EP1617973B1 - Verfahren zur herstellung von vliesstoffschleifartikeln mit trockenem körnigem material - Google Patents

Verfahren zur herstellung von vliesstoffschleifartikeln mit trockenem körnigem material Download PDF

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Publication number
EP1617973B1
EP1617973B1 EP20040749880 EP04749880A EP1617973B1 EP 1617973 B1 EP1617973 B1 EP 1617973B1 EP 20040749880 EP20040749880 EP 20040749880 EP 04749880 A EP04749880 A EP 04749880A EP 1617973 B1 EP1617973 B1 EP 1617973B1
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Prior art keywords
web
fibres
binder
particles
abrasive
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EP20040749880
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English (en)
French (fr)
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EP1617973A1 (de
Inventor
Guy M. Pollaud
Sandrine Maljean
Carmen Martin Rivera
Estrella Cabrero Gomez
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3M Innovative Properties Co
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3M Innovative Properties Co
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B24—GRINDING; POLISHING
    • B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D11/00—Constructional features of flexible abrasive materials; Special features in the manufacture of such materials
    • B24D11/001—Manufacture of flexible abrasive materials
    • B24D11/005—Making abrasive webs

Definitions

  • the present invention relates to a method of making abrasive articles.
  • Nonwoven abrasive articles comprising a nonwoven fibrous web to which abrasive particles are attached are known and are used extensively for cleaning, abrading, finishing and polishing applications on a variety of surfaces. Examples of such nonwoven abrasive articles, and methods by which they may be manufactured, are described in US-A-2 958 593 .
  • One method comprises forming an open, air-laid fibrous web, and spraying one surface of the web with a resin-abrasive slurry which is then cured. The other surface of the web is then sprayed with the same resin-abrasive slurry, which is also cured.
  • Roll-coating and dip-coating are mentioned in US-A-2 958 593 as alternative methods of applying the resin-abrasive slurry, and it is also mentioned that the resin and the abrasive particles may be applied separately. It is further stated that it may be desirable to employ one type of binder (for example, a light treatment of an elastomer) for adhesively bonding the web fibres together to integrate and unify the web, and a grit binder of different composition for bonding the mineral grains to the integrated and unified web.
  • binder for example, a light treatment of an elastomer
  • US-A-5 681 361 describes a method of making nonwoven abrasive articles, in which binder material and abrasive particles are applied to a nonwoven web in the form of dry particulate material, to reduce the use of liquid organic solvents during the manufacturing process and thereby address environmental concerns associated with the emission of volatile organic compounds (VOCs).
  • VOCs volatile organic compounds
  • the fibres of the web are pre-bonded together at their mutual points of contact before the abrasive particles and the particulate binder material are applied.
  • That pre-bonding may be effected either (i) by applying, to the web, a liquid pre-bond resin that is then cured, or (ii) by including, within the construction of the web, melt-bondable fibres that are caused to melt and then allowed to re-solidify.
  • the present invention is also concerned with the environmental aspects of the manufacture of nonwoven abrasives (including the use of liquid organic solvents and the accompanying risk that VOCs will escape into the atmosphere, the energy requirements of the manufacturing process, and the waste produced), and is additionally concerned with enabling nonwoven abrasive articles to be manufactured from alternative materials not previously considered suitable for that purpose.
  • the present invention provides a method of making an abrasive article, as per claim 1, including the steps of
  • a pre-bonded web is produced using dry materials only: consequently, no VOCs need be emitted during this part of the method, and the energy requirements are less than if liquid pre-bond resins were used. Any excess binder particles applied to the web need not be wasted but can be recovered and re-used.
  • an open, lofty web having adequate structural strength for use in a nonwoven abrasive article can be produced using fewer, or less resilient, fibres than would be required if the web were roll-coated or sprayed with liquid pre-bond resins.
  • open and "lofty” indicate that the pre-bonded web is of comparatively low density, having a network of many, relatively large, intercommunicated voids that comprise the greater amount (more than 50%, preferably substantially more than 50%) of the volume occupied by the web.
  • the terms indicate that the bonded web has a density no greater than 50 kg/m3, preferably no greater than 30 kg/m3 (especially when the web comprises synthetic fibres).
  • a first method in accordance with the invention comprises the steps of:
  • Step (i)(a) Forming fibres into an open, lofty, three-dimensional nonwoven web
  • the fibers that can be used to form the nonwoven web include both natural and synthetic fibers and mixtures thereof.
  • the fibers are typically in the form of staple and may be tensilized.
  • the fibers can be curled, crimped or straight.
  • Suitable synthetic fibers include those made of polyester (e.g., polyethylene terephthalate), polyamide (e.g., hexamethylene adipamide, polycaprolactum and aramids), polypropylene, acrylic (formed from a polymer of acrylonitrile), rayon, cellulose acetate, polyvinylidene chloride-vinyl chloride copolymers, and vinyl chloride-acrylonitrile copolymers, as well as carbon fibres and glass fibres.
  • polyester e.g., polyethylene terephthalate
  • polyamide e.g., hexamethylene adipamide, polycaprolactum and aramids
  • polypropylene e.g., acrylic (formed from a poly
  • Suitable natural fibers include those of cotton, wool, jute, coco, sisal, flax and hemp.
  • An important consideration in the selection of the fiber is that it is capable of withstanding the process temperatures to which it will subsequently be exposed (see below).
  • the fibers used may be virgin fibers or waste fibers reclaimed from garment cuttings, carpet manufacturing, fiber manufacturing, or textile processing, and so forth.
  • the fineness or linear density of the fibers used may vary widely, depending upon the results desired. Coarse fibers are generally more conducive to making abrasive articles for rough abrading jobs, while finer fibers are generally more appropriate for less aggressive scouring applications. Useful fibers generally are those having a linear density of from about 6 to 300 denier (more especially 10 to 200 denier) although finer or coarser fibers (or mixtures thereof) may be used depending, for example, on the application envisaged for the finished abrasive article.
  • the bales should be opened before use.
  • the selected fibres can then be dry-laid into an open, lofty, three-dimensional nonwoven fibrous web in any suitable way.
  • the web may, for example, be air-laid or carded and cross-lapped, and may additionally be needle-tacked. Processes for producing such webs are well known.
  • a preferred type of nonwoven web is an air-laid web as described in US-A-2 958 593 .
  • An air-laid nonwoven web can be formed by a "Rando-Webber” machine commercially available from Rando Machine Co., Ard, N.Y. With such processing equipment, a range of fibre lengths can be used although an average fiber length of about 10 cm. is most usual. However, with this, as with other types of conventional web forming equipment, fibers of different lengths, or combinations thereof also can be utilized to form the nonwoven web. As already mentioned, there are no particular limitations on the thickness of the fibers (apart from those imposed by processing considerations), as long as due regard is given to the resilience and toughness ultimately desired in the resulting web.
  • the physical characteristics of the web at this stage should be selected having regard to the desired properties of the abrasive article that is to be produced.
  • a very open, low density, web might be required (for example, when the abrasive article is a domestic scouring pad): in such a case, an air-laid web produced using fine fibres could be preferred.
  • a less open, higher density, web might be required: in such a case, a carded, cross-lapped and needle-tacked web using coarser fibres could be preferred.
  • the thickness of the web will depend on the way in which the web is produced and also on the nature of the fibres and the quantity used per unit area.
  • Step (i)(b) Contacting the web with dry particulate material that includes fusible binder particles
  • the nonwoven web that is formed as described in step (i)(a) above is then contacted with dry particulate material that includes fusible binder particles.
  • the binder will subsequently be activated, as described below, to form bonds between the fibres of the web and thus provide a pre-bonded web to which abrasive particles are subsequently applied.
  • the binder particles should therefore be selected having regard to the nature of the web fibres and the subsequent processing steps to which the pre-bonded web will be subjected, and having regard also to the desired properties of the abrasive article that is to be produced.
  • Particulate materials suitable for use in bonding nonwoven webs are known, and include thermosetting and thermoplastic powders that are activated by heat, as well as powders that are activated in other ways (for example, by moisture). Particulate materials suitable for bonding nonwoven webs for various purposes are described, for example, in US-A-4 053 674 , 4 457 793 , 5 668 216 , 5 886 121 , 5 804 005 , 5 9767 244 , 6 039 821 , 6 296 795 , 6 458 299 , and 6 472 462 .
  • the particulate binder materials most suitable for use in the manufacture of abrasive articles are those that will provide an abrasive article with good strength and water/heat resistance and, for use with a nonwoven web as described above, the particulate binder materials should be capable of being activated without damaging the web fibres.
  • Thermosetting particulate binder materials that have been proposed for use in the manufacture of nonwoven abrasive articles include formaldehyde-containing resins, such as phenol formaldehyde, novolac phenolics and especially those with added crosslinking agent (e.g., hexamethylenetetramine), phenoplasts, and aminoplasts; unsaturated polyester resins; vinyl ester resins; alkyd resins, allyl resins; furan resins; epoxies; polyurethanes; polyimides; and thermosetting acrylates.
  • formaldehyde-containing resins such as phenol formaldehyde, novolac phenolics and especially those with added crosslinking agent (e.g., hexamethylenetetramine), phenoplasts, and aminoplasts
  • unsaturated polyester resins vinyl ester resins
  • alkyd resins alkyd resins, allyl resins
  • furan resins epoxies
  • Thermoplastic particulate binder materials that have been proposed for use in the manufacture of nonwoven abrasive articles include polyolefin resins such as polyethylene and polypropylene; polyester and copolyester resins; vinyl resins such as poly(vinyl chloride) and vinyl chloride-vinyl acetate copolymers; polyvinyl butyral; cellulose acetate; acrylic resins including polyacrylic and acrylic copolymers such as acrylonitrile-styrene copolymers; polyamides (e.g., hexamethylene adipamide, polycaprolactum), and copolyamides.
  • polyolefin resins such as polyethylene and polypropylene
  • polyester and copolyester resins vinyl resins such as poly(vinyl chloride) and vinyl chloride-vinyl acetate copolymers
  • polyvinyl butyral polyvinyl butyral
  • acrylic resins including polyacrylic and acrylic copolymers such as
  • thermosetting and thermoplastic particulate binder materials may also be used.
  • the methods and equipment useful for applying the particulate binder material to the nonwoven web may be selected from among any known to be suitable for achieving an even distribution of the required amount of binder material throughout the web. Suitable methods include powder scattering or drop coating and powder spraying or sifting. In some cases, the application of particulate binder material to a nonwoven web may be followed by an impregnation step in which the web is passed through an alternating electrical field to distribute the binder material throughout the thickness of the web.
  • a preferred method of applying the particulate binder material to the nonwoven web uses an electrostatic powder spray gun, of the type known for use in powder coating applications, to direct electrically-charged binder particles downwards towards the web while the latter is being carried on a grounded, electrically-conductive open-mesh conveyor.
  • the binder particles will penetrate the whole thickness of the web, under the combined effects of electrostatic attraction, flow of atomising air from the spraygun, and gravity; and excess binder material that passes through the web can be collected below the conveyor and recycled.
  • the web can be premoistened to increase the amount of binder particles retained within it.
  • the size of the binder particles is selected to suit the method by which the binder material is applied to the nonwoven web and to ensure that the particles are small enough to penetrate into the interstitial spaces between the fibers of the web.
  • the particle size of the binder particles is less than about 1 mm, preferably less than about 500 micrometers.
  • the binder particles are to be applied to the web using an electrostatic powder spray gun, they preferably have a particle size no greater than 200 micrometers.
  • the amount of binder material applied to the nonwoven web should be adjusted to the minimum amount consistent with providing adequate bonding of the web having regard to the subsequent processing to which it will be subjected, and the nature of the abrasive article for which the bonded web will be used.
  • the binder material may be applied to the web in admixture with non-resinous powdered substances such as fillers, catalyst accelerators, flow aids, pigment powders, grinding aids, and anti-smearing agents.
  • non-resinous powdered substances such as fillers, catalyst accelerators, flow aids, pigment powders, grinding aids, and anti-smearing agents.
  • the nonwoven web containing the binder particles, formed as described in steps (i)(a) and (b) above, is then exposed to conditions that will cause the binder particles to form, a flowable liquid. It is found that the binder liquid tends to flow along and coat the web fibres so that, when the binder liquid subsequently solidifies, the web fibres will be bonded together at their mutual contact points.
  • the nonwoven web containing the binder material is heated to at least the cure temperature of the resin.
  • the cure temperature of the resin should be below the melting point (where applicable) of the web fibers.
  • the first effect of a temperature rise sufficiently above the glass transition temperature of the resin will be a softening of the binder material into a flowable fluid-like state, which will allows the resin to wet or contact the surface of the web fibres. Prolonged exposure to a sufficiently high temperature will then trigger a chemical reaction in the resin, forming a cross-linked three-dimensional molecular network that corresponds to a rigid plastic and binds the web fibres together at their mutual contact points.
  • the binder material comprises semi-crystalline thermoplastic particles (for example, polyolefins, hexamethylene adipamide, polycaprolactum)
  • thermoplastic particles for example, polyolefins, hexamethylene adipamide, polycaprolactum
  • the melting point of the binder material should be below the melting point (where applicable) of the web fibers (or brought into this range by incorporation of a plasticizer).
  • non-crystalline thermoplastic particles e.g., vinyl resins, acrylic resins
  • the nonwoven web containing the binder material is heated above the glass transition and rubbery region points of the binder material until the fluid flow region is achieved.
  • the nonwoven web is allowed to cool so that the binder fluid solidifies and binds the web fibres together at their mutual contact points.
  • the nonwoven web containing the particulate binder material is sprayed with water to produce a flowable binder fluid. Thereafter, the web is heated to a temperature sufficient to remove the moisture without damaging the fibres and thus leave the fibres bound together at their mutual contact points.
  • a moisture-activated binder material for example, a material based on a vinyl ester copolymer
  • the pre-bonded web at this stage has a certain minimum thickness.
  • a minimum thickness of 5 mm may be preferred.
  • Step (iii) Applying and bonding abrasive particles to the pre-bonded web
  • any appropriate method can be used to apply and bond abrasive particle to a pre-bonded web produced as described in step (ii) above, having regard to the nature of the pre-bonded web and the abrasive article that is to be produced.
  • Abrasive particles suitable for application to a pre-bonded web include all known abrasive particulate materials as well as combinations and agglomerates of such materials.
  • the abrasive particles may be of any size, from less than one micrometer to 2 mm or greater. Included among the suitable abrasive materials are particles of inorganic materials, for example aluminum oxide including ceramic aluminum oxide, heat-treated aluminum oxide and white-fused aluminum oxide; silicon carbide; tungsten carbide; alumina zirconia; diamond; ceria; cubic boron nitride; silicon nitride; garnet; and combinations of the foregoing. It is contemplated that abrasive agglomerates may also be used, such as those described in U.S. Pat.
  • Suitable abrasive particles also include softer, less aggressive materials such as thermosetting or thermoplastic polymer particles as well as crushed natural products such as crushed nut shells, for example.
  • Suitable polymeric materials for the abrasive particles include polyamide, polyester, poly(vinyl chloride), poly(methacrylic) acid, polymethylmethacrylate, polycarbonate, polystyrene and melamine-formaldehyde condensates. The selection of particle composition and particle size will depend on the contemplated end use of the finished abrasive article, taking into account the nature of the workpiece surface to be treated by the article and the abrasive effect desired.
  • the abrasive particles should have a particle size small enough to allow penetration of the particles into the interstices of the pre-bonded nonwoven web.
  • Chemically-active particles may also be used in combination with the aforementioned abrasive particles, including particles known to be effective as grinding aids such as those comprising poly (vinyl chloride) as well as particles providing effective lubricating properties in the finished article such as those comprising stearates of lithium and zinc, stearic acid and the like.
  • the abrasive particles may be mixed with a liquid binder composition to form a slurry which is then applied to the pre-bonded nonwoven web in any suitable way (for example, by spraying or by roll-coating).
  • the slurry may be applied to one side only of the nonwoven web or to both sides either simultaneously or in turn.
  • the binder composition is then cured to bind the abrasive particles to the fibres of the web.
  • the liquid binder composition may be applied alone to the pre-bonded web (for example, by spraying or by roll-coating) following which the abrasive particles can be drop coated, sprinkled, sprayed, or the like, in a dry condition upon a surface of the web, for example by conveying the web beneath an abrasive particle dispenser.
  • the binder composition is then cured to bind the abrasive particles to the fibres of the web.
  • the abrasive particles may be blended with a powdered resin binder, the blend then being applied in dry form to the pre-bonded nonwoven web.
  • the binder used to bond the abrasive particles to the pre-bonded nonwoven web can be any resin or adhesive known to be suitable for use as a make coat in abrasives manufacture, including water-based resins.
  • make coat compositions suitable for use in the manufacture of nonwoven abrasive materials are described in US-A-5 591 239 , US-A-5 919 549 , EP-A-0 776 733 and WO 01/62442 .
  • Preferred binders include phenolic resins (more especially for harder-wearing abrasive articles) and latex resins (more especially for softer abrasive articles, e.g. non-scratch for bathroom cleaning), and they may contain additives such as fillers, lubricants, grinding aids, wetting agents or surfactants, defoaming agents, and pigments or dyes.
  • a further resin layer may be applied to the web after the abrasive particles have been attached.
  • This optional resin layer also known as a size coat
  • This optional resin layer will serve to consolidate the nonwoven abrasive product and increase its wear resistance.
  • fibres 1 are supplied to web-forming equipment 2, for example a "Rando Webber" machine, to produce a nonwoven fibrous web 3 that is fed into a powder-coating booth 4 where it is contacted by a particulate pre-bond resin 5 supplied from a fluidizing hopper 6.
  • a particulate pre-bond resin 5 supplied from a fluidizing hopper 6.
  • Optional dry particle additives such as pigment powder and flow aids
  • the nonwoven web 3 is conveyed through the powder-coating booth 4 on a metallic open mesh conveyor belt 7 that is electrically-grounded, and the particulate resin is directed at the web from above by an electrostatic powder spray gun 8. Any resin that passes through the web 3 and the conveyor belt 7 is collected at the bottom of the booth 4 and can be re-used.
  • the web 3 can now be turned over and conveyed for a second time through the powder coating booth 4 to increase the amount of resin powder 5 that is loaded into the web at this stage.
  • the powder-containing nonwoven web 9 is then exposed to conditions that will liquefy the resin particles to a flowable condition, following which the resin is cured to form bonds between the web fibres.
  • the web is passed through an oven 10 in which it is heated first to liquefy the resin so that it will coat the web fibres, and then to cure the resin so that it will bond the fibres together at their mutual contact points.
  • the pre-bonded web 11 leaves the oven 10 and is allowed to cool.
  • the pre-bonded web 11 is then passed through a first spray booth 12 in which one surface of the web is sprayed with a slurry 13 of abrasive particles mixed with a liquid make-coat binder resin which is subsequently cured by passing the web through an oven 14.
  • the web then passes through a second spray booth 15 in which the other surface of the web is sprayed with the same abrasive-resin slurry 13.
  • the second resin coating is then cured in a second oven 16.
  • the second spray booth 15 and the second oven 16 are omitted and, instead, the web 11 is turned over when it has left the oven 14 and is conveyed again through the spray booth 12 so that the other side of the web can be sprayed with the slurry 13. The web is then passed for a second time through the oven 14.
  • the resulting nonwoven abrasive web 17 can then be converted (following storage if required) into abrasive articles such as, for example, abrasive pads for hand use or domestic scouring pads as described in our corresponding patent application of even date (applicant's ref. no. 57906GB002).
  • the particulate pre-bond resin 5 may be mixed with the web fibres 1 prior to the formation of the nonwoven web in the web-forming equipment 2.
  • the powder-coating booth 4 is omitted.
  • the powder-coating booth 4 may be replaced by the equipment illustrated in Fig. 2 , comprising a powder scattering unit 20 and a powder impregnation unit 21.
  • the web 3 from the web-forming equipment 2 passes into the unit 20, where the particulate pre-bond resin 5 (together with any optional dry particle additives) is distributed evenly from a dispenser 22 over the upper surface of the web. Any resin that happens to pass through the web is collected at the bottom of the unit 20 and can be re-used.
  • the web then passes into the impregnation unit 21, where it passes between two electrode plates 23 across which an alternating voltage is applied: the effect of this is to distribute the resin powder 5 throughout the thickness of the web, following which the web passes to the oven 10 as in Fig. 1 .
  • Brushes 24, contacting the upper and lower surfaces of the web are located downstream of the impregnation unit 21 to remove any excess resin powder, which.can be collected and re-used.
  • Epoxy resin powder "Beckrypox AF4" low temperature cure black thermoset powder (mean particle size 35 microns) from Dupont of Montbrison, France.
  • Copolyamide resin powder "Vestamelt 350 P1" thermoplastic powder 0-80 microns from Degussa of Marl, Germany.
  • Powder flow aid "Aerosil 200" hydrophilic fumed silica powder from Degussa of Marl, Germany.
  • Nylon 20 dtex staple fiber medium tenacity nylon 6.6 staple fiber type "RT174MT” from Rhodia of Neumunster, Germany.
  • Nylon 80 dtex staple fiber nylon 6.6 staple fiber type "R130” from Rhodia of Arras, France.
  • Sisal fibre cut fibre from Caruso of Ebersdorf, Germany. Coco fibre: cut fibre from Caruso of Ebersdorf, Germany.
  • Poly(vinyl chloride) particles "Etinox 631” from Aiscondel, Spain. Corundum particles: very fine grade (average particle size approximately 50 microns) brown fused aluminium oxide from Pechiney, France.
  • Latex resin "Styrofan ED609” from BASF, Spain.
  • Cross-linking agents (i) Cymel 303 and (ii) Cymel 307 from Dyno Cytec, Norway.
  • Phenolic resin "7983SW” from Bakelite AG of Iserlohn-Letmathe, Germany. Filler: calcium carbonate. Pigment: red or black, as required.
  • Fiber opener from Laroche of Cours La Ville, France
  • "Rando Webber” an air-lay nonwoven web forming machine from Rando Machine Co. of York, NY, USA
  • Web humidifier a water spray head of a type used for room humidification, available from Hydrofog of Chanteloup les Vignes, France.
  • Powder coating equipment "Versaspray II” electrostatic spray gun(s) from Nordson of Westlake, Ohio, USA, installed in a powder coating booth (also available from Nordson) and directed downwards towards a 30cm wide horizontal metallic open mesh conveyor belt, which is electrically-earthed. The/each gun was fitted with a 2.5 mm flat spray nozzle.
  • the powder coating booth was provided with a fluidizing hopper to contain powder (the hopper being fitted with a venturi pump to supply the powder to the gun); a recovery drum to collect waste powder at the bottom of the booth; and an air control unit for regulating the supply of fluidizing air to the hopper, and of flow and atomizing air to the pump and gun(s).
  • the hopper, pump and recovery drum are all available from Nordson.
  • the powder booth incorporated features that enabled the safe handling of fine powders (including air extraction through cartridge and HEPA filters, and a fire detection system).
  • Infra-red oven a "Curemaster Super” oven with three 1 kW short-wave infra-red heaters, available from Trisk of Sunderland, Tyne and Wear, UK
  • Through-air ovens a gas oven (4 meters long) and an electric oven (2 meters long), both available from Cavitec of Munchwilen, Switzerland.
  • Abrasive spray equipment a spray booth equipped with one reciprocating spray gun, available from Charvot of Grenoble, France; and a spray booth equipped with two spray guns, available as Model 21 from Binks Manufacturing Company, of Illinois, USA.
  • Schiefer cut test This test provided a measure of the cut (material removed from a work piece) by an abrasive article under wet conditions.
  • a 10.16 cm diameter circular specimen was cut from the abrasive material to be tested and secured by a pressure-sensitive adhesive to a back-up pad that had been pre-conditioned by soaking in water. The abrasive material was also pre-wetted. The back-up pad was secured to the driven plate of a Schiefer Abrasion Tester (available from Frazier Precision Company. Gaithersburg, Md.), which had been plumbed for wet testing.
  • a 30cm wide air-laid nonwoven web weighing 130 g/m 2 and comprising 20dtex nylon staple fibers was formed on the "Rando Webber" machine at a rate of 2 m/min.
  • the fibre bales had previously been pre-opened using the Laroche fibre opener.
  • the web was conveyed in line on the horizontal metallic open mesh conveyor belt through the powder coating booth, where epoxy resin powder was directed at the web by a single "Versaspray II" spray gun located 30cm above the web.
  • the powder was supplied to the spray gun from the hopper in which it was fluidized until gentle bubbling using air at a pressure of 0.5 bar.
  • the air pressure settings of the spray gun were 2-3 bar for the flow (or primary air) and 1-1.5 bar for the atomizing (or secondary) air and the maximum voltage (100 kV) was applied.
  • Resin powder was deposited in the web at a weight of about 58g/m 2 , and any epoxy resin powder that passed through the web was collected in the recovery drum, positioned underneath the open mesh conveyor belt.
  • the powdered web was then heated in the gas oven at 170°C for 2 min to fuse and cure the resin, using a low speed setting for the recirculating air to avoid dislodging the resin powder.
  • Abrasive particles were then applied to the bonded web in the following manner.
  • An abrasive-resin slurry was prepared by mixing together thoroughly corundum particles (55%), phenolic resin (20%), water (20%), filler (4%) and pigment (1%).
  • the slurry was then transferred to the supply tanks of the spray booth equipped with one reciprocating spray gun.
  • the bonded web was passed through the spray booth at a speed of 2m/min, and one side of the web was sprayed with the slurry at a weight in the range of about 180 - 220 g/m 2 .
  • the web was then passed through the gas oven in which it was heated at 180°C for about 2 minutes to cure the phenolic resin.
  • the web was then turned over and conveyed again through the spray booth and the gas oven with the other surface of the web uppermost.
  • the resulting nonwoven abrasive web was cut into abrasive hand-pads having a dimension of about 150 x 225 mm.
  • Example 1 was repeated with the exception that the air-laid web was formed from a mixture of 20dtex and 80dtex nylon staple fibers (50% of each), and the amount of resin powder deposited on the web was 47 g/m 2 .
  • Example 2 was repeated with the epoxy resin powder replaced by copolyamide resin powder.
  • the flow and homogeneity of the resin powder was improved by adding 0.5% of powder flow aid and by vibrating the hopper using a vibratory table. Fluidizing air was supplied to the hopper at a pressure of 1 bar, and the air pressure settings for the gun were 3 bar for the flow air and 4 bar for the atomizing air.
  • the amount of resin powder deposited on the web was 28 g/m 2 .
  • a 30cm wide air-laid nonwoven web weighing 190 g/m 2 was formed from the sisal fibres on the "Rando Webber" machine at a rate of 2 m/min.
  • the fibre bales had previously been pre-opened using the Laroche fibre opener.
  • the web was conveyed in line through the powder coating booth on the open mesh conveyor belt, where copolyamide resin powder (blended with 0.5% by weight of flow aid) was directed at the web by two "Versaspray II" spray guns, arranged one behind the other, that were fixed 30cm above the web and inclined on opposite sides of the vertical at an angle in the range of 20° - 30°.
  • the resin powder was supplied to the guns from the hopper, in which it was fluidized until gently bubbling using air at a pressure of 1.5 bar.
  • the air pressure settings for the guns were 2 bar for the flow air and 1 bar for the atomizing air, and the maximum voltage (100 kV) was applied.
  • Resin powder was deposited in the web at a weight of about 60 g/m 2 and any resin powder that passed through the web was collected in the recovery drum, positioned underneath the open mesh conveyor belt.
  • the powdered web was then heated in line, first in the infra-red oven at a temperature in the range of 150 - 160°C with the heaters positioned 3 cm above the web to pre-set the resin powder and then in the electric oven at a temperature of 160°C using a low-speed setting for the recirculating air.
  • the total residence time in the oven was 1 min.
  • the web was then turned over and conveyed again through the powder coating booth and the ovens with the other surface of the web uppermost.
  • Poly(vinylchloride) particles were then applied to the bonded web in the following manner.
  • An abrasive-resin slurry was prepared by thoroughly mixing together the particles (25%) and the latex resin (68.5%) with the cross-linking agents (1.2% of (i) and 5.3% of (ii)).
  • the slurry was then transferred to the supply tank of the spray booth having a single spray gun.
  • the bonded web was passed through the spray booth at a speed of 2 m/min, and sprayed on one side with the slurry from the gun which was reciprocated across the web to ensure even coverage of the web with the slurry at a coating weight of about 300 g/m 2 .
  • the web was then passed through the gas oven in which it was heated at 180°C for 2 min. to cure the latex resin.
  • the web was then turned over and conveyed again through the spray booth so that it was sprayed with slurry on the other side in the same manner. It was then again passed through the gas oven.
  • the resulting nonwoven abrasive web contained 150 g/m 2 of the poly(vinyl chloride) particles and was cut into domestic scouring pads having dimensions of about 75 x 90 mm.
  • Corundum particles were then applied to the bonded web in the following manner.
  • An abrasive-resin slurry was prepared by mixing together thoroughly the particles (25%) and the phenolic resin (75%).
  • the slurry was then transferred to the supply tank of the spray booth having four spray guns.
  • the bonded web was passed through the spray booth at a speed of 2 m/min, and sprayed on one side with the slurry from the guns to provide even coverage of the web with the slurry at a coating weight of about 230 - 260 g/m 2 .
  • the web was then passed through the gas oven in which it was heated at 180°C for 2 min. to cure the phenolic resin.
  • the web was then turned over and conveyed again through the spray booth so that it was sprayed with slurry on the other side in the same manner. It was then again passed through the gas oven to yield a nonwoven scouring web which was cut into domestic scouring pads.
  • Samples of the abrasive hand-pads resulting from Examples 1 to 3 were tested for abrasive performance.
  • the results are shown in the following Table together with the results for a reference sample (REF) prepared as described in Example 1 except that the pre-bonded web was prepared using a liquid phenolic resin applied by roll coating, rather than epoxy resin powder applied as described.
  • Samples 1 to 3 had a lower density (i.e. they were more open) than the reference sample because they were about 20% thicker although the initial fiber weights were about the same. This in turn indicates the possibility of producing effective abrasive products using a reduced amount of fibre. Moreover, the more open structure of Samples 1 to 3 means that they will be less likely to become clogged during use. The open structure is considered to be a consequence of the fact that the webs from which the Samples 1 to 3 were made were pre-bonded in a way that did not involve the web being subjected to pressure (e.g. as a result of contact by rollers).
  • Samples of the domestic scouring pads resulting from Examples 4 and 5 were used for cleaning soiled dishes in a simulated domestic environment and, based on a visual assessment, were found to perform at least as well as conventional synthetic scouring pads and, generally, better than traditional scouring pads made from natural fibres.
  • the scouring pads produced by the processes of Examples 4 and 5 offer the advantage that they can more easily be recycled after use since they are formed using natural vegetable fibres. Despite that, the homogeneity of the scouring pads is high compared with traditional natural fibre scourers making it possible to offer, to the consumer, an environmentally-friendly but comparatively standardized product. In addition, the scouring pads exhibit the advantageous openness of both traditional natural fibre scourers and conventional synthetic scourers, together with the abrasive performance of the latter. These advantages are considered to be a consequence of the fact that the scouring pads comprise a mechanically-formed (dry-laid) web of natural fibres which is pre-bonded in a way that does not involve the web being subjected to pressure (e.g. as a result of contact by rollers) that could irreversibly compress or damage the web fibres.
  • VOCs volatile organic compounds

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Polishing Bodies And Polishing Tools (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Claims (11)

  1. Verfahren zur Herstellung eines Schleifmittels, das die Schritte einschließt, in denen
    (I) eine dreidimensionale voluminöse Vliesfaserbahn (3) geformt wird, kontaktiert mit trockenem teilchenförmigem Material, das schmelzbare Bindemittelteilchen (5) einschließt,
    (II) die Bahn (9) Bedingungen ausgesetzt wird, die bewirken, dass die Bindemittelteilchen (5) ein fließfähiges flüssiges Bindemittel bilden, und dann das flüssige Bindemittel verfestigt wird, um Bindungen zwischen den Fasern der Bahn (9) zu bilden und dadurch eine voluminöse vorgebondete Bahn (11) mit mehr als 50 % miteinander kommunizierenden Hohlräumen zu bilden, und
    (III) Schleifteilchen auf die vorgebondete Bahn (11) aufgebracht werden und die Schleifteilchen an die Fasern der vorgebondeten Bahn (11) gebondet werden, um das Schleifmittel bereitzustellen.
  2. Verfahren nach Anspruch 1, wobei Schritt (I) das Formen von Fasern (1) zu einer dreidimensionalen Vliesbahn (3) und danach das Kontaktieren der Bahn (3) mit dem trockenen teilchenförmigen Material, oder
    das Mischen von Fasern (1) mit dem trockenen teilchenförmigen Material und dann das Formen der Mischung zu einer dreidimensionalen Vliesbahn (3) umfasst.
  3. Verfahren nach einem der vorstehenden Ansprüche, wobei die Fasern (1) der Bahn (3, 9, 11, 17) synthetische Fasern oder natürliche Fasern oder Mischungen davon umfassen.
  4. Verfahren nach einem der vorstehenden Ansprüche, wobei die schmelzbaren Bindemittelteilchen (5) wärmehärtbare oder thermoplastische Materialien umfassen.
  5. Verfahren nach einem der vorstehenden Ansprüche, wobei die Bindemittelteilchen (5) auf die Bahn (3) aufgebracht werden, ohne eine Kompressionskraft auf die Bahn (3) anzuwenden.
  6. Verfahren nach einem der vorstehenden Ansprüche, wobei die Bindemittelteilchen (5) unter Einwirkung einer elektrostatischen Kraft über die Gesamtdicke der Bahn (3) abgesetzt werden.
  7. Verfahren nach einem der vorstehenden Ansprüche, wobei eine elektrostatische Ladung an die Bindemittelteilchen (5) angelegt wird, die dann in Richtung der Bahn (3) gelenkt werden, während sich Letztere auf einer elektrisch geerdeten Trägeroberfläche befindet.
  8. Verfahren nach einem der vorstehenden Ansprüche, wobei die Bahn (9) Wärme und/oder Feuchtigkeit ausgesetzt wird, um zu bewirken, dass die Bindemittelteilchen (5) das fließfähige flüssige Bindemittel bilden.
  9. Verfahren nach einem der vorstehenden Ansprüche, wobei die Schleifteilchen durch mindestens ein Herstellungsbeschichtungsbindeharz an die Fasern der vorgebondeten Bahn gebondet werden, beispielsweise ein Harz ausgewählt aus der Gruppe bestehend aus: Latexharzen und Phenolharzen.
  10. Verfahren nach Anspruch 9, wobei das Herstellungsbeschichtungsbindemittelharz in flüssiger Form auf die vorgebondete Bahn (11) aufgebracht wird.
  11. Verfahren nach Anspruch 9 oder Anspruch 10, wobei die Schleifteilchen gleichzeitig mit dem Herstellungsbeschichtungsbindemittelharz auf die vorgebondete Bahn (11) aufgebracht werden.
EP20040749880 2003-04-25 2004-04-08 Verfahren zur herstellung von vliesstoffschleifartikeln mit trockenem körnigem material Expired - Lifetime EP1617973B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0309393 2003-04-25
PCT/US2004/010840 WO2004096494A1 (en) 2003-04-25 2004-04-08 Method of manufacturing nonwoven abrasive articles using dry particulate material

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EP1617973A1 EP1617973A1 (de) 2006-01-25
EP1617973B1 true EP1617973B1 (de) 2015-05-20

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JP (1) JP2006524584A (de)
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WO (1) WO2004096494A1 (de)

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GB0818186D0 (en) * 2008-10-06 2008-11-12 3M Innovative Properties Co Scouring material comprising natural fibres
KR101571668B1 (ko) * 2010-12-30 2015-11-25 생-고뱅 어브레이시브즈, 인코포레이티드 연마 물품용 이미드 가교 바인더
GB2498711B (en) * 2012-01-17 2014-02-26 Gurit Uk Ltd Prepreg for manufacturing composite materials
CN103111957B (zh) * 2012-11-13 2015-05-27 谢泽 一种基于纸与麻布复合作基材的工业砂带
WO2016087936A1 (en) 2014-12-01 2016-06-09 Zenith Epigenetics Corp. Substituted pyridinones as bromodomain inhibitors
US11351653B2 (en) 2016-09-26 2022-06-07 3M Innovative Properties Company Nonwoven abrasive articles having electrostatically-oriented abrasive particles and methods of making same
KR101849237B1 (ko) * 2016-11-15 2018-04-16 엠.씨.케이 (주) 글래스용 세정 브러쉬 및 이의 제조방법
KR102097691B1 (ko) * 2018-08-13 2020-04-07 주식회사 휴비스 팜 섬유가 포함된 부직포
CN109822470A (zh) * 2019-02-27 2019-05-31 昆山佳研磨具科技有限公司 汽车漆面内衬层打磨用百洁布及其生产工艺
CN113145670B (zh) * 2021-05-17 2022-04-08 山东绿钢环保科技股份有限公司 金属板带磨削除鳞系统

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BRPI0409695A (pt) 2006-04-18
EP1617973A1 (de) 2006-01-25
CN1802238B (zh) 2011-11-23
WO2004096494A1 (en) 2004-11-11
CN1802238A (zh) 2006-07-12
ES2545071T3 (es) 2015-09-08
JP2006524584A (ja) 2006-11-02
BRPI0409695B1 (pt) 2015-08-04

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