EP1295967A3 - Process for depositing a zinc-nickel alloy from an electrolyte - Google Patents
Process for depositing a zinc-nickel alloy from an electrolyte Download PDFInfo
- Publication number
- EP1295967A3 EP1295967A3 EP02020926A EP02020926A EP1295967A3 EP 1295967 A3 EP1295967 A3 EP 1295967A3 EP 02020926 A EP02020926 A EP 02020926A EP 02020926 A EP02020926 A EP 02020926A EP 1295967 A3 EP1295967 A3 EP 1295967A3
- Authority
- EP
- European Patent Office
- Prior art keywords
- zinc
- electrolyte
- derivatives
- salts
- carboxylic acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/565—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of zinc
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/06—Anodisation of aluminium or alloys based thereon characterised by the electrolytes used
- C25D11/10—Anodisation of aluminium or alloys based thereon characterised by the electrolytes used containing organic acids
Abstract
Die Erfindung betrifft ein Verfahren zur Abscheidung einer Zink-Nickel-Legierung aus einem Zink-Nickel-Elektrolyten, welches dadurch gekennzeichnet ist, das dem Elektrolyten zur Erweiterung des anwendbaren Stromdichtebereichs wenigstens eine aromatische Carbonsäure, deren Salze und/oder deren Derivate oder wenigstens eine aliphatische Carbonsäure, deren Salze und/oder deren Derivate, oder wenigstens eine aromatische und/oder aliphatische Carbonsäure, deren Salze und/oder deren Derivate zugegeben werden. Ferner wird ein für dieses Verfahren geeigneter Elektrolyt angegeben. Das erfindungsgemäße Verfahren ermöglicht es in vorteilhafter Weise, daß brauchbare Zink-Nickel-Legierungen über einen weiten Stromdichtebereich abgeschieden werden können, so daß auch die Beschichtung von profilierten Werkstücken möglich ist. Dabei kann mit einem ammoniumfreien Elektrolyten gearbeitet werden, was in vorteilhafter Weise die Belastung der Abwässer verringert.The invention relates to a method for depositing a zinc-nickel alloy from a zinc-nickel electrolyte, which is characterized in that the Electrolytes for extending the applicable current density range at least an aromatic carboxylic acid, its salts and / or their derivatives or at least one aliphatic carboxylic acid, its salts and / or derivatives thereof, or at least one aromatic and / or aliphatic carboxylic acid, the Salts and / or their derivatives are added. Furthermore, one for this Method specified suitable electrolyte. The inventive method allows advantageously that useful zinc-nickel alloys over a wide current density range can be deposited, so that the Coating of profiled workpieces is possible. It can with a ammonium-free electrolytes are worked, which advantageously the Reduced load on the wastewater.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10146559A DE10146559A1 (en) | 2001-09-21 | 2001-09-21 | Process for the deposition of a zinc-nickel alloy from an electrolyte |
DE10146559 | 2001-09-21 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1295967A2 EP1295967A2 (en) | 2003-03-26 |
EP1295967A3 true EP1295967A3 (en) | 2005-05-11 |
Family
ID=7699793
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP02020926A Withdrawn EP1295967A3 (en) | 2001-09-21 | 2002-09-19 | Process for depositing a zinc-nickel alloy from an electrolyte |
Country Status (6)
Country | Link |
---|---|
US (1) | US20030085130A1 (en) |
EP (1) | EP1295967A3 (en) |
JP (1) | JP4307810B2 (en) |
KR (1) | KR100556604B1 (en) |
CN (1) | CN1291068C (en) |
DE (1) | DE10146559A1 (en) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101223302A (en) * | 2005-05-26 | 2008-07-16 | 帕维科公司 | Trivalent chromium conversion coating and method of application thereof |
WO2007002070A2 (en) * | 2005-06-20 | 2007-01-04 | Pavco, Inc. | Zinc-nickel alloy electroplating system |
HUE026918T2 (en) * | 2006-07-13 | 2016-07-28 | Enthone Incorporated | Electrolyte composition und process for the deposition of a zinc-nickel alloy layer on a cast iron or steel substrate |
DE102006035233A1 (en) * | 2006-07-26 | 2008-01-31 | Mahle International Gmbh | Galvanic surface coating of a component |
US20100096274A1 (en) * | 2008-10-17 | 2010-04-22 | Rowan Anthony J | Zinc alloy electroplating baths and processes |
DE202008014947U1 (en) | 2008-11-11 | 2009-03-12 | Enthone Inc., West Haven | Galvanic bath for the separation of zinciferous layers |
DE102008056776A1 (en) | 2008-11-11 | 2010-05-12 | Enthone Inc., West Haven | Galvanic bath and method for the deposition of zinciferous layers |
DE102008058086B4 (en) * | 2008-11-18 | 2013-05-23 | Atotech Deutschland Gmbh | Method and device for cleaning electroplating baths for the deposition of metals |
KR101183255B1 (en) | 2012-04-13 | 2012-09-14 | 서영호 | Tin-zinc alloy plating solution |
JP5740616B1 (en) | 2014-09-25 | 2015-06-24 | ユケン工業株式会社 | Additive for acidic zinc alloy plating bath, acidic zinc alloy plating bath, and method for producing zinc alloy plated member |
EP3015571B1 (en) | 2014-10-27 | 2018-05-02 | ATOTECH Deutschland GmbH | Acidic zinc and zinc-nickel alloy plating bath composition and electroplating method |
PL3461933T3 (en) | 2017-09-28 | 2020-03-31 | Atotech Deutschland Gmbh | Method for electrolytically depositing a zinc-nickel alloy layer on at least a substrate to be treated |
EP3666929A1 (en) * | 2018-12-12 | 2020-06-17 | Dr.Ing. Max Schlötter GmbH & Co. KG | Boric acid and ammonium-free zinc electrolyte for the galvanic deposition of zinc coverings |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4388160A (en) * | 1980-02-20 | 1983-06-14 | Rynne George B | Zinc-nickel alloy electroplating process |
US4515663A (en) * | 1984-01-09 | 1985-05-07 | Omi International Corporation | Acid zinc and zinc alloy electroplating solution and process |
DE3534147A1 (en) * | 1985-09-25 | 1987-04-02 | Elektro Brite Gmbh | Chloride-containing bath for the electrodeposition of a zinc-nickel alloy on iron |
US4861442A (en) * | 1988-02-26 | 1989-08-29 | Okuno Chemical Industries Co., Ltd. | Zinc-nickel alloy plating bath and plating method |
US4889602A (en) * | 1986-04-14 | 1989-12-26 | Dipsol Chemicals Co., Ltd. | Electroplating bath and method for forming zinc-nickel alloy coating |
JPH0949097A (en) * | 1994-08-31 | 1997-02-18 | Kawasaki Steel Corp | Electric zinc-nickel alloy plating liquid and production of plated steel sheet |
US5700362A (en) * | 1994-04-15 | 1997-12-23 | Fukuda Metal Foil And Powder Co., Ltd. | Method of treating copper foil for printed circuits |
DE19941765A1 (en) * | 1998-09-15 | 2000-03-16 | Lpw Chemie Gmbh | Electroplating process for high-gloss zinc coatings on metal involves using aqueous acid electrolyte containing zinc salt and heterocyclic aromatic, especially N-alkyl-pyridine compound, as brightener |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4543166A (en) * | 1984-10-01 | 1985-09-24 | Omi International Corporation | Zinc-alloy electrolyte and process |
US4832802A (en) * | 1988-06-10 | 1989-05-23 | Mcgean-Rohco, Inc. | Acid zinc-nickel plating baths and methods for electrodepositing bright and ductile zinc-nickel alloys and additive composition therefor |
KR100276701B1 (en) * | 1994-08-31 | 2001-01-15 | 에모토 간지 | Electrolytic zinc-nickel alloy plating solution and method for producing steel sheet using the alloy plating solution |
US6238542B1 (en) * | 1998-09-15 | 2001-05-29 | Thomas Helden | Water soluble brighteners for zinc and zinc alloy electrolytes |
-
2001
- 2001-09-21 DE DE10146559A patent/DE10146559A1/en not_active Withdrawn
-
2002
- 2002-09-19 EP EP02020926A patent/EP1295967A3/en not_active Withdrawn
- 2002-09-19 KR KR1020020057221A patent/KR100556604B1/en active IP Right Grant
- 2002-09-20 JP JP2002274993A patent/JP4307810B2/en not_active Expired - Lifetime
- 2002-09-20 CN CNB021424853A patent/CN1291068C/en not_active Expired - Lifetime
- 2002-09-23 US US10/252,495 patent/US20030085130A1/en not_active Abandoned
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4388160A (en) * | 1980-02-20 | 1983-06-14 | Rynne George B | Zinc-nickel alloy electroplating process |
US4515663A (en) * | 1984-01-09 | 1985-05-07 | Omi International Corporation | Acid zinc and zinc alloy electroplating solution and process |
DE3534147A1 (en) * | 1985-09-25 | 1987-04-02 | Elektro Brite Gmbh | Chloride-containing bath for the electrodeposition of a zinc-nickel alloy on iron |
US4889602A (en) * | 1986-04-14 | 1989-12-26 | Dipsol Chemicals Co., Ltd. | Electroplating bath and method for forming zinc-nickel alloy coating |
US4889602B1 (en) * | 1986-04-14 | 1995-11-14 | Dipsol Chem | Electroplating bath and method for forming zinc-nickel alloy coating |
US4861442A (en) * | 1988-02-26 | 1989-08-29 | Okuno Chemical Industries Co., Ltd. | Zinc-nickel alloy plating bath and plating method |
US5700362A (en) * | 1994-04-15 | 1997-12-23 | Fukuda Metal Foil And Powder Co., Ltd. | Method of treating copper foil for printed circuits |
JPH0949097A (en) * | 1994-08-31 | 1997-02-18 | Kawasaki Steel Corp | Electric zinc-nickel alloy plating liquid and production of plated steel sheet |
DE19941765A1 (en) * | 1998-09-15 | 2000-03-16 | Lpw Chemie Gmbh | Electroplating process for high-gloss zinc coatings on metal involves using aqueous acid electrolyte containing zinc salt and heterocyclic aromatic, especially N-alkyl-pyridine compound, as brightener |
Non-Patent Citations (1)
Title |
---|
PATENT ABSTRACTS OF JAPAN vol. 1997, no. 06 30 June 1997 (1997-06-30) * |
Also Published As
Publication number | Publication date |
---|---|
KR100556604B1 (en) | 2006-03-06 |
DE10146559A1 (en) | 2003-04-10 |
JP4307810B2 (en) | 2009-08-05 |
KR20030025876A (en) | 2003-03-29 |
US20030085130A1 (en) | 2003-05-08 |
EP1295967A2 (en) | 2003-03-26 |
CN1291068C (en) | 2006-12-20 |
JP2003105585A (en) | 2003-04-09 |
CN1410602A (en) | 2003-04-16 |
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