EP1335965B1 - Traitement de surfaces pour ameliorer temporairement le comportement a l'enlevement de salissures - Google Patents
Traitement de surfaces pour ameliorer temporairement le comportement a l'enlevement de salissures Download PDFInfo
- Publication number
- EP1335965B1 EP1335965B1 EP01993668A EP01993668A EP1335965B1 EP 1335965 B1 EP1335965 B1 EP 1335965B1 EP 01993668 A EP01993668 A EP 01993668A EP 01993668 A EP01993668 A EP 01993668A EP 1335965 B1 EP1335965 B1 EP 1335965B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- use according
- formulation
- treated
- surfactant
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000002360 preparation method Methods 0.000 claims abstract description 34
- 238000004140 cleaning Methods 0.000 claims abstract description 27
- 238000000034 method Methods 0.000 claims abstract description 20
- 239000000203 mixture Substances 0.000 claims description 24
- 238000009472 formulation Methods 0.000 claims description 23
- 125000000217 alkyl group Chemical group 0.000 claims description 19
- 125000004432 carbon atom Chemical group C* 0.000 claims description 19
- 239000006260 foam Substances 0.000 claims description 18
- 239000004094 surface-active agent Substances 0.000 claims description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 150000001875 compounds Chemical class 0.000 claims description 12
- 238000005187 foaming Methods 0.000 claims description 12
- 230000000845 anti-microbial effect Effects 0.000 claims description 11
- 125000005233 alkylalcohol group Chemical group 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 8
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 8
- 239000011575 calcium Substances 0.000 claims description 8
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 7
- 229910052791 calcium Inorganic materials 0.000 claims description 7
- 238000004851 dishwashing Methods 0.000 claims description 7
- 239000000243 solution Substances 0.000 claims description 7
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 6
- 239000001110 calcium chloride Substances 0.000 claims description 6
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 6
- 235000011148 calcium chloride Nutrition 0.000 claims description 6
- -1 diphenylalkanes Chemical class 0.000 claims description 6
- 150000002681 magnesium compounds Chemical class 0.000 claims description 6
- 229920006395 saturated elastomer Polymers 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 6
- PYIDGJJWBIBVIA-UYTYNIKBSA-N lauryl glucoside Chemical compound CCCCCCCCCCCCO[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O PYIDGJJWBIBVIA-UYTYNIKBSA-N 0.000 claims description 5
- 229940048848 lauryl glucoside Drugs 0.000 claims description 5
- 238000011109 contamination Methods 0.000 claims description 4
- 150000002148 esters Chemical class 0.000 claims description 4
- 239000002736 nonionic surfactant Substances 0.000 claims description 4
- 150000002989 phenols Chemical class 0.000 claims description 4
- 229920003023 plastic Polymers 0.000 claims description 4
- 239000004033 plastic Substances 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- QZXSMBBFBXPQHI-UHFFFAOYSA-N N-(dodecanoyl)ethanolamine Chemical compound CCCCCCCCCCCC(=O)NCCO QZXSMBBFBXPQHI-UHFFFAOYSA-N 0.000 claims description 3
- 150000001298 alcohols Chemical class 0.000 claims description 3
- 150000003973 alkyl amines Chemical class 0.000 claims description 3
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 3
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 claims description 3
- 239000001639 calcium acetate Substances 0.000 claims description 3
- 235000011092 calcium acetate Nutrition 0.000 claims description 3
- 229960005147 calcium acetate Drugs 0.000 claims description 3
- 229960002713 calcium chloride Drugs 0.000 claims description 3
- 229940043430 calcium compound Drugs 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000011521 glass Substances 0.000 claims description 3
- 150000002357 guanidines Chemical class 0.000 claims description 3
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 claims description 3
- 239000011654 magnesium acetate Substances 0.000 claims description 3
- 235000011285 magnesium acetate Nutrition 0.000 claims description 3
- 229940069446 magnesium acetate Drugs 0.000 claims description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
- 229960002337 magnesium chloride Drugs 0.000 claims description 3
- 235000011147 magnesium chloride Nutrition 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 229910052573 porcelain Inorganic materials 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 3
- 239000002023 wood Substances 0.000 claims description 3
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical class CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims description 2
- DHVLDKHFGIVEIP-UHFFFAOYSA-N 2-bromo-2-(bromomethyl)pentanedinitrile Chemical compound BrCC(Br)(C#N)CCC#N DHVLDKHFGIVEIP-UHFFFAOYSA-N 0.000 claims description 2
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 claims description 2
- GUUULVAMQJLDSY-UHFFFAOYSA-N 4,5-dihydro-1,2-thiazole Chemical class C1CC=NS1 GUUULVAMQJLDSY-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 150000007513 acids Chemical class 0.000 claims description 2
- 150000001299 aldehydes Chemical class 0.000 claims description 2
- 150000001408 amides Chemical class 0.000 claims description 2
- 239000002280 amphoteric surfactant Substances 0.000 claims description 2
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 229940111121 antirheumatic drug quinolines Drugs 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 150000003937 benzamidines Chemical class 0.000 claims description 2
- 235000010290 biphenyl Nutrition 0.000 claims description 2
- 125000006267 biphenyl group Chemical group 0.000 claims description 2
- 150000001733 carboxylic acid esters Chemical class 0.000 claims description 2
- 125000002091 cationic group Chemical group 0.000 claims description 2
- 239000000919 ceramic Substances 0.000 claims description 2
- 238000000151 deposition Methods 0.000 claims description 2
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 2
- 229920001971 elastomer Polymers 0.000 claims description 2
- 239000000194 fatty acid Substances 0.000 claims description 2
- 229930195729 fatty acid Natural products 0.000 claims description 2
- 150000004665 fatty acids Chemical class 0.000 claims description 2
- 239000010438 granite Substances 0.000 claims description 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 150000002978 peroxides Chemical class 0.000 claims description 2
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical class C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 claims description 2
- 150000003222 pyridines Chemical class 0.000 claims description 2
- 239000010453 quartz Substances 0.000 claims description 2
- 150000003248 quinolines Chemical class 0.000 claims description 2
- 239000005060 rubber Substances 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- 150000003672 ureas Chemical class 0.000 claims description 2
- 239000013011 aqueous formulation Substances 0.000 claims 1
- 238000007654 immersion Methods 0.000 claims 1
- 229940035535 iodophors Drugs 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- 150000005217 methyl ethers Chemical class 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 7
- 238000004381 surface treatment Methods 0.000 abstract 1
- 239000002689 soil Substances 0.000 description 19
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 13
- 238000012360 testing method Methods 0.000 description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 239000003599 detergent Substances 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- 239000013530 defoamer Substances 0.000 description 5
- 235000013305 food Nutrition 0.000 description 5
- 229920002472 Starch Polymers 0.000 description 4
- MOVRNJGDXREIBM-UHFFFAOYSA-N aid-1 Chemical compound O=C1NC(=O)C(C)=CN1C1OC(COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)CO)C(O)C1 MOVRNJGDXREIBM-UHFFFAOYSA-N 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- 101100453960 Drosophila melanogaster klar gene Proteins 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 150000002222 fluorine compounds Chemical class 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- MITNMQMWBBEWFQ-UHFFFAOYSA-N 1-(4-chlorophenyl)-1-(3,4-dichlorophenyl)urea Chemical compound C=1C=C(Cl)C(Cl)=CC=1N(C(=O)N)C1=CC=C(Cl)C=C1 MITNMQMWBBEWFQ-UHFFFAOYSA-N 0.000 description 1
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 description 1
- NCKMMSIFQUPKCK-UHFFFAOYSA-N 2-benzyl-4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1CC1=CC=CC=C1 NCKMMSIFQUPKCK-UHFFFAOYSA-N 0.000 description 1
- TYBHZVUFOINFDV-UHFFFAOYSA-N 2-bromo-6-[(3-bromo-5-chloro-2-hydroxyphenyl)methyl]-4-chlorophenol Chemical compound OC1=C(Br)C=C(Cl)C=C1CC1=CC(Cl)=CC(Br)=C1O TYBHZVUFOINFDV-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical compound CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- GHXZTYHSJHQHIJ-UHFFFAOYSA-N Chlorhexidine Chemical compound C=1C=C(Cl)C=CC=1NC(N)=NC(N)=NCCCCCCN=C(N)N=C(N)NC1=CC=C(Cl)C=C1 GHXZTYHSJHQHIJ-UHFFFAOYSA-N 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- DKNPRRRKHAEUMW-UHFFFAOYSA-N Iodine aqueous Chemical compound [K+].I[I-]I DKNPRRRKHAEUMW-UHFFFAOYSA-N 0.000 description 1
- 244000218514 Opuntia robusta Species 0.000 description 1
- 235000003166 Opuntia robusta Nutrition 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- XEFQLINVKFYRCS-UHFFFAOYSA-N Triclosan Chemical compound OC1=CC(Cl)=CC=C1OC1=CC=C(Cl)C=C1Cl XEFQLINVKFYRCS-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- KHAVLLBUVKBTBG-UHFFFAOYSA-N caproleic acid Natural products OC(=O)CCCCCCCC=C KHAVLLBUVKBTBG-UHFFFAOYSA-N 0.000 description 1
- 125000001309 chloro group Chemical class Cl* 0.000 description 1
- 229960004106 citric acid Drugs 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 229930182478 glucoside Natural products 0.000 description 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 229960005150 glycerol Drugs 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 239000003752 hydrotrope Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- SMGTYJPMKXNQFY-UHFFFAOYSA-N octenidine dihydrochloride Chemical compound Cl.Cl.C1=CC(=NCCCCCCCC)C=CN1CCCCCCCCCCN1C=CC(=NCCCCCCCC)C=C1 SMGTYJPMKXNQFY-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 229960004063 propylene glycol Drugs 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000006748 scratching Methods 0.000 description 1
- 230000002393 scratching effect Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229960002703 undecylenic acid Drugs 0.000 description 1
- 238000012800 visualization Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 150000003754 zirconium Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
- C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/722—Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/14—Hard surfaces
Definitions
- the invention relates to the use of stable, aqueous preparations selected Substances contain, for the treatment of surfaces, to surfaces too which can be made easier at a later date using common means can clean, as identical surfaces, not with the claimed preparations treated as well as a cleaning method and a cleaning preparation.
- GB 2 058 823 A discloses liquid dishwashing detergents containing anionic surfactants, calcium and / or magnesium compounds, Hydrotropes, and alkyl phosphates or phosphonates.
- the present invention understands alkaline, neutral or acidic agents, depending on the surface and cleaning method with different Ingredients, such as surfactants, enzymes, oxidants, complexing agents, Chlorine derivatives, antimicrobial agents, corrosion inhibitors, defoamers or other ingredients.
- Ingredients such as surfactants, enzymes, oxidants, complexing agents, Chlorine derivatives, antimicrobial agents, corrosion inhibitors, defoamers or other ingredients.
- lauryl glucoside In the event that the preparations to be used according to the invention lauryl glucoside contain, these formulations are used so that the treated Surface due to the antimicrobial properties of lauryl glucoside receives additional antimicrobial protection.
- the preparations to be used according to the invention additionally one or more further surfactants selected from the groups anionic, cationic, nonionic, amphoteric surfactants, phosphoric esters, Alkylamine oxides and their salts and the silicone compounds it being particularly preferred that the present invention be used
- Preparations as another nonionic surfactant an alkoxylated Alkyl alcohol containing 8 to 22 carbon atoms in the alkyl chain, particularly preferred from the group of mixed ethoxylates / propoxylates of branched or unbranched alkyl alcohols having 8 to 22 carbon atoms in the alkyl moiety and the end-capped Ethoxylates of branched or unbranched alkyl alcohols with 8 to 22 carbon atoms in the alkyl chain, and most preferably from the group of mixed ethoxylated and propoxylated alkyl alcohols with 12 to 22 C atoms in the alkyl part, butyl ether of an ethoxylated alkyl alcohol
- the preparations to be used according to the invention preferably contain additionally one or more antimicrobial components selected from Groups of alcohols, aldehydes, antimicrobial acids, carboxylic esters, Acid amides, phenols, phenol derivatives, diphenyls, diphenylalkanes, urea derivatives, Oxygen, nitrogen acetals and formals, benzamidines, isothiazolines, Phthalimide derivatives, pyridine derivatives, antimicrobial surface-active compounds, Guanidines, antimicrobial amphoteric compounds, quinolines, 1,2-dibromo-2,4-dicyanobutane, iodo-2-propynyl-butyl-carbamate, iodine, iodophores, peroxides, it being particularly preferred when the formulations according to the invention selected as antimicrobial components one or more compounds from ethanol, n-propanol, i-propanol, 1,3-butanedio
- solubilizers such as, for example, cumene sulphonate, monohydric alcohols, such as isopropanol, butanol, ethanol and polyhydric Alcohols such as glycols or glycerol and their ethers and esters, wherein the term solubilizers also surfactants, such as fatty amine and other Substances with solubilizing properties may fall.
- preparations to be used according to the invention in a dosage form selected from stable aqueous solution, gel, or paste, and it is also preferred if the preparations according to the invention to be used from a non-aqueous Dosage form and a water-soluble shell, preferably polyvinyl alcohol most preferably the water-soluble shell contains part of the formulation ingredients, prepared by dissolving in water become.
- the preparations to be used according to the invention depending on the type of contamination, process, machine and otherwise conditional conditions, in undiluted or diluted form on the surface be applied, it being particularly preferred that the treated Surface is treated by dipping. It may be preferred on a case-by-case basis be that the preparations to be used according to the invention in undiluted or diluted form on the surfaces to be treated via aids, which can be selected from brush, sponge, rolls, cloths, rags, Brushes, wipers, rubber, pug, mop covers, sprayers be applied.
- the preparations to be used according to the invention with water to concentrations below 15,000 ppm, more preferably 15 to 10000 ppm and most preferably to 50 to 1000 ppm to dilute and to apply in this concentration the surfaces to be treated.
- the contact time between the preparations to be used according to the invention and the surfaces to be treated is preferably at least the time is necessary to wet the surface to be treated, taking particular preferred is when the contact time is longer than 5 seconds and completely is particularly preferred if after contact no rinsing with water he follows.
- the treatment temperature is preferably 5 to 95 ° C and is more preferably between 20 and 85 ° C.
- the preparations to be used according to the invention are for the treatment of surfaces of plastic and / or glass and / or ceramic and / or porcelain and / or quartz and / or granite and / or metal and / or wood used, it being particularly preferred that the treated Surfaces of dishes, windows, tiles, floor coverings, wood and stone surfaces and floors and walls and coated or uncoated tanks or other containers, lines, conveyor belts, containers, such as Refillable bottles made of glass, plastic, such as PET, or textiles come.
- preparations to be used according to the invention during or after manual or automatic dishwashing and / or dishwashing cleaning operations brought into contact with the surfaces to be treated wherein it is particularly preferred to use the invention Use preparations as rinse aid.
- Another object of the present invention is a method for purification of surfaces in which, in at least one process step, the surfaces brought into contact with a preparation to be used according to the invention be, with the effect that the treated surfaces after soiling easier to clean in a next cleaning process than that Surfaces that have not come into contact with these preparations.
- the tank of a one-tank dishwasher (eg Fa. Krefft) is filled with softened water and heated to 60 ° C operating temperature.
- the cleaning solution is adjusted so that the concentration of Perclin Supra in the tank is 1 g per liter of water.
- the supply of the dosing device for the rinse aid is connected.
- the grid position of the dosing device is adjusted so that about 0.57 g of rinse aid per liter of softened water are added.
- the one-tank dishwasher is set to a consumption of about 5 l softened water.
- the temperature of the water in the rinse cycle is set to 75 ° C.
- an about 6% aqueous corn starch containing After being boiled, cool the composition to 75 ° C and leave each dish Apply approx. 4 mL with a brush.
- the thus treated plates are allowed at least 3 Hours stand and then let the plates for 16 hours at about 100 ° C dry. After cooling, the plates are described as in the following text further treated.
- the tank of the one-tank dishwasher with turn filled with softened water. 1 liter of dishwasher detergent per liter of softened water Added Perclin Supra.
- the single-tank dishwasher is set to an operating temperature brought from 60 ° C.
- the soiled plates will turn introduced in an upright position by means of a dish rack in the dishwasher and the one-tank dishwasher is closed.
- the ever 60 seconds continuous cleaning step is repeated five times, so that a total of five minutes is cleaned.
- the dishwasher is opened and the dish rack taken with the dining plates of the dishwasher. The dining plates dry and cool at room temperature.
- the food plates are used for visualization the remaining starch residue in a short by default by loosening Iodine and potassium iodide immersed in water-prepared iodine solution.
- the device is filled with about 40 L of softened water. To harden the conditions About 180 g are added to the water when the circulating pump is switched on given to foaming detergents. At the same time you add about 10 g of the each to be examined rinse aid 1 to 4. Under continuous pumping The solution is raised to 60 ° C and the foam height determined via a measuring scale.
- Treatment with a preparation containing sodium lauryl sulfate and calcium chloride contains, therefore, a visible relief for the cleaning process of Surfaces, as shown in the example of the dining plates.
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Claims (18)
- Utilisation d'une composition aqueuse stable, contenant, sur base de la composition totale,A) de 0,2 à 40 % en poids d'un tensioactif moussant, non alcoxylé, contenant des radicaux alkyle, choisi parmi le groupe desa) sulfates d'alkyle avec un radical alkyle saturé ou insaturé, ramifié ou linéaire, ayant 8 à 22 atomes de carbone,b) glucosides d'alkyle avec un radical alkyle saturé ou insaturé, ramifié ou linéaire, ayant 8 à 22 atomes de carbone,c) éthanolamides d'acide gras avec un radical alkyle saturé ou insaturé, ramifié ou linéaire, ayant 8 à 22 atomes de carbone, ainsi queB) de 0,1 à 20 % en poids d'un métal bivalent sous forme liée, choisi parmi les composés du calcium ou du magnésium,
- Utilisation selon la revendication 1, caractérisée en ce que le composé du calcium ou du magnésium présent dans la composition, est choisi parmi le chlorure de calcium, l'acétate de calcium, le chlorure de magnésium et l'acétate de magnésium.
- Utilisation selon l'une des revendications 1 ou 2, caractérisée en ce que le laurylsulfate de sodium est présent dans la composition comme tensioactif du groupe a).
- Utilisation selon l'une des revendications 1 ou 2, caractérisée en ce que le laurylglucoside est présent dans la composition comme tensioactif du groupe b) .
- Utilisation selon l'une des revendications 1 ou 2, caractérisée en ce que le lauryléthanolamide est présent dans la composition comme tensioactif du groupe c) .
- Utilisation selon l'une des revendications 1 à 5, caractérisée en ce que la composition contient en outre, un ou plusieurs autres tensioactifs, choisis parmi le groupe des tensioactifs anioniques, cationiques, non ioniques, amphotères, les oxydes d'alkylamine, les composés du silicium et les esters d'acide phosphorique et leurs sels.
- Utilisation selon la revendication 6, caractérisée en ce qu'un alkylalcool avec 8 à 22 atomes de carbone dans la chaíne alkyle est présent dans la composition comme autre tensioactif non ionique.
- Utilisation selon la revendication 7, caractérisée en ce que l'autre tensioactif non ionique est un tensioactif non ou faiblement moussant, choisi parmi le groupe des éthoxylates/propoxylates mixtes d'alkylalcools ramifiés ou non ramifiés avec 12 à 22 atomes de carbone dans la partie alkyle.
- Utilisation selon la revendication 8, caractérisée en ce que l'autre tensioactif non ionique est un tensioactif non ou faiblement moussant, choisi parmi le groupe des méthyl- et/ou butyléthers d'alkylalcools éthoxylés avec 12 à 22 atomes de carbone dans la partie alkyle.
- Utilisation selon l'une des revendications 1 à 9, caractérisée en ce que la composition contient en outre, un ou plusieurs composants antimicrobiens, choisis parmi le groupe des alcools, aldéhydes, acides antimicrobiens, esters d'acide carboxylique, amides d'acide, phénols, dérivés de phénol, diphényles, diphénylalcanes, dérivés d'urée, acétals ainsi que formals oxygénés, azotés, benzamidines, isothiazolines, dérivés de phtalimide, dérivés de pyridine, composés tensioactifs antimicrobiens, guanidines, composés amphotères antimicrobiens, quinoléines, le 1,2-dibromo-2,4-dicyanobutane, le carbamate d'iodo-2-propynylbutyle, l'iode, l'iodophore, des peroxydes.
- Utilisation selon l'une des revendications 1 à 10, caractérisée en ce que la composition contient en outre, un solvant.
- Utilisation selon l'une des revendications 1 à 11, caractérisée en ce que la solution se présente comme une solution stable, un gel ou une pâte.
- Utilisation selon l'une des revendications 1 à 12, caractérisée en ce que la composition est préparée à partir d'une forme de présentation non aqueuse et d'une enveloppe soluble dans l'eau, par dissolution dans l'eau.
- Utilisation selon l'une des revendications 1 à 13, caractérisée en ce que la surface à traiter est traitée avec la composition non diluée ou diluée, par immersion.
- Utilisation selon l'une des revendications 1 à 13, caractérisée en ce que la surface à traiter est traitée avec la composition diluée ou non diluée, par un auxiliaire qui est choisi parmi un pinceau, une éponge, un rouleau, un linge, un chiffon, une brosse, un essuie, une gomme, un balai à franges, une racle, un dispositif de pulvérisation.
- Utilisation selon l'une des revendications 1 à 15, caractérisée en ce que les matériaux de la surface à traiter sont choisis parmi les matières plastiques et/ou le verre et/ou la céramique et/ou la porcelaine et/ou le quartz et/ou le granit et/ou un métal et/ou le bois.
- Utilisation selon la revendication 16, caractérisée en ce que les surfaces à traiter proviennent de la vaisselle.
- Utilisation selon l'une des revendications 1 à 17, caractérisée en ce que la composition est mise en oeuvre comme un produit de rinçage lors du rinçage de la vaisselle.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10055555A DE10055555A1 (de) | 2000-11-09 | 2000-11-09 | Behandlung von Oberflächen zur temporären Verbesserung des Schmutzablöseverhaltens |
DE10055555 | 2000-11-09 | ||
PCT/EP2001/012635 WO2002038716A1 (fr) | 2000-11-09 | 2001-10-31 | Traitement de surfaces pour ameliorer temporairement le comportement a l'enlevement de salissures |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1335965A1 EP1335965A1 (fr) | 2003-08-20 |
EP1335965B1 true EP1335965B1 (fr) | 2005-12-14 |
Family
ID=7662701
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP01993668A Expired - Lifetime EP1335965B1 (fr) | 2000-11-09 | 2001-10-31 | Traitement de surfaces pour ameliorer temporairement le comportement a l'enlevement de salissures |
Country Status (5)
Country | Link |
---|---|
US (1) | US20040110657A1 (fr) |
EP (1) | EP1335965B1 (fr) |
AT (1) | ATE312898T1 (fr) |
DE (2) | DE10055555A1 (fr) |
WO (1) | WO2002038716A1 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106318688A (zh) * | 2016-08-19 | 2017-01-11 | 盐城市艾斯特体育器材有限公司 | 一种乒乓球拍胶皮清洗液 |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE602006008466D1 (de) * | 2005-06-07 | 2009-09-24 | Reckitt Benckiser Inc | Saure reinigungsmittel für feste oberflächen |
US8383570B2 (en) | 2007-05-25 | 2013-02-26 | Ecolab Usa Inc. | Enhanced melting point rinse aid solid compositions with synergistic preservative |
US20110108068A1 (en) | 2007-05-25 | 2011-05-12 | Ecolab Usa Inc. | Enhanced melting point rinse aid solids |
US7741265B2 (en) * | 2007-08-14 | 2010-06-22 | S.C. Johnson & Son, Inc. | Hard surface cleaner with extended residual cleaning benefit |
WO2010078413A1 (fr) | 2008-12-31 | 2010-07-08 | Apinee, Inc. | Conservation du bois, compositions et procédés correspondants |
EP3936594A1 (fr) | 2009-05-12 | 2022-01-12 | Ecolab USA Inc. | Adjuvant de rinçage pour un drainage et un séchage rapide |
JP5513610B2 (ja) | 2009-05-28 | 2014-06-04 | エコラボ ユーエスエー インコーポレイティド | 無菌充填用の湿潤剤 |
US9878464B1 (en) | 2011-06-30 | 2018-01-30 | Apinee, Inc. | Preservation of cellulosic materials, compositions and methods thereof |
US9567551B2 (en) | 2012-06-22 | 2017-02-14 | Ecolab Usa Inc. | Solid rinse aid composition and method of making same |
US9011610B2 (en) | 2012-06-22 | 2015-04-21 | Ecolab Usa Inc. | Solid fast draining/drying rinse aid for high total dissolved solid water conditions |
US9982220B2 (en) | 2015-05-19 | 2018-05-29 | Ecolab Usa Inc. | Efficient surfactant system on plastic and all types of ware |
MY176504A (en) * | 2015-12-28 | 2020-08-12 | Colgate Palmolive Co | Dishwashing pastes |
US11155769B2 (en) | 2018-07-25 | 2021-10-26 | Ecolab Usa Inc. | Rinse aid formulation for cleaning automotive parts |
MX2021016078A (es) * | 2020-12-30 | 2022-07-01 | Colgate Palmolive Co | Composiciones opacas y metodos para las mismas. |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2058823B (en) * | 1979-09-17 | 1983-06-22 | Unilever Ltd | Dishwashing compositions |
GB9310365D0 (en) * | 1993-05-18 | 1993-06-30 | Unilever Plc | Hard surface cleaning compositions comprising polymers |
US5415814A (en) * | 1993-08-27 | 1995-05-16 | The Procter & Gamble Company | Concentrated liquid or gel light duty dishwashing detergent composition containing calcium xylene sulfonate |
MA25183A1 (fr) * | 1996-05-17 | 2001-07-02 | Arthur Jacques Kami Christiaan | Compositions detergentes |
US5922662A (en) * | 1996-08-07 | 1999-07-13 | Colgate Palmolive Company | High foaming nonionic surfactant based liquid detergent |
US6218351B1 (en) * | 1998-03-06 | 2001-04-17 | The Procter & Gamble Compnay | Bleach compositions |
DE19956238A1 (de) * | 1999-11-23 | 2001-06-28 | Henkel Ecolab Gmbh & Co Ohg | Verwendung von Formulierungen zur Behandlung von Oberflächen zur temporären Verbesserung des Schmutzablöseverhaltens |
ATE390474T1 (de) * | 1999-12-08 | 2008-04-15 | Unilever Nv | Verwendung von polymerem material zur behandlung harter oberflächen |
-
2000
- 2000-11-09 DE DE10055555A patent/DE10055555A1/de not_active Ceased
-
2001
- 2001-10-31 WO PCT/EP2001/012635 patent/WO2002038716A1/fr active IP Right Grant
- 2001-10-31 AT AT01993668T patent/ATE312898T1/de not_active IP Right Cessation
- 2001-10-31 EP EP01993668A patent/EP1335965B1/fr not_active Expired - Lifetime
- 2001-10-31 DE DE50108409T patent/DE50108409D1/de not_active Expired - Lifetime
- 2001-10-31 US US10/416,480 patent/US20040110657A1/en not_active Abandoned
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106318688A (zh) * | 2016-08-19 | 2017-01-11 | 盐城市艾斯特体育器材有限公司 | 一种乒乓球拍胶皮清洗液 |
Also Published As
Publication number | Publication date |
---|---|
DE50108409D1 (de) | 2006-01-19 |
WO2002038716A1 (fr) | 2002-05-16 |
DE10055555A1 (de) | 2002-05-29 |
EP1335965A1 (fr) | 2003-08-20 |
US20040110657A1 (en) | 2004-06-10 |
ATE312898T1 (de) | 2005-12-15 |
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