EP1346081A1 - Passivation method - Google Patents

Passivation method

Info

Publication number
EP1346081A1
EP1346081A1 EP01993716A EP01993716A EP1346081A1 EP 1346081 A1 EP1346081 A1 EP 1346081A1 EP 01993716 A EP01993716 A EP 01993716A EP 01993716 A EP01993716 A EP 01993716A EP 1346081 A1 EP1346081 A1 EP 1346081A1
Authority
EP
European Patent Office
Prior art keywords
passivation
chromium
layer
concentration
passivated layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP01993716A
Other languages
German (de)
French (fr)
Inventor
Ernst Walter Hillebrand
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hillebrand Walter GmbH and Co KG
Original Assignee
Hillebrand Walter GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hillebrand Walter GmbH and Co KG filed Critical Hillebrand Walter GmbH and Co KG
Publication of EP1346081A1 publication Critical patent/EP1346081A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/48—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 not containing phosphates, hexavalent chromium compounds, fluorides or complex fluorides, molybdates, tungstates, vanadates or oxalates
    • C23C22/53—Treatment of zinc or alloys based thereon
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/46—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing oxalates
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
    • C23C2222/10—Use of solutions containing trivalent chromium but free of hexavalent chromium

Definitions

  • the invention relates to a method for passivating zinc and zinc alloy layers and cadmium and cadmium alloy layers and claims the priority of German patent application 100 55 215.3, to which reference is made in terms of content.
  • a system with good corrosion protection properties is a galvanically applied zinc-nickel alloy, which is then chromated and can also be treated with an organic or inorganic layer. Good corrosion resistance is achieved using chromium (VI) to passivate the zinc / nickel layer.
  • VI chromium
  • the object of the present invention is to provide a method for passivation, which allows further improved corrosion protection properties, and a corresponding coating system.
  • the invention is based on the knowledge that the abandonment of the desire for a compact conversion layer, and thus the striving for a porous conversion layer, leads to improved end products if the porosity is used for the connection with at least one further layer.
  • the invention can be implemented by passivation with a chromium (III) and a less stable complexing agent - preferably a di- or tricarboxylic acid - such as oxalic acid-containing passivation solution using cobalt.
  • cobalt concentration of more than 30 g / l, preferably from 70 g / l to 100 g / l, in particular, about 90 g / l (concentrate - 12%), surprising corrosion protection values from 240 h to the first attack according to DIN 50961 im Salt spray cabinet according to DIN 50021 SS reached in production.
  • the process is preferably carried out at a temperature of up to 55 ° C. and a pH of 0.5 to 5.5.
  • the passivation is preferably carried out at pH 4. Particularly good results can be achieved with a sulfate-free solution. This is based on the knowledge that the use of sulfate leads to a disruption of the catalytic reaction and hinders the build-up of a corrosion-protecting chromium layer.
  • the passivated layer is aftertreated with an organic or inorganic coating that penetrates into the porous conversion layer.
  • An Aquares TM layer from Enthone-OMI GmbH, Neuss is preferably applied to the passivation layer. Particularly good corrosion protection can be achieved with a double Aquares layer. Surprisingly, the Aquares layer in the SEM is no longer detectable in some variants of the invention.
  • the corrosion protection properties and the chemical resistance can be further improved by a top coat containing a dry lubricant. According to the invention, this also forms a special bond with the porous conversion layer. This allows the desired friction and flow values to be achieved at the same time.
  • the combination of the dry lubricant Molykote®D-7100 from Dow Corning with the passivated zinc-nickel alloy according to the invention has surprising properties. Compared to known coating systems, this system is particularly resistant to chemicals and is insensitive to rim cleaners. It is therefore particularly suitable for wheel bolts. At the same time, the combination according to the invention is surprisingly insensitive to temperature.
  • This dry lubricant layer is preferably applied to a double Aquares layer.

Abstract

The invention relates to a method for passivating zinc, cadmium, or the alloys thereof, especially zinc-nickel alloys, with a chrome (VI)-free solution containing a weak complexing agent, preferably dicarboxylic or tricarboxylic acids, preferably a chrome (III)-oxalate complex and Co<2+>, the Co<2+> concentration being higher than 30g/l.

Description

"Passivierunαsverfahren" "Passivierunαsverfahren"
Die Erfindung betrifft ein Verfahren zum Passivieren von Zink- und Zinklegierungsschichten sowie Cadmium- und Cadmiumlegierungsschichten und nimmt die Priorität der deutschen Patentanmeldung 100 55 215.3 in Anspruch, auf die inhaltlich Bezug genommen wird.The invention relates to a method for passivating zinc and zinc alloy layers and cadmium and cadmium alloy layers and claims the priority of German patent application 100 55 215.3, to which reference is made in terms of content.
Es ist bekannt, metallische Oberflächen zur Erhöhung der Korrosionsbeständigkeit galvanisch mit Metallen oder Metallegierungen zu beschichten. Darüber hinaus ist es bekannt, die Korrosionsschutzwirkung der Beschichtung wiederum durch deren Modifikation sowie durch weitere Beschich- tungssysteme zu erhöhen. Ein System mit guten Korrosionsschutzeigenschaften stellt eine galvanisch aufgebrachte Zink-Nickellegierung dar, die anschließend chromatiert wird und des weiteren mit einer organischen oder anorganischen Schicht behandelt werden kann. Eine gute Korrosionsbeständigkeit wird dabei unter Verwendung von Chrom(VI) zur Passivierung der Zink/Nickel-Schicht erreicht.It is known to galvanically coat metallic surfaces with metals or metal alloys to increase the corrosion resistance. In addition, it is known to increase the corrosion protection effect of the coating in turn by modifying it and by means of further coating systems. A system with good corrosion protection properties is a galvanically applied zinc-nickel alloy, which is then chromated and can also be treated with an organic or inorganic layer. Good corrosion resistance is achieved using chromium (VI) to passivate the zinc / nickel layer.
Der guten Korrosionsbeständigkeit steht die Giftigkeit von Chrom(VI ^Verbindungen gegenüber. Dementsprechend wird seit längerem versucht, Systeme zu etablieren, die unter Vermeidung von Chrom(VI) eine ausreichend gute Korrosionsbeständigkeit gewährleisten. Dazu ist es bekannt, Chrom(lll)-haltige Passivierungslösungen einzusetzen, wie beispielsweise in der US 4 171 231 beschrieben, die aber aufgrund der des weiteren in der Lösung vorhandenen Oxidationsmittel im Ergebnis nicht zu Chrom(VI)-freien Passivierungsschichten führen, da Chrom(lll) im Pro- zess oxidiert wird.The good corrosion resistance is offset by the toxicity of chromium (VI ^ compounds. Accordingly, attempts have been made for a long time to establish systems which, with the avoidance of chromium (VI), ensure a sufficiently good corrosion resistance. For this purpose, it is known to use passivation solutions containing chromium (III), as described, for example, in US Pat. No. 4,171,231, which, however, do not result in chromium (VI) -free passivation layers due to the further oxidizing agents present in the solution, since chromium (III) is oxidized in the process.
Aus der DE 41 35 524 C 2, die zum Gegenstand der vorliegenden Beschreibung gemacht wird und auf die voll inhaltlich Bezug genommen wird, ist ein Passivierungsverfahren bekannt, bei dem mit einer Chrom(lll)-enthaltenden Passivierungslösung mit einer Oxalat-Komplexierung verbesserte Korrosionsschutzwerte erreicht werden (Tabelle II; Tabelle III). Verschiedene Beispiele von Chrom(III)-Passivierungsverbindungen sind in Tabelle IV der genannten Druckschrift wiedergegeben. Die gute Korrosionsschutzwirkung des in dieser Druckschrift beschriebenen Passivierungsverfahrens ist darauf zu- rückzuführen, daß die Verwendung von Oxalat zur Komplexierung den Einbau von Chrom in die Passivierungsschicht gegenüber den bekannten Komplexbildnern begünstigt.From DE 41 35 524 C 2, which is made the subject of the present description and to which full reference is made, a passivation method is known in which with a chromium (III) -containing passivation solution with oxalate complexation, improved corrosion protection values are achieved be (Table II; Table III). Various examples of chromium (III) passivation compounds are given in Table IV of the cited document. The good corrosion protection effect of the passivation process described in this publication is due to the fact that the use of oxalate for complexation favors the incorporation of chromium into the passivation layer compared to the known complexing agents.
Mit einem solchen Passivierungsverfahren lassen sich bereits gute Korrosi- onsschutzwerte erreichen. Des weiteren ist es bekannt, die Korrosionsschutzwirkung Chrom(lll)-basierender Passivierungsverfahren durch die Verwendung von Cobalt zu erhöhen.With such a passivation process, good corrosion protection values can already be achieved. Furthermore, it is known to increase the corrosion protection effect of chromium (III) -based passivation processes by using cobalt.
Die korrosionsschutzerhöhende Wirkung der Verwendung von Cobalt ist in der WO 97/40208 beschrieben, auf die hiermit Bezug genommen wird.The anti-corrosion effect of the use of cobalt is described in WO 97/40208, to which reference is hereby made.
Wie sich auch aus dieser Druckschrift ergibt, besteht in der Fachwelt das Bestreben, eine möglichst kompakte Konversionsschicht zu erzeugen, um die gewünschte Korrosions- und Chemikalienbeständigkeit der Beschichtung zu erreichen. Aufgabe der vorliegenden Erfindung ist es, ein Verfahren zur Passivierung bereitzustellen, die weiter verbesserte Korrosionsschutzeigenschaften erlaubt sowie ein entsprechendes Beschichtungssystem.As can also be seen from this document, there is a desire in the professional world to produce the most compact conversion layer possible in order to achieve the desired corrosion and chemical resistance of the coating. The object of the present invention is to provide a method for passivation, which allows further improved corrosion protection properties, and a corresponding coating system.
Die Aufgabe wird gelöst durch ein Verfahren und eine Passivierungslösung gemäß den unabhängigen Ansprüchen. Vorteilhafte Weiterbildungen sind Gegenstand der Unteransprüche.The object is achieved by a method and a passivation solution according to the independent claims. Advantageous further developments are the subject of the subclaims.
Der Erfindung liegt nun die Erkenntnis zugrunde, daß die Abkehr von dem Bestreben nach einer kompakten Konversionsschicht, und damit das Anstreben einer porösen Konversionsschicht zu verbesserten Endprodukten führt, wenn die Porosität für die Verbindung mit mindestens einer weiteren Schicht genutzt wird.The invention is based on the knowledge that the abandonment of the desire for a compact conversion layer, and thus the striving for a porous conversion layer, leads to improved end products if the porosity is used for the connection with at least one further layer.
Die Erfindung kann durch Passivierung mit einer Chrom(lll) und einen weniger stabilen Komplexbildner - vorzugsweise eine Di- oder Tricarbonsäure - wie Oxalsäure enthaltenden Passivierungslösung unter Verwendung von Cobalt verwirklicht werden.The invention can be implemented by passivation with a chromium (III) and a less stable complexing agent - preferably a di- or tricarboxylic acid - such as oxalic acid-containing passivation solution using cobalt.
Durch die Verwendung einer Cobaltkonzentration von über 30g/l, vorzugsweise von 70 g/l bis 100 g/l, insbesondere, ca. 90 g/l (Konzentrat - 12%) werden bereits überraschende Korrosionsschutzwerte von 240 h bis Erstangriff nach DIN 50961 im Salzsprühschrank nach DIN 50021 SS in der Produktion erreicht. Vorzugsweise beträgt das Chrom-Cobalt-Verhältnis 1 ,7:20 = 0,85.By using a cobalt concentration of more than 30 g / l, preferably from 70 g / l to 100 g / l, in particular, about 90 g / l (concentrate - 12%), surprising corrosion protection values from 240 h to the first attack according to DIN 50961 im Salt spray cabinet according to DIN 50021 SS reached in production. The chromium-cobalt ratio is preferably 1.7: 20 = 0.85.
Das Verfahren wird vorzugsweise bei einer Temperatur bis 55° C und einem pH-Wert von 0,5 bis 5,5 durchgeführt. Bevorzugt wird die Passivierung bei pH 4 durchgeführt. Besonders gute Ergebnisse lassen sich mit einer sulfat- freien Lösung erreichen. Dem liegt die Erkenntnis zugrunde, daß die Verwendung von Sulfat zu einer Störung der katalytischen Reaktion und Behinderung des Aufbaus einer korrosionsschützenden Chromschicht führt. Die passivierte Schicht wird mit einer organischen oder anorganischen Beschichtung nachbehandelt, die in die poröse Konversionsschicht eindringt. Vorzugsweise wird auf die Passivierungsschicht eine Aquares™-Schicht der Firma Enthone-OMI GmbH, Neuss aufgebracht. Ein besonders guter Korrosionsschutz läßt sich durch eine doppelte Aquares-Schicht erreichen. Erstaunlicherweise ist die Aquares-Schicht im REM in einigen Varianten der Erfindung nicht mehr nachweisbar.The process is preferably carried out at a temperature of up to 55 ° C. and a pH of 0.5 to 5.5. The passivation is preferably carried out at pH 4. Particularly good results can be achieved with a sulfate-free solution. This is based on the knowledge that the use of sulfate leads to a disruption of the catalytic reaction and hinders the build-up of a corrosion-protecting chromium layer. The passivated layer is aftertreated with an organic or inorganic coating that penetrates into the porous conversion layer. An Aquares ™ layer from Enthone-OMI GmbH, Neuss, is preferably applied to the passivation layer. Particularly good corrosion protection can be achieved with a double Aquares layer. Surprisingly, the Aquares layer in the SEM is no longer detectable in some variants of the invention.
Die Korrosionsschutzeigenschaften sowie die Chemikalienbeständigkeit läßt sich durch einen einen Trockenschmierstoff enthaltenden Topcoat weiter verbessern. Auch dieser geht erfindungsgemäß eine besondere Bindung mit der porösen Konversionsschicht ein. Hiermit lassen sich gleichzeitig die erwünschten Reibungs- und Fließwerte erzielen.The corrosion protection properties and the chemical resistance can be further improved by a top coat containing a dry lubricant. According to the invention, this also forms a special bond with the porous conversion layer. This allows the desired friction and flow values to be achieved at the same time.
Überraschende Eigenschaften weist die Kombination des Trockenschmierstoffs Molykote®D-7100 der Firma Dow Corning, mit der erfindungsgemäß passivierten Zink-Nickellegierung auf. Gegenüber bekannten Beschich- tungssystemen ist dieses System besonders chemikalienbeständig und weist eine Unempfindlichkeit gegen Felgenreiniger auf. Es eignet sich somit besonders für Radschrauben. Gleichzeitig ist eine überraschende Tempe- raturunempfindlichkeit der erfindungsgemäßen Kombination festzustellen.The combination of the dry lubricant Molykote®D-7100 from Dow Corning with the passivated zinc-nickel alloy according to the invention has surprising properties. Compared to known coating systems, this system is particularly resistant to chemicals and is insensitive to rim cleaners. It is therefore particularly suitable for wheel bolts. At the same time, the combination according to the invention is surprisingly insensitive to temperature.
Vorzugsweise wird diese Trockenschmierstoffschicht auf eine zweifache Aquares-Schicht aufgebracht. This dry lubricant layer is preferably applied to a double Aquares layer.

Claims

Patentansprüche: claims:
1. Verfahren zum Passivieren von Zink, Cadmium oder deren Legierungen, insbesondere Zink-Nickel-Legierungen mit einer Chrom(VI)-freien, einen schwachen Komplexbildner, vorzugsweise Di- oder Tricarbonsäuren, bevorzugt Chrom(lll)-Oxalat-Komplex und Co2+ enthaltenden Lösung, dadurch gekennzeichnet, daß die Co2+- Konzentration mehr als 30 g/l beträgt.1. Process for passivating zinc, cadmium or their alloys, in particular zinc-nickel alloys with a chromium (VI) -free, a weak complexing agent, preferably di- or tricarboxylic acids, preferably chromium (III) oxalate complex and Co 2 + containing solution, characterized in that the Co 2+ concentration is more than 30 g / l.
2. Verfahren nach Anspruch 1 , dadurch gekennzeichnet, daß die Co2+- Konzentration 70 bis 110 g/l beträgt.2. The method according to claim 1, characterized in that the Co 2+ concentration is 70 to 110 g / l.
3. Verfahren nach Anspruch 1 , dadurch gekennzeichnet, daß die Co2+- Konzentration ca. 90 g/l beträgt.3. The method according to claim 1, characterized in that the Co 2+ concentration is approximately 90 g / l.
4. Verfahren nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß die Passivierung bei 20° C bis 55° C durchgeführt wird.4. The method according to any one of the preceding claims, characterized in that the passivation is carried out at 20 ° C to 55 ° C.
5. Verfahren nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß die Passivierung bei pH 0,5 bis 5,5 durchgeführt wird.5. The method according to any one of the preceding claims, characterized in that the passivation is carried out at pH 0.5 to 5.5.
6. Verfahren nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß die Passivierung bei pH 4 durchgeführt wird.6. The method according to any one of the preceding claims, characterized in that the passivation is carried out at pH 4.
7. Verfahren nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß das Verhältnis von Chrom : Cobalt 1 ,7 : 2,0 beträgt. 7. The method according to any one of the preceding claims, characterized in that the ratio of chromium: cobalt is 1.7: 2.0.
8. Verfahren nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß die Lösung sulfatfrei ist.8. The method according to any one of the preceding claims, characterized in that the solution is sulfate-free.
9. Verfahren nach einem der vorhergehenden Ansprüche, dadurch ge- kennzeichnet, daß die passivierte Schicht mit einer weiteren Beschichtung behandelt wird.9. The method according to any one of the preceding claims, characterized in that the passivated layer is treated with a further coating.
10. Verfahren nach einem der vorhergehenden Ansprüche, gekennzeichnet durch eine Beschichtung mit Aquares™.10. The method according to any one of the preceding claims, characterized by a coating with Aquares ™.
11. Verfahren nach einem der vorhergehenden Ansprüche, gekennzeichnet durch eine zweifache Beschichtung mit Aquares™.11. The method according to any one of the preceding claims, characterized by a double coating with Aquares ™.
12. Verfahren nach einem der vorhergehenden Ansprüche, dadurch ge- kennzeichnet, daß die passivierte Schicht mit einem Trockenschmierstoff behandelt wird.12. The method according to any one of the preceding claims, characterized in that the passivated layer is treated with a dry lubricant.
13. Verfahren nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß die passivierte Schicht mit einem organischen Top- coat beschichtet wird.13. The method according to any one of the preceding claims, characterized in that the passivated layer is coated with an organic top coat.
14. Verfahren nach einem der vorhergehenden Ansprüche, dadurch gekennzeichnet, daß die passivierte Schicht mit einer PTFE-haltigen Schicht behandelt wird.14. The method according to any one of the preceding claims, characterized in that the passivated layer is treated with a PTFE-containing layer.
15. Verfahren nach dem vorhergehenden Anspruch, dadurch gekennzeichnet, daß die passivierte Schicht mit Molykote® D 7100 beschichtet wird. 15. The method according to the preceding claim, characterized in that the passivated layer is coated with Molykote® D 7100.
EP01993716A 2000-11-07 2001-11-07 Passivation method Withdrawn EP1346081A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10055215 2000-11-07
DE10055215A DE10055215A1 (en) 2000-11-07 2000-11-07 passivation
PCT/EP2001/012866 WO2002038829A1 (en) 2000-11-07 2001-11-07 Passivation method

Publications (1)

Publication Number Publication Date
EP1346081A1 true EP1346081A1 (en) 2003-09-24

Family

ID=7662484

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01993716A Withdrawn EP1346081A1 (en) 2000-11-07 2001-11-07 Passivation method

Country Status (12)

Country Link
US (1) US20040011431A1 (en)
EP (1) EP1346081A1 (en)
JP (1) JP2004513240A (en)
CN (1) CN1478155A (en)
AU (1) AU2002221819A1 (en)
BR (1) BR0115161A (en)
CA (1) CA2428138A1 (en)
CZ (1) CZ20031237A3 (en)
DE (1) DE10055215A1 (en)
MX (1) MXPA03004019A (en)
SK (1) SK5442003A3 (en)
WO (1) WO2002038829A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017194187A1 (en) 2016-05-11 2017-11-16 Surtec International Gmbh Conversion coatings for metal surfaces
EP1318214B2 (en) † 2001-11-30 2021-12-08 Dipsol Chemicals Co., Ltd. Processing solution for forming hexavalent chromium free and corrosion resistant conversion film on zinc or zinc alloy plating layers, hexavalent chromium free and corrosion resistant conversion film, method for forming the same

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1307323C (en) * 2004-06-14 2007-03-28 广州市集胜化工有限公司 Trivalent chromic rainbow color passivating agent for galvanizing and its production
EP1677371A1 (en) * 2004-12-30 2006-07-05 STMicroelectronics S.r.l. Dual resistance heater for phase change devices and manufacturing method thereof
US7276424B2 (en) * 2005-06-29 2007-10-02 Hewlett-Packard Development Company, L.P. Fabrication of aligned nanowire lattices
JP4993959B2 (en) * 2006-07-10 2012-08-08 日本化学工業株式会社 Chromium (III) organic acid aqueous solution and method for producing the same

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4359348A (en) * 1981-06-17 1982-11-16 Occidental Chemical Corporation Stabilized trivalent chromium passivate composition and process
US4384902A (en) * 1981-06-15 1983-05-24 Occidental Chemical Corporation Trivalent chromium passivate composition and process
US4349392A (en) * 1981-05-20 1982-09-14 Occidental Chemical Corporation Trivalent chromium passivate solution and process
US4367099A (en) * 1981-06-15 1983-01-04 Occidental Chemical Corporation Trivalent chromium passivate process
US4359347A (en) * 1981-04-16 1982-11-16 Occidental Chemical Corporation Chromium-free passivate solution and process
US4359345A (en) * 1981-04-16 1982-11-16 Occidental Chemical Corporation Trivalent chromium passivate solution and process
US4359346A (en) * 1981-04-16 1982-11-16 Occidental Chemical Corporation Trivalent chromium passivate solution and process for yellow passivate film
CA1228000A (en) * 1981-04-16 1987-10-13 David E. Crotty Chromium appearance passivate solution and process
FR2600072B1 (en) * 1986-06-13 1988-10-21 Dacral Sa ANTICORROSION COATING COMPOSITION WITH IMPROVED STABILITY, AND COATED SUBSTRATE
US4971635A (en) * 1987-02-06 1990-11-20 Guhde Donald J Low-cure coating composition
US5368655A (en) * 1992-10-23 1994-11-29 Alchem Corp. Process for chromating surfaces of zinc, cadmium and alloys thereof
DE19905134A1 (en) * 1999-02-09 2000-09-28 Hillebrand Walter Gmbh & Co Kg Passivation process

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO0238829A1 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1318214B2 (en) † 2001-11-30 2021-12-08 Dipsol Chemicals Co., Ltd. Processing solution for forming hexavalent chromium free and corrosion resistant conversion film on zinc or zinc alloy plating layers, hexavalent chromium free and corrosion resistant conversion film, method for forming the same
WO2017194187A1 (en) 2016-05-11 2017-11-16 Surtec International Gmbh Conversion coatings for metal surfaces
DE102016005656A1 (en) 2016-05-11 2017-11-16 Surtec International Gmbh Conversion layers for metallic surfaces

Also Published As

Publication number Publication date
AU2002221819A1 (en) 2002-05-21
CA2428138A1 (en) 2002-05-16
SK5442003A3 (en) 2003-10-07
BR0115161A (en) 2003-10-21
MXPA03004019A (en) 2004-02-12
WO2002038829A1 (en) 2002-05-16
JP2004513240A (en) 2004-04-30
CN1478155A (en) 2004-02-25
US20040011431A1 (en) 2004-01-22
DE10055215A1 (en) 2002-05-08
CZ20031237A3 (en) 2003-10-15

Similar Documents

Publication Publication Date Title
EP2507408B1 (en) Multi-stage pre-treatment method for metal components having zinc and iron surfaces
DE69732102T2 (en) Surface treated metallic corrosion resistant material and surface treatment agent
WO2008135478A2 (en) Preliminary metallizing treatment of zinc surfaces
CN101321894A (en) Wet on wet method and chrome-free acidic solution for the corrosion control treatment of steel surfaces
EP1978131B2 (en) Means for manufacturing corrosion protection coats on metal surfaces
DE102007021602A1 (en) Corrosion protection system for metals and pigment for this purpose
WO2005061761A1 (en) Two-stage conversion treatment
EP0459541A1 (en) Process for phosphating metal surfaces
EP0187917A1 (en) Process for improving the protection against corrosion of resin layers autophoretically deposited on metal surfaces
EP0359296B1 (en) Phosphating process
EP1346081A1 (en) Passivation method
EP2215285A1 (en) Zirconium phosphating of metal components, in particular iron
JP3967796B2 (en) Surface-treated metal material
WO2014012703A1 (en) Tinning pretreatment of galvanized steel in the presence of pyrophosphate
EP2743376B1 (en) Aqueous agent and coating method for the corrosion protection treatment of metal substrates
DE102009047523A1 (en) Multi-stage method for corrosion-inhibiting pretreatment of metallic components having the surfaces of zinc, comprises subjecting the metallic components with an aqueous treatment solution, and cleaning and degreasing the metal surface
EP1444381A1 (en) Method for the production of dark protective layers on flat objects made from titanium zinc
EP3728693B1 (en) Method for the corrosion protection and cleaning pretreatment of metallic components
EP2726650B1 (en) Electrolytic iron plating on zinc surfaces
DE102009042861A1 (en) Composition, useful to passivate zinc and its alloy, comprises passivation solution comprising chromium(III)-compound, soluble nitrates, fluorides and organic acids, and an activation solution comprising e.g. tin(II)- or tin(IV)-salts
DE102016114808B4 (en) Connector with connector housing protected against corrosion
WO2002079539A2 (en) Treatment of zinc and zinc alloy surfaces
EP1713955A1 (en) Black passivation of zinc or zinc alloy surfaces
KR101277940B1 (en) Blackened steel stheet with high adhesion property of blackened layer and surface appearance, and method for manufacturing the same
DE4333894C1 (en) Process for resin coating a metal surface

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20030605

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

AX Request for extension of the european patent

Extension state: AL LT LV MK RO SI

17Q First examination report despatched

Effective date: 20050627

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN

18W Application withdrawn

Effective date: 20050809