EP1409937B1 - Procede de production de vapeur d'eau et de distillation d'air - Google Patents
Procede de production de vapeur d'eau et de distillation d'air Download PDFInfo
- Publication number
- EP1409937B1 EP1409937B1 EP02751288A EP02751288A EP1409937B1 EP 1409937 B1 EP1409937 B1 EP 1409937B1 EP 02751288 A EP02751288 A EP 02751288A EP 02751288 A EP02751288 A EP 02751288A EP 1409937 B1 EP1409937 B1 EP 1409937B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- steam
- expansion means
- inlet
- unit
- industrial
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04521—Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04012—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling
- F25J3/04018—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling of main feed air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04012—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling
- F25J3/04024—Providing pressurised feed air or process streams within or from the air fractionation unit by compression of warm gaseous streams; details of intake or interstage cooling of purified feed air, so-called boosted air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04078—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression
- F25J3/0409—Providing pressurised feed air or process streams within or from the air fractionation unit providing pressurized products by liquid compression and vaporisation with cold recovery, i.e. so-called internal compression of oxygen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04109—Arrangements of compressors and /or their drivers
- F25J3/04115—Arrangements of compressors and /or their drivers characterised by the type of prime driver, e.g. hot gas expander
- F25J3/04121—Steam turbine as the prime mechanical driver
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04006—Providing pressurised feed air or process streams within or from the air fractionation unit
- F25J3/04109—Arrangements of compressors and /or their drivers
- F25J3/04145—Mechanically coupling of different compressors of the air fractionation process to the same driver(s)
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04521—Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
- F25J3/04527—Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general
- F25J3/04539—Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general for the H2/CO synthesis by partial oxidation or oxygen consuming reforming processes of fuels
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04521—Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
- F25J3/04527—Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general
- F25J3/04539—Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general for the H2/CO synthesis by partial oxidation or oxygen consuming reforming processes of fuels
- F25J3/04545—Integration with an oxygen consuming unit, e.g. glass facility, waste incineration or oxygen based processes in general for the H2/CO synthesis by partial oxidation or oxygen consuming reforming processes of fuels for the gasification of solid or heavy liquid fuels, e.g. integrated gasification combined cycle [IGCC]
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04521—Coupling of the air fractionation unit to an air gas-consuming unit, so-called integrated processes
- F25J3/04563—Integration with a nitrogen consuming unit, e.g. for purging, inerting, cooling or heating
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04763—Start-up or control of the process; Details of the apparatus used
- F25J3/04769—Operation, control and regulation of the process; Instrumentation within the process
- F25J3/04812—Different modes, i.e. "runs" of operation
- F25J3/04818—Start-up of the process
Definitions
- the present invention relates to a method of driving at least one compression machine of an air distillation unit which supplies oxygen and / or nitrogen and / or argon to a industrial unit producing water vapor, this process being of the type in which, in steady state, the compression machine is driven at least in part by means of steam relief with production of external work, fed by steam water from said industrial unit, this vapor being introduced at an inlet of said expansion means.
- Some industrial processes consuming oxygen and / or nitrogen and / or argon such as synthetic hydrocarbon production processes (so-called “Gas to Liquid” or “GTL” processes), are exothermic and generate water vapor.
- the steam is generally valorized as a source of entrainment, via a steam turbine, of at least one compression machine of the distillation unit. of air that produces oxygen.
- the steam turbine may be a back pressure turbine, escaping a pressure greater than atmospheric pressure, or a condensing turbine, escaping a pressure below atmospheric pressure and associated with a water condenser, cooled by water or ambient air, and a water recycling pump to the steam boiler.
- EP-A-0930268 discloses an air separation apparatus whose main compressor is coupled to an electric motor and a steam turbine which receives steam at two different pressures. During startup, the main compressor and the electric motor operate using electricity generated by a gas turbine.
- US Patent 6058736 describes a method of compressing an air flow supplying an industrial unit. It uses a gas turbine to drive the main compressor in steady state and a steam turbine during startup of the industrial unit.
- the invention aims to solve this problem in a particularly flexible manner, eliminating the electric motor.
- the subject of the invention is a method according to claim 1 or 2.
- the combined installation shown on the Figure 1 consists on the one hand of a GTL unit 1 which produces, among others, water vapor under high pressure in a line 2, and on the other hand an air distillation unit 3 which feeds unit 1 in gaseous oxygen gas HPGOX, via a line 4, and also in high pressure nitrogen gas HPGN, via a line 5 equipped with a nitrogen compressor 6.
- a GTL unit 1 which produces, among others, water vapor under high pressure in a line 2
- an air distillation unit 3 which feeds unit 1 in gaseous oxygen gas HPGOX, via a line 4, and also in high pressure nitrogen gas HPGN, via a line 5 equipped with a nitrogen compressor 6.
- HPGOX gaseous oxygen gas
- HPGN high pressure nitrogen gas
- the unit 3 essentially comprises a first compression machine constituted by a main air compressor 7 (or, alternatively, by several compressors in parallel), a second compression machine constituted by an air booster 8 (or, in variant, by several boosters in parallel), and a cold box 9.
- the latter essentially comprises an air distillation apparatus 10, for example a double column comprising a medium pressure distillation column and a low pressure distillation column coupled by a vaporizer-condenser, and a heat exchange line 11.
- the compressor 7 and the booster 8 are mounted on the same shaft 12, coupled to a steam turbine 13 via a Coupling device disengageable 14.
- the turbine 13 has two inputs: a high pressure inlet 15, located at the suction of the turbine, and a medium pressure inlet 16, located between the high pressure supply and the exhaust of the turbine .
- the exhaust port of the turbine has been indicated at 17 at atmospheric pressure or at a pressure above or below atmospheric pressure.
- the apparatus 10 produces liquid oxygen LOX under the low pressure, and this liquid oxygen is brought to the high production pressure by a pump 18, before being vaporized and reheated in the exchange line 11.
- Apparatus 10 also produces gaseous nitrogen GN, under low pressure and / or under medium pressure, which is heated in the exchange line and then compressed at 6 to the high production pressure.
- the atmospheric air, compressed at medium pressure at 7, is pre-cooled in an air or water pre-cooler 19, purified with water and CO 2 in an adsorption purification apparatus 20, and separated into two streams.
- a first medium pressure air stream which is cooled at 11 to the vicinity of its dew point to be distilled at 10
- a second air stream which is supercharged at 8 at a high pressure allowing the vaporization of the high pressure liquid oxygen in the exchange line.
- Unit 3 further comprises an auxiliary boiler 21 which produces auxiliary steam at medium pressure in a line 22.
- the latter provided with a valve 23, is connected to the medium pressure inlet 16 of the turbine 13 while line 2 is connected to the high pressure inlet 15.
- the high pressure steam is at about 60 bars and the average pressure steam at about 15 bars.
- a bypass 24 equipped with a valve 25 connects the inputs 15 and 16.
- a medium pressure steam booster can be supplied to the inlet 16, as indicated in dotted lines.
- the Figures 3A and 3B relate to the case where the auxiliary steam is at a pressure greater than that of the steam produced by the unit 1.
- the first start step is ( Figures 1 and 3A ) to introduce the auxiliary steam at the inlet 15.
- a second step shown in line mixed on the Figure 3A , the medium pressure steam, increasing flow, is introduced to the inlet 16, via the pipe 2, while the flow rate of the makeup steam is reduced correspondingly.
- the compressor 6 can be coupled to the shaft 12, replacing the booster 8 or in addition.
- auxiliary oxygen source for example a liquid oxygen storage tank
- the unit 1 can be started with this oxygen.
- the turbine 13 is then, at the start of the unit 3, fed a minority by the steam from the unit 1, and mainly by the auxiliary steam from the source 21.
- the ratio is for example 30% - 70%.
- the proportion of auxiliary steam gradually decreases, until the established regime, where it is a minority, especially less than 30% and, more preferably, less than 10%, or even zero.
- the turbine may be composed of either a single body with two inputs that correspond to different inlet pressures, or two bodies each having an inlet. In the latter case, a body of the turbine is fed with steam from the industrial unit 1, and the other body by auxiliary steam. The two bodies of the turbine are then either mechanically interconnected or mechanically connected to the body of at least one compression machine of the air distillation unit.
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Separation By Low-Temperature Treatments (AREA)
- Control Of Turbines (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0109307 | 2001-07-12 | ||
FR0109307A FR2827187B1 (fr) | 2001-07-12 | 2001-07-12 | Procede et installation de production de vapeur d'eau et de distillation d'air |
PCT/FR2002/002225 WO2003006902A1 (fr) | 2001-07-12 | 2002-06-27 | Procede et installation de production de vapeur d'eau et de distillation d'air |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1409937A1 EP1409937A1 (fr) | 2004-04-21 |
EP1409937B1 true EP1409937B1 (fr) | 2010-12-08 |
Family
ID=8865438
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02751288A Expired - Lifetime EP1409937B1 (fr) | 2001-07-12 | 2002-06-27 | Procede de production de vapeur d'eau et de distillation d'air |
Country Status (7)
Country | Link |
---|---|
US (1) | US7010919B2 (ja) |
EP (1) | EP1409937B1 (ja) |
JP (1) | JP4422478B2 (ja) |
DE (1) | DE60238537D1 (ja) |
ES (1) | ES2357500T3 (ja) |
FR (1) | FR2827187B1 (ja) |
WO (1) | WO2003006902A1 (ja) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060123844A1 (en) * | 2004-12-09 | 2006-06-15 | Patrick Le Bot | Integrated process for the separation of air and an integrated installation for the separation of air |
JP4240155B1 (ja) * | 2008-03-06 | 2009-03-18 | 三浦工業株式会社 | 蒸気システム |
US20090235641A1 (en) * | 2008-03-20 | 2009-09-24 | Kevin Marion Brown | T-Jet |
WO2020160842A1 (en) | 2019-02-07 | 2020-08-13 | Linde Gmbh | Gas treatment method and apparatus including an oxidative process for treating a sour gas mixture using gas from an air separation process |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3731495A (en) * | 1970-12-28 | 1973-05-08 | Union Carbide Corp | Process of and apparatus for air separation with nitrogen quenched power turbine |
US4223529A (en) * | 1979-08-03 | 1980-09-23 | General Electric Company | Combined cycle power plant with pressurized fluidized bed combustor |
US4326382A (en) * | 1980-10-24 | 1982-04-27 | E. H. Robbins | Power plant |
DE3660191D1 (en) * | 1985-08-05 | 1988-06-16 | Siemens Ag | Combined cycle power station |
US5628179A (en) * | 1993-11-04 | 1997-05-13 | General Electric Co. | Steam attemperation circuit for a combined cycle steam cooled gas turbine |
GB9717349D0 (en) * | 1997-08-15 | 1997-10-22 | Boc Group Plc | Air separation plant |
GB9801200D0 (en) * | 1998-01-20 | 1998-03-18 | Air Prod & Chem | Intergration of a cryogenic air separator with synthesis gas production and conversion |
-
2001
- 2001-07-12 FR FR0109307A patent/FR2827187B1/fr not_active Expired - Fee Related
-
2002
- 2002-06-27 ES ES02751288T patent/ES2357500T3/es not_active Expired - Lifetime
- 2002-06-27 JP JP2003512624A patent/JP4422478B2/ja not_active Expired - Fee Related
- 2002-06-27 US US10/483,917 patent/US7010919B2/en not_active Expired - Fee Related
- 2002-06-27 DE DE60238537T patent/DE60238537D1/de not_active Expired - Lifetime
- 2002-06-27 EP EP02751288A patent/EP1409937B1/fr not_active Expired - Lifetime
- 2002-06-27 WO PCT/FR2002/002225 patent/WO2003006902A1/fr active Application Filing
Also Published As
Publication number | Publication date |
---|---|
JP4422478B2 (ja) | 2010-02-24 |
EP1409937A1 (fr) | 2004-04-21 |
FR2827187B1 (fr) | 2004-07-23 |
US7010919B2 (en) | 2006-03-14 |
US20040211183A1 (en) | 2004-10-28 |
JP2004536251A (ja) | 2004-12-02 |
DE60238537D1 (de) | 2011-01-20 |
FR2827187A1 (fr) | 2003-01-17 |
ES2357500T3 (es) | 2011-04-27 |
WO2003006902A1 (fr) | 2003-01-23 |
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