EP1198422A1 - Procede de traitement d'eaux usees d'une station d'epuration biologique - Google Patents
Procede de traitement d'eaux usees d'une station d'epuration biologiqueInfo
- Publication number
- EP1198422A1 EP1198422A1 EP00969376A EP00969376A EP1198422A1 EP 1198422 A1 EP1198422 A1 EP 1198422A1 EP 00969376 A EP00969376 A EP 00969376A EP 00969376 A EP00969376 A EP 00969376A EP 1198422 A1 EP1198422 A1 EP 1198422A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- setpoint
- oxygen
- sewage
- wastewater
- content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
- C02F3/302—Nitrification and denitrification treatment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/006—Regulation methods for biological treatment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/14—NH3-N
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2209/00—Controlling or monitoring parameters in water treatment
- C02F2209/22—O2
Definitions
- the invention relates to a method for treating wastewater from a biological sewage treatment plant, comprising a first treatment stage in which an oxygen-containing gas is supplied to the wastewater in a controlled manner as a function of a predetermined ⁇ 2 setpoint for the oxygen content in the wastewater, ammonium compounds contained in the wastewater being below Formation of nitrates are oxidized, and a second treatment stage in which the nitrates are removed from the waste water with the formation of gaseous nitrogen.
- Oxygen is required for nitrification; specifically, 4.6 g 0 2 are required for the conversion of 1 g of NH 4 + ions. Oxygen is artificially added to the activated sludge to accelerate the process.
- the oxygen content can be kept at a predetermined 0 2 setpoint and an adequate oxygen supply to the microorganisms can be guaranteed.
- the level of the 0 2 setpoint depends on a large number of parameters, such as the type and extent of the dirt load to be expected, and can differ from wastewater treatment plant to wastewater treatment plant.
- the oxygen content is usually kept at a 0 2 setpoint of approximately 2 mg / l (mg per liter of waste water).
- the known method is very well suited for the elimination of nitrogen and it is characterized by high operational reliability.
- Technical oxygen is usually used to supply the microorganisms with oxygen during the first treatment stage. This results in a significant part of the operating costs in the known treatment method.
- the invention is therefore based on the object of reducing the oxygen requirement for wastewater purification and thus reducing the operating costs while maintaining a high level of operational reliability.
- this object is achieved according to the invention by continuously measuring the ammonium content or a property of the waste water which can be correlated therewith, and by specifying the 0 2 setpoint as a function of the measured ammonium content.
- the method according to the invention comprises a first and a second
- the first control mechanism regulates the supply of oxygen to the wastewater as a function of a predetermined O 2 setpoint.
- the controlled variable is therefore the oxygen content in the wastewater.
- the 0 2 setpoint for the oxygen content in the waste water is regulated depending on the ammonium content in the waste water.
- the controlled variable is the 0 2 setpoint. In the method according to the invention, this is therefore not a constant variable, but rather a variable which is predetermined by the ammonium content measured in the wastewater and is accordingly used in the first control mechanism.
- the oxygen input into the wastewater can be adapted to the current need for nitrification. It has been shown that the rate of nitrification depends on the oxygen content of the waste water. Therefore, especially in low load times, for example during the night, the oxygen content in the wastewater can be easily reduced, with the proviso that the reduction takes place as a function of the ammonium content of the wastewater.
- the O 2 setpoint is therefore not set constantly - as in the known method - but is set variably. This makes it possible to reduce the oxygen consumption for wastewater treatment without any noticeable impairment of the cleaning effect and accordingly to lower the operating costs.
- the O 2 setpoint is specified depending on the ammonium content. To determine the ammonium content, this is either measured directly in the wastewater, or a property of the wastewater that can be correlated with the ammonium content is measured. In the latter case, the corresponding correlatable property of the waste water can also be used as the control variable for the 0 2 setpoint instead of the ammonium content.
- the measurement can be carried out continuously or according to time intervals.
- the wastewater to be treated passes through the first and second treatment stages at least once. It can also go through the treatment stages several times, for example in a circuit.
- a lower limit of 0.5 mg / 1 is preferably specified for setting the O 2 setpoint. This specification serves to ensure the operational safety of the process, since the oxygen culture below this lower limit could impair the culture of the aerobic microorganisms and the effectiveness of wastewater treatment.
- a value of 3 mg / 1 is preferably specified as the upper limit for the 0 setpoint.
- the location of the measurement of the ammonium content or the property correlated therewith has an influence on the measured value and thus on the control behavior of the above-mentioned control mechanisms. For example, a measurement in the area before the first treatment stage - that is, before nitrification - will provide a different measured value for the ammonium content than a measurement in the area after the first or after the second treatment stage.
- a measurement in the area before the first treatment stage - that is, before nitrification - will provide a different measured value for the ammonium content than a measurement in the area after the first or after the second treatment stage.
- the ammonium content measured in this way is preferably kept at a nominal NH value in the range between 0.2 and 2.0 mg / l. If there is a deviation from the NH setpoint, the 0 2 setpoint is varied accordingly.
- Figure 1 shows an embodiment of the method according to the invention in a schematic representation
- Figure 2 is a measurement and control scheme for performing the method according to the invention.
- FIG. 1 shows schematically a number of basins (1-4) of a sewage treatment plant, as are usually used for the microbial treatment of organically polluted municipal and industrial wastewater. It is a pre-clarifier
- SPARE BLADE (RULE 26) 1, a denitrification tank 2, the actual activation tank 3 and one
- Secondary clarifier 4 The inflow of the wastewater to be treated to the primary clarifier 1 is with the arrow 5 and the drain from the aeration tank 3 into the secondary clarifier
- two so-called gassing mats 8 are mounted on the pool floor, via which technically pure oxygen is introduced into the waste water.
- the gassing mats 8 are connected via an oxygen supply line 9 to an oxygen tank (not shown in FIG. 1).
- the oxygen supply to the gassing mats 8 is controlled by means of a measuring and control device 10 as a function of a predetermined setpoint for the oxygen content in the wastewater of the activation tank 3.
- an oxygen measuring probe 11 is immersed in the activated sludge.
- the measured values determined by the oxygen measuring probe 11 are fed to the control device 10 via the line 12.
- the ammonium content of the waste water is measured in the discharge 6 from the aeration tank 3 to the secondary clarifier 4.
- an NH measuring device 13 is provided, which is also connected to the control device 10 via a line 14.
- Submersible agitators 15 are provided in the denitrification basin 2 and in the aeration basin 3, which prevent activated sludge from settling.
- the wastewater to be treated passes from the primary clarifier 1 and denitrification tank 2 into the activation tank 3, where the so-called nitrification takes place, in which ammonium compounds contained in the sewage water or in the activated sludge of the activation tank 3 are oxidized to nitrates by microorganisms.
- technical oxygen is introduced into the activated sludge via the gassing mats 8.
- the oxygen content of the activated sludge is continuously measured by means of the oxygen measuring probe 11 and by means of the control device 10 using a
- SPARE BLADE (RULE 26) first control mechanism kept at a predetermined 0 2 setpoint.
- the specification of the 0 2 setpoint lies in the range between 0.5 mg / 1 and 3 mg / 1.
- the specification of the O 2 setpoint results from a second control mechanism, which is based on a measurement of the ammonium content in the wastewater.
- the ammonium content is continuously measured in the area of the drain 6 and the measured values are fed to the control device 10.
- the NH 4 setpoint for the ammonium content in the region of the discharge 6 is 1.0 mg / l (liter, based on waste water).
- the 0 2 setpoint is lowered by means of the control device 10 as soon as the ammonium content falls below the preset NH setpoint and increases as soon as the ammonium content is above the preset NH 4 setpoint.
- Aeration tank 4 and the associated withdrawal of the setpoint during low load periods oxygen savings of up to 30% can be achieved.
- the control device 10 comprises a controller for the setting of the ammonium content in the outlet 6 of the aeration tank 3 (referred to as “NH controller”), an adjuster for the setting of the 0 2 content in the activation tank 3 (as the “O 2 setpoint value” Controller ”) and a controller for setting the 0 2 setpoint (referred to as” 0 2 setpoint controller ").
- SPARE BLADE Values for the setpoint of the ammonium concentration in sequence 6 (referred to as “NH 4 setpoint”) and an upper and a lower limit for the O 2 setpoint are specified and stored in the control device 10.
- the limit values for the O 2 - In the exemplary embodiment, the setpoint is 0.5 mg / l or 3 mg / l, and the NH setpoint is set to 1 mg / l.
- the oxygen content of the waste water 4 (hereinafter referred to as “actual value of O 2 ”) is measured at regular intervals by means of the oxygen measurement probe 11.
- the ammonium content of the waste water is also measured continuously determined in sequence 6 by means of the NH measuring device (hereinafter referred to as “NH actual value”) as soon as this.
- the actual NH 4 value is fed to the control device 10 and compared with the target value by means of a processor.
- the 0 2 setpoint for the oxygen control is reset, provided the 0 2 setpoint to be set is within the specified limit values.
- This new setting of the 0 2 setpoint takes place in the ⁇ 2 setpoint adjuster.
- the newly set O 2 setpoint is then used as the basis for the usual regulation of the oxygen content in the aeration tank by means of the 0 2 controller, ie in the event of a discrepancy between the actual O 2 value measured by means of the oxygen measuring probe 11 and the newly set 0 2 setpoint ( ⁇ O 2 # 0) the oxygen input via the gassing mats 8 is set accordingly.
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Biodiversity & Conservation Biology (AREA)
- Microbiology (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
Abstract
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19948197 | 1999-10-07 | ||
DE1999148197 DE19948197A1 (de) | 1999-10-07 | 1999-10-07 | Verfahren zur Behandlung von Abwasser einer biologischen Kläranlage |
PCT/EP2000/009623 WO2001025158A1 (fr) | 1999-10-07 | 2000-09-30 | Procede de traitement d'eaux usees d'une station d'epuration biologique |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1198422A1 true EP1198422A1 (fr) | 2002-04-24 |
Family
ID=7924737
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP00969376A Withdrawn EP1198422A1 (fr) | 1999-10-07 | 2000-09-30 | Procede de traitement d'eaux usees d'une station d'epuration biologique |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP1198422A1 (fr) |
DE (1) | DE19948197A1 (fr) |
WO (1) | WO2001025158A1 (fr) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1425483A4 (fr) | 2001-06-06 | 2008-12-03 | Univ Virginia | Solides cellulaires periodiques multifonctionnels et procede de fabrication desdits solides |
FR2871153B1 (fr) * | 2004-06-02 | 2006-08-11 | Otv Sa | Procede de traitement d'eaux a l'aide d'un reacteur biologique, dans lequel la vitesse d'air injecte dans le reacteur est regulee, et dispositif correspondant |
WO2012058102A1 (fr) | 2010-10-27 | 2012-05-03 | Miller Chemical & Fertilizer Corporation | Formulation d'engrais soluble à base de calcium |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4537682A (en) * | 1982-01-29 | 1985-08-27 | Environmental Research & Technology | Activated sludge wastewater treating process |
DE4024947A1 (de) * | 1990-08-07 | 1992-02-13 | Stewing Verwaltungsgesellschaf | Verfahren und klaeranlage zum reinigen von abwasser |
FR2685692B1 (fr) * | 1991-12-31 | 1997-03-28 | Omnium Traitement Valorisa | Procede d'epuration d'effluents industriels et/ou urbains du type boues activees. |
FR2753191B1 (fr) * | 1996-09-10 | 1998-11-06 | Degremont | Procede d'epuration de la pollution carbonee et de denitrification en milieu oxygene des eaux usees |
-
1999
- 1999-10-07 DE DE1999148197 patent/DE19948197A1/de not_active Withdrawn
-
2000
- 2000-09-30 EP EP00969376A patent/EP1198422A1/fr not_active Withdrawn
- 2000-09-30 WO PCT/EP2000/009623 patent/WO2001025158A1/fr not_active Application Discontinuation
Non-Patent Citations (1)
Title |
---|
See references of WO0125158A1 * |
Also Published As
Publication number | Publication date |
---|---|
DE19948197A1 (de) | 2001-05-31 |
WO2001025158A1 (fr) | 2001-04-12 |
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Effective date: 20020805 |
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RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: STADT NEUSTADT AN DER WEINSTRASSE Owner name: MESSER GRIESHEIM GMBH |
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RAP1 | Party data changed (applicant data changed or rights of an application transferred) |
Owner name: STADT NEUSTADT AN DER WEINSTRASSE Owner name: AIR LIQUIDE DEUTSCHLAND GMBH |
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STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
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18D | Application deemed to be withdrawn |
Effective date: 20060331 |