EP1275035A1

EP1275035A1 - Method for regulating a property of a product derived from a chemical transformation

Info

Publication number: EP1275035A1
Application number: EP02700244A
Authority: EP
Inventors: Marc Lacroix; Yves Hontoir
Original assignee: Solvay Polyolefins Europe Belgium SA; Solvay SA
Current assignee: Ineos Manufacturing Belgium NV
Priority date: 2001-02-19
Filing date: 2002-02-14
Publication date: 2003-01-15
Also published as: FR2821175A1; WO2002067062A1; JP2004519051A; US20040102935A1

Abstract

The invention concerns a method for regulating a property of a product derived from a chemical transformation process, consisting in: a) modelling the relationship between said property and characteristic physical quantities of the process; b) fixing a set point value for said property; c) introducing said set point value in a regulation system based on the model obtained in (a) so a to apply to the process at least a physical quantity calculated from said set point value; d) calculating with a model defined in (a), corrected by a factor taking into account the delay, of a model value of the property of the product corresponding to the characteristic physical quantity/quantities defined by the regulation system; e) continuously measuring the real value of the property and the model value of the property of the product; f) determining the difference between said real value and the model value of the property of the product; g) using said difference, after filtering, to adapt the set point value so as to align the real value and its model value. The invention also concerns a regulating device and a chemical transformation method using said device for implementing said method.

Description

Method for regulating a property of a product resulting from a chemical transformation

The present invention relates to a method for regulating a property of a product resulting from a chemical transformation process and a regulation device, as well as a chemical transformation method implementing such a method or such a regulation device. . The industrial application of any chemical transformation process, such as for example a process of synthesis, polymerization, degradation or depolymerization requires on the one hand the respect of more or less strict technical specifications of the product and on the other hand a economical and profitable use of inputs. The inevitable automation which results from it therefore requires adapted, but flexible methods of control or regulation allowing the best control of chemical processes.

The attempts at mathematical modeling that underlie these methods are as numerous as the chemical processes to be controlled. The models conventionally used are those of the PID type (that is to say comprising a proportional term, an integral term and a differential term) for the individual control of a more or less important number of parameters (for example the temperature , pressure, flow rates etc.). This type of model is however difficult to apply to a large number of chemical transformation processes, since the latter are often marred by dead times or significant delays, either in the process itself or in the measures necessary to supply the model. The consequences are significant rejects that do not meet the set specifications, due for example to the oscillation phenomenon generated by too late and therefore often excessive correction of the parameters in the model. The prediction techniques developed to respond to the limitations of conventional methods could not stand in the way of the success of these simple methods.

It would therefore be desirable to have a fully automated regulation method which is simpler and better suited to chemical transformation processes. The present invention therefore provides a method of regulating a property of a product resulting from a chemical transformation process, comprising a) modeling the relationship between said property and characteristic quantities of the process, b) fixing d '' a set value for said property, c) the introduction of this set value in a regulation system based on the model obtained in (a) in order to apply to the process at least one characteristic quantity calculated from this value setpoint, d) calculation using the model defined in (a), corrected by a factor taking into account the delay, of a model value of the property of the product corresponding to the characteristic quantity (s) ( s) defined by the control system, e) continuous measurement of the real value of product ownership, f) determination of the difference between this real value and the model value of the property of the product, g) the use of this difference, after filtering, to adapt the setpoint so as to align the actual value and its model value.

According to a preferred variant, the regulation method according to the invention comprises the calculation (d) of the model value of the property corresponding to the characteristic quantity (s) using the model obtained in (a ), corrected by the factor taking into account the delay and by a factor taking into account the dynamics of the process.

Such a method, which includes only one control loop and which does not involve a direct comparison between the set value and the real value of the property, therefore has an advantage of simplicity compared to conventional techniques which include a regulation based on the comparison of the real value with the set value to which a regulation is superimposed, making use separately of a model for the process and a model for the delay. On the other hand, the use of mathematical models defined for the calculation of model values allows computerization and therefore the complete automation of the process, without requiring human intervention for the compensation of errors due to delay or other external disturbances.

This method can be implemented for any chemical transformation process, such as a synthesis, polyaddition, polymerization, grafting, degradation, etc. process. However you have to understand that the process envisaged may also include other processing steps, whether of a chemical and / or physical nature, which are necessary for obtaining the desired finished product. By way of example, mention may be made of homogenization, kneading, washing, drying, granulation, molding, etc.

The property or properties of the product under consideration to be controlled and regulated obviously depends both on the process implemented and on the objective pursued. Mention may be made, by way of non-exhaustive illustration, of the chemical characteristics, such as the nature, respectively the composition of the resulting product, but above all of the physical characteristics, such as the molecular mass, respectively the distribution of the molecular masses, the melting point. , stiffness, viscosity, melt flow index (MFI), swelling in the melt, bubble stability, etc.

A particular embodiment of the present invention provides that such a method of regulation is applied to a process for converting a polymer in an extruder. It may, for example, be a process for crosslinking a polymer, in which use is made of crosslinking agents chosen, for example, from peroxide compounds and diazo compounds. It is preferably a depolymerization process using as reactants one or more polymers and one or more depolymerization agents. The objective of this depolymerization can for example be the adjustment of the rheological properties of the finished product and it will very often include other steps (called post-treatment), for example a granulation of the product leaving the extruder. The polymers envisaged include polymers and copolymers of olefins with two to eight carbon atoms, for example ethylene, propylene, etc. Typical polyolefins are (co) polymers of ethylene and propylene, such as, for example, a polypropylene homopolymer (PP) and copolymers of propylene with secondary amounts of other olefins. The nature of the depolymerization agents is not critical as long as they are suitable for this purpose. Examples are oxygen, oxygen-rich compounds, such as peroxides, persulfates and diazo compounds. Preferred depolymerizing agents include diaryl, dialkyl and arylalkyl peroxides. 2,5 Dimethyl-2,5 di (terbutylperoxide) hexane is well suited. It is also possible to use several depolymerization agents, separately or as a mixture. The term "reagents", as used in the context of the present invention, also includes other substances which are necessary for the proper performance of the process envisaged, but which do not directly intervene in the reaction or the reactions properly-called (s). They can be any useful additives or adjuvants, such as stabilizers, antioxidant additives, antistatic agents, organic or inorganic dyes and fillers, etc., these additives and adjuvants being able to be added at any appropriate time. Thus, the addition can be carried out simultaneously, as a mixture, successively or even at different stages of the process depending on the nature and the function of the additive or adjuvant considered.

Another aspect of the present invention contemplates carrying out the measurement of the real value of the property of the product on a sample of the finished product and not on an intermediate product as required by the prior art to reduce the effect of the delay. Indeed, as we mentioned above, the vast majority of chemical transformation processes used in industry involve several chemical and / or physical steps before obtaining the targeted product. The properties of this product are therefore likely to change throughout the process.

This variant of the present invention thus has the additional advantage of integrating into the regulation also other disturbances which are linked to the post-treatment of the product.

The technical instrumentation used for the analysis of the product and the determination of the real value of the property of the product obviously depends on the latter and is not critical. The choice will also depend on the simplicity of implementation, reliability, speed or availability. By way of example, for the determination of the melt flow index (MFI), rheometric techniques, spectrometric methods (IR, NIR, NMR) and ultrasound analysis are suitable, not exclusively.

The real value of the property is used to determine the difference between this real value and the model value, i.e. the value calculated using the mathematical model and corrected by the delay factor and optionally the factor dynamic. This difference is then used to adapt the setpoint so as to align the actual value and the model value. In a preferred aspect of the present invention, this difference is however firstly subjected to a filtering step having the aim of moderating the aggressiveness of the regulator, by example by introducing an appropriate filter, such as a low-pass type filter with adjustable time constant, into the control loop.

The mathematical model entering into the method of the present invention can be based on an equation of the type

MV = a + blV + ∑ ∑ Cy lRj Ϋ + ∑ ∑ dy iTj} ¹ + i = \ j = \ i = \ j = \

∑ ∑ ijiPj û∑ ∑ fijiFJΫ i = \ j = \ i = \ j = \

or : •

MV represents the model value or estimated value IV represents the initial value of the property [Rj] represents the concentrations of the reagents [Tj] represents temperatures characteristic of the process

[Pj] represents pressures characteristic of the process

[F,] represents the flow rates of reagents a, b, cjj, djj, ejj and fjj are constants i and j are natural integers greater than or equal to 1. Another embodiment of the present invention is a method of regulation in which the model is based on an equation of the npnp type

\ ogMV = a '+ b'logIV + ∑ ∑ c'ij [Rj] ^l + ∑ ∑ y [Tj] ¹ + i = lj = li = lj = lnpnp

∑ ∑ éij iPj + ∑ ∑ f'ij WÏ i = \ j = \ i = \ j = l

or

MV, IV, [Rj], [Tj], [Pj], [Fj], i and j have the meanings indicated above, and a ', b', c'y, d'y, e'jj and fjj are constants.

The delay factor can be represented by any known suitable method, for example by the "Smith predictor" method, as described for example in Chemical Engineering Progress, vol. 53 No 5, May 1957, p. 217-219. An advantageous embodiment of the regulation method according to the invention provides that the factor taking account of the delay is obtained by using a shift register. The factor taking into account the dynamics of the process is advantageously represented by a "LAG" type function or low-pass filter. A particularly simple function of this type giving good results is a function according to the formalism of the Laplace transforms corresponding to the equation y (t) = l / (l + pTp) in which p represents the period of the measurement and Tp the process time constant. Such methods and functions are well known to those skilled in the art. In addition, the present invention provides, in another aspect, a device for regulating a property of a product resulting from a chemical transformation process, comprising at least one unit allowing the regulation of at least one characteristic quantity on base of a setpoint value of the property to be regulated, - at least one calculation unit allowing the determination of a model value of the property to be regulated from the values of the characteristic quantity (s) defined by the regulator, means for continuously measuring the real value of the property of the product, - means for determining the difference between the real value and the model value of the property and for filtering this difference , means for adapting the set value so as to reduce this difference.

The device according to the invention preferably uses a regulation method in accordance with the present invention, as described above.

Another embodiment proposes a device in which the calculation unit uses a proportional, integral and / or differential term model corrected by a factor taking account of the delay and possibly by a factor taking into account the dynamics of the process. In one embodiment, the regulation unit uses the inverse of the model established for the calculation unit.

The characteristic quantities of the chemical transformation process which can be controlled by the device of the invention are chosen, for example, from the concentrations and flow rates of the reactants, the residence times, the pressures and / or the temperatures of one or more of the process steps. On the other hand, the present invention contemplates a chemical transformation method using a control device as described above or implementing a control method according to the invention, to control and regulate a property of a product resulting from 'a chemical transformation process.

As indicated above, this chemical transformation can represent or include, for example, one or more stages of synthesis, polyaddition, polymerization, grafting and / or degradation, as well as, optionally, one or more physical procedures, such as homogenization, kneading, drying, granulation, molding, etc. The preferred process according to the present invention is a depolymerization reaction using as reactants one or more polymers and one or more depolymerization agents.

The nature of the polymers has been described above and it is preferably a polyolefin, such as polypropylene.

The depolymerization agent (s) is (are) chosen in particular from oxygen, oxygen-rich compounds, peroxides, persulfates and diazo compounds, as described above.

As noted above, it is in principle possible to control any property of the finished product. Thus, in one embodiment of the method in accordance with the present invention, the property of the product to be controlled and regulated is the melt flow index (MFI) by acting on the parameters mentioned above. The melt index is determined for example continuously using a rheometer, an IR spectrometer, an NIR spectrometer, an NMR spectrometer and / or an aux analyzer. ultrasound, either directly online, or preferably on a sample of the finished product.

Online measurement involves drawing off part of the product flow, for example in the case of an extrusion upstream of the die to supply the chosen analyzer, for example a rheometer. However, in addition to the disadvantage that such a measure does not consider any variations linked to the post-treatment of the product, other disadvantages must be taken into account, in particular a delay or delay nevertheless significant (compared to the time constant process), even in the case of online measurement, the proximity of sensitive measurement equipment and / or the congestion resulting from the production installation. Continuous determination on the finished product is therefore preferred. It should be noted that the term continuous measurement of the real value of the property of the product is understood to mean a measurement carried out at a regular rate by means of an automatic device. When the method according to the present invention is applied to the regulation of the MFI, the model value of the MFI can be calculated on the basis of the model

MFI _out = A + B. MFI _in + C. [PER] + DT where MFI _0U t represents the estimated melt flow index of the product of the depolymerization

MFIj _n represents the melt flow index of the polymer reagent A, B, C and D represent constants

[PER] represents the concentration of depolymerization agent in the material entering the process, and

T represents the temperature at which the depolymerization reaction takes place.

In other cases, the method applied to the regulation of the melt flow index (MFI) of a polymer, in which the MFI model corresponds to a first order equation with respect to the concentration of depolymerization agent ([PER]) of type:

\ ogMFI _out = A '+ B'. \ ogMFI _in + C. [PER] + D'T or even a second order equation

\ ogMFI _out = A "+ B" ΛogMFI _in + C ". [PER] + C ₂ ". [PER ² + D "T where

MFI _or t, MFIj _n , [PER] and T have the meanings given above and A, B ', C, D', A ", B", Ci ", C2" and D "represent constants.

The delay factor as well as the dynamic factor are those described above in the context of the present invention and can be defined by any methods known per se, such as more particularly those mentioned above.

In practice, although the models listed above explicitly provide for the use of the concentration of the depolymerization agent to regulate the melt index, this property can also be acquired by more simply adjusting the feed rate. of the depolymerization agent. In the latter case, it is assumed that the change in volume due to quantities depolymerizing agent variables or, in other words, the dilution effect is negligible.

In a practical embodiment, the flow rate (concentration) of the depolymerization agent (s) is in turn regulated by a simple local feedback loop, for example of the PID type, so as to control the flow rate (concentration) actually supplied by the metering devices.

The actual flow can be determined by any device suitable for this purpose, generally a flow meter, such as a Coriolis flow meter. Another very simple and often sufficient possibility is to infer the flow rate of the rotation speed and the stroke of the pump piston.

The model underlying the process of the present invention can in some cases be further simplified. If raw materials of sufficiently constant quality are available, it can be assumed, for example, that the melt melt index of the polymer reagent (MFIj _n ) is invariable. It is the same for the temperature (T): if the process is operated under conditions of (essentially) stationary regime, the equation is further simplified.

In practice, the model will then be reduced to a linear model with a single first order variable. The delay factor can also be reduced to a pure delay and can be implemented by any suitable method, for example by the "Smith predictor" approach or by the use of a shift register. Also in practice, the factor taking into account the dynamics of the process is most often reduced to a first-order low-pass filter.

Figure 1 shows the general method according to the invention. Figure 2 shows the diagram of a possible application of the present invention: a depolymerization process which is controlled by a method of the present invention.

Figure 3 illustrates the case of Figure 2 using a simplified first-order model, assuming constant temperature and melt flow index (MFI).

Figure 4 presents examples of performances obtained in the case of a PP resin.

As shown in Figure 1, the setpoint (SP) is introduced into the regulation system (regulator -1) based on the model developed in step (a) and using for example the inverse of this model. The result of the regulation acts on the method (2) regulating the real value of the property (PV) and on the model (3) to calculate the model value (MV). The actual value (PV) is measured and compared to the model value (MV) to determine the deviation (E). This difference is then filtered and the filtered difference (Ef) is used to adapt the setpoint (SP).

Figure 2 is an example of application of this method. This is a process used to adjust the rheological characteristics of polypropylene (PP) resins. The initial resin (fluff - A) and other additives (B) are mixed in the extruder (1) then added with a depolymerization agent (L) before being extruded and granulated. The typical duration of this first stage is of the order of 0.1 minute. The granules are then washed (2), wrung (3) and dried (4). This step typically takes 0.5 minutes. The resulting granules which represent the finished product are then subjected to rheological measurements (MFI) after fusion, for example in a rheometer of the Gôttfert type. The time taken in this case is for example of the order of 5 to 20 minutes.

If we apply the diagram of Figure 1 to the process of Figure 2, we obtain the diagram of Figure 3. In the case of said Figure 3, the model is a simplified model of the type MFIOUT = K + g [PER ] (as described above), the factor taking into account the dynamics is a type function, according to the formalism of the Laplace transforms, and

1 + p.Tp also described above. τ is the delay and the filter is realized by a function of the type

1 + p.Tp

(according to Laplace formalism) in which p represents the period of the measurement and Tf the response time of the filter.

The typical delay or delay (τ) is, as we have seen in Figure 2, in the range of 5 to 20 minutes or more. The delay factor is in this case, for example, a Smith predictor or any other suitable method. The deposit (MFIgp) is used to determine the quantity (or concentration) of depolymerization agent required [PER] §p. This concentration is then introduced into the model and the result, that is to say the model value is compared with the real value (MFIpy) to determine the difference (E). After filtration, the filtered difference (Ef) is used to adapt the setpoint (MFI _S p). The concentration of depolymerization agent is varied by an amount

Δ [PER]. After a delay τ the MFIQUT begins to vary in turn until it stabilizes again at a value MFIQUT ⁺ ΔMFIQUT- The different parameters of the regulation can then be determined as follows: - gai • nd, e process, d, e ,: g = ΔMFI ₀ ___ _U __ _T _

A [PER] constant of the model K = MFI _Q UJ - g. [PER] process time constant: Tp = time required to reach 63% of ΔMFIouT taking into account the delay τ the time constant relating to the filtering of the difference E between the measured value and the calculated value is fixed at 1.5 min.

The following example and Figure 4 illustrate the invention. Examples

Depolymerization is carried out with a polypropylene resin (PP) with an initial MFI of the order of 1 g / 10 min. The depolymerization is carried out once with a conventional PID type regulation method and once using the regulation method of the present invention based on a first order model + delay + dynamic factor.

Figure 4 illustrates the performances obtained without and with regulation (diagrams 4A and 4B respectively) in accordance with the present invention. The diagrams show on the abscissa the time expressed in hours and on the ordinate the MFI expressed in g / 10 min and measured using a Gottferd device. The diagrams also show the upper and lower limits of the specifications.

Claims

R E V E N D I C A T I O N S

1 - Method for regulating a property of a product resulting from a chemical transformation process, comprising a) modeling the relationship between said property and characteristic quantities of the process, b) fixing a set value for said property, c) the introduction of this setpoint in a regulation system based on the model obtained in (a) in order to apply to the process at least one characteristic quantity calculated from this setpoint, d) the calculation using the model defined in (a), corrected by a factor taking into account the delay, of a model value of the property of the product corresponding to the characteristic quantity (s) defined ) by the regulatory system, e) continuous measurement of the real value of product ownership, f) determination of the difference between this real value and the model value of product ownership, g) use of this gap, ap very filtering, to adapt the setpoint so as to align the actual value and its model value.

2 - Method of regulation according to claim 1, in which the calculation (d) of the model value corresponding to the characteristic quantity (s) is carried out using the model defined in (a) corrected by the factor taking into account the delay and by a factor taking into account the dynamics of the process.

3 - Method of regulation according to any one of claims 1 or 2, applied to a process for the transformation of a polymer in an extruder such as for example a depolymerization process using as reactants one or more polymers and one or more depolymerization agents.

4 - Method according to any one of claims 1 to 3, wherein the measurement of the real value of the property of the product is done on a sample of finished product.

5 - Method of regulation according to any one of the preceding claims, in which the filter used is a low-pass type filter. 6 - Method of regulation according to any one of claims 1 to. 5, in which the model is based on an equation of the npnp type

MV = a + bIV + ∑ ∑ c iRj] ¹ ₊ ∑ ∑ dy W] ¹ + i = lj = li = \ j = l

or :

MV represents the model value or estimated value IV represents the initial value of the property [Rj] represents the concentrations of the reagents

[Tj] represents temperatures characteristic of the process [Pj] represents pressures characteristic of the process [Fj] represents the flow rates of reagents a, b, CJJ, djj, ejj and fjj are constants i and j are natural integers greater than or equal at 1.

7 - Method of regulation according to any one of claims 1 to 5, in which the model is based on an equation of the type npn P logMV = a '+ b'loglV + ∑ ∑ c'y [Rj] ¹ + ∑ ∑ y [Tjf + i = lj = li = lj = \ npn P

∑ ∑ e'ij [Pj ï + ∑ ∑ f'ij [F ^j ii = lj = li = \ j = \

or :

[Tj] represents temperatures characteristic of the process [Pj] represents pressures characteristic of the process [Fj] represents the flow rates of reagents a ', b', c'jj, d'jj, e'jj and fjj are constants i and j are natural integers greater than or equal to 1.

8 - Method of regulation according to any one of claims 1 to

7, wherein the delay factor is obtained by using a shift register.

9 - Method of regulation according to any one of claims 1 to

8, in which the factor taking into account the dynamics of the process is represented by a LAG or low pass filter type function.

10 - Device for regulating a property of a product resulting from a chemical transformation process, comprising - at least one unit allowing the regulation of at least one characteristic quantity on the basis of a set value of the property to regulate, at least one calculation unit allowing the determination of a model value of the property to be regulated from the values of the characteristic quantity (s) defined by the regulator, - means for continuous measurement of the real value of the property of the product, means of determining the difference between the real value and the model value of the property and of filtering this difference, means making it possible to adapt the set value of so as to reduce this difference.

11 - Device according to claim 10, characterized in that it uses a method according to any one of claims 1 to 9.

12 - Device according to claim 10, wherein the calculation unit uses a proportional, integral and / or differential term model corrected by a factor taking into account the delay and possibly by a factor taking into account the dynamics of the process.

13 - Device according to claim 12, wherein the regulator uses the inverse of the model established for the computing unit.

14 - Device according to any one of claims 10 to 13, in which the quantities characteristic of the chemical transformation process are chosen from the concentrations and flow rates of reagents, the residence times, the pressures and / or the temperatures of one or more of several process steps. 15 - Method of chemical transformation using a regulation device according to any one of claims 10 to 14 or implementing a regulation method according to any one of claims 1 to 9, to control and regulate a property of a product resulting from a chemical transformation process.

16 - Process according to claim 15, characterized in that the chemical transformation is a depolymerization reaction using as reactants one or more polymers and one or more depolymerization agents.

17 - Process according to claim 16, characterized in that at least one of the polymers is a polyolefin.

18 - Process according to claim 17, characterized in that the polyolefin is polypropylene.

19 - Process according to any one of claims 16 to 18, characterized in that at least one depolymerization agent is chosen from oxygen, oxygen-rich compounds, peroxides, persulfates and diazo compounds.

20 - Method according to any one of claims 16 to 19, characterized in that the property of the product to be controlled and regulated is the melt flow index (MFI).

21 - Process according to claim 20, characterized in that the determination of the melt flow index (MFI) is carried out using a rheometer, an IR spectrometer, an NIR spectrometer, an NMR spectrometer and / or an ultrasonic analyzer.

22 - Method according to any one of claims 15 to 21, characterized in that the determination of the real value of the property of the product is carried out directly online.

23 - Process according to claim 22, characterized in that the determination of the real value of the property of the product is carried out on a sample of the finished product. 24 - Process according to any one of claims 16 to 23 applied to the regulation of the melt flow index (MFI) of a polymer, in which the model value of the MFI is calculated based on the model

MFI _out = A + B. MFI _in + C. [PER] + DT where

MFI _or t represents the estimated melt flow index of the depolymerization product

MFIj _n represents the melt flow index of the polymer reagent A, B, C and D represent constants [PER] represents the concentration of depolymerization agent, and

25 - Process according to any one of claims 16 to 23 applied to the regulation of the melt flow index (MFI) of a polymer, in which the model value of MFI is calculated on the basis of the model \ gMFI _out = A '+ B'ΛogMFI _in + C'. [PER] + D'T where

MFI _0U t represents the estimated melt flow index of the depolymerization product

MFIj _n represents the melt melt index of the polymer reagent A ', B', C and D 'represent constants

[PER] represents the concentration of depolymerization agent, and

26 - Process according to any one of claims 16 to 23, applied to the regulation of the melt flow index (MFI) of a polymer, in which the model value of the MFI is calculated based on the model

\ gMFI _out = A "+ B". \ ogMFl _in + Cι ". [PER] + C2" - [PER] ² + D ".T where

MFI _0U t represents the estimated melt index of the product of the depolymerization FIj _n represents the melt index of the polymer reagent A ", B", Ci ", C2" and D "represent constants [PER] represents the concentration of depolymerization agent, and T represents the temperature at which the depolymerization reaction takes place. 27 - Method according to any one of claims 24 to 26, wherein the delay factor is obtained using a shift register.

28 - Process according to any one of claims 24 to 26, in which the factor taking into account the dynamics of the process is represented by first-order low-pass filter.

29 - Process according to any one of claims 24 to 28, in which the melt flow index is regulated by adjusting the concentration of depolymerization agent or by adjusting the flow rate of said depolymerization agent.

30 - Method according to any one of claims 24 to 29, characterized in that the melt melt index of the polymer reagent (MFIj _n ) and / or the temperature (T) are assumed to be constant.