EP1316845B1 - Thermographisches Aufzeichnungsmaterial mit verbesserter Entwickelbarkeit - Google Patents
Thermographisches Aufzeichnungsmaterial mit verbesserter Entwickelbarkeit Download PDFInfo
- Publication number
- EP1316845B1 EP1316845B1 EP02102623A EP02102623A EP1316845B1 EP 1316845 B1 EP1316845 B1 EP 1316845B1 EP 02102623 A EP02102623 A EP 02102623A EP 02102623 A EP02102623 A EP 02102623A EP 1316845 B1 EP1316845 B1 EP 1316845B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- recording material
- silver salt
- dispersion
- silver
- organic silver
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000463 material Substances 0.000 title claims description 113
- 230000001976 improved effect Effects 0.000 title description 5
- 239000006185 dispersion Substances 0.000 claims description 109
- 229910052709 silver Inorganic materials 0.000 claims description 99
- 239000004332 silver Substances 0.000 claims description 99
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 claims description 98
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 79
- -1 silver halide Chemical class 0.000 claims description 55
- 239000003638 chemical reducing agent Substances 0.000 claims description 42
- 239000003795 chemical substances by application Substances 0.000 claims description 39
- 239000002082 metal nanoparticle Substances 0.000 claims description 32
- 238000000034 method Methods 0.000 claims description 30
- 239000011230 binding agent Substances 0.000 claims description 22
- 238000000576 coating method Methods 0.000 claims description 20
- 239000011248 coating agent Substances 0.000 claims description 19
- 230000008569 process Effects 0.000 claims description 19
- 229910052751 metal Inorganic materials 0.000 claims description 14
- 239000002184 metal Substances 0.000 claims description 14
- 230000001965 increasing effect Effects 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 6
- IJAPPYDYQCXOEF-UHFFFAOYSA-N phthalazin-1(2H)-one Chemical group C1=CC=C2C(=O)NN=CC2=C1 IJAPPYDYQCXOEF-UHFFFAOYSA-N 0.000 claims description 4
- 239000000956 alloy Substances 0.000 claims description 3
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 3
- 229910052737 gold Inorganic materials 0.000 claims description 3
- 239000010931 gold Substances 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 239000010409 thin film Substances 0.000 claims description 3
- 150000005130 benzoxazines Chemical class 0.000 claims 2
- 239000002245 particle Substances 0.000 description 68
- AQRYNYUOKMNDDV-UHFFFAOYSA-M silver behenate Chemical compound [Ag+].CCCCCCCCCCCCCCCCCCCCCC([O-])=O AQRYNYUOKMNDDV-UHFFFAOYSA-M 0.000 description 46
- 239000000243 solution Substances 0.000 description 38
- 230000000052 comparative effect Effects 0.000 description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 30
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 29
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 24
- 239000010410 layer Substances 0.000 description 22
- 239000000203 mixture Substances 0.000 description 21
- 238000002360 preparation method Methods 0.000 description 19
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 19
- 238000010438 heat treatment Methods 0.000 description 18
- 238000006722 reduction reaction Methods 0.000 description 17
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 16
- 230000009467 reduction Effects 0.000 description 16
- 239000004615 ingredient Substances 0.000 description 15
- 239000004094 surface-active agent Substances 0.000 description 15
- 150000003378 silver Chemical class 0.000 description 14
- 238000003756 stirring Methods 0.000 description 14
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 description 13
- 239000007864 aqueous solution Substances 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 13
- 239000008367 deionised water Substances 0.000 description 13
- 239000007788 liquid Substances 0.000 description 13
- 239000002609 medium Substances 0.000 description 13
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 12
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- 101000682328 Bacillus subtilis (strain 168) 50S ribosomal protein L18 Proteins 0.000 description 10
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- 238000011161 development Methods 0.000 description 9
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- 235000021357 Behenic acid Nutrition 0.000 description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 8
- 229940116226 behenic acid Drugs 0.000 description 8
- 229910001961 silver nitrate Inorganic materials 0.000 description 8
- CVYDEWKUJFCYJO-UHFFFAOYSA-M sodium;docosanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCCCCCC([O-])=O CVYDEWKUJFCYJO-UHFFFAOYSA-M 0.000 description 8
- 229920002125 Sokalan® Polymers 0.000 description 7
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 6
- 239000002105 nanoparticle Substances 0.000 description 6
- 210000004940 nucleus Anatomy 0.000 description 6
- 229910052697 platinum Inorganic materials 0.000 description 6
- 238000001931 thermography Methods 0.000 description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 description 5
- 238000001035 drying Methods 0.000 description 5
- 238000000227 grinding Methods 0.000 description 5
- 238000011065 in-situ storage Methods 0.000 description 5
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 4
- ZTHYODDOHIVTJV-UHFFFAOYSA-N Propyl gallate Chemical compound CCCOC(=O)C1=CC(O)=C(O)C(O)=C1 ZTHYODDOHIVTJV-UHFFFAOYSA-N 0.000 description 4
- 150000008064 anhydrides Chemical class 0.000 description 4
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- TVIDDXQYHWJXFK-UHFFFAOYSA-N dodecanedioic acid Chemical compound OC(=O)CCCCCCCCCCC(O)=O TVIDDXQYHWJXFK-UHFFFAOYSA-N 0.000 description 4
- KBPUBCVJHFXPOC-UHFFFAOYSA-N ethyl 3,4-dihydroxybenzoate Chemical compound CCOC(=O)C1=CC=C(O)C(O)=C1 KBPUBCVJHFXPOC-UHFFFAOYSA-N 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
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- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 4
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- 150000002739 metals Chemical class 0.000 description 4
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- 230000002829 reductive effect Effects 0.000 description 4
- 229920002545 silicone oil Polymers 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 238000001228 spectrum Methods 0.000 description 4
- 108010010803 Gelatin Proteins 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
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- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 239000002270 dispersing agent Substances 0.000 description 3
- 235000019322 gelatine Nutrition 0.000 description 3
- 235000011852 gelatine desserts Nutrition 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 150000002823 nitrates Chemical class 0.000 description 3
- 239000003960 organic solvent Substances 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
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- 239000011347 resin Substances 0.000 description 3
- HRILWXJIWQHJMT-UHFFFAOYSA-M sodium;(4-methylphenyl)-oxido-oxo-sulfanylidene-$l^{6}-sulfane Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=S)C=C1 HRILWXJIWQHJMT-UHFFFAOYSA-M 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 238000007651 thermal printing Methods 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 238000000108 ultra-filtration Methods 0.000 description 3
- UXTZUUVTGMDXNG-UHFFFAOYSA-N 1,2-benzoxazine-3,4-dione Chemical class C1=CC=C2C(=O)C(=O)NOC2=C1 UXTZUUVTGMDXNG-UHFFFAOYSA-N 0.000 description 2
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 2
- NUWHYWYSMAPBHK-UHFFFAOYSA-N 3,4-dihydroxybenzonitrile Chemical compound OC1=CC=C(C#N)C=C1O NUWHYWYSMAPBHK-UHFFFAOYSA-N 0.000 description 2
- DZAUWHJDUNRCTF-UHFFFAOYSA-N 3-(3,4-dihydroxyphenyl)propanoic acid Chemical compound OC(=O)CCC1=CC=C(O)C(O)=C1 DZAUWHJDUNRCTF-UHFFFAOYSA-N 0.000 description 2
- LLLVZDVNHNWSDS-UHFFFAOYSA-N 4-methylidene-3,5-dioxabicyclo[5.2.2]undeca-1(9),7,10-triene-2,6-dione Chemical compound C1(C2=CC=C(C(=O)OC(=C)O1)C=C2)=O LLLVZDVNHNWSDS-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
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- 239000002202 Polyethylene glycol Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
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- 150000001299 aldehydes Chemical class 0.000 description 2
- 150000007933 aliphatic carboxylic acids Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- CCGGDOVGIDSGQN-UHFFFAOYSA-N benzo[f][1,2]benzoxazine-1,2-dione Chemical class C1=CC=CC2=C(C(C(=O)NO3)=O)C3=CC=C21 CCGGDOVGIDSGQN-UHFFFAOYSA-N 0.000 description 2
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- 239000003054 catalyst Substances 0.000 description 2
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- VFPFQHQNJCMNBZ-UHFFFAOYSA-N ethyl gallate Chemical compound CCOC(=O)C1=CC(O)=C(O)C(O)=C1 VFPFQHQNJCMNBZ-UHFFFAOYSA-N 0.000 description 2
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- LNTHITQWFMADLM-UHFFFAOYSA-N gallic acid Chemical compound OC(=O)C1=CC(O)=C(O)C(O)=C1 LNTHITQWFMADLM-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
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- YDSWCNNOKPMOTP-UHFFFAOYSA-N mellitic acid Chemical compound OC(=O)C1=C(C(O)=O)C(C(O)=O)=C(C(O)=O)C(C(O)=O)=C1C(O)=O YDSWCNNOKPMOTP-UHFFFAOYSA-N 0.000 description 2
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- FBSFWRHWHYMIOG-UHFFFAOYSA-N methyl 3,4,5-trihydroxybenzoate Chemical compound COC(=O)C1=CC(O)=C(O)C(O)=C1 FBSFWRHWHYMIOG-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
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- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
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- 125000002221 trityl group Chemical group [H]C1=C([H])C([H])=C([H])C([H])=C1C([*])(C1=C(C(=C(C(=C1[H])[H])[H])[H])[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 2
- OMDQUFIYNPYJFM-XKDAHURESA-N (2r,3r,4s,5r,6s)-2-(hydroxymethyl)-6-[[(2r,3s,4r,5s,6r)-4,5,6-trihydroxy-3-[(2s,3s,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxyoxan-2-yl]methoxy]oxane-3,4,5-triol Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O[C@H]2[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)O)[C@H](O)[C@H](O)[C@H](O)O1 OMDQUFIYNPYJFM-XKDAHURESA-N 0.000 description 1
- ARWCZKJISXFBGI-UHFFFAOYSA-N (3,4-dihydroxyphenyl)-phenylmethanone Chemical compound C1=C(O)C(O)=CC=C1C(=O)C1=CC=CC=C1 ARWCZKJISXFBGI-UHFFFAOYSA-N 0.000 description 1
- 150000005206 1,2-dihydroxybenzenes Chemical class 0.000 description 1
- PUCYIVFXTPWJDD-UHFFFAOYSA-N 1,6-dihydroxycyclohexa-2,4-dienecarboxylic acid Chemical compound OC1C=CC=CC1(O)C(O)=O PUCYIVFXTPWJDD-UHFFFAOYSA-N 0.000 description 1
- TUSDEZXZIZRFGC-UHFFFAOYSA-N 1-O-galloyl-3,6-(R)-HHDP-beta-D-glucose Natural products OC1C(O2)COC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC1C(O)C2OC(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-UHFFFAOYSA-N 0.000 description 1
- GGZHVNZHFYCSEV-UHFFFAOYSA-N 1-Phenyl-5-mercaptotetrazole Chemical compound SC1=NN=NN1C1=CC=CC=C1 GGZHVNZHFYCSEV-UHFFFAOYSA-N 0.000 description 1
- VHAOSIOWTHZVLG-UHFFFAOYSA-N 1-[3-(5-sulfanylidene-2h-tetrazol-1-yl)phenyl]decan-1-one Chemical compound CCCCCCCCCC(=O)C1=CC=CC(N2C(N=NN2)=S)=C1 VHAOSIOWTHZVLG-UHFFFAOYSA-N 0.000 description 1
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- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
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- DFZVZKUDBIJAHK-UHFFFAOYSA-N 2-hydroxyoctadecanoic acid silver Chemical compound [Ag].OC(C(=O)O)CCCCCCCCCCCCCCCC DFZVZKUDBIJAHK-UHFFFAOYSA-N 0.000 description 1
- WZHHYIOUKQNLQM-UHFFFAOYSA-N 3,4,5,6-tetrachlorophthalic acid Chemical compound OC(=O)C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1C(O)=O WZHHYIOUKQNLQM-UHFFFAOYSA-N 0.000 description 1
- YQUVCSBJEUQKSH-UHFFFAOYSA-N 3,4-dihydroxybenzoic acid Chemical class OC(=O)C1=CC=C(O)C(O)=C1 YQUVCSBJEUQKSH-UHFFFAOYSA-N 0.000 description 1
- KFIRODWJCYBBHY-UHFFFAOYSA-N 3-nitrophthalic acid Chemical compound OC(=O)C1=CC=CC([N+]([O-])=O)=C1C(O)=O KFIRODWJCYBBHY-UHFFFAOYSA-N 0.000 description 1
- RYYXDZDBXNUPOG-UHFFFAOYSA-N 4,5,6,7-tetrahydro-1,3-benzothiazole-2,6-diamine;dihydrochloride Chemical compound Cl.Cl.C1C(N)CCC2=C1SC(N)=N2 RYYXDZDBXNUPOG-UHFFFAOYSA-N 0.000 description 1
- LJCWONGJFPCTTL-UHFFFAOYSA-N 4-hydroxyphenylglycine Chemical compound OC(=O)C(N)C1=CC=C(O)C=C1 LJCWONGJFPCTTL-UHFFFAOYSA-N 0.000 description 1
- YFURRWKTIKKJEF-UHFFFAOYSA-N 7-methoxy-1,3-benzoxazine-2,4-dione Chemical compound O1C(=O)NC(=O)C=2C1=CC(OC)=CC=2 YFURRWKTIKKJEF-UHFFFAOYSA-N 0.000 description 1
- HQUVXRFXGBZDNB-UHFFFAOYSA-N 7-methyl-1,3-benzoxazine-2,4-dione Chemical compound O1C(=O)NC(=O)C=2C1=CC(C)=CC=2 HQUVXRFXGBZDNB-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/494—Silver salt compositions other than silver halide emulsions; Photothermographic systems ; Thermographic systems using noble metal compounds
- G03C1/498—Photothermographic systems, e.g. dry silver
- G03C1/49836—Additives
- G03C1/49845—Active additives, e.g. toners, stabilisers, sensitisers
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/494—Silver salt compositions other than silver halide emulsions; Photothermographic systems ; Thermographic systems using noble metal compounds
- G03C1/498—Photothermographic systems, e.g. dry silver
- G03C1/4989—Photothermographic systems, e.g. dry silver characterised by a thermal imaging step, with or without exposure to light, e.g. with a thermal head, using a laser
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/494—Silver salt compositions other than silver halide emulsions; Photothermographic systems ; Thermographic systems using noble metal compounds
- G03C1/498—Photothermographic systems, e.g. dry silver
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/494—Silver salt compositions other than silver halide emulsions; Photothermographic systems ; Thermographic systems using noble metal compounds
- G03C1/498—Photothermographic systems, e.g. dry silver
- G03C1/49827—Reducing agents
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/035—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein characterised by the crystal form or composition, e.g. mixed grain
- G03C2001/03588—Polydisperse emulsion
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/035—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein characterised by the crystal form or composition, e.g. mixed grain
- G03C2001/03594—Size of the grains
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/005—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein
- G03C1/06—Silver halide emulsions; Preparation thereof; Physical treatment thereof; Incorporation of additives therein with non-macromolecular additives
- G03C1/08—Sensitivity-increasing substances
- G03C1/09—Noble metals or mercury; Salts or compounds thereof; Sulfur, selenium or tellurium, or compounds thereof, e.g. for chemical sensitising
- G03C2001/091—Gold
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/74—Applying photosensitive compositions to the base; Drying processes therefor
- G03C2001/7448—Dispersion
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C2200/00—Details
- G03C2200/16—Black-and-white material
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C7/00—Multicolour photographic processes or agents therefor; Regeneration of such processing agents; Photosensitive materials for multicolour processes
- G03C7/30—Colour processes using colour-coupling substances; Materials therefor; Preparing or processing such materials
- G03C7/3041—Materials with specific sensitometric characteristics, e.g. gamma, density
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- Physics & Mathematics (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Heat Sensitive Colour Forming Recording (AREA)
Claims (16)
- Eine Dispersion, die zumindest ein wesentlich lichtunempfindliches organisches Silbersalz, ein Suspensionsmedium und mit Absicht zugesetzte Metallnanoteilchen in einem Molverhältnis, bezogen auf das Gesamtmolverhältnis des zumindest einen wesentlich lichtunempfindlichen organischen Silbersalzes, zwischen 0,05:1 und 10-6:1 enthält, dadurch gekennzeichnet, dass das wesentlich lichtunempfindliche organische Silbersalz wesentlich unlöslich im Suspensionsmedium ist.
- Dispersion nach Anspruch 1, dadurch gekennzeichnet, dass als Metall Silber, Gold, Palladium oder eine Legierung derselben verwendet wird.
- Dispersion nach Anspruch 1 und 2, dadurch gekennzeichnet, dass die Dispersion ferner strahlungsempfindliches Silberhalogenid enthält.
- Ein durch die nachstehenden Schritte gekennzeichnetes Verfahren zur Herstellung einer Dispersion nach Anspruch 1 oder 2 :(i) Anfertigung einer Dispersion eines lichtunempfindlichen organischen Silbersalzes, (ii) Anfertigung einer Dispersion von Metallkeimen, (iii) Vermischen der Dispersion von Metallkeimen von Schritt (ii) mit einer oder mehreren Dispersionen eines lichtunempfindlichen organischen Silbersalzes.
- Verfahren zur Herstellung eines wesentlich lichtunempfindlichen thermografischen Schwarzweiß-Aufzeichnungsmaterials mit einem wärmeempfindlichen Element und einem Träger, wobei das wärmeempfindliche Element zumindest ein wesentlich lichtunempfindliches organisches Silbersalz, ein organisches Reduktionsmittel dafür in thermischer wirksamer Beziehung dazu, ein Tönungsmittel und ein Bindemittel enthält, dadurch gekennzeichnet, dass das wärmeempfindliche Element ferner mit Absicht zugesetzte Metallnanoteilchen in einem Molverhältnis, bezogen auf das Gesamtmolverhältnis des zumindest einen wesentlich lichtunempfindlichen organischen Silbersalzes, zwischen 0,05:1 und 10-6:1 enthält, wobei das Verfahren durch die nachstehenden Schritte gekennzeichnet ist : (i) Vermischen einer Dispersion nach Anspruch 1 oder 2 mit einem Reduktionsmittel und einem Tönungsmittel und (ii) Auftrag der in Schritt (i) angefertigten Dispersion auf einen Träger.
- Verfahren zur Herstellung eines fotothermografischen Schwarzweiß-Aufzeichnungsmaterials mit einem wärmeempfindlichen Element und einem Träger, wobei das wärmeempfindliche Element zumindest ein wesentlich lichtunempfindliches organisches Silbersalz, ein organisches Reduktionsmittel dafür in thermischer wirksamer Beziehung dazu, ein Tönungsmittel und ein Bindemittel enthält, dadurch gekennzeichnet, dass das wärmeempfindliche Element ferner mit Absicht zugesetzte Metallnanoteilchen in einem Molverhältnis, bezogen auf das Gesamtmolverhältnis des zumindest einen wesentlich lichtunempfindlichen organischen Silbersalzes, zwischen 0,05:1 und 10-6:1 enthält, wobei das Verfahren durch die nachstehenden Schritte gekennzeichnet ist : (i) Vermischen einer Dispersion nach Anspruch 3 mit einem Reduktionsmittel und einem Tönungsmittel und (ii) Auftrag der in Schritt (i) angefertigten Dispersion auf einen Träger.
- Ein thermografisches Schwarzweiß-Aufzeichnungsmaterial mit einem wärmeempfindlichen Element und einem Träger, wobei das wärmeempfindliche Element zumindest ein wesentlich lichtunempfindliches organisches Silbersalz und ein Bindemittel enthält, dadurch gekennzeichnet, dass das wärmeempfindliche Element ferner mit Absicht zugesetzte Metallnanoteilchen in einem Molverhältnis, bezogen auf das Gesamtmolverhältnis des zumindest einen wesentlich lichtunempfindlichen organischen Silbersalzes, zwischen 0,05:1 und 10-6:1 enthält.
- Thermografisches Aufzeichnungsmaterial nach Anspruch 7, dadurch gekennzeichnet, dass das Molverhältnis der mit Absicht zugesetzten Metallnanoteilchen im wärmeempfindlichen Element zum Gesamtmolverhältnis des zumindest einen wesentlich lichtunempfindlichen organischen Silbersalzes zwischen 0,005:1 und 5 x 10-6:1 liegt.
- Thermografisches Aufzeichnungsmaterial nach Anspruch 7 oder 8, dadurch gekennzeichnet, dass das Molverhältnis der mit Absicht zugesetzten Metallnanoteilchen im wärmeempfindlichen Element zum Gesamtmolverhältnis des zumindest einen wesentlich lichtunempfindlichen organischen Silbersalzes zwischen 0,002:1 und 10-5:1 liegt.
- Thermografisches Aufzeichnungsmaterial nach einem der Ansprüche 7 bis 9, dadurch gekennzeichnet, dass das wärmeempfindliche Element ferner ein Tönungsmittel enthält.
- Thermografisches Aufzeichnungsmaterial nach Anspruch 10, dadurch gekennzeichnet, dass das Tönungsmittel ein Phthalazinon, ein Phthalazinon-Derivat, ein Pyridazon, ein Pyridazon-Derivat, ein Benzoxazin-Derivat oder ein substituiertes Benzoxazin-Derivat ist.
- Thermografisches Aufzeichnungsmaterial nach einem der Ansprüche 7 bis 11, dadurch gekennzeichnet, dass das wärmeempfindliche Element ferner strahlungsempfindliches Silberhalogenid enthält.
- Ein durch die nachstehenden Schritte gekennzeichnetes thermografisches Aufzeichnungsverfahren : (i) Anordnen einer Außenschicht eines thermografischen Aufzeichnungsmaterials nach einem der Ansprüche 7 bis 11 oder eines nach Anspruch 5 hergestellten thermografischen Aufzeichnungsmaterials in der Nähe einer Heizquelle, (ii) bildmäßige Beaufschlagung des thermografischen Aufzeichnungsmaterials, unter wesentlich wasserfreien Bedingungen, mit von der Heizquelle gelieferter Wärme zur Herstellung eines Bildes, wobei das Aufzeichnungsmaterial in der Nähe der Heizquelle gehalten wird, und (iii) Entfernen des thermografischen Aufzeichnungsmaterials von der Heizquelle.
- Aufzeichnungsverfahren nach Anspruch 13, dadurch gekennzeichnet, dass die Heizquelle ein Dünnfilm-Thermokopf ist.
- Ein durch die nachstehenden Schritte gekennzeichnetes fotothermografisches Aufzeichnungsverfahren : (i) bildmäßige aktinische Belichtung des fotothermografischen Aufzeichnungsmaterials nach Anspruch 12, (ii) Anordnen einer Außenschicht des fotothermografischen Aufzeichnungsmaterials in der Nähe einer Heizquelle, (iii) vollflächige Beaufschlagung des fotothermografischen Aufzeichnungsmaterials, unter wesentlich wasserfreien Bedingungen, mit von der Heizquelle gelieferter Wärme zur Herstellung eines Bildes, wobei das Aufzeichnungsmaterial in der Nähe der Heizquelle gehalten wird, und (iv) Entfernen des fotothermografischen Aufzeichnungsmaterials von der Heizquelle.
- Verwendung in einem thermografischen Aufzeichnungsmaterial mit einem wärmeempfindlichen Element, das zumindest ein wesentlich lichtunempfindliches organisches Silbersalz, ein organisches Reduktionsmittel dafür in thermischer wirksamer Beziehung dazu, ein Tönungsmittel und ein Bindemittel enthält, von Metallnanoteilchen, die dem wärmeempfindlichen Element mit Absicht in einem Molverhältnis, bezogen auf das Gesamtmolverhältnis des zumindest einen wesentlich lichtunempfindlichen organischen Silbersalzes, zwischen 0,05:1 und 10-6:1 zugesetzt werden, um das Verhältnis des Dmax-Wertes zur Gesamtmenge des zumindest einen wesentlich lichtunempfindlichen organischen Silbersalzes pro Flächeneinheit des thermografischen Aufzeichnungsmaterials zu steigern.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02102623A EP1316845B1 (de) | 2001-11-30 | 2002-11-22 | Thermographisches Aufzeichnungsmaterial mit verbesserter Entwickelbarkeit |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP01000691 | 2001-11-30 | ||
| EP01000691 | 2001-11-30 | ||
| EP02102623A EP1316845B1 (de) | 2001-11-30 | 2002-11-22 | Thermographisches Aufzeichnungsmaterial mit verbesserter Entwickelbarkeit |
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| Publication Number | Publication Date |
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| EP1316845A1 EP1316845A1 (de) | 2003-06-04 |
| EP1316845B1 true EP1316845B1 (de) | 2005-04-20 |
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| JP2517343B2 (ja) * | 1988-01-26 | 1996-07-24 | 富士写真フイルム株式会社 | 熱現像感光材料 |
| DE69506333T2 (de) * | 1994-07-11 | 1999-07-15 | Agfa Gevaert Nv | Tintenstrahldruckverfahren |
| US5882722A (en) * | 1995-07-12 | 1999-03-16 | Partnerships Limited, Inc. | Electrical conductors formed from mixtures of metal powders and metallo-organic decompositions compounds |
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| EP1316845A1 (de) | 2003-06-04 |
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