EP1541751A1 - Use of protective colloid stabilized polymers as coatings - Google Patents

Abstract

Use of protective colloid-stabilized polymer, comprising a protective colloid (I) and a polymer (II), for coating a substrate material with a double-dot coating is claimed.

Description

The invention relates to the use of a protective colloid-stabilized polymer for Coating of a carrier material.

For the bonding of textile materials, for example, such a material with a Hot melt adhesive coated and then glued to a second, superimposed material become. One possible coating is the so-called double dot coating (double dot coating). In this case, a sub-item is first printed on the material to be coated. This printing can be done by rotary screen printing. The sub-item is a paste containing an aqueous dispersion of an emulsifier-stabilized polymer, thickener and optionally pressure assistants. On the still wet sub-point is then Hot melt glue spread. Excess powder is sucked off. After that, the Subpoint with the hot melt adhesive powder first dried and sintered, or Hot melt adhesive is melted.

An example of a double-point coating is described in EP 0 547 261 B1. There there is disclosed a coated sheet comprising a coating carrier (present also referred to as a carrier material), a base or base layer applied thereon a plastic compound (also referred to herein as sub-item) and one on it provided second layer (also referred to herein as hot melt adhesive) comprises. The Base layer is composed of a crosslinkable, aqueous polymer dispersion, emulsion and / or solution produced. As polymer dispersions, self-crosslinking acrylic polymers, self-crosslinking polyvinyl esters or self-crosslinking styrene-acrylic or acrylic-vinyl ester copolymers used. The polymers used preferably have one Film formation temperature of at least 5 ° C and are usually in dispersion or emulsion form sour.

The disadvantage of this double-point coating is the adhesion values for the bonds Laundry and dry cleaning. The rheological behavior and the drying of the paste on the stencil in the rotary screen printing give a poor processing behavior.

The present invention is therefore based on the object to overcome these disadvantages.

According to the invention, this is achieved by the use of a protective colloid-stabilized polymer, comprising a protective colloid and a polymer, dissolved for coating a support material.

That a protective colloid-stabilized polymer at all for coating a Support material, e.g. textile material, which was then suitable for bonding Professional completely surprising. Prerequisite for bonding textile materials is that the bond during washing or cleaning is not solved. The expert but expects that protective colloid-stabilized polymers are soluble and thus the resulting adhesions with textiles are dissolved during washing. Surprisingly, however, this was not observed. Rather, it was even found in that the bonds obtainable using protective colloid-stabilized polymers very resistant to washing and cleaning.

The polymers used to date for coatings, in particular double-dot coatings, are, inter alia, emulsifier-stabilized polymers. Emulsifiers are compounds which can be subsumed under the term "surfactants". Protective colloids are surface-active substances, but they have very characteristic differences to surfactants. A characteristic feature of surfactants and their solutions is micelle formation. As the surfactant concentration increases, the number of molecules increases at the interface until there is no room for more. Then the time for the formation of micelles is given. One refers to detached aggregates of a larger number of surfactant molecules or ions as micelles. They are dynamic entities in equilibrium with the surrounding solution. The formation of micelles starts in a narrow range of concentration characteristic of each surfactant and depends on the molecular structure. It occurs at the concentration at which the surface is completely or substantially fully occupied and therefore the surface tension becomes independent of the increase in the concentration. By measuring the surface tension as a function of the concentration, the concentration at which the micelle formation begins can be determined in a simple manner. It is called the critical micelle concentration (CMC). Furthermore, the term "HLB value" (hydrophilic-lipophilic balance) was introduced for the characterization of surfactants. The surfactants are characterized according to the hydrophilic and hydrophobic groups taking into account the structure. The determination of the HLB value is based on empirical data: HLB = 20 (1-M0 / M), where M0 denotes the weight of the hydrophobic moiety and M denotes the total molecular weight.

Both the critical micelle formation concentration and the HLB value are characteristic Properties of surfactants and their solutions. Both properties have the Protective colloids not.

Protective colloid-stabilized polymers are known to the person skilled in the art. They are commercial or can be obtained by free-radically initiated polymerization of monomers below and optionally Hilfsmonomere be prepared. The free-radical polymerization of ethylenic unsaturated monomers can be made by suspension or emulsion polymerization. In the suspension and emulsion polymerization, in the presence of surface-active Substances of composition of 100-51% protective colloids and 0-49% emulsifiers polymerized. Suitable emulsifiers are both anionic, cationic and nonionic emulsifiers, for example anionic surfactants, such as alkyl sulfates having a Chain length of 8 to 18 carbon atoms, alkyl or alkylaryl ether sulfates having 8 to 18 carbon atoms in hydrophobic group and up to 60 ethylene or propylene oxide units, alkyl or Alkylarylsulfonate with 8 to 18 C-atoms, esters and half esters of sulfosuccinic acid with monohydric alcohols or alkylphenols, or nonionic surfactants such as alkyl polyglycol ethers or alkylaryl polyglycol ethers having up to 60 ethylene oxide or propylene oxide units.

Particularly preferred representatives of protective colloids are modified natural polymers, such as O-methylcellulose, O- (2-hydroxy-ethyl) -cellulose, O- (2-hydroxy-propyl) -cellulose, O- (2-hydroxy-propyl) -O-methyl-cellulose, O- (2-hydroxybutyl) -O-methyl-cellulose, carboxymethylcellulose (Na salt), starch ether, O- (2-hydroxypropyl) starch and lignosulfonic acid, synthetic homopolymers and copolymers, such as poly (vinyl alcohol) [partially saponified poly (vinyl acetate)], Poly (vinyl alcohol-co-ethylene), poly (methacrylic acid-sodium salts), poly [methacrylic acid-sodium-salt-co- (methacrylic acid-methyl ester)], Poly [acrylic acid-co-acrylic acid (2-ethyl-hexyl)], Poly [methacrylic acid (hydroxyl-alkyl ester)], poly (styrene-co-maleic acid-sodium salt), Poly (styrene-4-sulfonic acid-sodium-salt-co-maleic acid half ester), poly (ethylene-co-maleic acid-partial-ester) poly (oxirane), Poly (alkyl) vinyl ether), poly (acrylic acid sodium salt), poly (alkyl vinyl ether-co-maleic anhydride), Poly (vinyl acetate-co-maleic acid anhydride), poly (1-vinyl-2-pyrrolidone), Poly [(1-vinyl-2-pyrrolidone) -co-methacrylic acid alkyl ester], poly [(1-vinyl-2-pyrrolidone) -co-methacrylamide], Poly (vinyl pyridine) and poly (diallyl dimethyl ammonium chloride), Graft polymers, such as poly (vinyl chloride-g-vinyl alcohol), poly (styrene-g-vinyl alcohol), poly (styrene-g-acrylic acid), Poly [styrene-g- (1-vinyl-2-pyrrolidone)] and poly [acrylic acid tert-butyl ester g- (1-vinyl-2-pyrrolidone)], as well as condensation products, such as urea-formaldehyde condensates, Phenol-formaldehyde condensates and alkyd resins.

The polymers of the protective colloid-stabilized polymer are described below with reference to Monomers explained in more detail. Among polymers in the sense of the present invention are both Homo- and copolymers to understand. The monomers may be ethylenic unsaturated monomers act. These can be selected from vinyl esters of unbranched or branched alkylcarboxylic acids having 1 to 18 carbon atoms, acrylic acid esters or methacrylic acid esters of branched or unbranched alcohols or diols with 1 to 18 C atoms, C2-C20 mono- or di-carboxylic acids, their amides, N-methylolamides or Nitriles, C2-C20 sulfonic acids, 3-20-membered heterocyclic compounds with oxygen, Sulfur, selenium, tellurium, nitrogen, phosphorus, boron or aluminum as heteroatom, dienes with at least 4 C atoms, olefins having at least 2 C atoms, vinyl aromatics in particular with Benzene or naphthalene as aromatic, and C2-C20 vinyl halides.

Preferred vinyl esters are those having 1 to 12 C atoms, in particular vinyl acetate, Vinyl propionate, vinyl butyrate, vinyl 2-ethylhexanoate, vinyl laurate, 1-methyl vinyl acetate, vinyl pivalate and vinyl esters of α-branched monocarboxylic acids having 9 to 13 C atoms.

In a further preferred embodiment, the acrylic or methacrylic acid ester an ester of unbranched or branched alcohols having 1 to 15 carbon atoms, in particular Methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, n-butyl acrylate, n-butyl methacrylate, t-butyl acrylate, t-butyl methacrylate and 2-ethylhexyl acrylate, especially methyl acrylate, methyl methacrylate, n-butyl acrylate, t-butyl acrylate, t-butyl acrylate and 2-ethylhexyl acrylate.

Preferred mono- and di-carboxylic acids, their amides, N-methylol amides and nitriles selected from acrylic acid, methacrylic acid, fumaric acid, maleic acid, acrylamide, N-methylolacrylamide, N-methylolmethacrylamide and acrylonitrile.

The sulfonic acid is conveniently vinylsulfonic acid and 2-acrylamido-2-methylpropanesulfonic acid selected. The preferred heterocyclic compounds are Vinyl pyrrolidone and vinyl pyridine.

Preferably, the vinyl aromatic is styrene, methyl styrene or vinyl toluene.

Preferably, the vinyl halide is vinyl chloride.

In a preferred embodiment of the use according to the invention, the olefin selected from ethylene and propylene.

Preferred dienes are selected from 1,3-butadiene and isoprene.

In the use according to the invention, several, different from each other protective colloid-stabilized polymers are used.

Optionally, from 0.1 to 50 wt .-%, based on the total weight of Monomeric, Hilfsmonomere be copolymerized. Preference is given to 0.5 to 15 % By weight of auxiliary monomers used. Examples of auxiliary monomers are ethylenically unsaturated C2-C20 mono- and dicarboxylic acids, preferably acrylic acid, methacrylic acid, fumaric acid and maleic acid; ethylenically unsaturated C 2 -C 20 -carboxylic acid amides and nitriles, preferably acrylamide and acrylonitrile; Mono- and diesters of fumaric acid and maleic acid such as the diethyl and diisopropyl esters, as well as maleic anhydride, ethylenically unsaturated C 2 -C 20 -sulfonic acids or their salts (alkali, alkaline earth and ammonium salts), preferably Vinylsulfonic acid, 2-acrylamido-2-methylpropanesulfonic acid. Other examples are precrosslinking C2-C20 comonomers, such as polyethylenically unsaturated comonomers, For example, divinyl adipate, diallyl maleate, diallyl phthalate, allyl methacrylate or Triallyl cyanurate, or post-crosslinking comonomers, for example Acrlyamidoglykolsäure (AGA), Methylacrylamidoglycolic acid methyl ester (MAGME), N-methylolacrylamide (NMA), N-methylolmethacrylamide, N-methylolallyl carbamate, C2-C20 alkyl ethers, such as the isobutoxy ether or esters of N-methylolacrylamide, N-methylolmethacrlyamide and N-methylolallylcarbamate. Also suitable are epoxide-functional C2-C20 comonomers such as Glycidyl methacrylate and glycidyl acrylate. Further examples are silicon-functional C2-C20 comonomers such as acryloxypropyltri (alkoxy) and methacryloxypropyltri (alkoxy) silanes, Vinyltrialkoxysilane and Vinylmethyldialkoxysilane, wherein as alkoxy groups, for example Ethoxy and Ethoxypropylenglykolether residues may be included. Also mentioned are C2-C20 monomers with hydroxy or CO groups, for example methacrylic acid and Acrylic acid hydroxyalkyl esters, such as hydroxyethyl, hydroxypropyl or hydroxybutyl acrylate or methacrylate and compounds such as diacetoneacrylamide and acetylacetoxyethyl acrylate or methacrylate.

By the copolymerization of the monomers described above with the Auxiliary monomers can control the properties of the coatings, such as adhesion, cross-linking and Stabilization, be favorably influenced.

More preferably, the polymers are prepared from monomers or mixtures which one or more monomers from the group vinyl acetate, vinyl esters of α-branched Monocarboxylic acids having 9 to 13 C atoms, vinyl chloride, ethylene, methyl acrylate, Methyl methacrylate, ethyl acrylate, ethyl methacrylate, propyl acrylate, propyl methacrylate, n-butyl acrylate, n-butyl methacrylate, 2-ethylhexyl acrylate or styrene. Most preferred are mixtures of vinyl acetate with ethylene; of vinyl acetate, ethylene and a Vinyl esters of α-branched monocarboxylic acids having 9 to 13 carbon atoms; of n-butyl acrylate, 2-ethylhexyl acrylate and / or methyl methacrylate; of styrene with one or more monomers from the group of methyl acrylate, ethyl acrylate, propyl acrylate, n-butyl acrylate, 2-ethylhexyl acrylate; of vinyl acetate with one or more monomers from the group of methyl acrylate, Ethyl acrylate, propyl acrylate, n-butyl acrylate, 2-ethylhexyl acrylate and optionally ethylene; wherein said mixtures optionally still one or more of the above May contain auxiliary monomers. These mixtures have proven to be particularly favorable because they show excellent properties in coatings at low cost.

The monomer selection or the selection of the proportions by weight of the comonomers can be so be carried out that in general a glass transition temperature Tg of -50 ° C to + 120 ° C, preferably -30 ° C to + 95 ° C results. The glass transition temperature Tg of the polymer can be determined in a known manner by means of differential scanning calorimetry (DSC). The Tg can also be approximated by the Fox equation. After Fox T.G., Bull. Am. Physics Soc. 1, 3, p. 123 (1956): 1 / Tg = x1 / Tg1 + x2 / Tg2 + ... + xn / Tgn, where xn represents the mass fraction (wt .-% / 100) of the monomer n, and Tgn the Glass transition temperature in Kelvin of the homopolymer of the monomer n. Tg values for Homopolymers are described in Polymer Handbook 2nd Edition, J. Wiley & Sons, New York (1975) listed.

The polymerization of the above monomers and optionally auxiliary monomers to the polymer can be radically intiiert. The radically initiated polymerization of the ethylenically unsaturated Monomers can be made by suspension polymerization and emulsion polymerization.

The polymerization temperature may be 40 ° C to 100 ° C, preferably 60 ° C to 90 ° C. In the copolymerization of gaseous comonomers, such as ethylene, 1,3-butadiene or Vinyl chloride, can also under pressure, generally between 5 bar and 100 bar, worked become. The initiation of the polymerization can be carried out with the customary water-soluble or monomer-soluble initiators or redox initiator combinations take place. examples for water-soluble initiators are the sodium, potassium and ammonium salts of Peroxodisulfuric acid, hydrogen peroxide, t-butyl peroxide, potassium peroxodiphosphate, t-butyl peroxopivalate, Cumene hydroperoxide, isopropylbenzene monohydroperoxide, azobisisobutyronitrile. Examples of monomer-soluble initiators are dicetyl peroxydicarbonate, dicyclohexyl peroxydicarbonate, Dibenzoyl peroxide, tert-butyl peroxyneodecanoate, tert-butyl peroxy-2-ethylhexanoate and tert-butyl peroxypivalate. The mentioned initiators are in the In general, in an amount of 0.01 to 10.0 wt .-%, preferably 0.1 to 0.5 wt .-%, respectively based on the total weight of the monomers, used as redox initiators Combinations of the mentioned initiators can be used with reducing agents. Suitable reducing agents are the sulfites and bisulfites of the alkali metals and of ammonium, For example, sodium sulfite, the derivatives of sulfoxylic acid, such as zinc or Alkali metal formaldehyde sulfoxylates, for example sodium hydroxymethanesulfinate, and ascorbic acid. The amount of reducing agent is generally from 0.01 to 10.0 wt .-%, preferably 0.1 to 0.5 wt .-%, each based on the total weight of the monomers.

The monomers can be submitted in total, be metered in total or in Shares are submitted and added the remainder after the initiation of the polymerization become. The dosages can be carried out separately (spatially and temporally) or the All or part of the components to be dosed can be added pre-emulsified.

In the preferred methods of suspension and emulsion polymerization can be polymerized in the presence of the aforementioned protective colloids to the produce protective colloid-stabilized polymers.

The present invention, in particular in the above-described preferred Embodiments has a number of advantages: First, it has been found that very low compared to other prior art coating methods Coating quantities are sufficient for sufficiently good adhesion. This is one To achieve a significant reduction in costs, and exhibit the bonded textile materials a pleasant soft grip on. With the invention used Protective colloid-stabilized polymers is a very high adhesion of the bonded textiles determine. The connection of the scattering powder to the sub-point is very good. The Adhesions associated with the coating using a protective colloid stabilized polymer are very good wash and cleaning resistant. In addition, the penetrates with the sub-dot obtained in the protective colloid-stabilized polymer in the case of the double-point coating not in the textile substrate, i. A very effective kickback is achieved. Furthermore, pastes containing the protective colloid-stabilized polymer and to Making the subpoint used in colon coatings is a very good one Rheology and do not dry on the template.

For the production of coatings on support materials, the protective colloid-stabilized Polymers are used in the form of a paste. For the production of such Paste is made from a dispersion of the protective colloid-stabilized polymer in water went out. The amount of water, for example, about 70 wt .-%, based to the dispersion, and that of the protective colloid stabilized polymer about 30 wt .-%, also based on the dispersion amount. These polymer dispersions can then thickener and optionally printing assistant may be added, which then paste for coating to be obtained.

These pastes can, for example in rotary screen printing on the coated Carrier material can be applied. In this way, a sub item for the Colon coating are produced. At the subpoint can then Melted hot melt powder are sprinkled. Excess powder can subsequently be sucked off become. The sub-item can then be dried and sintered, or the scattering powder be melted.

The above-mentioned polymer dispersions have the advantage that they can be obtained by adding Compounds containing 2 or more epoxide, organo, halogen, hydroxy, aziridine, carbodiimide, Oxazoline, alcohol, amine, aminosilane, aminoformaldehyde, isocyanate or N-2-hydroxyalkylamide residues can be networked. In addition to the intramolecular crosslinking of the Polymer also occurs a crosslinking of the polymer with the Schutzkolloidhülle and with the added additives. As a result, particularly high adhesive strengths are achieved.

In the final formulation of the dispersion or the paste can still submit crosslinkers, for example, compounds having two or more epoxy, organo, halogen, hydroxy, Aziridine, carbodiimide, oxazoline, alcohol, amine, aminosilane, aminoformaldehyde, isocyanate or N-2-hydroxyalkylamide residues.

The substrates that can be coated may be materials to act of any kind. It can be flexible, not very flexible or not flexible at all. examples are textile materials of any kind, such as woven, knitted, woven knitted fabric, Raschelwaren (natural and synthetic fibers), fleece of any material. Furthermore, films can be coated be made, in particular of plastics of any kind, as well as paper, artificial leather, leather, Synthetic leather, foam and wood.

The invention will be explained below by way of example, without her mind limit.

Example 1: Production of a ready-to-print sub-grade paste from polymer dispersions without / with crosslinker

Dispersion 1 Vinylacetat/Ethylen-Dispersion mit einer Glasübergangstemperatur T_g (DSC) = +3°C, die polyvinylalkoholstabilisiert ist.

Dispersion 2 Styrol/Butadien-Dispersion mit einer Glasübergangstemperatur T_g (DSC) = +5°C, die polyvinylalkoholstabilisiert ist.

Dispersion 3 Acrylat-Dispersion mit einer Glasübergangstemperatur T_g (DSC) = +1°C, die polyvinylalkoholstabilisiert ist.

Tebelink® B-IC = Polysocyanat, modifiziert, Dr. Th. Böhme KG Chem. Fabrik GmbH & Co.
Tebelink® MFA = Partiell verethertes, modifiziertes Melamin-Formaldehyd-Kondensat, formaldehydarm (0,3%), Dr. Th. Böhme KG Chem. Fabrik GmbH & Co.

Comparative Dispersion 0 Self-crosslinking acrylate dispersion having a glass transition temperature T _g (DSC) = + 2 ° C., which is emulsifier-stabilized.

Dispersion 1 Vinyl acetate / ethylene dispersion having a glass transition temperature T _g (DSC) = + 3 ° C, which is polyvinyl alcohol stabilized.

Dispersion 2 styrene / butadiene dispersion having a glass transition temperature T _g (DSC) = + 5 ° C, which is polyvinyl alcohol stabilized.

Dispersion 3 acrylate dispersion with a glass transition temperature T _g (DSC) = + 1 ° C, which is polyvinyl alcohol stabilized.

Tebelink® B-IC = polysocyanate, modified, Dr. med. Th. Boehme KG Chem. Fabrik GmbH & Co.
Tebelink® MFA = partially etherified, modified melamine-formaldehyde condensate, low in formaldehyde (0.3%), Dr. Ing. Th. Boehme KG Chem. Fabrik GmbH & Co.

Submit water, stir in acrylate thickener until a homogeneous, viscous paste has formed and then add the polymer dispersion with stirring. When crosslinkers are used, they are added to the paste and stirred in homogeneously.
To improve the printability printing auxiliary agents such as alcohols and high molecular weight polyethylene oxide can be added. Paste viscosity varies depending on the coating machine. Typical values are between 7,000-15,000 m Pas, Haake Rotovisko VT02, spindle 2.

printing process

Rotary screen printing: Template CP 66, hole diameter 375 μm

Speed: 10 m / min, 150 ° C in the drying channel

Scattering powder: copolyamide, melting range approx. 115-125 ° C, powder 80-160 μm

2 substrates: standard non-woven (100% PES), fabric (100% PES, highly hydrophobic, elastic)

lamination

Kaschierbedingungen: 127°C Fugentemperatur, Durchlaufgeschwindigkeit 6 m/min, Fixierzeit: 10.5 s, Fixierdruck: 4 Bar

Kaschiermaterial: 55% Polyester/45% Wolle

Nr. Auflage
[g/m²] Unter-Punkt
[g/m²] Ober-Punkt
[g/m²] Original-Haftung Chemische Reinigung
(1 x) 40°C Wäsche
(1 x) 0a 11 4 7 8,0 6,6 8,4 1a 11 4 7 11,0 10,3 8,5 2a 11 4 7 11,5 10,7 8,9 3a 11 4 7 9,5 9,6 7,5 0b 11 4 7 8,5 8,4 7,3 1b 11 4 7 11,9 10,7 9,1 2b 11 4 7 12,2 10,9 9,5 3b 11 4 7 10,3 10,4 8,6 0c 11 4 7 8,2 7,4 8,5 1c 11 4 7 11,8 10,8 9,1 2c 11 4 7 12,3 11,7 9,9 3c 11 4 7 10,9 10,2 8,9 Laminating press Fa. Mayer

Laminating conditions: 127 ° C joint temperature, flow rate 6 m / min, fixing time: 10.5 s, fixing pressure: 4 bar

Lining material: 55% polyester / 45% wool

No. edition
[g / m ² ] Under Point
[g / m ² ] Ober-point
[g / m ² ] Original liability Chemical cleaning
(1 x) 40 ° C laundry
(1 x) 0a 11 4 7 8.0 6.6 8.4 1a 11 4 7 11.0 10.3 8.5 2a 11 4 7 11.5 10.7 8.9 3a 11 4 7 9.5 9.6 7.5 0b 11 4 7 8.5 8.4 7.3 1b 11 4 7 11.9 10.7 9.1 2 B 11 4 7 12.2 10.9 9.5 3b 11 4 7 10.3 10.4 8.6 0c 11 4 7 8.2 7.4 8.5 1c 11 4 7 11.8 10.8 9.1 2c 11 4 7 12.3 11.7 9.9 3c 11 4 7 10.9 10.2 8.9

Claims (18)

Use of a protective colloid-stabilized polymer comprising a protective colloid and a polymer for coating a carrier material. Use according to claim 1, wherein the protective colloid is selected from modified natural polymers, synthetic homo- and copolymers, graft polymers and condensation products. Use according to any one of the preceding claims wherein the polymer is of at least one ethylenically unsaturated monomer can be produced, which is selected from Vinyl esters of unbranched or branched alkylcarboxylic acids having 1 to 18 carbon atoms, Acrylic or methacrylic esters of branched or unbranched alcohols or Diols with 1 to 18 C atoms, C2-C20 mono- or di-carboxylic acids, their amides, N-methylolamides or nitriles, C2-C20 sulfonic acids, 3-20-membered heterocyclic compounds with oxygen, sulfur, selenium, tellurium, nitrogen, phosphorus, boron and aluminum as Heteroatom, dienes having at least 4 C atoms, olefins having at least 2 C atoms, Vinylaromatics and C2-C20 vinyl halides. Use according to claim 3, wherein the vinyl ester is selected from vinyl acetate, Vinyl propionate, vinyl butyrate, vinyl 2-ethylhexanoate, vinyl laurate, 1-methyl vinyl acetate, vinyl pivalate and vinyl esters of α-branched monocarboxylic acids having 9 to 13 C atoms. Use according to claim 3, wherein the acrylic acid or methacrylic acid ester is selected from methyl acrylate, methyl methacrylate, ethyl acrylate, ethyl methacrylate, Propyl acrylate, propyl methacrylate, n-butyl acrylate, n-butyl methacrylate, t-butyl acrylate, t-butyl methacrylate, 2-ethylhexyl acrylate. Use according to claim 3, wherein the mono- and di-carboxylic acids, their amides, N-methylolamides and nitriles are selected from acrylic acid, methacrylic acid, fumaric acid, Maleic acid, acrylamide, N-methylolacrylamide, N-methylolmethacrylamide and acrylonitrile. Use according to claim 3, wherein the sulfonic acid is selected from Vinylsulfonic acid and 2-acrylamido-2-methyl-propanesulfonic acid. Use according to claim 3, wherein the heterocyclic compound is selected under vinylpyrrolidone and vinylpyridine. Use according to claim 3, wherein the vinyl aromatic is selected from styrene, Methylstyrene and vinyltoluene. Use according to claim 3, wherein the vinyl halide is vinyl chloride. Use according to claim 1, wherein the olefin is selected from ethylene and Propylene. Use according to claim 3, wherein the diene is selected from 1,3-butadiene and Isoprene. Use according to one of the preceding claims, wherein for the production of the Polymer in addition to the monomer an auxiliary monomer in an amount of 0.1 to 50 wt .-%, based on the total weight of the polymer is used. Use according to any one of the preceding claims, wherein the polymer is a Glass transition temperature Tg of -50 ° C to 120 ° C has. Use according to one of the preceding claims, wherein the protective colloid-stabilized polymer in the form of an aqueous dispersion. Use according to one of the preceding claims, wherein the protective colloid-stabilized polymer in the form of a paste. Use according to one of the preceding claims, wherein the coating by Rotary screen printing is done. Use according to one of the preceding claims, wherein the coating has a Colon coating is.