls (12, 12') has a special cross-section (13, 13') with increased diameters in the end regions thereof for the purpose of lengthening the rolled strip edges with simultaneous reduction of tensile stresses and reduction of long strip fibres in regions near the edges of the strip.
  6. Device according to claim 5, characterised by a deflecting roll (15) that is convexly bendable or bent in the strip running direction (14) and is arranged between guide rolls (17) to change the tensile stress distribution of a strip (16) before it enters a rolling stand (20).
  7. Device according to claim 5 or claim 6, characterised in that on the run-in side of a rolling stand (20) it has means (21) for the direct application of additive, particularly to the rolled strip (16), for example lubricating oil with relatively high viscosity, and on the runout side of the work rolls (12, 12') it has means (22) for cooling the barrels of the work rolls and preferably additional means (23, 23') for removal of the lubricant, which advantageously spray the rolled strip (16) from both the strip upper side and the strip lower side with the associated spray media.
  8. Device according to one of more of claims 5 to 7, characterised in that it has a device that removes coolant in the runout side of the stand (20).
EP04764552A 2003-09-04 2004-08-27 Method and device for applying an adjustable tensile-stress distribution, in particular in the edge regions of cold-rolled metal strips Not-in-force EP1682288B1 (en)

Applications Claiming Priority (3)

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DE10340694 2003-09-04
DE10352546A DE10352546A1 (en) 2003-09-04 2003-11-11 Method and device for applying an adjustable tensile stress distribution, in particular in the edge regions of cold-rolled metal strips
PCT/EP2004/009578 WO2005023444A2 (en) 2003-09-04 2004-08-27 Method and device for applying an adjustable tensile-stress distribution, in particular in the edge regions of cold-rolled metal strips

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EP1682288B1 true EP1682288B1 (en) 2009-06-17

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EP (1) EP1682288B1 (en)
JP (1) JP4936889B2 (en)
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DE10352546A1 (en) 2005-03-31
EP1682288A2 (en) 2006-07-26
CN1845803A (en) 2006-10-11
RU2006110636A (en) 2006-08-10
ZA200601117B (en) 2007-04-25
WO2005023444A2 (en) 2005-03-17
WO2005023444A3 (en) 2006-01-26
CA2537501A1 (en) 2005-03-17
ATE433809T1 (en) 2009-07-15
CA2537501C (en) 2010-10-19
BRPI0414152B1 (en) 2015-10-20
TWI320726B (en) 2010-02-21
KR20060067967A (en) 2006-06-20
CN1845803B (en) 2010-09-15
US20070186609A1 (en) 2007-08-16
ES2325539T3 (en) 2009-09-08
KR101109459B1 (en) 2012-01-31
TW200520864A (en) 2005-07-01
JP4936889B2 (en) 2012-05-23
BRPI0414152A (en) 2006-10-31
DE502004009629D1 (en) 2009-07-30
RU2358820C2 (en) 2009-06-20
US7434435B2 (en) 2008-10-14
JP2007504007A (en) 2007-03-01

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