EP1254984B1 - Revêtement mural en fibre de verre avec un effet volumétrique - Google Patents

Revêtement mural en fibre de verre avec un effet volumétrique Download PDF

Info

Publication number
EP1254984B1
EP1254984B1 EP01110810A EP01110810A EP1254984B1 EP 1254984 B1 EP1254984 B1 EP 1254984B1 EP 01110810 A EP01110810 A EP 01110810A EP 01110810 A EP01110810 A EP 01110810A EP 1254984 B1 EP1254984 B1 EP 1254984B1
Authority
EP
European Patent Office
Prior art keywords
coating
process according
fabric
glass
glass fibre
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP01110810A
Other languages
German (de)
English (en)
Other versions
EP1254984A1 (fr
Inventor
Per Edlund
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Johns Manville Europe GmbH
Original Assignee
Johns Manville Europe GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to EP01110810A priority Critical patent/EP1254984B1/fr
Priority to ES01110810T priority patent/ES2353195T3/es
Priority to PT01110810T priority patent/PT1254984E/pt
Priority to AT01110810T priority patent/ATE482312T1/de
Priority to DE60143111T priority patent/DE60143111D1/de
Application filed by Johns Manville Europe GmbH filed Critical Johns Manville Europe GmbH
Priority to DK01110810.7T priority patent/DK1254984T3/da
Priority to CA002385108A priority patent/CA2385108A1/fr
Publication of EP1254984A1 publication Critical patent/EP1254984A1/fr
Application granted granted Critical
Publication of EP1254984B1 publication Critical patent/EP1254984B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00—Processes for producing special ornamental bodies
    • B44C5/04—Ornamental plaques, e.g. decorative panels, decorative veneers
    • B44C5/0423—Ornamental plaques, e.g. decorative panels, decorative veneers containing fibreglass elements
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0043—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
    • D06N3/005—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers obtained by blowing or swelling agent
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0002—Wallpaper or wall covering on textile basis
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2201/00—Chemical constitution of the fibres, threads or yarns
    • D06N2201/08—Inorganic fibres
    • D06N2201/082—Glass fibres
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2203/00—Macromolecular materials of the coating layers
    • D06N2203/02—Natural macromolecular compounds or derivatives thereof
    • D06N2203/024—Polysaccharides or derivatives thereof
    • D06N2203/028—Starch or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2205/00—Condition, form or state of the materials
    • D06N2205/02—Dispersion
    • D06N2205/023—Emulsion, aqueous dispersion, latex
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2205/00—Condition, form or state of the materials
    • D06N2205/08—Microballoons, microcapsules
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2209/00—Properties of the materials
    • D06N2209/06—Properties of the materials having thermal properties
    • D06N2209/067—Flame resistant, fire resistant

Definitions

  • Fiberglass wall coverings offer fire resistance, easy and uncomplicated handling and flexibility in use. They exhibit good abrasion resistance and appearance following painting. Typically, following adherence of the fiberglass wall covering to a structure, a uniform coating of a solid paint is applied, creating a textured painted wall effect.
  • GB 2 249 994 A describes applying a colored pattern by a heated roller to a glass fiber fabric treated with a polyvinyl chloride, acrylic or polyester coating having a solids content of between 6 and 35% by weight of dry extracts.
  • the outcome of the process produced a finished glass fabric with a fixed image.
  • the hot transfer of colored pigments onto a glass fabric at a temperature of between 130° and 210°C creates a rigid and stiff fabric, not conducive to packaging as a rolled good for later application to a wall.
  • EP 0 909 850 A2 describes an imprintable self-adhesive woven glass fabric and a process for applying a thin film of adhesive which may carry a decorative pattern directly on the untreated glass fiber fabric.
  • EP 0 875 618 describes a fiberglass nonwoven backing printed with ornamental designs by printing hard particle containing adhesives.
  • EP 0 445 461 describes a wall covering that has a discontinuous printed adhesive coating which creates the desired pattern.
  • US Patent 4,320,163 describes a three-dimensional ceiling board or wall covering by applying an intermediate foam layer of vinyl or acrylic to a glass fabric followed by printing and curing a pigmented foamable acrylic paste or vinyl plastisol upon the intermediate foam layer to produce volumetric structure on selected areas.
  • EP-A-1,035,187 describes a paintable glass fabric in which a size containing starch, an acrylic binder and other ingredients are applied to both sides of the fabric followed by the application of a reactivable glue to one side of the fabric.
  • the glass fiber fabric has the same properties as standard glass fiber wall coverings, such as excellent fire resistance.
  • a glass fiber fabric is produced by a process as claimed in claim 1..
  • While the present invention utilizes fiberglass fabric in woven rolled form, other fiberglass fabrics such as a nonwoven mat may also be utilized.
  • Figure 1 depicts a preferred apparatus arrangement for applying a standard first chemical dispersion on both sides of the glass fabric.
  • Figure 2 depicts the process for applying the second chemical dispersion to one side of the glass fabric in a preferred application technique using a rotating screen.
  • Figure 3 depicts an example of an image made according to the invention.
  • Figure 1 depicts a process for applying a first chemical treatment to a glass fabric.
  • the glass fabric is a woven product formed from fiber glass yarn.
  • the weave is typically a simple pattern, of up to eight shafts.
  • the fabric can be produced, for example, on Dornier weaving machines, Rapiers or Air-Jets, in typically two or three meter widths.
  • the fabric can be provided in roll form having a length of 1,500 - 6,000 meters.
  • Many fiber glass yarns may be selected for use when producing the woven materials for use in the present invention.
  • Preferred yarns include, for the warp direction continuous C-glass or E-glass of 9-10 ⁇ m (microns), 139-142 tex with 315 - 340 ends per meter.
  • An alternative warp yarn is continuous C-glass or E-glass of 6 - 9 ⁇ m (micron), 34 - 68 tex with 680 ends per meter.
  • a preferred glass is discontinuous spun E-glass or C-glass, 8 - 11 ⁇ m (micron), 165- 550 tex with 170 - 600 ends per meter.
  • An alternative weft yarn includes continuous volumized or bulked E-glass or C-glass of 8 - 11 ⁇ m (micron), 165- 550 tex with 170 - 600 ends per meter.
  • the present invention is also applicable to nonwoven glass fabrics, such as mat products. These can be produced, for example, by conventional wet-laid processes such as those described in U.S. Patent Nos. 4,112,174 ; 4,681,802 and 4,810,576 .
  • the glass fabric 1 preferably provided in roll form, is fed to the first impregnation bath 2 , typically with the aid of through rollers 3 and conventional conveyance means to contact on both surfaces a bath of the chemical dispersion.
  • a transfer or pick up roll may convey the chemical mixture to at least one of the glass fabric surfaces.
  • the first aqueous chemical dispersion consists of the components identified in Table 1 below where concentrations are provided on a weight basis.
  • Table 1 Starch binder 10 to 70% of dry substance Polymeric latex binder 20 to 80% of dry substance Cross-linker 0 to 15% of dry substance Pigments 10 to 30% of dry substance
  • rotary screens may be used to apply the chemicals to the glass fabric 1 .
  • the chemical mixture is supplied to the interior of the two rotating screens and applied to the glass fabric by contact with the rotating screens.
  • starch binder or CMCs (carboxy-methyl cellulose) can be used.
  • Starch binder derived from potatoes are preferred, but also corn can be used as a starch source.
  • the polymeric latex binders are preferably copolymers of vinyl acetate and acrylics, e.g. ethylvinyl acetate and styrene acrylics.
  • polyvinyl acetate (PVAc) or other polymeric latex binders can also be used.
  • Cross-linkers are agents that are reactive with certain functional groups located primarily on the polymeric latex. Cross-linkers preferably are used in a concentration of 3 to 12 percent on a dry basis to improve important characteristics such as film formation, hydrophobicity, wet strength etc. These reactive agents can be either organic or inorganic types, e.g. based on zirconium, urea/formaldehyde or glyoxal derivatives. Zirconium cross-linking agents (e. g. ammonium-zirconium-carbonate) are preferred.
  • the preferred formulation is the most cost effective and technically functional.
  • the mixture of table 1 is preferably water based, and has a dry substance percentage of between 5 and 20 weight percent, preferably between 10 and 12 weight percent in the first chemical bath.
  • white pigments such as titanium dioxide
  • coloured pigments can also be added or used to create coloured fabrics as well.
  • the fabric may be conveyed to a drying oven 4, which in the preferred embodiment of Figure 1 utilises steam heated cylinders 5. After drying the fabric can be cut into desired width, and collected for the secondary treatment described hereafter. A fabric length of 1,000 and 6,000 meters of treated fabric can be collected at batching stand 6. Alternatively, the subsequent application step wherein the second coating is applied can be carried out on a continuous basis.
  • This first impregnation step adds additional volume and opacity to the fabric. Typically 10 - 60 g/m 2 of the coating are applied to the wall covering. This leads to a pre-painted fabric which requires only one single painting step by the end-user. The time consuming second paint which is usually necessary for glass fabrics can be omitted.
  • FIG 2 a preferred method of applying the image coating is shown. Such application to one side only is on top of the previously dried first coating.
  • a rotating screen 11 such as available from Stork, may be used to selectively apply a secondary image coating to a select portion of the treated glass fabric 12 .
  • the rotating screen is preferably laser drilled with a desired image pattern, and the chemicals of the second chemical mixture are supplied to the interior of the rotating screen.
  • the chemical mixture 14 of the second coating are selectively applied to the glass fabric by contact with the rotating screen.
  • the image coating contains chemicals or chemical mixtures which expand or chemically react upon the application of heat.
  • chemicals like foaming agents or expandable microspheres are well known and commercially available over many years. Finely dispersed materials which expand upon heating can be used.
  • expandable thermoplastic microspheres are well suited for the image coating.
  • microspheres are commercially available (e.g. Expancel®, CASCO Nobel). They consist of a polymer shell encapsulating blowing agents which are gasified upon heating. Examples for usable polymers of the microspheres are arylic esters, methacrylic esters, vinylchoride, vinylidene chloride, styrene or butadiene or mixtures thereof.
  • blowing agents or propellants are for example CFCs or hydrocarbons, such as n-pentane, isopentane, isobutane, butane or other blowing agents, which are conventionally used in those microspheres.
  • the particle size of the unexpanded spheres is in the range of 1 ⁇ m-1mm, preferably 2-500 ⁇ m, more preferably 5-50 ⁇ m.
  • the thermoplastic shell softens resulting in a dramatic increase of the volume of the microspheres.
  • the volume of the microspheres increases more than 40 times corresponding to an increase of the microspheres by a factor 2-5.
  • Such microspheres are mostly used as fillers in polymers and paints.
  • a preferred aqueous chemical mixture useful in the secondary image coating of the present invention consists of those components set out in Table 2 below.
  • the concentration of said substances of table 2 in water is 10 - 50 %, preferably 20 - 40 % by weight.
  • Preferably 0.5 - 50 g/m 2 , and more preferred 5 - 40 g/m 2 of the image coating are applied to the glass fabric.
  • Table 2 Polymeric latex binder 20 to 80% of dry substance Expandable Chemicals 5 to 40% of dry substance
  • Polypropylene glycol 5 to 50% of dry substance Rheology modifier 0 to 20% of dry substance
  • the polymeric latex binders are preferably copolymers of vinyl acetate and acrylics, e.g. ethylvinyl acetate and styrene acrylics. However, polyvinyl acetate (PVAc) or other polymeric latex binders can also be used.
  • PVAc polyvinyl acetate
  • the secondary image coating may also contain pigments for image colouring. All kind of pigments which are suitable for the process can be used.
  • Rheology modifiers Thickener
  • Rheology modifiers may be also added to the image coating to improve the processability.
  • Rheology modifiers may be selected from the known group of acrylic thickener, polyurethane thickener or cellulose thickener, etc.
  • small amounts of de-foaming materials based on oil or silica can also be added to the chemical mixture to improve the efficiency of the printing process.
  • the image coating may be applied by a flat screen method, or any other method to selectively place the chemicals on the treated glass fibre surface.
  • the glass fabric now possessing an image coating, must be conveyed to a drying means which in the preferred embodiment of Figure 2 is depicted as air dryers 16.
  • air dryers 16 a drying means which in the preferred embodiment of Figure 2 is depicted as air dryers 16.
  • the expandable chemicals of the image coating react and cause the coating to expand. Induced by the chemical reaction and the expansion of the coating, a well distinguishable volumetric pattern can be created.
  • the form of these expanded or blown up spheres is typically spherical to oval in the cross section through the spheres ("regular form") and therefore different from those cavities of known foamed polymer structures which have an irregular form in the cross section through the foam. "Irregular" means any possible form of a foamed cavity.
  • the drying process also stabilises the coating and the created image pattern.
  • the fabric can be cut into desired widths and lengths, and collected into rolls at batching stand 18.
  • the drying temperatures and drying times which are needed to fully establish the images depends on the used image coating materials and the mixture compositions. With the preferred composition of Table 2, the fabric must be dried at 140°C for 240 sec.
  • FIG. 3 depicts an examples of the finished image which is created after having painted the treated glass fibre wall covering of the present invention.
  • Conventional types of glues can be used to apply the treated glass fabric to a wall or other interior structures.
  • the product of the present invention possesses the same benefits and favourable properties as untreated standard glass fibre wall covering, with the added benefit of a volumetric image effect in a user selected colour, combined with a less labour intensive process.
  • the image effect glass wall covering of the present invention results in a higher quality and in a more consistent appearance if compared to other painting methods, in particular when used in small spaces and interior corners.
  • All percent-ratios refer to weight percent.
  • a glass woven fabric consisting of 139 tex texturized warp yarns with 315 yarns per meter and 250 tex texturized glass staple fiber yarns with 200 yarns per meter is produced and impregnated on both sides with a 12 % aqueous mixture of 25% potato starch and 47% acrylic latex binder together with 6% zirconium cross-linker (ammonium-zirconium-carbonate) and 22% white, titanium oxide based pigment.
  • a 30 % aqueous dispersion is applied by using rotary screens to create an image at the fabric surface.
  • the formulation contains, based on dry substance, 70% polymeric binder, 15% microspheres-composition ( Expancel®) and 15% propylene glycol. After heating and drying in an air dryer oven the image (e.g. a logo as depicted in Fig. 3 ) develops.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)
  • Woven Fabrics (AREA)

Claims (17)

  1. Un procédé pour former un revêtement mural en fibre de verre avec un effet d'image volumétrique caractérisé par la réalisation des suivantes étapes:
    (a) pourvoir un tissu en fibre de verre;
    (b) former un premier revêtement séché sur tous les deux faces dudit tissu en fibre de verre qui est appliqué d'une dispersion aqueuse formée de
    (i) 10 à 70 % en poids de substance séchée d'un liant d'amidon,
    (ii) 20 à 80 % en poids de substance séchée d'un liant de latex polymère,
    (iii) 10 à 30 % en poids de substance séchée de pigments et
    (iv) 0 à 15 % en poids de substance séchée d'un agent de réticulation;
    (c) former subséquemment un second revêtement sur ledit premier revêtement séché sur une face dudit tissu en fibre de verre par l'application de manière sélective du second revêtement à une portion distincte du tissu en verre, ledit second revêtement appliqué d'une mixture chimique comprenant un liant polymère et des produits chimiques expansibles et réchauffer le second revêtement et créant par cela un motif d'image distincte.
  2. Un procédé selon la revendication 1 caractérisé en ce que ledit tissu en fibre de verre est un tissu tissé ou non tissé.
  3. Un procédé selon la revendication 1 caractérisé en ce que ledit composant d'amidon du premier revêtement séché est l'amidon de pomme de terre.
  4. Un procédé selon la revendication 1 caractérisé en ce que ledit composant de liant de latex polymère du premier revêtement séché est un liant de latex acrylique.
  5. Un procédé selon la revendication 1 caractérisé en ce que ladite dispersion aqueuse du premier revêtement séché comprend un agent de réticulation, particulièrement un agent de réticulation à base de zirconium.
  6. Un procédé selon la revendication 1 caractérisé en ce que ladite dispersion aqueuse du premier revêtement séché comprend le dioxyde de titane comme pigments.
  7. Un procédé selon la revendication 1 caractérisé en ce que ladite dispersion aqueuse dudit premier revêtement séché est appliquée dans un procédé continu.
  8. Un procédé selon la revendication 1 caractérisé en ce que ledit liant de latex polymère du second revêtement est un liant de latex acrylique.
  9. Un procédé selon la revendication 1 caractérisé en ce que lesdits produits chimiques expansibles du second revêtement sont des microsphères thermoplastiques.
  10. Un procédé selon la revendication 1 caractérisé en ce que ladite mixture chimique du second revêtement comprend aussi un modificateur rhéologique et des agents anti-mousse.
  11. Un procédé selon la revendication 1 caractérisé en ce que ladite mixture chimique du second revêtement comprend aussi des pigments.
  12. Un procédé selon la revendication 1 caractérisé en ce que le séchage du tissu en fibre de verre dans les étapes (b) et/ou (c) est réalisé par l'utilisation de cylindres de séchage ou dans les séchoirs à air.
  13. Un procédé selon la revendication 1 caractérisé en ce que l'application de ladite dispersion aqueuse dans l'étape (b) est réalisée par l'utilisation d'un applicateur à écran rotatif ou des rouleaux de transfert.
  14. Un procédé selon la revendication 1 caractérisé en ce que l'application de ladite mixture chimique dans l'étape (c) est réalisée par l'utilisation d'un applicateur à écran rotatif
  15. Un revêtement mural en fibre de verre avec un motif d'image distincte capable d'être obtenu par le procédé de la revendication 1.
  16. Un revêtement mural en fibre de verre selon la revendication 15, où le second revêtement séché expose un motif d'image volumétrique.
  17. Un revêtement mural en fibre de verre selon la revendication 15, où le second revêtement comprend une structure volumétrique comprenant une pluralité de cavités régulières.
EP01110810A 2001-05-04 2001-05-04 Revêtement mural en fibre de verre avec un effet volumétrique Expired - Lifetime EP1254984B1 (fr)

Priority Applications (7)

Application Number Priority Date Filing Date Title
ES01110810T ES2353195T3 (es) 2001-05-04 2001-05-04 Revestimientos murales de fibra de vidrio con efecto volumã‰trico.
PT01110810T PT1254984E (pt) 2001-05-04 2001-05-04 Revestimento de parede em fibra de vidro com efeito volumétrico
AT01110810T ATE482312T1 (de) 2001-05-04 2001-05-04 Glasfaserwandbeläge mit volumetrischem effekt
DE60143111T DE60143111D1 (de) 2001-05-04 2001-05-04 Glasfaserwandbeläge mit volumetrischem Effekt
EP01110810A EP1254984B1 (fr) 2001-05-04 2001-05-04 Revêtement mural en fibre de verre avec un effet volumétrique
DK01110810.7T DK1254984T3 (da) 2001-05-04 2001-05-04 Glasfibervægbeklædninger med volumetrisk effekt
CA002385108A CA2385108A1 (fr) 2001-05-04 2002-05-06 Revetements muraux en fibre de verre a effet volumetrique

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
EP01110810A EP1254984B1 (fr) 2001-05-04 2001-05-04 Revêtement mural en fibre de verre avec un effet volumétrique

Publications (2)

Publication Number Publication Date
EP1254984A1 EP1254984A1 (fr) 2002-11-06
EP1254984B1 true EP1254984B1 (fr) 2010-09-22

Family

ID=8177310

Family Applications (1)

Application Number Title Priority Date Filing Date
EP01110810A Expired - Lifetime EP1254984B1 (fr) 2001-05-04 2001-05-04 Revêtement mural en fibre de verre avec un effet volumétrique

Country Status (7)

Country Link
EP (1) EP1254984B1 (fr)
AT (1) ATE482312T1 (fr)
CA (1) CA2385108A1 (fr)
DE (1) DE60143111D1 (fr)
DK (1) DK1254984T3 (fr)
ES (1) ES2353195T3 (fr)
PT (1) PT1254984E (fr)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1481797A1 (fr) * 2003-05-23 2004-12-01 Casco Surfaces AB Matériau stratifié et procédé de sa fabrication
KR100533806B1 (ko) * 2003-07-10 2005-12-06 한국바이린주식회사 자동차 내장재 및 그 제조방법

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4320163A (en) * 1979-12-17 1982-03-16 Burlington Industries, Inc. Three-dimensional ceiling board facing
GB9005216D0 (en) 1990-03-08 1990-05-02 Allied Colloids Ltd Adhesives materials and their production
FR2668422B1 (fr) 1990-10-24 1995-03-10 Hexcel Genin Sa Procede pour l'impression de motifs colores sur un substrat a base de fibres de verre et nouveau produit obtenu.
US5356683A (en) * 1993-10-28 1994-10-18 Rohm And Haas Company Expandable coating composition
JPH09104798A (ja) * 1995-10-09 1997-04-22 Saiden Kagaku Kk 壁装飾用熱膨張性被覆組成物および凹凸模様を有する壁紙
IT1297842B1 (it) 1997-04-16 1999-12-20 Anni 90 S R L Procedimento realizzativo in continuo di fogli per rivestimenti murali con base di ancoraggio in tessuto-non-tessuto di fibra di vetro e
DE29718222U1 (de) 1997-10-14 1999-02-18 Sauer Wigbert H Textilglasgewebebahn
DE19811152A1 (de) * 1998-03-14 1999-09-16 Werner Abend Wetterbeständige Außentapete
FR2790716B1 (fr) * 1999-03-08 2001-05-11 Mermet Sa Toile a peindre destinee a former un revetement d'une surface interieure de batiment

Also Published As

Publication number Publication date
DE60143111D1 (de) 2010-11-04
PT1254984E (pt) 2010-12-16
EP1254984A1 (fr) 2002-11-06
ES2353195T3 (es) 2011-02-28
CA2385108A1 (fr) 2002-11-04
ATE482312T1 (de) 2010-10-15
DK1254984T3 (da) 2010-12-06

Similar Documents

Publication Publication Date Title
US4409280A (en) Decorative surface coverings
US4320163A (en) Three-dimensional ceiling board facing
US5169704A (en) Decorative inlaid sheet materials having multiple printed layers
US20090117275A1 (en) Methods of forming decorative veil
EP1162306B1 (fr) Revêtement de mur à base d'un tissu de verre préalablement encollé
US6759116B2 (en) Volumetric effect glass fiber wallcoverings
US4675212A (en) Process for manufacturing decorative surface coverings
US4140566A (en) Reinforced sheet-type wallcovering
EP0079723B1 (fr) Revêtement mural décoratif sous forme enroulée
EP1101749B1 (fr) Revêtements muraux en fibres de verre avec un effet de motif
EP1143064B1 (fr) Revêtement mural en fibre de verre pelable
EP1254984B1 (fr) Revêtement mural en fibre de verre avec un effet volumétrique
US20030096058A1 (en) Design effect fiberglass wallcoverings
US4433022A (en) Three-dimensional ceiling board facing
EP1262591B1 (fr) Revêtement mural préalablement encollé et pelable
JP2736635B2 (ja) 装飾シート
JPH09195177A (ja) ペンキ下地材の製造方法
JP2001248079A (ja) 新規な高品質壁紙及びその製造方法
KR200318306Y1 (ko) 기름을 코팅시킨 섬유층을 포함한 바닥재
JP3447679B2 (ja) ステキヒトサイズ度が３０分以上である壁紙及びその製造方法
JP2001310438A (ja) 凹凸のある装飾シートの製造方法
CA1187392A (fr) Couvre-plancher a haut pouvoir reflechissant
KR20050019529A (ko) 천연 또는 합성 섬유와 발포층이 조화된 바닥재
JPH0494927A (ja) 不燃性装飾用内装材
JP2001277406A (ja) 内外装用断熱性シート、その製造方法、および断熱性建築部材

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

AX Request for extension of the european patent

Free format text: AL;LT;LV;MK;RO;SI

17P Request for examination filed

Effective date: 20030429

AKX Designation fees paid

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

17Q First examination report despatched

Effective date: 20040510

RAP1 Party data changed (applicant data changed or rights of an application transferred)

Owner name: JOHNS MANVILLE EUROPE GMBH

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE CH CY DE DK ES FI FR GB GR IE IT LI LU MC NL PT SE TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REF Corresponds to:

Ref document number: 60143111

Country of ref document: DE

Date of ref document: 20101104

Kind code of ref document: P

REG Reference to a national code

Ref country code: DK

Ref legal event code: T3

REG Reference to a national code

Ref country code: SE

Ref legal event code: TRGR

REG Reference to a national code

Ref country code: PT

Ref legal event code: SC4A

Free format text: AVAILABILITY OF NATIONAL TRANSLATION

Effective date: 20101209

REG Reference to a national code

Ref country code: NL

Ref legal event code: T3

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Effective date: 20110216

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101223

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed

Effective date: 20110623

REG Reference to a national code

Ref country code: DE

Ref legal event code: R097

Ref document number: 60143111

Country of ref document: DE

Effective date: 20110623

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110531

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110531

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110531

REG Reference to a national code

Ref country code: DE

Ref legal event code: R082

Ref document number: 60143111

Country of ref document: DE

Representative=s name: MAI DOERR BESIER PATENTANWAELTE, DE

Ref country code: DE

Ref legal event code: R082

Ref document number: 60143111

Country of ref document: DE

Representative=s name: MAI DOERR BESIER EUROPEAN PATENT ATTORNEYS - E, DE

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20120528

Year of fee payment: 12

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110504

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100922

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IE

Payment date: 20130528

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: PT

Payment date: 20130424

Year of fee payment: 13

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100922

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20140527

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FI

Payment date: 20140529

Year of fee payment: 14

Ref country code: IT

Payment date: 20140523

Year of fee payment: 14

Ref country code: AT

Payment date: 20140423

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DK

Payment date: 20140602

Year of fee payment: 14

REG Reference to a national code

Ref country code: PT

Ref legal event code: MM4A

Free format text: LAPSE DUE TO NON-PAYMENT OF FEES

Effective date: 20141104

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: PT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20141104

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20140504

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 15

REG Reference to a national code

Ref country code: ES

Ref legal event code: FD2A

Effective date: 20150629

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: ES

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20140505

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20150520

Year of fee payment: 15

Ref country code: SE

Payment date: 20150519

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 20150518

Year of fee payment: 15

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20150529

Year of fee payment: 15

Ref country code: BE

Payment date: 20150520

Year of fee payment: 15

REG Reference to a national code

Ref country code: DK

Ref legal event code: EBP

Effective date: 20150531

REG Reference to a national code

Ref country code: AT

Ref legal event code: MM01

Ref document number: 482312

Country of ref document: AT

Kind code of ref document: T

Effective date: 20150504

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20150504

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150504

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150504

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: AT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150504

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150531

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20150504

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160531

REG Reference to a national code

Ref country code: DE

Ref legal event code: R119

Ref document number: 60143111

Country of ref document: DE

REG Reference to a national code

Ref country code: NL

Ref legal event code: MM

Effective date: 20160601

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160505

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160601

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20170131

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20160531

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20161201