EP1485528A2 - Insulating material - Google Patents

Insulating material

Info

Publication number
EP1485528A2
EP1485528A2 EP20030744608 EP03744608A EP1485528A2 EP 1485528 A2 EP1485528 A2 EP 1485528A2 EP 20030744608 EP20030744608 EP 20030744608 EP 03744608 A EP03744608 A EP 03744608A EP 1485528 A2 EP1485528 A2 EP 1485528A2
Authority
EP
European Patent Office
Prior art keywords
fibers
polyethylene terephthalate
bicomponent
nylon
mixtures
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP20030744608
Other languages
German (de)
French (fr)
Inventor
Jeffrey A. Tilton
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Owens Corning Intellectual Capital LLC
Original Assignee
Owens Corning
Owens Corning Fiberglas Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Owens Corning, Owens Corning Fiberglas Corp filed Critical Owens Corning
Publication of EP1485528A2 publication Critical patent/EP1485528A2/en
Withdrawn legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/54Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
    • D04H1/541Composite fibres, e.g. sheath-core, sea-island or side-by-side; Mixed fibres
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H5/00Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length
    • D04H5/06Non woven fabrics formed of mixtures of relatively short fibres and yarns or like filamentary material of substantial length strengthened or consolidated by welding-together thermoplastic fibres, filaments, or yarns
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/42Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
    • GPHYSICS
    • G10MUSICAL INSTRUMENTS; ACOUSTICS
    • G10KSOUND-PRODUCING DEVICES; METHODS OR DEVICES FOR PROTECTING AGAINST, OR FOR DAMPING, NOISE OR OTHER ACOUSTIC WAVES IN GENERAL; ACOUSTICS NOT OTHERWISE PROVIDED FOR
    • G10K11/00Methods or devices for transmitting, conducting or directing sound in general; Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
    • G10K11/16Methods or devices for protecting against, or for damping, noise or other acoustic waves in general
    • G10K11/162Selection of materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60RVEHICLES, VEHICLE FITTINGS, OR VEHICLE PARTS, NOT OTHERWISE PROVIDED FOR
    • B60R13/00Elements for body-finishing, identifying, or decorating; Arrangements or adaptations for advertising purposes
    • B60R13/08Insulating elements, e.g. for sound insulation
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
    • E04B1/76Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
    • E04B2001/7687Crumble resistant fibrous blankets or panels using adhesives or meltable fibres
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/608Including strand or fiber material which is of specific structural definition
    • Y10T442/627Strand or fiber material is specified as non-linear [e.g., crimped, coiled, etc.]
    • Y10T442/632A single nonwoven layer comprising non-linear synthetic polymeric strand or fiber material and strand or fiber material not specified as non-linear
    • Y10T442/633Synthetic polymeric strand or fiber material is of staple length
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/637Including strand or fiber material which is a monofilament composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/637Including strand or fiber material which is a monofilament composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material
    • Y10T442/638Side-by-side multicomponent strand or fiber material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/637Including strand or fiber material which is a monofilament composed of two or more polymeric materials in physically distinct relationship [e.g., sheath-core, side-by-side, islands-in-sea, fibrils-in-matrix, etc.] or composed of physical blend of chemically different polymeric materials or a physical blend of a polymeric material and a filler material
    • Y10T442/641Sheath-core multicomponent strand or fiber material

Definitions

  • the present invention relates generally to the field of acoustical and thermal insulation and, more particularly, to a unique new insulating material of low-melt and high-melt bicomponent fibers exhibiting a unique blend of structural and acoustical insulating properties.
  • Acoustical and thermal liners for application to vehicles are well known in the art. These liners typically rely upon both sound absorption, that is the ability to absorb incident sound waves and transmission loss, that is the ability to reflect incident sound waves, in order to provide sound attenuation. They also rely upon thermal shielding properties to prevent or reduce the transmission of heat from various heat sources (for example engine, transmission and exhaust system), to the passenger compartment of the vehicle. Such insulation is commonly employed as a hoodliner, dash liner and firewall liner. More recently, such liners have been employed on engine covers so as to attenuate the sound of the engine closer to its source. Examples of acoustical and thermal insulation in the form of liners are disclosed in a number of prior art patents including U.S.
  • Patents 4,851,283 to Holtrop et al. and 6,008,149 to Copperwheat As should be apparent from a review of these two patents, engineers have generally found it necessary to construct such liners from a laminate incorporating (a) one or more layers to provide the desired acoustical and thermal insulating properties and (b) one or more additional layers to provide the desire mechanical strength properties which allow simple and convenient installation as well as proper functional performance over a long service life.
  • laminated liners and insulators While a number of adhesives, adhesive webs and binding fibers have been specifically developed over the years to secure the various layers of the laminates together, laminated liners and insulators have an inherent risk of delamination and failure. The potential is, in fact, significant mainly due to the harsh operating environment to which such liners and insulators are subjected. Many liners and insulators are located near and/or are designed to shield high heat sources such as the engine, transmission and components of the exhaust system. As a result, the liners and insulators are often subjected to temperatures in excess of 200°F which have a tendency to degrade the adhesives or binders over time.
  • liners and insulators are subjected to water from the surface of the roadways which has a tendency to be drawn by capillary action into the interface between the layers of the liner or insulator. Such water may have a deleterious affect upon the integrity of the adhesive layer over time. This is particularly true when that water includes in solution salt or other chemicals from the roadway which are corrosive and destructive.
  • a need is therefore identified for a hood, dash, firewall or engine cover liner incorporating a nonlaminate acoustical and thermal insulating layer of polymer fibers • which avoids any inherent potential for delamination.
  • Such a liner is suitable for use in the high temperature operating environment of the engine compartment and capable of providing the desired mechanical strength and rigidity for ease of installation as well as the desired acoustical and thermal insulating properties.
  • the present invention relates to an insulating material exhibiting a unique combination of acoustical insulating and strength/ structural properties.
  • the insulating material comprises in weight percent from about 20-60% low melt bicomponent fiber, 10-40% high melt bicomponent fiber and 20-60% staple fiber.
  • the melt includes an average fiber diameter of between about 10-30 microns, more typically 16-24 microns and most typically 18-22 microns.
  • the material has a density of between about 1.0-10.0 pcf (16.02-160.2 kg/m 3 ) and a flexural strength of between about 40-1200 psi (275.79- 8273.71 kPa).
  • the insulating material has the acoustical absorption coefficients as follows: 0.17-0.24 at a frequency of 500 Hz, 0.29- 0.63 at a frequency of 1000 Hz, 0.50-0.94 at a frequency of 2000 Hz and 0.71-0.99 at a frequency of 4000 Hz all at 2 pcf (32.04 km/g 3 ) density.
  • the insulating material has a thermal conductivity value of between about 0.20 and 0.30 at 2 pcf (32.04 km/g 3 ) density.
  • the staple or bulking fibers are selected from a group of materials consisting of polyester fibers, polyethylene fibers, polypropylene fibers, nylon fibers, rayon fibers, glass fibers, natural fibers and mixtures thereof.
  • the low melt bicomponent fibers are selected from a group of materials consisting of copolyester/polyethylene terephthalate (CoPET/PET), poly 1,4 cyclohexanedimethyl terephthalate/polyethylene terephthalate (PCT/PET), poly 1,4 cyclohexanedimethyl terephthalate/ polypropylene (PCT/PP), glycol-modified polyethylene terephthalate/ polyethylene terephthalate (PETG/PET), propylene/polyethylene terephthalate (PP/PET), nylon 6/nylon 66, polyethylene/glass, or other combinations of polymers including polymer/glass and polymer/natural fiber that yield differential melt flow temperatures.
  • CoPET/PET copolyester/polyethylene terephthalate
  • PCT/PET poly 1,4 cyclohexanedimethyl terephthalate/polyethylene terephthalate
  • PCT/PP poly 1,4 cyclo
  • the bicomponent fibers may be any of a variety of configurations that yield acceptable fiber binding such as sheath-core, side-by-side, segmented pie, etc.
  • the low melt bicomponent fibers are described as having a melt flow temperature of about 100°C to 130°C (212°F to 266°F).
  • the high melt bicomponent fibers are selected from a group of materials consisting of copolyester/polyethylene terephthalate (CoPET/PET), poly 1,4 cyclohexanedimethyl terephthalate/polyethylene terephthalate (PCT/PET), poly 1,4 cyclohexanedimethyl terephthalate/ polypropylene (PCT/PP), glycol-modified polyethylene terephthalate/ polyethylene terephthalate (PETG/PET), propylene/polyethylene terephthalate (PP/PET), nylon 6/nylon 66, or other combinations of polymers that yield differential melt flow temperatures.
  • CoPET/PET copolyester/polyethylene terephthalate
  • PCT/PET poly 1,4 cyclohexanedimethyl terephthalate/polyethylene terephthalate
  • PCT/PP poly 1,4 cyclohexanedimethyl terephthalate/ polypropy
  • the bicomponent fibers may be any of a variety of configurations that yield acceptable fiber binding such as sheath-core, side-by-side, splitable segmented pie, etc.
  • the high melt bicomponent is described as having a melt flow temperature of about 170- 200°C.
  • Bicomponent fibers described as crystalline or semi-crystalline which have a melt flow temperature of generally about 150°C to 180°C (302°F to 356°F) may be substituted . in part or whole for the high melt bicomponent fiber.
  • Fig. 1 is a schematical side elevational view of one possible embodiment of the present invention
  • FIGS. 2-4 are schematical side elevational illustrations of other possible alternative embodiments of the present invention.
  • Fig. 5 is a graphical illustration comparing the flexural strength in the machine direction of the structural/acoustical insulating material of the present invention with a standard state of the art polymer formulation
  • Fig. 6 is a graphical illustration comparing the flexural strength in the cross machine direction of the structural/acoustical insulating material of the present invention with a standard state of the art polymer formulation.
  • the present invention relates to an insulating material that is particularly noteworthy for its combination of structural and acoustical properties. Specifically, as described below the insulating material yields at least a 100% improvement in elastic modulus over a standard polymer formulation while (1) maintaining equivalent acoustics to the standard formulation, (2) yielding high temperature performance and (3) having a minimal cost upcharge over standard formulations. While in the past it has generally been found necessary to give up a significant level of acoustical performance or utilize much higher priced fibers or both to gain improvement in structural properties, the present invention achieves the dramatic increase in elastic modulus without compromising acoustical properties or low production costs and as such represents a significant advance in the art.
  • the insulating material of the present invention comprises in weight percent from about 20-60%) low melt bicomponent fiber, 10-40%> high melt bicomponent fiber and 20- 60% staple fiber.
  • the melt includes an average fiber diameter of between about 10-30 microns, or typically 16-24 microns and most typically 18-22 microns.
  • the material has a density of between about 1.0-10.0 pcf (16.02-160.2 kg/m 3 ) and a flexural strength of between about 40-1200 psi (275.79-8273.71 kPa).
  • the bicomponent fibers are comprised of a principal polymer component and a binder polymer component.
  • the bicomponent fibers may be formed as sheath-core fibers with the principal polymer component forming the core material and the binder polymer component forming the sheath around the core. It should be understood, however, that other arrangements may be utilized such as a side-by-side arrangement. In any such arrangement, the binder polymer component binds the bicomponent fibers and the staple fibers to themselves and to each other.
  • the binder polymer component of the bicomponent fibers has a softening point lower than the softening point of the principal polymer component so that the two materials respond differently upon heating.
  • the binder component When heated to a temperature above the softening point of the binder polymer component but below the softening temperature of the principal polymer component, the binder component softens and becomes sticky, thereby bonding the various bicomponent fibers where they are in contact with each other and the staple fibers. As long as the temperature is not raised as high as the softening point of the principal polymer component, that component remains in the form of fibers.
  • the low melt bicomponent fibers are selected from a group of materials consisting of copolyester/polyethylene terephthalate (CoPET/PET), poly 1,4 cyclohexanedimethyl terephthalate/polyethylene terephthalate (PCT/PET), poly 1,4 cyclohexanedimethyl terephthalate/ polypropylene (PCT/PP), glycol-modified polyethylene terephthalate/ polyethylene terephthalate (PETG/PET), propylene/polyethylene terephthalate (PP/PET), nylon 6/nylon 66, polyethylene/glass, or other combinations of polymers including polymer/glass and polymer/natural fiber that yield differential melt flow temperatures.
  • CoPET/PET copolyester/polyethylene terephthalate
  • PCT/PET poly 1,4 cyclohexanedimethyl terephthalate/polyethylene terephthalate
  • PCT/PP poly 1,4 cyclo
  • the bicomponent fibers may be any of a variety of configurations that yield acceptable fiber binding such as sheath-core, side-by-side, segmented pie, etc.
  • the low melt bicomponent fibers are described as having a melt flow temperature of about 100°C to 130°C (212°F to 266°F).
  • the high melt bicomponent fibers are selected from a group of materials consisting of copolyester/polyethylene terephthalate (CoPET/PET), poly 1,4 cyclohexanedimethyl terephthalate/polyethylene terephthalate (PCT/PET), poly 1,4 cyclohexanedimethyl terephthalate/ polypropylene (PCT/PP), glycol-modified polyethylene terephthalate/ polyethylene terephthalate (PETG/PET), propylene/polyethylene terephthalate (PP/PET), nylon 6/nylon 66, or other combinations of polymers that yield differential melt flow temperatures.
  • CoPET/PET copolyester/polyethylene terephthalate
  • PCT/PET poly 1,4 cyclohexanedimethyl terephthalate/polyethylene terephthalate
  • PCT/PP poly 1,4 cyclohexanedimethyl terephthalate/ polypropy
  • the bicomponent fibers may be any of a variety of configurations that yield acceptable fiber binding such as sheath-core, side-by-side, splitable segmented pie, etc.
  • the high melt bicomponent is described as having a melt flow temperature of about 170°C to 200°C (338°F to 392°F).
  • Bicomponent fibers described as crystalline or semi- crystalline which have a melt flow temperature of generally about 150°C to 180°C (302°F to 356°F) may be substituted in part or whole for the high melt bicomponent fiber.
  • the insulating material provides unique acoustical insulating properties in combination with the flexural strength of between about 40-1200 psi (275.79- 8273.71 kPa).
  • the insulating material is characterized by acoustical absorption coefficients of 0.17-0.24 at a frequency of 500 Hz, 0.29-0.63 at a frequency of 1000 Hz, 0.50-0.94 at a frequency of 2000 Hz and 0.71-0.99 at a frequency of 4000 Hz all at 2 pcf (32.04 km g 3 ) density.
  • the insulating material also has a thermal conductivity value of between about 0.20 and 0.30 at 2 pcf (32.04 km g 3 ) density. Accordingly, it should be appreciated that the insulating material also provides good thermal insulating properties in conjunction with good acoustical insulating and structural properties.
  • the staple or bulking fibers utilized in the insulating material are selected from a group of materials consisting of polyester fibers, polyethylene fibers, polypropylene fibers, nylon fibers, rayon fibers, glass fibers, natural fibers and mixtures thereof.
  • the insulating material of the present invention may be utilized for a number of applications requiring the unique structural, acoustical insulating and, when appropriate for certain applications, thermal insulating properties of the present invention.
  • the insulating material of the present invention may be utilized in the construction of hood, dash, firewall or engine cover liners such as shown in Figs. 1-4 of the present invention.
  • the liner 10 shown in Fig. 1 comprises an acoustical and thermal insulating layer 12 of the insulating material of the present invention. More specifically, a single, nonlaminated layer 12 is provided with the necessary mechanical strength and rigidity to allow easy installation and the desired acoustical and thermal insulating properties.
  • the liner 10 also comprises a single, nonlaminated acoustical and thermal insulating layer 12 of the insulating material of the present invention.
  • the layer 12 includes a relatively high density, nonlaminate or unitary skin 14 of that insulating material along at least one face thereof.
  • the high density skin 14 will not delaminate from the layer 12 under the environmental conditions existing in the engine compartment and also adds structural integrity and strength to the liner 10 which aids significantly in handling and fitting the part during installation.
  • the high density skin 14 is also more aesthetically pleasing.
  • the high density skin 14 eliminates the need to provide an additional facing layer of another type of fabric material. This serves to virtually eliminate any potential for failure of the lining due to delamination. It also results in a liner 10 made exclusively of one material that is, therefore, fully recyclable.
  • the liner 10 includes a single, nonlaminated acoustical and thermal insulating layer 12 of the insulating material of the present invention in combination with a facing layer 16 over a first face 18 of the acoustical and thermal insulating layer.
  • the facing layer 16 may be constructed from a polymer material selected from a . group consisting of polyester, rayon, polyethylene, polypropylene, ethylene vinyl acetate, polyvinyl chloride and mixtures thereof.
  • the liner 10 comprises a single, nonlaminated acoustical and thermal insulating layer 12 of the insulating material of the present invention as described above in combination with a first facing layer 16 covering a first face 18 thereof and a second facing layer 20 covering a second, opposite face 22 thereof.
  • the second facing layer 20 may be constructed from the same or a different material as the first facing layer 16.
  • the first and second facing layers have a weight of between about 0.50-3.00 oz/sq yd (16.95-101.72 g/m ).
  • the acoustical and thermal insulating layer 12 may be a natural white or include any appropriate form of coloring or pigment in order to provide a gray or black color.
  • the acoustical and thermal insulating layer 12 may incorporate any appropriate color or pigment so as to substantially approximate the color of the first and/or second facing layers 16, 20 and/or the paint color of the vehicle. This provides significant aesthetic benefits. Specifically, when the liner 10 is molded under heat and pressure in order to nest with the hood, firewall or other appropriate body panel or superstructure of the engine compartment, the liner 10 is often subjected to deep drawing at one or more points.
  • This deep drawing has a tendency to spread the weave of the fabric facing 16, 20 thereby exposing a portion of the underlying face 18, 20 of the acoustical and thermal insulating layer to light. If the acoustical and thermal insulating layer 12 does not substantially match the color of the facing layer 16, 20 this creates an undesirable color variation in these deep drawn areas. In contrast, by matching the color of the layer 12 with the facings 16, 20, this color variation may be substantially eliminated.
  • the facing layer 16, 20 may become snagged or subjected to a partial tear exposing some of the face of the underlying acoustical and thermal insulating layer 12.
  • the insulating material of the present invention is produced in accordance with processing steps generally known in the art.
  • the fibers need to be blended in the given ratios and thermally bonded to form a semi-rigid blanket.
  • the fibers generally are packaged in 500-700 lb. (226.79-317.51 kg) bales.
  • Each of the three fibers is generally baled separately although it is possible to get the fibers from the fiber supplier blended in the proper ratio and baled together. For purposes of this description, it is assumed that the fibers come baled separately.
  • each baled fiber needs to be "opened" by a bale opening system common in the industry. The opening system fluffs up the fiber and sends the appropriate amount of fiber by weight to a blending area.
  • This fluffing serves to decouple the clustered fibrous masses and enhances fiber-to-fiber contact.
  • the blending area distributes the different fibers uniformly according to the desired fiber ratios. Once blended the fibers are uniformly distributed on a conveying system forming an unbonded "sheet” or “blanket” of uniformly distributed fibers.
  • Thermally activated powdered binders or other supplemental binding methods may be added during the fiber blending or conveying stages prior to the sheet entering the thermal bonding oven.
  • the oven is constructed to allow heated air to penetrate the fibrous pack and bring the fibers to a temperature sufficient to activate the binding fibers and/or other binding materials. If the blanket material is being produced for post molding applications, the oven temperature need only be high enough to activate at least some of the low melt binding fibers.
  • the post mold operation only needs to reach temperatures high enough to activate the higher melt fibers. If no post mold operation is to occur then the oven needs to be set to a temperature high enough to activate both the low melt and high melt fibers-in this case the required temperature would be at least 180°C (356°F). Once the fibers have reached the appropriate temperature the oven or post oven area should be capable of reducing the temperature below the activation point of the binding materials, in this case approximately below 100°C (212°F).
  • the desired thickness of the blanket is generally established in the oven process. After exiting the oven, additional binding materials such as powders can be added to the fibrous blanket or other treatments such as densifying one or both surfaces of the blanket can occur.
  • the blanket can now be handled and utilized "as is” for structural-acoustical applications or it can be post molded to produce parts of simple or highly complex shapes. Molding methods can vary among those typically used in the industry for molding of thermoplastic materials. One such method is to preheat the blanket material to a sufficient temperature to (re)activate all of the binding materials and then quickly transfer the heated blanket to a cold molding tool and press mold the part until the temperature of the fibers are below the activation point of the low melt binding fibers.
  • the structural/acoustical formulation for the insulating material of the present invention was tested and compared to a standard formulation of 40% low melt bicomponent having an average fiber diameter of 14.3 microns, 30% staple (bulking) fiber having an average fiber diameter of 12.4 microns and 30% staple (bulking) fiber having an average fiber diameter of 50.0 microns. Together, the standard formulation had an average fiber diameter of 30.0 microns. Flexural strength testing of the structural/acoustical formulation of the insulating material of the present invention and the standard formulation was then run in accordance with ASTM D1037 static three point bend. The results of this testing are clearly illustrated in Figs. 5 and 6.
  • Fig. 5 shows the flexural strength of the two formulations in the machine direction and Fig.
  • the structural acoustical formulation of the insulating material of the present invention also provides acoustical absorption coefficients somewhat better than those provided by the standard formulation and as such, provides significant gains in strength and enhanced acoustical insulating performance. As such, the present invention represents a significant advance in the art.
  • An insulating material providing a unique combination of structural strength, acoustical insulating and even thermal insulating properties is provided.
  • the insulating material is particularly suited for use as a hood, dash, firewall or engine cover liner. It provides the mechanical strength and rigidity to allow ease in handling and installation while also providing thermal and acoustical insulating properties that are consistently and reliably maintained over a long service life even in the high temperature and high moisture operating environment of the engine compartment. Such performance characteristics have heretofore been unavailable in a liner incorporating a single, nonlaminated layer of acoustical and thermal insulating material.

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  • Nonwoven Fabrics (AREA)
  • Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
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  • Laminated Bodies (AREA)
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Abstract

An insulating material is constructed in weight percent from about 20-60% low melt bicomponent fiber, 10-40% high melt bicomponent fiber and 20-60% staple fiber. The material provides a unique combination of strength, acoustical insulating and even thermal insulating properties heretofore unavailable in the art.

Description

INSULATING MATERIAL
TECHNICAL FIELD AND INDUSTRIAL APPLICABILITY OF THE INVENTION The present invention relates generally to the field of acoustical and thermal insulation and, more particularly, to a unique new insulating material of low-melt and high-melt bicomponent fibers exhibiting a unique blend of structural and acoustical insulating properties.
BACKGROUND OF THE INVENTION
Acoustical and thermal liners for application to vehicles are well known in the art. These liners typically rely upon both sound absorption, that is the ability to absorb incident sound waves and transmission loss, that is the ability to reflect incident sound waves, in order to provide sound attenuation. They also rely upon thermal shielding properties to prevent or reduce the transmission of heat from various heat sources (for example engine, transmission and exhaust system), to the passenger compartment of the vehicle. Such insulation is commonly employed as a hoodliner, dash liner and firewall liner. More recently, such liners have been employed on engine covers so as to attenuate the sound of the engine closer to its source. Examples of acoustical and thermal insulation in the form of liners are disclosed in a number of prior art patents including U.S. Patents 4,851,283 to Holtrop et al. and 6,008,149 to Copperwheat. As should be apparent from a review of these two patents, engineers have generally found it necessary to construct such liners from a laminate incorporating (a) one or more layers to provide the desired acoustical and thermal insulating properties and (b) one or more additional layers to provide the desire mechanical strength properties which allow simple and convenient installation as well as proper functional performance over a long service life.
While a number of adhesives, adhesive webs and binding fibers have been specifically developed over the years to secure the various layers of the laminates together, laminated liners and insulators have an inherent risk of delamination and failure. The potential is, in fact, significant mainly due to the harsh operating environment to which such liners and insulators are subjected. Many liners and insulators are located near and/or are designed to shield high heat sources such as the engine, transmission and components of the exhaust system. As a result, the liners and insulators are often subjected to temperatures in excess of 200°F which have a tendency to degrade the adhesives or binders over time.
Additionally, many liners and insulators are subjected to water from the surface of the roadways which has a tendency to be drawn by capillary action into the interface between the layers of the liner or insulator. Such water may have a deleterious affect upon the integrity of the adhesive layer over time. This is particularly true when that water includes in solution salt or other chemicals from the roadway which are corrosive and destructive. A need is therefore identified for a hood, dash, firewall or engine cover liner incorporating a nonlaminate acoustical and thermal insulating layer of polymer fibers which avoids any inherent potential for delamination. Such a liner is suitable for use in the high temperature operating environment of the engine compartment and capable of providing the desired mechanical strength and rigidity for ease of installation as well as the desired acoustical and thermal insulating properties.
SUMMARY OF THE INVENTION
Accordingly, the present invention relates to an insulating material exhibiting a unique combination of acoustical insulating and strength/ structural properties. The insulating material comprises in weight percent from about 20-60% low melt bicomponent fiber, 10-40% high melt bicomponent fiber and 20-60% staple fiber. The melt includes an average fiber diameter of between about 10-30 microns, more typically 16-24 microns and most typically 18-22 microns. The material has a density of between about 1.0-10.0 pcf (16.02-160.2 kg/m3) and a flexural strength of between about 40-1200 psi (275.79- 8273.71 kPa). Still more specifically describing the invention, the insulating material has the acoustical absorption coefficients as follows: 0.17-0.24 at a frequency of 500 Hz, 0.29- 0.63 at a frequency of 1000 Hz, 0.50-0.94 at a frequency of 2000 Hz and 0.71-0.99 at a frequency of 4000 Hz all at 2 pcf (32.04 km/g3) density.
Still further describing the invention, the insulating material has a thermal conductivity value of between about 0.20 and 0.30 at 2 pcf (32.04 km/g3) density. The staple or bulking fibers are selected from a group of materials consisting of polyester fibers, polyethylene fibers, polypropylene fibers, nylon fibers, rayon fibers, glass fibers, natural fibers and mixtures thereof. The low melt bicomponent fibers are selected from a group of materials consisting of copolyester/polyethylene terephthalate (CoPET/PET), poly 1,4 cyclohexanedimethyl terephthalate/polyethylene terephthalate (PCT/PET), poly 1,4 cyclohexanedimethyl terephthalate/ polypropylene (PCT/PP), glycol-modified polyethylene terephthalate/ polyethylene terephthalate (PETG/PET), propylene/polyethylene terephthalate (PP/PET), nylon 6/nylon 66, polyethylene/glass, or other combinations of polymers including polymer/glass and polymer/natural fiber that yield differential melt flow temperatures. The bicomponent fibers may be any of a variety of configurations that yield acceptable fiber binding such as sheath-core, side-by-side, segmented pie, etc. The low melt bicomponent fibers are described as having a melt flow temperature of about 100°C to 130°C (212°F to 266°F).
The high melt bicomponent fibers are selected from a group of materials consisting of copolyester/polyethylene terephthalate (CoPET/PET), poly 1,4 cyclohexanedimethyl terephthalate/polyethylene terephthalate (PCT/PET), poly 1,4 cyclohexanedimethyl terephthalate/ polypropylene (PCT/PP), glycol-modified polyethylene terephthalate/ polyethylene terephthalate (PETG/PET), propylene/polyethylene terephthalate (PP/PET), nylon 6/nylon 66, or other combinations of polymers that yield differential melt flow temperatures. The bicomponent fibers may be any of a variety of configurations that yield acceptable fiber binding such as sheath-core, side-by-side, splitable segmented pie, etc. The high melt bicomponent is described as having a melt flow temperature of about 170- 200°C. Bicomponent fibers described as crystalline or semi-crystalline which have a melt flow temperature of generally about 150°C to 180°C (302°F to 356°F) may be substituted . in part or whole for the high melt bicomponent fiber.
BRIEF DESCRIPTION OF THE DRAWING
The accompanying drawing incorporated in and forming apart of the specification, illustrates several aspects of the present invention, and together with the description serves to explain the principles of the invention. In the drawing:
Fig. 1 is a schematical side elevational view of one possible embodiment of the present invention;
Figs. 2-4 are schematical side elevational illustrations of other possible alternative embodiments of the present invention;
Fig. 5 is a graphical illustration comparing the flexural strength in the machine direction of the structural/acoustical insulating material of the present invention with a standard state of the art polymer formulation; and
Fig. 6 is a graphical illustration comparing the flexural strength in the cross machine direction of the structural/acoustical insulating material of the present invention with a standard state of the art polymer formulation.
Reference will now be made in detail to the present preferred embodiment of the invention, an example of which is illustrated in the accompanying drawing.
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an insulating material that is particularly noteworthy for its combination of structural and acoustical properties. Specifically, as described below the insulating material yields at least a 100% improvement in elastic modulus over a standard polymer formulation while (1) maintaining equivalent acoustics to the standard formulation, (2) yielding high temperature performance and (3) having a minimal cost upcharge over standard formulations. While in the past it has generally been found necessary to give up a significant level of acoustical performance or utilize much higher priced fibers or both to gain improvement in structural properties, the present invention achieves the dramatic increase in elastic modulus without compromising acoustical properties or low production costs and as such represents a significant advance in the art.
The insulating material of the present invention comprises in weight percent from about 20-60%) low melt bicomponent fiber, 10-40%> high melt bicomponent fiber and 20- 60% staple fiber. The melt includes an average fiber diameter of between about 10-30 microns, or typically 16-24 microns and most typically 18-22 microns. The material has a density of between about 1.0-10.0 pcf (16.02-160.2 kg/m3) and a flexural strength of between about 40-1200 psi (275.79-8273.71 kPa).
For purposes of clarity, the bicomponent fibers are comprised of a principal polymer component and a binder polymer component. The bicomponent fibers may be formed as sheath-core fibers with the principal polymer component forming the core material and the binder polymer component forming the sheath around the core. It should be understood, however, that other arrangements may be utilized such as a side-by-side arrangement. In any such arrangement, the binder polymer component binds the bicomponent fibers and the staple fibers to themselves and to each other. The binder polymer component of the bicomponent fibers has a softening point lower than the softening point of the principal polymer component so that the two materials respond differently upon heating. When heated to a temperature above the softening point of the binder polymer component but below the softening temperature of the principal polymer component, the binder component softens and becomes sticky, thereby bonding the various bicomponent fibers where they are in contact with each other and the staple fibers. As long as the temperature is not raised as high as the softening point of the principal polymer component, that component remains in the form of fibers. The low melt bicomponent fibers are selected from a group of materials consisting of copolyester/polyethylene terephthalate (CoPET/PET), poly 1,4 cyclohexanedimethyl terephthalate/polyethylene terephthalate (PCT/PET), poly 1,4 cyclohexanedimethyl terephthalate/ polypropylene (PCT/PP), glycol-modified polyethylene terephthalate/ polyethylene terephthalate (PETG/PET), propylene/polyethylene terephthalate (PP/PET), nylon 6/nylon 66, polyethylene/glass, or other combinations of polymers including polymer/glass and polymer/natural fiber that yield differential melt flow temperatures. The bicomponent fibers may be any of a variety of configurations that yield acceptable fiber binding such as sheath-core, side-by-side, segmented pie, etc. The low melt bicomponent fibers are described as having a melt flow temperature of about 100°C to 130°C (212°F to 266°F). The high melt bicomponent fibers are selected from a group of materials consisting of copolyester/polyethylene terephthalate (CoPET/PET), poly 1,4 cyclohexanedimethyl terephthalate/polyethylene terephthalate (PCT/PET), poly 1,4 cyclohexanedimethyl terephthalate/ polypropylene (PCT/PP), glycol-modified polyethylene terephthalate/ polyethylene terephthalate (PETG/PET), propylene/polyethylene terephthalate (PP/PET), nylon 6/nylon 66, or other combinations of polymers that yield differential melt flow temperatures. The bicomponent fibers may be any of a variety of configurations that yield acceptable fiber binding such as sheath-core, side-by-side, splitable segmented pie, etc. The high melt bicomponent is described as having a melt flow temperature of about 170°C to 200°C (338°F to 392°F). Bicomponent fibers described as crystalline or semi- crystalline which have a melt flow temperature of generally about 150°C to 180°C (302°F to 356°F) may be substituted in part or whole for the high melt bicomponent fiber. The insulating material provides unique acoustical insulating properties in combination with the flexural strength of between about 40-1200 psi (275.79- 8273.71 kPa). Specifically, the insulating material is characterized by acoustical absorption coefficients of 0.17-0.24 at a frequency of 500 Hz, 0.29-0.63 at a frequency of 1000 Hz, 0.50-0.94 at a frequency of 2000 Hz and 0.71-0.99 at a frequency of 4000 Hz all at 2 pcf (32.04 km g3) density. The insulating material also has a thermal conductivity value of between about 0.20 and 0.30 at 2 pcf (32.04 km g3) density. Accordingly, it should be appreciated that the insulating material also provides good thermal insulating properties in conjunction with good acoustical insulating and structural properties.
The staple or bulking fibers utilized in the insulating material are selected from a group of materials consisting of polyester fibers, polyethylene fibers, polypropylene fibers, nylon fibers, rayon fibers, glass fibers, natural fibers and mixtures thereof.
The insulating material of the present invention may be utilized for a number of applications requiring the unique structural, acoustical insulating and, when appropriate for certain applications, thermal insulating properties of the present invention. For example, the insulating material of the present invention may be utilized in the construction of hood, dash, firewall or engine cover liners such as shown in Figs. 1-4 of the present invention.
The liner 10 shown in Fig. 1 comprises an acoustical and thermal insulating layer 12 of the insulating material of the present invention. More specifically, a single, nonlaminated layer 12 is provided with the necessary mechanical strength and rigidity to allow easy installation and the desired acoustical and thermal insulating properties.
Advantageously, all of these benefits are achieved in a light weight liner 10 which may even be used in compact vehicles where fuel economy concerns lead manufacturers to seek weight savings wherever possible.
In a first alternative embodiment shown in Fig. 2, the liner 10 also comprises a single, nonlaminated acoustical and thermal insulating layer 12 of the insulating material of the present invention. The layer 12 includes a relatively high density, nonlaminate or unitary skin 14 of that insulating material along at least one face thereof.
Advantageously, the high density skin 14 will not delaminate from the layer 12 under the environmental conditions existing in the engine compartment and also adds structural integrity and strength to the liner 10 which aids significantly in handling and fitting the part during installation. The high density skin 14 is also more aesthetically pleasing. Still further, for many applications the high density skin 14 eliminates the need to provide an additional facing layer of another type of fabric material. This serves to virtually eliminate any potential for failure of the lining due to delamination. It also results in a liner 10 made exclusively of one material that is, therefore, fully recyclable.
Further, since the skin may be formed with a hot platen during the molding of the liner 10 to its desired shape, no additional processing step is required. This reduces production costs relative to a liner with a fabric or other facing since such a facing must be adhere to the acoustical and thermal insulating layer in a separate processing step. In yet another embodiment shown in Fig. 3, the liner 10 includes a single, nonlaminated acoustical and thermal insulating layer 12 of the insulating material of the present invention in combination with a facing layer 16 over a first face 18 of the acoustical and thermal insulating layer. The facing layer 16 may be constructed from a polymer material selected from a. group consisting of polyester, rayon, polyethylene, polypropylene, ethylene vinyl acetate, polyvinyl chloride and mixtures thereof.
In yet another alternative embodiment shown in Fig. 4, the liner 10 comprises a single, nonlaminated acoustical and thermal insulating layer 12 of the insulating material of the present invention as described above in combination with a first facing layer 16 covering a first face 18 thereof and a second facing layer 20 covering a second, opposite face 22 thereof. The second facing layer 20 may be constructed from the same or a different material as the first facing layer 16. Preferably the first and second facing layers have a weight of between about 0.50-3.00 oz/sq yd (16.95-101.72 g/m ). In accordance with yet another aspect of the present invention, the acoustical and thermal insulating layer 12 may be a natural white or include any appropriate form of coloring or pigment in order to provide a gray or black color. Alternatively, the acoustical and thermal insulating layer 12 may incorporate any appropriate color or pigment so as to substantially approximate the color of the first and/or second facing layers 16, 20 and/or the paint color of the vehicle. This provides significant aesthetic benefits. Specifically, when the liner 10 is molded under heat and pressure in order to nest with the hood, firewall or other appropriate body panel or superstructure of the engine compartment, the liner 10 is often subjected to deep drawing at one or more points. This deep drawing has a tendency to spread the weave of the fabric facing 16, 20 thereby exposing a portion of the underlying face 18, 20 of the acoustical and thermal insulating layer to light. If the acoustical and thermal insulating layer 12 does not substantially match the color of the facing layer 16, 20 this creates an undesirable color variation in these deep drawn areas. In contrast, by matching the color of the layer 12 with the facings 16, 20, this color variation may be substantially eliminated.
It should further be appreciated that during use the facing layer 16, 20 may become snagged or subjected to a partial tear exposing some of the face of the underlying acoustical and thermal insulating layer 12. Once again, by matching the color of the layer 12 with the facing 16, 20, any color variation is substantially eliminated and one's attention is not as readily drawn to the damaged area. Accordingly, an overall improved aesthetic appearance is maintained over the service life of the liner 10.
The insulating material of the present invention is produced in accordance with processing steps generally known in the art. The fibers need to be blended in the given ratios and thermally bonded to form a semi-rigid blanket. The fibers generally are packaged in 500-700 lb. (226.79-317.51 kg) bales. Each of the three fibers is generally baled separately although it is possible to get the fibers from the fiber supplier blended in the proper ratio and baled together. For purposes of this description, it is assumed that the fibers come baled separately. Generally each baled fiber needs to be "opened" by a bale opening system common in the industry. The opening system fluffs up the fiber and sends the appropriate amount of fiber by weight to a blending area. This fluffing serves to decouple the clustered fibrous masses and enhances fiber-to-fiber contact. The blending area distributes the different fibers uniformly according to the desired fiber ratios. Once blended the fibers are uniformly distributed on a conveying system forming an unbonded "sheet" or "blanket" of uniformly distributed fibers. Thermally activated powdered binders or other supplemental binding methods may be added during the fiber blending or conveying stages prior to the sheet entering the thermal bonding oven. The oven is constructed to allow heated air to penetrate the fibrous pack and bring the fibers to a temperature sufficient to activate the binding fibers and/or other binding materials. If the blanket material is being produced for post molding applications, the oven temperature need only be high enough to activate at least some of the low melt binding fibers. The post mold operation only needs to reach temperatures high enough to activate the higher melt fibers. If no post mold operation is to occur then the oven needs to be set to a temperature high enough to activate both the low melt and high melt fibers-in this case the required temperature would be at least 180°C (356°F). Once the fibers have reached the appropriate temperature the oven or post oven area should be capable of reducing the temperature below the activation point of the binding materials, in this case approximately below 100°C (212°F). The desired thickness of the blanket is generally established in the oven process. After exiting the oven, additional binding materials such as powders can be added to the fibrous blanket or other treatments such as densifying one or both surfaces of the blanket can occur. The blanket can now be handled and utilized "as is" for structural-acoustical applications or it can be post molded to produce parts of simple or highly complex shapes. Molding methods can vary among those typically used in the industry for molding of thermoplastic materials. One such method is to preheat the blanket material to a sufficient temperature to (re)activate all of the binding materials and then quickly transfer the heated blanket to a cold molding tool and press mold the part until the temperature of the fibers are below the activation point of the low melt binding fibers.
In the case of the samples used for structural testing in the following example, no post molding operation was utilized to achieve the desired test thickness.
The following examples are presented to further illustrate the invention, but it is not to be considered as limited thereto. EXAMPLE
The structural/acoustical formulation for the insulating material of the present invention was tested and compared to a standard formulation of 40% low melt bicomponent having an average fiber diameter of 14.3 microns, 30% staple (bulking) fiber having an average fiber diameter of 12.4 microns and 30% staple (bulking) fiber having an average fiber diameter of 50.0 microns. Together, the standard formulation had an average fiber diameter of 30.0 microns. Flexural strength testing of the structural/acoustical formulation of the insulating material of the present invention and the standard formulation was then run in accordance with ASTM D1037 static three point bend. The results of this testing are clearly illustrated in Figs. 5 and 6. Fig. 5 shows the flexural strength of the two formulations in the machine direction and Fig. 6 shows the flexural strength of the two formulation in the cross-machine direction. In both instances, it should be appreciated that the structural/acoustical formulation of the insulating material of the present invention provides at least a 100% improvement in elastic modulus over the standard formulation tested.
The structural acoustical formulation of the insulating material of the present invention also provides acoustical absorption coefficients somewhat better than those provided by the standard formulation and as such, provides significant gains in strength and enhanced acoustical insulating performance. As such, the present invention represents a significant advance in the art.
In summary, numerous benefits result from employing the concepts of the present invention. An insulating material providing a unique combination of structural strength, acoustical insulating and even thermal insulating properties is provided. The insulating material is particularly suited for use as a hood, dash, firewall or engine cover liner. It provides the mechanical strength and rigidity to allow ease in handling and installation while also providing thermal and acoustical insulating properties that are consistently and reliably maintained over a long service life even in the high temperature and high moisture operating environment of the engine compartment. Such performance characteristics have heretofore been unavailable in a liner incorporating a single, nonlaminated layer of acoustical and thermal insulating material.
The foregoing description of a preferred embodiment of the invention has been presented for purposes of illustration and description. It is not intended to be exhaustive or to limit the invention to the precise form disclosed.
The embodiment was chosen and described to provide the best illustration of the principles of the invention and its practical application to thereby enable one of ordinary skill in the art to utilize the invention in various embodiments and with various modifications as are suited to the particular use contemplated. For example, crystalline/semicrystalline bicomponent fibers having a melt flow temperature of about 150°C to about 180°C may be substituted in whole or in part for the high melt bicomponent fiber. All such modifications and variations are within the scope of the invention as determined by the appended claims when interpreted in accordance with the breadth to which they are fairly, legally and equitably entitled.

Claims

WHAT IS CLAIMED IS:
1. An insulating material, comprising in weight percent about 20-60% low melt bicomponent fiber, 10-40% high melt bicomponent fiber and 20-60% staple fiber.
2. The material of claim 1, including an average fiber diameter of between about 10-30 microns.
3. The material of claim 1, including an average fiber diameter of between about 16-24 microns.
4. The material of claim 1 , including an average fiber diameter of between about 18-22 microns.
5. The material of claim 1 , wherein said material has a density of between about 1.0-10.0 pcf (16.02-160.2 kg/m3) and a flexural strength of between about 40-1200 psi (275.79-8273.71 kPa).
6. The material of claim 5, wherein said material has the acoustical absorption coefficients as follows: freq (Hz) @ 2 pcf (32.04 kg/m3) density
500 0.17-0.24
1000 0.29-0.63
2000 0.50-0.94
4000 0J1-0.99 7. The material of claim 6, wherein said material has a thermal conductivity value of between about 0.20 and 0.30 at 2 pcf (32.04 kg/m3) density.
8. The material of claim 1 , wherein said low melt and high melt bicomponent fibers are a concentric sheath/core CoPET/PET.
9. The material of claim 8, wherein said staple fibers are selected from a group of materials consisting of polyester fibers, polyethylene fibers, polypropylene fibers, nylon fibers, rayon fibers, glass fibers, natural fibers and mixtures thereof.
10. The material of claim 1 , wherein said material has the acoustical absorption coefficients as follows: freq (Hz) @ 2 pcf (32.04 kg/m- !) density
500 0.17-0.24
1000 0.29-0.63
2000 0.50-0.94
4000 0.71-0.99
11. The material of claim 10, wherein said material has a thermal conductivity value of between about 0.20 and 0.30 at 2 pcf (32.04 kg/m3) density.
12. The material of claim 11, wherein said staple fibers are selected from a group of materials consisting of polyester fibers, polyethylene fibers, polypropylene fibers, nylon fibers, rayon fibers, glass fibers, natural fibers and mixtures thereof.
13. The material of claim 1, wherein said staple fibers are selected from a group of materials consisting of polyester fibers, polyethylene fibers, polypropylene fibers, nylon fibers, rayon fibers, glass fibers, natural fibers and mixtures thereof.
14. The material of claim 13, wherein said low melt bicomponent fibers are selected from a group of materials consisting of copolyester/ polyethylene terephthalate, poly 1,4 cyclohexanedimethyl terephthalate/polyethylene terephthalate, poly 1,4 cyclohexanedimethyl terephthalate/ polypropylene, glycol-modified polyethylene terephthalate/ polyethylene terephthalate, propylene/polyethylene terephthalate, nylon 6/nylon 66, polyethylene/glass, polymer/natural fibers and mixtures thereof that yield differential melt flow temperatures.
15. The material of claim 14, wherein said bicomponent fibers are in a configuration selected from a group consisting of sheath-core, side-by-side, segmented pie and mixtures thereof.
16. The material of claim 14, wherein said low melt bicomponent fibers have a melt flow temperature of about 100°C (212°F) to about 130°C (266°F).
17. The material of claim 13, wherein said high melt bicomponent fibers are selected from a group of materials consisting of copolyester/ polyethylene terephthalate, poly 1,4 cyclohexanedimethyl terephthalate/polyethylene terephthalate, poly 1,4 cyclohexanedimethyl terephthalate/ polypropylene, glycol-modified polyethylene terephthalate/ polyethylene terephthalate, propylene/polyethylene terephthalate, nylon 6/nylon 66, and mixtures thereof that yield differential melt flow temperatures.
18. The material of claim 17, wherein said high melt bicomponent fibers are in a configuration selected from a group consisting of sheath-core, side-by-side, splitable segmented pie and mixtures thereof.
19. The material of claim 17, wherein said high melt bicomponent fibers have a melt flow temperature of about 170°C (338°F) to about 200°C (392°F).
20. The material of claim 17, wherein crystalline/semicrystalline bicomponent fibers having a melt flow temperature of about 150°C (302°F) to about 180°C (356°F) are substituted in part or whole for said high melt bicomponent fiber.
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11207863B2 (en) 2018-12-12 2021-12-28 Owens Corning Intellectual Capital, Llc Acoustic insulator
US11666199B2 (en) 2018-12-12 2023-06-06 Owens Corning Intellectual Capital, Llc Appliance with cellulose-based insulator

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040163724A1 (en) * 2001-09-06 2004-08-26 Mark Trabbold Formaldehyde-free duct liner
US7815967B2 (en) * 2001-09-06 2010-10-19 Alain Yang Continuous process for duct liner production with air laid process and on-line coating
US20050160711A1 (en) * 2004-01-28 2005-07-28 Alain Yang Air filtration media
US20030041626A1 (en) * 2001-09-06 2003-03-06 Certainteed Corporation Insulation containing a mixed layer of textile fibers and of rotary and/or flame attenuated fibers, and process for producing the same
US20040192141A1 (en) * 2001-09-06 2004-09-30 Alain Yang Sub-layer material for laminate flooring
US7294218B2 (en) * 2003-10-17 2007-11-13 Owens Corning Intellectual Capital, Llc Composite material with improved structural, acoustic and thermal properties
US20080251187A1 (en) * 2003-10-17 2008-10-16 Enamul Haque Composite material with improved structural, acoustic and thermal properties
US20050266757A1 (en) * 2003-10-17 2005-12-01 Roekens Bertrand J Static free wet use chopped strands (WUCS) for use in a dry laid process
US20060057351A1 (en) * 2004-09-10 2006-03-16 Alain Yang Method for curing a binder on insulation fibers
US7279059B2 (en) * 2004-12-28 2007-10-09 Owens Corning Intellectual Capital, Llc Polymer/WUCS mat for use in automotive applications
US7252729B2 (en) * 2004-12-29 2007-08-07 Owens-Corning Fiberglas Technology Inc. Polymer/WUCS mat for use in sheet molding compounds
US20060137799A1 (en) * 2004-12-29 2006-06-29 Enamul Haque Thermoplastic composites with improved sound absorbing capabilities
US20060141260A1 (en) * 2004-12-29 2006-06-29 Enamul Haque Sandwich composite material using an air-laid process and wet glass
US7837009B2 (en) * 2005-04-01 2010-11-23 Buckeye Technologies Inc. Nonwoven material for acoustic insulation, and process for manufacture
CN101189380B (en) 2005-04-01 2012-12-19 博凯技术公司 Sound retardant nonwoven material and process for manufacture
US7878301B2 (en) * 2005-04-01 2011-02-01 Buckeye Technologies Inc. Fire retardant nonwoven material and process for manufacture
US7686132B2 (en) 2005-12-29 2010-03-30 3M Innovative Properties Company Porous membrane
US7727915B2 (en) 2006-01-18 2010-06-01 Buckeye Technologies Inc. Tacky allergen trap and filter medium, and method for containing allergens
US20080022645A1 (en) * 2006-01-18 2008-01-31 Skirius Stephen A Tacky allergen trap and filter medium, and method for containing allergens
EP2013393B1 (en) * 2006-04-27 2012-06-06 Libeltex Method for producing polymeric fiber insulation batts for residential and commercial construction applications
US20080003907A1 (en) * 2006-06-28 2008-01-03 Samuel Keith Black Facing Product for Vehicular Trim
US8652288B2 (en) 2006-08-29 2014-02-18 Ocv Intellectual Capital, Llc Reinforced acoustical material having high strength, high modulus properties
US20090019825A1 (en) * 2007-07-17 2009-01-22 Skirius Stephen A Tacky allergen trap and filter medium, and method for containing allergens
EP2297412B1 (en) * 2008-05-23 2018-06-13 Zephyros Inc. Sound absorption material and method of manufacturing sound absorption material
WO2010056372A1 (en) * 2008-11-14 2010-05-20 Armstrong World Industries, Inc. Fire and sag resistant acoustical panel
US8945678B2 (en) 2009-07-24 2015-02-03 Priscilla Burgess Soft batt insulation material and method for making
US9689097B2 (en) 2012-05-31 2017-06-27 Wm. T. Burnett Ip, Llc Nonwoven composite fabric and panel made therefrom
CN104755665B (en) * 2012-09-07 2017-07-11 帝人株式会社 Nonwoven fabric structure and method for producing same
US20140291068A1 (en) * 2013-03-29 2014-10-02 E I Du Pont De Nemours And Company Tunable acoustical absorbing composite batt
US9931016B2 (en) 2013-10-09 2018-04-03 Owens Corning Intellectual Capital, Llc Dishwasher insulation blanket
EP2939882A1 (en) * 2014-04-29 2015-11-04 Autoneum Management AG Acoustic Exterior trim part
EP2939828A1 (en) * 2014-04-29 2015-11-04 Autoneum Management AG Exterior trim part
EP2939881A1 (en) * 2014-04-29 2015-11-04 Autoneum Management AG Alternative Exterior Trim Part
WO2016187526A1 (en) 2015-05-20 2016-11-24 Zephyros, Inc. Multi-impedance composite
EP3277872B1 (en) * 2015-10-06 2019-05-22 Pimsa Otomotiv Tekstilleri Sanay Ve Ticaret Anonim Sirketi Method of increasing abrasion resistance in nonwoven automotive textiles
US20180134016A1 (en) * 2016-11-15 2018-05-17 Columbia Insurance Company Layered composite articles and methods of making same
US20190099970A1 (en) * 2017-10-02 2019-04-04 Faure Corporation 3d shoe upper fabrication method
DE102018110246B4 (en) * 2018-04-27 2020-12-31 Johann Borgers GmbH Nonwoven molded part
FR3104504B1 (en) * 2019-12-16 2022-06-24 Treves Products Services & Innovation Acoustic protection screen
FR3132495A1 (en) * 2022-02-07 2023-08-11 Treves Products, Services & Innovation Electrically powered motor vehicle floor architecture

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4547420A (en) * 1983-10-11 1985-10-15 Minnesota Mining And Manufacturing Company Bicomponent fibers and webs made therefrom
US4851283A (en) * 1988-12-05 1989-07-25 Monsanto Company Headliners having improved sound-absorbing characteristics
FI930780A (en) * 1992-11-30 1994-05-31 Albany Int Corp Synthetic insulationsmaterial
US5491186A (en) * 1995-01-18 1996-02-13 Kean; James H. Bonded insulating batt
DE69607164T2 (en) * 1995-06-23 2000-11-23 Minnesota Mining And Mfg. Co., Saint Paul SOUND INSULATION METHOD AND SOUND INSULATION ITEM
RU2154700C2 (en) * 1995-10-13 2000-08-20 Е.И. Дюпон Де Немур Энд Компани Method for manufacture of bulky fleecy jersey fabric
US5851355A (en) * 1996-11-27 1998-12-22 Bba Nonwovens Simpsonville, Inc. Reverse osmosis support substrate and method for its manufacture
JP3213252B2 (en) * 1997-03-03 2001-10-02 カネボウ株式会社 Sound absorbing material and method of manufacturing the same
US6008149A (en) * 1997-04-23 1999-12-28 Knowlton Nonwovens, Inc. Moldable composite article and method of manufacture
AU7987000A (en) * 1999-10-29 2001-05-08 Owens Corning Fibrous acoustical insulation product
JP4746181B2 (en) * 2000-05-22 2011-08-10 株式会社リコー Method for producing heat-sensitive stencil sheet and heat-sensitive stencil sheet

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO03078714A2 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11207863B2 (en) 2018-12-12 2021-12-28 Owens Corning Intellectual Capital, Llc Acoustic insulator
US11666199B2 (en) 2018-12-12 2023-06-06 Owens Corning Intellectual Capital, Llc Appliance with cellulose-based insulator

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BR0308064A (en) 2004-12-28
WO2003078714A2 (en) 2003-09-25
KR20040094804A (en) 2004-11-10
WO2003078714A3 (en) 2003-12-31
JP2005520941A (en) 2005-07-14
AU2003216453A1 (en) 2003-09-29
US20030176131A1 (en) 2003-09-18
MXPA04008914A (en) 2004-11-26
AU2003216453A8 (en) 2003-09-29
CA2478568A1 (en) 2003-09-25

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