EP1329680A1 - Plate-type heat exchanger - Google Patents
Plate-type heat exchanger Download PDFInfo
- Publication number
- EP1329680A1 EP1329680A1 EP02009896A EP02009896A EP1329680A1 EP 1329680 A1 EP1329680 A1 EP 1329680A1 EP 02009896 A EP02009896 A EP 02009896A EP 02009896 A EP02009896 A EP 02009896A EP 1329680 A1 EP1329680 A1 EP 1329680A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- heat exchanger
- exchanger block
- heat
- heat exchange
- exchange passages
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J5/00—Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants
- F25J5/002—Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants for continuously recuperating cold, i.e. in a so-called recuperative heat exchanger
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04284—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams
- F25J3/0429—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using internal refrigeration by open-loop gas work expansion, e.g. of intermediate or oxygen enriched (waste-)streams of feed air, e.g. used as waste or product air or expanded into an auxiliary column
- F25J3/04296—Claude expansion, i.e. expanded into the main or high pressure column
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04333—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using quasi-closed loop internal vapor compression refrigeration cycles, e.g. of intermediate or oxygen enriched (waste-)streams
- F25J3/04339—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using quasi-closed loop internal vapor compression refrigeration cycles, e.g. of intermediate or oxygen enriched (waste-)streams of air
- F25J3/04345—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion using quasi-closed loop internal vapor compression refrigeration cycles, e.g. of intermediate or oxygen enriched (waste-)streams of air and comprising a gas work expansion loop
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04248—Generation of cold for compensating heat leaks or liquid production, e.g. by Joule-Thompson expansion
- F25J3/04375—Details relating to the work expansion, e.g. process parameter etc.
- F25J3/04393—Details relating to the work expansion, e.g. process parameter etc. using multiple or multistage gas work expansion
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
- F25J3/04406—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system
- F25J3/04412—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air using a dual pressure main column system in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F28—HEAT EXCHANGE IN GENERAL
- F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
- F28D9/00—Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
- F28D9/0093—Multi-circuit heat-exchangers, e.g. integrating different heat exchange sections in the same unit or heat-exchangers for more than two fluids
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2205/00—Processes or apparatus using other separation and/or other processing means
- F25J2205/02—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum
- F25J2205/04—Processes or apparatus using other separation and/or other processing means using simple phase separation in a vessel or drum in the feed line, i.e. upstream of the fractionation step
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2245/00—Processes or apparatus involving steps for recycling of process streams
- F25J2245/50—Processes or apparatus involving steps for recycling of process streams the recycled stream being oxygen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2290/00—Other details not covered by groups F25J2200/00 - F25J2280/00
- F25J2290/32—Details on header or distribution passages of heat exchangers, e.g. of reboiler-condenser or plate heat exchangers
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2290/00—Other details not covered by groups F25J2200/00 - F25J2280/00
- F25J2290/42—Modularity, pre-fabrication of modules, assembling and erection, horizontal layout, i.e. plot plan, and vertical arrangement of parts of the cryogenic unit, e.g. of the cold box
Definitions
- the invention relates to a plate heat exchanger for indirect heat exchange of several fluid flows with one heat / coolant in one Heat exchanger block that has a variety of heat exchange passages for the Has heat / coolant, a first fluid stream and a second fluid stream.
- the invention further relates to a method for indirect heat exchange of multiple fluid flows with one heat / coolant in one Heat exchanger block, the heat / cold carrier, a first fluid flow and a second fluid flow through a variety of heat exchange passages.
- the feed air to be separated When air is decomposed at low temperatures, the feed air to be separated must be on the Process temperature are cooled. This is usually done in Main heat exchanger through indirect heat exchange of the feed air with the recovered gas flows.
- the main heat exchanger is usually called Plate heat exchanger designed a variety of Has heat exchange passages for the streams to be treated.
- an air separation plant will have two different air flows Pressure supplied and as gaseous products oxygen, pure nitrogen and impure Recovered nitrogen, five streams must pass through the heat exchanger block become.
- the heat exchanger block must therefore have ten connecting pieces for this Currents, five for the gas inlet and five for the gas outlet.
- the gas flows are then assigned from the respective inlet connection to the Heat exchange passages distributed or those from the Heat exchange passages emerging gas flows into the corresponding Outlet connection merged.
- DE 10021081 therefore proposes for large air separation plants to use split heat exchanger blocks divided by products so that only one fluid flow is passed through each heat exchanger block.
- fluid flows can be carried out without the aforementioned distribution zones routed directly from the connecting piece into the respective heat exchange passages become.
- the object of the present invention is therefore to provide a method and an apparatus for to develop indirect heating or cooling of multiple gas flows which the pressure loss in the heat exchanger is as low as possible.
- a plate heat exchanger solved type mentioned wherein the heat exchanger block a first Has sub-area in which all heat exchange passages for the first fluid flow are arranged, and has a second portion in which all Heat exchange passages for the second fluid flow are arranged, the first and the second partial area do not overlap and the first and the second Part of each extend over the entire height of the heat exchanger block, the height of the heat exchanger block being extended in the direction of the Main flow through the heat exchange passages is.
- the inventive method for indirect heat exchange of several Fluid flows with a heat / coolant in a heat exchanger block, wherein the heat / cold carrier, a first fluid stream and a second fluid stream through one A large number of heat exchange passages are guided, that the first fluid flow only through a first portion of the Heat exchanger blocks is passed and the second fluid flow through only one second portion of the heat exchanger block is passed, the first and the second section does not overlap and the first and the second Part of each extend over the entire height of the heat exchanger block, the height of the heat exchanger block being extended in the direction of the Main flow through the heat exchange passages is.
- the depth, height and width of the heat exchanger block are defined as follows: On Heat exchanger block has a plurality of arranged parallel to each other Partition plates on. The expansion of the heat exchanger block in one direction perpendicular to the partition plates is referred to below as depth. Between Partition plates are usually arranged so-called fins that cover the space between Subdivide two separating plates into several heat exchange passages at least over a large part of the heat exchanger block all in the same direction exhibit. The expansion of the heat exchanger block in the direction of flow through the heat exchange passages characterize its height. This direction is in hereinafter referred to simply as vertical. With width, therefore Expansion of the heat exchanger block in the remaining spatial direction perpendicular to the main flow direction in the heat exchange passages in the plane of the dividing plates.
- a distribution of the fluid flow over the entire cross-sectional area of the Heat exchanger blocks are no longer necessary.
- An integrated heat exchanger block is advantageously used, through which at least two fluid flows, preferably all fluid flows in the indirect Heat exchange can be carried out with one or more heating media.
- At least one Part of the heat exchange passages for the fluid flows is in the direction of Width divided into at least two areas. Preferably all are for the The fluid exchange passages provided are divided accordingly. It is but also possible and sensible, such a division only for a part the fluid flow passages.
- the subdivision is such that the space between two partition plates in which the individual heat exchange passages for the fluid streams run through or Multiple vertical partitions are divided into two or more areas between where no fluid exchange is possible. There are one within a range A large number of heat exchange passages, which are usually caused by vertical, so-called fins are separated from each other. The fins are mainly used for Guide the fluids, however, in contrast to the different areas partition walls, not essential for the insulation of a Heat exchange passage from an adjacent heat exchange passage.
- the division into individual areas can also be carried out cheaply so that the Areas occupy only part of the depth of the heat exchanger block. So for example, it is possible to split the heat exchanger block into two or more Divide strips that extend across the entire height of the heat exchanger block extend and each take up part of the depth or width of the block. at It is also advantageous to use several streams to adjust the width and width of the heat exchanger block to subdivide the depth and provide, for example, four areas, one of which is everyone is in a corner of the heat exchanger block.
- those for the respective extend Fluid flow provided heat exchange passages from one face of the block to the opposite end face and run essentially parallel to each other.
- a collector / distributor attached to the outside of the heat exchanger block, which covers the corresponding area of the end face and a connecting piece for the Has supply or discharge.
- the heat exchange passages are therefore without Cross-sectional tapering in the inlet and outlet via and the flow deflection in the collector / distributor takes place slowly. The pressure loss in the Heat exchanger block and the associated collectors / distributors minimized.
- At least one fluid flow is as low as possible Pressure loss should experience through such a partial area of the invention Head of heat exchanger blocks.
- the invention is advantageous.
- flow through one of the Subregions of the heat exchanger block according to the invention one or more Heating media with which the fluid flow exchanges its heat.
- the invention allows pressure drops in the heat exchanger blocks, measured from the inlet to the outlet, achieve about 70 mbar.
- the conventional heat exchangers in which the Distribution and consolidation of the gas flows between the entry and Outlet connection and the heat exchange passages through a in the Heat exchanger block integrated distribution zone with slanted fins Pressure drop of about 100 mbar when the gas flows with a pressure between 1.2 and 1.8 bar were removed from the low pressure column.
- the invention achieves a reduction in pressure drop of approximately 30 mbar. This means that the low pressure flows are 30 mbar lower Pressure than can otherwise be gained. To maintain the Heat exchange conditions at the main condenser are sufficient if the air after the air compressor is compressed to about 90 mbar lower pressure.
- the invention is particularly suitable in processes in which gas streams, one Have pressure of less than 3.5 bar, preferably between 1.1 and 1.8 bar, in hereinafter referred to as low pressure flows, in indirect heat exchange with a Heat or cold carriers are to be brought. According to the invention, this is done by a portion of the heat exchanger block only one of these Low pressure gas flows, i.e. for each of the gas streams that have a pressure of have less than 3.5 bar, a separate section of the Heat exchanger blocks provided.
- the method according to the invention is preferably used in low-temperature decomposition of application air application.
- Gas streams withdrawn from the double column rectifier have only a small amount Overpressure of about 0.1 to 0.8 bar above atmospheric pressure, so that a reduction the pressure drop is of great importance. This applies analogously to gaseous Argon product, since the crude argon column also operates under relatively low pressure becomes.
- the gas flows with the feed air in indirect are particularly preferred Heat exchange brought.
- the feed air can be divided into several flows through the heat exchanger block at different pressure levels be performed.
- the air supply can be below Pressure column pressure passed through the heat exchanger block and then into the Pressure column can be fed, on the other hand, the feed air can before Heat exchanger block post-compressed and after cooling for cooling be relaxed while working.
- the fluid stream is preferably passed through the heat exchanger block in such a way that he suffers a pressure drop of 120 to 300 mbar, preferably 120 to 200 mbar.
- a pressure drop of 120 to 300 mbar, preferably 120 to 200 mbar.
- FIG. 1 shows a process scheme known from the prior art Cryogenic air separation plant.
- Compressed and cleaned feed air 10 is partly directly one Main heat exchanger 1 supplied, in part 20 by means of a compressor 4 post-compressed, cooled in an aftercooler 5 and then in the Main heat exchanger 1 passed.
- This in the following as turbine air flow 20 designated compressed air is the main heat exchanger 1 at an intermediate point removed, relaxed in an air booster turbine 6 and into the low pressure column 3 one comprising a pressure column 2 and a low pressure column 3 Rectification unit initiated.
- the feed air 10 cooled in the main heat exchanger becomes the pressure column 2 fed to the rectification unit.
- the low pressure column 3 become more gaseous Oxygen 50, gaseous nitrogen 30 and gaseous impure nitrogen 40 as Regeneration gas removed at a pressure of about 1.3 bar.
- pressure nitrogen 60 is drawn off. It is also possible in the Rectification unit to obtain oxygen and nitrogen as liquid products 7, 8.
- the gas streams 30, 40, 50, 60 are fed into the main heat exchanger 1 and against the feed air flow 10 and the turbine air flow 20 by indirect Heat exchange warmed up.
- Figures 2 to 4 show the usual construction of the heat exchanger block 9.
- Figure 2 shows the lamella arrangement in the distribution zones 59 for the Oxygen passages 58, FIG. 3 for the pure nitrogen passages 38 and FIG. 4 correspondingly for the impure nitrogen passages 48.
- the Fluid flows 30, 40, 50 out against the air flow 10 and the turbine air flow 20.
- the distribution of the respective gaseous product among the corresponding ones Heat exchange passages 38, 48, 58 are conventionally carried out via distribution zones 39, 49, 59, which have slanted slats to the gas 30, 40, 50 from the To distribute supply lines to the passages 38, 48, 58 or in order to the gas passages 38, 48, 58 into the corresponding exhaust line merge.
- the distribution zones 39, 49, 59 both lead to a change in the direction of flow as well as cross-sectional changes, which in turn changes the Cause flow velocity. Both have a negative impact on the Block flow and creates an undesirable pressure drop across the Heat exchanger block 9. The pressure drop affects in particular the Gas streams that have a relatively low pressure between 1.1 and 1.8 bar, negative.
- FIG. 5 shows the structure of the main heat exchanger 1 according to the invention
- all streams 10, 20, 30, 40, 50, 60 are shared by one Heat exchanger block 9 out, that is, the main heat exchanger 1 is as integrated heat exchanger.
- the heat exchanger block 9 is off built up a large number of dividing plates parallel to the drawing plane, between which there are a large number of heat exchange passages.
- the expansion of the heat exchanger block 9 is perpendicular to Plane as its depth, its extension in the direction of the Heat exchange passages, which are indicated by arrows in FIGS. 2 to 4, as its height and its extent in the plane of the drawing perpendicular to Flow direction through the heat exchange passages referred to as its width.
- the feed air 10, the high pressure air 20 and that taken from the pressure column 2 gaseous pressurized nitrogen 60 are in the collector / distributor 11, 21, 61 in the Heat exchanger block 9 passed. These are in the heat exchanger block 9 Currents 10, 20, 60 in the usual way, each in one in the drawing shown distribution zone, which has sloping slats, over the entire Distributed width of the heat exchanger block 9, further by vertical Passed heat exchange passages and the respective via a further distribution zone Collectors 12, 22, 62 fed.
- the streams 10, 20, 60 experience pressure losses caused by the Current direction changes and the cross-sectional changes of the individual passages caused.
- the pressure losses of about 100 mbar are at Feed air 10
- the high pressure air 20 and the pressure nitrogen product 60 are not relevant, since these flows have a significantly higher absolute pressure of more than 5 bar exhibit.
- the low-pressure streams 30, 40, 50 one compared to the Atmospheric pressure have only slightly increased pressure, have such Pressure losses, on the other hand, are of great importance.
- the low-pressure flows 30, 40, 50 are therefore not via the distributed over the entire width of the heat exchanger block 9.
- the heat exchanger block 9 is divided in its width by dividing plates 70, so-called side bars, into three areas 33, 43, 53 divided. With each of these areas 33, 43, 53 are at the top and bottom End of the heat exchanger block 9 collector / distributor 31, 41, 51 and 32, 42, 52 connected.
- the collectors / distributors 31, 41, 51 and 32, 42, 52 are semi-cylindrical executed and have a connecting piece for the respective product supply or dissipation.
- the low-pressure stream 30, 40 introduced into the heat exchanger block 9 50 experiences no change in cross-section and no significant changes Current direction change.
- the pressure drop across the heat exchanger block 9 is compared to the pressure drop across a conventional block, such as that shown in FIGS to 4 has been reduced by about 30%. Furthermore, the cost of the Heat exchanger block 9 reduced because of the elaborate lamella cuts for the distribution zones 39, 49, 59 can be dispensed with in FIGS. 2 to 4.
- the new Heat exchanger blocks preferably only have a narrow distribution zone 73 am Entry and exit area of the heat exchange passages 33, 43, 53 are provided.
- the lamellae in the narrow distribution zone 73 are parallel to the ones underneath or arranged above the fins of the heat exchange passages 33, 43, 53, but have a smaller distance from each other. That in collector 31, 41, 51 entering gas thus builds up easily in front of the distribution zone 73, causing a uniform distribution of the gas to all passages of the distribution zone 73 and thus on all heat exchange passages 33, 43, 53 is reached.
- FIG. 6 shows a variant of the heat exchanger according to the invention.
- the heat exchanger block 9 is identical to the block shown in FIG. 5. in the In contrast to FIG. 5, however, there are no individual collectors / distributors 31, 41, 51 or 32, 42, 52 provided, but a the entire end face of the Heat exchanger blocks 9 spanning common collector / distributor 71. Der Space between the end face of the heat exchanger block 9 and the Collector / distributor 71 is corresponding to areas 33, 43, 53 by separating plates 72 divided and each provided with a connecting piece.
- FIGS. 7 and 8 show further embodiments of the invention.
- This Heat exchangers are used for example in air separation processes, where the top section of the low pressure column has been omitted, so that no more low-pressure nitrogen 30 is generated in the low-pressure column. The As a result, low-pressure flows are reduced to impure nitrogen 40 and oxygen 50.
- the main heat exchanger block 9 can thus be made simpler.
- the Heat exchange passages for the low pressure streams 40, 50 are as in the FIGS. 7 and 8 shown, designed according to the invention, the pressure flows 10, 20, 60 are distributed over the corresponding zones in the usual way Heat exchange passages distributed.
- the invention applies to all air separation processes in which at least two Low pressure flows occur, can be used with advantage.
- Air separation process with air circulation or with nitrogen circulation.
- FIG. 9 shows an example of a low-temperature air separation process with a single-turbine air circuit shown.
- the feed air 10 is compressed and as High-pressure air flow 90 led into the skin heat exchanger.
- Part 91 of the High pressure air is drawn from the heat exchanger at an intermediate point, relaxed and partly introduced into the pressure column, the other part 93 through the Heat exchanger 90 returned and added to the feed air 10 again.
- the rest of the high-pressure air 90 is passed as a high-pressure stream 92 directly into the pressure column.
- FIG. 10 shows an air separation process with a two-turbine air circuit and FIG. 12 the corresponding design of the main heat exchanger 9.
- Die Heat exchange passages for the low pressure streams 30, 40, 50 run analogously to 11, the currents 101, 104 which are under higher pressure, 105, 106, as shown in FIG. 12, are passed through the heat exchanger.
Abstract
Description
Die Erfindung betrifft einen Plattenwärmeaustauscher zum indirekten Wärmeaustausch von mehreren Fluidströmen mit einem Wärme-/Kälteträger in einem Wärmeaustauscherblock, der eine Vielzahl von Wärmeaustauschpassagen für den Wärme-/Kälteträger, einen ersten Fluidstrom und einen zweiten Fluidstrom besitzt. Die Erfindung bezieht sich ferner auf ein Verfahren zum indirekten Wärmeaustausch von mehreren Fluidströmen mit einem Wärme-/Kälteträger in einem Wärmeaustauscherblock, wobei der Wärme-/Kälteträger, ein erster Fluidstrom und ein zweiter Fluidstrom durch eine Vielzahl von Wärmeaustauschpassagen geleitet werden.The invention relates to a plate heat exchanger for indirect heat exchange of several fluid flows with one heat / coolant in one Heat exchanger block that has a variety of heat exchange passages for the Has heat / coolant, a first fluid stream and a second fluid stream. The The invention further relates to a method for indirect heat exchange of multiple fluid flows with one heat / coolant in one Heat exchanger block, the heat / cold carrier, a first fluid flow and a second fluid flow through a variety of heat exchange passages.
Bei der Tieftemperaturzerlegung von Luft muss die zu zerlegende Einsatzluft auf die Verfahrenstemperatur abgekühlt werden. Dies erfolgt üblicherweise im Hauptwärmeaustauscher durch indirekten Wärmeaustausch der Einsatzluft mit den gewonnenen Gasströmen. Der Hauptwärmeaustauscher ist in der Regel als Plattenwärmeaustauscher ausgebildet, der eine Vielzahl von Wärmeaustauschpassagen für die zu behandelnden Ströme besitzt.When air is decomposed at low temperatures, the feed air to be separated must be on the Process temperature are cooled. This is usually done in Main heat exchanger through indirect heat exchange of the feed air with the recovered gas flows. The main heat exchanger is usually called Plate heat exchanger designed a variety of Has heat exchange passages for the streams to be treated.
Werden einer Luftzerlegungsanlage beispielsweise zwei Luftströme unterschiedlichen Drucks zugeführt und als gasförmige Produkte Sauerstoff, Reinstickstoff und unreiner Stickstoff gewonnen, müssen durch den Wärmeaustauscherblock fünf Ströme geleitet werden. Der Wärmeaustauscherblock muss daher zehn Anschlussstutzen für diese Ströme, je fünf für den Gasein- und fünf für den Gasaustritt, aufweisen. Die Gasströme werden dann von dem jeweiligen Eintrittsstutzen auf die zugeordneten Wärmeaustauschpassagen verteilt beziehungsweise die aus den Wärmeaustauschpassagen austretenden Gasströme in die entsprechenden Austrittsstutzen zusammengeführt.For example, an air separation plant will have two different air flows Pressure supplied and as gaseous products oxygen, pure nitrogen and impure Recovered nitrogen, five streams must pass through the heat exchanger block become. The heat exchanger block must therefore have ten connecting pieces for this Currents, five for the gas inlet and five for the gas outlet. The gas flows are then assigned from the respective inlet connection to the Heat exchange passages distributed or those from the Heat exchange passages emerging gas flows into the corresponding Outlet connection merged.
Dies wird bisher durch in den Wärmeaustauscherblock integrierte Verteilzonen realisiert. In diesen Verteilzonen sind zumindest ein Teil der Lamellen, die die einzelnen Wärmeaustauschpassagen voneinander abgrenzen, schräg angeordnet, so dass das über den Eintrittsstutzen einströmende Gas in die Wärmeaustauschpassagen geführt wird bzw. dass die aus den Wärmeaustauschpassagen austretende Gasströmung zu dem Austrittsstutzen umgelenkt wird.So far, this has been achieved through distribution zones integrated in the heat exchanger block realized. In these distribution zones there are at least some of the lamellae that form the delimit individual heat exchange passages from one another, arranged obliquely, see above that the gas flowing in via the inlet connection into the heat exchange passages or that the exiting from the heat exchange passages Gas flow is diverted to the outlet port.
Die Strömungsbedingungen werden allerdings in den Verteilzonen stark geändert. Zum einen tritt durch die schräge Ausrichtung der Lamellen eine Änderung der Stromrichtung auf, zum anderen sind die Querschnitte der Wärmeaustauschpassagen in dem Verteilbereich deutlich verringert, wodurch Geschwindigkeitswechsel des durchströmenden Gases verursacht werden. Beide Effekte erzeugen einen unerwünschten Druckabfall in den Wärmeaustauscherblöcken.However, the flow conditions in the distribution zones are changed significantly. To the a change occurs due to the oblique alignment of the slats Current direction on the other are the cross sections of the heat exchange passages significantly reduced in the distribution area, which means that the speed change of the flowing gas are caused. Both effects create one undesirable pressure drop in the heat exchanger blocks.
In der DE 10021081 wird daher vorgeschlagen, bei großen Luftzerlegungsanlagen gesplittete, nach Produkten aufgeteilte Wärmeaustauscherblöcke einzusetzen, so dass durch jeden Wärmeaustauscherblock jeweils nur ein Fluidstrom geführt wird. Die Fluidströme können bei einer derartigen Ausführung ohne die genannten Verteilzonen direkt von den Anschlussstutzen in die jeweiligen Wärmeaustauschpassagen geleitet werden.DE 10021081 therefore proposes for large air separation plants to use split heat exchanger blocks divided by products so that only one fluid flow is passed through each heat exchanger block. The In such an embodiment, fluid flows can be carried out without the aforementioned distribution zones routed directly from the connecting piece into the respective heat exchange passages become.
Dieses Prinzip lässt sich aber nur bei großen Luftzerlegungsanlagen anwenden, bei denen ohnehin mehrere Wärmeaustauscherblöcke benötigt werden. Bei kleineren Luftzerlegungsanlagen, die nur über einen oder zwei Wärmeaustauscherblöcke verfügen, ist der Einsatz von solchen gesplitteten Wärmeaustauscherblöcken nicht sinnvoll.However, this principle can only be applied to large air separation plants where several heat exchanger blocks are needed anyway. With smaller ones Air separation plants that only have one or two heat exchanger blocks have, the use of such split heat exchanger blocks is not meaningful.
Aufgabe vorliegender Erfindung ist es daher, ein Verfahren und eine Vorrichtung zur indirekten Erwärmung oder Abkühlung von mehreren Gasströmen zu entwickeln, bei dem der Druckverlust in dem Wärmeaustauscher möglichst gering ist.The object of the present invention is therefore to provide a method and an apparatus for to develop indirect heating or cooling of multiple gas flows which the pressure loss in the heat exchanger is as low as possible.
Diese Aufgabe wird erfindungsgemäß durch einen Plattenwärmeaustauscher der eingangs genannten Art gelöst, wobei der Wärmeaustauscherblock einen ersten Teilbereich aufweist, in dem alle Wärmeaustauschpassagen für den ersten Fluidstrom angeordnet sind, und einen zweiten Teilbereich aufweist, in dem alle Wärmeaustauschpassagen für den zweiten Fluidstrom angeordnet sind, wobei sich der erste und der zweite Teilbereich nicht überschneiden und sich der erste und der zweite Teilbereich jeweils über die gesamte Höhe des Wärmeaustauscherblocks erstrecken, wobei die Höhe des Wärmeaustauscherblocks dessen Ausdehnung in Richtung der Hauptströmung durch die Wärmeaustauschpassagen ist.This object is achieved by a plate heat exchanger solved type mentioned, wherein the heat exchanger block a first Has sub-area in which all heat exchange passages for the first fluid flow are arranged, and has a second portion in which all Heat exchange passages for the second fluid flow are arranged, the the first and the second partial area do not overlap and the first and the second Part of each extend over the entire height of the heat exchanger block, the height of the heat exchanger block being extended in the direction of the Main flow through the heat exchange passages is.
Das erfindungsgemäße Verfahren zum indirekten Wärmeaustausch von mehreren Fluidströmen mit einem Wärme-/Kälteträger in einem Wärmeaustauscherblock, wobei der Wärme-/Kälteträger, ein erster Fluidstrom und ein zweiter Fluidstrom durch eine Vielzahl von Wärmeaustauschpassagen geleitet werden, zeichnet sich dadurch aus, dass der erste Fluidstrom nur durch einen ersten Teilbereich des Wärmeaustauscherblocks geleitet wird und der zweite Fluidstrom nur durch einen zweiten Teilbereich des Wärmeaustauscherblocks geleitet wird, wobei sich der erste und der zweite Teilbereich nicht überschneiden und sich der erste und der zweite Teilbereich jeweils über die gesamte Höhe des Wärmeaustauscherblocks erstrecken, wobei die Höhe des Wärmeaustauscherblocks dessen Ausdehnung in Richtung der Hauptströmung durch die Wärmeaustauschpassagen ist.The inventive method for indirect heat exchange of several Fluid flows with a heat / coolant in a heat exchanger block, wherein the heat / cold carrier, a first fluid stream and a second fluid stream through one A large number of heat exchange passages are guided, that the first fluid flow only through a first portion of the Heat exchanger blocks is passed and the second fluid flow through only one second portion of the heat exchanger block is passed, the first and the second section does not overlap and the first and the second Part of each extend over the entire height of the heat exchanger block, the height of the heat exchanger block being extended in the direction of the Main flow through the heat exchange passages is.
Tiefe, Höhe und Breite des Wärmeaustauscherblocks sind dabei wie folgt definiert: Ein Wärmeaustauscherblock weist eine Vielzahl von parallel zueinander angeordneten Trennplatten auf. Die Ausdehnung des Wärmeaustauscherblocks in einer Richtung senkrecht zu den Trennplatten wird im Folgenden als Tiefe bezeichnet. Zwischen den Trennplatten sind üblicherweise sogenannte Fins angeordnet, die den Raum zwischen jeweils zwei Trennplatten in mehrere Wärmeaustauschpassagen unterteilen, die zumindest über einen Großteil des Wärmeaustauscherblocks alle dieselbe Richtung aufweisen. Die Ausdehnung des Wärmeaustauscherblocks in Strömungsrichtung durch die Wärmeaustauschpassagen kennzeichnet dessen Höhe. Diese Richtung wird im folgenden der Einfachheit halber als Vertikale bezeichnet. Mit Breite wird folglich die Ausdehnung des Wärmeaustauscherblocks in der verbleibenden Raumrichtung senkrecht zur Hauptströmungsrichtung in den Wärmeaustauschpassagen in der Ebene der Trennplatten bezeichnet.The depth, height and width of the heat exchanger block are defined as follows: On Heat exchanger block has a plurality of arranged parallel to each other Partition plates on. The expansion of the heat exchanger block in one direction perpendicular to the partition plates is referred to below as depth. Between Partition plates are usually arranged so-called fins that cover the space between Subdivide two separating plates into several heat exchange passages at least over a large part of the heat exchanger block all in the same direction exhibit. The expansion of the heat exchanger block in the direction of flow through the heat exchange passages characterize its height. This direction is in hereinafter referred to simply as vertical. With width, therefore Expansion of the heat exchanger block in the remaining spatial direction perpendicular to the main flow direction in the heat exchange passages in the plane of the dividing plates.
Durch die erfindungsgemäße Aufteilung in einzelne Bereiche ist es möglich, auf einen Teil der Verteilzonen zu verzichten. Bestimmte Fluidstrompassagen enden nämlich in einem definierten Bereich der Stirnflächen des Wärmeaustauscherblocks, d.h. der durch die Breite und die Tiefe gekennzeichneten Flächen des Blocks, in dem keine weiteren Fluidstrompassagen enden. Der Anschlussstutzen für diesen Fluidstrom muss daher nur noch mit dem entsprechenden Bereich der Stirnfläche verbunden werden. The division into individual areas according to the invention makes it possible to use one To dispense with part of the distribution zones. Certain fluid flow passages end in a defined area of the end faces of the heat exchanger block, i.e. the areas of the block characterized by the width and depth in which none further fluid flow passages end. The connector for this fluid flow must therefore only be connected to the corresponding area of the end face.
Eine Verteilung des Fluidstromes über die gesamte Querschnittsfläche des Wärmeaustauscherblocks ist nicht mehr notwendig.A distribution of the fluid flow over the entire cross-sectional area of the Heat exchanger blocks are no longer necessary.
Von Vorteil wird ein integrierter Wärmeaustauscherblock eingesetzt, durch den mindestens zwei Fluidströme, vorzugsweise alle Fluidströme im indirekten Wärmeaustausch mit einem oder mehreren Heizmedien geführt werden. Zumindest ein Teil der Wärmeaustauschpassagen für die Fluidströme wird hierbei in Richtung der Breite in mindestens zwei Bereiche aufgeteilt. Vorzugsweise werden alle für die Fluidströme vorgesehenen Wärmeaustauschpassagen entsprechend aufgeteilt. Es ist aber durchaus auch möglich und sinnvoll, eine derartige Aufteilung nur für einen Teil der Fluidstrompassagen vorzunehmen.An integrated heat exchanger block is advantageously used, through which at least two fluid flows, preferably all fluid flows in the indirect Heat exchange can be carried out with one or more heating media. At least one Part of the heat exchange passages for the fluid flows is in the direction of Width divided into at least two areas. Preferably all are for the The fluid exchange passages provided are divided accordingly. It is but also possible and sensible, such a division only for a part the fluid flow passages.
Die Unterteilung erfolgt so, dass der Raum zwischen zwei Trennplatten, in dem die einzelnen Wärmeaustauschpassagen für die Fluidströme verlaufen, durch eine oder mehrere vertikale Trennwände in zwei oder mehrere Bereiche unterteilt wird, zwischen denen kein Fluidaustausch möglich ist. Innerhalb eines Bereichs befinden sich eine Vielzahl von Wärmeaustauschpassagen, die üblicherweise durch vertikal verlaufende, sogenannte Fins voneinander getrennt sind. Die Fins dienen im wesentlichen zur Führung der Fluide, aber, im Gegensatz zu den unterschiedliche Bereiche abtrennenden Trennwänden, nicht zwingend zur Isolierung einer Wärmeaustauschpassage von einer benachbarten Wärmeaustauschpassage.The subdivision is such that the space between two partition plates in which the individual heat exchange passages for the fluid streams run through or Multiple vertical partitions are divided into two or more areas between where no fluid exchange is possible. There are one within a range A large number of heat exchange passages, which are usually caused by vertical, so-called fins are separated from each other. The fins are mainly used for Guide the fluids, however, in contrast to the different areas partition walls, not essential for the insulation of a Heat exchange passage from an adjacent heat exchange passage.
Die Aufteilung in einzelne Bereiche kann ebenso günstig so erfolgen, dass die Bereiche jeweils nur einen Teil der Tiefe des Wärmeaustauscherblocks einnehmen. So ist es beispielsweise möglich, den Wärmeaustauscherblock in zwei oder mehrere Streifen zu unterteilen, die sich über die gesamte Höhe des Wärmeaustauscherblocks erstrecken und jeweils einen Teil der Tiefe oder der Breite des Blocks einnehmen. Bei mehreren Strömen ist es auch günstig, den Wärmeaustauscherblock in der Breite und der Tiefe zu unterteilen und zum Beispiel vier Bereiche vorzusehen, von denen sich jeder in einem Eck des Wärmeaustauscherblocks befindet.The division into individual areas can also be carried out cheaply so that the Areas occupy only part of the depth of the heat exchanger block. So For example, it is possible to split the heat exchanger block into two or more Divide strips that extend across the entire height of the heat exchanger block extend and each take up part of the depth or width of the block. at It is also advantageous to use several streams to adjust the width and width of the heat exchanger block to subdivide the depth and provide, for example, four areas, one of which is everyone is in a corner of the heat exchanger block.
In den erfindungsgemäßen Teilbereichen erstrecken sich die für den jeweiligen Fluidstrom vorgesehenen Wärmeaustauschpassagen von einer Stirnseite des Blocks zur gegenüberliegenden Stirnseite und verlaufen im wesentlichen parallel zueinander. An den beiden Stirnseiten, an denen die Wärmeaustauschpassagen enden, ist jeweils außen an dem Wärmeaustauscherblock ein Sammler/Verteiler angebracht, der den entsprechenden Bereich der Stimfläche abdeckt und einen Anschlussstutzen für die Zu- bzw. Ableitung aufweist. Die Wärmeaustauschpassagen gehen somit ohne Querschnittsverjüngung in die Zu- bzw. Ableitung über und die Strömungsumlenkung in dem Sammler/Verteiler erfolgt langsam. Der Druckverlust in dem Wärmeaustauscherblock und den zugehörigen Sammler/Verteilern wird dadurch minimiert.In the partial areas according to the invention, those for the respective extend Fluid flow provided heat exchange passages from one face of the block to the opposite end face and run essentially parallel to each other. On each of the two end faces where the heat exchange passages end a collector / distributor attached to the outside of the heat exchanger block, which covers the corresponding area of the end face and a connecting piece for the Has supply or discharge. The heat exchange passages are therefore without Cross-sectional tapering in the inlet and outlet via and the flow deflection in the collector / distributor takes place slowly. The pressure loss in the Heat exchanger block and the associated collectors / distributors minimized.
Erfindungsgemäß wird zumindest ein Fluidstrom, der einen möglichst geringen Druckverlust erfahren soll, durch einen solchen erfindungsgemäßen Teilbereich des Wärmeaustauscherblocks geleitet. Insbesondere bei Fluidströmen, die einen Druck von weniger als 3,5 bar, und ganz besonders einen Druck zwischen 1,1 und 1,8 bar, aufweisen, ist die Erfindung von Vorteil. Selbstverständlich strömen durch einen der erfindungsgemäßen Teilbereiche des Wärmeaustauscherblocks ein oder mehrere Heizmedien, mit denen der Fluidstrom seine Wärme austauscht.According to the invention, at least one fluid flow is as low as possible Pressure loss should experience through such a partial area of the invention Head of heat exchanger blocks. Especially with fluid flows that have a pressure of less than 3.5 bar, and especially a pressure between 1.1 and 1.8 bar, have, the invention is advantageous. Of course, flow through one of the Subregions of the heat exchanger block according to the invention one or more Heating media with which the fluid flow exchanges its heat.
Durch die Erfindung lassen sich Druckabfälle in den Wärmeaustauscherblöcken, gemessen vom Eintrittsstutzen bis zum Austrittsstutzen, von etwa 70 mbar erzielen. Demgegenüber tritt bei den herkömmlichen Wärmeaustauschem, bei denen die Verteilung und Zusammenführung der Gasströme zwischen dem Ein- bzw. Austrittsstutzen und den Wärmeaustauschpassagen durch eine in den Wärmeaustauscherblock integrierte Verteilzone mit schräg angeordneten Lamellen ein Druckabfall von etwa 100 mbar auf, wenn die Gasströme mit einem Druck zwischen 1,2 und 1,8 bar aus der Niederdrucksäule entnommen wurden. Auf der drucklosen Seite erreicht man durch die Erfindung eine Verringerung des Druckabfalls von etwa 30 mbar. Das bedeutet, dass die Niederdruckströme mit einem um 30 mbar niedrigeren Druck als sonst gewonnen werden können. Zur Aufrechterhaltung der Wärmeaustauschverhältnisse am Hauptkondensator reicht es dann aus, wenn die Luft nach dem Luftverdichter auf einen etwa 90 mbar niedrigeren Druck verdichtet wird.The invention allows pressure drops in the heat exchanger blocks, measured from the inlet to the outlet, achieve about 70 mbar. In contrast occurs in the conventional heat exchangers, in which the Distribution and consolidation of the gas flows between the entry and Outlet connection and the heat exchange passages through a in the Heat exchanger block integrated distribution zone with slanted fins Pressure drop of about 100 mbar when the gas flows with a pressure between 1.2 and 1.8 bar were removed from the low pressure column. On the unpressurized On the one hand, the invention achieves a reduction in pressure drop of approximately 30 mbar. This means that the low pressure flows are 30 mbar lower Pressure than can otherwise be gained. To maintain the Heat exchange conditions at the main condenser are sufficient if the air after the air compressor is compressed to about 90 mbar lower pressure.
Besonders geeignet ist die Erfindung bei Verfahren, bei denen Gasströme, die einen Druck von weniger als 3,5 bar, bevorzugt zwischen 1,1 und 1,8 bar, aufweisen, im folgenden als Niederdruckströme bezeichnet, in indirekten Wärmeaustausch mit einem Wärme- oder Kälteträger gebracht werden sollen. Erfindungsgemäß wird hierbei durch einen Teilbereich des Wärmertauscherblocks jeweils nur einer dieser Niederdruckgasströme geführt, d.h. für jeden der Gasströme, die einen Druck von weniger als 3,5 bar aufweisen, wird ein eigener Teilbereich des Wärmeaustauscherblocks vorgesehen.The invention is particularly suitable in processes in which gas streams, one Have pressure of less than 3.5 bar, preferably between 1.1 and 1.8 bar, in hereinafter referred to as low pressure flows, in indirect heat exchange with a Heat or cold carriers are to be brought. According to the invention, this is done by a portion of the heat exchanger block only one of these Low pressure gas flows, i.e. for each of the gas streams that have a pressure of have less than 3.5 bar, a separate section of the Heat exchanger blocks provided.
Bei Gasströmen mit einem Druck von mehr als ca. 4 bar spielt der Druckverlust in dem Wärmeaustauscherblock nur eine untergeordnete Rolle bzw. kann vernachlässigt werden. Es ist daher manchmal vorteilhaft, durch mindestens einen der Teilbereiche des Wärmeaustauscherblocks, durch den einer der Niederdruckgasströme geleitet wird, zusätzlich einen solchen Strom mit erhöhtem Druck zu führen.With gas flows with a pressure of more than approx. 4 bar, the pressure loss plays in the Heat exchanger block only a subordinate role or can be neglected become. It is therefore sometimes advantageous to go through at least one of the sub-areas of the heat exchanger block through which one of the low pressure gas flows is passed will also carry such a stream with increased pressure.
Das erfindungsgemäße Verfahren findet bevorzugt bei der Tieftemperaturzerlegung von Einsatzluft Anwendung. Die als Produkt aus der Niederdrucksäule eines Doppelsäulenrektifikators abgezogenen Gasströme besitzen lediglich einen geringen Überdruck von etwa 0,1 bis 0,8 bar über Atmosphärendruck, sodass eine Verringerung des Druckabfalls von hoher Bedeutung ist. Dies gilt in analoger Weise für gasförmiges Argonprodukt, da die Rohargonsäule ebenfalls unter relativ niedrigem Druck betrieben wird.The method according to the invention is preferably used in low-temperature decomposition of application air application. The as a product from the low pressure column Gas streams withdrawn from the double column rectifier have only a small amount Overpressure of about 0.1 to 0.8 bar above atmospheric pressure, so that a reduction the pressure drop is of great importance. This applies analogously to gaseous Argon product, since the crude argon column also operates under relatively low pressure becomes.
Besonders bevorzugt werden die Gasströme mit der Einsatzluft in indirekten Wärmeaustausch gebracht. Die Einsatzluft kann hierbei in mehreren auf unterschiedlichem Druckniveau liegenden Strömen durch den Wärmeaustauscherblock geführt werden. So kann die Einsatzluft beispielsweise zum einen unter Drucksäulendruck durch den Wärmeaustauscherblock geleitet und anschließend in die Drucksäule eingespeist werden, zum anderen kann die Einsatzluft vor dem Wärmeaustauscherblock nachverdichtet und nach Abkühlung zur Kälteerzeugung arbeitsleistend entspannt werden.The gas flows with the feed air in indirect are particularly preferred Heat exchange brought. The feed air can be divided into several flows through the heat exchanger block at different pressure levels be performed. For example, the air supply can be below Pressure column pressure passed through the heat exchanger block and then into the Pressure column can be fed, on the other hand, the feed air can before Heat exchanger block post-compressed and after cooling for cooling be relaxed while working.
In Ländern mit relativ niedrigen Energiekosten bringt eine Verringerung der Druckabfälle keinen Vorteil, da die mit der Energieeinsparung verbundenen Kosten hoch sind. Bei diesen Anwendungen ist es daher günstiger, nicht die Druckverluste zu minimieren, sondern die Strömungsgeschwindigkeiten zu erhöhen, um höhere Druckabfälle zu erzielen, wodurch letztlich ein kleinerer Wärmeaustauscherblock ausreichend ist. In countries with relatively low energy costs brings a reduction in Pressure drops are not an advantage because of the costs associated with saving energy are high. In these applications, it is therefore cheaper not to lose pressure minimize, but rather increase the flow velocities to higher ones Achieve pressure drops, ultimately resulting in a smaller heat exchanger block is sufficient.
Vorzugsweise wird der Fluidstrom so durch den Wärmeaustauscherblock geleitet, dass er einen Druckabfall von 120 bis 300 mbar, bevorzugt 120 bis 200 mbar, erleidet. Durch Anhebung des Druckabfalls wird eine größere Strömungsgeschwindigkeit als in den herkömmlichen Wärmeaustauschern erreicht, wodurch die Wärmeübergangszahlen verbessert werden, was letztlich dazu führt, dass das Blockvolumen des Wärmeaustauschers verringert werden kann. Bei gleichem Druckabfall im Wärmeaustauscherblock ermöglicht das erfindungsgemäße Verfahren gegenüber den bekannten Verfahren eine Reduktion der Blockvolumina um etwa 15%, woraus eine beträchtliche Kosteneinsparung resultiert.The fluid stream is preferably passed through the heat exchanger block in such a way that he suffers a pressure drop of 120 to 300 mbar, preferably 120 to 200 mbar. By increasing the pressure drop, a greater flow velocity than in reached the conventional heat exchangers, whereby the Heat transfer numbers are improved, which ultimately leads to that Block volume of the heat exchanger can be reduced. With the same The method according to the invention enables pressure drop in the heat exchanger block a reduction of the block volumes by about 15% compared to the known methods, which results in considerable cost savings.
Die Erfindung sowie weitere Einzelheiten der Erfindung werden im Folgenden anhand von in den Zeichnungen dargestellten Ausführungsbeispielen näher erläutert. Hierbei zeigen:
- Figur 1
- ein Verfahrensschema einer Tieftemperaturluftzerlegungsanlage,
Figuren 2bis 4- die Anordnung der Verteilpassagen in herkömmlichen Plattenwärmeaustauschem,
Figur 5- die Anordnung der Wärmeaustauschpassagen gemäß der Erfindung,
- Figur 6
- eine Variante der Ausführung nach Figur 5,
Figuren 7 und 8- die erfindungsgemäße Aufteilung des Wärmeaustauischers in zwei Teilbereiche,
Figur 9- das Verfahrensschema einer Luftzerlegungsanlage mit Ein-Turbinen-Luftkreislauf,
Figur 10- das Verfahrensschema einer Luftzerlegungsanlage mit Zwei-Turbinen-Luftkreislauf,
Figur 11- die erfindungsgemäße Anordnung der Wärmeaustauschpassagen
des Hauptwärmeaustauschers bei dem
Verfahren nach Figur 9 und Figur 12- die erfindungsgemäße Anordnung der Wärmeaustauschpassagen
des Hauptwärmeaustauschers bei dem
Verfahren nach Figur 10.
- Figure 1
- a process diagram of a cryogenic air separation plant,
- Figures 2 to 4
- the arrangement of the distribution passages in conventional plate heat exchangers,
- Figure 5
- the arrangement of the heat exchange passages according to the invention,
- Figure 6
- a variant of the embodiment of Figure 5,
- Figures 7 and 8
- the inventive division of the heat exchanger into two sub-areas,
- Figure 9
- the process diagram of an air separation plant with a single-turbine air circuit,
- Figure 10
- the process diagram of an air separation plant with a two-turbine air circuit,
- Figure 11
- the arrangement according to the invention of the heat exchange passages of the main heat exchanger in the method according to FIGS. 9 and
- Figure 12
- the arrangement according to the invention of the heat exchange passages of the main heat exchanger in the method according to FIG. 10.
Figur 1 zeigt ein aus dem Stand der Technik bekanntes Verfahrensschema einer Tieftemperaturluftzerlegungsanlage. FIG. 1 shows a process scheme known from the prior art Cryogenic air separation plant.
Verdichtete und gereinigte Einsatzluft 10 wird zum Teil direkt einem
Hauptwärmeaustauscher 1 zugeführt, zum Teil 20 mittels eines Verdichters 4
nachverdichtet, in einem Nachkühler 5 gekühlt und dann in den
Hauptwärmeaustauscher 1 geleitet. Diese im folgenden als Turbinenluftstrom 20
bezeichnete Druckluft wird an einer Zwischenstelle dem Hauptwärmeaustauscher 1
entnommen, in einer Luftbooster-Turbine 6 entspannt und in die Niederdrucksäule 3
einer eine Drucksäule 2 und eine Niederdrucksäule 3 umfassenden
Rektifikationseinheit eingeleitet.Compressed and cleaned
Die in dem Hauptwärmeaustauscher abgekühlte Einsatzluft 10 wird der Drucksäule 2
der Rektifikationseinheit zugeführt. Der Niederdrucksäule 3 werden gasförmiger
Sauerstoff 50, gasförmiger Stickstoff 30 sowie gasförmiger Unrein-Stickstoff 40 als
Regeneriergas mit einem Druck von etwa 1,3 bar entnommen. Am Kopf der
Drucksäule 2 wird Druckstickstoff 60 abgezogen. Ferner ist es möglich, in der
Rektifikationseinheit Sauerstoff und Stickstoff als flüssige Produkte 7, 8 zu gewinnen.
Die Gasströme 30, 40, 50, 60 werden in den Hauptwärmeaustauscher 1 geführt und
gegen den Einsatzluftstrom 10 und den Turbinenluftstrom 20 durch indirekten
Wärmeaustausch angewärmt.The
Die Figuren 2 bis 4 zeigen den bisher üblichen Aufbau des Wärmeaustauscherblocks
9. Figur 2 zeigt die Lamellenanordnung in den Verteilzonen 59 für die
Sauerstoffpassagen 58, Figur 3 für die Reinstickstoffpassagen 38 und Figur 4
entsprechend für die Unreinstickstoffpassagen 48.Figures 2 to 4 show the usual construction of the
Bei dem Verfahren gemäß Figur 1 werden in dem Wärmeaustauscherblock 9 die
Fluidströme 30, 40, 50 gegen den Luftstrom 10 und den Turbinenluftstrom 20 geführt.
Die Verteilung des jeweiligen gasförmigen Produktes auf die entsprechenden
Wärmeaustauschpassagen 38, 48, 58 erfolgt herkömmlich über Verteilzonen 39, 49,
59, die schräg angeordnete Lamellen aufweisen, um das Gas 30, 40, 50 aus den
Zufuhrleitungen auf die Passagen 38, 48, 58 zu verteilen beziehungsweise um das aus
den Passagen 38, 48, 58 austretende Gas in die entsprechende Abzugsleitung
zusammenzuführen. In the method according to FIG. 1, the
Fluid flows 30, 40, 50 out against the
Die Verteilzonen 39, 49, 59 führen sowohl zu einer Änderung der Strömungsrichtung
als auch zu Querschnittsveränderungen, welche wiederum Änderungen der
Strömungsgeschwindigkeit verursachen. Beides wirkt sich negativ auf die
Blockdurchströmung aus und erzeugt einen unerwünschten Druckabfall über dem
Wärmeaustauscherblock 9. Der Druckabfall wirkt sich insbesondere bei den
Gasströmen, die einen relativ niedrigen Druck zwischen 1,1 und 1,8 bar besitzen,
negativ aus.The
Figur 5 zeigt den erfindungsgemäßen Aufbau des Hauptwärmeaustauschers 1. In
diesem Fall werden alle Ströme 10, 20, 30, 40, 50, 60 durch einen gemeinsamen
Wärmeaustauscherblock 9 geführt, das heißt der Hauptwärmeaustauscher 1 ist als
integrierter Wärmeaustauscher ausgeführt. Der Wärmeaustauscherblock 9 ist aus
einer Vielzahl von parallel zur Zeichenebene liegenden Trennplatten aufgebaut,
zwischen denen sich jeweils eine Vielzahl von Wärmeaustauschpassagen befinden.FIG. 5 shows the structure of the main heat exchanger 1 according to the invention
In this case, all
Im folgenden wird die Ausdehnung des Wärmeaustauscherblocks 9 senkrecht zur
Zeichenebene als dessen Tiefe, seine Ausdehnung in Richtung der
Wärmeaustauschpassagen, die in den Figuren 2 bis 4 durch Pfeile gekennzeichnet ist,
als dessen Höhe und seine Ausdehnung in der Zeichenebene senkrecht zur
Strömungsrichtung durch die Wärmeaustauschpassagen als dessen Breite bezeichnet.In the following, the expansion of the
Die Einsatzluft 10, die Hochdruckluft 20 und der der Drucksäule 2 entnommene
gasförmige Druckstickstoff 60 werden über die Sammler/Verteiler 11, 21, 61 in den
Wärmeaustauscherblock 9 geleitet. Im Wärmeaustauscherblock 9 werden diese
Ströme 10, 20, 60 in üblicher Weise jeweils in einer in der Zeichnung nicht
dargestellten Verteilzone, die schräg verlaufende Lamellen aufweist, über die gesamte
Breite des Wärmeaustauscherblocks 9 verteilt, weiter durch senkrecht verlaufende
Wärmeaustauschpassagen geleitet und über eine weitere Verteilzone den jeweiligen
Sammlern 12, 22, 62 zugeführt.The
In den Verteilzonen erfahren die Ströme 10, 20, 60 Druckverluste, die durch die
Stromrichtungsänderungen und die Querschnittsänderungen der einzelnen Passagen
verursacht werden. Die Druckverluste von etwa 100 mbar sind jedoch bei der
Einsatzluft 10, der Hochdruckluft 20 und dem Druckstickstoffprodukt 60 nicht relevant,
da diese Ströme einen deutlich höheren absoluten Druck von mehr als 5 bar
aufweisen. Bei den Niederdruckströmen 30, 40, 50, die einen gegenüber dem
Atmosphärendruck nur geringfügig erhöhten Druck besitzen, haben solche
Druckverluste dagegen eine hohe Bedeutung.In the distribution zones, the
Erfindungsgemäß werden daher die Niederdruckströme 30, 40, 50 nicht über die
gesamte Breite des Wärmeaustauscherblocks 9 verteilt. Der Wärmeaustauscherblock
9 ist in seiner Breite durch Trennbleche 70, sogenannte side bars, in drei Bereiche 33,
43, 53 unterteilt. Mit jedem dieser Bereiche 33, 43, 53 sind am oberen und unteren
Ende des Wärmeaustauscherblocks 9 Sammler/Verteiler 31, 41, 51 bzw. 32, 42, 52
verbunden. Die Sammler/Verteiler 31, 41, 51 bzw. 32, 42, 52 sind halbzylindrisch
ausgeführt und besitzen einen Anschlussstutzen für die jeweilige Produktzu- bzw. -
ableitung. Der in den Wärmeaustauscherblock 9 eingeleitete Niederdruckstrom 30, 40,
50 erfährt keinerlei Querschnittsveränderung und keine wesentliche
Stromrichtungsänderung. Der Druckabfall über dem Wärmeaustauscherblock 9 ist
gegenüber dem Druckabfall über einem üblichen Block, wie er anhand der Figuren 2
bis 4 erläutert wurde, um etwa 30% verringert. Ferner werden die Kosten für den
Wärmeaustauscherblock 9 reduziert, da auf die aufwendigen Lamellenzuschnitte für
die Verteilzonen 39, 49, 59 in den Figuren 2 bis 4 verzichtet werden kann.According to the invention, the low-pressure flows 30, 40, 50 are therefore not via the
distributed over the entire width of the
Anstelle der aufwendigen Verteilzonen 39, 49, 59 mit schrägen Lamellen in den
bekannten Wärmeaustauscherblöcken (siehe Figuren 2 bis 4) ist bei den neuen
Wärmeaustauscherblöcken bevorzugt lediglich eine schmale Verteilzone 73 am
Eintritts- und Austrittsbereich der Wärmeaustauschpassagen 33, 43, 53 vorgesehen.
Die Lamellen in der schmalen Verteilzone 73 sind parallel zu den darunter bzw.
darüber liegenden Lamellen der Wärmeaustauschpassagen 33, 43, 53 angeordnet,
besitzen jedoch einen geringeren Abstand voneinander. Das in den Sammler 31, 41,
51 eintretende Gas staut sich dadurch leicht vor der Verteilzone 73, wodurch eine
gleichmäßige Verteilung des Gases auf alle Passagen der Verteilzone 73 und damit
auf alle Wärmeaustauschpassagen 33, 43, 53 erreicht wird.Instead of the
In Figur 6 ist eine Variante des erfindungsgemäßen Wärmeaustauschers dargestellt.
Der Wärmeaustauscherblock 9 ist identisch zu dem in Figur 5 gezeigten Block. Im
Gegensatz zu Figur 5 sind jedoch keine einzelnen Sammler/Verteiler 31, 41, 51 bzw.
32, 42, 52 vorgesehen, sondern ein die gesamte Stirnfläche des
Wärmeaustauscherblocks 9 überspannender gemeinsamer Sammler/Verteiler 71. Der
Raum zwischen der Stirnfläche des Wärmeaustauscherblocks 9 und dem
Sammler/Verteiler 71 ist entsprechend den Bereichen 33, 43, 53 durch Trennbleche 72
unterteilt und jeweils mit einem Anschlussstutzen versehen.FIG. 6 shows a variant of the heat exchanger according to the invention.
The
Die Figuren 7 und 8 zeigen weitere Ausführungsformen der Erfindung. Diese
Wärmeaustauscher kommen beispielsweise bei Luftzerlegungsverfahren zum Einsatz,
bei denen bei der Niederdrucksäule auf den obersten Abschnitt verzichtet wurde, so
dass in der Niederdrucksäule kein Niederdruckstickstoff 30 mehr erzeugt wird. Die
Niederdruckströme reduzieren sich dadurch auf den Unreinstickstoff 40 und Sauerstoff
50. Damit kann der Hauptwärmeaustauscherblock 9 einfacher gestaltet werden. Die
Wärmeaustauschpassagen für die Niederdruckströme 40, 50 werden, wie in den
Figuren 7 und 8 gezeigt, erfindungsgemäß gestaltet, die Druckströme 10, 20, 60
werden in üblicher Weise über Verteilzonen auf die entsprechenden
Wärmeaustauschpassagen verteilt.FIGS. 7 and 8 show further embodiments of the invention. This
Heat exchangers are used for example in air separation processes,
where the top section of the low pressure column has been omitted, so
that no more low-
Die Erfindung ist bei allen Luftzerlegungsverfahren, bei denen mindestens zwei Niederdruckströme vorkommen, mit Vorteil einsetzbar. So zum Beispiel bei Luftzerlegunsgverfahren mit Luftkreislauf oder mit Stickstoffkreislauf.The invention applies to all air separation processes in which at least two Low pressure flows occur, can be used with advantage. For example at Air separation process with air circulation or with nitrogen circulation.
In Figur 9 ist beispielhaft ein Tieftemperatur-Luftzerlegungsverfahren mit Ein-Turbinen-Luftkreislauf
dargestellt. Die Einsatzluft 10 wird hierbei verdichtet und als
Hochdruckluftstrom 90 in den Hautpwärmeaustauscher geführt. Ein Teil 91 der
Hochdruckluft wird an einer Zwischenstelle von dem Wärmeaustauscher abgezogen,
entspannt und zum Teil in die Drucksäule eingeleitet, zum anderen Teil 93 durch den
Wärmeaustauscher 90 zurückgeführt und der Einsatzluft 10 wieder zugegeben. Der
Rest der Hochdruckluft 90 wird als Hochdruckstrom 92 direkt in die Drucksäule geleitet.FIG. 9 shows an example of a low-temperature air separation process with a single-turbine air circuit
shown. The
In Figur 11 ist die erfindungsgemäße Ausführung des Wärmeaustauscherblocks 9 für
ein derartiges Verfahren dargestellt. Die Niederdruckströme 30, 40, 50 werden
wiederum durch die entsprechenden erfindungsgemäßen Teilbereiche des Blocks 9
geführt, die druckbehafteten Ströme 60, 90, 93 werden in bekannter Weise über
Verteilzonen auf die Wärmeaustauschpassagen verteilt.In Figure 11, the inventive design of the
Figur 10 zeigt ein Luftzerlegungsverfahren mit Zwei-Turbinen-Luftkreislauf und Figur 12
die entsprechende Ausgestaltung des Hauptwärmeaustauschers 9. Die
Wärmeaustauschpassagen für die Niederdruckströme 30, 40, 50 verlaufen analog zu
der Ausführung gemäß Figur 11, die unter höherem Druck stehenden Ströme 101, 104,
105, 106 werden, wie in Figur 12 dargestellt, durch den Wärmeaustauscher geführt.FIG. 10 shows an air separation process with a two-turbine air circuit and FIG. 12
the corresponding design of the
Claims (10)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10201832A DE10201832A1 (en) | 2002-01-18 | 2002-01-18 | Plate heat exchanger |
DE10201832 | 2002-01-18 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1329680A1 true EP1329680A1 (en) | 2003-07-23 |
EP1329680B1 EP1329680B1 (en) | 2011-01-26 |
Family
ID=7712498
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02009896A Expired - Lifetime EP1329680B1 (en) | 2002-01-18 | 2002-05-02 | Plate-type heat exchanger |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP1329680B1 (en) |
AT (1) | ATE497138T1 (en) |
DE (2) | DE10201832A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2645038A1 (en) * | 2012-03-29 | 2013-10-02 | Linde Aktiengesellschaft | Plate heat exchanger with multiple modules connected with profiles |
EP2645037A1 (en) * | 2012-03-29 | 2013-10-02 | Linde Aktiengesellschaft | Plate heat exchanger with multiple modules connected with metal strips |
WO2017074544A1 (en) * | 2015-10-27 | 2017-05-04 | Praxair Technology, Inc. | System and method for providing refrigeration to a cryogenic separation unit |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3282334A (en) * | 1963-04-29 | 1966-11-01 | Trane Co | Heat exchanger |
US3759322A (en) * | 1970-10-01 | 1973-09-18 | Linde Ag | Heat exchanger |
US4128410A (en) * | 1974-02-25 | 1978-12-05 | Gulf Oil Corporation | Natural gas treatment |
US5205351A (en) * | 1991-04-03 | 1993-04-27 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Process for vaporizing a liquid, heat exchanger therefor, and application thereof to an apparatus for air distillation with a double column |
US5979182A (en) * | 1997-03-13 | 1999-11-09 | Kabushiki Kaisha Kobe Seiko Sho | Method of and apparatus for air separation |
-
2002
- 2002-01-18 DE DE10201832A patent/DE10201832A1/en not_active Withdrawn
- 2002-05-02 AT AT02009896T patent/ATE497138T1/en active
- 2002-05-02 DE DE50214880T patent/DE50214880D1/en not_active Expired - Lifetime
- 2002-05-02 EP EP02009896A patent/EP1329680B1/en not_active Expired - Lifetime
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3282334A (en) * | 1963-04-29 | 1966-11-01 | Trane Co | Heat exchanger |
US3759322A (en) * | 1970-10-01 | 1973-09-18 | Linde Ag | Heat exchanger |
US4128410A (en) * | 1974-02-25 | 1978-12-05 | Gulf Oil Corporation | Natural gas treatment |
US5205351A (en) * | 1991-04-03 | 1993-04-27 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Process for vaporizing a liquid, heat exchanger therefor, and application thereof to an apparatus for air distillation with a double column |
US5979182A (en) * | 1997-03-13 | 1999-11-09 | Kabushiki Kaisha Kobe Seiko Sho | Method of and apparatus for air separation |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2645038A1 (en) * | 2012-03-29 | 2013-10-02 | Linde Aktiengesellschaft | Plate heat exchanger with multiple modules connected with profiles |
EP2645037A1 (en) * | 2012-03-29 | 2013-10-02 | Linde Aktiengesellschaft | Plate heat exchanger with multiple modules connected with metal strips |
CN103363823A (en) * | 2012-03-29 | 2013-10-23 | 林德股份公司 | A plate heat exchanger with multiple modules connected with profiles |
US9335102B2 (en) | 2012-03-29 | 2016-05-10 | Linde Aktiengesellschaft | Plate heat exchanger with several modules connected by sheet-metal strips |
CN103363823B (en) * | 2012-03-29 | 2017-03-01 | 林德股份公司 | There is the heat-exchangers of the plate type of the module of multiple section bar connections |
US10605536B2 (en) | 2012-03-29 | 2020-03-31 | Linde Aktiengesellschaft | Plate heat exchanger with several modules connected by sections |
WO2017074544A1 (en) * | 2015-10-27 | 2017-05-04 | Praxair Technology, Inc. | System and method for providing refrigeration to a cryogenic separation unit |
US10295252B2 (en) | 2015-10-27 | 2019-05-21 | Praxair Technology, Inc. | System and method for providing refrigeration to a cryogenic separation unit |
Also Published As
Publication number | Publication date |
---|---|
DE10201832A1 (en) | 2003-07-31 |
DE50214880D1 (en) | 2011-03-10 |
ATE497138T1 (en) | 2011-02-15 |
EP1329680B1 (en) | 2011-01-26 |
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