EP1563751B1 - Elément amortisseur pour une chaussure - Google Patents

Elément amortisseur pour une chaussure Download PDF

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Publication number
EP1563751B1
EP1563751B1 EP05010930A EP05010930A EP1563751B1 EP 1563751 B1 EP1563751 B1 EP 1563751B1 EP 05010930 A EP05010930 A EP 05010930A EP 05010930 A EP05010930 A EP 05010930A EP 1563751 B1 EP1563751 B1 EP 1563751B1
Authority
EP
European Patent Office
Prior art keywords
damping element
damping
element according
elements
connecting portion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP05010930A
Other languages
German (de)
English (en)
Other versions
EP1563751A1 (fr
Inventor
Theodor Hofmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Puma SE
Original Assignee
Puma AG Rudolf Dassler Sport
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Puma AG Rudolf Dassler Sport filed Critical Puma AG Rudolf Dassler Sport
Publication of EP1563751A1 publication Critical patent/EP1563751A1/fr
Application granted granted Critical
Publication of EP1563751B1 publication Critical patent/EP1563751B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00—Soles; Sole-and-heel integral units
    • A43B13/14—Soles; Sole-and-heel integral units characterised by the constructive form
    • A43B13/18—Resilient soles
    • A43B13/181—Resiliency achieved by the structure of the sole
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00—Soles; Sole-and-heel integral units
    • A43B13/14—Soles; Sole-and-heel integral units characterised by the constructive form
    • A43B13/18—Resilient soles
    • A43B13/20—Pneumatic soles filled with a compressible fluid, e.g. air, gas
    • A43B13/206—Pneumatic soles filled with a compressible fluid, e.g. air, gas provided with tubes or pipes or tubular shaped cushioning members
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B1/00—Footwear characterised by the material
    • A43B1/0009—Footwear characterised by the material made at least partially of alveolar or honeycomb material
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B1/00—Footwear characterised by the material
    • A43B1/0072—Footwear characterised by the material made at least partially of transparent or translucent materials
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B13/00—Soles; Sole-and-heel integral units
    • A43B13/14—Soles; Sole-and-heel integral units characterised by the constructive form
    • A43B13/18—Resilient soles
    • A43B13/20—Pneumatic soles filled with a compressible fluid, e.g. air, gas
    • A—HUMAN NECESSITIES
    • A43—FOOTWEAR
    • A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
    • A43B7/00—Footwear with health or hygienic arrangements
    • A43B7/32—Footwear with health or hygienic arrangements with shock-absorbing means
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/23—Sheet including cover or casing
    • Y10T428/234—Sheet including cover or casing including elements cooperating to form cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24149—Honeycomb-like
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24149—Honeycomb-like
    • Y10T428/24165—Hexagonally shaped cavities
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24628—Nonplanar uniform thickness material
    • Y10T428/24661—Forming, or cooperating to form cells

Definitions

  • the invention relates to a damping element for a shoe, in particular for a sports shoe, according to the preamble of claim 1.
  • a shoe which is equipped with a shoe sole, which already has a good damping behavior.
  • the shoe is equipped with a shoe sole with at least one consisting of a honeycomb body made of elastic, compressible material insert part, wherein the central axes of the gas-filled honeycomb cells are approximately perpendicular to the sole plane.
  • the honeycomb body is designed as a final shape in its dimensions, the honeycomb cells are sealed gas-tight at the periphery or at the edge of the honeycomb body.
  • the preamble of claim 1 is known from US-A-4 521 979 and US-A-3 608 215.
  • the invention is therefore based on the object , a damping element of the type mentioned in such a way that the damping behavior of the shoe is further improved.
  • the restoring force of the shoe sole is to be increased after the pressure relief so that the energy recovery in the pressure relief of the shoe can be further increased.
  • the damping element according to the invention is thus designed in the manner of a telescopic damper.
  • the first element acts as a cylinder-like receiving chamber into which the second element can penetrate in the manner of a piston. This can be achieved a high travel and the spring and damping characteristics of the shoe can be adapted to the desired interests. Furthermore, there is also the possibility to recover the energy expended in the compression of the damping element to a considerable extent.
  • the first element and the second element in a section perpendicular to the loading direction have a mutually corresponding shape. among them is to be understood that the cross-sectional geometry of the first and the second element are formed congruent to each other, so that a matching receiving and entry space is created in the first element for the second element.
  • the first element and the second element have a polygonal, in particular hexagonal, shape in a section perpendicular to the loading direction.
  • the damping element is designed in the manner of a honeycomb pattern.
  • the dimensions of the first element in a section perpendicular to the loading direction are greater than the corresponding dimensions of the second element. This will allow the second element to enter the space defined by the first element.
  • the first element is in the unloaded state of the damping element with its axial extent substantially outside the axial extent of the second element.
  • the piston-like second element is arranged in the unloaded state of the damping element axially outside of the cylinder-like first element. Only when loading the damping element in the loading direction then enters the "piston" in the "cylinder".
  • the first element and the second element are formed as hollow bodies, which are connected to each other via a connecting portion.
  • the connecting section can in unloaded state of the damping element in a plane perpendicular to the loading direction run flat. Equally, however, it can also be provided that the connecting section runs curved in the unloaded state of the damping element. With the latter embodiment, the entry of the "piston” is favored in the "cylinder" under load. This is also the case when the connecting portion consists of elastic material, as provided according to another embodiment of the invention.
  • first element, the connecting portion and the second element are integrally formed. It can be provided in particular that the first element and the second element are produced by an injection molding process. It is favorable if the first element, the connecting section and the second element are produced by a common injection molding process.
  • the elements form gas-tight chambers.
  • the second element facing away from the end of the first element is connected to a sealing film.
  • the end facing away from the first element of the second element may be connected to a sealing film.
  • the respective element and the sealing films can be gas-tightly connected to one another, in particular welded.
  • the elements may be made of plastic, in particular of thermoplastic material.
  • plastic polyethylene, polypropylene, polybutane, polyamide, polyurethane or a mixture of at least two of these plastics have proven.
  • the plastic may be translucent or transparent.
  • a multiplicity of first and / or second elements can be connected to one another or arranged next to one another.
  • the first elements are connected to one another in their lateral region.
  • Such an embodiment is particularly easy to implement in a geometry according to a honeycomb pattern.
  • first and second elements are arranged next to one another, it can be provided that the connecting portion of at least two adjacent first and second elements is formed as a common part. It is also possible that the plurality of juxtaposed first and second elements are connected to each other via the connecting portions. A further development provides that the first and second elements are arranged at a distance and parallel to each other.
  • damping element adaptation of the damping element to the specific needs in terms of geometry and function is facilitated by the fact that it can further be provided that the first and / or second elements at least partially in the unloaded state of the damping element have different heights.
  • the damping characteristics, as well as the ability of the damping element to absorb and return energy can be influenced by the choice of parameters that determine the geometry and material properties.
  • the material of the first element, of the second element and of the connecting section, as well as the geometric dimensions of said parts are selected for determining the rigidity of the damping element.
  • a damping element which increases the damping and the restoring force of the shoe sole and thus the energy recovery after the pressure relief of the shoe sole to a large extent. Due to the proposed embodiments is also achieved that the damping element according to the invention can be manufactured inexpensively and thus inexpensive.
  • a damping element 1 is shown in section.
  • the damping element 1 is integrated in a shoe (not shown), in particular in the sole of a sports shoe. It serves to absorb energy when loading the sole in the loading direction R and to release the energy stored in the damping element 1 when the sole is relieved.
  • the damping element 1 has a first element 2 and a second element 4, which are hexagonal in the manner of a honeycomb pattern.
  • the first element 2 has a receiving space 3, which results from the volume of the hexagonal body.
  • the extension of the first element 2 in the loading direction R is indicated by H (height of the first element 2 in the unloaded state of the damping element 1).
  • H height of the first element 2 in the unloaded state of the damping element 1.
  • the second element 4 is arranged, which extends over an axial height h in the loading direction R.
  • the dimensions-width B of the first element 2 and width b of the second element 4- are selected such that the second element 4 can enter the receiving space 3 when the damping element 1 is loaded in the loading direction R, which is defined by the first element 2.
  • the first element 2 and the second element 4 thus operate in the manner of a telescopic damper, wherein the first element 2 acts as a "cylinder", in which the second element 4 can enter in the manner of a "piston".
  • the upper axial end region of the first element 2 to be seen in FIG. 1 and the axial lower end region of the second element 4 are connected to one another via a connecting section 5. It is at the connecting portion 5 - as well as the first and second elements 2, 4 - is a part of elastic plastic material, so that when a loading force on the damping element 1 in the loading direction R deformation takes place, as shown schematically in Fig. 3rd is shown.
  • the second element 4 enters the receiving space 3 of the first element 2 like a piston.
  • the second element 4 facing away from the end 6 of the first element 2 is connected to a first sealing film 7, in particular welded.
  • the first element 2 facing away from the end 8 of the second element 4 is provided with a second sealing film 9.
  • These sealing film 9 is also connected to the second element 4, preferably welded.
  • the entire damping element 1 shown in FIG. 4 can be cut into a shoe and there, in particular, inserted into a midsole.
  • the second elements 4 press more and more into the axial region of the first elements 2.
  • the flat sealing foil 7 or 9 extends over a number of juxtaposed "piston-cylinder elements", ie a foil 7, 9 covers one Number of such elements.
  • a foil 7, 9 covers one Number of such elements.
  • This "lid” may be welded to the ends 6 and 8 of the elements 2 and 4, respectively; but it is also possible that it is injection-molded, for example, in injection molding of the elements 2 and 4, ie formed in situ with. It is preferably provided that the ends 6 of the first elements 2 are closed with a large-area film 7 (as shown in Fig. 1), while the ends 8 of the second elements 4 are closed only with individual film sections 9 in the form of "covers" ,
  • FIGS. 6a, 6b, 6c and 7 show an alternative embodiment of the damping element.
  • a plurality of first and second elements 2 and 4 are arranged side by side.
  • the first and second elements 2 and 4 are positioned at a distance and parallel to one another (shown without films 7 or 9, see FIG. 1).
  • connection of the individual units each consisting of a first and a second element 2 and 4, via the connecting portions 5, which also connect the first and the second element 2, 4 together.
  • the connecting portions 5 thus provide not only the connection between the first and second elements 2, 4 - in the axial direction - but also the connection of the individual sub-elements to the structure shown in the said figures.
  • first and second elements 2 and 4 at least partially in the illustrated unloaded state of the damping element different heights H and h (s., Fig. 1) exhibit.
  • the spring and damping characteristics of the damping element 1 By adapting the geometry and in particular these heights and the widths of the individual elements 2 and 4, the thickness and design of the connecting portions 5 and also by appropriate choice of the material from which these parts are made, the spring and damping characteristics of the damping element 1 arbitrarily adapted or selected.
  • the spring and damping characteristic of the damping element 1 - in particular the spring force on the spring travel - can thus be largely selected according to a desired course.
  • the respective function which must fulfill the individual partial damping element consisting of the first element, the second element and the connecting section, can thus be influenced, ie. H. whether it is more of a support or a damping effect is needed.
  • the damping element 1 according to the invention can also be used in combination with a conventional damping element, as is known in the art, in a shoe, in particular a sports shoe. This results in further possibilities to be able to optimally adapt the spring and damping behavior of a shoe, in particular a sports shoe, to the respective requirements.

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  • Health & Medical Sciences (AREA)
  • Epidemiology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Vibration Dampers (AREA)
  • Electric Cable Installation (AREA)
  • Springs (AREA)
  • Laminated Bodies (AREA)

Claims (21)

  1. Élément d'amortissement (1) pour une chaussure, en particulier pour une chaussure de sport, constitué d'au moins un premier élément (2) qui s'étend pour l'essentiel dans une direction de sollicitation (R) dans l'état non sollicité de l'élément d'amortissement (1) sur une hauteur prédétenninée (H) et, configuré sous forme de corps creux, définit un espace de réception (3) dans lequel peut s'enfoncer au moins partiellement un deuxième élément associé (4) dont les dimensions en coupe transversale sont inférieures à celles du premier élément (2), le deuxième élément (4) s'étendant pour l'essentiel dans la direction de sollicitation (R) dans l'état non sollicité de l'élément d'amortissement (1) sur une hauteur prédéterminée (h) et étant disposé coaxialement par rapport au premier élément (2), le deuxième élément (4) étant également configuré en forme de corps creux et les deux éléments associés l'un à l'autre (2, 4) étant reliés entre eux par le biais d'une section de liaison élastique (5) qui s'étend uniquement entre le premier élément (2) et le deuxième élément (4),
    caractérisé en ce que
    le premier élément (2) et le deuxième élément (4) présentent en coupe perpendiculairement à la direction de sollicitation (R) une forme correspondante, en fait une forme polygonale, en particulier hexagonale.
  2. Elément d'amortissement selon revendication 1, caractérisé en ce que dans l'état non sollicité de l'élément d'amortissement (1), la section de liaison (5) s'étend à plat dans un plan perpendiculaire a la direction de sollicitation (R).
  3. Elément d'amortissement selon revendication 1, caractérisé en ce que dans l'état non sollicité de l'élément d'amortissement (1), la section de liaison (5) s'étend de facon courbée dans un plan perpendiculaire à la direction de sollicitation (R).
  4. Elément d'amortissement selon l'une des revendications 1 à 3, caractérisé en ce que le premier élément (2), la section de liaison (5) et le deuxième élément (4) sont configurés d'une seule pièce.
  5. Elément d'amortissement selon l'une des revendications 1 à 4, caractérisé en ce que le premier élément (2) et le deuxième élément (4) sont fabriqués dans le cadre d'un procédé de moulage par injection.
  6. Elément d'amortissement selon les revendications 4 et 5, caractérisé en ce que le premier élément (2), la section de liaison (5) et le deuxième élément (4) sont fabriqués dans le cadre d'un procédé commun de moulage par injection.
  7. Elément d'amortissement selon l'une des revendications 1 à 6, caractérisé en ce que l'extrémité (6) du premièr élément (2) opposée au deuxième élément (4) est reliée a un film étanche (7).
  8. Elément d'amortissement selon l'une des revendications 1 à 7, caractélisé en ce que l'extrémité (8) du deuxième élément (4) opposée au premièr élément (2) est reliée a un film étanche (9).
  9. Elément d'amortissement selon la revendication 7 ou 8, caractérisé en ce que les éléments (2, 4) et les films étanches (7, 9) sont reliès entre eux, en particulier soudés, de facon étanche aux gaz.
  10. Elément d'amortissement selon l'une des revendications 7 à 9, caractérisé en ce que le premier élément (2), le deuxième élément (4), la section de liaison (5) et les films étanches (7, 9) forment une chambre flexible fermée étanche aux gaz.
  11. Elément d'amortissement selon l'une des revendications 1 à 10, caractérisé en ce que les éléments (2, 4) se composent d'une matière plastique, en particulier d'une matière thermoplastique.
  12. Elément d'amortissement selon la revendication 11, caractérisé en ce que la matière plastique est du polyéthylène, du polypropylène, du polybutane, du polyamide, du polyuréthane ou un mélange d'au moins deux de ces matières plastiques.
  13. Elément d'amortissement selon la revendication 11 ou 12. caractérisé en ce que la matière plastique est translucide ou transparente.
  14. Elément d'amortissement selon l'une des revendications 1 à 13, caractérisé en ce que plusieurs premiers et/ou deuxièmes éléments (2, 4) sont reliés entre eux.
  15. Elément d'amortissement selon la revendication 14, caractérisé en ce que les premiers éléments (2) sont reliés entre eux dans leur zone latérale.
  16. Elément d'amortissement selon l'une des revendications 1 à 13, caractérisé en ce que plusieurs premiers et/ou deuxièmes éléments (2, 4) sont disposés les uns à coté des autres.
  17. Elément d'amortissement selon la revendication 16, caractérisé en ce que la section de liaison (5) entre au moins deux premiers ou deuxièmes éléments (2, 4) adjacents est configurée sous forme de partie commune.
  18. Elément d'amortissement selon la revendication 17, caractérisé en ce que les nombreux premiers et deuxièmes éléments (2, 4) disposés les uns à coté des autres sont reliés entre eux via les sections de liaison (5).
  19. Elément d'amortissement selon l'une des revendications 16 à 18, caractérisé en ce que les premiers et deuxièmes éléments (2, 4) sont disposées parallèlement les uns aux autres et à une certaine distance les uns des autres.
  20. Elément d'amortissement selon l'une des revendications 14 à 19, caractérisé en ce que les premiers et/ou deuxièmes éléments (2, 4) présentent au moins partiellement, dans l'état non sollicité de l'élément d'amortissement (1), des hauteurs différentes (H, h).
  21. Elément d'amortissement selon l'une des revendications 1 à 20, caractérisé en ce que le matériau du premier élément (2), du deuxième élément (4) et de la section de liaison (5), ainsi que les dimensions géométriques de ces pièces, sont choisis de manière à déterminer les propriétés d'amortissement de l'élément d'amortissement (1).
EP05010930A 2002-05-01 2003-04-15 Elément amortisseur pour une chaussure Expired - Lifetime EP1563751B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE20206927U 2002-05-01
DE20206927U DE20206927U1 (de) 2002-05-01 2002-05-01 Dämpfungselement für einen Schuh
EP03729837A EP1499209B1 (fr) 2002-05-01 2003-04-15 Element amortisseur d'une chaussure

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
EP03729837A Division EP1499209B1 (fr) 2002-05-01 2003-04-15 Element amortisseur d'une chaussure

Publications (2)

Publication Number Publication Date
EP1563751A1 EP1563751A1 (fr) 2005-08-17
EP1563751B1 true EP1563751B1 (fr) 2006-09-06

Family

ID=27816299

Family Applications (2)

Application Number Title Priority Date Filing Date
EP05010930A Expired - Lifetime EP1563751B1 (fr) 2002-05-01 2003-04-15 Elément amortisseur pour une chaussure
EP03729837A Expired - Lifetime EP1499209B1 (fr) 2002-05-01 2003-04-15 Element amortisseur d'une chaussure

Family Applications After (1)

Application Number Title Priority Date Filing Date
EP03729837A Expired - Lifetime EP1499209B1 (fr) 2002-05-01 2003-04-15 Element amortisseur d'une chaussure

Country Status (18)

Country Link
US (1) US7153560B2 (fr)
EP (2) EP1563751B1 (fr)
JP (1) JP2005532845A (fr)
KR (1) KR100611426B1 (fr)
CN (1) CN100438792C (fr)
AT (2) ATE308256T1 (fr)
AU (1) AU2003240394B2 (fr)
BR (1) BR0308463B1 (fr)
CA (1) CA2477760C (fr)
DE (4) DE20206927U1 (fr)
ES (2) ES2248751T3 (fr)
IL (2) IL163747A0 (fr)
MX (1) MXPA04010799A (fr)
NO (1) NO325469B1 (fr)
PL (1) PL205489B1 (fr)
RU (1) RU2279235C2 (fr)
WO (1) WO2003092423A1 (fr)
ZA (1) ZA200406926B (fr)

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PL205489B1 (pl) 2010-04-30
KR100611426B1 (ko) 2006-08-09
DE50304985D1 (de) 2006-10-19
ES2248751T3 (es) 2006-03-16
ZA200406926B (en) 2006-06-28
EP1499209B1 (fr) 2005-11-02
IL163747A (en) 2008-12-29
EP1499209A1 (fr) 2005-01-26
DE20206927U1 (de) 2003-09-04
JP2005532845A (ja) 2005-11-04
DE10392004D2 (de) 2005-04-07
AU2003240394B2 (en) 2006-11-09
ATE308256T1 (de) 2005-11-15
CN1646039A (zh) 2005-07-27
US20050252037A1 (en) 2005-11-17
WO2003092423A8 (fr) 2004-01-08
IL163747A0 (en) 2005-12-18
NO325469B1 (no) 2008-05-05
NO20045254L (no) 2004-11-30
CA2477760C (fr) 2008-07-15
WO2003092423A1 (fr) 2003-11-13
CA2477760A1 (fr) 2003-11-13
RU2279235C2 (ru) 2006-07-10
BR0308463A (pt) 2005-01-11
ATE338486T1 (de) 2006-09-15
KR20050016379A (ko) 2005-02-21
MXPA04010799A (es) 2005-03-07
AU2003240394A1 (en) 2003-11-17
BR0308463B1 (pt) 2013-06-25
ES2273297T3 (es) 2007-05-01
EP1563751A1 (fr) 2005-08-17
PL371619A1 (en) 2005-06-27
US7153560B2 (en) 2006-12-26
DE50301557D1 (de) 2005-12-08
CN100438792C (zh) 2008-12-03

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