EP1561833B1 - Stahl zur Herstellung von hochfesten Bauteilen mit herausragender Tieftemperaturzähigkeit und Verwendungen eines solchen Stahls - Google Patents
Stahl zur Herstellung von hochfesten Bauteilen mit herausragender Tieftemperaturzähigkeit und Verwendungen eines solchen Stahls Download PDFInfo
- Publication number
- EP1561833B1 EP1561833B1 EP04002612A EP04002612A EP1561833B1 EP 1561833 B1 EP1561833 B1 EP 1561833B1 EP 04002612 A EP04002612 A EP 04002612A EP 04002612 A EP04002612 A EP 04002612A EP 1561833 B1 EP1561833 B1 EP 1561833B1
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- EP
- European Patent Office
- Prior art keywords
- weight
- steel
- use according
- content
- components
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 69
- 239000010959 steel Substances 0.000 title claims abstract description 69
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 229910052758 niobium Inorganic materials 0.000 claims abstract description 12
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 11
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 11
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 11
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 8
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 7
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 7
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 6
- 229910052742 iron Inorganic materials 0.000 claims abstract description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 6
- 239000012535 impurity Substances 0.000 claims description 5
- 230000000977 initiatory effect Effects 0.000 claims description 5
- 230000007704 transition Effects 0.000 claims description 4
- 229910001566 austenite Inorganic materials 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 abstract description 7
- 229910052799 carbon Inorganic materials 0.000 abstract description 6
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 abstract description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 abstract 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 abstract 2
- 239000010955 niobium Substances 0.000 abstract 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 abstract 2
- 239000011574 phosphorus Substances 0.000 abstract 2
- 239000011593 sulfur Substances 0.000 abstract 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 239000011651 chromium Substances 0.000 abstract 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 abstract 1
- 239000011733 molybdenum Substances 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 238000005096 rolling process Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- 238000005098 hot rolling Methods 0.000 description 5
- 238000005496 tempering Methods 0.000 description 4
- 230000002349 favourable effect Effects 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/44—Ferrous alloys, e.g. steel alloys containing chromium with nickel with molybdenum or tungsten
Definitions
- the invention relates to a steel for the production of high-strength components with outstanding low-temperature toughness.
- Such steels are used for example for the production of stop or lashing, as they are needed for the attachment and securing of loads.
- these steels are processed into hot-rolled bar steel, wire rod or bright steel, from which welded round steel chains are then made.
- the stainless steels 23 MnNiCrMo 5 3 and 23 MnNiCrMo 5 which are known for this purpose and are specified in DIN 17 115, each have (in% by weight) 0.20-0.26% C, ⁇ 0.25% Si, 1, 10-1.40% Mn, each 0.020% P and S, the sum of the contents of P and S not exceeding 0.035%, if necessary 0.020-0.050% Al, up to 0.014% N and 0.40-0.60% Cr.
- the steel 23 MnNiCrMo 5 2 is additionally supplemented with 0.20-0.30% Mo and 0.70-0.90% Ni, while the steel 23 MnNiCrMo 5 4 additionally has 0.50-0.60% Mo and 0.90 - contains 1.10% Ni.
- the object of the invention was therefore to provide a high-strength steel, which still has an excellent toughness even at low temperatures, so that the risk of breakage of each of the steel component produced is reduced to a minimum, even under unfavorable, harsh operating conditions.
- advantageous uses of this steel are to be specified.
- steel according to the invention for the production of high-strength components with outstanding low-temperature toughness has the following composition (in% by weight): C: 0.08 - 0.25%, Si: 0.10 - 0.30%, Mn: 0.80 - 1.60%, P: ⁇ 0.020%, S: ⁇ 0.015%, where the sum of P and S content is ⁇ 0.030%, Cr: 0.40 - 0.80%, Not a word: 0.30 - 0.50%, Ni: 0.70 - 1.20%, al: 0.020-0.060%, N: 0.007-0.018%, V: ⁇ 0.15%, Nb: ⁇ 0.07%, where the sum of V and Nb content is ⁇ 0.020%, Remaining iron and unavoidable impurities.
- the individual alloy components are selected such that a property profile which optimally meets the requirements is achieved.
- This is achieved by the inventively predetermined contents of Cr, Ni and N and the minimum sum of the contents of Nb and V.
- inventive Steel good cold forming and has high strength in the finished state.
- it is characterized by a high notched impact strength and such a low brittle fracture transition temperature that it comes only at temperatures for brittle fracture, which are substantially lower than the brittle fracture temperature of known from the prior art steels.
- the C contents lying in the range from 0.08 to 0.25% by weight ensure the good low-temperature resistance of steels according to the invention. Particularly positive results are obtained in this context if the C content is 0.16-0.23% by weight.
- the good through-hardenability and tempering resistance of the steel according to the invention is achieved .
- the safety with which this combined effect is achieved can be increased by increasing the Cr content to 0.40-0.65% by weight and the Mo contents to 0.35-0.50% by weight. % can be set.
- steel according to the invention in the sum contains at least 0.02 wt .-% Nb and V and at the same time the contents of V to max. 0.15 wt .-% and Nb to max. 0.07 wt .-% are limited, ensuring that the desired fine grain structure is still preserved even at higher temperatures.
- V is not present in the steel according to the invention or only as an unavoidable impurity.
- finished steel according to the invention regularly has an austenite grain size finer than ASTM 10.
- the fineness of the structure of the invention steel is thus substantially larger than that of known steels, for which according to DIN 17 115 an austenite grain size of ASTM 5 is required.
- the invention thus provides a steel which still has excellent toughness even at low temperatures. Due to the favorable combination of its properties, the risk of breakage of a component produced from inventive steel is reduced to a minimum even under unfavorable, harsh operating conditions.
- Steel according to the invention is preferably processed into rolled steel.
- the aim of the processing is to preserve the finest possible fine-grained structure of the steel according to the invention via each of the processing steps. This includes not only the process steps performed during heating and rolling, but also the annealing treatments that occur and performed after deformation to the component.
- the heating and rolling conditions are selected such that, despite onset of diffusion processes during heating, high rolling temperatures are avoided in order to suppress the formation of coarse grain.
- the temperatures during further forming are also selected by a controlled withdrawal of energy during hot forming so that the desired microstructure is obtained with its fine-grained structure.
- steel according to the invention is particularly suitable for the production of high-strength components by cold forming with subsequent tempering.
- These components may be, for example, means for carrying, pulling, lifting, conveying or securing loads associated with the highest strength class.
- Such summarized under the preamble stop and lashing items include, for example, attachment points, hooks, brackets, loops, chains, joints, swirl elements, rockers, struts, spindle and ratchet tensioner, load blocks and the like.
- inventive steel means for connecting components with excellent performance properties are, for example, bolts or other connection or force transmission elements, such as screws, clamps, rods or the like.
- Chains produced according to the invention can safely withstand high loads even in great cold, without the risk of breakage or comparable damage occurring.
- round steel chains, in particular welded round steel chains can be produced which are able to cope with the highest demands.
- the components made of steel according to the invention regularly have a strength of at least 1200 MPa, in particular more than 1550 MPa, 1600 MPa or 1650 MPa. It should be emphasized in this context that, with a strength of at least 1550 MPa, the brittle fracture transition temperature FATT of the components made from steel according to the invention is regularly at most - 60 ° C. This limit temperature is significantly lower than in known steels.
- the notch impact value is regularly more than 45 J and the respective component has a technical crack initiation toughness J IC of more than 170 N / mm at -60 ° C., in particular more than 185 N / mm.
- the crack initiation toughness J IC is one in the ASTM 1820 defined value, which allows an assessment of the ductile fracture tendency of a steel material.
- the high toughness of the steel according to the invention is also noticeable in that the components produced from such steel regularly have an elongation at break of more than 28%.
- the rolled steel After hot rolling and a long-term heat treatment, which was done to set a favorable for the subsequent cold working strength, the rolled steel has been formed into chain links, which have been closed after assembly of the chain by welding.
- the chains produced in this way had a fine grain structure of ASTM 11, a strength of 1270 N / mm 2 and a brittle fracture transition temperature FATT of -70 ° C determined at this strength. Its impact value was 557 J at -60 ° C test temperature and the elongation at break was 28%.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
- Heat Treatment Of Articles (AREA)
Priority Applications (12)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE200420021326 DE202004021326U1 (de) | 2004-02-05 | 2004-02-05 | Stahl zur Herstellung von hochfesten Bauteilen mit herausragender Tieftemperaturzähigkeit und Verwendungen eines solchen Stahls |
ES04002612T ES2286518T3 (es) | 2004-02-05 | 2004-02-05 | Acero para la fabricacion de componentes altamente resistentes con sobresaliente tenacidad a bajas temperaturas y usos de un acero de este tipo. |
DE502004003457T DE502004003457D1 (de) | 2004-02-05 | 2004-02-05 | Stahl zur Herstellung von hochfesten Bauteilen mit herausragender Tieftemperaturzähigkeit und Verwendungen eines solchen Stahls |
AT04002612T ATE359382T1 (de) | 2004-02-05 | 2004-02-05 | Stahl zur herstellung von hochfesten bauteilen mit herausragender tieftemperaturzähigkeit und verwendungen eines solchen stahls |
EP04002612A EP1561833B1 (de) | 2004-02-05 | 2004-02-05 | Stahl zur Herstellung von hochfesten Bauteilen mit herausragender Tieftemperaturzähigkeit und Verwendungen eines solchen Stahls |
DK04002612T DK1561833T3 (da) | 2004-02-05 | 2004-02-05 | Stål til fremstilling af höjstyrkekomponenter med fremragende lavtemperatursejhed samt anvendelser af et sådant stål |
BRPI0503588-0B1A BRPI0503588B1 (pt) | 2004-02-05 | 2005-02-04 | aÇo para produÇço de componentes de alta resistÊncia com excelente tenacidade em baixa temperatura e componentes de aÇo |
US10/551,506 US20070107808A1 (en) | 2004-02-05 | 2005-02-04 | Steel for production of high-strength components with excellent low-temperature toughness and uses of a steel of this type |
JP2006551811A JP2007520633A (ja) | 2004-02-05 | 2005-02-04 | 優れた低温じん性を有する高強度部品を製造するための鋼及び前記タイプの鋼の使用 |
CN200580000079.7A CN1764734B (zh) | 2004-02-05 | 2005-02-04 | 生产具有良好的低温韧性的高强度部件用钢以及这种类型钢的使用 |
PCT/EP2005/001163 WO2005075693A1 (de) | 2004-02-05 | 2005-02-04 | Stahl zur herstellung von hochfesten bauteilen mit herausragender tieftemperaturzähigkeit und verwendungen eines solchen stahls |
ZA200507292A ZA200507292B (en) | 2004-02-05 | 2005-09-09 | Steel for producing high tensile structural components with excellent toughness at low temperatures and uses of such a steel |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04002612A EP1561833B1 (de) | 2004-02-05 | 2004-02-05 | Stahl zur Herstellung von hochfesten Bauteilen mit herausragender Tieftemperaturzähigkeit und Verwendungen eines solchen Stahls |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1561833A1 EP1561833A1 (de) | 2005-08-10 |
EP1561833B1 true EP1561833B1 (de) | 2007-04-11 |
Family
ID=34673678
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP04002612A Expired - Lifetime EP1561833B1 (de) | 2004-02-05 | 2004-02-05 | Stahl zur Herstellung von hochfesten Bauteilen mit herausragender Tieftemperaturzähigkeit und Verwendungen eines solchen Stahls |
Country Status (11)
Country | Link |
---|---|
US (1) | US20070107808A1 (pt) |
EP (1) | EP1561833B1 (pt) |
JP (1) | JP2007520633A (pt) |
CN (1) | CN1764734B (pt) |
AT (1) | ATE359382T1 (pt) |
BR (1) | BRPI0503588B1 (pt) |
DE (1) | DE502004003457D1 (pt) |
DK (1) | DK1561833T3 (pt) |
ES (1) | ES2286518T3 (pt) |
WO (1) | WO2005075693A1 (pt) |
ZA (1) | ZA200507292B (pt) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102005034140A1 (de) * | 2005-07-19 | 2007-01-25 | Rud-Kettenfabrik Rieger & Dietz Gmbh U. Co. | Hochfeste Stahlkette für den Tieftemperaturbereich |
CN101407893B (zh) * | 2008-11-25 | 2011-04-06 | 武汉钢铁(集团)公司 | 一种高强度大线能量焊接耐火抗震建筑用钢及其生产方法 |
DE102011054840A1 (de) | 2011-10-26 | 2013-05-02 | Rud Ketten Rieger & Dietz Gmbh U. Co. Kg | Härtbarer Stahl für Hebe-, Anschlag-, Spann- und/oder Zurrmittel der Güteklasse 8 und darüber, Bauelement der Hebe-, Anschlag-, Spann- und/oder Zurrtechnik sowie Verfahren zur Herstellung eines solchen Bauelements |
CN103451529B (zh) * | 2013-08-23 | 2015-09-16 | 苏州长盛机电有限公司 | 一种铝钛铁合金材料 |
CN104532143B (zh) * | 2014-12-22 | 2016-11-16 | 江阴兴澄特种钢铁有限公司 | 一种矿用大规格、高强度链条钢及其制备方法 |
CN108603260B (zh) * | 2016-02-19 | 2021-08-13 | 日本制铁株式会社 | 钢 |
US20200165711A1 (en) * | 2016-02-19 | 2020-05-28 | Nippon Steel & Sumitomo Metal Corporation | Steel |
WO2020041085A1 (en) | 2018-08-21 | 2020-02-27 | Exxonmobil Upstream Research Company | Mooring chains comprising high manganese steels and associated methods |
CN109058278A (zh) * | 2018-09-26 | 2018-12-21 | 安徽博耐克摩擦材料有限公司 | 一种汽车刹车线 |
CN109026974A (zh) * | 2018-09-26 | 2018-12-18 | 安徽博耐克摩擦材料有限公司 | 一种汽车用刹车线 |
CN109266975B (zh) * | 2018-10-25 | 2021-08-31 | 青岛天赢智能工业股份有限公司 | 一种高强度高低温冲击韧性合金及其制备和热处理工艺 |
KR102065276B1 (ko) * | 2018-10-26 | 2020-02-17 | 주식회사 포스코 | 극저온 인성 및 연성이 우수한 압력용기용 강판 및 그 제조 방법 |
CN110484818B (zh) * | 2019-09-03 | 2020-08-14 | 山东钢铁股份有限公司 | 一种石油防喷器胶芯支撑体用钢及其生产方法 |
CN116623103A (zh) * | 2023-05-16 | 2023-08-22 | 南京钢铁股份有限公司 | 一种破断力120kN级高强链条及其制备方法 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3432368A (en) * | 1965-02-25 | 1969-03-11 | Ishikawajima Harima Heavy Ind | Method for manufacturing nitride-containing low-carbon structural steels |
US4138278A (en) * | 1976-08-27 | 1979-02-06 | Nippon Steel Corporation | Method for producing a steel sheet having remarkably excellent toughness at low temperatures |
US4605449A (en) * | 1981-05-19 | 1986-08-12 | Arbed S.A. | Process for producing a rolled steel product having high weldability, a high yield strength and a good notch impact toughness at very low temperatures |
JPH04141546A (ja) * | 1990-09-28 | 1992-05-15 | Aichi Steel Works Ltd | 熱間鍛造用非調質鋼 |
US5282906A (en) * | 1992-01-16 | 1994-02-01 | Inland Steel Company | Steel bar and method for producing same |
US5352304A (en) * | 1992-11-16 | 1994-10-04 | Allegheny Ludlum Corporation | High strength low alloy steel |
AU663023B2 (en) * | 1993-02-26 | 1995-09-21 | Nippon Steel Corporation | Process for manufacturing high-strength bainitic steel rails with excellent rolling-contact fatigue resistance |
JPH10168542A (ja) * | 1996-12-12 | 1998-06-23 | Nippon Steel Corp | 低温靭性と疲労強度に優れた高強度鋼材及びその製造方法 |
JP4132545B2 (ja) * | 2000-02-23 | 2008-08-13 | 新日本製鐵株式会社 | 低サイクル疲労特性の優れた高強度・高靭性免震ダンパー用鋼棒 |
CN1108397C (zh) * | 2000-06-02 | 2003-05-14 | 江阴兴澄钢铁有限公司 | 高强度、高韧性、耐腐蚀系泊链用钢及其生产工艺 |
GB2392919B (en) * | 2002-09-12 | 2005-01-19 | Corus Uk Ltd | Corrosion resistant steels |
-
2004
- 2004-02-05 DE DE502004003457T patent/DE502004003457D1/de not_active Expired - Lifetime
- 2004-02-05 AT AT04002612T patent/ATE359382T1/de active
- 2004-02-05 EP EP04002612A patent/EP1561833B1/de not_active Expired - Lifetime
- 2004-02-05 DK DK04002612T patent/DK1561833T3/da active
- 2004-02-05 ES ES04002612T patent/ES2286518T3/es not_active Expired - Lifetime
-
2005
- 2005-02-04 US US10/551,506 patent/US20070107808A1/en not_active Abandoned
- 2005-02-04 JP JP2006551811A patent/JP2007520633A/ja active Pending
- 2005-02-04 BR BRPI0503588-0B1A patent/BRPI0503588B1/pt active IP Right Grant
- 2005-02-04 CN CN200580000079.7A patent/CN1764734B/zh active Active
- 2005-02-04 WO PCT/EP2005/001163 patent/WO2005075693A1/de active Application Filing
- 2005-09-09 ZA ZA200507292A patent/ZA200507292B/xx unknown
Also Published As
Publication number | Publication date |
---|---|
DE502004003457D1 (de) | 2007-05-24 |
ES2286518T3 (es) | 2007-12-01 |
BRPI0503588A (pt) | 2006-03-07 |
EP1561833A1 (de) | 2005-08-10 |
DK1561833T3 (da) | 2007-08-20 |
JP2007520633A (ja) | 2007-07-26 |
CN1764734A (zh) | 2006-04-26 |
WO2005075693A1 (de) | 2005-08-18 |
BRPI0503588B1 (pt) | 2013-09-10 |
US20070107808A1 (en) | 2007-05-17 |
CN1764734B (zh) | 2010-12-08 |
ZA200507292B (en) | 2007-04-25 |
ATE359382T1 (de) | 2007-05-15 |
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