EP1595620A1 - Verlorene Form Giessverfahren - Google Patents

Verlorene Form Giessverfahren Download PDF

Info

Publication number
EP1595620A1
EP1595620A1 EP05103958A EP05103958A EP1595620A1 EP 1595620 A1 EP1595620 A1 EP 1595620A1 EP 05103958 A EP05103958 A EP 05103958A EP 05103958 A EP05103958 A EP 05103958A EP 1595620 A1 EP1595620 A1 EP 1595620A1
Authority
EP
European Patent Office
Prior art keywords
layer
mullite
layers
particles
solidification
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP05103958A
Other languages
English (en)
French (fr)
Other versions
EP1595620B1 (de
Inventor
Arnaud Biramben
Patrick Calero
Patrick Chevalier
Jean-Christophe Husson
Christian Marty
Patrice Ragot
Pierre Richard
Franck Truelle
Isabelle Valente
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Safran Aircraft Engines SAS
Original Assignee
SNECMA SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SNECMA SAS filed Critical SNECMA SAS
Publication of EP1595620A1 publication Critical patent/EP1595620A1/de
Application granted granted Critical
Publication of EP1595620B1 publication Critical patent/EP1595620B1/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C9/00Moulds or cores; Moulding processes
    • B22C9/02Sand moulds or like moulds for shaped castings
    • B22C9/04Use of lost patterns
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C9/00Moulds or cores; Moulding processes
    • B22C9/12Treating moulds or cores, e.g. drying, hardening

Definitions

  • the present invention relates to the manufacture of parts such as blading complex geometries according to the technique known as lost wax foundry.
  • a model wax or other equivalent material easily removable by the following. If necessary we group together several models into one cluster. We made around this model a ceramic mold by soaking in a first slip to form a first layer of material in contact with its area. Sand the surface of this layer to reinforce and facilitate the hanging of the next layer, and we dry the whole: what constitutes respectively the stuccage and drying operations. We then repeat the soaking operation in slip of possible compositions different, operation always associated with the successive operations of stuccage and drying. Thus, a ceramic shell consisting of a plurality of layers.
  • the slips are composed of particles of ceramic materials, flour, such as alumina, mullite, zircon or the like, with a mineral colloidal binder and adjuvants, if any, depending on the rheology desired.
  • These adjuvants make it possible to control and stabilize characteristics of the different types of layers, while avoiding the effects of different physicochemical characteristics of raw materials constituting the slips. It can be a wetting agent, a plasticizer or a texturizer based, for the latter, the desired thickness for the deposit.
  • the carapace mold is then dewaxed, which is an operation by which eliminates the material constituting the original model. After elimination of the model, we obtain a ceramic mold whose cavity reproduces all the details of the model. The mold then undergoes heat treatment at high temperature or "cooking", which gives it the mechanical properties required.
  • the carapace mold is thus ready for the manufacture of the metal part by casting.
  • the step The next step is to sink a molten metal into the mold cavity and then to the solidify.
  • solidification techniques In the field of lost-wax foundry, there is currently a distinction several solidification techniques, therefore several casting techniques, according to the nature of the alloy and the expected properties of the part resulting from the casting. It may be directed solidification with columnar structure (DS), directed solidification with monocrystalline structure (SX) or solidification equiaxe (EX) respectively.
  • DS columnar structure
  • SX directed solidification with monocrystalline structure
  • EX solidification equiaxe
  • the shell is broken by a shaking operation, and we complete the manufacture of the metal part.
  • shells can be made at through several processes. Each carapace must have properties specific to ensure the desired type of solidification. For example, for equiaxed solidification, several different processes can be one using a silicate binder of ethyl, another using a silica binder colloid. For directed solidification, shells can be made from different fillers, based on silico-aluminous, silica-zircon or silica.
  • the invention achieves these objectives with the following method.
  • the method is characterized by the fact that ceramic particles of the slips comprise a refractory oxide or a a mixture of refractory oxides without zircon, none of the layers comprising zircon.
  • the slip for the formation of the reinforcement layers is much more fluid than the second slip.
  • the binder for different slips is a solution colloidal mineral such as colloidal silica.
  • the stucco grains for the layers of contact, intermediate and reinforcement are made from mullite grains and no zircon.
  • the stuccage operations are carried out with stucco grains covering a size range between 80 and 1000 microns.
  • stucco is preferably applied by dusting to the first layers, and is preferably applied by fluidized bed, for layers from the fourth.
  • Stucco is applied automatically, so that the movements of the robot can make a carapace mold having a porosity after baking, between 20 and 35%. More shell is porous, the more it reduces its sensitivity to thermal shocks such as those products during different types of pouring.
  • the baking cycle of the mold comprises a heating up to a temperature between 1000 and 1150 ° C, preferably between 1030 ° C and 1070 ° C.
  • the first slip can be formed from mullite flours and of alumina without zircon, with or without germinating.
  • the contact is composed mainly of mullite flour in quantity between 40 and 80% by weight, possibly of alumina flour, a binder based on colloidal silica, and organic adjuvants.
  • the contact layer is composed of a mixture of alumina flours and mullite in quantities between 40 and 80% by weight and between 2 and 30% by weight, remainder comprising a binder based on colloidal silica, a germinant, and organic adjuvants.
  • the second and third slip are common to any solidification process, and comprise a mixture of alumina and mullite flours in an amount of between 45 and 95% by weight, and mullite grains in an amount of between 0 and 25% by weight.
  • the mold structure thus defined finds, indifferently, a use for the manufacture of a part with solidification of directed type with a columnar structure, the contact layer being formed mainly from a mullite flour, for the manufacture of a monocrystalline structured type solidification-type part, the contact layer being formed predominantly from a mullite flour or else for producing a piece with equiaxed type solidification, the contact layer being formed from a mixture of alumina flour and mullite.
  • the invention also relates to a method for manufacturing parts by casting molten metal that, irrespective of the type of solidification, directed to columnar structure, directed at monocrystalline or equiaxed structure, molds with a common shell skeleton: intermediate layer and common reinforcement layer.
  • the invention also relates to an installation for the production of parts by casting a molten metal in a shell mold comprising a station of manufacture of molds and casting stations for different solidifications, said stations being fed with molds having reinforcement layers identical.
  • the method of manufacturing shell molds for use common to all types of parts includes a first step of manufacturing the model in wax or other equivalent material known in the field.
  • wax or other equivalent material known in the field.
  • the models are shaped to the dimensions of the final pieces, alloys.
  • the carapace manufacturing steps are preferably carried out by a robot whose movements are common to all types of parts, programmed to have an optimal action on the quality of the deposits made, and to free oneself the geometric aspect of the various blades.
  • slips are prepared in which they are quenched successively the models or the cluster to make a deposit of matter ceramic.
  • layer # 1 contact, once the model removed from the first slip after an immersion phase, the covered model undergoes a dewatering phase then topping. Then, sprinkles of stucco are applied to do not disturb the thin layer of contact.
  • mullite whose granulometry in this first layer is fine. It is between 80 and 250 microns. The surface condition of the pieces in final depends in part.
  • the No. 1 layer is dried.
  • the dipping is then carried out in a second slip to form a layer N ° 2, called intermediate.
  • the composition is the same regardless of the solidification mode adopted.
  • a stucco is deposited by dusting and dried.
  • mullite whose particle size is average. It can be between 120 and 1000 microns.
  • the state of porosity final shells depend in part on it.
  • the model is then quenched in a third slip to form the layer No. 3 which is the first so-called reinforcement layer.
  • the same stucco is then applied to layer 2 by dusting, and dried.
  • the soaking operations are repeated in the third slip, stuccage and drying to form the layers of "reinforcement".
  • the stuccage is carried out by fluidized bed.
  • a glazing operation is performed which does not include a stuccage operation.
  • the carapace in final can consist of 5 to 12 layers.
  • Soak programs are optimized for each type of layer, in order to to overcome the geometrical aspect of the different types of pieces, and are therefore common to all references.
  • the interlayer drying range is optimized for each type of layer, to overcome the geometric aspect of the different types of parts.
  • the range is therefore common.
  • the range allows indeed for each type of layer, a drying of molds with geometries as different as vanes movers, distributors, or structural parts.
  • the baking cycle of molds is the same for all types of solidification, and thus free from the type of room. It includes a rising phase in temperature, a plateau at the cooking temperature and a phase of cooling.
  • the cooking cycle is chosen to optimize the properties mechanical shells so as to allow cold handling without risk of breakage, and in order to minimize sensitivity to thermal shock that can be generated during the different stages of casting.

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Molds, Cores, And Manufacturing Methods Thereof (AREA)
  • Mold Materials And Core Materials (AREA)
EP05103958A 2004-05-12 2005-05-11 Verlorene Form Giessverfahren Expired - Lifetime EP1595620B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0405143 2004-05-12
FR0405143A FR2870147B1 (fr) 2004-05-12 2004-05-12 Procede de fonderie a cire perdue

Publications (2)

Publication Number Publication Date
EP1595620A1 true EP1595620A1 (de) 2005-11-16
EP1595620B1 EP1595620B1 (de) 2011-07-20

Family

ID=34939801

Family Applications (1)

Application Number Title Priority Date Filing Date
EP05103958A Expired - Lifetime EP1595620B1 (de) 2004-05-12 2005-05-11 Verlorene Form Giessverfahren

Country Status (5)

Country Link
US (1) US7318466B2 (de)
EP (1) EP1595620B1 (de)
JP (1) JP4937528B2 (de)
CA (1) CA2507170C (de)
FR (1) FR2870147B1 (de)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2208556A1 (de) * 2009-01-06 2010-07-21 General Electric Company Gussformen zur Verwendung in gerichteten Erstarrungsverfahren und Herstellungsverfahren
FR3071423A1 (fr) * 2017-09-22 2019-03-29 Safran Barbotine de fonderie
RU2774243C2 (ru) * 2017-09-22 2022-06-16 Сафран Литейный шликер
WO2024149952A1 (fr) * 2023-01-12 2024-07-18 Safran Procédé de fabrication d'un moule comprenant des particules fissurantes

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1935530A1 (de) * 2006-12-21 2008-06-25 Siemens Aktiengesellschaft Verfahren zur Herstellung einer keramischen Formschale und Verwendung derselben
JP5178366B2 (ja) * 2008-07-14 2013-04-10 伊藤忠セラテック株式会社 精密鋳造用鋳型製造用スタッコ材及びそれを用いた精密鋳造用鋳型
CN104646633B (zh) * 2013-11-20 2017-06-30 沈阳工业大学 局部可自由伸缩的单晶叶片用复杂结构陶瓷型芯制备工艺
JP6317995B2 (ja) * 2014-05-08 2018-04-25 伊藤忠セラテック株式会社 精密鋳造鋳型製造用スラリーのフィラー材及びそれを用いて得られたスラリー並びに精密鋳造鋳型
JP2016002572A (ja) * 2014-06-18 2016-01-12 伊藤忠セラテック株式会社 精密鋳造鋳型製造用スラリー組成物及びその製造方法
JP6368596B2 (ja) * 2014-09-11 2018-08-01 伊藤忠セラテック株式会社 精密鋳造鋳型製造用スラリー組成物及びその製造方法
FR3068271B1 (fr) 2017-06-29 2021-12-10 Safran Aircraft Engines Procede de fonderie avec coulee en moule chaud
CN108115088B (zh) * 2017-12-23 2020-01-21 青田保俐铸造有限公司 一种石膏复合聚合物粘性砂浆的熔模型壳铸造工艺
FR3085286B1 (fr) 2018-08-28 2021-08-06 Safran Aircraft Engines Procede de fabrication d'une eprouvette a plusieurs couches ceramiques, eprouvette obtenue par la mise en œuvre d'un tel procede de fabrication et utilisation d'une telle eprouvette pour un essai de compression uniaxiale a chaud
FR3103400B1 (fr) 2019-11-21 2022-08-19 Safran Aircraft Engines Moule de fonderie, procede de fabrication du moule et procede de fonderie
FR3145299B1 (fr) 2023-01-27 2025-10-24 Safran Aircraft Engines Moule de fonderie
CN117139559A (zh) * 2023-08-30 2023-12-01 中国机械总院集团沈阳铸造研究所有限公司 一种尺寸稳定的大型陶瓷型壳制作方法
CN117139560A (zh) * 2023-08-30 2023-12-01 中国机械总院集团沈阳铸造研究所有限公司 定向或单晶高温合金熔模铸造用惰性陶瓷型壳制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3859153A (en) * 1970-06-25 1975-01-07 Du Pont Refractory laminate having improved green strength
EP0399727A1 (de) 1989-05-20 1990-11-28 ROLLS-ROYCE plc Keramikwerkstoffe für eine Giessform
US5618633A (en) 1994-07-12 1997-04-08 Precision Castparts Corporation Honeycomb casting
WO2001045876A1 (en) * 1999-12-21 2001-06-28 Howmet Research Corporation Crack resistant shell mold and method

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS51126922A (en) * 1975-04-30 1976-11-05 Hitachi Metals Ltd Investment casting mold
JPH07116773A (ja) * 1993-10-20 1995-05-09 Mitsubishi Heavy Ind Ltd 精密鋳造用鋳型の製造方法
JPH09155503A (ja) * 1995-12-05 1997-06-17 Hitachi Ltd 精密鋳造用鋳型および鋳造方法
JPH09253790A (ja) * 1996-03-27 1997-09-30 Kubota Corp 粉粒体被覆処理用流動槽
US5766329A (en) * 1996-05-13 1998-06-16 Alliedsignal Inc. Inert calcia facecoats for investment casting of titanium and titanium-aluminide alloys
JPH10156484A (ja) * 1996-11-20 1998-06-16 Mitsubishi Heavy Ind Ltd 精密鋳造用鋳型
EP0963262B1 (de) * 1997-01-27 2002-05-02 AlliedSignal Inc. Verfahren zur herstellung eines tiegels mit integriertem form zur preiswerten herstellung von gamma-tial-gussteilen
US6431255B1 (en) * 1998-07-21 2002-08-13 General Electric Company Ceramic shell mold provided with reinforcement, and related processes
JP2000280047A (ja) * 1999-03-31 2000-10-10 Meidensha Corp ロストワックスコーティングシステム
US6582197B2 (en) * 2001-02-22 2003-06-24 Simon E. Coulson Method of investment casting with casting identification
US6648060B1 (en) * 2002-05-15 2003-11-18 Howmet Research Corporation Reinforced shell mold and method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3859153A (en) * 1970-06-25 1975-01-07 Du Pont Refractory laminate having improved green strength
EP0399727A1 (de) 1989-05-20 1990-11-28 ROLLS-ROYCE plc Keramikwerkstoffe für eine Giessform
US5618633A (en) 1994-07-12 1997-04-08 Precision Castparts Corporation Honeycomb casting
WO2001045876A1 (en) * 1999-12-21 2001-06-28 Howmet Research Corporation Crack resistant shell mold and method

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2208556A1 (de) * 2009-01-06 2010-07-21 General Electric Company Gussformen zur Verwendung in gerichteten Erstarrungsverfahren und Herstellungsverfahren
US8307881B2 (en) 2009-01-06 2012-11-13 General Electric Company Casting molds for use in directional solidification processes and methods of making
FR3071423A1 (fr) * 2017-09-22 2019-03-29 Safran Barbotine de fonderie
RU2774243C2 (ru) * 2017-09-22 2022-06-16 Сафран Литейный шликер
US11833579B2 (en) 2017-09-22 2023-12-05 Safran Casting slurry
WO2024149952A1 (fr) * 2023-01-12 2024-07-18 Safran Procédé de fabrication d'un moule comprenant des particules fissurantes
FR3144930A1 (fr) * 2023-01-12 2024-07-19 Safran Procédé de fabrication d'un moule comprenant des particules fissurantes

Also Published As

Publication number Publication date
CA2507170A1 (fr) 2005-11-12
JP2005324253A (ja) 2005-11-24
CA2507170C (fr) 2012-12-11
US20050252634A1 (en) 2005-11-17
FR2870147A1 (fr) 2005-11-18
EP1595620B1 (de) 2011-07-20
US7318466B2 (en) 2008-01-15
JP4937528B2 (ja) 2012-05-23
FR2870147B1 (fr) 2007-09-14

Similar Documents

Publication Publication Date Title
CA2507170C (fr) Procede de fonderie a cire perdue
CN114180945A (zh) 一种陶瓷型芯型壳一体件增材制造方法
CN102962401A (zh) 一种用于钛及钛合金精密铸造的SrZrO3型壳及其制备方法
US6845811B2 (en) Reinforced shell mold and method
CN111299510A (zh) 一种铝合金铸件型壳制备方法
EP1595618B1 (de) Verlorene Wachsform-Giessverfahren mit Kontaktschicht
FR2954193A1 (fr) Procede de fonderie a la cire perdue
KR101755832B1 (ko) 자동차 배기계용 정밀주조부품 제조방법
EP3487649B1 (de) Verfahren zur herstellung einer schalenform
CN1895816B (zh) 失蜡铸造法
FR2666528A1 (fr) Procede de preparation d'un moule de fonderie a partir de mousse alveolaire et barbotines ceramiques utilisees.
WO2021001633A1 (fr) Procede de fabrication d'une piece metallique
CN1895815B (zh) 使用接触层的失蜡铸造法
WO2024149952A1 (fr) Procédé de fabrication d'un moule comprenant des particules fissurantes
FR3071422A1 (fr) Moule carapace en ceramique pour fonderie a la cire perdue
FR3146077A1 (fr) Procédé de réalisation d’un moule carapace pour fabriquer une pièce de turbomachine, telle qu’une aube de turbomachine
FR3160911A1 (fr) Procédé de fabrication d’un moule carapace
FR3125446A1 (fr) Procédé de réalisation d’une préparation réfractaire pour la fabrication d’un moule en céramique, préparation obtenue par ce procédé, procédé de fabrication d’un moule en céramique et moule pour aube de turbomachine obtenu par ce procédé
FR2829410A1 (fr) Isolation thermique des carapaces de fonderie
FR3044569A1 (fr) Procede de fabrication de moules ceramiques pour fonderie a la cire perdue et installation permettant de mettre en oeuvre un tel procede
JP2020156655A (ja) ワックス模型の作製方法
WO2014057904A1 (ja) 精密鋳造用鋳型及びその製造方法
CN112239369A (zh) 一种梯度空心陶瓷型芯及其制备方法
FR2967364A1 (fr) Carapace de moulage a modele perdu et procede de fabrication de cette carapace

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20050511

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU MC NL PL PT RO SE SI SK TR

AX Request for extension of the european patent

Extension state: AL BA HR LV MK YU

AKX Designation fees paid

Designated state(s): DE FR GB

17Q First examination report despatched

Effective date: 20090528

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): DE FR GB

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

Free format text: NOT ENGLISH

REG Reference to a national code

Ref country code: DE

Ref legal event code: R096

Ref document number: 602005029056

Country of ref document: DE

Effective date: 20110908

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20120423

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 602005029056

Country of ref document: DE

Effective date: 20120423

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 11

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 12

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 13

REG Reference to a national code

Ref country code: FR

Ref legal event code: CD

Owner name: SAFRAN AIRCRAFT ENGINES

Effective date: 20170717

REG Reference to a national code

Ref country code: FR

Ref legal event code: CD

Owner name: SAFRAN AIRCRAFT ENGINES, FR

Effective date: 20170717

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20240419

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20240418

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20240418

Year of fee payment: 20

REG Reference to a national code

Ref country code: DE

Ref legal event code: R071

Ref document number: 602005029056

Country of ref document: DE

REG Reference to a national code

Ref country code: GB

Ref legal event code: PE20

Expiry date: 20250510

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GB

Free format text: LAPSE BECAUSE OF EXPIRATION OF PROTECTION

Effective date: 20250510