EP1232301A1 - Flüssigkeitsundurchlässige, feuchtigkeitsdurchlässige teppichunterlage - Google Patents

Flüssigkeitsundurchlässige, feuchtigkeitsdurchlässige teppichunterlage

Info

Publication number
EP1232301A1
EP1232301A1 EP00972091A EP00972091A EP1232301A1 EP 1232301 A1 EP1232301 A1 EP 1232301A1 EP 00972091 A EP00972091 A EP 00972091A EP 00972091 A EP00972091 A EP 00972091A EP 1232301 A1 EP1232301 A1 EP 1232301A1
Authority
EP
European Patent Office
Prior art keywords
underlay
caφet
layer
film
moisture vapor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP00972091A
Other languages
English (en)
French (fr)
Inventor
Peter Michael Murphy
James Thomas Summers
Prentice Lee Huffines
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Invista Technologies Saerl
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of EP1232301A1 publication Critical patent/EP1232301A1/de
Withdrawn legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/12Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G27/00Floor fabrics; Fastenings therefor
    • A47G27/04Carpet fasteners; Carpet-expanding devices ; Laying carpeting; Tools therefor
    • A47G27/0437Laying carpeting, e.g. wall-to-wall carpeting
    • A47G27/0468Underlays; Undercarpets
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N7/00Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
    • D06N7/0063Floor covering on textile basis comprising a fibrous top layer being coated at the back with at least one polymer layer, e.g. carpets, rugs, synthetic turf
    • D06N7/0089Underlays
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0276Polyester fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2305/00Condition, form or state of the layers or laminate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/724Permeability to gases, adsorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/726Permeability to liquids, absorption
    • B32B2307/7265Non-permeable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/728Hydrophilic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/73Hydrophobic
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2471/00Floor coverings
    • B32B2471/02Carpets

Definitions

  • Water resistant carpet underlays provide a way to clean spills on carpet more thoroughly by helping to contain the spill above the padding or floor. If a spill is not removed from under the carpet, the spill will allow the growth of mold, mildew, and bacteria. Not only may the padding and wood flooring deteriorate as a result, but such conditions are conducive to the formation of odors and allergens. Spills on fitted or wall-to-wall carpeting are particularly insidious since detection and prevention of the seepage into the padding following a spill is typically impractical with large or fitted carpets. A spill on broadloom carpeting often puddles on the padding or flooring where it can not be removed by cleaning. This spill then accelerates the growth of mold, mildew and odors.
  • the prior art also describes water impermeable carpeting constructed using sheets of plastic, such as polyethylene and poly(ethylene/vinyl acetate), that are laminated to the carpet.
  • plastic such as polyethylene and poly(ethylene/vinyl acetate)
  • backings are expensive, create manufacturing difficulties, and prevent desirable breathability (air permeability) of the carpet. Thus the growth of mold and mildew are not prevented.
  • an improved underlay material could be fabricated that would maintain its water impermeability even when spills are absorbed by stamping on an absorbent material laid over the spill. It is also desirable that the underlay is air permeable so that moisture is not trapped beneath it leading to mold and mildew.
  • the present invention provides such an improved underlay having liquid impermeability while maintaining vapor breathability.
  • the present invention comprises a carpet underlay comprising a composite of a fibrous substrate having opposite first and second planar sides, and at least one film affixed to the first side of said substrate, said underlay impermeable to liquids and permeable to moisture vapor.
  • the present invention further comprises a carpet underlay comprising a composite of a fibrous substrate, an optional control layer affixed to said substrate, a tie layer affixed to said control layer or to said substrate, and a moisture vapor permeable film affixed to said tie layer, said underlay impermeable to liquids and differentially permeable to moisture vapor.
  • the present invention further comprises a tufted pile carpet comprising: a) a primary backing having a surface tufted with pile yarns and an underside to which a latex has been applied; b) an optional secondary backing having a surface and an underside, wherein the surface of the secondary backing is adhered to the underside of the primary backing; and c) an underlay of the present invention as described above adjacent to or affixed to the primary or secondary backing.
  • the present invention further comprises a carpet cushion of a material providing resiliency, support, or noise reduction having opposite first and second planar sides and having adjacent to or affixed to one of said sides an underlay of the present invention as described above.
  • the present invention further comprises a process for rendering a carpet or a carpet cushion impermeable to liquids and permeable to moisture vapor comprising placing adjacent to or affixing to an underside of said carpet or said carpet cushion an underlay of the present invention as described above.
  • the present invention comprises a carpet underlay comprising a composite of a fibrous substrate having opposite first and second planar sides, and at least one film affixed to the first side of said substrate, said underlay exhibiting impermeability to liquids and permeability to moisture vapor.
  • the film is formed from a polymeric material that is impermeable to liquids but through which water vapor can readily permeate.
  • Important attributes of the underlay or impermeable barrier for carpets provided by the present invention are (1) the ability to keep the underlying carpet pad and floor dry under a wide range of spills and cleaning techniques, and (2) the ability to prevent the retention of trapped moisture under the barrier by allowing it to evaporate promptly.
  • breathable liquid-impermeable underlay is used hereinafter to describe such composites comprising a fibrous substrate affixed to a film formed from a polymeric material that is impermeable to liquids but through which moisture vapor can readily permeate.
  • breathable denotes a moisture vapor transport rate of 100 g/m 2 /day or more, determined by Test Method 2 described below.
  • CRI located in Dalton GA, means any kind of material placed under carpet to provide resiliency, support, and noise reduction when walked upon (CRI 105
  • the invention provides a moisture vapor permeable, liquid impermeable composite comprising a fibrous substrate and at least one film.
  • the composite is a laminate or a coating product and is free of pinholes or pores.
  • pinholes means small holes inadvertently formed in the film, while pores means small holes formed intentionally to enhance porosity to air, moisture, vapor, or liquids.
  • the fibrous substrate component of the breathable liquid-impermeable underlay is any woven or non-woven fabric or web, and is preferably a light non- woven fabric, selected from the group consisting of polyester, polyolefin, polyamide, poly(trimethylene terephthalate) synthetic fibers, natural fibers, bicomponent fibers, cellulosic fibers, wool, cotton, acrylic, jute, and copolymers and blends thereof.
  • cellulosic is meant fibrous cellulose-based products made from wood or other plants.
  • Bicomponent fibers include fibers made of two polymers, blends of polymeric fibers with natural or synthetic fibers, and blends of natural and synthetic fibers.
  • Suitable nonwoven materials include spunbonded webs, scrims, carded webs, flashspun webs, or nonwoven sheets comprised of blends of polymer fibers. Preferred are underlays wherein the fibrous substrate is a polyester spun-laced nonwoven fabric.
  • nonwoven fabrics such as SONTARA, a spun- laced nonwoven fabric available from E. I. du Pont de Nemours and Company, Wilmington DE.
  • SONTARA is a spunlaced fabric formed by a hydroentangling process in which staple fibers are entangled through "hydraulic needling" to form a strong, fabric-like structure.
  • SONTARA consists of fibers and/or wood pulp entangled in predetermined, repeating patterns forming strong structures without binder and having tensile strength greater than one pound per inch of fabric width for each ounce per square yard (5.3 g per cm fabric width for each g/m 2 ).
  • the manufacture of SONTARA is described in US Patents 3,797,074 and 3,485,706.
  • the film component of the breathable liquid-impermeable underlay is any solid and void- and pore-free polymeric film through which water molecules may readily diffuse.
  • the film is impermeable to liquids, and permeable to moisture vapor. It is typically a thermoplastic or thermoset polymer material that can be coated or extruded or laminated. Suitable polymers include vulcanized silicone rubbers, silicone polymers, polyurethanes, polyether esters, polyether amides, polyurethane esters, polyurethane ethers, polyvinyl alcohol, and copolymers and blends thereof.
  • Particularly preferred are films of HYTREL, a butylene/poly(alkylene ether) phthalate copolymer available from E. I. du Pont de Nemours and Company, Wilmington DE.
  • film components wherein either (a) the film has a first layer and second layer, each of said layers being comprised of a different moisture vapor permeable polymer composition, or (b) the film has one hydrophilic layer and one hydrophobic layer.
  • films having a bicomponent structure are described in US Patent 4,725,481.
  • Use of a bicomponent film of a hydrophilic layer and a hydrophobic layer bonded together permits differential transfer of moisture vapor to prevent buildup of moisture. This is because the bicomponent film has a separation ratio for water vapor of at least about 1.2 as determined by ASTM E-96-66 (Procedure BW).
  • the separation ratio for water vapor is described by the ASTM method as the value of the water vapor transmission rate measured with the hydrophilic layer of the film next to the water surface divided by the value of the water vapor transmission rate of the film with the hydrophobic layer next to the water surface.
  • the film has a higher water vapor transmission rate when water vapor passes in the direction of the hydrophilic layer of film and then through the hydrophobic layer.
  • placement of the hydrophilic layer of film next to the floor or the padding results in a reduction of accumulation of moisture vapor between the underlay and the floor or padding due to the higher rate of transmission from the hydrophilic layer through the hydrophobic layer.
  • the water vapor transmission rates of the hydrophilic and hydrophobic layers can be regulated by the thickness of the layer and the chemical composition of the layer.
  • a second embodiment of the present invention comprises a breathable liquid-impermeable underlay comprising a composite of a fibrous substrate, an optional control layer affixed to said substrate, a tie layer affixed to said control layer or to said substrate, and a moisture vapor permeable film affixed to said tie layer, said underlay exhibiting impermeability to liquids and differential permeability to moisture vapor.
  • an optional control layer is positioned between the fibrous substrate and a tie layer. This control layer acts as a vapor control layer.
  • the optional control layer is a polymer capable of reducing the moisture vapor transmission rate of the composite.
  • the control layer is selected from the group consisting of polyethylene, polypropylene or a copolymer thereof.
  • a tie layer is present between the fibrous substrate or optional control layer and the moisture vapor impermeable film.
  • the tie layer functions to improve adhesion to the fibrous substrate.
  • the tie layer is capable of compatabilizing the fibrous substrate or control layer and the film layer and forms a strong bond with both. It also works in combination with the moisture vapor impermeable film to enable the composite to exhibit differential permeability.
  • the tie layer can also comprise further additives known in the art.
  • the tie layer is a copolymer of ethylene co-monomer units and vinyl acetate co-monomer units. Structure of such control layer, tie layer, and moisture vapor permeable layer are described in patent application, US Serial number
  • the composite of the second embodiment is capable of exhibiting differential permeability.
  • the moisture vapor transmission rate in one direction through the layers of the composite is greater than that in the opposite direction.
  • the moisture vapor transmission rate in the direction away from the film layer and tie layer and towards the fibrous substrate layer is greater than the moisture vapor transmission rate in the direction away from the substrate layer and towards the tie layer and film layer.
  • the moisture vapor transmission rate of each layer is primarily dependent upon the chemical composition of the layer and the thickness of the layer. These parameters can be adjusted to optimize performance.
  • the composites of the present invention are prepared by lamination or coating techniques.
  • the film is laminated to or coated on the fibrous substrate by any of various methods well known to those skilled in the art in an amount sufficient to provide liquid impermeability and a moisture vapor transport rate (MNTR) of at least 100 g/m 2 /day.
  • MNTR moisture vapor transport rate
  • Such methods include the use of adhesives (adhesive lamination), heat bonds (thermal lamination), pressure bonding, ultrasonic bonding, dynamic mechanical bonding, and extrusion coating, or any other suitable attachment means, or combinations of these attachment means.
  • Processes for the extrusion melt coating of a polymer resin onto non- woven or other substrates are well known.
  • the process generally involves the steps of heating the polymer to a temperature above its melting point, extruding it through a flat die onto a substrate which passes through the curtain of molten polymer, subjecting the coated substrate to pressure to effect adhesion, and then cooling.
  • the extrusion melt coating method is widely used since it allows economical production of a laminated structure in a one-step procedure.
  • formation of the laminate structure of the invention is effected by coextrusion of the respective layers onto the substrate, either by simultaneous coextrusion of the respective layers through independent orifices of a multi-orifice die, and thereafter uniting the still molten layers, or, preferably, by single-channel coextrusion in which molten streams of the respective polymers are first united within a channel leading to a die manifold, and thereafter extruded together from the die orifice under conditions of streamline flow without intermixing onto the substrate.
  • laminating techniques may also be used, for example by lamination of a preformed film layer and a preformed tie layer, or a preformed film layer, a preformed tie layer and a preformed control layer, either before or simultaneously with lamination thereof with the substrate, or by casting.
  • lamination techniques would involve thermal lamination of the respective layers on hot roll calendering equipment, wherein the temperature used to bond the layers to the substrate is sufficient to effect melting or softening of one or more layers, and with the application of sufficient pressure, the layers become bonded.
  • the process is an extrusion coating process wherein the tie layer is coextruded with said film layer, or, if the control layer is included, wherein the control layer, the tie layer, and the film layer are coextruded together.
  • Minimum film thickness can be less than 1 mil (25 ⁇ m).
  • the moisture vapor permeable film is substantially free of pinholes or pores. Extrusion coating a thin layer of the film onto the fibrous substrate is a preferred manufacturing technique.
  • the breathable liquid-impermeable underlays of this invention are used alone, underneath but not attached to an overlying carpet, underneath and attached to an overlying ca ⁇ et, underneath an overlying carpet and attached to padding, or any combination thereof.
  • the breathable liquid-impermeable underlays of the present invention show improved liquid impermeability, especially impermeability to liquids under pressure, such liquids as water, hot and cold beverages, oils, detergent solutions, and alcohols.
  • liquids under pressure such liquids as water, hot and cold beverages, oils, detergent solutions, and alcohols.
  • a film of HYTREL laminated to a SONTARA non- woven fabric provides better liquid impermeability than SONTARA treated with a water repellant while maintaining a high moisture vapor transport rate.
  • the fibrous substrate provides the strength and dimensional stability at a lower cost than an equal strength film of the HYTREL alone, which provides the liquid impermeability.
  • the breathable liquid-impermeable underlay is laid with the film layer on top or underneath, and preferably with the film on top.
  • the breathable liquid-impermeable underlay is laid under the ca ⁇ et either unattached to the ca ⁇ et, or affixed to the ca ⁇ et or affixed to the padding by any conventional method that does not involve puncturing the underlay.
  • the present invention further comprises a tufted pile ca ⁇ et comprising: a) a primary backing having a surface tufted with pile yarn and an underside to which a latex has been applied; b) an optional secondary backing having a surface and an underside, wherein the surface of the secondary backing is adhered to the underside of the primary backing; and c) an underlay of the present invention as previously described.
  • An underlay of the present invention described above is laid below, or optionally affixed to, the underside of the ca ⁇ et by an adhesive applied to the upper side of the underlay.
  • the underlay is treated with adhesive on both sides to attach it to both the underside of the ca ⁇ et and the padding.
  • Such attachment prevents movement of the underlay as the ca ⁇ et is laid, and also prevents any movement due to traffic after the installation is complete, but liquid impermeability of the barrier does not require attachment.
  • the present invention further comprises a ca ⁇ et cushion of a material providing resiliency, support, or noise reduction having opposite first and second planar sides and having adjacent to or affixed to one side an underlay of the present invention as described above.
  • the present invention further comprises a process for rendering ca ⁇ et or ca ⁇ et cushion impermeable to liquids and permeable to moisture vapor comprising placing adjacent to or affixing to a surface of said ca ⁇ et or cushion an underlay of the present invention as described above.
  • the underlay of the present invention is useful to provide an impermeable barrier between a ca ⁇ et and ca ⁇ et cushion, between a ca ⁇ et and floor, or between a ca ⁇ et cushion and floor.
  • the underlay also prevents retention of any trapped moisture by allowing evaporation. This prevents damage to the ca ⁇ et cushion and floor and prevents the formation of mold and mildew.
  • a 5 -layer test stack was prepared as follows: (1) A sample of residential ca ⁇ eting with water permeable, latex was placed over (2) the underlay sample which was in turn placed on (3) a white absorbent paper towel placed over (4) rebond ca ⁇ et padding which was placed over (5) a wood particle board sheet.
  • the paper towels used were single-fold paper towels available from Kimberly-Clark, Dallas TX. Since the test requires no visible wetness of the towel, the choice of paper towel is not critical and other thin absorbent media, such as Whatman No.l Filter paper may be substituted. A colored aqueous solution may be used to aid visual detection. Then 100 ml of water, at a room temperature of 24 +/- 3°C (75+/- 5°F) was slowly poured onto the ca ⁇ et sample through a cylinder of about 8 cm diameter and from a height of about 1 meter to create a circular puddle. The cylinder was removed and the sample was left undisturbed for 20 minutes. For the 0 psi (0 kPa, i.e.
  • the ca ⁇ et and underlay were removed. If any water spot was visible on the towel (designated “wet” in the results), then the underlay was judged a failure to provide sufficient water impermeability to a water spill. If the paper towel between the padding and ca ⁇ et was dry (designated “dry” in the results), the underlay was judged acceptable and provided sufficient water impermeability to a water spill. Alternatively, the water was "blotted” from the ca ⁇ et pile with dry paper towels at a given pressure. After ten “blottings” with the given pressure, the ca ⁇ et and underlay were removed.
  • the underlay was judged a failure (or "wet") and did not provide sufficient water impermeability for a water spill followed by blotting at the given pressure. If the paper towel between the padding and ca ⁇ et was "dry", the underlay was judged to provide sufficient water impermeability for a water spill followed by blotting at the given pressure. Blotting pressures of 0, 3, 8, 16, and 33 psi (0, 21, 55, 110, and 227 kPa) were utilized. A blotting pressure of 33 psi or 228 kPa exceeds the pressure exerted by a typical homeowner standing on a paper towel to accelerate the blotting of a spill. After a "wet” or fail rating, tests at higher blotting pressures were not made (denoted by "X” in Table 1). The blotting pressures were created by placing weights on a circular disc as follows:
  • Moisture Vapor Transport Rate is measured in an "up cup” configuration, over a saturated head of water vapor according to the procedure described the American Society for Testing Materials (ASTM) Standard ASTM E96-92.
  • HYTREL 4778 was fed to a 1.5-inch (3.8 cm) diameter extruder connected to a melt combining block, heated to about 225°C, and extruded at 25 ⁇ m. The molten HYTREL 4778 then passed through a die connected to the combining block having a 35 inch (89 cm) wide die block heated to about 225°C. A film was formed exiting from the die that had a thickness of 1 mil (25 ⁇ m). The film exiting from the die was coated on a nonwoven lightweight scrim fabric of spun bonded polyethylene terephthalate (SONTARA 8000) as a substrate.
  • SONTARA 8000 nonwoven lightweight scrim fabric of spun bonded polyethylene terephthalate
  • the underlay was tested according to Test Methods 1 and 2 using the following ca ⁇ ets: 1) 28 oz/yd 2 (950g/m 2 ) Berber level loop polypropylene ca ⁇ et, 2) 42 oz/yd 2 (1425 g/m 2 ) nylon cut-pile ca ⁇ et, and 3) 65 oz/yd 2 (2200g/m 2 ) nylon cut- pile ca ⁇ et.
  • the results are shown in Table 1 as Examples 1, 2 and 3 respectively. Examples 4, 5, 6
  • HYTREL 8206 was fed to a 1.5 inch (3.8 cm) diameter extruder connected to a melt combining block.
  • HYTREL 4778 was fed to a 1 inch (2.5 cm) diameter extruder that was also connected to the same melt combining block.
  • the HYTREL 8206 was heated to about 225 °C and coextruded at 20 ⁇ m and the HYTREL 4778 was heated to about 225°C and coextruded at 10 ⁇ m to the melt combining block connected to the extruders.
  • the coextruded layers were combined in the melt block. The layers were then passed through a die connected to the combining block having a 35 inch (89 cm) wide die block heated to about 225 °C.
  • a bonded bicomponent film was formed exiting from the die that had a combined thickness of 1 mil (25 ⁇ m).
  • the HYTREL 8206 was 0.8 mil (20 ⁇ m) thick, and the HYTREL 4778 was 0.2 mil (5 ⁇ m) thick.
  • the bicomponent film exiting from the die was coated on a nonwoven lightweight scrim fabric of spun bonded polyethylene terephthalate (SONTARA 8000) as a substrate with the HYTREL 8206 layer next to the scrim fabric.
  • the underlay was tested according to Test Methods 1 and 2 using the following ca ⁇ ets: 1) 28 oz/yd 2 (950g/m 2 )
  • Example 1 except that the fabric substrate was SONTARA 8004.
  • the underlay was tested according to Test Methods 1 and 2 using the following ca ⁇ ets: 1) 28 oz/yd 2 (950g/m 2 ) Berber level loop polypropylene ca ⁇ et, 2) 42 oz/yd 2 (1425 g/m 2 ) nylon cut-pile ca ⁇ et, and 3) 65 oz/yd 2 (2200g/m 2 ) nylon cut-pile ca ⁇ et.
  • the results are shown in Table 1 as Examples 10, 11 and 12 respectively.
  • Example 16 KC MICROCOOL laminate nonwoven fabric (described in the footnotes to Table 1 below) was used as purchased as the underlay and tested according to
  • HYTREL G4778 a polyether-ester block copolymer, was dried and fed into an extrusion hopper.
  • the molten polymer was extruded at 20 ⁇ m.
  • the film formed from the die was deposited
  • HYTREL G4778 (a polyether-ester block copolymer) was dried and fed into an extrusion hopper.
  • the molten polymer was extruded at 20 ⁇ m.
  • the film formed from the die was deposited
  • HYTREL G4778 (a polyether-ester block copolymer) and BYNEL 50E631 (an anhydride-modified polypropylene resin) were dried and fed into an extrusion hopper at a weight ratio of 87% HYTREL and 13 % BYNEL.
  • Example 9 9 film formed from the die was deposited onto a 0.5 oz/yd (17 g/m ) spunbonded polypropylene (SBPP) nonwoven fabric between nip and casting rolls.
  • SBPP spunbonded polypropylene
  • the nip roll temperature was 80°C and the casting roll temperature was 40°C.
  • the nip roll pressure was 80 psi (550 kPa).
  • the film thickness was controlled by the coating line speed.
  • the line speed for the Example 22 sample was 42 feet per minute (12.8 meters per minute) which produced a 1.0 mil (25 ⁇ m) film thickness.
  • the Example 21 sample having a 0.8 mil (20 ⁇ m) film thickness was produced by a line speed of 60 feet per minute
  • SONTARA 8000 and 8004 are 1.2 and 1.6 oz/yd 2 (41 and 54 g/m 2 ), respectively, spunlaced nonwoven polyester fabric available from E. I. du Pont de Nemours and Company, Wilmington DE.
  • SONTARA 8827 is a 2 oz/yd 2 (68 g/m 2 ) spunlaced nonwoven fabric having a composition of 55%/45% weight percent wood pulp/polyester available from E. I. du Pont de Nemours and Company, Wilmington DE.
  • HDK is a 1 oz/yd 2 (34 g/m 2 ) polyester, powder bonded, non-woven fabric available from H.D.K. Industries Inc., Greenville SC.
  • HYTREL 4778 is a copolyether ester thermoplastic elastomer, having a melting point of 208°C, a vicat softening temperature of 175°C, a shore hardness of 47D, and a water abso ⁇ tion of 2.3%.
  • HYTREL 4778 available from E. I. du Pont de Nemours and Company, Wilmington DE.
  • HYTREL 8206 is a copolyether ester thermoplastic elastomer, having a melting point of 200°C, a vicat softening temperature of
  • HYTREL Blend is a Du Pont HYTREL film blend No. P 18-3892 available from Clopay Co ⁇ ., Cincinnati OH.
  • HYTREL CO-EX denotes an extrusion coating of first a layer of 80% by weight of HYTREL 8206 on the fabric followed by a 20% by weight of a second extrusion coating layer of HYTREL 4778.
  • TYVEK Home Wrap is a 1.8 oz/yd (61 g/m ) spunbond olefin nonwoven fabric available from by
  • W/H Housewrap is Weyerhaeuser CHOICE WRAP Housewrap manufactured by Weyerhaeuser, Tacoma WA.
  • O-C Housewrap is Owens-Corning PINKWRAP Housewrap manufactured by Owens-Corning, Toledo, OH.
  • the spunbonded polyester (SBPET), a nonwoven fabric with a basis weight of 0.9 oz/yd 2 (31 g/m 2 ), is available from American Non-wovens, Vernon, AL.
  • HYTREL G4778 is a thermoplastic polyester elastomer made of polyether-ester block copolymers manufactured by E. I. du Pont de Nemours and Company, Wilmington, DE.
  • BYNEL 50E631 is an anhydride-modified polypropylene resin manufactured by E. I. du Pont de Nemours and Company,
  • KC MICROCOOL is a laminate nonwoven fabric available from Kimberly-Clark, Irving, TX and believed to be a tri-layer structure with two outside layers of spunbonded polypropylene and a middle layer of microporous polypropylene film made by inco ⁇ oration of calcium carbonate in the polypropylene film followed by stretching in the machine direction to create the microporous film prior to thermal bonding lamination.
  • microporous the KC MICROCOOL fabric acts as a breathable liquid-impermeable underlay, passing the requirements of Test Methods 1 and 2, as shown in Table 1 for Example 16.
  • Example breathable liquid-impermeable underlays of the present invention provided liquid water impermeability even under the highest blotting pressures used while providing an adequate MVTR of greater than 100 g/m /day. Comparative examples failed the blotting test, or, in the case of impermeable thermoplastic films such as Comparative Example C, acted as an undesirable moisture vapor barrier.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)
  • Carpets (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
EP00972091A 1999-10-12 2000-10-12 Flüssigkeitsundurchlässige, feuchtigkeitsdurchlässige teppichunterlage Withdrawn EP1232301A1 (de)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US15878699P 1999-10-12 1999-10-12
US158786P 1999-10-12
US66947700A 2000-09-25 2000-09-25
US669477 2000-09-25
PCT/US2000/028150 WO2001027382A1 (en) 1999-10-12 2000-10-12 Liquid impermeable, moisture vapour permeable carpet underlay

Publications (1)

Publication Number Publication Date
EP1232301A1 true EP1232301A1 (de) 2002-08-21

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EP (1) EP1232301A1 (de)
JP (1) JP2003511156A (de)
AU (1) AU1080501A (de)
CA (1) CA2386038A1 (de)
WO (1) WO2001027382A1 (de)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7279058B2 (en) 2000-05-03 2007-10-09 L&P Property Management Company Composite carpet cushion and process
US6872445B2 (en) 2002-04-17 2005-03-29 Invista North America S.A.R.L. Durable, liquid impermeable and moisture vapor permeable carpet pad
US8273066B2 (en) 2003-07-18 2012-09-25 Kimberly-Clark Worldwide, Inc. Absorbent article with high quality ink jet image produced at line speed
CN101855076A (zh) 2007-11-09 2010-10-06 纳幕尔杜邦公司 离聚物及其制品
US20130029550A1 (en) * 2010-03-25 2013-01-31 Ibco Srl Breathable coated fabric
US10337141B2 (en) 2012-04-16 2019-07-02 Engineered Floors LLC Textile floor-covering with liquid blocking surface
WO2015057650A1 (en) 2013-10-14 2015-04-23 Invista Technologies S.À R.L. Breathable composite film

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5601910A (en) * 1995-04-18 1997-02-11 E. I. Du Pont De Nemours And Company Rug underlay substantially impervious to liquids
EP0927274A1 (de) * 1996-09-18 1999-07-07 E.I. Du Pont De Nemours And Company Flüssigkeitsundurchlässige teppichunterlage
DE19712671A1 (de) * 1997-03-26 1998-10-01 Hoelter Heinz Denaturierender Teppichboden gegen Hausstaubmilben, Keime und ähnliche Schadstoffe

Non-Patent Citations (1)

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Title
See references of WO0127382A1 *

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CA2386038A1 (en) 2001-04-19
AU1080501A (en) 2001-04-23
WO2001027382A1 (en) 2001-04-19
JP2003511156A (ja) 2003-03-25

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