EP1272070B1 - Method for producing bristles used to administer media, bristles produced according to said method and brushware comprising bristles of this type - Google Patents

Method for producing bristles used to administer media, bristles produced according to said method and brushware comprising bristles of this type Download PDF

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Publication number
EP1272070B1
EP1272070B1 EP01933759A EP01933759A EP1272070B1 EP 1272070 B1 EP1272070 B1 EP 1272070B1 EP 01933759 A EP01933759 A EP 01933759A EP 01933759 A EP01933759 A EP 01933759A EP 1272070 B1 EP1272070 B1 EP 1272070B1
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EP
European Patent Office
Prior art keywords
bristle
core
cavities
medium
jacket
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP01933759A
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German (de)
French (fr)
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EP1272070A1 (en
Inventor
Georg Weihrauch
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Pedex GmbH
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Pedex GmbH
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Publication date
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Publication of EP1272070A1 publication Critical patent/EP1272070A1/en
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    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46BBRUSHES
    • A46B15/00Other brushes; Brushes with additional arrangements
    • A46B15/0002Arrangements for enhancing monitoring or controlling the brushing process
    • A46B15/0004Arrangements for enhancing monitoring or controlling the brushing process with a controlling means
    • A46B15/001Arrangements for enhancing monitoring or controlling the brushing process with a controlling means with means indicating the remaining useful life of brush
    • AHUMAN NECESSITIES
    • A46BRUSHWARE
    • A46DMANUFACTURE OF BRUSHES
    • A46D1/00Bristles; Selection of materials for bristles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2929Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]

Definitions

  • the invention relates to a method for producing Bristles for applying media by adding bristles cut-to-length filament extruded and with recesses for Recording of the medium is provided, from which the medium if the bristles are used as intended.
  • the invention further relates to those produced by this method Bristles and bristles with such bristles.
  • Bristle goods with bristles for applying media in Above all, liquid, viscous or powdery form in the field of body, hair and oral care, but also in the household and in the technical area of application. below the invention is primarily in connection with Toothbrushes as one of the essential application examples described.
  • the hollow bristle may also be radial Walls braced so that they are three or four axially parallel Has chambers.
  • the desired media are in introduced in liquid form. To this end become filaments with the cross-sectional shape of the finished bristle extruded and multiple filaments into multi-strand strands up to 5.5 cm in diameter and up to a length 1.2 m combined. The strand will end with one dipped in the liquid medium and on the opposite open ends of the filaments created negative pressure.
  • a polymer article is known from US Pat. No. 4,775,585 known in the form of a fiber which has a full cross section, a medium in partial areas of the cross section is introduced, which is released from the fiber in use shall be.
  • the subareas of the medium contained in the Fiber can either be circular sectors over the circumference be distributed or an outer ring of cross section form. A defined delivery of the medium is based on this Way not to achieve.
  • the invention has for its object a method propose using the media of any consistency and any Effect in an economical way in a bristle introduced and when used as intended in the desired Dosage during the life of the bristle can be delivered.
  • the media of made on the outside in the recesses open to the outside do not have to go through a pressure drop alone over a greater distance with corresponding pressure losses be sucked in.
  • the recesses can in particular can also be filled with a constant media density.
  • the consistency of the media also plays a role in the contribution no significant role; they can be liquid, viscous or be dispersed.
  • the delivery in use takes place immediately through the circumferential gaps or openings by this are so narrow that the medium is held back and can only emerge when used, for example by the forces occurring when brushing or by am Use existing media that match the medium in the Bristles interact and wash them out or detach.
  • the come Saliva or a dentifrice the simplest for cleaning brushes Fall water or moisture in question.
  • the filament with a mechanical Properties of the bristle with extruding core extruded will, the recesses spaced from the center of the core molded in and opening to the circumference of the filament and be filled with the medium from the outside, and that then on the filament at least in some areas layer at least partially covering the recesses is applied, which the release of the medium under the when the bristle is used as intended Controls conditions.
  • this procedure there is less crucial to the shape of the circumferential opening and on the opening width. Rather, by choosing the material of the layer, its thickness and the Extent of coverage of the recesses containing the medium the delivery of the medium in time and depending on the service life of those equipped with such bristles Bristle goods can be controlled.
  • the medium can be opened Bristle end or by the slow wear of the Jacket exposed openings of the recesses or are released by diffusion through the jacket, whereby the coat in contrast to the bristle according to WO 98/24341 can be comparatively thin-walled, since it is filled is not exposed to compressive forces.
  • the recesses are formed when extruding the filament become.
  • the recesses are preferred essentially axially parallel, possibly with a distance molded from each other.
  • the recesses are located away from the center of the core molded outward extending capillary gaps be or that the recesses as channels with circumferential openings narrowed into a gap.
  • the capillary-like gaps result in a retention effect for the medium and this is only among the Use prevailing conditions, e.g. B. by brush pressure, delivered by external media or the like.
  • the shape and / or the width of the column matched to the consistency of the medium. It is also of advantage if the gaps are molded so that they are completely closed in the unloaded state and only open under pressure.
  • the recesses that are open to the outside can be particularly economically in a continuous process on one Fill continuous filament. This can be done in that the filament through a media bath, if necessary under Pressure is set, or by a nozzle-like narrowing Cross section with the medium supplied on the circumference is passed through. Is the opening width of the recesses large enough and the consistency of the medium sufficient Filling can also be viscous without pressure using the continuous process happen. In this case it is recommended to make the recesses then by one applied to the filament Close coat.
  • the jacket is preferably made of a thermoplastic Plastic on the filament filled with the medium is extruded. It is preferably extruded in excess and shrink-wrapped onto the filament, which is particularly gentle on thermally sensitive media stay; liquid components cannot evaporate and thermally reactive components do not decompose. Becomes a jacket, as mentioned above, made of one that is permeable to the medium Applied plastic, he can if necessary partially by a diffusion-proof material to be covered locally and / or the rate of diffusion to control.
  • the coat is made of a transparent plastic, can media consumption, for example through appropriate Coloring of the media, optically controlled, if necessary the type of media can also be visualized.
  • an effect indicator for the Bristle function may be provided to ensure that the bristle is only used as long as it is used for the has the required properties as intended, or to design the bristle technically so that it is no longer used as practicable. This can be done happen that a jacket made of a thermoplastic Plastic with fillers that determine its wear factor is applied to the filament, the plastic and the fillers added to the permissible Degree of wear of the bristle when used as intended be coordinated. With this procedure you can also any other bristles that may only be made consist of a core and a jacket, with an effective indicator equip.
  • the wear factor solid articles are particularly suitable, which the Reduce intermolecular bond in the polymer of the jacket and control the wear factor by type, size and quantity.
  • the solids can be selected so that they are at the same time in the application perform a function, e.g. B. calcium carbonate or chloride as reminalizing agents in toothbrushes.
  • the addition of waxes, especially ionomer wax also has proved to be favorable, since these are in the polymer matrix distribute more evenly and thus for a more even Cause wear factor. This also makes the gliding behavior the bristle is influenced favorably. That is at the same time a fine adjustment of an effective indication is also possible.
  • different media with different functions can also be layered in the recesses or housed separately locally and correspondingly dispensed locally separately.
  • components of an active ingredient that are affine to one another and are only supposed to develop their effect on site, for example, can be accommodated locally separately.
  • An example is the desired formation or regression of calcium fluoride layers on the teeth, which can be formed in the ionizing medium from Ca (+) and F (-) ions, which in turn are made up of locally separated Ca and F compounds in the humid atmosphere of the mouth and throat can be generated.
  • the media or active ingredient components can also by a Layered accommodation in the recesses separately and only be brought together at the time of delivery.
  • the diffusion rate can also be achieved through layer formation control the media or active ingredients.
  • the core can be extruded as a monofilament or multi-core. and can optionally the core and / or the jacket can also be foamed during extrusion or afterwards.
  • the invention relates to a bristle that consists of the Filament produced according to the invention by cutting to length Desired size is obtained, as well as a bristle product with a Bristle holder, on the bristles of the type mentioned below Formation of the bristle or part thereof attached become.
  • the Bristles should be closed at least at their use end. This can be done, for example, by thermal methods such as welding, friction welding, laser welding or the like. happen.
  • Fig.1 shows in figures a) to f) different process stages in the production of a filament from which Bristles can be obtained by cutting to length.
  • the Filament 1 is in the form of a mechanical properties the later determining bristle core 2 in conventionally extruded from a plastic melt.
  • the Core 2 from a massive center 3 with outgoing from there and outwardly opening recesses 4, which at this embodiment by a cross-like profile of the extruded core can be obtained (Fig.1a).
  • the filament is then stretched in a conventional manner (Fig.1b) in order to obtain a molecular longitudinal orientation.
  • the cross-section becomes due to the lengthening when the core is stretched reduced accordingly.
  • the Core 2 advantageously thermally stabilized (Fig.1c)
  • the filament extruded and pretreated in this way 1 with its recesses 4 is then with the Medium 6 filled.
  • the filament 1 is through one indicated in FIG. 1d with a circular line 5 Canal pulled, which may be different from a larger one Cross section nozzle-like to the cross section of the core 2 narrowed and into which the medium is constantly fed, so that the medium 6 of the recesses 4 of the filament 1st is recorded.
  • the medium 6 can also be under Pressure can be supplied, as indicated by the hint in Fig. 1e a greater density of the medium 6 is indicated.
  • a sheath layer 7 to the medium filled filament, which is film-like and is in use the bristle wears out quickly to release the medium 6.
  • this cladding layer 7 can also be a thin-walled one Acting coat that is made of an open to diffusion Polymer exists that either diffuses the medium 6 enabled at the place of use of the bristle or only in connection with media at the place of use, e.g. Saliva, water or the like acquires the necessary permeability.
  • the coat 7 is preferably on the already filled filament 1 extruded with excess compared to the core 2 and then shrunk onto the core by cooling.
  • the bristle 8 thus consists of a core 2 with the Medium 6 in the recesses and the jacket 7.
  • FIG. 3 shows schematically a section of a bristle product 62, e.g. in the area of the head of a toothbrush, with a Bristle holder 9 to which the bristles 8 are attached.
  • a Bristle holder 9 to which the bristles 8 are attached.
  • the toothbrush 8 pressure and act on the bristle Bending forces that to the schematically indicated, temporary Deform bristle 8. Based on these Forces the medium 6 occurs, as indicated by the directional arrows, at the free end of the bristle. At the same time diffuses the medium if there is an appropriate composition has, through the walls of the jacket, if necessary with the participation of the media available at the place of use such as saliva, water, dentifrices or the like. This is shown again in FIG. 4 on an enlarged scale.
  • Fig. 5 to 10 show cross sections of filaments 1, which is a separate one depending on the consistency of the medium Do not require coating or a coat.
  • Fig. 5 shows a filament that is in the form of an essentially circular core 2 extruded with a solid center 3 is.
  • recesses are made molded in the form of capillary-like column 10, which in the shown Embodiment in regular, radial arrangement are provided.
  • the capillary gaps 10 are in the manner described with reference to Fig.1 filled the medium.
  • Figure 6 shows a similar embodiment in which the capillary Column 10 additionally in the direction of extrusion are provided with a profile 11, whereby a better Retention for the medium is achieved.
  • the filament 1 in turn from a solid core 2 and an outer Core part 12, which can consist of a different plastic than the core 2, for example from one of the later Bristle imparting the necessary mechanical properties Polymer is formed while the core part 12 is made of another, tailored to the usage properties Polymer can exist.
  • the filament 1 is axially parallel to the core 2 channel-like recesses 13 on the gap-like Open openings 14 on the circumference of filament 1.
  • 8 again shows a filament 1 in the form of an extruded one Core 2, which is only a few near the circumference, evenly distributed channels 15 with a gap-like opening 16 has.
  • the filament is 1 again extruded as core 2 with a solid center 3, of which a large number of capillary-like gaps 17 Extend outward like a shovel.
  • the capillary Columns 17 are approximately 18 at the circumference of filament 1 closed.
  • the capillary-like column 17 is scoop-shaped delimiting webs 20 are elastically deformable.
  • excess medium is turned in the opposite direction or by passing a corresponding one Envelope cross-section squeezed so that the capillary Column 17 on the circumference of filament 1 or the later bristle are almost closed.
  • the bristle goods with bristles equipped in this way the compressive forces cause the bristle to deform, so that the medium emerges on the circumference.
  • FIG. 10 shows a filament 1 with a rectangular cross section, in which in turn axially parallel channels 21 are formed, the openings 22 narrowed at the circumference of the filament 1 flow out.
  • FIG. 11 shows a filament 1 with sector-shaped recesses 23, and a central core 3, that of transverse Channels 24 is interspersed.
  • the sector-shaped recesses 23 and the transverse channels 24 are filled with the medium.
  • This filament 1 is advantageously turn coated with a film or with an extruded one Coat provided as described with reference to Figures 1 to 4 is.
  • Fig. 12 shows a filament 1 in the form of a coiled Core 2, in which the recesses 63 extend helically.
  • This version of the filament 1 can also easily fill with the medium and will advantageously then extruded a jacket.
  • Fig. 13 shows one Filament 1 in the form of a wavy core 2, in which the recesses 64 are formed by the wave troughs, 14 with a filament 1 in the form of a core 2 annular recesses 65 reproduces. Even with these Both embodiments are preferably made after filling of the filament 1 extruded a sheath.
  • FIG. 16 shows a filament 1 with an extruded core 2 of rectangular cross section, for example, by a circular channel is drawn, moving the medium 6 builds on the side surfaces of the rectangular core 2. Then a jacket 7 is extruded and if necessary fixed by cooling and shrinking.
  • Fig.17 gives a core 2 with evenly distributed Wells 26 again, in the same way as before described can be filled with the medium 6. On the Core 2 with the medium 6 is then again a coat 7 extruded.
  • the exemplary embodiment according to FIG. 18 differs from that of Fig. 17 only by the shape and number of depressions 26.
  • the embodiment according to FIG. 19 is again a filament in the form of a core 2 with a cross-shaped cross-section with the formation of open to the outside Recesses 27 which are filled with the medium.
  • the core 2 has bulges 28 at the free ends of its arms Thickenings 29 on.
  • a jacket 30 is extruded, the the beaded thickenings. 29 includes so that a kind positive connection is created.
  • the embodiment of FIG. 20 characterized in that the Arms 28 of core 2 run straight and after filling the recesses formed between the arms 28 of the jacket 31 is extruded and shrunk.
  • Fig. 21 shows a filament 1 in the form of a core 2, wherein different designs of recesses are indicated. These can be groove-like, straight-line depressions 32 or groove-shaped, curved recesses 33 or around act individual hole-like depressions 34.
  • the filament has 1 a core 2 with recesses in the form of equidistant arranged slots 35 which are transverse to the axis of the Filaments run and, for example, after extrusion be molded.
  • Fig. 24 shows a filament 1, the core 2 of a variety parallel Mönofile 36 exists, the recesses formed by the spaces 37 between the monofilaments 36 become. After filling the gaps and if necessary calibrating the monofilament accordingly a jacket 38 extruded.
  • Fig. 25 shows a filament 1 in the form of a core 2, which is similar the embodiment of Figure 7 with one or more axially parallel channels 39 is provided, which over extend gap-like openings 40 to the outside. additionally can openings 41 with a slightly larger cross section at a distance be provided from each other.
  • the same filament is used as in Fig. 26 with a core 2 with recesses 42 a sheath 44 made of a diffusion-open polymer, for example the one on the surface of the bristle desired properties.
  • a sheath 44 made of a diffusion-open polymer, for example the one on the surface of the bristle desired properties.
  • Fig. 28 shows a filament 1 with a star-shaped cross section Core, in which the recesses 46 between the Star points are formed and on the turn a coat 47 is extruded.
  • the jacket 47 with a plastic or textile fiber bandaged.
  • the filament is made 1 from a core 2 similar to the embodiment according to Fig.11 with sector-shaped recesses 23 and an extruded Sheath 49, which is provided with a perforation 50 is, on the one hand, a controlled escape of the medium allow, on the other hand, the surface of the finished bristle give a structure that increases the brushing effect.
  • Fig. 30 shows a filament 1 with a cross shape Core 2 and a jacket 7.
  • media 51, 52 and 53 housed, which issued simultaneously and either have different effects or but consist of components that only close at the place of use react to an active ingredient. Instead, different ones Media is also layered in a recess become.
  • the filament 1 according to FIG. 31 again consists of a Core 2, the irregularly arranged recesses 54, 55 and 56 and is surrounded by a jacket 7. Also here the recesses can be made according to their size and Shape absorb different media.
  • Figure 32 shows a portion of a bristle 8 that is similar that is constructed according to FIG. 2, that is to say from a core 2 with in its recesses medium 6 and a Coat 7 is made.
  • the bristle 8 is on its usage side End 57 closed, for example by the jacket 8 is thermally shaped accordingly.
  • FIG. 33 and 34 show an embodiment of a bristle 8 with open end 58, in FIG. 33 in the initial state and in Fig. 34 after a certain period of use, while the coat 8 has been removed and the medium has been dispensed is. This means that both mechanical wear, as well as the delivery of the medium is visually visible.
  • Fig. 35 to 38 shows another variant for the indication of Media consumption and / or wear of the bristle.
  • the purpose of the core 2 may be several at a distance Recesses arranged from each other in the form of circumferential Grooves or the like in which an indicator medium 59 is housed.
  • an indicator medium 59 is housed.
  • the Wear of the jacket 7 in the region of the end 58 of the bristle 8 and only core 2 remains. Disappear successively the markings 59 so that the user on the one hand about the delivery of the medium or the wear the bristle is visually informed.
  • Fig. 39 shows a bristle 8, on which regular Wear at the end of 59 a more or less regular top 60 training.
  • the core 2 an annular groove 61, possibly with a Indicator medium can be filled so that after disappearing the same signals the expiry of the (optimal) service life becomes.

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  • Brushes (AREA)
  • Artificial Filaments (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Noodles (AREA)

Description

Die Erfindung betrifft ein Verfahren zur Herstellung von Borsten zum Applizieren von Medien, indem ein zu Borsten ablängbares Filament extrudiert und mit Ausnehmungen zur Aufnahme des Mediums versehen wird, aus denen das Medium bei bestimmungsgemäßem Gebrauch der Borsten abgegeben wird. Ferner betrifft die Erfindung nach diesem Verfahren hergestellte Borsten und Borstenwaren mit solchen Borsten.The invention relates to a method for producing Bristles for applying media by adding bristles cut-to-length filament extruded and with recesses for Recording of the medium is provided, from which the medium if the bristles are used as intended. The invention further relates to those produced by this method Bristles and bristles with such bristles.

Borstenwaren mit Borsten zum Applizieren von Medien in flüssiger, viskoser oder pulverartiger Form finden vor allem im Bereich der Körper-, Haar- und Mundpflege, aber auch im Haushalt und im technischen Bereich Anwendung. Nachstehend ist die Erfindung vornehmlich im Zusammenhang mit Zahnbürsten als eines der wesentlichen Anwendungsbeispiele beschrieben.Bristle goods with bristles for applying media in Above all, liquid, viscous or powdery form in the field of body, hair and oral care, but also in the household and in the technical area of application. below the invention is primarily in connection with Toothbrushes as one of the essential application examples described.

Bei Zahnbürsten ist es bekannt, Zahnbelag durch Aufbringen einer geeigneten Indikatorfarbe kenntlich zu machen, um den Benutzer der Zahnbürste zum verstärkten Bürsten der solchermaßen indizierten Stellen der Zähne zu veranlassen (DE 195 45 644). Zu diesem Zweck sind die Borsten mit der Indikatorfarbe oder mit diese Farbe enthaltenden Mikrokapseln beschichtet und ist die Schicht gegebenenfalls zusätzlich versiegelt. Auch eine Hohlborste mit eingebrachtem Indikatormedium ist in diesem Zusammenhang beschrieben. Wie diese Hohlborsen gefüllt werden, ist in der Druckschrift nicht erläutert. Ferner ist es bekannt (CA 549 168), die Borsten einer für den einmaligen Gebrauch bestimmten Zahnbürste mit einem Zahnpflegemittel zu beschichten. Auch sind Borsten bekannt (US 5.678.275), die am Umfang mit unregelmäßig gestalteten Furchen versehen sind. Sie dienen aber nicht zur Aufnahme von Medien, sondern sollen beim Zähneputzen Schmutzpartikel aufnehmen, um diese aus dem Mundraum zu entfernen.With toothbrushes, it is known to apply dental plaque a suitable indicator color to indicate the Toothbrush users to intensify brushing in such a way to induce indicated areas of the teeth (DE 195 45 644). For this purpose, the bristles with the Indicator color or with microcapsules containing this color coated and the layer is optionally additional sealed. Also a hollow bristle with an inserted indicator medium is described in this context. How these hollow bores are filled is in the publication not explained. It is also known (CA 549 168) that Bristles of a single-use toothbrush to be coated with a dentifrice. Also are Bristles known (US 5,678,275) that are irregular on the circumference designed furrows. But they serve not to hold media, but should be used when brushing teeth Pick up dirt particles to get them out of your mouth to remove.

Es ist weiterhin bekannt (WO 98/24341), therapeutisch wirksame Medien oder sonstige Medien mit dentalmedizinischer Wirkung in einer Hohlborste unterzubringen, die bei Gebrauch am freien offenen Ende der Borste abgegeben werden sollen. Die Hohlborste ist gegebenenfalls auch durch radiale Wände ausgesteift, so daß sie drei oder vier achsparallele Kammern aufweist. Die gewünschten Medien werden in flüssig aufbereiteter Form eingebracht. Zu diesem Zweck werden Filamente mit der Querschnittsform der fertigen Borste extrudiert und mehrere Filamente zu mehradrigen Strängen mit bis zu 5,5 cm Durchmesser und einer Länge bis zu 1,2 m zusammengefaßt. Der Strang wird mit seinem einen Ende in das flüssige Medium getaucht und an den gegenüberliegenden offenen Enden der Filamente Unterdruck angelegt. Da aufgrund der kapillarartigen Hohlräume und der großen Stranglänge ein hoher Unterdruck erforderlich ist und ein Kollabieren der Wände aufgrund der Elastizität der hier in Frage kommenden Kunststoffe vermieden werden muß, zwingt dies zu großen Wandstärken und läßt sich ein vollständiges Füllen der Hohlborsten kaum verwirklichen. Viskose oder disperse Medien lassen sich wegen des hohen Druckabfalls in den kapillarartigen Hohlräumen überhaupt nicht einbringen. Bei Gebrauch der Borste erfolgt die Abgabe des Mediums nur über das offene Ende der Borsten und damit völlig unkontrolliert und unvollständig. It is also known (WO 98/24341), therapeutically effective Media or other media with dental medicine Effect to accommodate in a hollow bristle that is in use be delivered to the free open end of the bristle should. The hollow bristle may also be radial Walls braced so that they are three or four axially parallel Has chambers. The desired media are in introduced in liquid form. To this end become filaments with the cross-sectional shape of the finished bristle extruded and multiple filaments into multi-strand strands up to 5.5 cm in diameter and up to a length 1.2 m combined. The strand will end with one dipped in the liquid medium and on the opposite open ends of the filaments created negative pressure. There due to the capillary-like cavities and the large ones A length of high vacuum is required and a Collapse of the walls due to the elasticity of the in here Questioning upcoming plastics must be avoided this to large wall thicknesses and can be a complete Hardly fill the hollow bristles. Viscose or disperse media can be in because of the high pressure drop do not insert the capillary-like cavities at all. When using the bristle, the medium is only dispensed over the open end of the bristles and thus completely uncontrolled and incomplete.

Aus der US 4 775 585 ist ein Polymer-Artikel beispielsweise in Form einer Faser bekannt, die einen Vollquerschnitt aufweist, wobei in Teilbereiche des Querschnittes ein Medium eingebracht wird, das bei Gebrauch aus der Faser abgegeben werden soll. Die das Medium enthaltenen Teilbereiche der Faser können dabei entweder als Kreissektoren über den Umfang verteilt sein oder einen äußeren Ring des Querschnittes bilden. Eine definierte Abgabe des Mediums ist auf diese Weise nicht zu erreichen.For example, a polymer article is known from US Pat. No. 4,775,585 known in the form of a fiber which has a full cross section, a medium in partial areas of the cross section is introduced, which is released from the fiber in use shall be. The subareas of the medium contained in the Fiber can either be circular sectors over the circumference be distributed or an outer ring of cross section form. A defined delivery of the medium is based on this Way not to achieve.

04 09. 2002 Aus der US 4 101 308 ist eine Faser bekannt, die mit einer porösen Beschichtung versehen wird, in deren Hohlräume ein Medium eingebracht wird. Aufgrund der offenen Hohlräume wird das Medium jedoch relativ schnell und unkontrolliert abgegeben. Zur Bildung einer elektrisch leitenden Faser kann als Medium ein Elektrolyt verwendet und die Faser außenseitig mit einer isolierenden, undurchlässigen Beschichtung aus Schellack versehen werden. Eine Abgabe des Mediums ist dabei nicht vorgesehen.04 09. 2002 From US 4 101 308 a fiber is known, which with a porous coating is provided in the cavities Medium is introduced. Because of the open cavities however, the medium becomes relatively quick and uncontrolled issued. To form an electrically conductive fiber can use an electrolyte as the medium and the fiber on the outside with an insulating, impermeable coating be made from shellac. A delivery of the medium is not provided.

Der Erfindung liegt die Aufgabe zugrunde, ein Verfahren vorzuschlagen, mit dem Medien beliebiger Konsistenz und beliebiger Wirkung in wirtschaftlicher Weise in eine Borste eingebracht und beim bestimmungsgemäßen Gebrauch in der gewünschten Dosierung während der Nutzungsdauer der Borste abgegeben werden können.The invention has for its object a method propose using the media of any consistency and any Effect in an economical way in a bristle introduced and when used as intended in the desired Dosage during the life of the bristle can be delivered.

Diese Aufgabe wird erfindungsgemäß durch ein Verfahren gemäß Anspruch 1 oder ein Verfahren gemäß Anspruch 2 gelöst. In einer ersten Ausgestaltung der Erfindung ist vorgesehen, daß das Filament mit einem die mechanischen Eigenschaften der Borste mitbestimmenden Kern extrudiert, die Ausnehmungen mit Abstand vom Zentrum des Kerns ausgehend und sich zum Umfang des Filaments öffnend eingeformt und mit einer umfangsseitigen Öffnung in Form eines Spaltes ausgebildet und von außen mit dem Medium gefüllt werden, wobei die Spalte so geformt werden, daß sie im unbelasteten Zustand der Borste geschlossen sind und sich unter Druck erst unter den beim bestimmungsgemäßen Gebrauch der Borste herrschenden Bedingungen öffnen, so daß das Medium abgegeben wird.This object is achieved according to the invention by a method Claim 1 or a method according to claim 2 solved. In a first embodiment of the invention, that the filament with the mechanical properties the bristle co-determines the core, the recesses starting from and away from the center of the core molded to the circumference of the filament and with a peripheral opening formed in the form of a gap and be filled with the medium from the outside, the Columns are shaped so that they are unloaded the bristles are closed and under pressure only under those prevailing when the bristle is used as intended Open conditions so that the medium is dispensed.

Bei dem erfindungsgemäßen Verfahren werden die Medien von außen her in die nach außen offenen Ausnehmungen eingebracht, müssen also nicht allein durch ein Druckgefälle über eine größere Distanz mit entsprechenden Druckverlusten eingesaugt werden. Die Ausnehmungen können somit insbesondere auch mit gleichbleibender Mediendichte gefüllt werden. Auch spielt die Konsistenz der Medien für das Einbringen keine maßgebliche Rolle; sie können flüssig, viskos oder dispers sein. Die Abgabe bei Gebrauch erfolgt unmittelbar durch die umfangseitigen Spalte bzw. Öffnungen, indem diese so eng gestaltet sind, daß das Medium zurückgehalten wird und erst bei Gebrauch austreten kann, beispielsweise durch die beim Bürsten auftretenden Kräfte oder durch am Gebrauchsort vorhandene Medien, die mit dem Medium in der Borste in Wechselwirkung treten und diese ausschwemmen oder herauslösen. Im Falle einer Zahnbürste kommen hierfür der Speichel oder ein Zahnpflegemittel, bei Reinigungsbürsten im einfachsten Fall Wasser oder Feuchtigkeit in Frage.In the method according to the invention, the media of made on the outside in the recesses open to the outside, do not have to go through a pressure drop alone over a greater distance with corresponding pressure losses be sucked in. The recesses can in particular can also be filled with a constant media density. The consistency of the media also plays a role in the contribution no significant role; they can be liquid, viscous or be dispersed. The delivery in use takes place immediately through the circumferential gaps or openings by this are so narrow that the medium is held back and can only emerge when used, for example by the forces occurring when brushing or by am Use existing media that match the medium in the Bristles interact and wash them out or detach. In the case of a toothbrush, the come Saliva or a dentifrice, the simplest for cleaning brushes Fall water or moisture in question.

In einer anderen vorteilhaften Ausführung des Verfahrens ist vorgesehen, daß das Filament mit einem die mechanischen Eigenschaften der Borste mitbestimmenden Kern extrudiert wird, die Ausnehmungen mit Abstand vom Zentrum des Kerns ausgehend und sich zum Umfang des Filaments öffnend eingeformt und von außen mit dem Medium gefüllt werden, und daß anschließend auf das Filament zumindest bereichsweise eine die Ausnehmungen zumindest teilweise abdeckende Schicht aufgebracht wird, welche die Abgabe des Mediums unter den beim bestimmungsgemäßen Gebrauch der Borste herrschenden Bedingungen steuert. Bei diesem Verfahren kommt es weniger entscheidend auf die Form der umfangseitigen Öffnung und auf die Öffnungsweite an. Vielmehr kann durch die Auswahl des Materials der Schicht, durch deren Dicke und durch das Ausmaß der Abdeckung der das Medium enthaltenden Ausnehmungen die Abgabe des Mediums zeitlich und in Abhängigkeit von der Gebrauchsdauer der mit solchen Borsten ausgerüsteten Borstenware gesteuert werden.In another advantageous embodiment of the method it is intended that the filament with a mechanical Properties of the bristle with extruding core extruded will, the recesses spaced from the center of the core molded in and opening to the circumference of the filament and be filled with the medium from the outside, and that then on the filament at least in some areas layer at least partially covering the recesses is applied, which the release of the medium under the when the bristle is used as intended Controls conditions. With this procedure, there is less crucial to the shape of the circumferential opening and on the opening width. Rather, by choosing the material of the layer, its thickness and the Extent of coverage of the recesses containing the medium the delivery of the medium in time and depending on the service life of those equipped with such bristles Bristle goods can be controlled.

Werden, wie vorzugsweise vorgesehen, die Ausnehmungen durch einen Mantel verschlossen, kann das Medium über das offene Borstenende oder durch die bei der langsamen Abnutzung des Mantels freigelegten Öffnungen der Ausnehmungen oder auch durch Diffusion durch den Mantel abgegeben werden, wobei der Mantel im Gegensatz zur Borste nach der WO 98/24341 vergleichsweise dünnwandig sein kann, da er beim Füllen keinen Druckkräften ausgesetzt ist.Are, as preferably provided, the recesses closed a coat, the medium can be opened Bristle end or by the slow wear of the Jacket exposed openings of the recesses or are released by diffusion through the jacket, whereby the coat in contrast to the bristle according to WO 98/24341 can be comparatively thin-walled, since it is filled is not exposed to compressive forces.

Ein besonders wirtschaftliches Verfahren ergibt sich dann, wenn die Ausnehmungen beim Extrudieren des Filaments ausgeformt werden. Hierbei werden die Ausnehmungen vorzugsweise im wesentlichen achsparallel, gegebenenfalls mit Abstand voneinander eingeformt.A particularly economical process results if the recesses are formed when extruding the filament become. Here, the recesses are preferred essentially axially parallel, possibly with a distance molded from each other.

Eine andere Variante besteht darin, daß die Ausnehmungen nach dem Extrudieren des Filaments ausgeformt werden. Dabei kommt eine im wesentlichen radiale Einformung von Ausnehmungen beliebiger Kontur und Anordnung in Frage.Another variant is that the recesses after extruding the filament. there there is an essentially radial indentation of recesses any contour and arrangement in question.

Bei beiden vorgenannten Verfahrensvarianten kann vorgesehen sein, daß die Ausnehmungen als sich vom Zentrum des Kerns nach außen erstreckende kapillarartige Spalte eingeformt werden oder daß die Ausnehmungen als Kanäle mit umfangsseitig zu einem Spalt verengten Öffnungen eingeformt werden. Durch die kapillarartigen Spalte ergibt sich ein Rückhalteeffekt für das Medium und wird dieses erst unter den bei Gebrauch herrschenden Bedingungen, z. B. durch den Bürstdruck, durch hinzutretende externe Medien oder dgl. abgegeben.In both of the aforementioned method variants, provision can be made be that the recesses are located away from the center of the core molded outward extending capillary gaps be or that the recesses as channels with circumferential openings narrowed into a gap. The capillary-like gaps result in a retention effect for the medium and this is only among the Use prevailing conditions, e.g. B. by brush pressure, delivered by external media or the like.

Vorzugsweise wird die Form und/oder die Weite der Spalte auf die Konsistenz des Mediums abgestimmt. Dabei ist ferner von Vorteil, wenn die Spalte so eingeformt werden, daß sie im unbelasteten Zustand vollständig geschlossen sind und sich erst unter Druck öffnen.Preferably the shape and / or the width of the column matched to the consistency of the medium. It is also of advantage if the gaps are molded so that they are completely closed in the unloaded state and only open under pressure.

Die sich nach außen offenen Ausnehmungen lassen sich in besonders wirtschaftlicher Weise im Durchlaufverfahren an einem Endlosfilament füllen. Dies kann dadurch geschehen, daß das Filament durch ein Medienbad, das gegebenenfalls unter Druck gesetzt wird, oder durch einen sich düsenartig verengenden Querschnitt mit dem umfangsseitig zugeführten Medium hindurchgeführt wird. Ist die Öffnungsweite der Ausnehmungen groß genug und die Konsistenz des Mediums ausreichend viskos kann das Füllen auch drucklos im Durchlaufverfahren geschehen. In diesem Fall empfiehlt es sich, die Ausnehmungen anschließend durch einen auf das Filament aufgebrachten Mantel zu schließen.The recesses that are open to the outside can be particularly economically in a continuous process on one Fill continuous filament. This can be done in that the filament through a media bath, if necessary under Pressure is set, or by a nozzle-like narrowing Cross section with the medium supplied on the circumference is passed through. Is the opening width of the recesses large enough and the consistency of the medium sufficient Filling can also be viscous without pressure using the continuous process happen. In this case it is recommended to make the recesses then by one applied to the filament Close coat.

Der Mantel besteht vorzugsweise aus einem thermoplastischen Kunststoff, der auf das mit dem Medium gefüllte Filament aufextrudiert wird. Er wird vorzugsweise mit Übermaß extrudiert und durch Abkühlen auf das Filament aufgeschrumpft, wodurch insbesondere thermischempfindliche Medien geschont bleiben; flüssige Bestandteile können nicht ausdampfen und thermisch reaktive Komponenten sich nicht zersetzen. Wird ein Mantel, wie oben erwähnt, aus einem für das Medium diffusionsoffenen Kunststoff aufgebracht, kann er gegebenenfalls bereichsweise durch ein diffusionsdichtes Material abgedeckt werden, um die Diffusion lokal und/oder die Diffusionsrate zu steuern.The jacket is preferably made of a thermoplastic Plastic on the filament filled with the medium is extruded. It is preferably extruded in excess and shrink-wrapped onto the filament, which is particularly gentle on thermally sensitive media stay; liquid components cannot evaporate and thermally reactive components do not decompose. Becomes a jacket, as mentioned above, made of one that is permeable to the medium Applied plastic, he can if necessary partially by a diffusion-proof material to be covered locally and / or the rate of diffusion to control.

Besteht der Mantel aus einem transparenten Kunststoff, kann der Medienverbrauch, beispielsweise durch entsprechende Einfärbung der Medien, optisch kontrolliert, gegebenenfalls auch die Art der Medien visualisiert werden.If the coat is made of a transparent plastic, can media consumption, for example through appropriate Coloring of the media, optically controlled, if necessary the type of media can also be visualized.

Zusätzlich zur Anzeige des Mediums und/oder seines Verbrauchs oder stattdessen kann auch eine Wirkanzeige für die Borstenfunktion vorgesehen sein, um zu gewährleisten, daß die Borste nur so lange genutzt wird, wie sie die für den bestimmungsgemäßen Gebrauch notwendigen Eigenschaften aufweist, oder aber die Borste technisch so auszulegen, daß sie nicht länger als tunlich genutzt wird. Dies kann dadurch geschehen, daß ein Mantel aus einem thermoplastischen Kunststoff mit dessen Verschleißfaktor bestimmenden Füllstoffen auf das Filament aufgebracht wird, wobei der Kunststoff und die ihm beigegebenen Füllstoffe auf den zulässigen Abnutzungsgrad der Borste beim bestimmungsgemäßen Gebrauch abgestimmt werden. Mit diesem Verfahren lassen sich auch beliebige andere Borsten, die gegebenenfalls nur aus einem Kern und einem Mantel bestehen, mit einer Wirkanzeige ausstatten. Als den Verschleißfaktor bestimmende Füllstoffe kommen insbesondere Feststoffartikel in Frage, welche die intermolekulare Bindung im Polymer des Mantels reduzieren und den Verschleißfaktor durch Art, Größe und Menge steuern. Im Falle einer Applikationsborste können die Feststoffe so ausgewählt werden, daß sie bei der Applikation zugleich eine Funktion erfüllen, z. B. Calciumcarbonat oderchlorid als reminalisierende Wirkstoffe bei Zahnbürsten. Auch die Zugabe von Wachsen, insbesondere Ionomerwachs, hat sich als günstig erwiesen, da sich diese in der Polymermatrix gleichmäßiger verteilen und damit für einen gleichmäßigen Verschleißfaktor sorgen. Auch wird dadurch das Gleitverhalten der Borste günstig beeinflußt. Damit ist zugleich auch eine Feinjustierung einer Wirkanzeige möglich.In addition to displaying the medium and / or its consumption or instead, an effect indicator for the Bristle function may be provided to ensure that the bristle is only used as long as it is used for the has the required properties as intended, or to design the bristle technically so that it is no longer used as practicable. This can be done happen that a jacket made of a thermoplastic Plastic with fillers that determine its wear factor is applied to the filament, the plastic and the fillers added to the permissible Degree of wear of the bristle when used as intended be coordinated. With this procedure you can also any other bristles that may only be made consist of a core and a jacket, with an effective indicator equip. As fillers that determine the wear factor solid articles are particularly suitable, which the Reduce intermolecular bond in the polymer of the jacket and control the wear factor by type, size and quantity. In the case of an application bristle, the solids can be selected so that they are at the same time in the application perform a function, e.g. B. calcium carbonate or chloride as reminalizing agents in toothbrushes. The addition of waxes, especially ionomer wax, also has proved to be favorable, since these are in the polymer matrix distribute more evenly and thus for a more even Cause wear factor. This also makes the gliding behavior the bristle is influenced favorably. That is at the same time a fine adjustment of an effective indication is also possible.

Gemäß einer weiteren Verfahrensvariante können auch verschiedene Medien mit unterschiedlicher Funktion bei der Applikation in den Ausnehmungen geschichtet oder lokal getrennt untergebracht und entsprechend lokal getrennt abgegeben werden. In gleicher Weise lassen sich beispielsweise zueinander affine Komponenten eines Wirkstoffs, der seine Wirkung erst vor Ort entfalten soll, lokal getrennt unterbringen. Als Beispiel sei die erwünschte Bildung oder Rückbildung von Calciumfluoridschichten auf den Zähnen erwähnt, die im ionisierenden Medium aus Ca(+) und F(-) Ionen gebildet werden können, die wiederum aus lokal getrennt untergebrachten Ca- und F-Verbindungen in der feuchten Atmosphäre des Mund- und Rachenraums erzeugt werden können.According to a further variant of the method, different media with different functions can also be layered in the recesses or housed separately locally and correspondingly dispensed locally separately. In the same way, components of an active ingredient that are affine to one another and are only supposed to develop their effect on site, for example, can be accommodated locally separately. An example is the desired formation or regression of calcium fluoride layers on the teeth, which can be formed in the ionizing medium from Ca (+) and F (-) ions, which in turn are made up of locally separated Ca and F compounds in the humid atmosphere of the mouth and throat can be generated.

Die Medien oder Wirkstoffkomponenten können auch durch eine schichtweise Unterbringung in den Ausnehmungen getrennt untergebracht und erst bei der Abgabe zusammengebracht werden. Auch läßt sich durch die Schichtenbildung die Diffusionsrate der Medien oder Wirkstoffe steuern. The media or active ingredient components can also by a Layered accommodation in the recesses separately and only be brought together at the time of delivery. The diffusion rate can also be achieved through layer formation control the media or active ingredients.

Es lassen sich ferner Wirkstoffe und/oder Füllstoffe im Kern oder im Mantel oder in beiden unterbringen. Schließlich kann der Kern als Monofil oder auch mehradrig extrudiert. und können der Kern und/oder der Mantel gegebenenfalls auch beim Extrudieren oder danach geschäumt werden.There can also be active ingredients and / or fillers in the Place core or in the coat or in both. Finally the core can be extruded as a monofilament or multi-core. and can optionally the core and / or the jacket can also be foamed during extrusion or afterwards.

Die Erfindung betrifft schließlich eine Borste, die aus dem erfindungsgemäß hergestellten Filament durch Ablängen auf Wunschmaß erhalten wird, sowie eine Borstenware mit einem Borstenträger, an dem Borsten der vorgenannten Art unter Bildung des Borstenbesatzes oder eines Teils desselben befestigt werden.Finally, the invention relates to a bristle that consists of the Filament produced according to the invention by cutting to length Desired size is obtained, as well as a bristle product with a Bristle holder, on the bristles of the type mentioned below Formation of the bristle or part thereof attached become.

In einigen Anwendungsfällen kann es sich empfehlen, die Borsten zumindest an ihrem nutzungsseitigen Ende zu schließen. Dies kann beispielsweise durch thermische Verfahren wie Schweißen, Reibschweißen, Laserschweißen od.dgl. geschehen.In some use cases it may be advisable to use the Bristles should be closed at least at their use end. This can be done, for example, by thermal methods such as welding, friction welding, laser welding or the like. happen.

Nachstehend sind das erfindungsgemäße Verfahren und nach dem Verfahren hergestellte Borsten anhand einiger Ausführungsbeispiele in der Zeichnung beschrieben. In der Zeichnung zeigen:

Fig.1
verschiedene Phasen a) bis f) der Herstellung eines Filaments, das jeweils im Querschnitt wieder-gegeben ist;
Fig.2
einen Längsschnitt II-II eines Filaments;
Fig.3
einen schematischen Schnitt einer Borstenware mit einer Borste aus einem Filament gemäß Fig.2;
Fig.4
eine schematische Darstellung der Medienabgabe;
Fig.5 bis 10
Querschnitte. verschiedener Ausführungsformen einer Borste;
Fig.11
einen Querschnitt einer weiteren Ausführungsform des Kerns einer Borste;
Fig.12 bis 14
Ansichten weiterer Ausführungsformen des Kerns einer Borste;
Fig.15
einen Schnitt XV-XV gemäß Fig.14;
Fig.16 bis 20
Querschnitte einiger weiterer Ausführungsbeispiele von Borsten mit aufextrudiertem Mantel;
Fig.21
eine Ansicht einer Borste;
Fig.22
einen Schnitt XXII-XXII gemäß Fig.21;
Fig.23 bis 25
weitere Ansichten von Ausführungsbeispielen der Borste;
Fig.26
einen Querschnitt einer Borste mit Teilbeschichtung;
Fig.27
einen Querschnitt einer Borste mit Mantel und Teilbeschichtung;
Fig.28
eine perspektivische Ansicht einer Borste mit Mantel und zusätzlicher Bandagierung;
Fig.29
eine perspektivische Ansicht einer Borste mit perforiertem Mantel;
Fig.30
einen Querschnitt einer Borste mit verschiedenen Medien in distanzierten Ausnehmungen;
Fig.31
einen Längsschnitt einer Borste mit unterschiedlichen Ausnehmungen am Kern;
Fig.32
einen Längsschnitt einer Borste mit einem verschlossenen Ende;
Fig.33
einen Längsschnitt einer Borste im Ausgangszustand;
Fig.34
die Borste gemäß Fig.33 während oder nach der Nutzungsdauer;
Fig.35 bis 38
je einen Längsschnitt einer Borste mit Wirkanzeige
Fig.39
einen Längsschnitt einer Borste mit einer Anzeige des Abnutzungsgrades.
The method according to the invention and bristles produced according to the method are described below with the aid of some exemplary embodiments in the drawing. The drawing shows:
Fig.1
different phases a) to f) the production of a filament, which is reproduced in each case in cross section;
Fig.2
a longitudinal section II-II of a filament;
Figure 3
a schematic section of a bristle product with a bristle made of a filament according to Figure 2;
Figure 4
a schematic representation of the media delivery;
Fig. 5 to 10
Cross-sections. different embodiments of a bristle;
Figure 11
a cross section of a further embodiment of the core of a bristle;
Fig. 12 to 14
Views of further embodiments of the core of a bristle;
Figure 15
a section XV-XV of Figure 14;
Fig. 16 to 20
Cross sections of some further embodiments of bristles with extruded jacket;
Figure 21
a view of a bristle;
Figure 22
a section XXII-XXII according to Figure 21;
Fig. 23 to 25
further views of exemplary embodiments of the bristle;
Figure 26
a cross section of a bristle with partial coating;
Fig.27
a cross section of a bristle with sheath and partial coating;
Figure 28
a perspective view of a bristle with a jacket and additional bandaging;
Figure 29
a perspective view of a bristle with a perforated jacket;
Fig.30
a cross section of a bristle with different media in distant recesses;
Fig.31
a longitudinal section of a bristle with different recesses on the core;
fig.32
a longitudinal section of a bristle with a closed end;
fig.33
a longitudinal section of a bristle in the initial state;
Fig.34
the bristle according to FIG. 33 during or after the period of use;
Fig. 35 to 38
each a longitudinal section of a bristle with effective indication
Fig.39
a longitudinal section of a bristle with an indication of the degree of wear.

Fig.1 zeigt in den Abbildungen a) bis f) verschiedene Verfahrensstufen bei der Herstellung eines Filamentes, aus dem Borsten durch Ablängen auf Wunschmaß erhalten werden. Das Filament 1 wird in Form eines die mechanischen Eigenschaften der späteren Borste wesentlich bestimmenden Kerns 2 in herkömmlicher Weise aus einer Kunststoffschmelze extrudiert. Beim gezeigten Ausführungsbeispiel besteht der Kern 2 aus einem massiven Zentrum 3 mit von dort ausgehenden und sich nach außen öffnenden Ausnehmungen 4, die bei diesem Ausführungsbeispiel durch ein kreuzartiges Profil des extrudierten Kerns erhalten werden (Fig.1a). Das Filament wird anschließend in herkömmlicher Weise verstreckt (Fig.1b), um eine molekulare Längsorientierung zu erhalten. Durch das Längen beim Verstrecken des Kerns wird der Querschnitt entsprechend reduziert. Anschließend wird der Kern 2 mit Vorteil thermisch stabilisiert (Fig.1c)Fig.1 shows in figures a) to f) different process stages in the production of a filament from which Bristles can be obtained by cutting to length. The Filament 1 is in the form of a mechanical properties the later determining bristle core 2 in conventionally extruded from a plastic melt. In the embodiment shown, the Core 2 from a massive center 3 with outgoing from there and outwardly opening recesses 4, which at this embodiment by a cross-like profile of the extruded core can be obtained (Fig.1a). The filament is then stretched in a conventional manner (Fig.1b) in order to obtain a molecular longitudinal orientation. The cross-section becomes due to the lengthening when the core is stretched reduced accordingly. Then the Core 2 advantageously thermally stabilized (Fig.1c)

Das auf diese Weise extrudierte und vorbehandelte Filament 1 mit seinen Ausnehmungen 4 wird anschließend mit dem Medium 6 gefüllt. Beispielsweise wird das Filament 1 durch einen in Fig.1d mit einer kreisförmigen Linie 5 angedeuteten Kanal gezogen, der sich gegebenenfalls von einem größeren Querschnitt düsenartig auf den Querschnitt des Kerns 2 verengt und in den das Medium ständig zugeführt wird, so daß das Medium 6 von den Ausnehmungen 4 des Filaments 1 aufgenommen wird. Stattdessen kann das Medium 6 auch unter Druck zugeführt werden, wie dies in Fig. 1e durch die Andeutung einer größeren Dichte des Mediums 6 angedeutet ist. Bei der gezeigten Ausführungsform mit einem sehr offenen Querschnitt der Vertiefungen empfiehlt es sich, auf das mit dem Medium gefüllte Filament eine Hüllschicht 7 aufzubringen, die filmartig ausgebildet ist und sich bei Gebrauch der Borste schnell abnutzt, um das Medium 6 abzugeben. Bei dieser Hüllschicht 7 kann es sich aber auch um einen dünnwandigeren Mantel handeln, der aus einem diffusionsoffenen Polymer besteht, das entweder eine Diffusion des Mediums 6 am Gebrauchsort der Borste ermöglicht oder erst in Verbindung mit Medien am Gebrauchsort, z.B. Speichel, Wasser oder dergleichen die notwendige Permeabilität erlangt. Der Mantel 7 wird vorzugsweise auf das bereits gefüllte Filament 1 mit Übermaß gegenüber dem Kern 2 aufextrudiert und anschließend durch Abkühlen auf den Kern aufgeschrumpft.The filament extruded and pretreated in this way 1 with its recesses 4 is then with the Medium 6 filled. For example, the filament 1 is through one indicated in FIG. 1d with a circular line 5 Canal pulled, which may be different from a larger one Cross section nozzle-like to the cross section of the core 2 narrowed and into which the medium is constantly fed, so that the medium 6 of the recesses 4 of the filament 1st is recorded. Instead, the medium 6 can also be under Pressure can be supplied, as indicated by the hint in Fig. 1e a greater density of the medium 6 is indicated. In the embodiment shown with a very open one Cross section of the wells it is recommended to use the to apply a sheath layer 7 to the medium filled filament, which is film-like and is in use the bristle wears out quickly to release the medium 6. at this cladding layer 7 can also be a thin-walled one Acting coat that is made of an open to diffusion Polymer exists that either diffuses the medium 6 enabled at the place of use of the bristle or only in connection with media at the place of use, e.g. Saliva, water or the like acquires the necessary permeability. The coat 7 is preferably on the already filled filament 1 extruded with excess compared to the core 2 and then shrunk onto the core by cooling.

Fig.2 zeigt den Abschnitt einer Borste 8, die aus einem gemäß Fig.1 hergestellten Filament durch Zuschneiden erhalten wird. Die Borste 8 besteht also aus einem Kern 2 mit dem Medium 6 in den Ausnehmungen und dem Mantel 7.2 shows the section of a bristle 8, which consists of a Fig.1 obtained filament obtained by cutting becomes. The bristle 8 thus consists of a core 2 with the Medium 6 in the recesses and the jacket 7.

Fig.3 zeigt schematisch einen Ausschnitt einer Borstenware 62, z.B. im Bereich des Kopfs einer Zahnbürste, mit einem Borstenträger 9, an dem die Borsten 8 befestigt sind. Bei Benutzung der Zahnbürste wirken auf die Borste 8 Druckund Biegekräfte, die zu der schematisch angedeuteten, zeitweiligen Verformung der Borste 8 führen. Aufgrund dieser Kräfte tritt das Medium 6, wie mit den Richtungspfeilen angedeutet, am freien Ende der Borste aus. Zugleich diffundiert das Medium, wenn es eine entsprechende Zusammensetzung aufweist, durch die Wände des Mantels, gegebenenfalls unter Mitwirkung der am Verwendungsort vorhandenen Medien wie Speichel, Wasser, Zahnpflegemittel oder dergleichen. Dies ist in Fig.4 in vergrößertem Maßstab nochmals dargestellt.3 shows schematically a section of a bristle product 62, e.g. in the area of the head of a toothbrush, with a Bristle holder 9 to which the bristles 8 are attached. When using the toothbrush 8 pressure and act on the bristle Bending forces that to the schematically indicated, temporary Deform bristle 8. Based on these Forces the medium 6 occurs, as indicated by the directional arrows, at the free end of the bristle. At the same time diffuses the medium if there is an appropriate composition has, through the walls of the jacket, if necessary with the participation of the media available at the place of use such as saliva, water, dentifrices or the like. This is shown again in FIG. 4 on an enlarged scale.

In den Fig.5 bis 10 sind Querschnitte von Filamenten 1 gezeigt, die je nach Konsistenz des Mediums eine gesonderte Beschichtung oder einen Mantel nicht erforderlich machen. Fig.5 zeigt ein Filament, das in Form eines im wesentlichen kreisförmigen Kerns 2 mit einem massiven Zentrum 3 extrudiert ist. Anläßlich des Extrudierens werden Ausnehmungen in Form kapillarartiger Spalte 10 eingeformt, die beim gezeigten Ausführungsbeispiel in regelmäßiger, radialer Anordnung vorgesehen sind. Die kapillarartigen Spalten 10 werden in der mit Bezug auf Fig.1 beschriebenen Weise mit dem Medium gefüllt.5 to 10 show cross sections of filaments 1, which is a separate one depending on the consistency of the medium Do not require coating or a coat. Fig. 5 shows a filament that is in the form of an essentially circular core 2 extruded with a solid center 3 is. On the occasion of the extrusion, recesses are made molded in the form of capillary-like column 10, which in the shown Embodiment in regular, radial arrangement are provided. The capillary gaps 10 are in the manner described with reference to Fig.1 filled the medium.

Fig.6 zeigt eine ähnliche Ausführungsform, bei der die Kapillarartigen Spalte 10 zusätzlich in Extrusionsrichtung mit einem Profil 11 versehen sind, wodurch ein besseres Rückhaltevermögen für das Medium erzielt wird.Figure 6 shows a similar embodiment in which the capillary Column 10 additionally in the direction of extrusion are provided with a profile 11, whereby a better Retention for the medium is achieved.

Bei dem Ausführungsbeispiel gemäß Fig.7 besteht das Filament 1 wiederum aus einem massiven Kern 2 und einem äußeren Kernteil 12, das aus einem anderen Kunststoff bestehen kann als der Kern 2, der beispielsweise aus einem der späteren Borste die notwendigen mechanischen Eigenschaften verleihenden Polymer gebildet ist, während das Kernteil 12 aus einem anderen, auf die Gebrauchseigenschaften abgestimmten Polymer bestehen kann. Das Filament 1 weist achsparallel zum Kern 2 kanalartige Ausnehmungen 13 auf, die über spaltartige Öffnungen 14 am Umfang des Filaments 1 auslaufen. Fig.8 zeigt wiederum ein Filament 1 in Form eines extrudierten Kerns 2, der lediglich nahe des Umfangs einige wenige, gleichmäßig verteilte Kanäle 15 mit spaltartiger Öffnung 16 aufweist.In the embodiment shown in Figure 7, the filament 1 in turn from a solid core 2 and an outer Core part 12, which can consist of a different plastic than the core 2, for example from one of the later Bristle imparting the necessary mechanical properties Polymer is formed while the core part 12 is made of another, tailored to the usage properties Polymer can exist. The filament 1 is axially parallel to the core 2 channel-like recesses 13 on the gap-like Open openings 14 on the circumference of filament 1. 8 again shows a filament 1 in the form of an extruded one Core 2, which is only a few near the circumference, evenly distributed channels 15 with a gap-like opening 16 has.

Bei dem Ausführungsbeispiel gemäß Fig.9 ist das Filament 1 wiederum als Kern 2 mit einem massiven Zentrum 3 extrudiert, von dem eine Vielzahl kapillarartiger Spalte 17 sich schaufelartig nach außen erstrecken. Die kapillarartigen Spalte 17 sind am Umfang des Filaments 1 bei 18 annähernd geschlossen. Die die kapillarartigen Spalte 17 schaufelförmig begrenzenden Stege 20 sind elastisch verformbar. Auf diese Weise kann das Füllen der kapillarartigen Spalte 17 dadurch erleichtert werden, daß das Filament entgegen der Schaufelkrümmung gedreht wird, so daß sich die Spalte öffnen. Nach dem Füllen wird überschüssiges Medium durch Drehen in der Gegenrichtung oder durch Passieren eines entsprechenden Hüllquerschnitts ausgequetscht, so daß die kapillarartigen Spalte 17 am Umfang des Filaments 1 bzw. an der späteren Borste annähernd geschlossen sind. Bei Gebrauch der Borstenware mit solchermaßen ausgerüsteten Borsten bewirken die Druckkräfte eine Verformung der Borste, so daß das Medium umfangseitig austritt.In the exemplary embodiment according to FIG. 9, the filament is 1 again extruded as core 2 with a solid center 3, of which a large number of capillary-like gaps 17 Extend outward like a shovel. The capillary Columns 17 are approximately 18 at the circumference of filament 1 closed. The capillary-like column 17 is scoop-shaped delimiting webs 20 are elastically deformable. On in this way the filling of the capillary-like gaps 17 be facilitated in that the filament against the Blade curvature is rotated so that the gaps open. After filling, excess medium is turned in the opposite direction or by passing a corresponding one Envelope cross-section squeezed so that the capillary Column 17 on the circumference of filament 1 or the later bristle are almost closed. In use the bristle goods with bristles equipped in this way the compressive forces cause the bristle to deform, so that the medium emerges on the circumference.

Fig.10 zeigt ein Filament 1 mit rechteckigem Querschnitt, in das wiederum achsparallele Kanäle 21 eingeformt sind, die über spaltartig verengte Öffnungen 22 am Umfang des Filaments 1 ausmünden.10 shows a filament 1 with a rectangular cross section, in which in turn axially parallel channels 21 are formed, the openings 22 narrowed at the circumference of the filament 1 flow out.

Fig.11 zeigt ein Filament 1 mit sektorförmigen Ausnehmungen 23, und einem zentralen Kern 3, der von quer verlaufenden Kanälen 24 durchsetzt ist. Die sektorförmigen Ausnehmungen 23 und die Querkanäle 24 werden mit dem Medium gefüllt. Dieses Filament 1 wird vorteilhafterweise wiederum mit einem Film beschichtet oder mit einem aufextrudierten Mantel versehen, wie dies mit Bezug auf die Fig.1 bis 4 beschrieben ist.11 shows a filament 1 with sector-shaped recesses 23, and a central core 3, that of transverse Channels 24 is interspersed. The sector-shaped recesses 23 and the transverse channels 24 are filled with the medium. This filament 1 is advantageously turn coated with a film or with an extruded one Coat provided as described with reference to Figures 1 to 4 is.

Fig.12 zeigt ein Filament 1 in Form eines gewendelten Kerns 2, bei dem die Ausnehmungen 63 schraubenförmig verlaufen. Auch diese Ausführung des Filaments 1 läßt sich problemlos mit dem Medium füllen und wird vorteilhafterweise anschließend ein Mantel aufextrudiert. Fig.13 zeigt ein Filament 1 in Form eines wellenförmigen Kerns 2, bei dem die Ausnehmungen 64 durch die Wellentäler gebildet werden, während Fig.14 ein Filament 1 in Form eines Kerns 2 mit ringförmigen Ausnehmungen 65 wiedergibt. Auch bei diesen beiden Ausführungsformen wird vorzugsweise nach dem Füllen des Filaments 1 ein Mantel aufextrudiert.Fig. 12 shows a filament 1 in the form of a coiled Core 2, in which the recesses 63 extend helically. This version of the filament 1 can also easily fill with the medium and will advantageously then extruded a jacket. Fig. 13 shows one Filament 1 in the form of a wavy core 2, in which the recesses 64 are formed by the wave troughs, 14 with a filament 1 in the form of a core 2 annular recesses 65 reproduces. Even with these Both embodiments are preferably made after filling of the filament 1 extruded a sheath.

Fig.16 zeigt ein Filament 1 mit einem extrudierten Kern 2 von rechteckigem Querschnitt, das beispielsweise durch einen kreisförmigen Kanal gezogen wird, wobei sich das Medium 6 an den Seitenflächen des rechteckigen Kerns 2 aufbaut. Anschließend wird ein Mantel 7 aufextrudiert und gegebenenfalls durch Abkühlen und Aufschrumpfen fixiert.16 shows a filament 1 with an extruded core 2 of rectangular cross section, for example, by a circular channel is drawn, moving the medium 6 builds on the side surfaces of the rectangular core 2. Then a jacket 7 is extruded and if necessary fixed by cooling and shrinking.

Fig.17 gibt einen Kern 2 mit gleichmäßig verteilt angeordneten Vertiefungen 26 wieder, die in gleicher Weise wie zuvor beschrieben mit dem Medium 6 gefüllt werden. Auf den Kern 2 mit dem Medium 6 wird anschließend wieder ein Mantel 7 aufextrudiert. Das Ausführungsbeispiel gemäß Fig.18 unterscheidet sich von dem der Fig.17 nur durch die Form und Anzahl der Vertiefungen 26.Fig.17 gives a core 2 with evenly distributed Wells 26 again, in the same way as before described can be filled with the medium 6. On the Core 2 with the medium 6 is then again a coat 7 extruded. The exemplary embodiment according to FIG. 18 differs from that of Fig. 17 only by the shape and number of depressions 26.

Bei dem Ausführungsbeispiel gemäß Fig.19 handelt es sich wiederum um ein Filament in Form eines Kerns 2 mit einem kreuzförmigen Querschnitt unter Bildung von nach außen offenen Ausnehmungen 27, die mit dem Medium gefüllt werden. Der Kern 2 weist an den freien Enden seiner Arme 28 wulstartige Verdickungen 29 auf. Nach dem Füllen der Ausnehmungen 27 des Kerns 2 wird ein Mantel 30 aufextrudiert, der die wulstförmigen Verdickungen. 29 umfaßt, so daß eine Art formschlüssige Verbindung entsteht. Hiervon unterscheidet sich das Ausführungsbeispiel gemäß Fig.20 dadurch, daß die Arme 28 des Kerns 2 geradeaus laufen und nach dem Füllen der zwischen den Armen 28 gebildeten Ausnehmungen der Mantel 31 aufextrudiert und aufgeschrumpft wird.The embodiment according to FIG. 19 is again a filament in the form of a core 2 with a cross-shaped cross-section with the formation of open to the outside Recesses 27 which are filled with the medium. The core 2 has bulges 28 at the free ends of its arms Thickenings 29 on. After filling the recesses 27 of the core 2, a jacket 30 is extruded, the the beaded thickenings. 29 includes so that a kind positive connection is created. Different from this the embodiment of FIG. 20 characterized in that the Arms 28 of core 2 run straight and after filling the recesses formed between the arms 28 of the jacket 31 is extruded and shrunk.

Fig.21 zeigt ein Filament 1 in Form eines Kerns 2, wobei verschiedene Ausführungen von Ausnehmungen angedeutet sind. Es kann sich um nutenartige, geradlinige Vertiefungen 32 oder nutenförmige, gekrümmte Vertiefungen 33 oder auch um einzelne lochartige Vertiefungen 34 handeln.Fig. 21 shows a filament 1 in the form of a core 2, wherein different designs of recesses are indicated. These can be groove-like, straight-line depressions 32 or groove-shaped, curved recesses 33 or around act individual hole-like depressions 34.

Bei dem Ausführungsbeispiel gemäß Fig.23 weist das Filament 1 einen Kern 2 mit Ausnehmungen in Form von äquidistant angeordneten Schlitzen 35 auf, die quer zur Achse des Filaments verlaufen und beispielsweise nach dem Extrudieren eingeformt werden.In the exemplary embodiment according to FIG. 23, the filament has 1 a core 2 with recesses in the form of equidistant arranged slots 35 which are transverse to the axis of the Filaments run and, for example, after extrusion be molded.

Fig.24 zeigt ein Filament 1, dessen Kern 2 aus einer Vielzahl paralleler Mönofile 36 besteht, wobei die Ausnehmungen durch die Zwischenräume 37 zwischen den Monofilen 36 gebildet werden. Nach dem Füllen der Zwischenräume und gegebenenfalls entsprechendem Kalibrieren des Monofilstrangs wird ein Mantel 38 aufextrudiert.Fig. 24 shows a filament 1, the core 2 of a variety parallel Mönofile 36 exists, the recesses formed by the spaces 37 between the monofilaments 36 become. After filling the gaps and if necessary calibrating the monofilament accordingly a jacket 38 extruded.

In Fig.24 ist der Mantel 38 teilweise aufgebrochen gezeigt. Er ist mit Füllstoffen 65 versehen, die das Verschleißverhalten des Kunststoffs und damit die Abnutzung des Mantels bestimmen.24 shows the jacket 38 partially broken open. He is provided with fillers 65, the wear behavior of the plastic and thus the wear of the jacket determine.

Fig.25 zeigt ein Filament 1 in Form eines Kerns 2, der ähnlich dem Ausführungsbeispiel gemäß Fig.7 mit ein oder mehr achsparallelen Kanälen 39 versehen ist, die sich über spaltartige Öffnungen 40 nach außen erstrecken. Zusätzlich können Öffnungen 41 mit etwas größerem Querschnitt mit Abstand voneinander vorgesehen sein.Fig. 25 shows a filament 1 in the form of a core 2, which is similar the embodiment of Figure 7 with one or more axially parallel channels 39 is provided, which over extend gap-like openings 40 to the outside. additionally can openings 41 with a slightly larger cross section at a distance be provided from each other.

Beim Ausführungsbeispiel gemäß Fig.26 ist wiederum ein Filament 1 in Form eines extrudierten Kerns 2 mit umfangseitig angeordneten Ausnehmungen 42, die sämtlich durch eine nachträglich aufgebrachte Schicht 43 abgedeckt sind, die entweder bei Benutzung aufgrund ihres Verschleißes das Medium in den Ausnehmungen 42 freigibt oder aber eine solche Permeabilität aufweist, daß das Medium, gegebenenfalls unter Mitwirkung der Medien am Gebrauchsort, ein langsames Ausdiffundieren der Medien gestattet.In the exemplary embodiment according to FIG. 26, there is again a filament 1 in the form of an extruded core 2 with circumferential arranged recesses 42, all of which by a subsequently applied layer 43 are covered, the either the medium when used due to its wear releases in the recesses 42 or such Permeability has that the medium, if necessary with the participation of the media at the place of use, a slow one Media diffusion allowed.

Bei dem Ausführungsbeispiel gemäß Fig.27 ist dasselbe Filament wie in Fig.26 mit einem Kern 2 mit Ausnehmungen 42 mit einem Mantel 44 aus einem diffusionsoffenen Polymer umhüllt, der beispielsweise die an der Oberfläche der Borste gewünschten Eigenschaften aufweist. Durch zusätzliche Teilbeschichtungen 45 im Bereich der Ausnehmungen 42 wird die Diffusionsdichte und damit die Medienabgabe gesteuert.In the exemplary embodiment according to FIG. 27, the same filament is used as in Fig. 26 with a core 2 with recesses 42 a sheath 44 made of a diffusion-open polymer, for example the one on the surface of the bristle desired properties. With additional partial coatings 45 in the area of the recesses 42 Diffusion density and thus the media delivery controlled.

Fig.28 zeigt ein Filament 1 mit einem im Querschnitt sternförmigen Kern, bei dem die Ausnehmungen 46 zwischen den Sternzacken gebildet sind und auf dem wiederum ein Mantel 47 aufextrudiert ist. Zusätzlich ist der Mantel 47 mit einer Kunststoff- oder Textilfaser bandagiert.Fig. 28 shows a filament 1 with a star-shaped cross section Core, in which the recesses 46 between the Star points are formed and on the turn a coat 47 is extruded. In addition, the jacket 47 with a plastic or textile fiber bandaged.

Bei dem Ausführungsbeispiel gemäß Fig.29 besteht das Filament 1 aus einem Kern 2 ähnlich der Ausführungsform gemäß Fig.11 mit sektorförmigen Ausnehmungen 23 und einem aufextrudierten Mantel 49, der mit einer Perforation 50 versehen ist, die einerseits ein gesteuertes Austreten des Mediums gestatten, andererseits der Oberfläche der fertigen Borste eine Struktur verleihen, die die Bürstwirkung steigert.In the exemplary embodiment according to FIG. 29, the filament is made 1 from a core 2 similar to the embodiment according to Fig.11 with sector-shaped recesses 23 and an extruded Sheath 49, which is provided with a perforation 50 is, on the one hand, a controlled escape of the medium allow, on the other hand, the surface of the finished bristle give a structure that increases the brushing effect.

Fig.30 zeigt ein Filament 1 mit einem wiederum kreuzförmigen Kern 2 und einem Mantel 7. In den Ausnehmungen 4 zwischen dem Kern 2 und dem Mantel 7 sind verschiedene Medien 51, 52 und 53 untergebracht, die gleichzeitig abgegeben werden und entweder verschiedene Wirkungen entfalten oder aber aus Komponenten bestehen, die erst am Gebrauchsort zu einem Wirkstoff reagieren. Stattdessen können verschiedene Medien in einer Ausnehmung auch geschichtet untergebracht werden. Fig. 30 shows a filament 1 with a cross shape Core 2 and a jacket 7. In the recesses 4 between the core 2 and the jacket 7 are different media 51, 52 and 53 housed, which issued simultaneously and either have different effects or but consist of components that only close at the place of use react to an active ingredient. Instead, different ones Media is also layered in a recess become.

Das Filament 1 gemäß Fig.31 besteht wiederum aus einem Kern 2, der unregelmäßig angeordnete Ausnehmungen 54, 55 und 56 aufweist und von einem Mantel 7 umgeben ist. Auch hier können die Ausnehmungen entsprechend ihrer Größe und Form verschiedene Medien aufnehmen.The filament 1 according to FIG. 31 again consists of a Core 2, the irregularly arranged recesses 54, 55 and 56 and is surrounded by a jacket 7. Also here the recesses can be made according to their size and Shape absorb different media.

Fig.32 zeigt einen Abschnitt einer Borste 8, die ähnlich derjenigen gemäß Fig.2 aufgebaut ist, also aus einem Kern 2 mit in dessen Ausnehmungen befindlichem Medium 6 und einem Mantel 7 besteht. Die Borste 8 ist an ihrem nutzungsseitigen Ende 57 geschlossen, indem beispielsweise der Mantel 8 thermisch entsprechend geformt wird.Figure 32 shows a portion of a bristle 8 that is similar that is constructed according to FIG. 2, that is to say from a core 2 with in its recesses medium 6 and a Coat 7 is made. The bristle 8 is on its usage side End 57 closed, for example by the jacket 8 is thermally shaped accordingly.

Fig.33 und 34 zeigen ein Ausführungsbeispiel einer Borste 8 mit offenem Ende 58, und zwar in Fig.33 im Ausgangszustand und in Fig.34 nach einer gewissen Benutzungsdauer, während der der Mantel 8 abgetragen und das Medium abgegeben worden ist. Hierdurch wird also sowohl die mechanische Abnutzung, als auch die Abgabe des Mediums optisch sichtbar.33 and 34 show an embodiment of a bristle 8 with open end 58, in FIG. 33 in the initial state and in Fig. 34 after a certain period of use, while the coat 8 has been removed and the medium has been dispensed is. This means that both mechanical wear, as well as the delivery of the medium is visually visible.

Fig.35 bis 38 zeigt eine andere Variante zur Indikation des Medienverbrauchs und/oder der Abnutzung der Borste. Zu diesem Zweck weist der Kern 2 gegebenenfalls mehrere mit Abstand voneinander angeordnete Ausnehmungen in Form von umlaufenden Rillen oder dergleichen auf, in denen ein Indikatormedium 59 untergebracht ist. Bei Gebrauch beginnt die Abnutzung des Mantels 7 im Bereich des Endes 58 der Borste 8 und bleibt nur noch der Kern 2 stehen. Dabei verschwinden sukzessive die Markierungen 59, so daß der Benutzer einerseits über die Abgabe des Mediums bzw. den Verschleiß der Borste optisch informiert wird.Fig. 35 to 38 shows another variant for the indication of Media consumption and / or wear of the bristle. To this The purpose of the core 2 may be several at a distance Recesses arranged from each other in the form of circumferential Grooves or the like in which an indicator medium 59 is housed. When used, the Wear of the jacket 7 in the region of the end 58 of the bristle 8 and only core 2 remains. Disappear successively the markings 59 so that the user on the one hand about the delivery of the medium or the wear the bristle is visually informed.

Schließlich zeigt Fig.39 eine Borste 8, an der sich bei regelmäßiger Abnutzung am Ende 59 eine mehr oder weniger regelmäßige Spitze 60 ausbildet. Auch hier weist der Kern 2 eine ringförmige Rille 61 auf, die gegebenenfalls mit einem Indikatormedium gefüllt sein kann, so daß nach Verschwinden desselben der Ablauf der (optimalen) Gebrauchsdauer signalisiert wird.Finally, Fig. 39 shows a bristle 8, on which regular Wear at the end of 59 a more or less regular top 60 training. Here too, the core 2 an annular groove 61, possibly with a Indicator medium can be filled so that after disappearing the same signals the expiry of the (optimal) service life becomes.

Claims (51)

  1. Method of producing bristles for applying media, through extrusion of a filament, which can be cut into bristles, and providing same with cavities for receiving the medium, from which the medium is discharged during appropriate use of the bristles, characterized in that the filament (1) is extruded with a core (2) which also determines the mechanical properties of the bristle (8), with the cavities (10,13,15,17) being formed at a separation from the center (3) of the core (2) to open towards the circumference of the filament (1) via a gap (14,16,18,22) formed at the circumference, wherein the cavities are filled with medium (6) from the outside, the gaps (14,16,18,22) being formed such that they are closed in an unloaded state of the bristle (8) and first open in response to pressure generated during proper use of the bristle (8) to release the medium (6).
  2. Method of producing bristles for applying media in that a filament, which can be cut into bristles, is extruded and provided with cavities for receiving the medium, from which the medium is released during appropriate use of the bristles, characterized in that the filament (1) is extruded with a core (2) which also determines the mechanical properties of the bristle (8), the cavities (4) being formed at a separation from the center (3) of the core to open towards the circumference of the filament, and are filled with the medium (6) from the outside, the filament (1) subsequently being provided, at least in parts, with a layer which at least partially covers the cavities (4) to control discharge of the medium (6) under normal conditions of use of the bristle (8).
  3. Method according to claim 2, characterized in that the layer is disposed in the form of a jacket (7) covering the core (2).
  4. Method according to claim 1 or 2, characterized in that the cavities (4) are formed during extrusion of the core (2).
  5. Method according to claim 1 or 2, characterized in that the cavities (35) are formed after extrusion of the core (2).
  6. Method according to any one of the claims 1 through 5, characterized in that the cavities are formed as capillary gaps (10,17).
  7. Method according to any one of the claims 1 through 5, characterized in that the cavities are formed as channels (13,15) having openings which narrow into a gap (14,16) at the circumference of the core (2).
  8. Method according to claim 1, 6 or 7, characterized in that the shape and/or width of the gaps (10,14,16,17) is matched to the consistency of the medium (6).
  9. Method according to claims 2 and 6 or claims 2 and 7, characterized in that the gaps (17) are formed such that they are closed in the unloaded state of the bristle (8) and open under pressure.
  10. Method according to claim 1 or 2, characterized in that the cavities (4) are filled with the pressurized medium (6) via the circumferential openings.
  11. Method according to claim 10, characterized in that the filament (1) is guided through a volume in which the medium (6) is kept under pressure.
  12. Method according to claim 1 or 2, characterized in that the filament (1) having the cavities (4) is guided through a substantially non-pressurized medium (6), thereby at least partially filling the cavities.
  13. Method according to any one of the claims 10 through 12, characterized in that the filament (1) is provided with a jacket (7) forming the covering layer after filling the cavities (4).
  14. Method according to claim 13, characterized in that a jacket (7) of thermoplastic material is extruded onto the filament (1) filled with the medium (6).
  15. Method according to claim 14, characterized in that the jacket (7) is extruded with a larger size than the filament (1) and is shrunk onto the filament (1) through cooling.
  16. Method according to any one of the claims 13 through 15, characterized in that a jacket (7) is applied onto the filament (1), the jacket (7) being made from a plastic material which permits diffusion of the medium (6) and/or media present at the location of the intended use of the bristle (8).
  17. Method according to claim 16, characterized in that the jacket (7) of a diffusion-permitting plastic material is covered at least in part by a diffusion-tight layer.
  18. Method according to claim 2, characterized in that the jacket (7) of a transparent plastic material forming the covering layer is applied onto the filament (1).
  19. Method according to claim 1 or 2, characterized in that different media (51,52,53) are introduced into spaced apart cavities (4) of the filament (1).
  20. Method according to claim 19, characterized in that media are introduced into separated cavities (4), those media (51,52,53) each comprising a component which becomes active only through combination of components.
  21. Method according to claim 1 or 2, characterized in that different media, and/or media having one component which becomes active only upon combination of the components, are introduced in layers into at least one cavity.
  22. Method according to claim 1 or 2, characterized in that active components are directly introduced into the core (2) and/or jacket (7).
  23. Method according to claim 1 or 2, characterized in that filling agents are directly introduced into the core (2) and/or the jacket (7).
  24. Method according to claim 1 or 2, characterized in that the core (2) is extruded as a multifilament (36).
  25. Method according to claim 1 or 2, characterized in that the core (2) and/or jacket (7) is extruded from a directly or indirectly foamable plastic material.
  26. Method of producing a bristle according to claim 1 or 2, characterized in that a jacket (38) is applied onto the filament (1), the jacket (38) being made from a plastic material having filling agents (65) which determine its wear factor.
  27. Method according to claim 26, characterized in that the plastic material and the added filling agents (65) are matched to the admissible wear factor of the bristle (8) during appropriate use.
  28. Bristle of plastic material for brushes to apply media which are accommodated in cavities of the bristle and which are released by the bristle during appropriate use of the brush, characterized in that the bristle (8) has a core (2) which contributes to determination of its mechanical properties, wherein the cavities (4) are disposed at a separation from the center of the core (2), extend towards the circumference of the bristle (8), and have at least one opening in the form of a gap (14,16,18,20) at the circumference, the gaps (10,14,17) being closed in an unloaded state of the bristle (8), to first open in response to conditions established during proper use thereof to release the medium (6).
  29. Bristle of plastic material for brushes to apply media which are accommodated in cavities of the bristle and which are released by the bristle during appropriate use of the brush, characterized in that the bristle (8) has a core (2) which contributes to determination of its mechanical properties, wherein the cavities (4) are disposed at a separation from the center of the core (2), extend towards the circumference of the bristle (8), and have at least one opening, wherein at least portions of the core (2) are coated with a layer (43) at least partially covering the cavities (42).
  30. Bristle according to claim 29, characterized in that the layer (43) completely covers the cavities (42).
  31. Bristle according to claim 29, characterized in that the layer is formed as a jacket (7,30,31,38,44) surrounding the core (2).
  32. Bristle according to claim 31, characterized in that the jacket (49) is perforated and the perforations (50) are connected with the cavities (23) of the core (2).
  33. Bristle according to claim 31, characterized in that the jacket (7) consists of a plastic material which permits diffusion of the medium (6) in the cavities of the core.
  34. Bristle according to claim 31 or 32, characterized in that the jacket (7) consists of a plastic material which permits diffusion of a medium present at the location of appropriate use of the brush (62).
  35. Bristle according to claim 33 or 34, characterized in that the jacket (7) of the diffusion-permitting plastic material is coated in parts in a diffusion-tight fashion.
  36. Bristle according to any one of the claims 31 through 35, characterized in that the jacket (7) consists of a plastic material comprising filling agents (65) which determine the wear factor of the jacket during use of the bristle.
  37. Bristle according to any one of the claims 31 through 36, characterized in that the jacket (7) is formed of a transparent plastic material.
  38. Bristle according to any one of the claims 31 through 37, characterized in that the jacket (7) consists of a plastic material filled with active components.
  39. Bristle according to any one of the claims 28 to 38, characterized in that the cavities are formed as capillary gaps (10,17).
  40. Bristle according to any one of the claims 28 to 39, characterized in that the cavities are formed as channels (13,15), parallel to the center (3) of the core (2) and having openings which narrow into a gap (14,16) at the circumference of the core (2).
  41. Bristle according to any one of the claims 28 through 40, characterized in that the shape and/or the width of the gap (10,14,16,17) is matched to the consistency of the medium (6).
  42. Bristle according to any one of the claims 28 to 41, characterized in that the cavities (22) extend about the circumference of the core (2) in a helical fashion.
  43. Bristle according to any one of the claims 28 to 42, characterized in that the cavities (24) are annularly disposed at the circumference of the core (2).
  44. Bristle according to any one of the claims 28 to 43, characterized in that the cavities (32,33) are disposed like grooves about the circumference of the core (2).
  45. Bristle according to any one of the claims 28 to 44, characterized in that the core (2) is wavy and the cavities (23) are formed by the wave troughs.
  46. Bristle according to any one of the claims 28 to 45, characterized in that the cavities are slots (35) extending transverse to the core (2).
  47. Bristle according to any one of the claims 28 through 46, characterized in that the core (2) includes cavities which are filled with a medium (59) which indicates the degree of the mechanical wear and/or release of the medium (6).
  48. Bristle according to any one of the claims 28 through 47,
    characterized in that spaced apart cavities (4) of the core (2) contain different media (51,52,53).
  49. Bristle according to claim 48, characterized in that the spaced-apart cavities (4) contain media (51,52,53) having different components which form an active component only after being released at the location of use.
  50. Brush, consisting of a bristle support (9) and a bristle field mounted thereto, characterized in that at least part of the bristle field is formed of bristles (8) in accordance with any one of the claims 28 through 49.
  51. Brush according to claim 50, characterized in that the peripheral region of the bristle field comprises the bristles (8) in accordance with any one of the claims 28 through 49.
EP01933759A 2000-04-09 2001-03-27 Method for producing bristles used to administer media, bristles produced according to said method and brushware comprising bristles of this type Expired - Lifetime EP1272070B1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10017306A DE10017306A1 (en) 2000-04-09 2000-04-09 Process for the production of bristles for the application of media
DE10017306 2000-04-09
PCT/EP2001/003466 WO2001076414A1 (en) 2000-04-09 2001-03-27 Method for producing bristles used to administer media, bristles produced according to said method and brushware comprising bristles of this type

Publications (2)

Publication Number Publication Date
EP1272070A1 EP1272070A1 (en) 2003-01-08
EP1272070B1 true EP1272070B1 (en) 2003-11-05

Family

ID=7637904

Family Applications (1)

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EP01933759A Expired - Lifetime EP1272070B1 (en) 2000-04-09 2001-03-27 Method for producing bristles used to administer media, bristles produced according to said method and brushware comprising bristles of this type

Country Status (27)

Country Link
US (1) US7014800B2 (en)
EP (1) EP1272070B1 (en)
JP (1) JP2003529428A (en)
KR (1) KR100749535B1 (en)
CN (1) CN1427682A (en)
AR (1) AR027774A1 (en)
AT (1) ATE253311T1 (en)
AU (1) AU2001260156A1 (en)
BR (1) BR0109942A (en)
CA (1) CA2405071A1 (en)
CZ (1) CZ20023344A3 (en)
DE (2) DE10017306A1 (en)
EG (1) EG22737A (en)
ES (1) ES2208596T3 (en)
HU (1) HUP0300553A2 (en)
IL (2) IL152045A0 (en)
MX (1) MXPA02009893A (en)
NO (1) NO20024844L (en)
PL (1) PL358755A1 (en)
PT (1) PT1272070E (en)
RU (1) RU2002129889A (en)
SK (1) SK14442002A3 (en)
TR (1) TR200202327T2 (en)
TW (1) TW548083B (en)
WO (1) WO2001076414A1 (en)
YU (1) YU76402A (en)
ZA (1) ZA200207881B (en)

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US20130000659A1 (en) * 2011-12-01 2013-01-03 Davis John J Toothbrush/toothpaste fluoride dosing toothbrush, system and method
US9603685B2 (en) * 2013-09-09 2017-03-28 LeedTech Resources Company, LLC Method of manufacturing an interdental cleaner
AU2013407533B2 (en) * 2013-12-12 2017-01-12 Colgate-Palmolive Company Multi-component bristle having components with different oral care additives, and oral care implement comprising the same
EP2918191B1 (en) 2014-03-11 2024-01-24 The Procter & Gamble Company Head for an oral care implement
US10098447B2 (en) 2014-07-15 2018-10-16 The Procter & Gamble Company Oral-care implement having color-communicative element
US10702057B2 (en) 2015-07-07 2020-07-07 Colgate-Palmolive Company Oral care implement and monofilament bristle for use with the same
EP3251552B1 (en) 2016-06-03 2021-03-10 The Procter and Gamble Company Head for an oral care implement and oral care implement
EP3251548B1 (en) 2016-06-03 2024-02-14 The Procter & Gamble Company Filament for an oral care implement and oral care implement
US10251470B1 (en) 2017-10-10 2019-04-09 The Procter & Gamble Company Head for an oral care implement and oral care implement
US11219302B2 (en) 2017-10-10 2022-01-11 The Procter & Gamble Company Head for an oral care implement and oral care implement
EP3747309B1 (en) 2019-06-05 2023-12-06 The Procter & Gamble Company Head for an oral care implement and oral care implement
EP3747308A1 (en) 2019-06-05 2020-12-09 The Procter & Gamble Company Head for an oral care implement and oral care implement
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Also Published As

Publication number Publication date
DE50100916D1 (en) 2003-12-11
SK14442002A3 (en) 2003-04-01
IL152045A0 (en) 2003-05-29
AR027774A1 (en) 2003-04-09
RU2002129889A (en) 2004-03-20
DE10017306A1 (en) 2001-10-11
AU2001260156A1 (en) 2001-10-23
ZA200207881B (en) 2003-10-01
EG22737A (en) 2003-07-30
US20030044604A1 (en) 2003-03-06
JP2003529428A (en) 2003-10-07
CZ20023344A3 (en) 2003-01-15
YU76402A (en) 2003-08-29
CN1427682A (en) 2003-07-02
WO2001076414A1 (en) 2001-10-18
TR200202327T2 (en) 2003-02-21
KR20020089438A (en) 2002-11-29
NO20024844L (en) 2002-12-09
HUP0300553A2 (en) 2003-07-28
US7014800B2 (en) 2006-03-21
IL152045A (en) 2007-09-20
BR0109942A (en) 2003-05-27
KR100749535B1 (en) 2007-08-16
PT1272070E (en) 2004-03-31
MXPA02009893A (en) 2003-04-14
TW548083B (en) 2003-08-21
ATE253311T1 (en) 2003-11-15
EP1272070A1 (en) 2003-01-08
NO20024844D0 (en) 2002-10-07
PL358755A1 (en) 2004-08-23
CA2405071A1 (en) 2002-10-03
ES2208596T3 (en) 2004-06-16

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