EP1178106B1 - Utilisation de produits de nettoyage aqueux concentrés comme renforçateurs de détergence pour le nettoyage de carreaux de grès-cérame fin - Google Patents

Utilisation de produits de nettoyage aqueux concentrés comme renforçateurs de détergence pour le nettoyage de carreaux de grès-cérame fin Download PDF

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Publication number
EP1178106B1
EP1178106B1 EP01117825A EP01117825A EP1178106B1 EP 1178106 B1 EP1178106 B1 EP 1178106B1 EP 01117825 A EP01117825 A EP 01117825A EP 01117825 A EP01117825 A EP 01117825A EP 1178106 B1 EP1178106 B1 EP 1178106B1
Authority
EP
European Patent Office
Prior art keywords
cleaning
weight
trial product
anionic
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP01117825A
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German (de)
English (en)
Other versions
EP1178106A1 (fr
Inventor
Felix Dr. Müller
Jörg Peggau
Helen Armstrong
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Evonik Operations GmbH
Original Assignee
TH Goldschmidt AG
Goldschmidt GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by TH Goldschmidt AG, Goldschmidt GmbH filed Critical TH Goldschmidt AG
Publication of EP1178106A1 publication Critical patent/EP1178106A1/fr
Application granted granted Critical
Publication of EP1178106B1 publication Critical patent/EP1178106B1/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/65—Mixtures of anionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/86—Mixtures of anionic, cationic, and non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/14—Hard surfaces
    • C11D2111/24—Mineral surfaces, e.g. stones, frescoes, plasters, walls or concretes

Definitions

  • the invention relates to the use of aqueous cleaning agent concentrates based on non-ionic, anionic, amphoteric surfactants, optionally with the use of customary auxiliaries and additives, which is characterized in that they contain alkoxylated amine compounds as cleaning enhancers for cleaning porcelain stoneware tiles.
  • stoneware stands for hard-fired tiles, which can be glazed or unglazed with or without a fired ceramic surface coating. According to the DIN standard, there is a subdivision based on water absorption capacity and type of production. DIN EN 176 defines stoneware and porcelain stoneware tiles.
  • the displacement space (V) according to DIN 51 130 is specified for profiled slabs and tiles.
  • Tiles and slabs are generally considered to be easy to clean and easy to clean. This applies without restriction to flat, smooth and hard substrates of R classes 9 to 11. However, with increasing R class the surfaces become increasingly rougher. Rough surfaces of class R 12 and in particular profiled tiles of classes R 12 to 13 and V 8 to 10, so-called porcelain stoneware tiles, are problematic.
  • the cleaning effort increases considerably with increasing roughness / unevenness of the surface, especially if due to porosity there is additional surface enlargement.
  • GB-A-2 334 723 describes cleaning agents for glass and smooth, bright, shiny surfaces, consisting of one or more ethoxylated quaternary ammonium compounds, at least one glycol ether and / or C 1-22 alcohol and at least one anionic surfactant.
  • the cleaning agent should not leave any stains or streaks after cleaning and should have antimicrobial and antistatic properties.
  • cleaning agents for manual and machine cleaning are generally complex mixtures of anionic, nonionic and amphoteric / zwitterionic surfactants, which contain common auxiliaries and additives such as alkalis, complexing agents, solubilizers, chlorine bleach additive and optionally mild abrasives. They are used in concentrations of approx. 0.5 to 10% by weight.
  • the object of the present invention was therefore to overcome these disadvantages of the known commercially available cleaning agents overcome and to provide improved cleaning agents that ensure reliable cleaning of rough and profiled tiles, so-called porcelain stoneware, at the same or reduced application concentrations.
  • the aqueous cleaning agent concentrates according to the present invention contain, based on the total mixture, water in the range from approximately 45 to approximately 95 parts by weight, preferably approximately 70 to approximately 90 parts by weight. In the application, they can be diluted with additional water to the desired or customary or required application concentration of approximately 0.5 part by weight to approximately 10 parts by weight.
  • Suitable fatty acids are in particular coconut fatty acid, palm fatty acid, tallow fatty acid, which have a chain distribution of approximately 6 to approximately 20, mainly approximately 8 to approximately 18, carbon atoms and can be both saturated and unsaturated.
  • the double bonds can be hydrogenated in whole or in part by the known processes, so that the iodine numbers are in the range from approximately 0 to approximately 50, in particular in the range from approximately 15 to approximately 40.
  • Suitable alkoxylating agents are ethylene oxide, propylene oxide or butylene oxide alone or as copolymers with both statistical and blockwise distribution.
  • ethoxylated compounds with a degree of alkoxylation of about 5 to 10 are particularly preferred.
  • These compounds are cleaning formulations consisting of mixtures of one or more surfactants from the group of anionic, nonionic, amphoteric compounds and, if appropriate, customary auxiliaries and additives such as alkalis, complexing agents, solubilizers, addition of chlorine bleach and mild abrasives in amounts of approximately 0.1 to 5, in particular 0.5 to 3 parts by weight are added.
  • the cationic cleaning boosters in the presence of anionic compounds do not tend to form insoluble complexes and to precipitate out.
  • the surface-active compounds which can also be used according to the invention are the anionic, non-ionic, amphoteric / zwitterionic surfactants customary in this field for the production of cleaning agents for household and industry.
  • the compounds can be used individually or as mixtures and are, for example, anionic, nonionic and amphoteric surfactants such as alkali, ammonium or magnesium alkyl sulfates or alkyl ether sulfates, secondary alkane sulfonates, alkali ⁇ -olefin sulfonates, sulfosuccinates, acyl isethionates, sarcosides, taurides, alkyl polyglucosides , Ether citrates, carboxylates, ether carboxylates, alkyl amide ether sulfates, and ethoxylates of fatty alcohols, glycerides, oils, fatty acids but also fatty acid esters, amine oxides, alkyl betaines, alkyl amido betaines, propionates, glycinates, acetates and sulfobetaines and sodium, potassium or triethanolamine soap.
  • Trial product D (base D) Wt .-% TEGOTENS EC 11 (decyl ethoxylate, end-capped) 10 REWOPOL D 510 (sodium isoctyl sulfate) 9 Na stearate 1.2 TEGOTENS DO (decamine oxide) 4.35 triethanolamine 2.0 IDS (30%, sodium iminosuccinate) 0.9 water
  • Trial product E (base E) Wt .-% REWOPOL D 510 (sodium isooctyl sulfate) 4.8
  • REWOPOL SBDO 75 (diisooctyl sulfosuccinate) 0.9 Na phosphonate DTPMP 0.32 water
  • Typical usage dilutions of floor cleaners A 3.0% Especially for professional porcelain stoneware cleaning B 0.9% Normal household all-purpose floor cleaner C 0.9% Normal household all-purpose floor cleaner Base D 0.3% Highly concentrated floor cleaner Base E 1.2% Floor cleaner with base silk
  • the cleaning solution was diluted with tap water from the city of Essen (water hardness ⁇ 10) to the respective application concentration.
  • the pipette tip was used for the test (Rainin (2.5 ml) EPD 2) positioned 0.3 mm above the tile.
  • the porcelain stoneware tiles were first washed in the dishwasher at 70 ° C without surfactant.
  • the spreading area in length and width was determined using a slide gauge. Each solution was repeated at least five times to correct the error. The area of the drop is calculated using the formula for an ellipse.
  • Table 2a Stoneware surface A Basis cleaner D in 0.3% solution Wet area cm 2 Increase [%] Original basis 3.3 - + 1% trial product 1 26.1 797 + 1% trial product 2 18.2 558 + 2% trial product 1 16.2 495 + 2% trial product 2 12.2 402 + 2% trial product 3 9.6 291 + 2% trial product 4 7.8 236 + 2% trial product 5 16.9 512 + 2% trial product 6 7.5 228 + 2% trial product 7 7.1 215 + 2% trial product 8 16.3 494 + 2% trial product 9 8.0 242 + 2% trial product 10 7.6 230
  • test solution E contains only short-chain anionic surfactants, a weakness in the emulsifying behavior is known for such surfactant systems.
  • the emulsification behavior of weakly emulsifying, short-chain anionic surfactant solutions is greatly optimized by adding the cleaning boosters according to the invention. If the emulsion breaks, water will settle instead of the oil. This settling water does not affect the cleaning power or the dirt carrying capacity during cleaning.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Detergent Compositions (AREA)

Claims (5)

  1. Utilisation de concentrés de produits de nettoyage aqueux à base de tensioactifs non ioniques, anioniques et/ou amphotères, le cas échéant avec utilisation d'additifs et d'adjuvants courants, caractérisés en ce qu'ils contiennent des composés aminés alkoxylés de formule générale

            [R1, R2, R3, R4N]+ X-

    dans laquelle
    R1 = un radical alkyle à chaîne droite, le cas échéant ramifié, contenant le cas échéant des liaisons multiples, de 8 à 22 atomes de carbone
    R2 = -(CH2CHR5O)n-R6 avec R5 = H, -CH3, -C2H5; R6 = H, -CH3, -C2H5, -C3H7 ou -C4H9 et n = 1 à 25
    R3 = R1 ou R2
    R4 = -CH3 ou -C2H5 et
    X- = un radical anionique, en particulier, sulfate de méthyle, sulfate d'éthyle, phosphate, chlorure, bromure, iodure
    comme renforçateurs de détergence pour le nettoyage de carreaux de grès cérame fin.
  2. Utilisation de concentrés de produits de nettoyage aqueux selon la revendication 1, qui contiennent, rapporté au mélange total, à part de l'eau, pour l'essentiel:
    0,1 à 10 partie(s) en poids d'au moins un tensioactif anionique, le cas échéant
    0,0 à 20 partie(s) en poids d'au moins un tensioactif non ionique, le cas échéant
    0,0 à 10 partie(s) en poids d'au moins un tensioactif amphotère/zwitterionique et le cas échéant
    0,1 à 10 partie(s) en poids d'adjuvants et d'additifs courants, caractérisés en ce que les concentrés de produits de nettoyage contiennent 0,1 à 5 partie(s) en poids de composés aminés alkoxylés de formule générale


            [R1, R2, R3, R4N]+ X-

    dans laquelle
    R1 = un radical alkyle à chaîne droite, le cas échéant ramifié, contenant le cas échéant des liaisons multiples, de 8 à 22 atomes de carbone
    R2 = -(CH2CHR5O)n-R6 avec R5 = H, -CH3, -C2H5; R6 = H, -CH3, -C2H5, -C3H7 ou -C4H9 et n = 1 à 25
    R3 = R1 ou R2
    R4 = -CH3 ou -C2H5 et
    X- = un radical anionique, en particulier, sulfate de méthyle, sulfate d'éthyle, phosphate, chlorure, bromure, iodure
    comme renforçateurs de détergence pour le nettoyage de carreaux de grès cérame fin.
  3. Utilisation de concentrés de produits de nettoyage aqueux selon la revendication 1, caractérisés en ce qu'ils contiennent, comme renforçateurs de détergence, des composés aminés alkoxylés quaternaires de formule générale [R1, R2, R3, R4N]+ X-
    dans laquelle
    R1 = un radical alkyle à chaîne droite, contenant des liaisons multiples, de 12 à 18 atomes de carbone
    R2, R3= -(CH2CHR5O)n-R6 avec R5 = H; R6 = H, et la somme de tous les n = 5-20
    R4 = -CH3 et
    X- = sulfate de méthyle, sulfate d'éthyle, chlorure.
  4. Utilisation de concentrés de produits de nettoyage aqueux selon la revendication 3, caractérisés en ce qu'ils contiennent, comme renforçateurs de détergence, des composés aminés alkoxylés quaternaires de formule générale [R1, R2, R3, R4N]+ X-, dans laquelle R1 = les radicaux d'acide gras de coco, acide gras de palme, acide gras de suif.
  5. Utilisation de concentrés de produits de nettoyage aqueux selon la revendication 1, caractérisés en ce qu'ils contiennent, comme renforçateurs de détergence, le méthosulfate de pentaéthoxy-méthylammonium de coco et/ou l'éthosulfate d'éthyl-bis-(polyéthoxyéthanol)-ammonium de suif.
EP01117825A 2000-08-04 2001-07-21 Utilisation de produits de nettoyage aqueux concentrés comme renforçateurs de détergence pour le nettoyage de carreaux de grès-cérame fin Expired - Lifetime EP1178106B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10038198 2000-08-04
DE10038198A DE10038198A1 (de) 2000-08-04 2000-08-04 Wässrige Reinigungsmittelkonzentrate für raue, insbesondere profilierte Fliesen und Platten

Publications (2)

Publication Number Publication Date
EP1178106A1 EP1178106A1 (fr) 2002-02-06
EP1178106B1 true EP1178106B1 (fr) 2004-04-28

Family

ID=7651394

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EP01117825A Expired - Lifetime EP1178106B1 (fr) 2000-08-04 2001-07-21 Utilisation de produits de nettoyage aqueux concentrés comme renforçateurs de détergence pour le nettoyage de carreaux de grès-cérame fin

Country Status (7)

Country Link
US (1) US6544350B2 (fr)
EP (1) EP1178106B1 (fr)
JP (1) JP2002097491A (fr)
AT (1) ATE265515T1 (fr)
CA (1) CA2352865A1 (fr)
DE (2) DE10038198A1 (fr)
ES (1) ES2220633T3 (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004036067A1 (de) * 2004-07-24 2006-02-16 Goldschmidt Gmbh Wässrige Reinigungsmittelkonzentrate für raue, insbesondere profilierte Fliesen und Platten
US7332463B2 (en) * 2005-04-22 2008-02-19 On Legal Grounds, Inc. Colloidal cleaning system comprising a saponified fatty acid and an anionic/nonionic surfactant mixture
DE102009001748A1 (de) 2009-03-23 2010-09-30 Evonik Goldschmidt Gmbh Formulierungen enthaltend Sorbitancarbonsäureester
DE102014207386A1 (de) * 2014-04-17 2015-10-22 Evonik Degussa Gmbh Tensidzusammensetzungen und hoch ölhaltige Formulierungen enthaltend diese
US9920284B2 (en) 2015-04-22 2018-03-20 S. C. Johnson & Son, Inc. Cleaning composition with a polypropdxylated 2-(trialkylammonio)ethanol ionic liquid
FR3047488B1 (fr) * 2016-02-05 2020-02-28 Laboratoires Anios Compositions detergentes pour le nettoyage dans l'industrie cosmetique et pharmaceutique.
EP3532584A1 (fr) 2016-10-26 2019-09-04 S.C. Johnson & Son, Inc. Composition de nettoyage désinfectante comprenant un liquide ionique d'amines quaternaires
EP3532585B1 (fr) 2016-10-26 2022-06-01 S.C. Johnson & Son, Inc. Composition désinfectante de nettoyage comprenant un sel hydroxycarboxylate d'ammonium quaternaire
EP3532586B1 (fr) 2016-10-26 2022-05-18 S.C. Johnson & Son, Inc. Composition de nettoyage désinfectante contenant un sel d'hydroxycarboxylate d'ammonium quaternaire

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4284435A (en) * 1979-11-28 1981-08-18 S. C. Johnson & Son, Inc. Method for spray cleaning painted surfaces
US6017874A (en) * 1995-09-29 2000-01-25 The Procter & Gamble Company Liquid laundry detergents containing selected quaternary ammonium compounds
GB2329901A (en) * 1997-09-30 1999-04-07 Reckitt & Colman Inc Acidic hard surface cleaning and disinfecting compositions
DE19800392C2 (de) * 1998-01-08 2002-10-02 Ecolab Gmbh & Co Ohg Reinigung harter Oberflächen mit rheopexen wäßrigen Reinigungsmitteln (II)
AU2105999A (en) * 1998-01-09 1999-07-26 Witco Corporation Novel quaternary ammonium compounds, compositions containing them, and uses thereof
GB9804022D0 (en) * 1998-02-26 1998-04-22 Reckitt & Colmann Prod Ltd Improvements in or relating to organic compounds
GB2336369B (en) * 1998-04-14 2002-06-19 Reckitt & Colman Inc Improvements in or relating to organic compositions
GB2336370B (en) * 1998-04-14 2002-09-04 Reckitt & Colman Inc Improvements in or relating to organic compositions
GB9817457D0 (en) * 1998-08-12 1998-10-07 Reckitt & Colman Inc Improvements in or related to organic compositions
GB9903478D0 (en) * 1999-02-17 1999-04-07 Reckitt & Colman Inc Improvements in or relating to organic compositions
US6465411B2 (en) * 2000-12-21 2002-10-15 Clariant International Ltd. Pine oil cleaning composition

Also Published As

Publication number Publication date
DE10038198A1 (de) 2002-02-21
ATE265515T1 (de) 2004-05-15
DE50102104D1 (de) 2004-06-03
US20020169093A1 (en) 2002-11-14
JP2002097491A (ja) 2002-04-02
EP1178106A1 (fr) 2002-02-06
ES2220633T3 (es) 2004-12-16
US6544350B2 (en) 2003-04-08
CA2352865A1 (fr) 2002-02-04

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