EP1366278A1 - METHOD FOR catalyst temperature control - Google Patents
METHOD FOR catalyst temperature controlInfo
- Publication number
- EP1366278A1 EP1366278A1 EP02716715A EP02716715A EP1366278A1 EP 1366278 A1 EP1366278 A1 EP 1366278A1 EP 02716715 A EP02716715 A EP 02716715A EP 02716715 A EP02716715 A EP 02716715A EP 1366278 A1 EP1366278 A1 EP 1366278A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- overrun
- temperature
- exhaust gas
- internal combustion
- combustion engine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01N—GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
- F01N3/00—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
- F01N3/08—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
- F01N3/0807—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents
- F01N3/0828—Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by using absorbents or adsorbents characterised by the absorbed or adsorbed substances
- F01N3/0842—Nitrogen oxides
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D41/00—Electrical control of supply of combustible mixture or its constituents
- F02D41/02—Circuit arrangements for generating control signals
- F02D41/021—Introducing corrections for particular conditions exterior to the engine
- F02D41/0235—Introducing corrections for particular conditions exterior to the engine in relation with the state of the exhaust gas treating apparatus
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D41/00—Electrical control of supply of combustible mixture or its constituents
- F02D41/02—Circuit arrangements for generating control signals
- F02D41/04—Introducing corrections for particular operating conditions
- F02D41/12—Introducing corrections for particular operating conditions for deceleration
- F02D41/123—Introducing corrections for particular operating conditions for deceleration the fuel injection being cut-off
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D2200/00—Input parameters for engine control
- F02D2200/02—Input parameters for engine control the parameters being related to the engine
- F02D2200/08—Exhaust gas treatment apparatus parameters
- F02D2200/0802—Temperature of the exhaust gas treatment apparatus
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D2200/00—Input parameters for engine control
- F02D2200/02—Input parameters for engine control the parameters being related to the engine
- F02D2200/10—Parameters related to the engine output, e.g. engine torque or engine speed
- F02D2200/1012—Engine speed gradient
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02D—CONTROLLING COMBUSTION ENGINES
- F02D2200/00—Input parameters for engine control
- F02D2200/50—Input parameters for engine control said parameters being related to the vehicle or its components
- F02D2200/501—Vehicle speed
Definitions
- the invention relates to a method for controlling a temperature of a catalyst system with the features mentioned in the preambles of independent claims 1 and 2.
- the NO x catalytic converter system comprises at least one NO x storage catalytic converter and usually one or more upstream catalytic converters.
- the internal combustion engine is operated discontinuously in lean and rich lambda intervals, with nitrogen oxides (NO x ) of the exhaust gas being stored in the NO x storage catalytic converter with ⁇ > 1 during the lean operating intervals and released and reduced in the rich operating intervals with ⁇ ⁇ 1 ( NO x regeneration).
- a conversion of other pollutant components such as carbon monoxide (CO) and unburned hydrocarbons (HC) takes place in a known manner on 3-way catalytic components of the pre-catalyst and / or the NO x storage catalytic converter.
- CO carbon monoxide
- HC unburned hydrocarbons
- NO x catalyst systems are relatively temperature sensitive. In this way, irreversible damage to the catalyst system can occur even at exhaust gas temperatures upstream of the NO x storage catalytic converter above 800 ° C., so that the catalyst activity decreases significantly over the life of the vehicle. This concerns both the NO x storage and regeneration during the lean and rich operating intervals as well as the HC, CO and NO x conversion behavior with stoichiometric exposure.
- exhaust gas cooling measures for lowering the exhaust gas temperature are known.
- Another known measure for reducing the exhaust gas temperature consists in enriching the air-fuel mixture to ⁇ ⁇ 1.
- a particular problem with regard to the temperature load of the NO x catalytic converter system is the unavoidable overrun phases during normal driving, which can occur, for example, when the vehicle is decelerating or on gradients, one of which Driver predetermined driving torque is less than an instantaneous thrust torque of the vehicle.
- the fuel supply is usually interrupted and the internal combustion engine is not operated with a fire (overrun cutoff). This means that high oxygen concentrations reach the exhaust gas and the catalyst system, which still contains high HC masses at the beginning of the overrun phase, especially after high or full load operation.
- the object of the present invention is to provide a method for controlling a temperature of a catalyst system which largely avoids damaging temperature peaks in overrun phases, in particular after high or full load operation of the internal combustion engine.
- the procedure should go beyond that keep fuel consumption as low as possible, do not impair driving comfort and driving safety and can be easily integrated into an engine control concept.
- the air-fuel ratio is predetermined during the fired overrun phase as a function of a measured or calculated temperature of the exhaust gas and / or the NO x catalyst system. If the temperature of at least one component of the catalyst system is already relatively close to a catalyst-specific critical temperature threshold at the beginning of the overrun phase, a relatively low lambda value, i.e. a strong mixture enrichment, is specified for the overrun phase in order to lower the temperature as much as possible.
- the exhaust gas and / or the catalyst system is at a relatively low temperature, a lambda value close to 1 can be specified. It can further be provided that the fuel cut-off is not suppressed, ie the fuel cut-off is released if the temperature of the exhaust gas and / or the NO x catalyst system does not exceed a predeterminable low temperature threshold. It will usually be useful, depending on a specific one Catalyst quality, in particular of a catalyst coating and / or a catalyst carrier, to specify different temperature thresholds for the preliminary and main or NO x storage catalyst.
- vehicle propulsion is understood to mean an operating phase in which the internal combustion engine does positive work, ie is not in an overrun phase.
- the specification of a maximum permissible temperature of the exhaust gas upstream of the precatalyst in a vehicle propulsion phase of the internal combustion engine is provided from 920 to 1040 ° C., preferably from 950 to 1000 ° C.
- a maximum permissible temperature of the exhaust gas upstream of the NO x storage catalytic converter in vehicle propulsion can be set from 830 to 920 ° C., in particular from 850 to 880 ° C.
- the latter embodiment of the method can particularly advantageously be further developed in such a way that even during the fired overrun phase, the internal combustion engine is acted upon by an air-fuel ratio which is set as a function of the predetermined maximum permissible temperature of the exhaust gas and / or the NO x catalyst system.
- the relatively low lambda value resulting from this measure during the overrun phase of usually 0J to 0.95, in particular 0.8 to 0.9, leads to a slight reduction in the consumption advantage achieved compared to the latter embodiment of the method, but still promotes it lower residual oxygen levels in the thrust extend the life of the Catalyst system. Temperature peaks are almost completely eliminated due to the lambda value that is almost the same under load and in thrust.
- a problem can arise from the fact that the firing of the overrun phases always generates a certain useful torque, as a result of which the speed reduction expected by the driver in the overrun phase is less than expected.
- This problem can be alleviated by a further development of the method, in that a useful torque generated in the overrun phase is at least partially compensated for by shifting an ignition point in the "late" direction and thus reducing the engine efficiency.
- this measure is only useful to a limited extent to avoid the useful torque.
- the useful torque is particularly undesirable on downhill gradients, since active driving safety can be jeopardized here by extended deceleration distances. Furthermore, the damaging effect of the higher exhaust gas temperature is particularly pronounced here, since a downhill section is often preceded by a full-gas gradient section at which maximum engine speeds and exhaust gas temperatures are reached.
- the suppression of the overrun cutoff and / or the air-fuel ratio during the overrun phase and / or a maximum permissible temperature specification for the exhaust gas and / or the catalyst system during the overrun phase as a function of a deviation an actual vehicle speed and / or an actual vehicle acceleration is controlled by a target vehicle speed and / or target vehicle acceleration to be expected in the plane in accordance with a current engine torque.
- a slope or slope detection is first carried out, for example, by comparing the actual instantaneous actual vehicle speed with a target vehicle speed, which is determined as a function of the torque given by the internal combustion engine for driving in the plane.
- the actual vehicle speed or acceleration required for the gradient detection can be determined in a known manner, for example, via the engine speed and an engaged gear and / or on the basis of a wheel speed measured by wheel speed sensors and a dynamic wheel radius. Different methods for speed detection are also conceivable.
- the theoretical target vehicle speed or acceleration in the plane is preferably determined as a function of a torque output by the internal combustion engine and determined by the engine control.
- other engine control variables which approximately describe the engine torque can also be used as a replacement variable, for example an accelerator pedal position, the amount of fuel injected, an air mass meter signal and an exhaust gas lambda signal.
- the engine torque or the substitute variable is then correlated with a change in speed during vehicle operation in the plane with the aid of a stored map.
- Figure 1 schematically shows a structure of an internal combustion engine with a downstream exhaust tract
- FIG. 3 temporal courses of the quantities according to FIG. 2 according to a first embodiment of the present invention
- FIG. 4 temporal courses of the quantities according to FIG. 2 according to a second embodiment of the present invention
- FIG. 5 temporal courses of the quantities according to FIG. 2 according to a third embodiment of the present invention.
- FIG. 7 gradient-dependent courses of the sizes according to FIG. 6 according to a fifth embodiment of the present invention.
- FIG. 1 shows a schematic representation of an internal combustion engine 10 with an exhaust gas duct 12 connected downstream of it.
- the exhaust gas duct 12 houses a small-volume pre-catalytic converter 14, typically a 3-way catalytic converter, and a large-volume NO connected downstream of it x storage catalytic converter 16.
- the NO x storage catalytic converter 16 is subjected to discontinuous lean and rich exhaust gas atmospheres, nitrogen oxides NO x being stored in the lean operating phases and NO x regeneration and conversion in the rich operating phases.
- the lean-rich cycles and the air-fuel ratio lambda are typically regulated with the aid of a lambda probe 18 arranged downstream of the internal combustion engine 10 and a further gas sensor 20 which is installed downstream of the NO x storage catalytic converter 16.
- the gas sensor 20 can also be a lambda sensor or preferably a NO x sensor.
- a temperature sensor 22 determines an exhaust gas temperature upstream of the NO x storage catalytic converter 16.
- FIG. 2 illustrates the temperature-damaging catalytic converter damage during the course of various parameters during a fuel cut-off approved according to the prior art.
- the graph 100 shows the course of a vehicle speed v.
- the speed v is initially at a constant high level, then decreases continuously in a deceleration phase, for example because the driver withdraws a gas request in order to finally assume a constantly low level.
- the vehicle is in an overrun phase ⁇ s , in which the requested driving torque is less than an instantaneous overrun torque generated by the vehicle.
- the time course of the air-fuel ratio ⁇ is shown with graph 102.
- During the initial high-load operation there is a relatively strong mixture enrichment with ⁇ ⁇ 1.
- the overrun cutoff in overrun phases is suppressed according to the invention under certain conditions by operating the internal combustion engine 10 during the overrun phase ⁇ s .
- This principle is shown in its simplest embodiment in FIG. 3 on the basis of the same profile of the vehicle speed v as in FIG. 2 (graph 100).
- the internal combustion engine 10 is accordingly operated with a stoichiometric air-fuel ratio or a small excess of fuel, so that the oxygen present is largely consumed during the combustion process.
- FIG. 3 also shows the temperature profile 104 when the fuel cut-off according to FIG. 2.
- the lack of pronounced temperature peaks in Figure 3 allows a significant extension of the life of the catalyst system and the guarantee of sufficient catalytic activity over the life.
- the firing of the propulsion phase caused ⁇ s a certain fuel consumption with respect to the admission of the fuel cut-off according to FIG 2.
- the suppression of the overrun cut-off is only permitted if the temperature at the beginning of the overrun phase ⁇ s is already relatively high, in particular 700 ° C., preferably 750 ° C. Furthermore, the lambda specification during the overrun phase ⁇ s can be set in proportion to the present temperature.
- FIG. 4 A further development of the principle shown in FIG. 3 is shown in FIG. 4, again with an identical speed profile 100.
- a maximum permissible temperature specification for the exhaust gas and / or the catalyst system is increased by 30 to during high-load operation (non-overrun operation) 150 K, especially around 50 to 100 K, compared to the previous examples.
- this corresponds to an exhaust gas temperature upstream of the pre-catalytic converter 14 of 920 to 1040 ° C., in particular 950 to 1000 ° C.
- FIG. 5 shows the lambda and temperature profiles (102 '"and 104'") if instead of a fixed lambda specification also during the overrun phase ⁇ s, a function of the maximum temperature specification for the exhaust gas and / or the lambda value setting the NO x catalyst system 14, 16 is permitted.
- This measure usually leads to lambda values between 0J and 0.95 during the overrun phase ⁇ s , in particular from 0.8 to 0.9.
- This greater mixture enrichment resulting in the overrun phase ⁇ s leads to a partial loss of fuel savings according to the exemplary embodiment shown in FIG. 4, but because of the lambda value which is almost the same under load and in the overrun, it at least almost completely eliminates temperature peaks in favor of the catalyst service life.
- Two further exemplary embodiments take into account the problem of a useful torque generated by the fired thrust on downhill sections.
- it is provided to carry out a slope detection by determining a deviation ⁇ v of a calculated target driving speed and / or acceleration in the plane (v So n) from a current actual driving speed (V
- graph 106 shows the lambda curve in a thrust phase ⁇ s , which is regulated as a function of the determined speed deviation ⁇ v.
- the overrun fuel cutoff is suppressed by operating the internal combustion engine 10 with a lambda ⁇ 1 being fired.
- the air-fuel ratio ⁇ is ignited at a constant ignition timing at a crankshaft angle KWW before top dead center OT (graph 110). If the gradient is greater than ⁇ v k , the overrun cutoff is permitted, resulting in an almost infinite lambda value in the overrun. In this way, an extension of a deceleration path caused by the useful torque and the resulting dangers or irritations of the driver are avoided.
- the approval of the overrun fuel cutoff and / or the specification of the critical gradient ⁇ v k can be controlled as a function of the current exhaust gas or catalyst temperature.
- Graph 108 shows the slope-dependent lambda curve in the fired vehicle propulsion, i.e. when there is no thrust situation.
- the maximum permissible exhaust gas and / or catalyst temperature is reduced above the critical gradient ⁇ v k , which results in a lambda reduction in accordance with the required cooling.
- the temperature or lambda reduction in vehicle propulsion has the advantage that an overrun cut-off can easily be carried out on a slope above ⁇ v k , when a thrust phase ⁇ s begins without the temperature peak resulting from the exposure to oxygen reaching the critical temperature range.
- the ignition timing is shifted according to graph 110 up to a crankshaft angle KWW after top dead center OT in order to reduce combustion efficiency and thus the resulting useful torque.
- the overrun cutoff is permitted if the predetermined critical gradient ⁇ v k is exceeded.
- the vehicle is under engine load (non-overrun)
- the maximum permissible exhaust gas and / or catalytic converter temperature is continuously reduced as the gradient increases, whereupon a decreasing lambda curve occurs according to graph 108 '.
- the processes shown in FIGS. 6 and 7 lead to an improved catalyst life without significant consumption influences. All processes can also be tailored to the condition of the catalytic converter, in particular the catalytic converter temperature or existing damage.
- the method shown in FIG. 7 offers the best coordination with regard to driving behavior.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Exhaust Gas After Treatment (AREA)
- Electrical Control Of Air Or Fuel Supplied To Internal-Combustion Engine (AREA)
- Combined Controls Of Internal Combustion Engines (AREA)
- Electrical Control Of Ignition Timing (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10110500 | 2001-02-28 | ||
DE10110500A DE10110500A1 (en) | 2001-02-28 | 2001-02-28 | Process for temperature control of a catalyst system |
PCT/EP2002/001075 WO2002077430A1 (en) | 2001-02-28 | 2002-02-01 | Method for controlling a working mode of an internal combustion engine |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1366278A1 true EP1366278A1 (en) | 2003-12-03 |
EP1366278B1 EP1366278B1 (en) | 2004-09-08 |
Family
ID=7676336
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02716715A Expired - Lifetime EP1366278B1 (en) | 2001-02-28 | 2002-02-01 | METHOD FOR catalyst temperature control |
Country Status (6)
Country | Link |
---|---|
US (1) | US7051516B2 (en) |
EP (1) | EP1366278B1 (en) |
JP (1) | JP4467886B2 (en) |
CN (1) | CN1308583C (en) |
DE (2) | DE10110500A1 (en) |
WO (1) | WO2002077430A1 (en) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10154974B4 (en) | 2001-11-06 | 2019-01-24 | Volkswagen Ag | Method and device for switching an internal combustion engine from a fired operation to an unfired overrun operation |
DE10323249A1 (en) * | 2003-05-22 | 2005-01-05 | Volkswagen Ag | Method for operating an internal combustion engine |
DE10350778A1 (en) * | 2003-10-30 | 2005-06-02 | Robert Bosch Gmbh | Method for operating a drive unit |
US7181905B2 (en) * | 2003-12-02 | 2007-02-27 | Ford Global Technologies, Llc | Lean-burn engine exhaust air-fuel and temperature management strategy for improved catalyst durability |
US7263433B2 (en) | 2003-12-02 | 2007-08-28 | Ford Global Technologies, Llc | Computer device to calculate emission control device functionality |
DE102004006882B4 (en) * | 2004-02-12 | 2007-10-04 | Audi Ag | Method for controlling the mixture enrichment of a lean-running internal combustion engine of a vehicle, in particular of a motor vehicle |
DE102004019830B4 (en) * | 2004-04-23 | 2008-03-27 | Audi Ag | Method for operating an internal combustion engine of a vehicle, in particular of a motor vehicle, and internal combustion engine |
DE102006003488A1 (en) * | 2006-01-25 | 2007-07-26 | Robert Bosch Gmbh | Operating method for controller for use in internal combustion engine, involves supplying air-fuel mixture with air ratio, production of exhaust gas with exhaust gas temperature and adjustment of ignition angle based on torque requirement |
DE102006037752B3 (en) * | 2006-08-11 | 2007-04-19 | Siemens Ag | Method for operation of internal-combustion engine involves several cylinders and injection valve are assigned to cylinders, to measure fuel and exhaust manifold, in which exhaust probe is arranged |
JP5023915B2 (en) * | 2006-10-27 | 2012-09-12 | 日産自動車株式会社 | Exhaust purification catalyst regeneration control device for exhaust purification system of internal combustion engine and catalyst regeneration method thereof |
DE102007037541A1 (en) * | 2007-08-09 | 2009-02-12 | Zf Friedrichshafen Ag | Method for operating drive chain of motor vehicle, involves detecting metrologically or analytically temperature of catalyzer of drive chain during throttle cutoff by temperature model |
AT513359B1 (en) * | 2012-08-17 | 2014-07-15 | Ge Jenbacher Gmbh & Co Og | Method for operating an internal combustion engine |
JP6057164B2 (en) * | 2012-12-28 | 2017-01-11 | スズキ株式会社 | Fuel injection control device for internal combustion engine |
AT521758B1 (en) * | 2018-10-05 | 2023-07-15 | Avl List Gmbh | Method and arrangement of a gasoline engine with an improved exhaust aftertreatment by means of an overrun fuel cut-off strategy |
WO2021163863A1 (en) * | 2020-02-18 | 2021-08-26 | 潍柴动力股份有限公司 | Engine control method and device |
CN111608774B (en) * | 2020-04-09 | 2021-12-17 | 东风汽车集团有限公司 | Method for accelerating ignition process of catalytic converter by utilizing ignition efficiency of engine |
DE102021205508A1 (en) | 2021-05-31 | 2022-12-01 | Robert Bosch Gesellschaft mit beschränkter Haftung | Method, computing unit and computer program for operating an internal combustion engine |
CN115523035B (en) * | 2022-09-19 | 2024-01-30 | 东风柳州汽车有限公司 | Vehicle control method, device, equipment and storage medium |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4329916A1 (en) * | 1993-09-04 | 1995-03-09 | Bosch Gmbh Robert | Control method, in a motor vehicle with an automatic gear system |
US5570575A (en) * | 1993-10-06 | 1996-11-05 | Nissan Motor Co., Ltd. | Fuel delivery control apparatus for use with internal combustion engine |
JP3622279B2 (en) * | 1995-07-31 | 2005-02-23 | 日産自動車株式会社 | Fuel supply control device for internal combustion engine |
JPH10103098A (en) * | 1996-10-01 | 1998-04-21 | Unisia Jecs Corp | Vehicular controller |
US6059057A (en) * | 1997-06-02 | 2000-05-09 | Toyota Jidosha Kabushiki Kaisha | Catalyst temperature control apparatus for hybrid vehicle |
DE19729676C5 (en) * | 1997-07-11 | 2004-04-15 | Ford Global Technologies, LLC (n.d.Ges.d. Staates Delaware), Dearborn | Method for operating an internal combustion engine for protecting an exhaust gas treatment device |
JP3591283B2 (en) * | 1998-01-29 | 2004-11-17 | 日産自動車株式会社 | Engine exhaust purification device |
US6240721B1 (en) * | 1998-09-17 | 2001-06-05 | Toyota Jidosha Kabushiki Kaisha | Internal combustion engine and method for controlling an internal combustion engine |
JP3374773B2 (en) * | 1998-12-28 | 2003-02-10 | トヨタ自動車株式会社 | Catalyst deterioration detection device for internal combustion engine |
JP2000303828A (en) * | 1999-04-20 | 2000-10-31 | Toyota Motor Corp | Exhaust emission control device of hybrid car |
JP4389372B2 (en) * | 2000-09-29 | 2009-12-24 | マツダ株式会社 | Engine fuel control device |
-
2001
- 2001-02-28 DE DE10110500A patent/DE10110500A1/en not_active Withdrawn
-
2002
- 2002-02-01 JP JP2002575454A patent/JP4467886B2/en not_active Expired - Lifetime
- 2002-02-01 DE DE50200961T patent/DE50200961D1/en not_active Expired - Lifetime
- 2002-02-01 WO PCT/EP2002/001075 patent/WO2002077430A1/en active IP Right Grant
- 2002-02-01 EP EP02716715A patent/EP1366278B1/en not_active Expired - Lifetime
- 2002-02-01 CN CNB028044584A patent/CN1308583C/en not_active Expired - Lifetime
- 2002-02-01 US US10/467,092 patent/US7051516B2/en not_active Expired - Lifetime
Non-Patent Citations (1)
Title |
---|
See references of WO02077430A1 * |
Also Published As
Publication number | Publication date |
---|---|
CN1489669A (en) | 2004-04-14 |
CN1308583C (en) | 2007-04-04 |
DE10110500A1 (en) | 2002-10-02 |
US7051516B2 (en) | 2006-05-30 |
WO2002077430A1 (en) | 2002-10-03 |
US20040074228A1 (en) | 2004-04-22 |
EP1366278B1 (en) | 2004-09-08 |
DE50200961D1 (en) | 2004-10-14 |
JP4467886B2 (en) | 2010-05-26 |
JP2004523688A (en) | 2004-08-05 |
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