EP1458809A2 - Zusammensetzung, und verpackungsfolie, verpackungsbeutel, verpackungsbehälter wobei diese zusammensetzun verwendet wird - Google Patents
Zusammensetzung, und verpackungsfolie, verpackungsbeutel, verpackungsbehälter wobei diese zusammensetzun verwendet wirdInfo
- Publication number
- EP1458809A2 EP1458809A2 EP02795426A EP02795426A EP1458809A2 EP 1458809 A2 EP1458809 A2 EP 1458809A2 EP 02795426 A EP02795426 A EP 02795426A EP 02795426 A EP02795426 A EP 02795426A EP 1458809 A2 EP1458809 A2 EP 1458809A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- container
- propylene
- film
- container packaging
- base polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000004806 packaging method and process Methods 0.000 title claims abstract description 54
- 239000012785 packaging film Substances 0.000 title claims abstract description 45
- 229920006280 packaging film Polymers 0.000 title claims abstract description 45
- 239000011342 resin composition Substances 0.000 title claims abstract description 31
- 229920005601 base polymer Polymers 0.000 claims abstract description 46
- 229920001903 high density polyethylene Polymers 0.000 claims abstract description 30
- 239000004700 high-density polyethylene Substances 0.000 claims abstract description 30
- 239000000565 sealant Substances 0.000 claims abstract description 26
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 19
- 239000000314 lubricant Substances 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 239000010410 layer Substances 0.000 claims description 37
- 230000001954 sterilising effect Effects 0.000 claims description 27
- 238000004659 sterilization and disinfection Methods 0.000 claims description 27
- 238000007639 printing Methods 0.000 claims description 5
- 230000004888 barrier function Effects 0.000 claims description 4
- 239000011241 protective layer Substances 0.000 claims description 4
- 238000011109 contamination Methods 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 38
- 229940063583 high-density polyethylene Drugs 0.000 description 20
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 18
- 239000005977 Ethylene Substances 0.000 description 18
- 230000000903 blocking effect Effects 0.000 description 13
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 10
- 238000000465 moulding Methods 0.000 description 10
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 10
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 10
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 8
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 8
- 239000000654 additive Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 8
- -1 polypropylene Polymers 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 229920001971 elastomer Polymers 0.000 description 7
- 239000000806 elastomer Substances 0.000 description 7
- 239000004743 Polypropylene Substances 0.000 description 6
- 230000000996 additive effect Effects 0.000 description 6
- 238000001816 cooling Methods 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 238000001125 extrusion Methods 0.000 description 6
- 239000004711 α-olefin Substances 0.000 description 6
- 229920001400 block copolymer Polymers 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 229920000098 polyolefin Polymers 0.000 description 5
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 4
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- 239000004035 construction material Substances 0.000 description 4
- 238000004512 die casting Methods 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 229920000139 polyethylene terephthalate Polymers 0.000 description 4
- 229920005604 random copolymer Polymers 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 238000010030 laminating Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 229920001384 propylene homopolymer Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 238000007788 roughening Methods 0.000 description 3
- 239000002356 single layer Substances 0.000 description 3
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 230000000740 bleeding effect Effects 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 229940069096 dodecene Drugs 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000001802 infusion Methods 0.000 description 2
- 239000011256 inorganic filler Substances 0.000 description 2
- 229910003475 inorganic filler Inorganic materials 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 229920003067 (meth)acrylic acid ester copolymer Polymers 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012790 adhesive layer Substances 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 239000012611 container material Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000002788 crimping Methods 0.000 description 1
- 238000000502 dialysis Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000009820 dry lamination Methods 0.000 description 1
- 230000003028 elevating effect Effects 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 description 1
- UFRKOOWSQGXVKV-UHFFFAOYSA-N ethene;ethenol Chemical compound C=C.OC=C UFRKOOWSQGXVKV-UHFFFAOYSA-N 0.000 description 1
- 239000004715 ethylene vinyl alcohol Substances 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 239000005337 ground glass Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229920000554 ionomer Polymers 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
- C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/04—Homopolymers or copolymers of ethene
- C09J123/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/02—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J123/10—Homopolymers or copolymers of propene
- C09J123/14—Copolymers of propene
- C09J123/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/10—Homopolymers or copolymers of propene
- C08J2323/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
- C08L2666/06—Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
Definitions
- Resin Composition and Container Packaging Film, Container Packaging Bag and Container Package Using the Resin Composition
- the present invention relates to a resin composition and to a container packaging film and the like used in a container packaging bag for housing a container filled with a food or a medicament. More specifically, the present invention relates to a container packaging film ensuring excellent appearance and excellent antiblocking property between a container and a container packaging bag after high-pressure steam sterilization, and also a sealant film, a laminate, a container packaging bag and a container package using the container packaging film.
- packaging of housing a container filled with a food, a medicament or the like in a container packaging bag has been performed.
- the purpose of packaging varies depending on use and the container packaging bag is being used for various purposes, for example, for the purpose of mainly protecting the contents from deterioration, such as prevention of scratches on the container surface, prevention of mechanical damage of the container itself and prevention of permeation of oxygen or ultraviolet light , and for the purpose of describing the contents in the container, such as clarification of contents or handling standard by printing or the like.
- the problem often encountered in packaging a container in a container packaging bag is that the container and the container packaging bag undergo blocking during storage of the packaged container in a storehouse or the like and the container cannot be easily taken out from the container packaging bag on use.
- the case of subjecting a container package obtained by packaging a container in a container packaging bag to high- pressure steam sterilization before use is recently increasing.
- the high-pressure steam sterilization temperature is sometimes more elevated to shorten the high-pressure steam sterilization time.
- the blocking is more liable to occur as the temperature increases and therefore, it is a great technical subject demanded for the container package to solve this problem of blocking.
- the high-pressure steam sterilization is performed by depressurizing the container package to reduce the volume between the medical container and the container packaging bag and to provide a state in which the container packaging bag and the medical container are in tight contact .
- blocking is readily generated.
- a method of physically roughening the surface of the heat-seal layer of film to reduce the contact area with the container as in the case of wrapping a polyolefin-base container with a film having a heat-seal layer composed of a polyolefin-base resin.
- this method include a method of imparting a roughness to the film by roughening treatment (e.g. Japanese Unexamined Patent Application, First Publication No. Hei 5-309124), a method of imparting a physical deformation to the film by crimping, embossing, or the like.
- Other method using a resin composition includes a method in which a polymer composition comprising polybutene-1 and polypropylene and/or poly-4- metylpentene-1 is used for inner surfaces of a container packaging bag(e.g., Japanese Unexamined Patent Application, First Publication No. Hei 5-31156). Furthermore, a method of adding an additive to the polyolefin constituting the heat-seal surface of film can be used.
- the additive used here includes an inorganic filler such as silica and talc, an organic antiblocking agent such as spherical crosslinked methyl methacrylate, a metallic soap-base lubricant such as calcium stearate, and a fatty acid amide-base lubricant often used as a slipping agent of film, such as erucic acid amide .
- an inorganic filler such as silica and talc
- an organic antiblocking agent such as spherical crosslinked methyl methacrylate
- a metallic soap-base lubricant such as calcium stearate
- a fatty acid amide-base lubricant often used as a slipping agent of film, such as erucic acid amide .
- the present invention has been made and the main object of the present invention is to provide a resin composition comprising a polyolefin-base material and suitable for a container packaging film having excellent appearance and antiblocking property and free from fear of mingling of a foreign matter into the contents of the container. Also, the object of the present invention is to provide a container packaging film comprising the resin composition of the present invention; a sealant film, a laminate, a container packaging bag and a container package using the container packaging film.
- the present inventors have found that these objects can be attained by forming a resin composition comprising a combination of specific polyolefin- base resins into a container packaging film and using the film for the surface to come into contact with a container.
- the present invention has been accomplished based on this finding. More specifically, the present invention relates to a resin composition and a container packaging film, a sealant film, a laminate, a container packaging bag and a container package using the resin composition, shown in the following (1) to (10).
- a resin composition comprising from 40 to 90 mass% of a propylene-base polymer and from 10 to 60 mass% of a high-density polyethylene (the total of the propylene-base polymer and the high-density polyethylene is 100 mass%), and substantially not containing a lubricant and not containing an antiblocking agent, and the ratio of MFR of the propylene-base polymer at 230°C to MFR of the high-density polyethylene at 190°C being from 5 to 200.
- a container packaging film made from a composition comprising a propylene-base polymer and a high- density polyethylene, the coefficient of kinetic friction between the container packaging films after high pressure steam sterilization at 125 °C for 30 min. being 0.4 or less, and substantially not containing a lubricant and not containing an antiblocking agent .
- a container packaging film made from a composition comprising from 40 to 90 mass% of a propylene- base polymer and from 10 to 60 mass% of a high-density polyethylene (the total of the propylene-base polymer and the high-density polyethylene is 100 mass%), the ratio of MFR of the propylene-base polymer at 230°C to MFR of the high-density polyethylene at 190°C being from 5 to 200, and substantially not containing a lubricant and not containing an antiblocking agent .
- a sealant film comprising a support layer and a sealant layer, wherein the sealant layer is the container packaging film described in (2) or (3).
- a laminate comprising a layer composed of the container packaging film described in ( 2 ) or ( 3 ) , or the sealant film described in (4), and at least one layer selected from the group consisting of a gas barrier layer, a printing layer and a protective layer.
- a container packaging bag, wherein the surface coming into contact with a container is the container packaging film described in ( 2 ) or ( 3 ) .
- a container package wherein a container is housed in the container packaging bag described in ( 6 ) and subjected to high-pressure steam sterilization.
- the propylene-base polymer for use in the present invention is a propylene homopolymer or a propylene* ⁇ -olefin copolymer containing a propylene and an -olefin having from 2 to 20 carbon atoms except for propylene.
- the ⁇ -olefin include ethylene, 1-butene, 1-pentene, 1-hexene, 4- methylpentene-1, 1-octene, 1-decene and 1-dodecene. These are used individually or in combination of two or more thereof.
- ⁇ -olefins preferred are ethylene, 1- butene, 1-pentene, 1-hexene, 4-methylpentene-l and 1-octene, more, preferred is ethylene.
- examples thereof include a random copolymer and a so-called block copolymer commonly called high-impact polypropylene.
- a block copolymer is preferred because when a sealant film described later is formed, the interlayer adhesive strength with the support layer and the flexibility are excellent.
- the catalyst used at the production of the propylene-base polymer is not particularly limited, and a metallocene-base catalyst other than a conventional Ziegler'Natta catalyst can be used. These can be produced by various production processes such as bulk process, solution process, slurry process and gas-phase process.
- the MFR (melt flow rate) of the propylene-base polymer measured in accordance with JIS K 7210 under the conditions of a temperature of 230°C and a load of 21.18N is preferably from 0.1 to 50 g/10 min. If the MFR is less than this range. the moldability is liable to decrease, whereas if the MFR exceeds this range, the strength and the heat-seal property are liable to decrease.
- the MFR is more preferably from 0.1 to 20 g/10 min, still more preferably from 0.25 to 20 g/10 min.
- the high-density polyethylene for use in the present invention is an ethylene homopolymer or an ethylene* -olefin copolymer containing an ethylene and an ⁇ -olefin having from 3 to 20 carbon atoms.
- the ⁇ -olefin include propylene, 1-butene, 1-pentene, 1-hexene, 4- methylpentene-1 , 1-octene, 1-decene and 1-dodecene. These are used individually or in combination of two or more thereof. Among these, preferred are 1-butene, 1-pentene, 1- hexene, 4-methylpentene-l and 1-octene.
- the density of the high-density polyethylene used in the present invention is usually 0.940 g/cm 3 or more, preferably 0.945 g/cm 3 or more, more preferably 0.950 g/cm 3 or more.
- the upper limit is not particularly limited but is about 0.965 g/cm 3 . If the density is less than 0.940 g/cm 3 , poor antiblocking property is liable to result and particularly when sterilization is performed at a temperature exceeding 121°C, the antiblocking property is liable to greatly decrease.
- the MFR of the high-density polyethylene measured in accordance with JIS K 7210 under the conditions of a temperature of 190°C and a load of 21.18N is preferably from 0.05 to 50 g/10 min. With MFR in this range, the resin composition can have a melt tension in an appropriate range and a film can be easily molded.
- the MFR is more preferably from 0.05 to 20 g/10 min, still more preferably from 0.1 to 10 g/10 min.
- the propylene-base polymer is from 40 to 90 mass%, preferably from 60 to 80 mass . %. If the ratio of the propylene-base polymer blended is less than 40 mass%, the appearance of the container packaging film is worsened or the heat resistance is disadvantageously insufficient, whereas if the ratio of the propylene-base polymer blended exceeds 90 mass%, the antiblocking property deteriorates .
- the ratio [MFR(PP)/MFR(HD) ] of MFR of the propylene-base polymer tMFR(PP)] to MFR of the high-density polyethylene [MFR(HD) ] is from 5 to 200, preferably from 10 to 100, more preferably from 15 to 50. If the MFR(PP) /MFR(HD) is less than 5, the antiblocking property may not be sufficiently high, whereas if it exceeds 200, problems disadvantageously arise in the moldability or in the film appearance, for example, gel, fish eye or the like is readily generated on the container packaging film.
- the container packaging film of the present invention is made from a resin composition comprising a propylene-base polymer and a high-density polyethylene, and not substantially containing lubricant and not containing antiblocking agent, wherein the coefficient of kinetic friction between the container packaging films after high pressure steam sterilization at 125 °C for 30 min. is 0.4 or less.
- the coefficient of kinetic friction is a value obtained according to JIS K 7125. If the coefficient of kinetic friction is 0.4 or less, then ease of opening of a container packaging film ameliorates and container can be more easily taken out of the container package. Furthermore, the coefficient of kinetic friction tends to be decreased if the blending ratio of the high- ensity polyethylene is decreased.
- the container packaging film made from the resin composition of the present invention has excellent heat resistance and antiblocking properties .
- the method for obtaining the container packaging film of the present invention is not particularly limited and this film can be obtained, for example, by mixing respective components for use in the resin composition of the present invention in a mixer such as mixing roll, Banbury mixer. Hens ⁇ hel, tumbler and ribbon blender, once forming the mixture into pellets using an extruder or the like, and thereafter molding a film according to various film molding methods .
- a mixer such as mixing roll, Banbury mixer. Hens ⁇ hel, tumbler and ribbon blender, once forming the mixture into pellets using an extruder or the like, and thereafter molding a film according to various film molding methods .
- the film molding method include a method of producing a film by a water cooling or air cooling extrusion inflation method or a T-die casting method.
- the thickness of the container packaging film of the present invention is from 30 to 300 ⁇ m, preferably from 30 to 200 ⁇ m.
- the container packaging film of the present invention can be used as a single layer sealant film but can also be used as a sealant film where a sealant layer and a support layer are laminated using the container packaging film as the sealant layer.
- a sealant film having high transparency and having high smoothness in the support layer side can be obtained.
- the support layer is not particularly limited but general polyolefins such as ethylene-base polymer and propylene-base polymer can be used. Among these, a propylene-base polymer is preferred because of its high heat resistance. Examples , of the propylene-base polymer include homopolypropylene , propylene • ethylene random copolymer and propylene • ethylene block copolymer. Among these, propylene ⁇ ethylene block copolymer is preferred because of high impact resistance.
- the laminate of the present invention comprises a layer composed of the container packaging film or sealant film of the present invention, and at least one layer selected from the group consisting of a gas barrier layer, a printing layer and a protective layer.
- the material for use in the gas barrier layer, printing layer and protective layer is not particularly limited but specific examples thereof include polyethylene, polypropylene, ethylne • vinyl acetate copolymer saponification product (EVOH) , aluminum foil, biaxially stretched or non-stretched polyamide, biaxially stretched or non-stretched polyethylene terephthalate (PET) or polyethylene naphthalate (PEN), aluminum oxide-deposited PET and silica-deposited PET.
- various known molding methods can be used. Specific examples thereof include a method of simultaneously molding a plurality of layers by melt molding, such as water cooling or air cooling (co) extrusion (multilayer) inflation method and (co)extrusion (multilayer) T-die casting method, a method of molding single layer films or sheets and laminating these films or sheets using an adhesive or the like, such as dry lamination method, and a method of previously molding one part film or sheet and melt- laminating the other part film or sheet thereon, such as extrusion lamination method.
- a water cooling or air cooling (co) extrusion (multilayer) inflation method and a (co)extrusion (multilayer) T-die method are preferred.
- the container packaging bag of the present invention is obtained by forming the container packaging film or sealant film of the present invention into a bag using heat- seal.
- the container packaging film composed of the resin composition of the present invention is used.
- the container packaging bag can be obtained by using the container packaging film, sealant film or laminate of the present invention and heat-sealing it into a bag form by means of heat, high-frequency wave, ultrasonic wave or the like.
- a method of obtaining the container after vacuum molding may also be used.
- the resin composition of the present invention can be also formed into a container from the beginning by a hollow molding method or the like. Needless to say, a surface of the container packaging film can be subjected to roughening treatment, depending on the use.
- the container package of the present invention is obtained by housing a container in the container packaging bag of the present invention and subjecting it to high- pressure steam sterilization.
- high-pressure steam sterilization a method such as submerging system and spray system commonly used in the retort field and medical field is used.
- the high-pressure steam sterilization temperature which has been heretofore on the order from 100 to 115°C is recently elevated and a high- pressure steam sterilization temperature of 121°C or more is employed.
- the construction material of the container is also changing from polyethylene, vinyl chloride and the like to propylene-base polymer and the like having high heat resistance and the high-pressure steam sterilization is performed after packaging a container.
- the container includes a single layer container composed of a single material and a multilayer container composed of various materials. In either case, an adhesive layer may be provided, if desired.
- polyolefin-base resins are used as the container material in many cases.
- the container package housing such a container exhibits superior heat resistance and very excellent antiblocking property after the high- pressure steam sterilization at 121°C or more, and also exhibits excellent antiblocking property after high pressure steralization at 125°C.
- the container is composed of a polyolefin-base resin-made flexible sheet or film
- the container is tightly contacted with the container packaging bag to readily generate blocking.
- the container package of the present invention scarcely undergoes blocking.
- the container package of the present invention free from fear of bleeding of an antiblocking agent is advantageous .
- a propylene-base polymer is used for the surface of a container coming into direct contact with the container packaging bag of the present invention, namely, the outer surface of the container, a propylene-base copolymer comprising ethylene or butene-1 as a copolymerization component, or a propylene-base polymer having added thereto an elastomer component such as styrene-base elastomer and olefin-base elastomer is sometimes used so as to impart flexibility to the container.
- the propylene-base copolymer or propylene-base polymer containing an elastomer component readily undergoes blocking as compared with a propylene homopolymer and therefore, the effect of the container package of the present invention having excellent antiblocking property is more clearly exerted.
- the resin composition comprising a specific propylene-base polymer and a specific high-density polyethylene of the present invention, other polymers can of course be blended within a range so as not to impair the object of the present invention.
- Such a polymer include a so-called high-pressure low-density polyethylene, a linear low-density polyethylene, an ethylene* ⁇ -olefin elastomer, various styrene-base elastomers such as styrene*butadiene elastomer, an ethylene'vinyl acetate copolymer, an ethylene* (meth) acrylic acid ester copolymer, an ethylene • (meth) crylic acid copolymer and its ionomer,- however, the present invention is not limited thereto.
- the blending ratio of the other polymers to the whole resin composition of the present invention is less than 40 mass%, and preferably less than 20 mass%.
- an organic or inorganic filler and other commonly used known additives such as antistatic agent, antioxidant, anticlouding agent, organic or inorganic pigment, ultraviolet absorbent and dispersant may be appropriately blended, if desired, so as to, for example, improve the strength, reduce the volume or lower the calorie at the burning for disposal, within the range of not seriously impairing the effect of the present invention.
- a lubricant and an antiblocking agent are necessary to be substantially absent to such an extent of not causing bleeding.
- substantially absent means that a lubricant and antiblocking may be present to such an extent that they do not bleed.
- an antiblocking agent it is preferable for an antiblocking agent to be present at 4000 ppm or less, and for a lubricant to be 4000 ppm or less. It is more preferable for the antiblocking agent to be 1000 ppm or less, and for the lubricant to be 1000 ppm or less. Most preferably, they are not contained at all.
- the propylene-base polymer and high-density polyethylene used are described below.
- the MFR of propylene- base polymer was measured in accordance with JIS K 7210 at a temperature of 230°C under a load of 21.18N.
- the MFR of high-density polyethylene was measured in accordance with
- JIS K 7210 at a temperature of 190°C under a load of 21.18N.
- A2 Propylene • ethylene random copolymer having an MFR of 5 g/10 min, ethylene content: 4.3 mass%.
- A3 Propylene • ethylene block copolymer having an MFR of
- Bl MFR: 1 g/10 min, density: 0.960 g/cm 3
- B2 MFR: 0.6 g/10 min, density: 0.955 g/cm 3 (Additives )
- the propylene • ethylene random copolymer of A2 was molded at a temperature of 230°C using a T-die film casting machine to obtain a film having a thickness of 200 ⁇ m.
- This film was cut into 20 cm x 20 cm square, two films were combined and three edges of one film were heat-sealed with three edges of another film, respectively, at temperature of 180°C and pressure of 0.2MPa, for 1 second with heat-sealing width being 10 mm, to obtain a container. After filling 1 liter of distilled water in this container, the remaining one edge and another part one edge were heat-sealed and this was used as a container sample.
- a propylene-base polymer, a high-density polyethylene and an additive were mixed by a Henschel mixer to give a composition shown in Table 1.
- the obtained composition was cast at a temperature of 230°C by a T-die casting machine to obtain a container packaging film of 70 ⁇ m.
- This film was cut into a 35 cm square, two films were combined, and three edges of one film were heat-sealed with three edges of another film, respectively, at temperature of 180°C and pressure of 0.2MPa, for 1 second with heat-sealing width being 10 mm, to manufacture a container packaging bag.
- the container sample prepared above was housed. Then, while depressurizing the inside by a vacuum pump, the remaining one edge and another part one edge of films were heat-sealed to obtain a container package.
- This sample was subjected to a sterilization treatment at 125°C for 30 minutes using a spray-system high-pressure steam sterilizer.
- the container after the high-pressure steam sterilization is taken out of the container packaging bag, and a region of 30 cm x 30 cm of the container package was divided into 9 sections each in a size of 10 cm x 10 cm and the roughened state of the inner and outer surfaces was observed with an eye.
- the number of sections in a uniform ground glass state and having a good appearance and the number of sections having a non-uniformly roughened surface and a poor appearance were counted and the evaluation was performed according to the following criteria:
- ⁇ The number of sections having a good appearance is from 4 to 6.
- the container package after the high-pressure steam sterilization was opened and the container was taken out with a hand from the container package.
- the evaluation was performed according to the following criteria:
- the container can be easily taken out without causing any catch or resistance.
- Blocking is weakly generated between a part of the container and a part of the container packaging bag but the container can be easily taken out.
- Two-layers sealant film having, as a sealant layer, a resin composition with the same kind and blending amount as in Example 1, and, as support layer, propylene-base polymer as shown in Table 2 was subjected to cast using a multilayer T-die casting machine at 230°C. Evaluation of the film impact is shown in Table 2.
- Table 1
- Blending ratio assuming that the total of propylene- base polymer + high-density polyethylene is 100 mass%.
- the container packaging film comprising the resin composition of the present invention uses an inexpensive polyolefin and therefore, costs low.
- the film has excellent appearance and antiblocking property and therefore, when formed into a container packaging bag, the container can be easily taken out.
- the film does not substantially contain a lubricant and not contain an antiblocking agent and free of fear of contamination of the container and therefore, can be used in the field of container packaging such as medical container packaging.
- the present invention is useful.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Wrappers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Packages (AREA)
- Bag Frames (AREA)
Applications Claiming Priority (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2001397606 | 2001-12-27 | ||
JP2001397606 | 2001-12-27 | ||
US35003002P | 2002-01-23 | 2002-01-23 | |
US350030P | 2002-01-23 | ||
JP2002335008 | 2002-11-19 | ||
JP2002335008A JP2006016410A (ja) | 2001-12-27 | 2002-11-19 | 樹脂組成物、それを用いた容器包装用フィルム、容器包装袋及び容器包装体 |
PCT/JP2002/013500 WO2003055943A2 (en) | 2001-12-27 | 2002-12-25 | Resin composition, and container packaging film, container packaging bag and container package using the resin composition |
Publications (1)
Publication Number | Publication Date |
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EP1458809A2 true EP1458809A2 (de) | 2004-09-22 |
Family
ID=27348027
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02795426A Withdrawn EP1458809A2 (de) | 2001-12-27 | 2002-12-25 | Zusammensetzung, und verpackungsfolie, verpackungsbeutel, verpackungsbehälter wobei diese zusammensetzun verwendet wird |
Country Status (5)
Country | Link |
---|---|
US (1) | US20050031815A1 (de) |
EP (1) | EP1458809A2 (de) |
CN (1) | CN1608106A (de) |
AU (1) | AU2002360214A1 (de) |
WO (1) | WO2003055943A2 (de) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2005097358A (ja) * | 2003-09-22 | 2005-04-14 | Showa Denko Plastic Products Co Ltd | ポリプロピレン系成形体及び容器 |
US20050085785A1 (en) * | 2003-10-17 | 2005-04-21 | Sherwin Shang | High impact strength film and non-pvc containing container and pouch and overpouch |
GB0607280D0 (en) * | 2006-04-11 | 2006-05-17 | Exxonmobil Chem Patents Inc | Process for extrusion coating and laminating oriented polypropylene film, tie-layer compositions for such a process and multi-layer films with layers bonded |
JP2010265449A (ja) * | 2009-04-14 | 2010-11-25 | Tosoh Corp | プロピレン重合体樹脂組成物 |
EP2452974A4 (de) * | 2009-07-09 | 2013-03-06 | Mitsui Du Pont Polychemical | Polymerzusammensetzung, verfahren zur herstellung einer nicht gedehnten folie, nicht gedehnte folie, wärmeversiegelungsmaterial und verpackungsmaterial |
CN102218875B (zh) * | 2011-03-31 | 2014-05-28 | 常州市嘉鹏塑料制品有限公司 | 防粘连医用复合薄膜 |
WO2019134120A1 (en) * | 2018-01-05 | 2019-07-11 | Baxter International Inc | Multi-layer articles and methods for producing the same |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4578316A (en) * | 1984-12-19 | 1986-03-25 | Mobil Oil Corporation | Multi-layer oriented polypropylene films with low COF skin(s) |
US4894266A (en) * | 1987-08-05 | 1990-01-16 | American National Can Company | Multiple layer packaging sheet material |
US5358791A (en) * | 1993-03-01 | 1994-10-25 | American National Can Company | Sterilizable packaging film |
ES2239318T3 (es) * | 1994-03-15 | 2005-09-16 | Otsuka Pharmaceutical Factory, Inc. | Utilizacion de una pelicula de sellado que evita la contaminacion en el embalaje medico. |
MY117691A (en) * | 1997-07-17 | 2004-07-31 | Otsuka Pharma Co Ltd | Multilayer film and container |
JP2001199023A (ja) * | 2000-01-17 | 2001-07-24 | Japan Polyolefins Co Ltd | 易カット性積層体およびその製造方法 |
JP2001253026A (ja) * | 2000-03-14 | 2001-09-18 | Showa Denko Plastic Products Co Ltd | 積層フィルム |
-
2002
- 2002-12-25 US US10/499,974 patent/US20050031815A1/en not_active Abandoned
- 2002-12-25 EP EP02795426A patent/EP1458809A2/de not_active Withdrawn
- 2002-12-25 CN CNA028260317A patent/CN1608106A/zh active Pending
- 2002-12-25 WO PCT/JP2002/013500 patent/WO2003055943A2/en not_active Application Discontinuation
- 2002-12-25 AU AU2002360214A patent/AU2002360214A1/en not_active Abandoned
Non-Patent Citations (1)
Title |
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See references of WO03055943A2 * |
Also Published As
Publication number | Publication date |
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US20050031815A1 (en) | 2005-02-10 |
AU2002360214A1 (en) | 2003-07-15 |
WO2003055943A2 (en) | 2003-07-10 |
CN1608106A (zh) | 2005-04-20 |
WO2003055943A3 (en) | 2004-02-19 |
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