EP1335965B1 - Traitement de surfaces pour ameliorer temporairement le comportement a l'enlevement de salissures - Google Patents

Traitement de surfaces pour ameliorer temporairement le comportement a l'enlevement de salissures Download PDF

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Publication number
EP1335965B1
EP1335965B1 EP01993668A EP01993668A EP1335965B1 EP 1335965 B1 EP1335965 B1 EP 1335965B1 EP 01993668 A EP01993668 A EP 01993668A EP 01993668 A EP01993668 A EP 01993668A EP 1335965 B1 EP1335965 B1 EP 1335965B1
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EP
European Patent Office
Prior art keywords
use according
formulation
treated
surfactant
alkyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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EP01993668A
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German (de)
English (en)
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EP1335965A1 (fr
Inventor
Werner Strothoff
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Ecolab Inc
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Ecolab Inc
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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0094High foaming compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/825Mixtures of compounds all of which are non-ionic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/835Mixtures of non-ionic with cationic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/86Mixtures of anionic, cationic, and non-ionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0026Low foaming or foam regulating compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/046Salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146Sulfuric acid esters
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38Cationic compounds
    • C11D1/52Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/662Carbohydrates or derivatives
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • C11D1/721End blocked ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/722Ethers of polyoxyalkylene glycols having mixed oxyalkylene groups; Polyalkoxylated fatty alcohols or polyalkoxylated alkylaryl alcohols with mixed oxyalkylele groups
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces

Definitions

  • the invention relates to the use of stable, aqueous preparations selected Substances contain, for the treatment of surfaces, to surfaces too which can be made easier at a later date using common means can clean, as identical surfaces, not with the claimed preparations treated as well as a cleaning method and a cleaning preparation.
  • GB 2 058 823 A discloses liquid dishwashing detergents containing anionic surfactants, calcium and / or magnesium compounds, Hydrotropes, and alkyl phosphates or phosphonates.
  • the present invention understands alkaline, neutral or acidic agents, depending on the surface and cleaning method with different Ingredients, such as surfactants, enzymes, oxidants, complexing agents, Chlorine derivatives, antimicrobial agents, corrosion inhibitors, defoamers or other ingredients.
  • Ingredients such as surfactants, enzymes, oxidants, complexing agents, Chlorine derivatives, antimicrobial agents, corrosion inhibitors, defoamers or other ingredients.
  • lauryl glucoside In the event that the preparations to be used according to the invention lauryl glucoside contain, these formulations are used so that the treated Surface due to the antimicrobial properties of lauryl glucoside receives additional antimicrobial protection.
  • the preparations to be used according to the invention additionally one or more further surfactants selected from the groups anionic, cationic, nonionic, amphoteric surfactants, phosphoric esters, Alkylamine oxides and their salts and the silicone compounds it being particularly preferred that the present invention be used
  • Preparations as another nonionic surfactant an alkoxylated Alkyl alcohol containing 8 to 22 carbon atoms in the alkyl chain, particularly preferred from the group of mixed ethoxylates / propoxylates of branched or unbranched alkyl alcohols having 8 to 22 carbon atoms in the alkyl moiety and the end-capped Ethoxylates of branched or unbranched alkyl alcohols with 8 to 22 carbon atoms in the alkyl chain, and most preferably from the group of mixed ethoxylated and propoxylated alkyl alcohols with 12 to 22 C atoms in the alkyl part, butyl ether of an ethoxylated alkyl alcohol
  • the preparations to be used according to the invention preferably contain additionally one or more antimicrobial components selected from Groups of alcohols, aldehydes, antimicrobial acids, carboxylic esters, Acid amides, phenols, phenol derivatives, diphenyls, diphenylalkanes, urea derivatives, Oxygen, nitrogen acetals and formals, benzamidines, isothiazolines, Phthalimide derivatives, pyridine derivatives, antimicrobial surface-active compounds, Guanidines, antimicrobial amphoteric compounds, quinolines, 1,2-dibromo-2,4-dicyanobutane, iodo-2-propynyl-butyl-carbamate, iodine, iodophores, peroxides, it being particularly preferred when the formulations according to the invention selected as antimicrobial components one or more compounds from ethanol, n-propanol, i-propanol, 1,3-butanedio
  • solubilizers such as, for example, cumene sulphonate, monohydric alcohols, such as isopropanol, butanol, ethanol and polyhydric Alcohols such as glycols or glycerol and their ethers and esters, wherein the term solubilizers also surfactants, such as fatty amine and other Substances with solubilizing properties may fall.
  • preparations to be used according to the invention in a dosage form selected from stable aqueous solution, gel, or paste, and it is also preferred if the preparations according to the invention to be used from a non-aqueous Dosage form and a water-soluble shell, preferably polyvinyl alcohol most preferably the water-soluble shell contains part of the formulation ingredients, prepared by dissolving in water become.
  • the preparations to be used according to the invention depending on the type of contamination, process, machine and otherwise conditional conditions, in undiluted or diluted form on the surface be applied, it being particularly preferred that the treated Surface is treated by dipping. It may be preferred on a case-by-case basis be that the preparations to be used according to the invention in undiluted or diluted form on the surfaces to be treated via aids, which can be selected from brush, sponge, rolls, cloths, rags, Brushes, wipers, rubber, pug, mop covers, sprayers be applied.
  • the preparations to be used according to the invention with water to concentrations below 15,000 ppm, more preferably 15 to 10000 ppm and most preferably to 50 to 1000 ppm to dilute and to apply in this concentration the surfaces to be treated.
  • the contact time between the preparations to be used according to the invention and the surfaces to be treated is preferably at least the time is necessary to wet the surface to be treated, taking particular preferred is when the contact time is longer than 5 seconds and completely is particularly preferred if after contact no rinsing with water he follows.
  • the treatment temperature is preferably 5 to 95 ° C and is more preferably between 20 and 85 ° C.
  • the preparations to be used according to the invention are for the treatment of surfaces of plastic and / or glass and / or ceramic and / or porcelain and / or quartz and / or granite and / or metal and / or wood used, it being particularly preferred that the treated Surfaces of dishes, windows, tiles, floor coverings, wood and stone surfaces and floors and walls and coated or uncoated tanks or other containers, lines, conveyor belts, containers, such as Refillable bottles made of glass, plastic, such as PET, or textiles come.
  • preparations to be used according to the invention during or after manual or automatic dishwashing and / or dishwashing cleaning operations brought into contact with the surfaces to be treated wherein it is particularly preferred to use the invention Use preparations as rinse aid.
  • Another object of the present invention is a method for purification of surfaces in which, in at least one process step, the surfaces brought into contact with a preparation to be used according to the invention be, with the effect that the treated surfaces after soiling easier to clean in a next cleaning process than that Surfaces that have not come into contact with these preparations.
  • the tank of a one-tank dishwasher (eg Fa. Krefft) is filled with softened water and heated to 60 ° C operating temperature.
  • the cleaning solution is adjusted so that the concentration of Perclin Supra in the tank is 1 g per liter of water.
  • the supply of the dosing device for the rinse aid is connected.
  • the grid position of the dosing device is adjusted so that about 0.57 g of rinse aid per liter of softened water are added.
  • the one-tank dishwasher is set to a consumption of about 5 l softened water.
  • the temperature of the water in the rinse cycle is set to 75 ° C.
  • an about 6% aqueous corn starch containing After being boiled, cool the composition to 75 ° C and leave each dish Apply approx. 4 mL with a brush.
  • the thus treated plates are allowed at least 3 Hours stand and then let the plates for 16 hours at about 100 ° C dry. After cooling, the plates are described as in the following text further treated.
  • the tank of the one-tank dishwasher with turn filled with softened water. 1 liter of dishwasher detergent per liter of softened water Added Perclin Supra.
  • the single-tank dishwasher is set to an operating temperature brought from 60 ° C.
  • the soiled plates will turn introduced in an upright position by means of a dish rack in the dishwasher and the one-tank dishwasher is closed.
  • the ever 60 seconds continuous cleaning step is repeated five times, so that a total of five minutes is cleaned.
  • the dishwasher is opened and the dish rack taken with the dining plates of the dishwasher. The dining plates dry and cool at room temperature.
  • the food plates are used for visualization the remaining starch residue in a short by default by loosening Iodine and potassium iodide immersed in water-prepared iodine solution.
  • the device is filled with about 40 L of softened water. To harden the conditions About 180 g are added to the water when the circulating pump is switched on given to foaming detergents. At the same time you add about 10 g of the each to be examined rinse aid 1 to 4. Under continuous pumping The solution is raised to 60 ° C and the foam height determined via a measuring scale.
  • Treatment with a preparation containing sodium lauryl sulfate and calcium chloride contains, therefore, a visible relief for the cleaning process of Surfaces, as shown in the example of the dining plates.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)

Claims (18)

  1. Utilisation d'une composition aqueuse stable, contenant, sur base de la composition totale,
    A) de 0,2 à 40 % en poids d'un tensioactif moussant, non alcoxylé, contenant des radicaux alkyle, choisi parmi le groupe des
    a) sulfates d'alkyle avec un radical alkyle saturé ou insaturé, ramifié ou linéaire, ayant 8 à 22 atomes de carbone,
    b) glucosides d'alkyle avec un radical alkyle saturé ou insaturé, ramifié ou linéaire, ayant 8 à 22 atomes de carbone,
    c) éthanolamides d'acide gras avec un radical alkyle saturé ou insaturé, ramifié ou linéaire, ayant 8 à 22 atomes de carbone, ainsi que
    B) de 0,1 à 20 % en poids d'un métal bivalent sous forme liée, choisi parmi les composés du calcium ou du magnésium,
       sous forme diluée dans l'eau ou non diluée, pour le traitement de surfaces solides pendant ou après les processus de lavage manuel ou en machine de la vaisselle, comme agent pour améliorer l'aptitude à l'enlèvement des salissures ou contamination ultérieurement appliquées sur les surfaces ainsi traitées.
  2. Utilisation selon la revendication 1, caractérisée en ce que le composé du calcium ou du magnésium présent dans la composition, est choisi parmi le chlorure de calcium, l'acétate de calcium, le chlorure de magnésium et l'acétate de magnésium.
  3. Utilisation selon l'une des revendications 1 ou 2, caractérisée en ce que le laurylsulfate de sodium est présent dans la composition comme tensioactif du groupe a).
  4. Utilisation selon l'une des revendications 1 ou 2, caractérisée en ce que le laurylglucoside est présent dans la composition comme tensioactif du groupe b) .
  5. Utilisation selon l'une des revendications 1 ou 2, caractérisée en ce que le lauryléthanolamide est présent dans la composition comme tensioactif du groupe c) .
  6. Utilisation selon l'une des revendications 1 à 5, caractérisée en ce que la composition contient en outre, un ou plusieurs autres tensioactifs, choisis parmi le groupe des tensioactifs anioniques, cationiques, non ioniques, amphotères, les oxydes d'alkylamine, les composés du silicium et les esters d'acide phosphorique et leurs sels.
  7. Utilisation selon la revendication 6, caractérisée en ce qu'un alkylalcool avec 8 à 22 atomes de carbone dans la chaíne alkyle est présent dans la composition comme autre tensioactif non ionique.
  8. Utilisation selon la revendication 7, caractérisée en ce que l'autre tensioactif non ionique est un tensioactif non ou faiblement moussant, choisi parmi le groupe des éthoxylates/propoxylates mixtes d'alkylalcools ramifiés ou non ramifiés avec 12 à 22 atomes de carbone dans la partie alkyle.
  9. Utilisation selon la revendication 8, caractérisée en ce que l'autre tensioactif non ionique est un tensioactif non ou faiblement moussant, choisi parmi le groupe des méthyl- et/ou butyléthers d'alkylalcools éthoxylés avec 12 à 22 atomes de carbone dans la partie alkyle.
  10. Utilisation selon l'une des revendications 1 à 9, caractérisée en ce que la composition contient en outre, un ou plusieurs composants antimicrobiens, choisis parmi le groupe des alcools, aldéhydes, acides antimicrobiens, esters d'acide carboxylique, amides d'acide, phénols, dérivés de phénol, diphényles, diphénylalcanes, dérivés d'urée, acétals ainsi que formals oxygénés, azotés, benzamidines, isothiazolines, dérivés de phtalimide, dérivés de pyridine, composés tensioactifs antimicrobiens, guanidines, composés amphotères antimicrobiens, quinoléines, le 1,2-dibromo-2,4-dicyanobutane, le carbamate d'iodo-2-propynylbutyle, l'iode, l'iodophore, des peroxydes.
  11. Utilisation selon l'une des revendications 1 à 10, caractérisée en ce que la composition contient en outre, un solvant.
  12. Utilisation selon l'une des revendications 1 à 11, caractérisée en ce que la solution se présente comme une solution stable, un gel ou une pâte.
  13. Utilisation selon l'une des revendications 1 à 12, caractérisée en ce que la composition est préparée à partir d'une forme de présentation non aqueuse et d'une enveloppe soluble dans l'eau, par dissolution dans l'eau.
  14. Utilisation selon l'une des revendications 1 à 13, caractérisée en ce que la surface à traiter est traitée avec la composition non diluée ou diluée, par immersion.
  15. Utilisation selon l'une des revendications 1 à 13, caractérisée en ce que la surface à traiter est traitée avec la composition diluée ou non diluée, par un auxiliaire qui est choisi parmi un pinceau, une éponge, un rouleau, un linge, un chiffon, une brosse, un essuie, une gomme, un balai à franges, une racle, un dispositif de pulvérisation.
  16. Utilisation selon l'une des revendications 1 à 15, caractérisée en ce que les matériaux de la surface à traiter sont choisis parmi les matières plastiques et/ou le verre et/ou la céramique et/ou la porcelaine et/ou le quartz et/ou le granit et/ou un métal et/ou le bois.
  17. Utilisation selon la revendication 16, caractérisée en ce que les surfaces à traiter proviennent de la vaisselle.
  18. Utilisation selon l'une des revendications 1 à 17, caractérisée en ce que la composition est mise en oeuvre comme un produit de rinçage lors du rinçage de la vaisselle.
EP01993668A 2000-11-09 2001-10-31 Traitement de surfaces pour ameliorer temporairement le comportement a l'enlevement de salissures Expired - Lifetime EP1335965B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10055555A DE10055555A1 (de) 2000-11-09 2000-11-09 Behandlung von Oberflächen zur temporären Verbesserung des Schmutzablöseverhaltens
DE10055555 2000-11-09
PCT/EP2001/012635 WO2002038716A1 (fr) 2000-11-09 2001-10-31 Traitement de surfaces pour ameliorer temporairement le comportement a l'enlevement de salissures

Publications (2)

Publication Number Publication Date
EP1335965A1 EP1335965A1 (fr) 2003-08-20
EP1335965B1 true EP1335965B1 (fr) 2005-12-14

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Family Applications (1)

Application Number Title Priority Date Filing Date
EP01993668A Expired - Lifetime EP1335965B1 (fr) 2000-11-09 2001-10-31 Traitement de surfaces pour ameliorer temporairement le comportement a l'enlevement de salissures

Country Status (5)

Country Link
US (1) US20040110657A1 (fr)
EP (1) EP1335965B1 (fr)
AT (1) ATE312898T1 (fr)
DE (2) DE10055555A1 (fr)
WO (1) WO2002038716A1 (fr)

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US9567551B2 (en) 2012-06-22 2017-02-14 Ecolab Usa Inc. Solid rinse aid composition and method of making same
US9011610B2 (en) 2012-06-22 2015-04-21 Ecolab Usa Inc. Solid fast draining/drying rinse aid for high total dissolved solid water conditions
US9982220B2 (en) 2015-05-19 2018-05-29 Ecolab Usa Inc. Efficient surfactant system on plastic and all types of ware
MY176504A (en) * 2015-12-28 2020-08-12 Colgate Palmolive Co Dishwashing pastes
US11155769B2 (en) 2018-07-25 2021-10-26 Ecolab Usa Inc. Rinse aid formulation for cleaning automotive parts
MX2021016078A (es) * 2020-12-30 2022-07-01 Colgate Palmolive Co Composiciones opacas y metodos para las mismas.

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DE19956238A1 (de) * 1999-11-23 2001-06-28 Henkel Ecolab Gmbh & Co Ohg Verwendung von Formulierungen zur Behandlung von Oberflächen zur temporären Verbesserung des Schmutzablöseverhaltens
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CN106318688A (zh) * 2016-08-19 2017-01-11 盐城市艾斯特体育器材有限公司 一种乒乓球拍胶皮清洗液

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DE50108409D1 (de) 2006-01-19
WO2002038716A1 (fr) 2002-05-16
DE10055555A1 (de) 2002-05-29
EP1335965A1 (fr) 2003-08-20
US20040110657A1 (en) 2004-06-10
ATE312898T1 (de) 2005-12-15

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