EP1219142B1 - Systeme a haut rendement pour chauffer de l'aluminium pour le mettre en fusion - Google Patents

Systeme a haut rendement pour chauffer de l'aluminium pour le mettre en fusion Download PDF

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Publication number
EP1219142B1
EP1219142B1 EP99974023A EP99974023A EP1219142B1 EP 1219142 B1 EP1219142 B1 EP 1219142B1 EP 99974023 A EP99974023 A EP 99974023A EP 99974023 A EP99974023 A EP 99974023A EP 1219142 B1 EP1219142 B1 EP 1219142B1
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watts
heater
metal
heating
anyone
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EP1219142A4 (fr
EP1219142A1 (fr
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C. Edward Eckert
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Priority claimed from US08/995,191 external-priority patent/US5963580A/en
Priority claimed from US09/326,518 external-priority patent/US6069910A/en
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    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00—Ohmic-resistance heating
    • H05B3/0004—Devices wherein the heating current flows through the material to be heated
    • H05B3/0009—Devices wherein the heating current flows through the material to be heated the material to be heated being in motion
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00—Ohmic-resistance heating
    • H05B3/02—Details
    • H05B3/03—Electrodes
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00—Ohmic-resistance heating
    • H05B3/40—Heating elements having the shape of rods or tubes
    • H05B3/42—Heating elements having the shape of rods or tubes non-flexible
    • H05B3/48—Heating elements having the shape of rods or tubes non-flexible heating conductor embedded in insulating material
    • H—ELECTRICITY
    • H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
    • H05B3/00—Ohmic-resistance heating
    • H05B3/60—Heating arrangements wherein the heating current flows through granular powdered or fluid material, e.g. for salt-bath furnace, electrolytic heating

Definitions

  • This invention relates to aluminum and more particularly, it relates to heating and melting aluminum with very high efficiency and with remarkably low melt loss or skim generation.
  • Aluminum is melted either continuously, that is, continuous recirculation or in static furnaces using natural gas.
  • natural gas fired reverberatory continuous melting furnaces aluminum is recirculated using a molten metal pump, from the furnace, through a side bay or aluminum charging bay to a molten metal treatment bay and then back to the furnace.
  • Aluminum metal to be melted is submerged in the charging bay.
  • the skim or dross and other impurities resulting from the melting are removed in the melt treatment bay. Heat usually generated using natural gas is applied in the furnace.
  • metal treatment In static furnaces, aluminum metal is charged directly to the furnace or through an open charge bay. Metal treatment may be provided using a side bay.
  • This method of melting has the problem that it is very inefficient. That is, these furnaces operate at a 22-30% thermal efficiency because heat transfer to the melt in the furnace is effected by radiation from overhead natural gas burners to the melt. In this method of heating, large quantities of heated gases are lost as they are exhausted up the stack, creating environmental problems.
  • This method of heating has the disadvantage that the surface temperature of the melt increases dramatically, resulting in significant skim generation and in melt loss due to oxidation of the molten aluminum. The problem is aggravated as a layer of aluminum oxide or skim forms on the surface of the melt. That is, the layer of aluminum oxide formed on the surface operates as a thermal barrier or insulator to the natural gas fire flames impinging on the surface.
  • Aluminum oxide has a characteristically low thermal conductivity and therefore greatly inhibits heat transfer to the molten aluminum.
  • this method results in very high levels of melt loss due to the high surface temperature and conversion of aluminum to aluminum oxide. That is, melt loss is a significant problem encountered in this method of heating, generally averaging 2 to 5%.
  • the high levels of skim generated in melting requires intensive molten metal treatment downstream to remove entrained skim particles.
  • induction melting which can be either channel or coreless
  • coreless induction furnaces only have a thermal efficiency of about 60 to 70%, have to use a water cooled inductor surrounding the crucible and have to use a complex power supply to maintain a power factor of near unity for efficiency purposes.
  • the power supplies are large, involve a reactor and capacitor and also must use water cooling.
  • Induction heating also has the problem that it stirs or agitates the melt. This constantly exposes new surface to air which oxidizes the metal to form aluminum oxide. The oxides along with other impurities are mixed into the melting, resulting in serious metal quality problems. This requires intensive metal treatment with gases and/or salts downstream. This results in environmental problems from disposing of the salts. Also, it adds greatly to the expense of producing high quality metal.
  • the present invention provides such a heating and melting system.
  • a portable heat generating means such as a turbo alternator for electric power generation and utilization of exhaust heat to heat or condition solid charge to be melted.
  • a method and system of heating a body of molten aluminum for example, contained in a heating bay, the method comprising providing a body of molten aluminum; projecting an electric powered heater into the body of molten aluminum; passing electric current through the element and adding heat to the body of molten aluminum.
  • the heater is comprised of a sleeve suitable for immersing in the molten aluminum.
  • the sleeve may have a closed end and is comprised of a composite material comprised of an inner layer of metal such as titanium or titanium alloy having an outside surface having a refractory coating thereon exposed to the molten aluminum, the refractory coating being resistant to attack by the molten aluminum.
  • An electric heating element is located in the sleeve in heat transfer relationship therewith for adding heat to the molten aluminum.
  • FIG. 1 there is shown a schematic of a recirculating system for heating and/or melting metal such as aluminum.
  • a molten aluminum reservoir 200 is provided and molten aluminum is recirculated along line 202 to a pumping bay 204 which operates to pump molten metal from reservoir 200 and through subsequent steps.
  • Molten aluminum is removed from reservoir 200 along line 206 for casting, for example.
  • Any type of molten aluminum pump may be used which efficiently recirculates molten aluminum through the subsequent treatment stages.
  • Such pumps or impellers are disclosed in U.S. Patents 3,997,336 and 4,128,415, for example.
  • the molten aluminum is removed or conveyed along line 206 to heating bay or stage 208.
  • heat is added for purposes of melting solid aluminum charged in a subsequent bay.
  • the melt is heated to a temperature in the range of about 648.9 to 815.6°C (1200° to 1500°F) in heat bay 208.
  • Heating bay 208 is accomplished by either electric powered immersion heaters or by electric powered radiation heaters (described hereinafter) mounted close to the surface of the molten metal, e.g. 1.27 to 45.7 cm (1/2 to 18 inches) from the surface of the molten aluminum.
  • heating bay 208 is covered with an insulating cover to capture radiant heat and direct it towards the melt.
  • molten aluminum is then directed along line 210 to a charging bay 212 where aluminum metal is added for purposes of melting.
  • a charging bay 212 where aluminum metal is added for purposes of melting.
  • pumping and melting may be performed in the same bay.
  • the charge may be forcibly submerged along with fluxing salts by any suitable means to accelerate the melting process, such as disclosed in U.S. Patents 3,997,336; 4,128,415 and 4,286,985.
  • the melt is conveyed along line 214 to metal treatment bay 216 wherein the metal can be treated for purposes of removing impurities such as dissolved gases, e.g., hydrogen, fluxing salts, and undissolved solid particles such as metal oxides.
  • the metal treatment in bay 216 can comprise treatment with a fluxing gas to remove the impurities to the surface of the melt to form a skim layer which can be removed.
  • Fluxing may be achieved by any fluxing means, for example, using a uni-directional impeller but is preferably carried out by the process and apparatus using a bi-directional impeller disclosed in U.S. Patents 5,364,450; 5,462,580; 5,462,581; 5,616,167; and 5,630,863.
  • melt After the melt has been treated in metal treatment bay 216, it is recirculated back into molten metal reservoir 200 from where the molten metal is withdrawn along line 206, as needed.
  • natural gas flow rate 8.99x10 6 BTU / hr x 1MCF / 1,050,000 BTU x 1 / 0.26- 32.93 MCF natural gas
  • the savings using the process of the invention are about $2 million/month, taking melt loss into consideration. For some companies, this can be a savings of $100 million per year.
  • bay 208 is used for illustration purposes. That is, heat can be applied in line or channel 202 or in line or channel 206 utilizing the heating means of the present invention. Further, heat may be applied to the melt just prior to it being withdrawn from reservoir 200 at 202A. It will be appreciated that heat can be applied anywhere in reservoir 200; however, by applying heat at location 202A, hotter molten metal can be recirculated. Or, heat can be applied at several locations when the heat is supplied in accordance with the present invention.
  • the present invention has the advantage that it greatly reduces melt loss.
  • Melt loss is the amount of molten aluminum that is lost in the heating and/or melting process to the formation of aluminum oxide and the metallic aluminum that becomes entrained therein.
  • This combination is often referred to as skim or dross and may have other materials such as fluxing salts entrained or entrapped therein.
  • the skim or dross requires intensive processing to recover free metallic aluminum therefrom and presents an environmental disposal problem because of the salt content.
  • the amount of aluminum lost to skim is quite large and is only one of the considerable detriments of the conventional melting and heating systems. Melt loss due to conventional heating and/or melting can be as high as 5%.
  • the heating system in accordance with the present invention employs high watt density immersion heaters capable of watt densities of 3.9 to 58.1 watts/cm 2 (25 to 375 watts/in 2 ) of heater surface for applying heat to the melt beneath the surface of the melt where substantially all the heat generated is applied to the melt with only minimal heat losses. That is, compared to conventional heating of 25% efficiency, the present invention results in a heating efficiency of greater than 90% and typically greater than 95% efficiency, with only minimal melt loss, typically 1 to 2%, depending to some extent on the heating and/or melting operation and cleanliness of the solid metal being melted.
  • FIG. 2 there is shown a schematic of an electric heater assembly 10 for use in the heating and/or melting system of the invention.
  • the electric heater assembly is comprised of a protective sleeve 12 and an electric heating element 14.
  • a lead 18 extends from electric heating element 14 and terminates in a plug 20 suitable for plugging into a power source.
  • a suitable element 14 is available from International Heat Exchange, Inc., Yorba Linda, CA 92687 under the designation Maxi-Zone, or Ogden Manufacturing Co., Arlington Heights, IL 60005.
  • protective sleeve 12 is comprised of titanium tube 30 having an end 32 which preferably is closed. While the protective sleeve is illustrated as a tube, it will be appreciated that any configuration that protects or envelops electric heating element 14 may be employed. Thus, reference to tube or sleeve herein is meant to include such configurations.
  • a refractory coating 34 is employed which is resistant to attack by the environment in which the electric heater assembly is used. A bond coating may be employed between the refractory coating 34 and titanium tube 30. Electric heating element 14 is seated or secured in tube 30 by any convenient means.
  • electric heating element 14 is encapsulated in a metal tube 15, e.g., steel or Inconel tube, which is then inserted into tube 30 to provide an interference or friction fit.
  • a metal tube 15 e.g., steel or Inconel tube
  • electric heating element 14 when it utilizes a metal tube 15, has the outside surface of tube 15 in contact with the inside surface of tube 30 to promote heat transfer through tube 30 into the molten metal.
  • air gaps between the surface of metal tube 15 of electric heating element 14 and inside surface of tube 30 should be minimized.
  • tube 10 may be fabricated from any metal or metalloid material suitable for contacting molten metal and which material is resistant to dissolution or has controlled dissolution or erosion by the molten metal.
  • Other materials that may be used to fabricate tube 30 include niobium, chromium, molybdenum, combinations of NiFe (364 NiFe) and NiTiC (40 Ni 60TiC), particularly when such materials have low thermal expansion, all referred to herein as metals.
  • Tube 30 Other metals suitable for tube 30 include: 400 series stainless steel including 410, 416 and 422 stainless steel; Greek ascoloy; precipitation hardness stainless steels, e.g., 15-7 PH, 174-PH and AM350; Inconel; nickel based alloys, e.g., Unitemp 1753; Kovar, Invar, Super Nivar, Elinvar, Fernico, Fernichrome; metal having composition 30-68 wt.% Ni, 0.02-0.2 wt.% Si, 0.01-0.4 wt.% Mn, 48-60 wt.% Co, 9-10 wt.% Cr, the balance Fe.
  • the metal or metalloid be coated with a material such as a refractory resistant to attack by molten metal and suitable for use as a protective sleeve.
  • a material such as a refractory resistant to attack by molten metal and suitable for use as a protective sleeve.
  • cast iron tubes may be employed, for example, for molten aluminum without a protective refractory coating.
  • cast iron tubes have a dissolution rate in molten aluminum in the range of 0.0033 to 0.167 in 2 of area loss/in 2 of original area/hr. (0,0033 to 0,167 m 2 of area loss/m 2 of original area/hr).
  • the material or metal of construction for tube 30 may have a thermal conductivity of less than 51.9 W/m°C (30 BTU/ft hr °F), and less than 25.9 W/m°C (15 BTU/ft hr °F), with material having a thermal conductivity of less than 17.3 W/m°C (10 BTU/ft hr °F) being useful.
  • Another important feature of a desirable material for tube 30 is thermal expansion.
  • a suitable material should have a thermal expansion coefficient of less than 6.86 x 10 -5 mm/mm/°C (15 x 10 -6 in/in/°F), with a preferred thermal expansion coefficient being less than 4.57 x 10 -5 mm/mm/°C (10 x 10 -6 in/in/°F), and the most preferred being less than 3.43 x 10 -5 mm/mm/°C (7.5 x 10 -6 in/in/°F) and typically less than 2.28 x 10 -5 mm/mm/°C (5 x 10 -6 in/in/°F).
  • the material or metal useful in the present invention can have a controlled chilling power. Chilling power is defined as the product of heat capacity, thermal conductivity and density.
  • the metal in accordance with the invention may have a chilling power of less than 28391.3 W/m 2 . °C (5000 BTU/ft 2 hr °F), preferably less than 11356.5 W/m 2 .°C (2000 BTU/ft 2 hr °F), and typically in the range of 567.8 to 4258.7 W/m 2 .°C (100 to 750 BTU/ft 2 hr °F).
  • the preferred material for fabricating into tubes 30 is a titanium base material or alloy having a thermal conductivity of less than 51.9 W/m°C (30 BTU/ft hr °F), preferably less than 25.9 W/m°C (15 BTU/ft hr °F), and typically less than 17.3 W/m°C (10 BTU/ft hr°F), and having a thermal expansion coefficient less than 6.86 x 10 -5 mm/mm/°C (15 x 10 -6 in/in/°F), preferably less than 4.57 x 10 -5 mm/mm/°C (10 x 10 -6 in/in/°F), and typically less than 2.28 x 10 -5 mm/mm/°C (5 x 10 -6 in/in/°F).
  • the titanium material or alloy should have a chilling power as noted, and for titanium, the chilling power can be less than 2839.1 (500), and preferably less than 2271.3 (400), and typically in the range of 567.8 to 1703.5 W/m 2 .°C (100 to 300 BTU/ft 2 hr °F).
  • the titanium base alloy need not be coated to protect it from dissolution.
  • refractory-type coatings should be provided to protect against dissolution of the metal or metalloid tube by the molten metal.
  • the titanium alloy that should be used is one that preferably meets the thermal conductivity requirements, the chilling power and, more importantly, the thermal expansion coefficient noted herein. Further, typically, the titanium alloy should have a yield strength of 2.1 x 10 5 Pa (30 ksi) or greater at room temperature, preferably 4.8 x 10 5 Pa (70 ksi), and typical 6.9 x 10 5 Pa (100 ksi).
  • the titanium alloys included herein and useful in the present invention include CP (commercial purity) grade titanium, or alpha and beta titanium alloys or near alpha titanium alloys, or alpha-beta titanium alloys.
  • the alpha or near-alpha alloys can comprise, by wt.%, 2 to 9 Al, 0 to 12 Sn, 0 to 4 Mo, 0 to 6 Zr, 0 to 2 V and 0 to 2 Ta, and 2.5 max. each of Ni, Nb and Si, the remainder titanium and incidental elements and impurities.
  • Specific alpha and near-alpha titanium alloys contain, by wt.%, about:
  • the alpha-beta titanium alloys comprise, by wt.%, 2 to 10 Al, 0 to 5 Mo, 0 to 5 Sn, 0 to 5 Zr, 0 to 11 V, 0 to 5 Cr, 0 to 3 Fe, with 1 Cu max., 9 Mn max., 1 Si max., the remainder titanium, incidental elements and impurities.
  • Specific alpha-beta alloys contain, by wt.%, about:
  • the beta titanium alloys comprise, by wt.%, 0 to 14 V, 0 to 12 Cr, 0 to 4 Al, 0 to 12 Mo, 0 to 6 Zr and 0 to 3 Fe, the remainder titanium and impurities.
  • beta titanium alloys contain, by wt.%, about:
  • a refractory coating 34 is applied to the outside surface of tube 30.
  • the coating should be applied above the level to which the electric heater assembly is immersed in the molten metal.
  • the refractory coating can be any refractory material which provides the tube with a molten metal resistant coating.
  • the refractory coating can vary, depending on the molten metal.
  • titanium or titanium alloy readily forms titanium oxide, it is important in the present invention to avoid or minimize the formation of titanium oxide on the surface of titanium tube 30 to be coated with a refractory layer. That is, if oxygen permeates the refractory coating, it can form titanium oxide and eventually cause spalling of the refractory coating and failure of the heater.
  • a layer of titanium nitride is formed on the titanium surface.
  • the titanium nitride is substantially impermeable to oxygen and can be less than about 1 ⁇ m thick.
  • the titanium nitride layer can be formed by reacting the titanium surface with a source of nitrogen, such as ammonia, to provide the titanium nitride layer.
  • a refractory coating may comprise at least one of alumina, zirconia, yittria stabilized zirconia, magnesia, magnesium titanite, or mullite or a combination of alumina and titania. While the refractory coating can be used on the metal or metalloid comprising the tube, a bond coating can be applied between the base metal and the refractory coating. The bond coating can provide for adjustments between the thermal expansion coefficient of the base metal alloy, e.g., titanium, and the refractory coating when necessary.
  • the bond coating thus aids in minimizing cracking or spalling of the refractory coat when the tube is immersed in the molten metal or brought to operating temperature.
  • the bond coat can be advantageous in preventing cracking, particularly if there is a considerable difference between the thermal expansion of the metal or metalloid and the refractory.
  • Typical bond coatings comprise Cr-Ni-Al alloys and Cr-Ni alloys, with or without precious metals.
  • Bond coatings suitable in the present invention are available from Metco Inc., Cleveland, Ohio, under the designation 460 and 1465.
  • the refractory coating should have a thermal expansion that is plus or minus five times that of the base material.
  • the ratio of the coefficient of expansion of the base material can range from 5:1 to 1:5, preferably 1:3 to 1:1.5.
  • the bond coating aids in compensating for differences between the base material and the refractory coating.
  • the bond coating has a thickness of 2.54 to 127 ⁇ m (0.1 to 5 mils) with a typical thickness being about 12.7 ⁇ m (0.5 mil).
  • the bond coating can be applied by sputtering, plasma or flame spraying, chemical vapor deposition, spraying, dipping or mechanical bonding by rolling, for example.
  • the refractory coating is applied.
  • the refractory coating may be applied by any technique that provides a uniform coating over the bond coating.
  • the refractory coating can be applied by aerosol, sputtering, plasma or flame spraying, for example.
  • the refractory coating has a thickness in the range of 7.62 to 1066.8 ⁇ m (0.3 to 42 mils), preferably 127 to 381 ⁇ m (5 to 15 mils), with a suitable thickness being about 254 ⁇ m (10 mils).
  • the refractory coating may be used without a bond coating.
  • boron nitride may be applied as a thin coating on top of the refractory coating.
  • the boron nitride may be applied as a dry coating, or a dispersion of boron nitride and water may be formed and the dispersion applied as a spray.
  • the boron nitride coating is not normally more than about 50.8 or 76.2 ⁇ m (2 or 3 mils), and typically it is less than 50.8 ⁇ m (2 mils).
  • the heater assembly of the invention can operate at watt densities of 3.9 to 38.8 watts/cm 2 (25 to 250 watts/in 2 ) and typically 6.2 to 27.1 watts/cm 2 (40 to 175 watts/in 2 ).
  • the heater assembly for use in the heating and melting system has the advantage of a metallic-composite sheath for strength and improved thermal conductivity.
  • the strength is important because it provides resistance to mechanical abuse and permits an ultimate contact with the internal element.
  • intimate contact between heating element metal tube 15 and sheath I.D. provides for substantial elimination of an annular air gap between heating element and sheath.
  • the annular air gap resulted in radiation heat transfer and also back radiation to the element from inside the sheath wall which limits maximum heat flux.
  • the heater used in accordance with the invention employs an interference fit that results in essentially only conduction.
  • heating element tube 15 is not in intimate contact with the protection tube resulting in an annular air gas or space therebetween.
  • the element is operated at a temperature independent of the tube. Heat from the element is not efficiently removed or extracted by the tube, greatly limiting the efficiency of the heaters.
  • the element has to be operated below a certain fixed temperature to avoid overheating the element, greatly limiting the heat flux.
  • the heater assembly very efficiently extracts heat from the heating element and is capable of operating close to molten metal, e.g., aluminum temperature.
  • the heater assembly is capable of operating at watt densities of 6.2 to 27.1 watts/cm 2 (40 to 175 watts/in 2 ).
  • the low coefficient of expansion of the composite sheath, which is lower than heating element tube 15, provides for intimate contact of the heating element with the composite sheath.
  • a contact medium such as a low melting point, low vapor pressure metal alloy may be placed in the heating element receptacle in the baffle.
  • the low melting metal alloy can comprise lead-bismuth eutectic having the characteristic low melting point, low vapor pressure and low oxidation and good heat transfer characteristics. Magnesium or bismuth may also be used.
  • the heater can be protected, if necessary, with a sheath of stainless steel; or a chromium plated surface can be used. After a molten metal contact medium is used, powdered carbon may be applied to the annular gap to minimize oxidation.
  • a powdered material 40 may be placed in the heating element receptacle.
  • the contact medium is a powdered material, it can be selected from silica carbide, magnesium oxide, carbon or graphite, for example.
  • the particle size should have a median particle size in the range from about 0.03 mm to about 0.3 mm or equivalent U.S. Standard sieve series. This range of particle size greatly improves the packing density of the powder and hence the heat transfer from electric element wire 42 (Fig. 3) to protective sleeve 12. For example, if mono-size material is used, this results in a one-third void fraction. The range of particle size reduces the void fraction below one-third significantly and improves heat transfer. Also, packing the range of particle size tightly improves heat transfer.
  • baffles When baffles are used, the shape of the opening, straightness and surface topography present in the baffle also determine the intimacy of fit between the heater and baffle material. Commercial refractory casting techniques do not always assure that the most desirable conditions (i.e., circular cross section, straightness, and smooth interior surface of the holes to provide a close fit diameter) for heat transfer are obtained.
  • tubes of machined graphite or carbon, or suitable metals, such as titanium, titanium alloys, Kovar, Invar, and Nilo may be used as inserts. Such inserts would be installed in the mold used to cast the baffle prior to introducing the refractory material to be cast.
  • the tubes not only function as cores to form the holes during casting, but to provide improved heat transfer by creating more optimum conditions.
  • Heating elements that are suitable for use in the present invention are available from Ogden Manufacturing Co., Arlington Heights, IL 60005, or International Heat Exchange Inc., Yorba Linda, CA 92687. These heating elements are often encased in steel or Inconel tubes and use ICA or nichrome elements.
  • thermocouple (not shown) may be inserted between sleeve 12 and heating element 14 or heating element wire 42.
  • the thermocouple may be used for purposes of control of the heating element to ensure against overheating of the element in the event that heat is not transferred away sufficiently fast from the heating assembly.
  • the thermocouple can be used for sensing the temperature of the molten metal. That is, sleeve 12 may extend below or beyond the end of the heating element to provide a space and the sensing tip of the thermocouple can be located in the space.
  • thermocouple placed in the heater senses the temperature of the heater element.
  • the thermocouple can be connected to a controller such as a cascade logic controller to integrate the heater element temperature into the control loop.
  • cascade logic controllers are available from Watlow Controls, Winona, Minnesota, designated Series 988.
  • Heating element wire or member 42 for employment in the present invention is preferably comprised of titanium or a titanium alloy.
  • the titanium or titanium alloy useful for heating element member 42 can be selected from the above list of titanium alloys. Titanium or titanium alloy is particularly suitable because of its high melting point which is 1725°C (3137°F) for high purity titanium. That is, a titanium element can be operated at a higher heater internal temperature compared to conventional elements, e.g., Nichrome which melts at 1454°C (2650°F). Thus, a titanium based element 42 can provide higher watt densities without melting the element. Further, electrical characteristics for titanium remain more constant at higher temperatures. Titanium or titanium alloy forms a titanium oxide coating or titania layer (a coherent oxide layer) which protects the heating element wire.
  • an oxidant material is added or provided within the sleeve of the heater assembly to provide a source of oxygen for purposes of forming or repairing the coherent titanium oxide layer.
  • the oxidant may be any material that forms or repairs the titanium oxide layer.
  • the source of oxygen can include manganese dioxide or potassium permanganate which may be added with the powdered contact medium.
  • the oxidant such as manganese dioxide or potassium permanganate
  • a powder contact medium to provide a source of oxygen for conventional heating wire such as ICA elements. This permits conventional heating elements to be sealed.
  • intimate contact or fit can be obtained by swaging metal tube 30 about or onto heating element 14.
  • element 14 is circular in cross section and, therefore, tube 30 can be swaged tightly onto element 14, thereby substantially eliminating air gaps.
  • Swaging includes the operation of working and partially reshaping metal tube 30, particularly the inside diameter, placing in compression, the tube contents, and more exactly fitting the outside diameter of element 14 to eliminate air gaps between element 14 and tube 30.
  • intermediate tubes may be placed between the heating element of the heater assembly and tube 30.
  • the invention contemplates the employment of a preferred heating element wire 42 (Fig. 3) surrounded by an electrical insulating material such as a powder which has good heat conduction, e.g., magnesium oxide, contained by tube 30 only without any intermediate tubes such as steel tubes.
  • Intimate contact and dense fill of the MgO powder is essential to proper heater operation; one means of providing improved fill density is to form a slurry comprising fluid or liquid vehicle, i.e., water or alcohol, and the dispersoid powder, i.e., MgO. Once a heater tube is filled with the slurry, entrapped air can be removed by vibration and/or vacuum.
  • fluid or liquid vehicle i.e., water or alcohol
  • a chemical binder may be employed that incorporates a chemical reaction to consume the vehicle, or progressive volitalization can be used to properly evaporate the vehicle.
  • Progressive volitalization is a process that heats the tube from the closed end towards the open end in a progressive manner. Suitable heating means include induction, radiation and microwave/radio frequency. The heating means is moved from the closed to open end of the tube, thus assuring vapor phase vehicle to freely pass through the remaining liquid slurry.
  • the contact medium can be a powdered material located between the heating element and the tube.
  • the powdered material can be selected from silicon carbide, magnesium oxide and carbon or graphite if the heating element is contained in an intermediate tube. If no intermediate tube is used, the contact medium must provide electrical insulation as well as good heat conduction.
  • the powdered material should have a median particle size ranging from about 0.03 to 0.3 mm.
  • the powdered material has the effect of filling any voids between the heating element and the tube.
  • the range of size for the powdered material improves heat conduction by minimizing void fraction. Swaging is very beneficial with the powdered material because the swaging effectively packs the powder tighter for improved heat conduction.
  • the inside of tube 30 may be treated to provide a roughening effect or controlled RMS for improved packing of powder against the inside wall of tube 30. That is, having a range of particle size and a roughened inside wall provides a higher level of contact by said powdered contact medium and therefore a greater level of heat conduction to the wall. In addition, providing the element with a roughened surface improves heat conduction to the powdered contact medium. If an intermediate metal tube, e.g., a steel tube, is used, then it is also important to provide it with a roughened surface for heat transfer.
  • an intermediate metal tube e.g., a steel tube
  • Another contact medium that may be used includes high temperature pastes such as anti-seize compounds having a nickel or copper base.
  • the molten aluminum reservoir can be provided with an inert gas atmosphere (inert to aluminum).
  • the surface of molten aluminum exposed to the atmosphere can be minimized by design of the lid or top of the molten metal reservoir because there is now no need for a large surface area to be contacted with impinging gas fired flames. That is, the molten reservoir can be designed on a volumetric basis rather than a surface area heated by overhead burners.
  • Efficiency of heating the heating and/or melting system in accordance with the invention can use novel electric power generation means including turbine engines coupled to an electric power generator.
  • Economic fuel sources can be selected for the turbine for power generation and scrap to be melted, e.g., beverage container scrap, can be delaquered and preheated using exhaust gases from the turbine which can have temperatures in the range of 426.7 to 537.8°C (800° to 1000°F).
  • oily milling chips can be pretreated with turbine exhaust gases to remove impurities prior to melting.
  • the turbine generator provides a source of power which is portable. That is, because of the high efficiency of this melting system, smaller molten metal reservoirs can be utilized, greatly improving efficiency and economics of the heating and/or melting process.

Landscapes

  • Manufacture And Refinement Of Metals (AREA)

Claims (21)

  1. Procédé de chauffage ou de fusion de l'aluminium solide caractérisé en ce qu'il comprend les étapes consistant à :
    (a) faire circuler de l'aluminium en fusion à partir d'un réservoir au travers d'un compartiment de pompage, d'un compartiment de chauffage et d'un compartiment de charge de l'aluminium vers ledit réservoir ; et
    (b) chauffer ledit aluminium en fusion dans ledit compartiment de chauffage avec un chauffage électrique dans lequel ledit chauffage fonctionne à une densité en watt comprise dans la plage de 3,9 à 58,1 watts/cm2 (25 à 375 watts/in2) et dans lequel ledit chauffage comprend :
    (i) un manchon convenable pour l'immersion dans ledit aluminium en fusion, le manchon étant composé d'un métal ou d'un matériau composite constitué d'une couche interne de métal ayant un coefficient de dilatation thermique inférieur à 4,57x10-5 mm/mm/°C (10x10-6 in/in/°F) et ayant une surface externe ayant un revêtement résistant sur celle-ci exposée audit aluminium en fusion, ledit revêtement résistant étant résistant à l'attaque dudit aluminium en fusion et ayant un coefficient de dilatation thermique inférieur à 4,57x10-5 mm/mm/°C(10x10-6 in/in/°F) ; et
    (ii) un élément de chauffage électrique situé dans ledit manchon en relation de transfert de chaleur avec celui-ci pour ajouter de la chaleur audit aluminium en fusion.
  2. Procédé selon la revendication 1, dans lequel le chauffage électrique fonctionne à une densité en watt de 3,9 à 54,3 watts/cm2 (25 à 350 watts/in2).
  3. Procédé selon la revendication 1 ou 2, dans lequel le chauffage électrique fonctionne à une densité en watt de 7,8 à 38,8 watts/cm2 (50 à 250 watts/in2).
  4. Procédé selon l'une quelconque des revendications précédentes dans lequel ledit chauffage fonctionne à une densité en watt de 7,8 à 31,0 watts/cm2 (50 à 200 watts/in2).
  5. Procédé selon l'une quelconque des revendications précédentes, dans lequel ledit chauffage fonctionne à une densité en watt de 11,6 à 23,25 watts/cm2 (75 à 150 watts/in2).
  6. Procédé selon la revendication 1 ou 2, dans lequel ledit chauffage fonctionne à une densité en watt de 3,9 à 38,8 watts/cm2 (25 à 250 watts/in2).
  7. Procédé selon la revendication 6, dans lequel ledit chauffage fonctionne à une densité en watt de 4,7 à 31,0 watts/cm2 (30 à 200 watts/in2).
  8. Procédé selon la revendication 7, dans lequel ledit chauffage fonctionne à une densité en watt de 6,2 à 27,1 watts/cm2 (40 à 175 watts/in2) .
  9. Procédé selon la revendication 8, dans lequel ledit chauffage fonctionne à une densité en watt de 6,2 à 23,3 watts/cm2 (40 à 150 watts/in2).
  10. Procédé selon l'une quelconque des revendications précédentes, comprenant un compartiment de traitement de l'aluminium en fusion situé après ledit compartiment de charge de l'aluminium dans lequel ledit aluminium en fusion est traité pour retirer les impuretés de celui-ci.
  11. Procédé selon la revendication 10, dans lequel ledit aluminium en fusion est fondu dans ledit traitement dans le but de retirer lesdites impuretés.
  12. Procédé selon l'une quelconque des revendications précédentes, dans lequel l'aluminium en fusion dans ledit compartiment de chauffage est chauffé à une température dans la plage de 551,7 à 1010,0 °C (1025 à 1850 °F).
  13. Procédé selon l'une quelconque des revendications précédentes, dans lequel ladite couche interne de métal est le titane.
  14. Procédé selon l'une quelconque des revendications précédentes, dans lequel ledit métal est un alliage à base de titane choisi dans le groupe constitué d'alliages de titane, alpha, bêta, quasi-alpha et alpha-bêta.
  15. Procédé selon la revendication 14, dans lequel ledit métal est un alliage à base de titane sélectionné parmi le groupe constitué d'un grade 6242, 1100 et CP.
  16. Procédé selon l'une quelconque des revendications 1 à 12, dans lequel ladite couche interne de métal est choisie à partir d'aciers inoxydables non austénitiques, "Invar" et "Kovar".
  17. Procédé selon l'une quelconque des revendications précédentes, dans lequel le recouvrement résistant est choisi dans le groupe constitué de l'un de Al2O3, ZrO2, Y2O3, ZrO2 stabilisé, et Al2O3-TiO2.
  18. Procédé selon l'une quelconque des revendications précédentes, dans lequel le revêtement résistant a une couche de nitrure de bore par dessus.
  19. Procédé selon l'une quelconque des revendications précédentes, dans lequel un revêtement liant est fourni entre la couche de métal et le revêtement résistant.
  20. Procédé selon la revendication 19, dans lequel le revêtement liant comprend un alliage choisi dans le groupe constitué d'un alliage Cr-Ni-Al et d'un alliage Cr-Ni.
  21. Procédé selon l'une quelconque des revendications précédentes, dans lequel à la fois ladite couche interne et ladite couche résistante ont des coefficients d'expansion inférieurs à 2,28x10-5 mm/mm/°C (5x10-6 in/in/°F).
EP99974023A 1997-12-22 1999-09-14 Systeme a haut rendement pour chauffer de l'aluminium pour le mettre en fusion Expired - Lifetime EP1219142B1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/995,191 US5963580A (en) 1997-12-22 1997-12-22 High efficiency system for melting molten aluminum
US09/326,518 US6069910A (en) 1997-12-22 1999-06-04 High efficiency system for melting molten aluminum
PCT/US1999/021216 WO2001020950A1 (fr) 1997-12-22 1999-09-14 Systeme a haut rendement pour chauffer de l'aluminium pour le mettre en fusion

Publications (3)

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EP1219142A1 EP1219142A1 (fr) 2002-07-03
EP1219142A4 EP1219142A4 (fr) 2003-02-12
EP1219142B1 true EP1219142B1 (fr) 2005-04-06

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CN115291579B (zh) * 2022-09-30 2022-12-23 南通启锦智能科技有限公司 一种孕育剂生产设备的自整定优化控制系统

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DE3600019A1 (de) * 1985-02-11 1986-08-14 Scantherm A/S, Fredrikstad Verfahren zum zufuehren von waermeenergie zu einer metallschmelze und dabei verwendbares heizelement
FR2699038B1 (fr) * 1992-12-08 1995-02-24 Electricite De France Canne thermoplongeante pour le chauffage électrique de produits fusibles et son application notamment à l'aluminium.
US5603571A (en) * 1993-08-18 1997-02-18 Eckert; C. Edward Thermocouple assembly including an outer sleeve made in part of a titanium alloy
US5850073A (en) * 1997-02-18 1998-12-15 Eckert; C. Edward Electric heating element and heater assembly
US5850072A (en) * 1997-02-18 1998-12-15 Eckert; C. Edward Electric heater assembly
US5894541A (en) * 1997-02-18 1999-04-13 Eckert; C. Edward Electric heater assembly

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WO2001020950A1 (fr) 2001-03-22
EP1219142A4 (fr) 2003-02-12
EP1219142A1 (fr) 2002-07-03

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