EP1568758A2 - Lubricant compositons for automatic transmissions - Google Patents
Lubricant compositons for automatic transmissions Download PDFInfo
- Publication number
- EP1568758A2 EP1568758A2 EP05075442A EP05075442A EP1568758A2 EP 1568758 A2 EP1568758 A2 EP 1568758A2 EP 05075442 A EP05075442 A EP 05075442A EP 05075442 A EP05075442 A EP 05075442A EP 1568758 A2 EP1568758 A2 EP 1568758A2
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- EP
- European Patent Office
- Prior art keywords
- fluid
- viscosity index
- index improver
- dispersant viscosity
- lubricating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/02—Mixtures of base-materials and thickeners
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M145/00—Lubricating compositions characterised by the additive being a macromolecular compound containing oxygen
- C10M145/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M145/10—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate
- C10M145/12—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate monocarboxylic
- C10M145/14—Acrylate; Methacrylate
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/04—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/06—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing conjugated dienes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
- C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
- C10M2209/084—Acrylate; Methacrylate
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
- C10M2217/022—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amino group
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/08—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having metal-to-carbon bonds
- C10M2227/081—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions having metal-to-carbon bonds with a metal carbon bond belonging to a ring, e.g. ferocene
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/01—Physico-chemical properties
- C10N2020/02—Viscosity; Viscosity index
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/02—Pour-point; Viscosity index
Definitions
- the present disclosure relates to lubricant compositions and methods utilizing the lubricant compositions to provide and/or improve anti-shudder capabilities of automotive transmission fluids.
- the present disclosure also provides lubricant compositions that provide and/or improve compatibility with elastomeric components.
- new high energy type friction materials are being developed and used.
- the new high energy friction materials are able to withstand high speeds wherein internal transmission plate surface speeds are up to about 65 m/second. It is also important that the friction material be useful under limited lubrication conditions.
- One such material being developed for automatic transmission applications is a carbon fiber containing material.
- Friction modifiers are used in transmission fluids to control friction between surfaces (e.g., the members of a torque converter clutch or a shifting clutch) at low sliding speeds. The result is a friction vs. velocity (u-v) curve that has a positive slope, which in turn leads to smooth clutch engagements and minimizes "stick-slip” behavior (e.g., shudder, noise, and harsh shifts).
- u-v friction vs. velocity
- Many conventional friction modifiers are thermally unstable. Upon prolonged exposure to heat, these additives decompose, and the benefits they confer on clutch performance may be lost.
- deterioration of structural elastomeric elements or components such as seals, belts, gaskets, bushings, filters, and/or hoses in engines, transmissions, gears, and/or axles may occur.
- Such deterioration may be attributed to interactions between the elastomeric material of said elements and the reactive or deteriorative components of a lubricant composition or fluid.
- a lubricating fluid should provide appropriate swelling of seals, gaskets, and the like. It is additionally an object of the compositions and methods of the present invention to reduce the deterioration of, improve the compatibility with, and promote proper swell of such seals, hoses, and like elements and components.
- a power transmitting fluid for use in a power transmitting device may comprising a major amount of a base oil and a minor amount of an additive composition.
- the additive composition may comprise at least one non-dispersant viscosity index improver, wherein the power transmitting fluid provides anti-shudder performance to the power transmitting device.
- a lubricating fluid having compatibility with an elastomeric component may comprise a major amount of a base oil and a minor amount of an additive composition having at least one non-dispersant viscosity index improver.
- a method of improving the anti-shudder capabilities of a power transmission fluid may comprise lubricating a power transmission with a power transmission fluid comprising a major amount of a base oil and a minor amount of an additive composition comprising at least one non-dispersant viscosity index improver.
- a method of improving the torque performance of a power transmission fluid may comprise lubricating a power transmission with a power transmission fluid comprising a major amount of a base oil and a minor amount of an additive composition comprising at least one non-dispersant viscosity index improver.
- a method of improving the compatibility of a lubricating fluid with an elastomeric component may comprise lubricating an elastomeric component with a fluid comprising a major amount of a base oil and a minor amount of an additive composition comprising at least one non-dispersant viscosity index improver.
- a method of promoting seal swell of an elastomeric seal may comprise lubricating the elastomeric seal with a lubricating fluid comprising a major amount of a base oil and a minor amount of an additive composition comprising at least one non-dispersant viscosity index improver.
- a method of making a power transmitting fluid having anti-shudder capabilities may comprise adding to a major amount of a base oil a minor amount of an additive composition having a non-dispersant viscosity index improver.
- a method of making a lubricating fluid having improved compatibility with an elasotmeric component may comprise adding to a major amount of a base oil a minor amount of an additive composition having a non-dispersant viscosity index improver.
- the oils used to lubricate those transmissions should be formulated to endure higher temperatures and pressures.
- the oil should be formulated so that important oil properties change as little as possible in the face of these stresses.
- the shear stability properties of the oil which depend in great measure on the additive package, should stay relatively constant over a wide range of temperatures and operating speeds. This ensures smooth engagement of torque converter and shifting clutches and minimized shudder, vibration and noise, and improved fuel economy as constant viscosity allows good hydraulic control.
- compositions and methods that provide and/or improve anti-shudder performance of power transmission fluids, and also methods for providing and/or improving the compatibility of lubricating fluids with elastomeric components, for example, seals, gaskets, belts, and/or hoses.
- Non-dispersant viscosity index improvers are known to improve rheological properties, such as viscosity index, of power transmission fluids and/or lubricating fluids.
- the compositions of the present disclosure provide a single solution to multiple problems, and thus an inherent cost benefit.
- a power transmission fluid may include a base oil and an additive composition.
- the additive composition may include a non-dispersant viscosity index improver.
- Non-dispersant viscosity index improvers differ from dispersant viscosity index improvers by the absence of dispersant functional groups.
- a non-dispersant viscosity index improver suitable for use in at least one of the present embodiments may comprise a polymethacrylate, an olefin copolymer, a polystyrene, a metallocene polymer, a polymer of a hydrogenated diene and/or a copolymer thereof with a vinyl amine, a homopolymer of a hydrogenated conjugated diene or a copolymer thereof with a vinyl aromatic hydrocarbon, and the like.
- a wide range of molecular weight polymers of the latter type can be utilized as the base polymer of the non-dispersant viscosity index improver, and such polymers may include linear, branched, or star-shaped configurations.
- a non-dispersant viscosity index improver in the compositions and methods of the present embodiments eliminate and/or reduce the need for conventionally utilized friction-modifying agents or other agents for providing anti-shudder performance. Further, inclusion of a non-dispersant viscosity index improver may improve the anti-shudder properties of a fluid relative to a fluid including a dispersant viscosity index improver. Embodiments may include an amount of a non-dispersant viscosity index improver sufficient to provide and/or improve the anti-shudder characteristics of a power transmission fluid. For example, an additive composition may comprise from about 0.01 wt% to about 50 wt% of non-dispersant viscosity index improver.
- an additive composition may comprise from about 1.0 wt% to about 25 wt% of non-dispersant viscosity index improver. As an even further example, an additive composition may comprise from about 3 wt% to about 15 wt% of non-dispersant viscosity index improver.
- elastomeric components found within an automotive transmission, including an automatic and manual transmission, a gear component, and/or an axle component.
- elastomeric components may comprise seals, hoses, gaskets, belts, and the like. Further, these components may be composed of elastomeric materials such as nitrile rubber, polyacrylate, silicone, fluoroelastomers, and/or chlorinated polyethylene. Elastomeric components may deteriorate, shrink, or fail to swell properly because of contact with certain chemicals contained in lubricating fluids. Further, some chemicals, such as seal swell agents, may improve the tolerance of seals and hoses to lubricating fluids.
- Embodiments disclosed herein have been found to positively interact with seals and hoses to improve tensile strength and/or elongation. Both of these factors are indicative of proper seal swell and resistance or tolerance to deterioration.
- Such embodiments include a lubricating fluid comprising a non-dispersant viscosity index improver.
- a non-dispersant viscosity index improver in the compositions and methods of the present embodiments eliminate and/or reduce the need for conventionally utilized seal swell agents or other agents.
- inclusion of a non-dispersant viscosity index improver in a lubricating fluid may improve the compatibility of the lubricating fluid with elastomeric components.
- this improvement may be compared to fluids including dispersant viscosity index improvers and/or fluids including a conventional seal swell agent.
- Embodiments may include a suitable amount of a non-dispersant viscosity index improver sufficient to provide the desired swelling and/or provide or improve the compatibility between a lubricating fluid and elastomeric components.
- a non-dispersant viscosity index improver may comprise from about 0.01 wt% to about 50 wt% of non-dispersant viscosity index improver.
- an additive composition may comprise from about 1.0 wt% to about 25 wt% of non-dispersant viscosity index improver.
- an additive composition may comprise from about 3 wt% to about 15 wt% of non-dispersant viscosity index improver.
- Base oils suitable for use in formulating transmission fluid compositions may be selected from any of the synthetic or natural oils or mixtures thereof.
- Natural oils include animal oils and vegetable oils (e.g., castor oil, lard oil) as well as mineral lubricating oils such as liquid petroleum oils and solvent treated or acid-treated mineral lubricating oils of the paraffinic, naphthenic or mixed paraffinic-naphthenic types. Oils derived from coal or shale are also suitable.
- the base oil typically has a viscosity of about 2 to about 15 cSt or, as a further example, about 2 to about 10 cSt at 100° C. Further, gas-to-liquid stocks are also suitable.
- the synthetic base oils include alkyl esters of dicarboxylic acids, polyglycols, and alcohols, poly-alpha-olefins, including polybutenes, alkyl benzenes, organic esters of phosphoric acids, and polysilicone oils.
- Synthetic oils include hydrocarbon oils such as polymerized and interpolymerized olefins (e.g., polybutylenes, polypropylenes, propylene isobutylene copolymers, etc.); poly(1-hexenes), poly-(1-octenes), poly(1-decenes), etc.
- alkylbenzenes e.g., dodecylbenzenes, tetradecylbenzenes, dinonylbenzenes, di-(2-ethylhexyl)benzenes, etc.
- polyphenyls e.g., biphenyls, terphenyl, alkylated polyphenyls, etc.
- Alkylene oxide polymers and interpolymers and derivatives thereof where the terminal hydroxyl groups have been modified by esterification, etherification, etc. constitute another class of known synthetic oils that may be used.
- Such oils are exemplified by the oils prepared through polymerization of ethylene oxide or propylene oxide, the alkyl and aryl ethers of these polyoxyalkylene polymers (e.g., methylpolyisopropylene glycol ether having an average molecular weight of about 1000, diphenyl ether of polyethylene glycol having a molecular weight of about 500-1000, diethyl ether of polypropylene glycol having a molecular weight of about 1000-1500, etc.) or mono- and polycarboxylic esters thereof, for example, the acetic acid esters, mixed C 3-8 fatty acid esters, or the C 13 Oxo acid diester of tetraethylene glycol.
- esters of dicarboxylic acids e.g., phthalic acid, succinic acid, alkyl succinic acids, alkenyl succinic acids, maleic acid, azelaic acid, suberic acid, sebacic acid, fumaric acid, adipic acid, linoleic acid dimer, malonic acid, alkyl malonic acids, alkenyl malonic acids, etc.
- alcohols e.g., butyl alcohol, hexyl alcohol, dodecyl alcohol, 2-ethylhexyl alcohol, ethylene glycol, diethylene glycol monoether, propylene glycol, etc.
- these esters include dibutyl adipate, di(2-ethylhexyl)sebacate, di-n-hexyl fumarate, dioctyl sebacate, diisooctyl azelate, diisodecy
- Esters useful as synthetic oils also include those made from C 5 to C 12 monocarboxylic acids and polyols and polyol ethers such as neopentyl glycol, trimethylol propane, pentaerythritol, dipentaerythritol, tripentaerythritol, etc.
- the base oil used which may be used to make the transmission fluid compositions as described herein may be selected from any of the base oils in Groups I-V as specified in the American Petroleum Institute (API) Base Oil Interchangeability Guidelines.
- Such base oil groups are as follows: Base Oil Group Sulfur (wt%) Saturates (wt%) Viscosity Index Group I > 0.03 and/or ⁇ 90 80 to 120 Group II ⁇ 0.03 And ⁇ 90 80 to 120 Group III ⁇ 0.03 And ⁇ 90 ⁇ 120 Group IV all polyalphaolefins (PAOs) Group V all others not included in Groups I-IV
- the base oil may be a poly-alpha-olefin (PAO).
- PAO poly-alpha-olefin
- the poly-alpha-olefins are derived from monomers having from about 4 to about 30, or from about 4 to about 20, or from about 6 to about 16 carbon atoms.
- PAOs include those derived from octene, decene, mixtures thereof, and the like.
- PAOs may have a viscosity of from about 2 to about 15, or from about 3 to about 12, or from about 4 to about 8 cSt at 100° C.
- PAOs examples include 4 cSt at 100° C poly-alpha-olefins, 6 cSt at 100° C poly-alpha-olefins, and mixtures thereof. Mixtures of mineral oil with the foregoing poly-alpha-olefins may be used.
- the base oil may be an oil derived from Fischer-Tropsch synthesized hydrocarbons.
- Fischer-Tropsch synthesized hydrocarbons are made from synthesis gas containing H 2 and CO using a Fischer-Tropsch catalyst.
- Such hydrocarbons typically require further processing in order to be useful as the base oil.
- the hydrocarbons may be hydroisomerized using processes disclosed in U.S. Pat. Nos. 6,103,099 or 6,180,575; hydrocracked and hydroisomerized using processes disclosed in U.S. Pat. Nos. 4,943,672 or 6,096,940; dewaxed using processes disclosed in U.S. Pat. No. 5,882,505; or hydroisomerized and dewaxed using processes disclosed in U.S. Pat. Nos. 6,013,171; 6,080,301; or 6,165,949.
- Unrefined, refined and rerefined oils either natural or synthetic (as well as mixtures of two or more of any of these) of the type disclosed hereinabove can be used in the base oils.
- Unrefined oils are those obtained directly from a natural or synthetic source without further purification treatment.
- a shale oil obtained directly from retorting operations a petroleum oil obtained directly from primary distillation or ester oil obtained directly from an esterification process and used without further treatment would be an unrefined oil.
- Refined oils are similar to the unrefined oils except they have been further treated in one or more purification steps to improve one or more properties.
- Rerefined oils are obtained by processes similar to those used to obtain refined oils applied to refined oils which have been already used in service. Such rerefined oils are also known as reclaimed or reprocessed oils and often are additionally processed by techniques directed to removal of spent additives, contaminants, and oil breakdown products.
- the base oil may be combined with an additive composition as disclosed in embodiments herein to provide a power transmission fluid.
- the base oil may be present in the power transmission fluid in an amount from about 50 wt% to about 95 wt %.
- the power transmission fluid may also include conventional additives of the type used in automatic transmission fluid formulations in addition to the components described above.
- additives include, but are not limited to, ashless dispersants, friction modifiers, antioxidants, extreme pressure additives, corrosion inhibitors, antiwear additives, antirust additives, metal deactivators, antifoamants, pour point depressants, air entrainment additives, metallic detergents, and/or additional seal swell agents.
- Additives used in formulating the compositions described herein can be blended into the base oil individually or in various sub-combinations. However, it is suitable to blend all of the components concurrently using an additive concentrate (i.e., additives plus a diluent, such as a hydrocarbon solvent).
- an additive concentrate i.e., additives plus a diluent, such as a hydrocarbon solvent.
- the use of an additive concentrate takes advantage of the mutual compatibility afforded by the combination of ingredients when in the form of an additive concentrate simulates actual plant blending conditions. Also, the use of a concentrate reduces blending time and lessens the possibility of blending errors.
- the power transmission fluids disclosed herein may include fluids suitable for any power transmitting application, such as a step automatic transmission, having from about 3 to about 7 speeds, or a manual transmission. Further, the power transmission fluids of the present disclosure are suitable for use in transmissions with a slipping torque converter, a lock-up torque converter, a starting clutch, and/or one or more shifting clutches. Such transmissions include three-, four-, five-, six-, and seven-speed transmissions, and continuously variable transmissions (chain, belt, or disk type). They may also be used in manual transmissions, including automated manual and dual-clutch transmissions.
- Fluids tested in the following examples included the following components prepared in the proportions disclosed below. Components that were varied are discussed with respect to each example below. Unless otherwise specified tested samples were identical except for varied components.
- Antifoam agents 0 -1.5 0.05 - 0.20 Friction Modifiers 0 - 5.0 0.005 - 0.25 Dispersant 0 -10 1 - 5% Seal Swell Agents 0 - 20 0 -10 Polymethacrylate viscosity index improver 0.5-30 3-25 Basestock 60 - 90 60 - 90 Diluent Oil 0 - 20 2 - 5
- a polymethacrylate non-dispersant viscosity index improver was used in Formula A at a concentration of 5.13 wt%, and a viscosity index improver with dispersant functionality was used in Formula B at a concentration of 5.13 wt%.
- the two automatic transmission fluids were subjected to shudder testing by evaluating friction characteristics using the ZF GK rig.
- This test was developed by ZF to measure a slip-controlled clutch's opening and closing performance.
- An interchangeable intermediate shaft allows the measurement of frictional vibration that is the basis for evaluation of "green” or initial shudder characteristics of the test fluid.
- the Green Shudder portion of the "GVRK-Kurztest CFT23" consists of a torque controlled continuous slip module, containing three 20-minute sections. The entire sequence encompasses 60 minutes of test time. During each 20-minute section, force is proportional to both slip speed and output torque.
- Measurements in Figures 1 and 2 are displayed as torque over the function of time.
- the variation in torque measurements is indicative of shudder. Fluids without shudder will display constant torque over time. Fluids with shudder will display varying torque over time.
- Shudder tests were run with a polymethacrylate non-dispersant viscosity index improver fluid (Formula A) in Figure 1 and a dispersant viscosity index improver (Formula B) in Figure 2.
- the green shudder characteristics of Formula A in Figure 1 show a reduction in green shudder associated with the incorporation of a non-dispersant viscosity index improver.
- the results using Formula A demonstrate no green shudder, as evidenced by constant torque over time.
- the results using Formula B demonstrate varying torque over time which is indicative of green shudder.
- non-dispersant viscosity index improver in a lubricating fluid was tested for compatibility by representative elastomeric component.
- the component tested was a hose composed of a chlorinated polyethylene.
- Table 1 demonstrates the results obtained from the testing of several power transmission fluid with the chlorinated polyethylene hose. The performance was determined by the tensile strength and the elongation of the hose at the end of the test, with a more positive number indicating better performance. Sample 1 did not contain any of non-dispersant viscosity index improver, dispersant viscosity index improver, or seal swell agent.
- Sample 2 contained an equal amount of a non-dispersant viscosity index improver and a dispersant viscosity index improver.
- Sample 3 contained an equal amount of a non-dispersant viscosity index improver and a dispersant viscosity index improver and additionally a seal swell agent.
- Sample 4 contained a non-dispersant viscosity index improver and a seal swell agent. All other components in the fluids tested were identical.
- each numerical parameter should at least be construed in light of the number of reported significant digits and by applying ordinary rounding techniques. Notwithstanding that the numerical ranges and parameters setting forth the broad scope of the invention are approximations, the numerical values set forth in the specific examples are reported as precisely as possible. Any numerical value, however, inherently contains certain errors necessarily resulting from the standard deviation found in their respective testing measurements. It is intended that the specification and examples be considered as exemplary only, with a true scope and spirit of the invention being indicated by the following claims.
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- Chemical Kinetics & Catalysis (AREA)
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- Organic Chemistry (AREA)
- Lubricants (AREA)
- Mechanical Operated Clutches (AREA)
Abstract
Description
| Base Oil Group | Sulfur (wt%) | Saturates (wt%) | Viscosity Index | |
| Group I | > 0.03 | and/or | < 90 | 80 to 120 |
| Group II | ≤ 0.03 | And | ≥ 90 | 80 to 120 |
| Group III | ≤ 0.03 | And | ≥ 90 | ≥ 120 |
| Group IV | all polyalphaolefins (PAOs) | |||
| Group V | all others not included in Groups I-IV |
| Component type | Example 2 Proportion in Finished Fluid, wt% | Example 2 Proportion in Finished Fluid, wt% |
| Antioxidants | 0.1 - 2.5 | 0.2 - 0.5 |
| Rust Inhibitors | 0 - 0.2 | 0 - 0.06 |
| Thiadiazole | 0 - 2.0 | 0.01 - 0.6 |
| Antifoam agents | 0 -1.5 | 0.05 - 0.20 |
| Friction Modifiers | 0 - 5.0 | 0.005 - 0.25 |
| Dispersant | 0 -10 | 1 - 5% |
| Seal Swell Agents | 0 - 20 | 0 -10 |
| Polymethacrylate viscosity index improver | 0.5-30 | 3-25 |
| Basestock | 60 - 90 | 60 - 90 |
| Diluent Oil | 0 - 20 | 2 - 5 |
Claims (23)
- A lubricating fluid having compatibility with an elastomeric component, including:(a) a major amount of a base oil; and(b) a minor amount of an additive composition having at least one non-dispersant viscosity index improver.
- The fluid of claim 1, wherein the fluid further promotes swelling of the elastomeric component.
- The fluid of any one of claims 1-2, wherein the non-dispersant viscosity index improver includes a polymethacrylate viscosity index improver.
- The fluid of any one of claims 1-3, wherein the non-dispersant viscosity index improver is present in an amount from 0.01 wt% to 50 wt% in the additive composition.
- The fluid of any one of claims 1-3, wherein the non-dispersant viscosity index improver is present in an amount from 1 wt% to 25 wt% in the additive composition.
- The fluid of any one of claims 1-3, wherein the non-dispersant viscosity index improver is present in an amount from 3 wt% to 15 wt% in the additive composition.
- The fluid of any one of claims 1-6, wherein the base oil includes one or more of a natural lubricating oil, a synthetic lubricating oil, and a mixture thereof.
- The fluid of any one of claims 1-7, wherein the fluid is free of a dispersant viscosity index improver.
- The fluid of any one of claims 1-8, wherein the fluid is suitable for use in an automatic transmission, a continuously variable transmission, a slipping torque converter, a step automatic transmission, a clutch-to-clutch transmission, and a transmission with a wet starting clutch.
- The fluid of any one of claims 1-9, wherein the elastomeric component includes one or more of a seal, a hose, a gasket, and a belt.
- The fluid of any one of claims 1-10, wherein the elastomeric component is composed of any one of a chlorinated polyethylene, a nitrile rubber, a polyacrylate, a fluoroelastomer, and a silicone.
- The fluid of any one of claims 1-11, wherein the compatibility of the fluid with an elastomeric component is improved relative to a fluid free of a non-dispersant viscosity index improver.
- The fluid of any one of claims 1-11, wherein the compatibility of the fluid with an elastomeric component is improved relative to a fluid free of a non-dispersant viscosity index improver and containing a dispersant viscosity index improver.
- The fluid of any one of claims 1-13, wherein the fluid further contains a seal swell agent.
- The fluid of any one of claims 1-14, wherein the lubricating fluid is a power transmitting fluid, and the power transmitting fluid provides improved anti-shudder performance relative to a power transmitting fluid free of at least one non-dispersant viscosity index improver and containing a dispersant viscosity index improver.
- An automatic transmission lubricated with the fluid of claim 15.
- The automatic transmission of claim 16, wherein the transmission is a continuously variable transmission.
- A method of lubricating a power transmission having an elastomeric component, including the steps of adding to, and operating in said power transmission, a fluid as set forth in any one of claims 1-15.
- A method of improving the anti-shudder capabilities of a power transmission fluid, including the step of:lubricating a power transmission with a power transmission fluid as claimed in claim 15.
- A method of improving the torque performance of a power transmission, including the step of:lubricating a power transmission with a power transmission fluid as claimed in claim 15.
- A method of promoting seal swell of an elastomeric seal, including the step of lubricating the elastomeric seal with a lubricating fluid as claimed in any one of claims 1-14.
- A method of making a power transmitting fluid as claimed in claim 15, having anti-shudder capability, including the step of adding to a major amount of a base oil, a minor amount of an additive composition having a non-dispersant viscosity index improver.
- A method of making a lubricating fluid as claimed in any one of claims 1-14, having improved compatibility with an elastomeric component, including the step of adding to a major amount of a base oil, a minor amount of an additive composition having a non-dispersant viscosity index improver.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/788,734 US20050192186A1 (en) | 2004-02-27 | 2004-02-27 | Lubricant compositions for providing anti-shudder performance and elastomeric component compatibility |
| US788734 | 2004-02-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1568758A2 true EP1568758A2 (en) | 2005-08-31 |
| EP1568758A3 EP1568758A3 (en) | 2006-07-19 |
Family
ID=34750538
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP05075442A Withdrawn EP1568758A3 (en) | 2004-02-27 | 2005-02-24 | Lubricant compositons for automatic transmissions |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US20050192186A1 (en) |
| EP (1) | EP1568758A3 (en) |
| JP (1) | JP2005240034A (en) |
| KR (1) | KR100664428B1 (en) |
| CN (1) | CN1673323A (en) |
| AU (1) | AU2005200174A1 (en) |
| CA (1) | CA2491823A1 (en) |
| SG (1) | SG114784A1 (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2008013754A2 (en) * | 2006-07-28 | 2008-01-31 | Exxonmobil Research And Engineering Company | Lubricant compositions, their preparation and use |
| CA2658631A1 (en) * | 2006-07-28 | 2008-01-31 | Exxonmobil Research And Engineering Company | Novel application of thickeners to achieve favorable air release in lubricants |
| EP2049632A4 (en) * | 2006-07-28 | 2012-05-02 | Exxonmobil Res & Eng Co | IMPROVING LUBRICANT DEATH SPEEDS |
| US7770914B2 (en) * | 2007-07-31 | 2010-08-10 | Autoliv Asp, Inc. | Passenger airbag mounting apparatus |
| US20110162723A1 (en) * | 2008-10-14 | 2011-07-07 | Evonik Rohmax Additives Gmbh | Hydraulic fluid composition that reduces hydraulic system noise |
| US8933001B2 (en) * | 2010-03-31 | 2015-01-13 | Chevron Oronite Company Llc | Method for improving fluorocarbon elastomer seal compatibility |
| US10227544B2 (en) * | 2013-08-15 | 2019-03-12 | Infineum International Limited | Automotive transmission fluid compositions for improved energy efficiency |
| US10650621B1 (en) | 2016-09-13 | 2020-05-12 | Iocurrents, Inc. | Interfacing with a vehicular controller area network |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4943672A (en) * | 1987-12-18 | 1990-07-24 | Exxon Research And Engineering Company | Process for the hydroisomerization of Fischer-Tropsch wax to produce lubricating oil (OP-3403) |
| US5112509A (en) * | 1988-12-22 | 1992-05-12 | Texaco, Inc. | Non-dispersant, shear-stabilizing, and wear-inhibiting viscosity index improver |
| US5652201A (en) * | 1991-05-29 | 1997-07-29 | Ethyl Petroleum Additives Inc. | Lubricating oil compositions and concentrates and the use thereof |
| US5891786A (en) * | 1995-01-12 | 1999-04-06 | Ethyl Corporation | Substantially metal free synthetic power transmission fluids having enhanced performance capabilities |
| CN1181166C (en) * | 1995-12-08 | 2004-12-22 | 埃克森研究工程公司 | Biodegradable High Performance Hydrocarbon Base Oils |
| US5882505A (en) * | 1997-06-03 | 1999-03-16 | Exxon Research And Engineering Company | Conversion of fisher-tropsch waxes to lubricants by countercurrent processing |
| US6048826A (en) * | 1997-06-04 | 2000-04-11 | Idemitsu Kosan Co., Ltd. | Lubricating oil composition |
| US5942472A (en) * | 1997-06-12 | 1999-08-24 | Exxon Chemical Patents Inc. | Power transmission fluids of improved viscometric and anti-shudder properties |
| US5916852A (en) * | 1997-09-02 | 1999-06-29 | Exxon Chemical Patents Inc. | Power transmission fluids with improved friction break-in |
| JPH11116982A (en) * | 1997-10-09 | 1999-04-27 | Mitsubishi Oil Co Ltd | Lubricating oil composition |
| US6013171A (en) * | 1998-02-03 | 2000-01-11 | Exxon Research And Engineering Co. | Catalytic dewaxing with trivalent rare earth metal ion exchanged ferrierite |
| US6180575B1 (en) * | 1998-08-04 | 2001-01-30 | Mobil Oil Corporation | High performance lubricating oils |
| US5955405A (en) * | 1998-08-10 | 1999-09-21 | Ethyl Corporation | (Meth) acrylate copolymers having excellent low temperature properties |
| US6080301A (en) * | 1998-09-04 | 2000-06-27 | Exxonmobil Research And Engineering Company | Premium synthetic lubricant base stock having at least 95% non-cyclic isoparaffins |
| US6165949A (en) * | 1998-09-04 | 2000-12-26 | Exxon Research And Engineering Company | Premium wear resistant lubricant |
| US6103099A (en) * | 1998-09-04 | 2000-08-15 | Exxon Research And Engineering Company | Production of synthetic lubricant and lubricant base stock without dewaxing |
| US20020151441A1 (en) * | 2001-02-14 | 2002-10-17 | Sanjay Srinivasan | Automatic transmission fluids with improved anti-shudder properties |
| JP3831203B2 (en) * | 2001-04-06 | 2006-10-11 | 三洋化成工業株式会社 | Viscosity index improver and lubricating oil composition |
| US6627584B2 (en) * | 2002-01-28 | 2003-09-30 | Ethyl Corporation | Automatic transmission fluid additive comprising reaction product of hydrocarbyl acrylates and dihydrocarbyldithiophosphoric acids |
| JP2004155924A (en) | 2002-11-07 | 2004-06-03 | Tonengeneral Sekiyu Kk | Lubricating oil composition for transmission |
| KR20040072434A (en) * | 2003-02-12 | 2004-08-18 | 에스케이 주식회사 | Lubricating oil composition for automatic transmission |
-
2004
- 2004-02-27 US US10/788,734 patent/US20050192186A1/en not_active Abandoned
-
2005
- 2005-01-10 CA CA002491823A patent/CA2491823A1/en not_active Abandoned
- 2005-01-14 AU AU2005200174A patent/AU2005200174A1/en not_active Abandoned
- 2005-01-27 KR KR1020050007542A patent/KR100664428B1/en not_active Expired - Fee Related
- 2005-02-18 JP JP2005042654A patent/JP2005240034A/en active Pending
- 2005-02-24 EP EP05075442A patent/EP1568758A3/en not_active Withdrawn
- 2005-02-25 SG SG200501254A patent/SG114784A1/en unknown
- 2005-02-28 CN CNA2005100521847A patent/CN1673323A/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| EP1568758A3 (en) | 2006-07-19 |
| JP2005240034A (en) | 2005-09-08 |
| AU2005200174A1 (en) | 2005-09-15 |
| SG114784A1 (en) | 2005-09-28 |
| KR100664428B1 (en) | 2007-01-03 |
| CN1673323A (en) | 2005-09-28 |
| CA2491823A1 (en) | 2005-08-27 |
| KR20050087734A (en) | 2005-08-31 |
| US20050192186A1 (en) | 2005-09-01 |
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