EP1334306B1

EP1334306B1 - Apparatus and method for transferring a cryogenic fluid

Info

Publication number: EP1334306B1
Application number: EP01990051A
Authority: EP
Inventors: Zbigniew Zurecki; John Herbert Frey; Jean-Philippe Trembley
Original assignee: Air Products and Chemicals Inc
Current assignee: Air Products and Chemicals Inc
Priority date: 2000-11-14
Filing date: 2001-11-08
Publication date: 2005-01-12
Anticipated expiration: 2021-11-08
Also published as: TW536601B; ATE287064T1; EP1334306A2; AU2002228925B2; AU2002228925B9; CN1474920A; BR0115316B1; DE60108415D1; WO2002040915A2; WO2002040915A3; JP4242645B2; AU2892502A; BR0115316A; MXPA03004259A; CA2428777C; DE60108415T2; CA2428777A1; CN1237303C; JP2004514095A

Abstract

A method and apparatus are set forth for transferring a cryogenic fluid. A polymeric, coaxial transfer line is utilized where a first portion of the cryogenic fluid flows through the inner tube while a second portion flows through an annulus between the inner tube and outer tube which annulus is at a lower pressure than the inside tube. In one embodiment, the inner tube is substantially non-porous and the transfer line is preceded by a flow control means to distribute at least part of the first and second portions of the cryogenic fluid to the inner tube and annulus respectively. In a second embodiment, the inner tube is porous with respect to both gas permeation and liquid permeation such that both a gaseous part and a liquid part of the first portion permeates into the annulus to form at least a part of the second portion.

Description

In many cryogenic fluid transfer applications, it is important that the fluid be transferred in a 100% liquid state, or as close to 100% as possible. Conventionally, this required the fluid to be initially phase-separated and/or subcooled in a heat exchanger and/or vacuum jacketing the line to keep it well insulated. Otherwise, the heat leak in the transfer line would cause boil-off, thereby causing flow undulations in the transfer line and resulting in a non-steady, pulsing and generally undesirable flow. Heat leak is particularly a problem for long transfer lines.

The present invention addresses this first concern for cryogenic transfer lines with a coaxial or "tube-in-tube" geometry where a first portion of the cryogenic fluid flows through the inner tube while a second portion flows through an annulus between the inner tube and outer tube which annulus is at a lower pressure than the inside tube. By virtue of this pressure differential, one skilled in the art can appreciate that the liquid in the annulus can provide a refrigeration duty to the liquid inside the inner tube (e.g. such as by boiling) such that this inner liquid is cooled and stays a saturated liquid. Preferably, the liquid is even subcooled slightly such that a "cushion" of refrigeration is available to fight heat leak.

It is also important in many cryogenic fluid transfer applications that the transfer line be lightweight and flexible. This provides for maximum degrees of freedom during installation, operation and maintenance and also enables the line to withstand repeated bending. The present invention addresses this second concern for cryogenic transfer lines by making at least a portion of the line out of a polymeric flexible material.

The prior art does not provide for a cryogenic fluid transfer line that addresses both of these important concerns.

WO 01/63169, considered as closest prior art, discloses a coaxial transfer tube in which cryogenic fluid to be transferred flows through an inner conduit. The walls of the inner conduit allow gaseous cryogen to escape into the annulus between the inner and outer conduits. The outer conduit is sealed at both ends to provide a dosed volume. A vent may be provided to vent some of the gaseous cryogen from the closed volume. Both conduits may be fabricated from flexible polymeric materials.

U.S. 3,696,627 (Longsworth) teaches a liquid cryogen transfer system having a rigid coaxial piping arrangement for subcooling and stabilizing cryogen flow during transfer. U.S. 4,296,610 (Davis), 4,336,689 (Davis), 4,715,187 (Steams) and 5,477,691 (White) teach similar systems.

Chang et al. teaches non-metallic, flexible cryogenic transfer lines for use in cryosurgical systems where the cryogen is used to cool the cryoprobe in a cryosurgical system ("Development of a High-Performance Multiprobe Cryosurgical Device", Biomedical Instrumentation and Technology, Sept./Oct. 1994, pp. 383-390). Due to the heat leak boil-off resulting from the design of the flexible lines in Chang, combined with intrinsically poor insulation, such lines must be short and fed with a substantially subcooled cryogenic liquid (e.g. liquid nitrogen at -214 °C.) in order to work properly. This requires the up-stream usage of complex and expensive cryogenic storage, supply and control systems.

Cryogenic transfer lines are also taught for use in machining applications where the cryogen is used to cool the interface of the cutting tool and the workpiece. See for example U.S. 2,635,399 (West), 5,103,701 (Lundin), 5,509,335 (Emerson), 5,592,863 (Jaskowiak), 5,761,974 (Wagner) and 5,901,623 (Hong). Similar to Chang, such lines must be short and fed with a substantially subcooled cryogenic liquid to combat heat leak boil-off and thus requires an expensive up-stream subcooling system.

U.S. 3,433,028 (Klee) discloses a coaxial system for conveying cryogenic fluids over substantial distances in pure single phase. Using fixed-size, inlet orifices in the cryogenic-conveying inner line, the liquid is admitted to the outer line where it vaporizes when subject to an external heat leak. A thermal sensor-based flow control unit, mounted at the exit end of this coaxial line, chokes the flow of the vapor in the outer line depending on the value of temperature required, usually 10 to 38 °C (50 to 100 °F) more than the boiling point of the liquid in the inner line. As a result, the outer line pressure may be near the cryogenic source pressure, and its vapor always will be warmer than the inner line liquid. Moreover, high heat leaks cannot be fully countered since the amount of liquid admitted to the outer line for evaporation is permanently limited by the fixed-size inlet orifices. These operating principles necessitate the use of high-pressure resistant, non-flexing metal tubes and a thick-wall thermal insulation in the construction of the line.

JP 06210105 A teaches a polymeric coaxial transfer line for non-cryogeriic degassing applications. The tube material characteristics preclude the use of the transfer line in cryogenic applications.

The present invention is a method and apparatus for transferring a cryogenic fluid. An at least part polymeric, coaxial (i.e. "tube-in-tube" geometry) transfer line is utilized where a first portion of the cryogenic fluid flows through an inner conduit while a second portion flows through an annulus between the inner conduit and outer conduit which annulus is at a lower pressure than the inside conduit. In one embodiment, the inner conduit is substantially non-porous and the transfer line is preceded by a flow control means to distribute at least part of the first and second portions of the cryogenic fluid to the inner conduit and annulus respectively. In a second embodiment, a least a portion of the inner conduit is porous with respect to both gas permeation and liquid permeation such that both a gaseous part and a liquid part of the first portion permeates into the annulus to form at least a part of the second portion.

The invention will now be described by way of example only and with reference to Figure 1 which is a schematic drawing of one embodiment of the present invention.

The present invention's polymeric, coaxial transfer line is best illustrated with respect to a general embodiment thereof such as Figure 1's embodiment where the transfer line 22 is preceded by a flow control box 20. Transfer line 22 comprises an inner tube 72 surrounded by an outer tube 74 surrounded by insulation 70 surrounded by flexible protective casing 68. A first portion of the cryogenic fluid flows through the inner tube 72 while a second portion flows through the annulus between the inner tube 72 and outer tube 74. The first portion is at a higher pressure than the second portion.

At least a portion of the transfer line is made of a flexible polymeric material. In one possible embodiment, substantially all of the inner tube 72 and substantially all of the outer tube 74 are made of a flexible, polymeric material. In another possible embodiment, substantially all of the outer tube 74 can be made of a flexible polymeric material while substantially all of the inner tube 72 can be made of a flexible non-polymeric material that does not become brittle at cryogenic temperatures such as (i) copper and its alloys, (ii) aluminium and its alloys, (iii) nickel and its alloys, (iv) austenitic stainless steels, (v) dense graphite or (vi) ceramic fiber textile-woven tubing products. In yet another embodiment, substantially all of the outer tube can be made of a flexible insulating material. In still another embodiment, instead of being tubes, the inner and/or outer conduits could have cross sections that are substantially in the shape of a rectangle, polygon, oval or other regularly shaped geometric figure.

The inner tube can be substantially non-porous such that little, if any, of the second portion of the fluid in the annulus is a result of permeation through the inner tube. Or, at least a portion of the inner tube can have holes drilled into it and/or be porous with respect to both gas permeation and liquid permeation such that both a gaseous part and a liquid part of the first portion permeates into the annulus to form at least a part of the second portion. Or, certain sections of the inner tube, perhaps spaced equally along the length of the inner tube, could be of enhanced porosity.

The transfer line is advantageously preceded by a flow control means to distribute at least part of the first and second portions of the cryogenic fluid to the inner tube and annulus respectively such as flow control box 20 in Figure 1. The flow control means would also typically integrate the means (e.g. valve) to reduce the pressure of the second portion of fluid that is distributed to the annulus, at least a fraction of which second portion of fluid is distributed into the annulus as a liquid. By virtue of this pressure differential, the liquid in the annulus can provide a refrigeration duty to the fluid inside the inner tube. In the case of an at least partially porous inner tube, the permeation from the inner tube into the annulus gas can supplement at least a portion of the fluid distribution performed by the flow control box. The connections and internal components of the flow control box include three on/off (e.g. solenoid) valves (61, 62, 63) and a manual metering valve 64, which valves are in fluid communication with the inlet 30 to the flow control box and adapted to receive and pressure regulate a flow of the cryogenic fluid. A key internal component of flow control box 20 is 3-way coupling 66 which introduces the first and second portions of the cryogenic fluid to the inner tube and annulus respectively. Thread connection 78 connects the 3-way coupling 66 to the outer tube 74. An optional line clamp 76 may be used to clamp the outer tube to the thread connection. Flow control box 20 has an insulated casing and optionally contains insulating filler. Pressure relief valve 84 is optional. On/off

valves

62 and 63 have an internal bypass orifice (86, 88) drilled in their internal wall or valve seat.

At least a fraction of the second portion of fluid in the annulus can be transferred to the transfer destination and/or cooling target along with the liquid stream in the inner tube. Optionally, at least a fraction of the second portion of fluid in the annulus can be vented away from the transfer destination/cooling target. In the former case, this can be accomplished via the use of a coaxial nozzle having an inner conduit in fluid communication with the inner tube of the transfer line and an outer conduit in fluid communication with the annulus of the transfer line. In the latter case where all of the annulus fluid is vented, this would remove the constraint that the flow direction in the annulus be concurrent with the flow direction in the inner tube. Preferably, any nozzle should include thermal shrink connectors to prevent leaks between the interface of the transfer line and nozzle.

Examples of suitable polymeric materials for the present invention's transfer line include carbon-based polymers, carbon-flourine based polymers, co-polymers and composites thereof such as Teflon™ products. (Teflon™ is a registered trademark of E.I. DuPont de Nemours and Company).

Examples of cryogenic fluids that can be transferred by the present invention's transfer line include nitrogen, argon or mixtures thereof.

The present invention's apparatus and method for transferring a cryogenic fluid is particularly suitable for transfer locations and/or cooling targets that require a relatively low flow rate and a rapid liquid response. Examples of such transfer destinations and/or cooling targets for the present invention's transfer line include:

(i) an environmental test chamber used for stress screening electronic components;

(ii) a component to be shrink fitted;

(iii) a specimen holding container used in for biological storage;

(iv) a nitrogen droplet dispenser;

(v) a cutting tool and/or workpiece in a machining application; and

(vi) a cryoprobe in a cryosurgical system.

Claims

A method of transferring a cryogenic fluid utilizing a transfer line comprising an inner conduit surrounded by an outer conduit at least a portion of the transfer line being made of a flexible polymeric material, said method comprising flowing a first portion of the cryogenic fluid through the inner conduit, the first portion being at a higher pressure than a second portion in an annulus between the inner and outer conduits and characterized by flowing the second portion through the annulus, at least a fraction of the second portion of fluid inside the annulus is liquid which provides a refrigeration duty to the first portion of fluid inside the inner conduit.
The method of Claim 1, wherein the outer conduit is a tube and wherein the inner conduit is a tube of substantially non-porous polymeric material.
The method of Claim 1 or 2, wherein at least a portion of the inner conduit is porous with respect to both gas permeation and liquid permeation such that, in use, both a gaseous part and a liquid part of the first portion permeates from the inner conduit into the annulus to form at least a part of the second portion.
The method of Claim 3, wherein certain sections of the inner conduit along the length of the inner conduit are of enhanced porosity.
The method of Claim 1, comprising distributing at least part of the first and second portions of the cryogenic fluid to the inner conduit and annulus respectively by flow control means.
The method of Claim 5, wherein the flow control means is a flow control box comprising:

(i) an inlet adapted to receive the cryogenic fluid;

(ii) a plurality of valves in fluid communication with the inlet and adapted to receive and pressure regulate a flow of the cryogenic fluid wherein at least one of the valves is an on/off valve and at least one of the valves is a metering valve; and

(iii) a three-way coupling having a first end in fluid communication with at least one of the valves and a second end in fluid communication with the transfer line.
The method of Claim 1, comprising transferring at least a fraction of the second portion of fluid in the annulus to a transfer destination and/or cooling target along with the liquid stream in the inner conduit via the use of a coaxial nozzle having an inner conduit in fluid communication with the inner conduit of the transfer line and an outer conduit in fluid communication with the annulus of the transfer line.
The method of Claim 1, comprising venting at least a fraction of the second portion from the annulus away from the transfer destination and/or cooling target.
The method of any of Claims 1 to 8, comprising transferring a cryogenic fluid selected from the group consisting of nitrogen, argon or mixtures thereof.
The method of any of Claims 1 to 9, comprising delivering at least a portion of the cryogenic fluid to a transfer destination and/or cooling target selected from the group consisting of:

(i) an environmental test chamber used for stress screening electronic components;

(ii) a component to be shrink fitted;

(iii) a specimen holding container used in for biological storage;

(iv) a nitrogen droplet dispenser;

(v) a cutting tool and/or workpiece in a machining application; and

(vi) a cryoprobe in a cryosurgical system.
The method of any of Claims 1 to 10, wherein substantially all of the inner conduit and substantially all of the outer conduit are made of a flexible, polymeric material.
The method according to any of Claims 1 to 10, wherein substantially all of the outer conduit is made of a flexible polymeric material while substantially all of the inner conduit is made of a flexible non-polymeric material selected from the group consisting of (i) copper and its alloys, (ii) aluminum and its alloys, (iii) nickel and its alloys, (iv) austenitic stainless steels, (v) dense graphite or (vi) ceramic fiber textile-woven tubing products.
The method of any of Claims 1 to 12, wherein the polymeric material is selected from the group consisting of carbon-flourine based polymers, co-polymers and composites thereof.
A transfer line (22) for transferring a cryogenic fluid comprising an inner conduit (72) surrounded by an outer conduit (74), both being adapted to contain cryogenic fluid, at least a portion of the transfer line (22) being made of a flexible polymeric material, and wherein, the inner conduit (72) is arranged, in use, to contain a flow of a first portion of the cryogenic fluid and the outer conduit (74) is arranged, in use, to contain a second portion of the cryogenic fluid in an annulus between the inner conduit (72) and outer conduits (74), the first portion being, in use, at a higher pressure than the second portion;
and characterised in that,

a) The outer conduit (72) is open at either end and arranged to contain a flow of the second portion along the annulus;

b) at least a fraction of the second portion of fluid inside the annulus is liquid that provides a refrigeration duty to the first portion of fluid inside the inner conduit (72);
The transfer line (22) of Claim 14, wherein the outer conduit (74) is a tube and wherein the inner conduit (72) is a tube made of substantially non-porous polymeric material.
The transfer line (22) of Claim 14, wherein at least a portion of the inner conduit (72) is made of a polymeric material which is porous with respect to both gas permeation and liquid permeation such that, in use, both a gaseous part and a liquid part of the first portion permeates into the annulus to form at least a part of the second portion.
The transfer line (22) of Claim 16, wherein certain sections of the inner conduit (72) along the length of the inner conduit (72) are of enhanced porosity.
The transfer line (22) of Claim 14, wherein, in use, at least a fraction of the second portion is vented from the annulus away from a transfer destination and/or cooling target.
The transfer line (22) of any of Claims 14 to 18, wherein substantially all of the inner conduit (72) and substantially all of the outer conduit (74) are made of a flexible, polymeric material.
The transfer line (22) of any of Claims 14 to 19, wherein substantially all of the outer conduit (74) is made of a flexible polymeric material while substantially all of the inner conduit (72) is made of a flexible non-polymeric material selected from the group consisting of (i) copper and its alloys, (ii) aluminum and its alloys, (iii) nickel and its alloys, (iv) austenitic stainless steels, (v) dense graphite or (vi) ceramic fiber textile-woven tubing products.
The transfer line (22) of Claim 20, wherein substantially all of the outer conduit (74) is made of a flexible polymeric insulating material.
The transfer line (22) of any of Claims 14 to 21, wherein the flexible polymeric material is selected from the group consisting of carbon based polymers, carbon-flourine based polymers, co-polymers and composites thereof.
The transfer line (22) of any of Claims 14 to 22, arranged to transfer, in use, a cryogenic fluid selected from the group consisting of nitrogen, argon or mixtures thereof.
The transfer line (22) of any of Claims 14 to 23, wherein the transfer line (22) is used to deliver at least a portion of the cryogenic fluid to a transfer destination and/or cooling target selected from the group consisting of:

(i) an environmental test chamber used for stress screening electronic components;

(ii) a component to be shrink fitted;

(iii) a specimen holding container used in for biological storage;

(iv) a nitrogen droplet dispenser;

(v) a cutting tool and/or workpiece in a machining application; and

(vi) a cryoprobe in a cryosurgical system.
A transfer apparatus for a cryogenic fluid comprising a transfer line (22) as claimed in any of Claims 14 to 24 and a coaxial nozzle, wherein at least a fraction of the second portion of fluid in the annulus of the transfer line (22) is transferable to a transfer destination and/or cooling target along with the liquid stream in the inner conduit (72) via the coaxial nozzle which has an inner conduit in fluid communication with the inner conduit (72) of the transfer line (22) and an outer conduit in fluid communication with the annulus of the transfer line (22).
A transfer apparatus for cryogenic fluid comprising a transfer line (22) as Claimed in any of Claims 14 to 24 and flow control means (20) which precedes the transfer line (22) to distribute, in use, at least part of the first and second portions of the cryogenic fluid to the inner conduit (72) and annulus respectively.
Apparatus as claimed in Claim 26, wherein the flow control means (20) is a flow control box comprising:

(i) an inlet (30) adapted to receive the cryogenic fluid;

(ii) a plurality of valves (61, 62, 63, 64) in fluid communication with the inlet (30) and adapted to receive and pressure regulate a flow of the cryogenic fluid wherein at least one of the valves is an on/off valve (61, 62, 63) and at least one of the valves is a metering valve (64); and

(iii) a three-way coupling (66) having a first end in fluid communication with at least one of the valves (61, 62, 63, 64) and a second end in fluid communication with the transfer line (22).