EP1248669A1 - Rückstrahlendes konfetti - Google Patents

Rückstrahlendes konfetti

Info

Publication number
EP1248669A1
EP1248669A1 EP00936328A EP00936328A EP1248669A1 EP 1248669 A1 EP1248669 A1 EP 1248669A1 EP 00936328 A EP00936328 A EP 00936328A EP 00936328 A EP00936328 A EP 00936328A EP 1248669 A1 EP1248669 A1 EP 1248669A1
Authority
EP
European Patent Office
Prior art keywords
confetti
pieces
retroreflective
sheeting
light
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP00936328A
Other languages
English (en)
French (fr)
Inventor
Darrell R. James
Peter J. Swain
John L. Vandenberg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Publication of EP1248669A1 publication Critical patent/EP1248669A1/de
Withdrawn legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00Optical elements other than lenses
    • G02B5/12Reflex reflectors
    • G02B5/122Reflex reflectors cube corner, trihedral or triple reflector type
    • G02B5/124Reflex reflectors cube corner, trihedral or triple reflector type plural reflecting elements forming part of a unitary plate or sheet
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63HTOYS, e.g. TOPS, DOLLS, HOOPS OR BUILDING BLOCKS
    • A63H37/00Jokes; Confetti, streamers, or other dance favours ; Cracker bonbons or the like
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63HTOYS, e.g. TOPS, DOLLS, HOOPS OR BUILDING BLOCKS
    • A63H33/00Other toys
    • A63H33/22Optical, colour, or shadow toys

Definitions

  • the present invention relates generally to decorative visual displays. More particularly, the invention relates to decorative visual displays involving the use of confetti.
  • Confetti comprising small bits of paper has also been used for celebrations such as parades.
  • the confetti is thrown out of windows or projected into the air and allowed to fall gently to the ground.
  • the confetti helps create a festive mood, but the attention of onlookers is not drawn to the confetti in the same way that it is drawn to fireworks.
  • WO 99/36477 (Whitney et al. I) and WO 99/36478 (Whitney et al. II) discloses glitter that, in loose form, can.be used as confetti and thrown into the air to create a visual display or effect.
  • the glitter comprises particles of a film comprising a plurality of alternating layers of at least a first and second polymeric material wherein at least one of the first or second polymeric materials is birefringent.
  • Confetti using other types of materials and using specific particle shapes has also been proposed in the literature.
  • the confetti of the prior art is generally composed of particles that are either diffusely reflective, such as ordinary white office paper, or specularly reflective, such as the glitter of Whitney et al. I or II.
  • Retroreflective materials have been used for many decades in roadway signs and vehicle license plates to increase the conspicuity of such items to vehicle drivers.
  • Retroreflective materials have the property of reflecting incident light, such as light from a vehicle headlamp, back in the general direction from which the light originated, regardless of the angle at which the incident light impinges on the surface of the material.
  • incident light such as light from a vehicle headlamp
  • retroreflective sheeting generally uses either: (i) a monolayer of tiny glass beads or microspheres that cooperate with a specular or diffuse reflector, or (ii) a surface provided with a multitude of specularly reflective facets arranged as prismatic cube corner elements.
  • the beads can be embedded between layers of polymers, or partially exposed to the atmosphere, or partially exposed to air that is trapped between a substrate in which the beads are partially embedded and a transparent cover film that is selectively bonded to the substrate.
  • the facets of the cube corner elements can individually reflect by total internal reflection at a polymer-air interface, or by reflection at a metal film or the like.
  • confetti composed of pieces of retroreflective material.
  • the retroreflective confetti produces a brilliant display when dispersed into the air in a region illuminated by a light source and viewable by an observer who is situated close enough to the light source to view retroreflected light.
  • a method of doing business includes collecting and packaging pieces of retroreflective material suitable for use as confetti, and providing the packaged pieces to a customer for use as confetti.
  • FIG. 1 is a perspective view of a container of retroreflective confetti
  • FIG. 2 is a view of an entertainer dispersing the confetti of FIG. 1 into the air to create a decorative visual display
  • FIG. 3a is a simplified two-dimensional representation of an observer, a light source, and a piece of confetti, the figure also illustrating the entrance angle ⁇ and the observation angle ⁇ ;
  • FIGS. 3b,c,d are views similar to FIG. 3a wherein the piece of confetti is a diffuse reflector such as paper (FIG. 3b), a specular reflector such as a mirror film (FIG. 3c), and a retroreflector (FIG. 3d);
  • the piece of confetti is a diffuse reflector such as paper (FIG. 3b), a specular reflector such as a mirror film (FIG. 3c), and a retroreflector (FIG. 3d);
  • FIG. 4 is an idealized graph showing relative visual impact of an illuminated piece of confetti as a function of entrance angle ⁇ ;
  • FIG. 5 is an overhead view of an arrangement for providing a brilliant visual display for a group of observers
  • FIG. 6 is a perspective view of an alternative arrangement for providing a brilliant visual display for a group of observers; and FIGS. 7a,b,c are sectional views of cube corner retroreflective material suitable for use as confetti.
  • FIG. 1 shows a box 10 filled with individual pieces of retroreflective material 12.
  • the retroreflective pieces can be made most conveniently by providing larger pieces or even a long web of retroreflective material, and cutting at least a portion of the material to form the individual pieces.
  • a manufacturing or slitting line for a web of retroreflective material is provided. Material is removed along one or both edges of the web, and the removed material is further cut into pieces of a desired size, collected, and placed into box 10. The remainder of the retroreflective web material may undergo further processing, but is eventually used in conventional applications such as roadway signs, vehicle license plates, clothing, or the like.
  • pieces of retroreflective may undergo further processing, but is eventually used in conventional applications such as roadway signs, vehicle license plates, clothing, or the like.
  • retroreflective by-product materials are advantageous from an environmental standpoint in reducing waste. Regardless of the origin of the individual pieces of retroreflective material 12, they are collected and boxed or otherwise packaged so that they can be sold and shipped to a user. The user can be an end user such as an entertainer, a theatrical designer, a special effects designer, or the like.
  • the user can alternatively be an entity in the chain of commerce between the manufacturer and the end user, such as a distributor or a business that further prepares the retroreflective confetti before distribution and sale to end users.
  • Such further preparation may include, for example, packing the confetti into canisters that can be thrown or launched into .the air, or mixing the confetti with water in a sealed transparent globe that can simulate a winter scene by shaking.
  • an entertainer 14 throws a handful of the retroreflective material (in loose form) into the air to disperse the retroreflective pieces in a region 16 that can be viewed by an audience.
  • the simple box 10 of FIG. 1 can be used, as well as bags, canisters, and sealed, dissolvable, and/or frangible containers.
  • Each bag, box, canister, or container can contain pieces of a single color, or instead a plurality of different colored-pieces can be packaged.
  • the packaging can also serve as a dispenser for the confetti.
  • FIGS. 3a-d illustrate schematically the lighting conditions suitable for viewing the confetti in retroreflected light.
  • FIGS. 3a-d also illustrate the fundamental differences in reflectivity that make retroreflective confetti substantially more striking in visual appearance than either diffusely reflective confetti or specularly reflective confetti.
  • a randomly oriented piece of confetti 20 is disposed to be illuminated by a light source 22 and viewed by an observer 24.
  • the piece 20 has a front surface defining an axis 26 that is perpendicular to the surface.
  • Axis 26 is also referred to as the surface normal of piece 20.
  • An illumination axis 28 extends from the light source 22 to the piece 20.
  • An observation axis 30 extends from observer 24 to piece 20.
  • Angle ⁇ , as shown, is referred to as the entrance angle, and angle is referred to as the observation angle.
  • the observer 24 is close enough to the light source 22, or the piece 20 of confetti is far enough away from the observer 24 or light source 22, so that the observation angle cc is very small, typically less than 2 degrees, more preferably less than 1 degree, and even more preferably on the order of about 0.2 degrees or less.
  • a theoretically perfect retroreflector would only reflect light back along the path from which it was incident, such that only an observer 24 located on illumination axis 28 could view the retroreflected light.
  • Practical retroreflective sheeting however directs light in a narrow cone centered on the illumination axis 28, such that an observer disposed proximate the light source 22 is able to view the retroreflected light.
  • an observer "disposed proximate the light source” or a light source "disposed proximate the observer” means that the observation angle is very small as described above, regardless of the physical distance between the light source and the observer.
  • FIG. 3b shows the same arrangement as that of FIG. 3a, except that the generic piece of confetti 20 is relabeled as piece 32, the front surface of which is diffusely reflective as with ordinary paper confetti.
  • Light 34 that is incident upon piece 32 along illumination axis 28 strikes the confetti and is diffusely reflected in all directions, depicted as reflected light 36.
  • the reflected light 36 enables the observer to perceive the confetti, but the diffuse reflection does not attract significant attention.
  • FIG. 3c also shows the same arrangement as that of FIG. 3a, except that the generic piece of confetti is relabeled as piece 38.
  • Piece 38 is specularly reflective for light incident on its front surface, as with mirror film confetti.
  • Light 34 that is incident upon piece 38 along illumination axis 28 strikes the confetti and is specularly reflected in a direction that makes an angle of reflection ⁇ with respect to surface normal 26 equal to the entrance angle ⁇ .
  • the specularly reflected light 40 is directed away from the observer 24 in the situation shown, and thus the specularly reflective piece 38 will not be visible to observer 24 in the absence of other light sources.
  • the piece 38 will be visible to observer 24 as a bright spot of light only when the piece 38 is oriented precisely to the point where surface normal 26 bisects the observation angle .
  • this condition is met extremely rarely.
  • only a tiny fraction of specularly reflective pieces 38 in a cloud of dispersed confetti appear bright to an observer at any given time.
  • the flashes of light reflected from such pieces are extremely brief.
  • FIG. 3d likewise shows the arrangement of FIG. 3a, except that the generic piece of confetti is relabeled as 42.
  • Piece 42 is retroreflective for light impinging on its front surface.
  • Light 34 that is incident upon piece 42 along illumination axis 28 strikes the confetti and is retroreflected in an intense beam or cone of light 44 that overlaps with the observation axis 30. The observer sees a bright spot of light. Because of the nature of retroreflection, the retroreflected light 44 remains centered on axis 28 for a wide range of entrance angles ⁇ . A piece of such confetti tumbling randomly through the air therefore appears bright to the observer for much of its travel time.
  • Curve 50 represents the relative visual impact of the diffusely reflective confetti piece 32 (FIG. 3b). Curve 50 is considerably lower than the maxima of the other curves but changes only gradually with entrance angle ⁇ .
  • Curve 54 represents the relative visual impact of the retroreflective confetti piece 42. Like curve 52, curve 54 has a very high peak visual impact. However, like curve 50 (and unlike curve 52), curve 54 decreases very gradually with increasing ⁇ . As an illustration, the coefficient of retroreflection R A for most types of retroreflective sheeting available today changes from a maximum value at ⁇ « 0 degrees to half of its maximum value at ⁇ « 30 to 60 degrees. Thus, FIG. 4 illustrates in graphical fashion the tremendous advantage of retroreflective confetti over simple paper confetti or mirror film confetti.
  • FIG. 5 an arrangement is shown for providing a brilliant visual display for a plurality of observers 56.
  • Observers 56 are shown seated in an observation area 58 so that they can view region 60, where retroreflective confetti is dispersed.
  • an array of light sources 62 is provided proximate observation area 58 such that the observation angle ⁇ remains small as discussed in connection with FIG. 3a.
  • the observers 56 perceive a dazzling visual display, an example of which is crudely depicted in FIG. 2.
  • Colors can be displayed particularly well with retroreflective confetti because of the high visual impact (unlike paper confetti), the relatively long duration flashes and high percentage of visually active pieces (unlike mirror film confetti), and ease of color selection (unlike fireworks). For best contrast, non-retroreflective objects in or near region 60 are dimly illuminated from the standpoint of observers 56.
  • FIG. 6 illustrates another arrangement for providing such a display.
  • the retroreflective confetti is packed into a canister 64 which is launched high into the air by a cannon 66 or by other known means. See, e.g., U.S. Patent Nos. 5,529,527 (Watkins) and 5,803,791 (Chiles); German Patent DE 29510276. While in the air, the canister releases the confetti in a region 68 that is illuminated by a spotlight or similar light source 70. Observers 72 are situated close enough to source 70 to observe the brilliant visual display produced by the retroreflective confetti.
  • FIG. 7a-c illustrate three known types of retroreflective prismatic cube corner sheeting that can be used to make the retroreflective confetti of the invention.
  • beaded retroreflective sheeting can also be used for this purpose.
  • Prismatic cube corner sheetings however generally have somewhat higher coefficients of retroreflection than beaded sheetings, and thus may be preferred in some applications.
  • a retroreflective sheeting 74 is shown retroreflecting an incident beam of light 76.
  • the retroreflection is achieved by a multitude of individual reflecting facets 78 arranged as cube corner elements 80.
  • Each cube corner element comprises three approximately mutually perpendicular facets 78.
  • the facets 78 can reflect light by total internal reflection or by a specularly reflective coating (not shown) such as aluminum.
  • the cube corner elements can be tilted or canted in either a positive or negative sense such that their individual symmetry axes are nonparallel to the surface normal of the front 82 of the sheeting.
  • the sheeting is preferably composed of polymeric materials for ease of manufacture.
  • the cube corner elements 80 are composed of a polymeric material having a relatively high elastic modulus, and are bonded to a body layer 84 composed of a polymeric material having a relatively low elastic modulus.
  • This sheeting is described in more detail in U.S. Patent No. 5,450,235 (Smith et al.).
  • the sheeting can be made to preferentially retroreflect certain colors by incorporating known dyes into cube corner elements 80, body layer 84, or an additional film to be laminated to front surface 82.
  • Sheeting 86 includes a top film 88 and a cube corner layer 90, the layer 90 including cube corner elements as described above.
  • the facets of the cube corner elements reflect by virtue of total internal reflection, and to preserve that reflection a seal film 92 is provided to maintain an air space 94 at the facets.
  • Seal film 92 seals to portions 90a of layer 90 to provide closed cells of trapped air.
  • a pressure sensitive adhesive layer 96 is provided on the seal film and a readily removable release liner 98 is also included so that the sheeting can easily be applied to a substrate by removing the liner and pressing the adhesive against the substrate.
  • pieces of the sheeting are used as confetti, and provided the pieces are sized for easy manipulation by the human hand, observers may wish to retrieve fallen pieces so that they can apply the pieces to books, shoes, clothing, or other desired substrates. Such retrieval can be further encouraged by die-cutting or otherwise shaping the pieces to have an outline in the shape of a cartoon character, letter, or other easily recognizable form.
  • Adhesive layers can of course be used on other cube corner sheeting constructions that do not include a seal film, and can also be used on beaded retroreflective sheeting.
  • adhesive that is exposed along the periphery of each piece may cause some pieces to stick together so that they tumble in an undesirable manner. To avoid this potential problem a fine dust can be applied to the pieces before they are collected and packaged. Simply scattering the pieces onto an office or factory floor and sweeping up the pieces may suffice.
  • Adhesives or other bonding mechanisms can also be used to bond one retroreflective sheeting to another, and the resultant combination sheeting can then be cut up into pieces for confetti.
  • the individual sheetings are preferably bonded to each other so that the combination sheeting is retroreflective from both sides.
  • Pieces of such combination sheeting can double the brightness of a display made using an equal number of confetti pieces that are retroreflective on only one side.
  • the combination sheeting can have sheeting of a first color on one side and sheeting of a second color on the other side for enhanced visual effect.
  • a thin foil of iron, steel, or other known materials that are attracted to magnets can be adhered to the back side of confetti pieces, or sandwiched between individual sheetings in a piece of combination sheeting, to aid in retrieval.
  • the confetti can then be quickly and easily collected with a magnet for reuse in additional visual displays.
  • FIG. 7c shows a side sectional view of a known cube corner sheeting 100 that exhibits a glittering appearance in daytime lighting conditions.
  • the cube corner elements 102 on the back side of the sheeting are randomly tilted to produce the glittering appearance.
  • Such sheeting is sold by Minnesota Mining and Manufacturing Company under the product designation 3MTM ScotchliteTM Reflective Material High Gloss Sparkle Film, and is described in U.S. Patent No. 5,770,124 (Marecki et al.).
  • Confetti made from pieces of this type of sheeting not only exhibits the distinctive retroreflective properties described above, but also can produce a pleasing glittering effect in non-retroreflected light.
  • additional light sources can be provided to illuminate the dispersed confetti from the side, from behind, and/or at oblique angles to accentuate the glittering appearance.
  • the confetti of the present invention can comprise irregularly shaped pieces such as are obtained by cutting up a strip of sheeting with a chipper-shredder, or regularly- shaped pieces such as are obtained by die-cutting. Regularly-shaped pieces can have the outline of well-known symbols, characters, insignia, or copyrighted or trademarked subject matter. The pieces can also be molded, bent, twisted, or curled to form non- planar shapes for enhanced fluttering, tumbling, or visual effects.
  • the confetti need not consist exclusively of pieces of retroreflective material, but can also include pieces of more conventional confetti. With respect to size, the maximum dimension ("width") of the individual pieces of confetti can vary widely. For most applications, widths on the order of about 0.1 to 1 inch will be adequate for display purposes and convenient for handling. Other applications may well benefit from widths substantially smaller or larger than this range.
  • the reflectivity of a piece of retroreflective material depends not only on the entrance angle and observation angle, but also on the angle of rotation about an axis perpendicular to the piece. This angle of rotation is commonly referred to as the orientation angle. Effects of orientation angle are usually minimal for beaded retroreflective sheeting because of the inherent rotational symmetry of the beads. Such effects are more significant for cube corner prismatic sheeting, and may be exploited in the design of particular visual effects.
  • confetti can be made from known polymeric sheeting that is only partially retroreflective.
  • One such sheeting described in U.S. Patent No. 5,056,892 (Cobb, Jr.) has a structured surface of parallel linear prisms that retroreflect light only if the illumination axis of the light source is perpendicular to the prism axes. Because pieces of such sheeting are not fully retroreflective, confetti composed exclusively of such material would not be expected to have a visual impact as great as a confetti of retroreflective particles.
  • Light sources that can be used in visual displays of the invention include conventional floodlamps, arc-lamps, incandescent bulbs, and the like.
  • the sources can be continuous or strobed/pulsed. Laser sources can also be used, as long as adequate measures are taken to avoid eye damage to observers.
  • the sources can be mounted in a fixed position or instead moveable with the head of an observer, as on a hat or held by hand close to the observer's eyes. Glossary of selected terms
  • Confetti means pieces of material that in use are dispersed or scattered into the air or other fluid medium for visual effect.
  • Entrance angle means the angle between the illumination axis and the surface normal.
  • Illumination axis means an axis that extends from a light source to a surface of interest.
  • Light means electromagnetic radiation perceptible to the human eye, generally in the range from about 400 to 700 nm in wavelength.
  • Observation angle means the angle between the illumination axis and the observation axis.
  • Observation axis means an axis that extends from a surface of interest to a detector such as the eye of an observer.
  • Reflectivity is a measure of the apparent brightness of an article when viewed under standard retroreflective conditions (i.e., -4° entrance angle, and 0.2° observation angle), which brightness is normalized for the area of the article and the illumination from the light source used.
  • the reflectivity is also referred to as the coefficient of retroreflection (R A ), and is expressed in units of candelas per lux per square meter (cd/(lux • m 2 )) Reference is made to ASTM Standard Method E808-98, "Standard Practice For Describing Retroreflection".
  • R A coefficient of retroreflection
  • a "retroreflective" article is one that reflects a sufficient amount of light incident upon it at an oblique angle back in the general direction from which the light originated, so that the article has a reflectivity of at least about 10 cd/(lux • m 2 ).
  • Preferred retroreflective articles have a reflectivity of about 100 cd/(lux • m 2 ) or more, and most preferably about 500 cd/(lux • m 2 ) or more.
  • Surface normal means an axis passing through a surface of interest and oriented perpendicular to such surface.

Landscapes

  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Illuminated Signs And Luminous Advertising (AREA)
  • Toys (AREA)
  • Optical Elements Other Than Lenses (AREA)
EP00936328A 2000-01-21 2000-05-26 Rückstrahlendes konfetti Withdrawn EP1248669A1 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US489653 1983-04-28
US48965300A 2000-01-21 2000-01-21
PCT/US2000/014525 WO2001052962A1 (en) 2000-01-21 2000-05-26 Retroreflective confetti

Publications (1)

Publication Number Publication Date
EP1248669A1 true EP1248669A1 (de) 2002-10-16

Family

ID=23944717

Family Applications (1)

Application Number Title Priority Date Filing Date
EP00936328A Withdrawn EP1248669A1 (de) 2000-01-21 2000-05-26 Rückstrahlendes konfetti

Country Status (8)

Country Link
EP (1) EP1248669A1 (de)
JP (1) JP2004500185A (de)
KR (1) KR20020071956A (de)
CN (1) CN1424933A (de)
AU (1) AU2000251654A1 (de)
CA (1) CA2396163A1 (de)
HK (1) HK1051009A1 (de)
WO (1) WO2001052962A1 (de)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE202014101365U1 (de) 2014-03-24 2014-03-31 Sabine Rother Bio-Konfetti

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7168815B2 (en) 2004-01-21 2007-01-30 3M Innovative Properties Company Retroreflective elements and articles
BRPI0506984B1 (pt) * 2004-01-21 2016-11-22 3M Innovative Properties Co marcação de pavimento, e, elemento retrorreflexivo
US7156528B2 (en) 2004-01-21 2007-01-02 3M Innovative Properties Company Retroreflective elements and articles
JP6854742B2 (ja) * 2017-10-31 2021-04-07 株式会社シマノ リフレクタ及び自転車を含む小型車両
CN114420015B (zh) * 2021-12-24 2024-02-09 合肥通用机械研究院有限公司 一种具备折叠收纳功能的移动展示系统

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US4149304A (en) 1977-09-12 1979-04-17 Brynjegard Olaf G Method of making rolls for forming radar reflective surfaces
US5056892A (en) 1985-11-21 1991-10-15 Minnesota Mining And Manufacturing Company Totally internally reflecting thin, flexible film
US5529527A (en) 1993-04-23 1996-06-25 Watkins; James O. Readily removable confetti cannons
US5582532A (en) * 1994-12-08 1996-12-10 Tucker; Sheridan G. Glitter toy
DE29510276U1 (de) 1995-06-24 1996-10-24 Hans-Friedrich Mayer GmbH, 42555 Velbert Konfetti-Packung
US5770124A (en) 1996-04-30 1998-06-23 Minnesota Mining And Manufacturing Company Method of making glittering cube-corner retroreflective sheeting
US5803791A (en) 1996-08-30 1998-09-08 Chiles; Daniel T. Launcher and pod combination, for dispensing miniature flyers at altitude
CA2312711C (en) 1997-12-16 2008-03-18 Reflexite Corporation Perforated retroreflective film
WO1999036477A1 (en) 1998-01-13 1999-07-22 Minnesota Mining And Manufacturing Company Visible mirror film glitter
EP1047732B1 (de) 1998-01-13 2002-09-11 Minnesota Mining And Manufacturing Company Glitzernde filmpartikel mit farbveränderung
US6096247A (en) * 1998-07-31 2000-08-01 3M Innovative Properties Company Embossed optical polymer films

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE202014101365U1 (de) 2014-03-24 2014-03-31 Sabine Rother Bio-Konfetti

Also Published As

Publication number Publication date
JP2004500185A (ja) 2004-01-08
AU2000251654A1 (en) 2001-07-31
CA2396163A1 (en) 2001-07-26
CN1424933A (zh) 2003-06-18
KR20020071956A (ko) 2002-09-13
HK1051009A1 (zh) 2003-07-18
WO2001052962A1 (en) 2001-07-26

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