EP1367350A1 - Wärmetauscher mit gewickelten Rohrschlangen - Google Patents

Wärmetauscher mit gewickelten Rohrschlangen Download PDF

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Publication number
EP1367350A1
EP1367350A1 EP02011583A EP02011583A EP1367350A1 EP 1367350 A1 EP1367350 A1 EP 1367350A1 EP 02011583 A EP02011583 A EP 02011583A EP 02011583 A EP02011583 A EP 02011583A EP 1367350 A1 EP1367350 A1 EP 1367350A1
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EP
European Patent Office
Prior art keywords
coil wound
tube
tubes
bundle
group
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP02011583A
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English (en)
French (fr)
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EP1367350B2 (de
EP1367350B1 (de
Inventor
Timothy Truong
Yu-Nan Liu
Glenn Eugene Kinard
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Air Products and Chemicals Inc
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Air Products and Chemicals Inc
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Application filed by Air Products and Chemicals Inc filed Critical Air Products and Chemicals Inc
Priority to EP02011583A priority Critical patent/EP1367350B2/de
Priority to DE60207689T priority patent/DE60207689T3/de
Priority to ES02011583T priority patent/ES2254555T5/es
Priority to AT02011583T priority patent/ATE311580T1/de
Publication of EP1367350A1 publication Critical patent/EP1367350A1/de
Application granted granted Critical
Publication of EP1367350B1 publication Critical patent/EP1367350B1/de
Publication of EP1367350B2 publication Critical patent/EP1367350B2/de
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    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/006—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the refrigerant fluid used
    • F25J1/008—Hydrocarbons
    • F25J1/0087—Propane; Propylene
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
    • F25J1/0022—Hydrocarbons, e.g. natural gas
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0047—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
    • F25J1/0052—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
    • F25J1/0047—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle
    • F25J1/0052—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream
    • F25J1/0055—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using an "external" refrigerant stream in a closed vapor compression cycle by vaporising a liquid refrigerant stream originating from an incorporated cascade
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0211—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle
    • F25J1/0214—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle
    • F25J1/0215—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle with one SCR cycle
    • F25J1/0216—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a multi-component refrigerant [MCR] fluid in a closed vapor compression cycle as a dual level refrigeration cascade with at least one MCR cycle with one SCR cycle using a C3 pre-cooling cycle
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
    • F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
    • F25J1/0243—Start-up or control of the process; Details of the apparatus used; Details of the refrigerant compression system used
    • F25J1/0257—Construction and layout of liquefaction equipments, e.g. valves, machines
    • F25J1/0262—Details of the cold heat exchange system
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J5/00—Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants
    • F25J5/002—Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants for continuously recuperating cold, i.e. in a so-called recuperative heat exchanger
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/0066—Multi-circuit heat-exchangers, e.g. integrating different heat exchange sections in the same unit or heat-exchangers for more than two fluids
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/02—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being helically coiled
    • F28D7/024—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being helically coiled the conduits of only one medium being helically coiled tubes, the coils having a cylindrical configuration
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2220/00—Processes or apparatus involving steps for the removal of impurities
    • F25J2220/60—Separating impurities from natural gas, e.g. mercury, cyclic hydrocarbons
    • F25J2220/64—Separating heavy hydrocarbons, e.g. NGL, LPG, C4+ hydrocarbons or heavy condensates in general
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2240/00—Processes or apparatus involving steps for expanding of process streams
    • F25J2240/40—Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2290/00—Other details not covered by groups F25J2200/00 - F25J2280/00
    • F25J2290/12—Particular process parameters like pressure, temperature, ratios

Definitions

  • Coil wound heat exchangers are used in the process industries for heating or cooling fluid streams at high heat transfer rates which require large heat transfer areas.
  • Coil wound heat exchangers also known as spiral wound or spool wound heat exchangers, are particularly useful for cooling and condensing high pressure gas streams.
  • LNG liquefied natural gas
  • large surface areas are required for the indirect transfer of heat between refrigerants and the pressurized feed gas, which is cooled from ambient temperature to yield LNG at temperatures near-260°F.
  • Coil wound heat exchangers are ideally suited for use in LNG process cycles at cryogenic conditions.
  • Coil wound heat exchangers utilize tubing bundles constructed of large numbers of long tubes which are helically wound about an axial central core or mandrel. Numerous tube layers are formed in the radial direction, each layer being separated from adjacent layers by axial spacers or spacer wires. One or more bundles can be installed in a pressure vessel with appropriate headers and piping for introducing streams to be cooled into the tubes and withdrawing cooled liquefied streams from the tubes. Additional piping is used for fluid flow between bundles. Refrigeration typically is provided in these exchangers by mixed refrigerants vaporizing on the outer side, or shell side, of the tubes.
  • the invention relates to a coil wound tubing assembly for use in a coil wound heat exchanger, which tubing assembly comprises a first coil wound tubing bundle and a second coil wound tubing bundle, wherein one or more groups of tubes in the first coil wound tubing bundle are connected in direct fluid flow communication with one or more groups of tubes in the second coil wound tubing bundle, characterized in that the first and the second coil wound tubing bundles differ in one or more parameters selected from a group including mandrel outer diameter, spacer thickness, number of spacers, number of tubes, tubing inner diameter, tubing outer diameter, tube length, tube pitch, and tube winding angle.
  • Each group of tubes in the first coil wound tubing bundle may be connected in direct fluid flow communication with a group of tubes in the second coil wound tubing bundle.
  • the first and second coil wound tubing bundles may be vertically oriented and the second coil wound tubing bundle may be located above the first coil wound tubing bundle.
  • the first and second coil wound tubing bundles may be coaxial.
  • the invention also relates to a coil wound heat exchanger system which comprises a vertical cylindrical heat exchanger vessel comprising a first section having a first diameter; a first coil wound tubing bundle disposed axially in the first section of the heat exchanger vessel; and a second coil wound tubing bundle disposed axially in the first section of the heat exchanger vessel above the first coil wound tubing bundle, wherein one or more groups of tubes in the first coil wound tubing bundle are connected in direct fluid flow communication with one or more groups of tubes in the second coil wound tubing bundle.
  • the first and the second coil wound tubing bundles may differ in one or more parameters selected from a group including mandrel outer diameter, spacer thickness, number of spacers, number of tubes, tubing inner diameter, tubing outer diameter, bundle outer diameter, tube length, tube pitch, and tube winding angle.
  • the first coil wound tubing bundle may include:
  • the second coil wound tubing bundle may include:
  • the coil wound heat exchanger system may further comprise:
  • the coil wound heat exchanger system may further comprise means for aggregating the outlet ends of a plurality of tubes in the first coil wound tubing bundle to form a second group of tube outlets, means for aggregating the inlet ends of a plurality of tubes in the second coil wound tubing bundle to form a second group of tube inlets, and means for placing the second group of tube outlets in the first coil wound tubing bundle in fluid flow communication with the second group of tube inlets in the second coil wound tubing bundle.
  • the coil wound heat exchanger system also may further comprise means for aggregating the outlet ends of a plurality of tubes in the first coil wound tubing bundle to form a third group of tube outlets, means for aggregating the inlet ends of a plurality of tubes in the second coil wound tubing bundle to form a third group of tube inlets, and means for placing the third group of tube outlets in the first coil wound tubing bundle in fluid flow communication with the third group of tube inlets in the second coil wound tubing bundle.
  • the coil wound heat exchanger system also may further comprise means for aggregating the inlet ends of a plurality of tubes in the first coil wound tubing bundle to form a first group of tube inlets, and means for placing the first group of tube inlets in the first coil wound tubing bundle in fluid flow communication with a feed gas inlet line.
  • the system may include means for aggregating the inlet ends of a plurality of tubes in the first coil wound tubing bundle to form a second group of tube inlets, and means for placing the second group of tube inlets in the first coil wound tubing bundle in fluid flow communication with a vapor refrigerant inlet line.
  • the system also may comprise means for aggregating the inlet ends of a plurality of tubes in the first coil wound tubing bundle to form a third group of tube inlets, and means for placing the third group of tube inlets in the first coil wound tubing bundle in fluid flow communication with a liquid refrigerant inlet line.
  • the system may include means for aggregating the outlet ends of a plurality of tubes in the second coil wound tubing bundle to form a first group of tube outlets, means for aggregating the outlet ends of a plurality of tubes in the second coil wound tubing bundle to form a second group of tube outlets, and means for aggregating the outlet ends of two or more additional sets of tubes in the second coil wound tubing bundle to form a third group of tube outlets.
  • a refrigerant distributor may be disposed above the second coil wound tubing bundle.
  • the coil wound heat exchanger system may also comprise means for placing the third group of tube outlets in the second coil wound tubing bundle in fluid flow communication with the refrigerant distributor above the second wound coil tubing bundle.
  • the coil wound heat exchanger system may further comprise:
  • the coil wound heat exchanger system may further include means for aggregating the inlet ends of a plurality of tubes in the third coil wound tubing bundle to form a first group of tube inlets and means for placing the first group of tube inlets in the third coil wound tubing bundle in fluid flow communication with the first group of tube outlets in the second coil wound tubing bundle.
  • the coil wound heat exchanger system may further comprise means for aggregating the inlet ends of a plurality of tubes in the third coil wound tubing bundle to form a second group of tube inlets and means for placing the second group of tube inlets in the third coil wound tubing bundle in fluid flow communication with the second group of tube outlets in the second coil wound tubing bundle. Also, the system may utilize means for aggregating the outlet ends of a plurality of tubes in the third coil wound tubing bundle to form a first group of tube outlets, and means for placing the first group of tube outlets in the third coil wound tubing bundle in fluid flow communication with a cooled liquid product outlet line.
  • Another embodiment may include a refrigerant distributor disposed above the third coil wound tubing bundle.
  • the coil wound heat exchanger system may further comprise means for aggregating the outlet ends of a plurality of tubes in the third coil wound tubing bundle to form a second group of tube outlets and means for placing the second group of tube outlets in the third coil wound tubing bundle in fluid flow communication with the refrigerant distributor above the third wound coil tubing bundle.
  • Piping means may be included for withdrawing refrigerant vapor from the vertical heat exchanger vessel at a location below the first coil wound tubing bundle.
  • the coil wound heat exchanger system also may utilize a refrigerant redistributor disposed below the second coil wound tubing bundle and above the first coil wound tubing bundle.
  • the invention relates to a process for gas liquefaction which comprises
  • the process may further comprise introducing the further cooled and partially liquefied feed stream into a first group of coil wound tubes in a third coil wound tubing bundle and further cooling the cooled feed stream by indirect heat exchange with a refrigerant to yield a liquefied product.
  • the first, second, and third coil wound tubing bundles may be vertically oriented, the second coil wound tubing bundle may be located above the first coil wound tubing bundle, and the third coil wound tubing bundle may located above the second coil wound tubing bundle.
  • the first, second, and third coil wound tubing bundles may be disposed coaxially in a vertical cylindrical heat exchanger vessel having a first section with a first diameter and a second section with a second diameter, wherein the first and second wound coil tubing bundles are disposed in the first section and the third wound coil tubing bundle is disposed in the second section, and wherein the first and the second coil wound tubing bundles differ in one or more parameters selected from a group including mandrel outer diameter, spacer thickness, number of spacers, number of tubes, tubing inner diameter, tubing outer diameter, tube length, tube pitch, tube winding angle, and bundle diameter.
  • Fig. 1 is a schematic illustration of a heat exchanger according to the prior art.
  • Fig. 2 is a schematic illustration of an exemplary heat exchanger according to the present invention.
  • Fig. 3 is a schematic flow diagram of an exemplary gas liquefaction process which uses the heat exchanger of the present invention.
  • Coil wound heat exchangers have been used for many years in cryogenic gas liquefaction and the cryogenic separation of gas mixtures. This type of exchanger has found particularly widespread application in the liquefaction of low-boiling gases such as helium, hydrogen, and methane. Most of the world's baseload LNG production uses wound coil heat exchangers for gas liquefaction and for intermediate cooling of mixed component refrigerants.
  • the present invention may be used in any process application of coil wound heat exchangers, particularly those operating at cryogenic temperatures. These applications often involve high heat transfer rates, large heat transfer areas, and/or large temperature changes between a process stream inlet and outlet.
  • the invention is illustrated by, but is not limited to, the liquefaction of natural gas as described below.
  • FIG. 1 A main heat exchanger of a type known in the natural gas liquefaction field is shown in the schematic drawing of Fig. 1.
  • This particular exchanger utilizes two coil wound bundles for the final cooling and liquefaction of a pretreated natural gas feed.
  • Main heat exchanger 1 comprises pressure vessel 3, warm heat exchange zone 5, and cold heat exchange zone 9.
  • a first coil wound heat exchanger bundle is utilized in cold heat exchange zone 5 in which a feed gas provided in line 11 is initially cooled in tube circuit 13 against a vaporizing refrigerant (later described) on the shell side of the bundle.
  • Tube circuit 13 represents multiple tubes which are part of a coil wound bundle, wherein the bundle also includes tube circuits 31 and 39 as described later. Tubes typically may be made of aluminum.
  • Feed gas in line 15 which has been cooled and at least partially condensed optionally is reduced in pressure across throttling valve 17.
  • the reduced-pressure feed then flows via line 19 into tube circuit 21 in cold heat exchange zone 9, wherein the feed is further cooled and withdrawn as product via line 23.
  • a two-phase compressed refrigerant typically a multicomponent refrigerant containing light hydrocarbons and optionally nitrogen, is supplied via line 25 from a refrigerant compression system (not shown) and flows into phase separator 27.
  • Refrigerant liquid is withdrawn via line 29, subcooled in tube circuit 31, and reduced in pressure across throttling valve 33.
  • a hydraulic expansion turbine may be used to extract work from the refrigerant liquid prior to throttling valve 33.
  • the refrigerant from throttling valve 33 is combined with refrigerant flowing downward from cold heat exchange zone 9 (described later) and the combined refrigerant is distributed via distributor 35.
  • the combined refrigerant flows downward over the outer or shell side of the coil wound bundle therein while vaporizing and warming to provide a portion of the refrigeration for cooling the feed gas in tube circuit 13 as earlier described.
  • the vaporizing refrigerant provides some of the refrigeration to subcool the refrigerant vapor in tube circuit 31 and to cool the liquid refrigerant in tube circuit 39 (described below).
  • Vapor refrigerant is withdrawn from separator 27 via line 37, is cooled and may be partially condensed in tube circuit 39 in warm heat exchange zone 5, and finally passes through tube circuit 41 in cold heat exchange zone 9, wherein it is liquefied and optionally subcooled.
  • This refrigerant is reduced in pressure across throttling valve 43 and distributed via distributor 45 in cold heat exchange zone 9.
  • This refrigerant flows downward over the outer or shell side of the coil wound bundle and vaporizes to provide a portion of the refrigeration for cooling the feed gas in tube circuit 21 as earlier described.
  • the vaporizing refrigerant provides some of the refrigeration to cool the refrigerant in tube circuit 41.
  • Distributor 45 is shown schematically and may include means for phase separation and distribution of separate vapor and liquid refrigerant streams to heat exchange zone 9.
  • Two-phase refrigerant leaving the shell side of cold heat exchange zone 9 enters warm heat exchange zone 5 and joins with the refrigerant discharged from throttling valve 33.
  • the combined refrigerant is distributed via distributor 35 and flows downward over the outer or shell side of the coil wound bundle in warm heat exchange zone 5.
  • the refrigerant is typically totally vaporized upon reaching the bottom of heat exchanger pressure vessel 3, and is withdrawn as vapor via line 47. This vapor is compressed in the refrigerant compression system (not shown) and optionally precooled to provide the two-phase cooled compressed refrigerant via line 25 as earlier described.
  • Tube circuits 13, 31, and 39 in warm heat exchange zone 5 are parts of a single coil wound tubing bundle which is installed in warm heat exchange zone 5 of heat exchanger pressure vessel 3.
  • This coil wound tubing bundle can be fabricated by methods known in the art of coil wound heat exchanger fabrication in which groups of long aluminum tubes of similar length are helically wound about an axial central core or mandrel.
  • the mandrel may be a cylindrical pipe having a length, outer diameter, and wall thickness which impart the required structural strength to support the desired layers of tubing.
  • solid rods may be wound helically about and in contact with the mandrel, spacers may be installed on the wound rods parallel to the mandrel axis, and then tubes may be helically wound in a first layer in contact with the spacers.
  • each layer typically is separated from adjacent layers by axial or helical spacers or spacer wires.
  • Winding can be done with the mandrel axis oriented vertically in a fixed position while the tubing is wound onto the coil bundle from reels adapted to move circumferentially about the axis, and also to move upward and downward parallel to the axis.
  • These exchangers are often known as spool-wound exchangers.
  • the bundles can be built by rotating the mandrel and bundle on a lathe about a fixed horizontal axis while tubing is wound onto the coil from reels adapted to move axially, i.e., from side to side.
  • This coil wound tubing bundle is characterized by a number of fabrication or dimensional parameters which include the mandrel outer diameter, spacer thickness, number of spacers, number of tubes, tubing inner diameter, tubing outer diameter, bundle outer diameter, tube length, tube pitch, and tube winding angle.
  • the tubes in each of tube circuits 13, 31, and 39 typically are aggregated at each end, for example by gathering the multiple tubes from each circuit into one or more tube sheets which can be connected to inlet and outlet lines.
  • Tube circuits 21 and 41 are part of a single coil wound tubing bundle which is installed in cold heat exchange zone 9 of heat exchanger pressure vessel 3. This coil wound tubing bundle can be fabricated by the same methods described above for the wound coil in warm heat exchange zone 5. Each of tube circuits 21 and 41 is aggregated at each end, for example by gathering the multiple tubes from each circuit into one or more tube sheets which can be connected to inlet and outlet lines.
  • the net vapor fraction increases and the heat transfer mechanism changes gradually from predominantly two-phase boiling heat transfer at the cold or top end to single-phase vapor heat transfer at the warm or bottom end. While the nature of the heat transfer mechanism changes significantly from top to bottom of the bundle, none of the fabrication parameters of the coil wound bundle change from top to bottom. Certain of these parameters determine the basic fluid flow and heat transfer characteristics of the bundle. These parameters include but are not limited to the outer tube diameter, the radial tube spacing between tube layers (which is fixed by the spacer thickness), tube pitch (distance between tubes in a given layer), and the tube winding angle.
  • the cross-sectional annular open flow area between the tube layers is essentially constant from the top to the bottom of the bundle.
  • the design of the heat transfer and fluid flow characteristics of the coil wound tubing bundle in warm heat exchange zone 5 therefore is a compromise among boiling heat transfer, condensing heat transfer, and single phase vapor heat transfer for the tube and shell side fluids.
  • the present invention addresses these problems by splitting the coil wound tubing bundle in warm heat exchange zone 5 into at least two smaller coil wound tubing bundles.
  • Each of these smaller bundles may be fabricated with fewer manufacturing restrictions compared with the fabrication of a single large bundle. Smaller tubing bundles use smaller mandrels, which may result in higher heat transfer area per unit bundle length.
  • Each of the split bundles can be designed to match more closely the nature of the heat exchange and fluid flow phenomena which occur in each bundle. For example, heat transfer coefficient correlations which utilize the liquid fraction as an important design parameter can be individually tailored to a selected range of liquid fractions encountered in each of the smaller bundles.
  • FIG. 2 An embodiment of the invention is illustrated in Fig. 2, in which warm heat exchange zone 5 of Fig. 1 has been replaced by lower or warm heat exchange zone 201 and middle heat exchange zone 203.
  • This drawing is for illustration only and is not meant to indicate the relative scale of any components of main heat exchanger 2.
  • Lower heat exchange zone 201 contains tube circuits 205, 207, and 209 which make up a single coil wound tubing bundle installed in heat exchanger pressure vessel 3. This coil wound tubing bundle may be fabricated by any of the known methods described above. Tubes containing the feed gas may be wound on any layer along with tubes containing high pressure refrigerants.
  • Middle heat exchange zone 203 may contain tube circuits 211, 213, and 215 which make up another coil wound tubing bundle which may be installed above the coil wound tubing bundle in lower heat exchange zone 201.
  • This coil wound tubing bundle also may be fabricated by any of the known methods described above.
  • Tubes containing the feed gas also may be wound on any layer along with tubes containing high pressure refrigerants.
  • Each of the coil wound tubing bundles in heat exchange zones 201 and 203 may be characterized by a number of fabrication or dimensional parameters which include the mandrel outer diameter, spacer thickness, number of spacers, number of tubes, tubing inner diameter, tubing outer diameter, bundle outer diameter, tube length, tube pitch, and tube winding angle. Other fabrication or dimensional parameters may be used to characterize coil wound tubing bundles as desired.
  • the two coil wound tubing bundles may differ in one or more of the parameters described above, and may be designed such that the overall operating performance of main heat exchanger 2 is optimized.
  • a coil wound tubing bundle is defined as a fabricated assembly which comprises a plurality of long aluminum tubes which are helically wound about an axial central core or mandrel.
  • Heat exchanger pressure vessel 3 typically is oriented vertically, the axes of the coil wound tubing bundles typically are vertical, and the bundles are typically coaxial with the exchanger pressure vessel.
  • the tube winding angle may be defined as the included angle formed between the tube axis and a plane perpendicular to the bundle axis (i.e., the mandrel axis).
  • the tube winding angle may be between 2 and 25 degrees.
  • Tube pitch may be defined as the center-to-center distance between adjacent wound tubes in which the center-to-center distance is measured perpendicular to the axes of the tubes. Tube pitch may vary between 1.0 and 2.0 times the tube diameter.
  • the tubing inner and outer diameters have the usual meaning.
  • the bundle outer diameter is the diameter based on the outer surface of the tubes in the last layer of the bundle.
  • the tube length in a bundle may be defined as the average length of the tubes in the bundle including the coiled portion and the tails at either end of the tubes.
  • the spacer may be a cylindrical rod or wire, or alternatively may be a rod of generally rectangular or other desired cross section.
  • the meaning of the term "spacer thickness" is the radial distance between the opposite sides of the spacer which are in contact with the tubes in two successive layers in a bundle.
  • the number of spacers means the total number of spacers in the bundle.
  • Each spacer may be oriented generally parallel to the axis of the mandrel, may be oriented helically in relation to the bundle axis, or may use any other desired orientation.
  • the tubes in tube circuits 205, 207, and 209 may extend beyond the actual wound coil in "tails" which may be aggregated or gathered together into groups so that each tail in the group can be inserted and fixed into a tube sheet.
  • tails For example, the outlet ends of a plurality of tubes in a coil wound tubing bundle may be aggregated by insertion and fixing in a tube sheet to form a group of tube outlets. Similar means may be used to aggregate the inlet ends of the plurality of tubes in the coil wound tubing bundle.
  • These tube sheets in turn may be joined, for example by means of flanges, to sections of pipes to carry fluid to and from the wound tubing bundle.
  • One or more tube sheets at the lower end of tube circuit 205 may be connected to feed gas inlet line 11, one or more tube sheets at the lower end of tube circuit 207 may be connected to refrigerant vapor inlet line 37, and one or more tube sheets at the lower end of tube circuit 209 may be connected to refrigerant liquid inlet line 29.
  • one or more tube sheets at the upper end of tube circuit 205 may be connected to feed transfer line 217
  • one or more tube sheets at the upper end of tube circuit 207 may be connected to refrigerant transfer line 219
  • one or more tube sheets at the upper end of tube circuit 209 may be connected to refrigerant transfer line 221.
  • connection of a tube sheet in one coil wound tubing bundle to a tube sheet in another wound tubing bundle provides for fluid flow communication between the respective tube circuits in the two bundles.
  • fluid flow communication means that some or all of the fluid leaving one bundle may flow through this connection into the other bundle.
  • fluid leaving one bundle may be withdrawn from heat exchanger pressure vessel 3, subjected to another process step, and returned to the other bundle at a different composition and/or flow rate.
  • direct fluid flow communication means that all of the fluid leaving one bundle flows through this connection at a constant composition and flow rate into the other bundle.
  • feed transfer line 217 may be extended through the wall of heat exchanger 3 to an external check valve (not shown) and then back through the wall of heat exchanger vessel 3 to connect with the lower end of tube circuit 211.
  • feed transfer line 217 may be extended through the wall of heat exchanger vessel 3 to withdraw the cooled feed gas for an intermediate treatment step, after which the treated feed gas is returned in a line through the wall of heat exchanger 3 to connect with the lower end of tube circuit 211.
  • line 219 may be extended through the wall of heat exchanger 3 to an external check valve (not shown) and then back through the wall of heat exchanger vessel 3 to connect with the lower end of tube circuit 213.
  • the tubes in tube circuits 211, 213, and 215 may extend beyond the actual wound bundle in "tails" which may be aggregated or gathered together into groups so that each tail in the group can be inserted and fixed into a tube sheet.
  • the tube sheets in turn may be joined, for example by means of flanges, to sections of pipes to carry fluid to and from the wound tubing bundle.
  • One or more tube sheets at the lower end of tube circuit 211 may be connected to feed transfer line 217
  • one or more tube sheets at the lower end of tube circuit 213 may be connected to refrigerant transfer line 219
  • one or more tube sheets at the lower end of tube circuit 215 may be connected to refrigerant transfer line 221.
  • one or more tube sheets at the upper end of tube circuit 211 may be connected to feed transfer line 223, one or more tube sheets at the upper end of tube circuit 213 may be connected to refrigerant transfer line 225, and one or more tube sheets at the upper end of tube circuit 215 may be connected to refrigerant transfer line 227.
  • Refrigerant transfer line 227 may be connected to throttling valve 33 and refrigerant distributor 35. Reduced pressure refrigerant from throttling valve 33 is combined with downward-flowing partially-vaporized refrigerant from heat exchange zone 9 and the combined refrigerant is distributed by refrigerant distributor 35.
  • This distributor is shown schematically and may include means for phase separation and distribution of separate vapor and liquid refrigerant streams to heat exchange zone 203.
  • coil wound tubing bundle includes the coiled section of the bundle as well as the tails at either end of the coiled section.
  • Feed transfer line 223 optionally may be connected via line 15 to throttling valve 17, which if used is connected via line 16 to tube circuit 21. If throttling valve 17 is not used, feed transfer line 223 directly connects tube circuits 211 and 21.
  • the tubes in tube circuits 21 and 41 may extend beyond the actual wound bundle in "tails" which may be aggregated or gathered together into groups so that each tail in the group can be inserted and fixed into a tube sheet.
  • the tube sheets in turn may be joined, for example by means of flanges, to pipe sections which carry fluid to and from the coil wound tubing bundle.
  • One or more tube sheets at the lower end of tube circuit 21 may be connected to feed transfer line 16, and one or more tube sheets at the lower end of tube circuit 41 may be connected to refrigerant transfer line 225.
  • one or more tube sheets at the upper end of tube circuit 21 may be connected to feed product line 23, and one or more tube sheets at the upper end of tube circuit 41 may be connected to refrigerant transfer line 42.
  • Refrigerant transfer line 42 is connected to throttling valve 43 and refrigerant distributor 45.
  • This distributor is shown schematically and may include means for phase separation and distribution of separate vapor and liquid refrigerant streams to heat exchange zone 9.
  • Liquefied product in line 23 may be reduced in pressure across throttling valve 24 to yield a final liquid product which is sent to storage and flash gas which may be used as fuel. If the liquid is at a sufficiently low temperature in line 23, it will remain as liquid after pressure reduction downstream of valve 24.
  • Redistributor 229 may utilize any type of cocurrent two-phase distributor known in the art.
  • One type of redistributor which may be used in this service for example, comprises a fan-shaped, enclosed, perforated plate which distributes the vapor and liquid refrigerant phases evenly over the top of the coil wound tubing bundle in heat exchanger zone 201.
  • Redistributor 229 is shown schematically and may include means for phase separation and distribution of separate vapor and liquid refrigerant streams to heat exchange zone 201.
  • the coil wound tubing bundle which is made up of tube circuits 205, 207, and 209 in heat exchange zone 201 may be characterized by a number of fabrication or dimensional parameters which include the mandrel outer diameter, spacer thickness, number of spacers, number of tubes, tubing inner diameter, tubing outer diameter, bundle outer diameter, tube length, tube pitch, and tube winding angle.
  • the coil wound tubing bundle which is made up of tube circuits 211, 213, and 215 in heat exchange zone 203 also may be characterized by a number of fabrication or dimensional parameters which include the mandrel outer diameter, spacer thickness, number of spacers, number of tubes, tubing inner diameter, tubing outer diameter, bundle outer diameter, tube length, tube pitch, and tube winding angle.
  • the fabrication parameters in each of these coil wound tubing bundles may be selected to optimize the heat transfer process in each of heat transfer zones 201 and 203. Some of the parameters may be essentially the same in the two coil wound tubing bundles, while the others may be different.
  • the tube outer diameter, tube pitch, and tube winding angle may be the same in both coil wound tubing bundles, while the mandrel outer diameter, spacer thickness, bundle outer diameter, and bundle length may be different in each of the two coil wound tubing bundles.
  • the proper selection of these parameters in the two coil wound tubing bundles will allow improved overall heat exchanger performance. For example, when the invention is applied to the main heat exchanger in the production of LNG, a higher production rate may be realized for a given overall main heat exchanger size. Alternatively, for a given production rate, a smaller main heat exchanger may be used.
  • each of the split bundles can be designed to match more closely the nature of the heat exchange and fluid flow phenomena which occur in each bundle.
  • Heat transfer coefficient correlations which utilize the liquid fraction as an important design parameter can be individually tailored to a selected range of liquid fraction encountered in each of the bundles in heat transfer zones 201 and 203.
  • propane precooled mixed refrigerant process utilizes one or more coil wound heat exchangers, and can utilize the present invention for improved process performance.
  • propane refrigeration is used to precool the natural gas feed, and final cooling and liquefaction of the clean, precooled gas is provided by a mixed refrigerant system.
  • Compressed mixed refrigerant in the mixed refrigerant loop may be cooled and partially condensed by propane refrigeration.
  • a first mixed refrigerant system may used to precool the natural gas feed and a second mixed refrigerant system may be used to provide final gas cooling and liquefaction.
  • an ammonia absorption refrigeration system may be used to precool the feed gas and the mixed refrigerant.
  • the present invention may be used with any natural gas liquefaction process which uses coil wound heat exchangers.
  • the split bundle concept may be used in any process which uses wound coil heat exchangers. This could include, for example, cryogenic processing of natural gas to recover light hydrocarbons as liquefied petroleum gas (LPG) and the recovery of helium from natural gas.
  • LPG liquefied petroleum gas
  • the following Examples illustrate the present invention but do not limit the invention to any of the specific details described therein.
  • a natural gas feed stream is provided in line 301 at 1,431 psia and has a composition (in vol%) of 93% methane, 4% ethane, 0.6% propane, 0.3% butane, 0.1% isobutane, 0.8% nitrogen, and trace amounts of higher hydrocarbons and water.
  • the feed stream in line 301 is initially cooled to -34°F, through a series of cascade heat exchangers 303, 305, and 307 which are cooled by a closed circuit precooling refrigeration system using propane as the refrigerant.
  • Propane is the preferred refrigerant because it provides refrigeration duty at the desired operational temperature and pressure, and also because it is available from the separated natural gas liquids for initial charging of and makeup to the propane and mixed refrigerant systems.
  • the precooled high pressure feed is introduced via line 309 into expander turbine 311 where it is reduced in pressure to 725 psia at -88°F, while producing mechanical energy.
  • the expanded feed containing vapor and liquid in line 313 is introduced into the top of the scrub column 315.
  • Fractionation column 315 operates at approximately 725 psia to separate a methane-rich fraction and a heavier hydrocarbon fraction from the feed gas.
  • the heavier hydrocarbons are removed from the bottom of column 315 via line 317 and a portion of the stream is recycled through reboiling heat exchanger 319 in order to provide reboil vapor for the column.
  • NGL natural gas liquid
  • a methane-rich gas stream is withdrawn via line 323 as an overhead from fractionation column 315 at a temperature of ⁇ 87°F and is compressed in compressor 325 which is driven by expander 311.
  • the methane-rich gas is discharged from compressor 325 in line 327 at 1037 psia and a temperature of ⁇ 47°F.
  • the methane-rich gas in line 327 is introduced into main heat exchanger 329 where it is cooled, liquefied, and subcooled to yield a LNG product as described below.
  • Main heat exchanger 329 is similar to main heat exchanger 1 of Fig. 2 earlier described.
  • the methane-rich feed stream is cooled initially in tube circuit 331, which forms a coil wound tubing bundle together with tube circuits 333 and 335 located in heat exchange zone 337. Refrigeration is provided by vaporizing multicomponent hydrocarbon refrigerant on the shell side of the exchanger as described later.
  • Cooled methane-rich feed flows from tube circuit 331 via feed transfer line 339, which optionally may be extended through the wall of heat exchanger vessel 367 to an external check valve (not shown) and then back through the wall of heat exchanger vessel 367 to connect with the lower end of tube circuit 341.
  • the cooled methane-rich feed stream is further cooled and liquefied in tube circuit 341, which forms a coil wound tubing bundle together with tube circuits 343 and 345 located in heat exchange zone 347. Refrigeration is provided by vaporizing multicomponent hydrocarbon refrigerant on the shell side of the exchanger as described below. Cooled methane-rich feed flows from tube circuit 341 via feed transfer line 349 as high pressure liquid. The cooled stream is reduced in pressure to approximately 300 psia across throttling valve 351.
  • the cooled liquid methane-rich feed stream is further cooled in tube circuit 357, which forms together with tube circuit 359 a coil wound tubing bundle located in heat exchange zone 361. Refrigeration is provided by vaporizing multicomponent hydrocarbon refrigerant on the shell side of the exchanger as described below. Cooled methane-rich liquid product flows from tube circuit 359 via product transfer line 363 at approximately -250°F. and 270 psia. The liquid is reduced to near atmospheric pressure across throttling valve 365 and the small volume of vapor formed by this pressure reduction step is separated (not shown) from the final LNG product and used as plant fuel gas. The LNG product is pumped to storage (not shown) for eventual export.
  • Vapor phase methane which develops during storage of the LNG product is removed and compressed (not shown) for inclusion as plant fuel.
  • the liquid in line 363 may be subcooled to a lower temperature such that no flash occurs when the liquid is flashed across valve 365.
  • the refrigeration for the liquefaction process described above is provided by a multicomponent refrigerant which vaporizes while flowing downward over the shell side of the three coil wound tubing bundles in heat exchange zones 337, 347, and 361 within exchanger vessel 367.
  • a multicomponent refrigerant vapor stream is withdrawn from the bottom of exchanger vessel 367 via line 369 and has a composition (in vol%) of 47% ethane, 41% methane, 8.9% propane, and 2.9% nitrogen.
  • Makeup multiple component refrigerant may be introduced into the liquefaction refrigeration loop as required via line 371.
  • the combined makeup refrigerant and recycle refrigerant in line 373 at 40 psia and -40°F is compressed in compressor 375 and cooled by cooling water in heat exchanger 377.
  • the refrigerant is further compressed in compressor 379 and cooled by cooling water in heat exchanger 381 to yield a compressed refrigerant stream in line 383 at 638 psia and 54°F.
  • This compressed, warm, multiple component refrigerant is cooled and partially condensed in evaporative heat exchangers 385, 387, and 389 by indirect heat exchange with vaporizing propane refrigerant supplied via lines 391, 393, and 395.
  • the multicomponent refrigerant exits heat exchanger 389 in line 397 at a pressure of 620 psia and a temperature of-30°F.
  • the multicomponent refrigerant is separated in separator 399, vapor is withdrawn via line 401 (about 25% of the total molar refrigerant flow) and liquid is withdrawn via line 403 (about 75% of the total molar refrigerant flow).
  • the liquid refrigerant enters via line 403 and is subcooled by flow through tube circuit 335 of the coil wound bundle in heat exchange zone 337 and tube circuit 345 of the coil wound bundle in heat exchange zone 347.
  • Subcooled refrigerant at -200°F and 517 psia in line 405 is reduced in pressure across throttling valve 407, and the reduced pressure refrigerant is combined with refrigerant from the shell side of heat exchange zone 361.
  • the combined refrigerant is distributed onto the coil wound bundle in heat exchange zone 347 through distributor 409.
  • the vapor from separator 399 is removed via line 401 and flows through tube circuits 333, 343, and 359 wherein it is cooled and liquefied.
  • Liquid refrigerant at -250°F is withdrawn via line 411, reduced in pressure across throttling valve 413, and distributed via distributor 415 over the coil wound bundle in heat exchange zone 361.
  • the downward-flowing refrigerant is redistributed by redistributor 416, after which the refrigerant continues in downward flow over the coil wound bundle in heat exchange zone 337.
  • Vaporized refrigerant is withdrawn via line 369 and is recycled to compression as described earlier.
  • Propane vapor streams in lines 417, 419, and 421 are compressed to 200 psia in multistage compressor 423.
  • the compressed propane is aftercooled and totally condensed in water-cooled heat exchangers 425 and 427, and the resulting compressed liquid propane is delivered to liquid reservoir 429.
  • the liquid refrigerant is further subcooled in water-cooled heat exchanger 431 before being passed to refrigeration duty through line 433.
  • the refrigerant is expanded through valve 435 and delivered to supply suction drum 437.
  • the refrigerant vapor from drum 437 which vapor is formed due to flash across valve 435 and evaporation in exchangers 303 and 385, flows to recompression via line 421.
  • the liquid refrigerant from drum 437 is removed in line 439 and split into lines 441 and 443.
  • the refrigerant in line 443 is expanded across valve 445 and introduced into supply suction drum 447.
  • the refrigerant in line 441 is divided to flow into lines 449 and 391, which provide propane refrigerant respectively to be vaporized in feed cooling heat exchanger 303 and multicomponent refrigerant cooling exchanger 385 earlier described. Vaporized propane from exchangers 303 and 385 is returned via line 450 to supply suction drum 437.
  • the single component refrigerant in supply suction drum 447 is separated into a vapor and a liquid phase.
  • This vapor phase formed by flash across valve 445 and evaporation in exchangers 305 and 387 is removed from supply suction drum 447 via line 419 for recompression in compressor 423.
  • the liquid phase is removed in line 451 which splits into lines 453 and 455.
  • the refrigerant in line 455 is expanded across valve 457 and introduced into supply suction drum 459.
  • the liquid refrigerant stream in line 453 is further split into lines 461 and 393, which provide propane refrigerant to be vaporized respectively in feed cooling heat exchanger 305 and multicomponent refrigerant cooling exchanger 387 earlier described. Vaporized propane from exchangers 305 and 387 is returned via line 463 to supply suction drum 447.
  • the single component refrigerant delivered to supply suction drum 459 through line 455 and valve 457 is separated into a vapor phase and a liquid phase.
  • the vapor phase along with vapor from line 469 is removed via line 417 for recompression in compressor 423.
  • the liquid phase is removed in line 465 which splits into lines 467 and 395, which provide propane refrigerant to be vaporized respectively in feed cooling heat exchanger 307 and multicomponent refrigerant cooling exchanger 389 earlier described.
  • Vaporized propane from exchangers 307 and 389 is returned via line 469 to supply suction drum 459.
  • the vapor is supplied to the compressor 423 for recompression via line 417.
  • a two-bundle main heat exchanger as illustrated in Fig. 1 is operated for the production of liquefied natural gas using a propane precooled mixed refrigerant cycle similar to that of Example 1 above.
  • the physical design parameters of the coil wound bundle in heat exchange zone 5 are given in Table 1.
  • Physical Design Parameters of Coil Wound Bundle for Example 2 (Heat Exchange Zone 5, Fig. 1) Bundle outer diameter, ft. 15 Bundle length, ft. 65 Tube length, ft 870 Tube outer diameter, in. 0.75 Mandrel outer diameter, in. 65 Spacer thickness, in. 0.23 Surface area, sq. ft. 314,000 Number of feed tubes 870 Number of vapor refrigerant tubes 350 Number of liquid refrigerant tubes 630 Total number of tubes 1,840
  • a split bundle main heat exchanger as illustrated in Fig. 2 is operated for the production of liquefied natural gas at the same production rate as Example 1 using a propane precooled mixed refrigerant cycle similar to that of Example 1.
  • the physical design parameters of the coil wound bundles in heat exchange zones 201 and 203 are given in Table 2.
  • the pressure drop characteristics of the combined coil wound bundles in heat exchanger zones 201 and 203 (Fig. 2) are approximately the same as those of heat exchange zone 3 (Fig. 1).
  • Physical Design Parameters of Coil Wound Bundles for Example 3 Heating Exchange Zones 201 and 203, Fig. 2)
  • Zone 201 Warm bundle
  • Zone 203 Middle bundle
  • Tube length ft. 570 200 Tube outer diameter, in. 0.75 0.75 Mandrel outer diameter, in. 60 50 Spacer thickness, in. 0.25 0.16 Surface area, sq. ft. 224,000 38,000 Number of feed tubes 950 350 Number of vapor refrigerant tubes 390 126 Number of liquid refrigerant tubes 660 490 Total number of tubes 2,000 970
  • the invention is illustrated in the Examples above for use in the main heat exchanger of the propane-precooled natural gas liquefaction process of Fig. 3.
  • the invention also may be applied to coil wound heat exchangers used in other natural gas liquefaction processes.
  • coil wound heat exchangers used in the well-known dual mixed refrigerant (MR) natural gas liquefaction process can be modified according to the present invention.
  • Examples of the dual MR natural gas liquefaction process are disclosed in U.S. Patents 4,504,296 and 6,119,479.
  • natural gas is cooled in a first coil wound heat exchanger by a first recirculating mixed refrigerant system and is further cooled and liquefied in a second coil wound heat exchanger by a second recirculating mixed refrigerant system.
  • the split bundle concept of the present invention may be used in either or both of the first and second coil wound heat exchangers in the dual MR process.
  • the present invention offers improved heat exchanger performance and size characteristics compared with conventional heat exchanger design.
  • Splitting a single bundle into two or more separate bundles with different design parameters offers the potential for improved production for a given exchanger surface area or, alternatively, offers the potential for using a smaller heat exchanger surface area for a given production rate.
  • Splitting a bundle also may allow the design of an exchanger with more heat exchanger surface area for a given exchanger.
  • split bundle configuration Another advantage of the split bundle configuration is that the axial expansion and contraction in each of two shorter bundles during startup and shutdown will be less than the corresponding expansion and contraction of a single bundle. This reduces mechanical stresses in the shorter bundles compared to the stresses in a single longer bundle.

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007014617A1 (de) * 2005-07-29 2007-02-08 Linde Aktiengesellschaft Gewickelter wärmetauscher mit unterschiedlichen materialien
WO2007014618A1 (de) * 2005-07-29 2007-02-08 Linde Aktiengesellschaft Gewickelter wärmetauscher mit verschiedenen rohrdurchmessern
CN102575897A (zh) * 2009-04-21 2012-07-11 林德股份公司 液化富烃馏分的方法
US20130098103A1 (en) * 2010-06-30 2013-04-25 Shell Internationale Research Maatschappij B.V. Method of treating a hydrocarbon stream comprising methane, and an apparatus therefor
EP2857782A1 (de) 2013-10-04 2015-04-08 Shell International Research Maatschappij B.V. Wärmetauscher mit gewickelter Spule und Verfahren zur Kühlung eines Prozessstroms
US20160209118A1 (en) * 2015-01-16 2016-07-21 Air Products And Chemicals, Inc. Shell-Side Fluid Distribution in Coil Wound Heat Exchangers
CN109957423A (zh) * 2017-12-22 2019-07-02 阿克森斯公司 用于加氢处理或加氢转化的绕管式热交换器
US10359228B2 (en) 2016-05-20 2019-07-23 Air Products And Chemicals, Inc. Liquefaction method and system
CN111964482A (zh) * 2020-08-21 2020-11-20 仲恺农业工程学院 一种缠绕管式蒸发器
WO2021072082A1 (en) * 2019-10-08 2021-04-15 Air Products And Chemicals, Inc. Heat exchange system and method of assembly
US20220196331A1 (en) * 2019-04-12 2022-06-23 Linde Gmbh Web design and arrangement for reducing a radial distribution fault in a wound heat exchanger
CN115388675A (zh) * 2022-08-18 2022-11-25 上海核工程研究设计院有限公司 一种可涡流检查的环绕堆内组件式螺旋缠绕管换热组件
WO2023197683A1 (zh) * 2022-10-28 2023-10-19 山东京博装备制造安装有限公司 一种丙烷脱氢工艺
CN117006867A (zh) * 2023-09-25 2023-11-07 江苏双勤新能源科技有限公司 一体式热交换器

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20230147084A1 (en) 2021-11-05 2023-05-11 Air Products And Chemicals, Inc. Mitigation of Shell-Side Liquid Maldistribution in Coil Wound Heat Exchanger Bundles

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2952985A (en) * 1954-09-20 1960-09-20 Clarence W Brandon Apparatus for fractionating and refrigerating with or by miscible fluids
FR1381767A (fr) * 1963-02-06 1964-12-14 Sulzer Ag Echangeur de chaleur disposé dans un récipient sous pression de section circulaire
GB1135871A (en) * 1965-06-29 1968-12-04 Air Prod & Chem Liquefaction of natural gas
US3516261A (en) * 1969-04-21 1970-06-23 Mc Donnell Douglas Corp Gas mixture separation by distillation with feed-column heat exchange and intermediate plural stage work expansion of the feed
GB1578505A (en) * 1977-02-02 1980-11-05 Guldager Consult Heat exchangers
US4504296A (en) 1983-07-18 1985-03-12 Air Products And Chemicals, Inc. Double mixed refrigerant liquefaction process for natural gas
US6119479A (en) 1998-12-09 2000-09-19 Air Products And Chemicals, Inc. Dual mixed refrigerant cycle for gas liquefaction
US6347532B1 (en) * 1999-10-12 2002-02-19 Air Products And Chemicals, Inc. Gas liquefaction process with partial condensation of mixed refrigerant at intermediate temperatures

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0857285B1 (de) † 1995-10-05 2003-04-23 BHP Petroleum Pty. Ltd. Verflüssigungsapparat
DE19848280C2 (de) † 1998-10-20 2003-01-30 Linde Ag Wärmetauscher zum Verflüssigen eines Kohlenwasserstoff-reichen Stromes
TW480325B (en) † 1999-12-01 2002-03-21 Shell Int Research Plant for liquefying natural gas

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2952985A (en) * 1954-09-20 1960-09-20 Clarence W Brandon Apparatus for fractionating and refrigerating with or by miscible fluids
FR1381767A (fr) * 1963-02-06 1964-12-14 Sulzer Ag Echangeur de chaleur disposé dans un récipient sous pression de section circulaire
GB1135871A (en) * 1965-06-29 1968-12-04 Air Prod & Chem Liquefaction of natural gas
US3516261A (en) * 1969-04-21 1970-06-23 Mc Donnell Douglas Corp Gas mixture separation by distillation with feed-column heat exchange and intermediate plural stage work expansion of the feed
GB1578505A (en) * 1977-02-02 1980-11-05 Guldager Consult Heat exchangers
US4504296A (en) 1983-07-18 1985-03-12 Air Products And Chemicals, Inc. Double mixed refrigerant liquefaction process for natural gas
US6119479A (en) 1998-12-09 2000-09-19 Air Products And Chemicals, Inc. Dual mixed refrigerant cycle for gas liquefaction
US6347532B1 (en) * 1999-10-12 2002-02-19 Air Products And Chemicals, Inc. Gas liquefaction process with partial condensation of mixed refrigerant at intermediate temperatures

Cited By (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8297074B2 (en) 2005-07-29 2012-10-30 Linde Aktiengesellschaft Coiled heat exchanger having different materials
WO2007014618A1 (de) * 2005-07-29 2007-02-08 Linde Aktiengesellschaft Gewickelter wärmetauscher mit verschiedenen rohrdurchmessern
CN101233378B (zh) * 2005-07-29 2010-08-04 林德股份公司 具有不同管径的缠绕式换热器
CN101233379B (zh) * 2005-07-29 2010-09-01 林德股份公司 具有不同材料的缠绕式换热器
AU2006275170B2 (en) * 2005-07-29 2010-11-25 Linde Aktiengesellschaft Coiled heat exchanger having different materials
WO2007014617A1 (de) * 2005-07-29 2007-02-08 Linde Aktiengesellschaft Gewickelter wärmetauscher mit unterschiedlichen materialien
NO346539B1 (no) * 2009-04-21 2022-09-26 Linde Ag Fremgangsmåte for kondensasjon av en hydrokarbonrik fraksjon
CN102575897B (zh) * 2009-04-21 2014-11-26 林德股份公司 液化富烃馏分的方法
RU2568697C2 (ru) * 2009-04-21 2015-11-20 Линде Акциенгезелльшафт Способ сжижения фракции, обогащенной углеводородами
CN102575897A (zh) * 2009-04-21 2012-07-11 林德股份公司 液化富烃馏分的方法
WO2010121752A3 (de) * 2009-04-21 2012-10-11 Linde Aktiengesellschaft Verfahren zum verflüssigen einer kohlenwasserstoff-reichen fraktion
US20130098103A1 (en) * 2010-06-30 2013-04-25 Shell Internationale Research Maatschappij B.V. Method of treating a hydrocarbon stream comprising methane, and an apparatus therefor
US10215485B2 (en) * 2010-06-30 2019-02-26 Shell Oil Company Method of treating a hydrocarbon stream comprising methane, and an apparatus therefor
EP2857782A1 (de) 2013-10-04 2015-04-08 Shell International Research Maatschappij B.V. Wärmetauscher mit gewickelter Spule und Verfahren zur Kühlung eines Prozessstroms
US20160209118A1 (en) * 2015-01-16 2016-07-21 Air Products And Chemicals, Inc. Shell-Side Fluid Distribution in Coil Wound Heat Exchangers
US10359228B2 (en) 2016-05-20 2019-07-23 Air Products And Chemicals, Inc. Liquefaction method and system
CN109957423A (zh) * 2017-12-22 2019-07-02 阿克森斯公司 用于加氢处理或加氢转化的绕管式热交换器
US20220196331A1 (en) * 2019-04-12 2022-06-23 Linde Gmbh Web design and arrangement for reducing a radial distribution fault in a wound heat exchanger
WO2021072082A1 (en) * 2019-10-08 2021-04-15 Air Products And Chemicals, Inc. Heat exchange system and method of assembly
US11187467B2 (en) 2019-10-08 2021-11-30 Air Products And Chemicals, Inc. Heat exchange system and method of assembly
US11391512B2 (en) 2019-10-08 2022-07-19 Air Products And Chemicals, Inc. Heat exchange system and method of assembly
EP4166877A1 (de) * 2019-10-08 2023-04-19 Air Products and Chemicals, Inc. Wärmeaustauschsystem und montageverfahren
US11859903B2 (en) 2019-10-08 2024-01-02 Air Products And Chemicals, Inc. Heat exchange system and method of assembly
CN111964482A (zh) * 2020-08-21 2020-11-20 仲恺农业工程学院 一种缠绕管式蒸发器
CN115388675A (zh) * 2022-08-18 2022-11-25 上海核工程研究设计院有限公司 一种可涡流检查的环绕堆内组件式螺旋缠绕管换热组件
CN115388675B (zh) * 2022-08-18 2024-06-07 上海核工程研究设计院股份有限公司 一种可涡流检查的环绕堆内组件式螺旋缠绕管换热组件
WO2023197683A1 (zh) * 2022-10-28 2023-10-19 山东京博装备制造安装有限公司 一种丙烷脱氢工艺
CN117006867A (zh) * 2023-09-25 2023-11-07 江苏双勤新能源科技有限公司 一体式热交换器
CN117006867B (zh) * 2023-09-25 2024-01-26 江苏双勤新能源科技有限公司 一体式热交换器

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EP1367350B2 (de) 2012-10-24
EP1367350B1 (de) 2005-11-30
ATE311580T1 (de) 2005-12-15
ES2254555T5 (es) 2013-02-15
ES2254555T3 (es) 2006-06-16
DE60207689D1 (de) 2006-01-05
DE60207689T2 (de) 2006-06-14
DE60207689T3 (de) 2013-01-24

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