EP1570495B1 - Elektrisches kabel mit geschäumter halbleitender isolationsabschirmung - Google Patents

Elektrisches kabel mit geschäumter halbleitender isolationsabschirmung Download PDF

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Publication number
EP1570495B1
EP1570495B1 EP02784773A EP02784773A EP1570495B1 EP 1570495 B1 EP1570495 B1 EP 1570495B1 EP 02784773 A EP02784773 A EP 02784773A EP 02784773 A EP02784773 A EP 02784773A EP 1570495 B1 EP1570495 B1 EP 1570495B1
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European Patent Office
Prior art keywords
shield
insulation
foaming agent
insulation shield
chemical foaming
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English (en)
French (fr)
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EP1570495A1 (de
Inventor
Frank L. Kuchta
Stephen H. Foulger
Jason Carden
Chengjun Liu
Andrew Maunder
Alberto Bareggi
Luca Balconi
Cristiana Scelza
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Prysmian SpA
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Prysmian SpA
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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
    • H01B13/06—Insulating conductors or cables
    • H01B13/14—Insulating conductors or cables by extrusion
    • H01B13/142—Insulating conductors or cables by extrusion of cellular material
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/446—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylacetals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/447—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from acrylic compounds
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B9/00—Power cables
    • H01B9/02—Power cables with screens or conductive layers, e.g. for avoiding large potential gradients
    • H01B9/027—Power cables with screens or conductive layers, e.g. for avoiding large potential gradients composed of semi-conducting layers

Definitions

  • the present invention relates to electrical cables, with an improved semiconductive insulation shield and the method of making the same. More specifically, the invention is concerned with an electrical cable with a foamed semiconductive insulation shield which serves as both a cushioning layer and an electrical shield.
  • the foamed semiconductive insulation shield is a closed-cell foamed semiconductive insulation shield.
  • Electric power cables for medium and high voltage typically include a central core electrical conductor of copper or aluminum, an overlaying semiconductive conductor shield, an electrical insulation layer formed over the conductor shield, a semiconductive insulation shield and a metallic shield overlaying the insulation shield.
  • an overall plastic jacket is positioned radially external to said metallic shield.
  • the thickness of each of these layers is determined by voltage rating and conductor size and is specified by industry standards such as those published by the Insulated Conductors Engineering Association (ICEA), the Association of Edison Illuminating Companies (AEIC), and Underwriters Laboratories (UL). Electrical cable performance criteria are specified and tested according to AEIC and ICEA standards.
  • the conductor shield is most often a semiconducting polymer extruded over the electrical conductor.
  • the insulation layer is usually a thermoplastic or thermoset material such as crosslinked polyethylene (XLPE), ethylene-propylene rubber (EPR), or polyvinyl chloride (PVC).
  • the insulation layer may include additives to enhance the life of the insulation. For example, tree retardant additives are often added to XLPE to inhibit the growth of water trees in the insulation.
  • the insulation shield is usually an extrudable semiconducting polymer. The insulation shield must have a smooth interface with the insulation layer and exhibit an acceptably low voltage drop through its thickness and eliminate discharge.
  • the AEIC specifies that the insulation shield must have a volume resistivity of less than 500 ⁇ m (Ohms x meters) at 90° C and 110° C.
  • Insulation shields usually form a layer which is adhered to the insulation layer, or for high voltage cables, bonded to the insulation layer.
  • the metallic shield overlaying the insulation shield may consist of, for example, a lead or aluminum sheath, a longitudinally applied corrugated copper tape with an overlapped seam or welded seam, helically applied wires (i.e. drain wires or concentric neutral wires), or flat copper straps. It is important that the insulation shield be in electrical contact with the metallic shield.
  • U.S. Patent No. 5,281,757 hereinafter the '757 patent
  • U.S. Patent No. 5,246,783 disclose examples of electric power cables and methods of making the same.
  • this tape may be for waterblocking, cushioning, or both. If for cushioning or bedding, this tape most often is employed in conjunction with a metallic shield comprised of lead or aluminum sheaths, copper tape with or without welded seam or with sealed overlap longitudinally applied corrugated copper tapes as in the heretofore referenced '757 patent.
  • the cushioning effect of the tape layer eases the pressure on the metallic shield due to the expansion and contraction of the electrical cable core resulting from varying load cycles on the cable.
  • the use of cushioning or bedding layers are known under concentric neutral wire metallic shields; however, due to the expansion and contraction of the electrical cable core, the concentric neutral wires often indent the insulation shield.
  • US Patent No. 4,145,567 to Bahder discloses an electric power cable which employs a semiconducting compressible layer of closed-cell foamed plastic extruded over the insulation shield and under a metallic shield comprised of a longitudinally folded tape with bonded or welded overlap seam.
  • a semiconducting compressible layer of closed-cell foamed plastic extruded over the insulation shield and under a metallic shield comprised of a longitudinally folded tape with bonded or welded overlap seam.
  • the compressible layer between the insulation shield and the inside surface of the metal shield accommodates the expansion of the core by decreasing in radial thickness.
  • the compressible layer expands again, so that it maintains contact with the cable core and the metal shield at all times.
  • the pressure exerted by the compressible layer against the insulation shield and the metallic shield is sufficient to prevent any flow of fluid lengthwise of the cable if the metal shield becomes punctured by lightening or other cause.
  • Examples given for Bahdcr's compressible layer are EPR which is either semiconducting when used with a copper metallic shield or filled with high dielectric constant fillers such as titanium dioxide, barium titanate, or magnesium zirconate.
  • the compressible layer disclosed by Bahder functions as a cushioning layer which is used in electric cable constructions in addition to an insulation shield.
  • Another example of a cable with a semiconductive cushion tape is disclosed in JP11167822 .
  • a semiconductive foamed layer could be used as an insulation shield without running the risk that electrical failures (e. g. partial discharges) can occur.
  • said foamed, i. e. compressible, layer could be used as both an insulation shield and a cushioning layer suitable for elastically and uniformly absorbing the radial forces of expansion and contraction of the cable due to thermal cycles thereof during use.
  • the Applicant found an improved electrical power cable, preferably for medium or high voltage applications, as set out in claim 1.
  • a metallic shield overlies the foamed insulation shield.
  • the foamed semiconductive insulation shield is a closed-cell foamed semiconductive insulation shield.
  • the foamed insulation shield serves as both an insulation shield and a cushioning or compressible layer.
  • a cushioning layer is provided by the insulation shield itself to compensate for the expansion and contraction of the cable core with varying loads, thereby eliminating the need for separate tapes or cushion layers.
  • the entire insulation shield is compressible, there will be less void to fill compared to conventional insulation shields during splices and terminations. That is, accessory reliability enhancement is achieved because the foamed insulation shield will conform to the splice/termination sleeve such that only a small void remains between the sleeve and the insulation shield. This small void is easier to fill. This significantly decreases the likelihood of failure due to partial discharge and eventual erosion of the insulation layer.
  • the foamed insulation shield of the present invention can also be used under concentric neutral wires to eliminate insulation layer indent. Because the foamed insulation shield of the present invention is the same thickness as conventional insulation shields, less material is used in its manufacture and therefore the cost of the insulation shield is significantly less than conventional insulation shields. Additionally, because the foamed insulation shield of the present invention comprises the entire insulation shield, the additional manufacturing steps of applying tape layers, cushioning or compressible layers over the conventional insulation shield are eliminated.
  • the invention has numerous advantages and applications. Therefore, it is one object of the present invention to provide an electrical power cable which incorporates a foamed insulation shield which functions not only as an insulation shield but also as a cushioning layer which allows for expansion and contraction of the cable core during cable load cycles without putting undue stress on the metallic shield or on the underlying insulation layer.
  • a separate cushioning layer such as semiconducting tape
  • FIG. 1 is an illustration of an electric power cable of an embodiment of the present invention incorporating the foamed insulation shield under a metallic shield;
  • FIG. 2 is an optical micrograph of a cross-section of the foamed insulation shield of an embodiment of the present invention made using an exothermic foaming agent and a catalyst, when the nitrogen pressure used during manufacturing was approximately 930kPa (135 psi);
  • FIG. 3 is a graph showing the distance/temperature profile of the continuous vulcanization (CV) tube in Example 2;
  • FIG. 4 is an optical micrograph of a cross-section of the foamed insulation shield of an embodiment of the present invention made using a hybrid exothermic/endothermic foaming agent, cured in a steam CV tube;
  • FIG. 5 is a graph showing the distance/temperature profile of the CV tube in Example 3.
  • FIG 6 is an illustration of a cable splice depicting a void space between the termination sleeve and a conventional insulation shield
  • FIG. 7 is an illustration of a cable splice depicting the reduced void space between the termination sleeve and the insulation shield of an embodiment of the present invention.
  • a shielded electrical cable 10 of an embodiment of the present invention comprises an electrical central core conductor 12, an overlaying conductor shield 14, at least one insulation layer 16 formed over the conductor shield, a closed Ge4 foamed semiconductive insulation shield 18 formed over and adhered to the insulation layer 16, and an outer metallic shield 22.
  • an overall plastic jacket (not shown) is included.
  • the central core conductor 12 may be a solid conductor as shown or it may be stranded.
  • the core conductor is preferably of aluminum or copper.
  • the overlaying conductor shield 14 is preferably a semiconducting crosslinked polymer. Suitable conductor shields arc available from many commercial sources as would be known to one skilled in the art.
  • the insulation layer 16 is preferably an XLPE, a tree retardant XLPE (TRXLPE), an EPR, or an EPDM, all of which are crosslinked insulations, and are commercially available in the industry.
  • the metallic shield 22 may be a solid or bonded metallic layer of lead or aluminum or it may be a longitudinally folded copper or aluminum tape with an overlap seam welded or sealed with an adhesive which allows the overlap seam to move with variations in temperature as described in the '757 patent.
  • the metallic shield might also be helically applied concentric neutral wires and/or copper tape.
  • the overall plastic jacket (not shown) is preferably an insulative thermoplastic polymer, for example, polyvinyl chloride (PVC) or a polyethylene (PE).
  • the foamed semiconductive insulation shield 18 is preferably comprised of a base material, which may advantageously be one of a number of commercially available materials marketed for insulation shield applications, such as LE-315A supplied by Nova Borealis or HFDA-0693 or HFDC-0692 supplied by Union Carbide Corporation. It is preferable that the base material be comprised of a crosslinkable ethylene acetate such as ethylene vinyl acetate (EVA), ethylene butyl acetate (EBA), or ethylene ethyl acetate (EEA), with other additives such as processing aids, secondary resins, and chemical crosslinking agents and aids.
  • EVA ethylene vinyl acetate
  • EBA ethylene butyl acetate
  • EOA ethylene ethyl acetate
  • the insulation shield base material must be filled with a conductive filler, such as carbon black, preferably in an amount from about 20% to about 40% by weight, or in any event, in an amount sufficient for the insulation shield to exhibit a volume resistivity of less than about 500 ⁇ m.
  • a conductive filler such as carbon black
  • the insulation shield is foamed, in general, by adding a chemical foaming agent to the base material prior to extrusion of the base material onto the insulation layer.
  • the insulation shield is foamed such that the density reduction of the insulation shield is between about 10% to about 40%. Less than about 10% density reduction does not provide many benefits. Greater than about 40% density reduction, depending on the materials employed, usually will result in a degradation of material properties needed for an insulation shield for electrical cables.
  • the chemical foaming agent is activated by heat from a continuous vulcanization (CV) process.
  • the chemical foaming agent decomposes, releasing a gas, and thereby foams the insulation shield base material.
  • the chemical foaming agent is selected such that its activation or decomposition temperature is greater than the extrusion temperature so that decomposition of the foaming agent occurs after extrusion and substantially simultaneous with the crosslinking of the .conductor shield, the insulation layer and the insulation shield, as will be described in more detail hereinafter.
  • the chemical foaming agent may be of the endothermic or exothermic type or a hybrid endothermic/exothermic agent.
  • the chemical foaming agents may be added directly to the insulation shield base material and mixed before extrusion, or more preferably the chemical foaming agents are supplied in a masterbach with a compatible carrier resin, preferably an EVA, an EBA, or an EEA and mixed with the insulation shield base material in an amount of from about 1% to about 8% by weight of the insulation shield base material when mixed. It is important that the chemical foaming agent be well dispersed in the insulation shield base material. Good dispersion is dependent on the mixing and extrusion equipment and the relative melt flow indices (MFI) of the chemical foaming agent masterbach and the insulation shield base material.
  • MFI melt flow indices
  • good dispersion of the chemical foaming agent in the insulation shield base material was achieved in a 120 mm diameter extruder with a length to diameter ratio of 20:1 utilizing a Barrier Flight Mixing Screw and a chemical foaming agent masterbach resin with an MFI greater than that of the insulation shield base material.
  • good dispersion is both a function of shear rates in the mixer and relative viscosities of the components.
  • exothermic foaming agent may depend on the selection of the base material for the insulation shield and compatibility therewith, extrusion profiles and processes, CV process and parameters, the desired amount of foaming, cell size, and structure, as well as other design considerations particular to the cable being produced.
  • exothermic chemical foaming agents will reduce density the most and produce a foam with larger cells.
  • Endothermic foaming agents produce foams with a finer cell structure. This is a result, at least in part, of the endothermic foaming agent releasing less gas and having a better nucleation controlled rate of gas releases than an exothermic foaming agent.
  • the resulting foam will have an increase in the number of voids but a decrease in the size of the voids. This may, in some systems, provide a smoother interface between the insulation shield and the insulation layer.
  • Use of hybrid foaming agents results in a lower gas yield than an exothermic foaming agent and, therefore, smooth surfaces and a finer cell structure are produced while at the same time retaining some of the benefits of an exothermic foaming agent.
  • foaming agents which may be used include CELOGEN® OT from Uniroyal Chemical, an exothermic foaming agent; azodicarboamide, an exothermic foaming agent; or one of the following foaming agents marketed by Clariant of Winchester, VA: HYDROCEROL® BIH 40 E, an endothermic foaming agent; HYDROCEROL® CT1267, a hybrid exothermic/endothermic foaming agent; HYDROCEROL® CT1271, a hybrid exothermic/endothermic foaming agent; HYDROCEROL® CT1555, a hybrid exothermic/endothermic foaming agent; HYDROCEROL® CT1557, a hybrid exothermic/endothermic foaming agent; HYDROCEROL® CT1376, an exothermic foaming agent; and HYDROCEROL® CT1542, an exothermic foaming agent.
  • CELOGEN® OT from Uniroyal Chemical
  • an exothermic foaming agent an exothermic foaming agent
  • a catalyst material may be included in the masterbach, especially when employing an exothermic foaming agent.
  • the catalyst material may be used to adjust the decomposition temperature of the foaming agent.
  • a suitable catalyst material is BIK® OT (registered trademark of Uniroyal Chemical).
  • the interface between the foamed semiconductive insulation shield and the insulation layer is preferably substantially void-free.
  • the foamed semiconductive insulation shield preferably has a closed-cell structure so as not to provide channels for water propagation between the insulation layer and the insulation shield, for mechanical strength, to ensure electrical continuity, and to assist in forming a skin 24 at the interface between the insulation shield 18 and the insulation layer 16 as open cells or voids at the interface may result in partial discharge and erosion of the insulation layer.
  • the choice of chemical foaming agent, carrier, and processing conditions significantly affect the formation of the skin or the smoothness of this interface also.
  • An electrical central core conductor is advanced on a conventional cable extrusion line through an extrusion crosshead.
  • a semiconductive conductor shield is extruded onto the electrical conductor.
  • a crosslinkable insulation layer is extruded onto the conductor shield.
  • a crosslinkable insulation shield material having a chemical foaming agent incorporated therein is extruded over the insulation layer.
  • the conductor shield, the insulation layer and the insulation shield material are triple-extruded.
  • the conductor shield is extruded separately, and the insulation layer and insulation shield are co-extruded.
  • the chemical foaming agent and the extrusion temperature are selected so that the decomposition temperature of the chemical foaming agent is greater than the extrusion temperature.
  • the electrical cable is advanced into a conventional CV tube.
  • the CV tube is at an elevated temperature to supply heat in order to activate the crosslinking agents in the conductor shield, the insulation layer and in the insulation shield material.
  • the heat of the CV tube must be sufficient to both crosslink the conductor shield, the insulation layer and insulation shield and to decompose the chemical foaming agent.
  • the Applicant has found that the distance/time that the insulation shield material is maintained above the decomposition temperature in the CV tube is an important parameter for obtaining the desired density reduction (and possibly surface quality) in the insulation shield due to foaming.
  • the Applicant has found that when the insulation shield attains a temperature in the CV tube just above the foaming agent's decomposition temperature, the density reduction of the insulation shield due to foaming was increased from a 5% reduction to a 26% reduction by increasing the time the shield was kept above the decomposition temperature by about 1.5 times, from. 5.8 minutes to 8.6 minutes.
  • the Applicant has found that reducing the decomposition temperature of the foaming agent, decreasing the line speed to increase this time, or alternating the temperature profile of the CV tube to increase this time, will each aid in obtaining the desired density reduction.
  • the decomposition temperature may be around 200°C [ ⁇ 390°F] (or significantly less such as about 160°C [ ⁇ 320°F] depending on the foaming agent used)
  • many of the foaming agents suitable for the present invention have a recommended processing temperature range of 210°C to 240°C [ ⁇ 410°F to 464°F] (or more, again depending on the foaming agent used) to achieved optimum gas yield.
  • the CV tube In a dry cure CV line, the CV tube is usually at a temperature of about 400°C [750°F] and pressurized with nitrogen gas to about 930 kPa (135 psi) to about 1034 kPa (150 psi). In a steam-cure CV line, the CV tube is pressurised with saturated steam to a range of about 1379 kPa (200 psi) to about 1793 kPa (260 psi) at a temperature of about 193°C [380°F] to about 210°C [410°F].
  • the CV tube is electrically heated to about 380°C [715°F] with the tube pressurized with steam to about 1034 kPa (150 psi) to about 1379 kPa (200 psi).
  • the CV tubes are pressurized in order to prevent foaming of the insulation layer due to the decomposition of the crosslinking agent when crosslinking.
  • foaming the insulation shield in the CV line is counterintuitive.
  • the chemical foaming agent decomposition, crosslinking, and foaming of the insulation shield occur in the CV tube substantially concurrently.
  • the decomposition of the foaming agent is preferably complete before the crosslinking of the insulation shield is complete.
  • the cable is then cooled and a metallic shield may be applied either on the same manufacturing line or, most often, in a separate operation.
  • foaming of polymers is done at ambient pressure or in a vacuum.
  • decomposition of the chemical foaming agent under the high pressure of the CV tubes as in the present invention is unique in the art.
  • the foamed insulation shield could be applied over the insulation layer in a separate extrusion operation, thereby eliminating the complications of decomposing the chemical foaming agent under the pressure of the CV tube, this separate additional extrusion step would increase the cost of manufacturing, could promote defects at the insulation layer/insulation shield interface, and defeat one of the objects of the present invention; that is, to provide an electrical power cable which incorporates an insulation shield that also functions as a cushioning layer, thus decreasing the cost of the cable and eliminating a process step in cable manufacture.
  • the preferred insulation shield material (as used In Examples 1-4.) is an EVA-based material having a primary resin of EVA with a 45% vinyl acetate (VA) content in an amount of about 45% to about 55% by weight of the insulation shield material.
  • a secondary resin of nitrile rubber (NBR) with an acrylonitrile (ACN) content of about 33% in the amount of about 10-20% by weight is included.
  • Carbon black in an amount sufficient to make the insulation shield material semiconductive, typically about 20-40%, is included.
  • Other additives, typical to insulation shield materials such as antioxidants, processing aids and crosslinking agents in amounts less than about 5% each are also included.
  • Example 1 exhibited a density reduction of 32% and 20% respectively.
  • Example 1 was further processed by helically applying six No. 14 AWG copper concentric neutral wires and extruding over these wires an overall plastic jacket. It was observed that the concentric neutral wires created an indent in the foamed insulation shield; however, importantly, the indent did not transfer through to the insulation layer. Further, upon application of heat, the indent disappeared.
  • FIG. 2 is cross-sectional view of the foamed insulation shield 18 of Example 1, which shows more closely the closed-cell structure of the foamed insulation shield 18 and the "skin" 24 which formed at the insulation shield / insulation layer interface.
  • the foamed insulation shield of Example 1 included a catalyst in order to lower the start of decomposition of the chemical foaming agent by approximately 15 °C (27 °F), from about 190 °C (374 °F) to about 175 °C (347 °F).
  • the results of lowering the decomposition temperature of the foaming agent in Example 1 demonstrates the importance and relationship between the decomposition temperature of the foaming agent and the process conditions in the CV curing tube in obtaining a satisfactory foamed insulation shield.
  • Example 1 The cable of Example 1 was subjected to the standard qualification testing for electric power cable performance as specified by AEIC. These tests included: volume resistivity, high voltage time testing analysis (HVTT), and partial discharge (PD) analysis.
  • Example 1 passed the AEIC specification for volume resistivity, with a value of 2 ⁇ m at 90°C and 0.45 ⁇ m at 110°C, well within the AEIC requirement of ⁇ 500 ⁇ m at 90°C and 110°C.
  • the cable of Example 1 also passed the AEIC specification for HVTT, with a value of 700 volts/mil (V/mil) unconditioned and 1200 V/mil after conditioning at 100 hours at 90°C.
  • the AEIC specification for partial discharge is: PD ⁇ 5 picocolumbs (pC) at 4Vg (4 times the rated voltage to ground).
  • Example 1 had an inception level of PD at 20kV and at 4Vg (in this case 35kV) of 5 pC.
  • the cable of Example 2 was observed to have superior surface quality.
  • the foamed insulation shield of the cable of Example 2 was subjected to testing for insulation shield physical properties at original and aged 7 days at 121°C and 136°C; hot creep/set at 150°C; bond strength at ambient temperature, -10°C, and +40°C; and field strippability at +40°C.
  • the results of these tests demonstrated that the insulation shield of Example 2 met and/or exceeded applicable AEIC/ICEA industry specifications.
  • FIG. 3 shows the distance / temperature profile of the CV tube for Example 2. It can be seen that the insulation shield obtained a temperature above the decomposition temperature of the foaming agent for about 55 meters, or 3.33 minutes, based on the linespeed of approximately 274 mm/s (54 fpm) in Table 1. The time the insulation shield was in the recommended working range of the foaming agent for optimum gas yield was about 1.2 minutes. Lengthening this time by reducing the decomposition temperature of the foaming agent with the addition of a catalyst, slowing down the linespeed, or by increasing the temperature of the latter heating zones of the tube would all help increase the density reduction if desired.
  • a semiconductive insulation shield according to an embodiment of the present invention employing a hybrid exothermic / endothermic chemical foaming agent, was extruded along with a conductor shield and an insulation layer onto No. 1/0 A WG conductor (approximate equivalent of 53.49 mm 2 metric conductor), and foamed and crosslinked in a steam environment at elevated temperature and pressure.
  • Table 2 gives the formulations and process conditions for Example 3.
  • Table 2 (Original) Example Foaming Agent/Type Insulation Shield Composition Insulation CV Curing Process Conditions Linespeed (fpm) 3 Hydrocerol CT1271 Hybrid: Endothermic/ Exothermic Decomp.
  • EVA Base Resin and additives carbon black, chemical crosslinking agent, processing aids
  • CT 1271 70% Active content in EVA carrier
  • EPR Steam at approximately 1400kPa (203 psi) and tube temperature zones 1.4 at 380°C 33-53
  • Example 3 achieved a density reduction of about 28% and had very good surface quality. When tested for partial discharge according to AEIC requirements, Example 3 exhibited less than 2pC at 52 kV, which meets AEIC standards. Example 3 demonstrates that the gained insulation shield of the present embodiment may be achieved on steam cure CV lines.
  • Fig. 4 shows in cross-section the cell structure and skin of the foamed insulation shield of the present example.
  • Fig. 5 shows the distance / temperature profile of the CV tube for Example 3. It is noted that the insulation shield was just above (200°C) the decomposition temperature of the foaming agent (190 °C) for 11.6 minutes, based on the linespeed in Table 2, resulting in a 28% density reduction of the insulation shield.
  • a semiconductive insulation shield according to an embodiment of the present invention employing a hybrid exothermic / endothermic chemical foaming agent, was extruded along with a conductor shield and insulation layer onto No. 1/0 AWG conductor, and foamed and crosslinked in a N 2 environment at elevated temperature and pressure.
  • Table 3 gives the formulations and process conditions for Example 4.
  • Table 3 (Original) Example Foaming Agent/Type Insulation Shield Composition Insulation CV-Curing Process Conditions Linespeed (fpm) 4 Hydrocerol CT1271 Hybrid: Endothermic/ Exothermic Decomp.
  • EVA Base Resin and additives carbon black, chemical crosslinking agent, processing aids: 4% by weight CT 1271 (70% Active content in EVA carrier) EPR N 2 at 135 psi and tube zone temperature 725/725/700/700/ 675/650°F 35
  • Table 3 Example Foaming Agent/Type Insulation Shield Composition Insulation CV Curing Process Conditions Linespeed (mm/s) 4 Hybrid; Endothermic/ Exothermic Decomp.
  • the foamed insulation shield of Example 4 achieved a density reduction of about 32%.
  • the cable of Example 4 was tested according to AEIC requirements and successfully complied with those requirements.
  • the tested cable passed wafer boil testing as specified in AEIC Standard CS6-94 Section G. 2 which indicated the foamed insulation shield had been effectively crosslinked.
  • the electrical testing data of the cable all met the AEIC specifications including those from the alternating current (AC) withstand, partial discharge, dissipation factor, hot impulse, and volume resistivity at room temperature, 90°C and 130°C.
  • the cable of Example 4 experienced the same CV tube distance/temperature profile as shown in FIG. 3 for Example 2. However, because of the slower linespeed of the present example, the insulation shield was above the decomposition temperature of the foaming agent for 5.1 minutes and in the high end of the working temperature range of the foaming agent for almost 2 minutes.
  • a semiconductive insulation shield according to an embodiment of the present invention employing an endothermic chemical foaming agent, was extruded along with a conductor shield and insulation layer onto No. 1/0 AWG conductor, foamed and crosslinked in a nitrogen gas environment at elevated temperature and pressure.
  • Table 4 gives the formulations and process conditions for Example 5.
  • HFDC-0692 available from Union Carbide, was used as the base material for the insulation shield.
  • the foamed insulation shield of Example 5 achieved a density reduction of about 10% and had good surface quality.
  • This example shows how the use of a purely endothermic foaming agent does not result in as great a density reduction of the insulation shield with similar active content of chemical foaming agent.
  • the cable of the embodiment of the present invention with a foamed insulation shield enhances accessory reliability as illustrated in FIGS. 6 and 7 .
  • a large void area 45 between the insulation layer 16 and the splice or termination sleeve 40 results as the insulation shield 30 has compression resistance.
  • These large voids are normally filled with grease; however, it is difficult to fill the void completely. Because of this, the voids can potentially cause failure of the termination or splice due to partial discharge which will eventually erode the insulation.
  • foamed insulation shield 18 of the present embodiment as illustrated in FIG.
  • the insulation shield 18 compresses under the sleeve 40 when terminating or splicing the cable 10 and will substantially conform to the sleeve 40. Therefore, a significantly smaller void area 48 between the insulation layer 16 and the sleeve 40 results. This small void is more easily filled and requires less grease.
  • the ability of the foamed insulation shield 18 to deform under pressure, such as that pressure which results from sleeve 40, allows enhanced reliability of terminations and splices to cables of the present invention.

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  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Insulated Conductors (AREA)
  • Insulation, Fastening Of Motor, Generator Windings (AREA)

Claims (28)

  1. Elektrisches Stromkabel (10), umfassend:
    einen Leiter (12)
    eine halbleitende Leiterabschirmung (14), die den Leiter (12) überzieht;
    eine quervernetzte Isolationsschicht (16), die über der Leiterabschirmung (14) gebildet ist;
    dadurch gekennzeichnet, dass
    eine geschäumte quervernetzte halbleitende Isolationsabschirmung (18) über der Isolationsschicht (16) positioniert ist und an diese gebunden ist.
  2. Elektrisches Stromkabel (10) gemäß Anspruch 1, worin die Grenzfläche zwischen der Isolationsschicht (16) und der geschäumten Isolationsabschirmung (18) im wesentlichen frei von Leerräumen ist.
  3. Elektrisches Stromkabel (10) gemäß Anspruch 1, worin die geschäumte Isolationsabschirmung (18) eine geschlossenzellige Struktur hat.
  4. Elektrisches Stromkabel (10) gemäß Anspruch 1, das weiterhin eine metallische Abschirmung (22) umfasst, die die geschäumte Isolationsabschirmung (18) überzieht.
  5. Elektrisches Stromkabel (10) gemäß Anspruch 1, worin die geschäumte Isolationsabschirmung (18) aus einer schäumbaren zusammensetzung gebildet ist, die ein chemisches Schäummittel mit einer Zersetzungstemperatur größer als einer Extrusionstemperatur umfasst, und worin das chemische Schäummittel aus der Gruppe ausgewählt ist, die aus exothermen Schäummitteln, endothermen Schäummitteln und hybriden exothermen/endothermen Schäummitteln besteht.
  6. Elektrisches Stromkabel (10) gemäß Anspruch 3, worin die Isolationsabschirmung (18) ein Basismaterial umfasst, das ein quervernetzbares Ethylenacetat umfasst, das der Gruppe ausgewählt ist, die aus EVA, EBA und EEA besteht.
  7. Elektrisches Stromkabel (10) gemäß Anspruch 6, worin das chemische Schäummittel einen Masterbach umfasst.
  8. Elektrisches Stromkabel (10) gemäß Anspruch 7, worin der Masterbach einen Träger ausgewählt aus der Gruppe, die aus EVA, EBA und EEA besteht und ein aktives chemisches Schäummittel umfasst.
  9. Elektrisches Stromkabel (10) gemäß Anspruch 8, worin der Träger einen Schmelzflussindex (MFI) hat, der größer als der der Tsolationsabschirmung (18) ist.
  10. Elektrisches Stromkabel (10) gemäß Anspruch 7, worin das chemische Schäummittel etwa 1 Gew.% bis etwa 8 Gew.% der Isolationsabschirmung (18) ausmacht.
  11. Elektrisches Stromkabel (10) gemäß Anspruch 1, worin das Schäumen der Isolationsabschirmung (18) eine etwa 10%ige bis etwa 40%ige Reduzierung der Dichte der Isolationsabschirmung (18) verursacht.
  12. Verfahren zur Herstellung eines elektrischen Stromkabels (10) gemäß Anspruch 1, umfassend:
    Fördern eines elektrischen Leiters (12) durch ein Extrusionskopfteil;
    Extrudieren einer hableitenden Leiterabschirmung (14) über den elektrischen Leiter (12);
    Extrudieren eine quervernetzbaren elektrischen Isolationsschicht (16) über die Leiterabschirmung (14);
    Extrudieren eines halbleitenden, quervernetzbaren Isolierungsabschirmungsmaterials (18), das ein chemisches Schäummittel enthält, über die Isolationsschicht (16);
    Erwärmen der Leiterabschirmung (14), der Isolationsschicht (16) und der Isolationsabschirmung (18) auf eine Temperatur gleich oder größer als die Zersetzungstemperatur des chemischen Schäummittels, um das chemische Schäummittel zu zersetzen;
    Quervernetzen des Isolationsabschirmungsmaterials (18);
    Quervernetzen der Isolationsschicht (16);
    Quervernetzen der Leiterabschirmung (14); und
    Schäumen der Isolationsabschirmung (18).
  13. Verfahren gemäß Anspruch 12, worin das chemische Schäummittel eine Zersetzungstemperatur und einen Verarbeitungstemperaturbereich hat.
  14. Verfahren gemäß Anspruch 13, worin der Extrusionsschritt bei einer Temperatur durchgeführt wird, die geringer als die Zersetzungstemperatur des chemischen Schäummittels ist.
  15. Verfahren gemäß Anspruch 12, worin der Erwärmungsschritt bei einem größeren Druck als dem Atmosphärendruck durchgeführt wird.
  16. Verfahren gemäß Anspruch 12, worin das chemische Schäummittel eine Zersetzungstemperatur und einen Verarbeitungstemperaturbereich hat, die Extrusion bei einer Temperatur durchgeführt wird, die geringer ist als die zersetzungstemperatur des chemischen Schäummittels; und
    das Erwärmen der Leiterabschirmung (14), der Isolationsschicht (16) und der Isolationsabschirmung (18) bei einem Druck größer als dem Atmosphärendruck durchgeführt wird.
  17. Verfahren gemäß Anspruch 12 oder 16, weiterhin umfassend: Abkühlen des elektrischen Stromkabels (10) nach dem Schäumungsschritt.
  18. Verfahren gemäß Anspruch 17, weiterhin umfassend:
    Aufbringen einer metallischen Abschirmung (22) über die geschäumte Isolationsabschirmung (18) nach dem Abkühlungsschritt.
  19. Verfahren gemäß Anspruch 15 oder 16, worin der Erwärmungsschritt bei einem Druck größer als etwa 930 kPa (135 psi) durchgeführt wird.
  20. Verfahren gemäß Anspruch 13 oder 16, worin das chemische Schäummittel ein exothermes Schäummittel ist und worin das Isolationsabschirmungsmaterial (18) weiterhin einen Katalysator umfasst, der die Zersetzungstemperatur des chemischen Schäummittels herabsetzt.
  21. Verfahren gemäß Anspruch 12 oder 16, worin der Erwärmungsschritt bei etwa 316°C (600 F) bis etwa 399°C (750°F) durchgeführt wird.
  22. Verfahren gemäß Anspruch 12, worin der Erwärmungsschritt bei mehr als etwa 188°C (370°C) durchgeführt wird.
  23. Verfahren gemäß Anspruch 12 oder Anspruch 16, worin die drei Extrusionsschritte gleichzeitig durchgeführt werden.
  24. Verfahren gemäß Anspruch 12 oder 16, worin die drei Quervernetzungsschritte und der Schäumungsschritt im wesentlichen gleichzeitig durchgeführt werden.
  25. Verfahren gemäß Anspruch 13 oder 17, worin die Isolationsabschirmung (18) beim Erwärmungsschritt über mindestens etwa 1 Minute im Verabreitsungstemperaturbereich des Schäummittels gehalten wird.
  26. Verfahren gemäß Anspruch 12, worin das chemische Schäummittel nach der Extrusion der Isolationsaabschirmung (18) auf die Isolationsschicht (16) bei einem Druck größer als dem Atmosphärendruck zersetzt wird.
  27. Verfahren gemäß Anspruch 26, worin das chemische Schäummittel ein exothermisch Schäummittel ist und worin der Druck größer oder gleich etwa 930 kPa (135 psi) ist.
  28. Verfahren gemäß Anspruch 27, worin vor der Extrusion auf die Isolierungsschicht (16) ein Katalysator zur Isolationsabschirmung (18) hinzugefügt wird.
EP02784773A 2002-12-11 2002-12-11 Elektrisches kabel mit geschäumter halbleitender isolationsabschirmung Expired - Lifetime EP1570495B1 (de)

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PCT/US2002/039416 WO2004053896A1 (en) 2002-12-11 2002-12-11 Electrical cable with foamed semiconductive insulation shield

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EP1570495A1 EP1570495A1 (de) 2005-09-07
EP1570495B1 true EP1570495B1 (de) 2011-05-11

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NZ565048A (en) 2005-07-15 2010-06-25 Prysmian Cavi Sistemi Energia Cable having expanded, strippable jacket
JP5420663B2 (ja) * 2009-07-07 2014-02-19 株式会社フジクラ 発泡電線及びこれを有する伝送ケーブル
ES2720524T3 (es) 2015-12-18 2019-07-22 Borealis Ag Proceso para la fabricación de un cable de alimentación y cable de alimentación obtenible del mismo
CN114324486B (zh) * 2022-03-16 2022-05-27 国网天津市电力公司电力科学研究院 一种电缆缓冲层的缺陷检测方法、装置、设备及存储介质

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01167822A (ja) * 1987-12-24 1989-07-03 Matsushita Electric Ind Co Ltd 液晶表示パネル

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4145567A (en) * 1977-06-06 1979-03-20 General Cable Corporation Solid dielectric cable resistant to electrochemical trees
FR2725555B1 (fr) * 1994-10-11 1996-11-22 Alcatel Cable Cable de puissance
DE69814921T2 (de) * 1997-12-22 2004-03-11 Pirelli S.P.A. Elektrisches kabel mit eine halbleitende wasserblockierende expandierte schicht

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01167822A (ja) * 1987-12-24 1989-07-03 Matsushita Electric Ind Co Ltd 液晶表示パネル

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BR0215488A (pt) 2004-12-28
WO2004053896A1 (en) 2004-06-24
AU2002346702B2 (en) 2008-05-22
EP1570495A1 (de) 2005-09-07
AU2002346702A1 (en) 2004-06-30
CA2508862A1 (en) 2004-06-24
ATE509352T1 (de) 2011-05-15

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