EP1161382B1 - Water soluble package - Google Patents

Water soluble package Download PDF

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Publication number
EP1161382B1
EP1161382B1 EP00912519A EP00912519A EP1161382B1 EP 1161382 B1 EP1161382 B1 EP 1161382B1 EP 00912519 A EP00912519 A EP 00912519A EP 00912519 A EP00912519 A EP 00912519A EP 1161382 B1 EP1161382 B1 EP 1161382B1
Authority
EP
European Patent Office
Prior art keywords
package
sheet
body portion
water soluble
package according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Revoked
Application number
EP00912519A
Other languages
German (de)
French (fr)
Other versions
EP1161382A1 (en
Inventor
David Brian Edwards
William John Mccarthy
Patricia Richardson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Unilever PLC
Unilever NV
Original Assignee
Unilever PLC
Unilever NV
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Filing date
Publication date
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Application filed by Unilever PLC, Unilever NV filed Critical Unilever PLC
Priority to EP03003920A priority Critical patent/EP1314654A3/en
Priority to EP03013108A priority patent/EP1361172B1/en
Publication of EP1161382A1 publication Critical patent/EP1161382A1/en
Application granted granted Critical
Publication of EP1161382B1 publication Critical patent/EP1161382B1/en
Anticipated expiration legal-status Critical
Revoked legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D75/00Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes, or webs of flexible sheet material, e.g. in folded wrappers
    • B65D75/28Articles or materials wholly enclosed in composite wrappers, i.e. wrappers formed by associating or interconnecting two or more sheets or blanks
    • B65D75/30Articles or materials enclosed between two opposed sheets or blanks having their margins united, e.g. by pressure-sensitive adhesive, crimping, heat-sealing, or welding
    • B65D75/32Articles or materials enclosed between two opposed sheets or blanks having their margins united, e.g. by pressure-sensitive adhesive, crimping, heat-sealing, or welding one or both sheets or blanks being recessed to accommodate contents
    • B65D75/36Articles or materials enclosed between two opposed sheets or blanks having their margins united, e.g. by pressure-sensitive adhesive, crimping, heat-sealing, or welding one or both sheets or blanks being recessed to accommodate contents one sheet or blank being recessed and the other formed of relatively stiff flat sheet material, e.g. blister packages, the recess or recesses being preformed
    • B65D75/366Articles or materials enclosed between two opposed sheets or blanks having their margins united, e.g. by pressure-sensitive adhesive, crimping, heat-sealing, or welding one or both sheets or blanks being recessed to accommodate contents one sheet or blank being recessed and the other formed of relatively stiff flat sheet material, e.g. blister packages, the recess or recesses being preformed and forming one compartment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D65/00Wrappers or flexible covers; Packaging materials of special type or form
    • B65D65/38Packaging materials of special type or form
    • B65D65/46Applications of disintegrable, dissolvable or edible materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D75/00Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes, or webs of flexible sheet material, e.g. in folded wrappers
    • B65D75/28Articles or materials wholly enclosed in composite wrappers, i.e. wrappers formed by associating or interconnecting two or more sheets or blanks
    • B65D75/30Articles or materials enclosed between two opposed sheets or blanks having their margins united, e.g. by pressure-sensitive adhesive, crimping, heat-sealing, or welding
    • B65D75/32Articles or materials enclosed between two opposed sheets or blanks having their margins united, e.g. by pressure-sensitive adhesive, crimping, heat-sealing, or welding one or both sheets or blanks being recessed to accommodate contents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/042Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
    • C11D17/043Liquid or thixotropic (gel) compositions

Definitions

  • the invention relates to a water soluble package containing a fluid substance for release on dissolution of the package.
  • Detergent compositions for the machine washing of laundry are provided in many forms.
  • Probably the most prevalent form of laundry detergent is washing powder or granules.
  • a problem with the use of these forms of detergent is that the product needs to be dosed into the machine in such a way that the detergent is quickly and thoroughly dissolved in the wash water of the machine without coming into contact with the laundry in a solid form.
  • many dosing devices which seek to overcome this problem have been proposed.
  • 0 343 070 and 0 343 069 teaches the use of a flexible fabric sock which holds the particulate detergent in the machine, the fabric of the sock being permeable to water so as to allow water enter the sock and carry the detergent out of the sock through the fabric walls in the form of an aqueous solution.
  • More recently unit dose forms of detergent have been proposed in the form of compressed tablets of detergent powder.
  • a problem encountered with the provision of detergent tablets is that the tablets need to be strong enough to withstand storage and transport, yet weak enough to disintegrate and dissolve quickly in the washing machine.
  • a further problem is the need to prevent the tablets "posting" in the porthole and between the drums of conventional washing machines.
  • a water soluble package containing a fluid substance for release on dissolution of the package, characterised in that the package has a body portion for containing the substance comprising a first sheet of a water soluble material thermoformed to form a body wall of the body portion, and a second sheet of water soluble material superposed on the first sheet and sealed thereto along a continuous region of the superposed sheets to form a base wall of the body portion, and in that the body portion of the package is generally dome shaped.
  • the invention yields water soluble packages which are sufficiently robust to withstand (to a commercially acceptable level) the rigours of packaging and transport even when the fluid substance inside the package is a domestic consumer product such as a laundry detergent.
  • the combination of thermoforming the packages of the invention and forming the packages into a dome shape confers surprising advantages on the packages of the invention. It is thought that thermoforming reduces stress on the film during forming compared to other forming techniques. As will be shown below, applicants have found that the dome is a shape which yields greater uniformity of film thickness over the package and greater impact resistance of the package.
  • the maximum height of the body wall above the base wall is preferably less than or equal to the maximum width of the base wall.
  • the base wall is preferably generally circular but other dome shaped body portions according to the invention are envisaged.
  • dome shapes having rectangular, oval, square and triangular bases are envisaged.
  • the base of the dome will be substantially flat.
  • the base may be somewhat concave or convex. In any case the resulting package is aysmmetrical about the base wall, although of course there can be one or more planes of symmetry perpendicular to the base wall.
  • the water soluble film is thermoformable and, in one embodiment of the invention, is polyvinyl alcohol, or a polyvinyl alcohol derivative.
  • the water soluble film of the base wall is the same material as that used to make the body wall. It is important that the body wall be thermoformed rather than cold formed because applicants have discovered that cold forming stresses the film and weakens the end package as a result.
  • the thermoformed body wall of a package according to the invention is of substantially uniform thickness.
  • substantially uniform it is meant that at any measured point the thickness of the thermoformed film is preferably less than about ⁇ 25%, even more preferably less than about ⁇ 20% and most preferably less than about ⁇ 15%, different from the original thickness of the film pre-thermoforming.
  • the film has a thickness of between 10 and 1000 microns. More preferably the film has a thickness of between 20 and 80 microns, most preferably between 40 and 60 microns.
  • an exterior surface of the film is treated with BITREXTM to discourage ingestion of the package of the invention by children.
  • the substance contained within the package may be a liquid, a gel or a paste. If the substance is a liquid then preferably the liquid has a viscosity between 100 and 1000 centipoise, more preferably between 300 and 800 centipoise, even more preferably between 500 and 700 centipoise, and most preferably about 600 centipoise, when measured at 20°C at 105s -1 . In a preferred embodiment of the invention the substance is present in an amount of between 10 and 500ml, preferably between 10 and 100ml, most preferably between 10 and 50ml. Suitably, the capsule contains between 20 and 30ml of a fluid composition.
  • the fluid composition is a laundry treatment agent such as a laundry detergent, fabric conditioner or fabric care formulation.
  • a laundry treatment agent such as a laundry detergent, fabric conditioner or fabric care formulation.
  • other compositions for domestic consumer use may be envisaged, such as disinfectants, personal care products, and the like.
  • the composition is substantially non-aqueous, however the composition may comprise some water, for example between about 1 and about 5% water
  • the invention also relates to a process for producing a package according to the invention, the process comprising the steps of:
  • the first sheet of water-soluble material is thermoformed by means of a heating plate.
  • the sheet of water-soluble material intimately contacts the heating plate, typically by applying a vacuum between the heating plate and the sheet of water-soluble material.
  • the vacuum applied will be of less than 0.6 Bar.
  • the sheet may be blown into contact with the heating plate.
  • the thermoforming sheet can be blown or sucked off the heating plate and into a suitable dome-shaped mould.
  • the process includes an additional step of, prior to the addition of the fluid substance, applying a vacuum to the thermoformed body wall to maintain the shape of the body portion at least until after the heat sealing step.
  • the invention also relates to a process for the machine washing of laundry by employing a package according to the invention, wherein the fluid substance contained within the package comprises a laundry treatment agent, the process comprising the steps of:
  • thermoforming process where a number of packages according to the invention are produced from two sheets of water soluble material.
  • recesses are formed in the sheet using a forming die having a plurality of cavities with dimensions corresponding generally to the dimensions of the packages to be produced.
  • a single heating plate is used for thermoforming the film for all the cavities, and in the same way a single sealing plate is described.
  • a first sheet of polyvinyl alcohol film is drawn over a forming die so that the film is placed over the plurality of forming cavities in the die.
  • Each cavity is generally dome shape having a round edge, the edges of the cavities further being radiussed to remove any sharp edges which might damage the film during the forming or sealing steps of the process.
  • Each cavity further includes a raised surrounding flange.
  • the film is delivered to the forming die in a crease free form and with minimum tension.
  • the film is heated to 100 to 120°C, preferably approximately 110°C, for up to 5 seconds, preferably approximately 700 micro seconds.
  • a heating plate is used to heat the film, which plate is positioned to superpose the forming die.
  • a vacuum of 0.5 bar is pulled through the pre-heating plate to ensure intimate contact between the film and the pre-heating plate, this intimate contact ensuring that the film is heated evenly and uniformly (the extent of the vacuum is dependant of the thermoforming conditions and the type of film used, however in the present context a vacuum of less than 0.6 bar was found to be suitable)
  • Non-uniform heating results in a formed package having weak spots.
  • thermoformed film is moulded into the cavities blowing the film off the heating plate and/or by sucking the film into the cavities thus forming a plurality of recesses in the film which, once formed, are retained in their thermoformed orientation by the application of a vacuum through the walls of the cavities. This vacuum is maintained at least until the packages are sealed.
  • the composition in this case a non-aqueous liquid detergent is added to each of the recesses.
  • a second sheet of polyvinyl alcohol film is then superposed on the first sheet across the filled recesses and heat-sealed thereto using a sealing plate.
  • the heat sealing plate which is generally flat, operates at a temperature of about 140 to 160°C, and contacts the films for 1 to 2 seconds and with a force of 8 to 30kg/cm 2 , preferably 10 to 20kg/cm 2 .
  • the raised flanges surrounding each cavity ensure that the films are sealed together along the flange to form a continuous seal.
  • the radiussed edge of each cavity is at least partly formed by a resiliently deformable material, such as for example silicone rubber. This results in reduced force being applied at the inner edge of the sealing flange to avoid heat/pressure damage to the film.
  • the packages formed are separated from the web of sheet film using cutting means. At this stage it is possible to release the vacuum on the die, and eject the formed packages from the forming die. In this way the packages are formed, filled and sealed while nesting in the forming die. In addition they may be cut while in the forming die as well.
  • the relative humidity of the atmosphere is controlled to ca. 50% humidity. This is done to maintain the heat sealing characteristics of the film.
  • the objective of this experimental work was to create thermoformed packages different shapes from the same material under the same conditions with the same depth of draw and approximately the same volume.
  • the formed packages were then tested for thickness at specific points using a micrometer. The results were then compared between shapes,
  • the rectangular shape shown is used only as an example to show the various points.
  • Points A & E are the same.
  • Points B, C and D are all equivalent in the dome shape and they were represented by Point F below.
  • the objective of this test was to show any differences, which exist, between the impact resistance of the dome shape and other shapes.
  • test specimen was placed on a hard surface immediately below the suspended dart. The dart was allowed to fall, striking the specimen centrally. The specimen was then examined and any rupture or leak recorded. If there was no rupture or leak, the specimen was subjected to successive impacts, each at a higher dart weight, until rupture did occur.
  • Dome, triangle (ie triangular pyramid) and cube shapes were tested.
  • Each package was formed from polyvinyl alcohol supplied by Chris Craft under reference CC8534.
  • the film thickness was 75 ⁇ m.
  • dome-shaped packages according to the invention containing a liquid laundry detergent, were placed randomly in a fibreboard box.
  • the box was made of "M-flute" material of dimensions 170 x 85 x 54 mm which had a total filled weight of 609g.
  • the box was sealed closed and subjected to a vertical drop of 1.2 m on to a hard flat surface on the short dimensions.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Composite Materials (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Packages (AREA)
  • Wrappers (AREA)
  • Detergent Compositions (AREA)
  • Laminated Bodies (AREA)
  • Bag Frames (AREA)

Description

The invention relates to a water soluble package containing a fluid substance for release on dissolution of the package.
Detergent compositions for the machine washing of laundry are provided in many forms. Probably the most prevalent form of laundry detergent is washing powder or granules. A problem with the use of these forms of detergent is that the product needs to be dosed into the machine in such a way that the detergent is quickly and thoroughly dissolved in the wash water of the machine without coming into contact with the laundry in a solid form. In this regard many dosing devices which seek to overcome this problem have been proposed. One such device disclosed in European Patent Nos. 0 343 070 and 0 343 069 teaches the use of a flexible fabric sock which holds the particulate detergent in the machine, the fabric of the sock being permeable to water so as to allow water enter the sock and carry the detergent out of the sock through the fabric walls in the form of an aqueous solution. More recently unit dose forms of detergent have been proposed in the form of compressed tablets of detergent powder. A problem encountered with the provision of detergent tablets is that the tablets need to be strong enough to withstand storage and transport, yet weak enough to disintegrate and dissolve quickly in the washing machine. A further problem is the need to prevent the tablets "posting" in the porthole and between the drums of conventional washing machines. More recently these problems have been addressed by the provision of detergent tablets having specific chemical disintegrants which allow quick disintegration of the tablets in the aqueous environment of a washing machine, and by the provision of loosely fitting net bags which aid tablet disintegration and prevent "posting". However, as many of the current detergent tablets contain bleach and other irritant substances, the problem of handling the tablets remains.
The provision of detergent compositions in water-soluble films has been known for some time. Most of the documents relating to this subject describe water soluble film envelopes formed using a vertical form-fill-seal (VFFS) route. A problem with envelopes produced using this VFFS method is that, due to the constraints of the process, the resultant envelopes have seals which incorporate defined weak points where the seals overlap at corners. This results in envelopes which are easily corrupted as a result of impacts suffered during transport. In an attempt to overcome the problems associated with such VFFS envelopes, European Patent Application No. 0 608 910 describes thermoformed water soluble packages for pesticidal compositions. While this specification attempts to provide a solution to the problem of weak seals, the packages of EP-A-0608910 have other weak points and are designed specifically for containing pesticidal compositions.
The packaging and transport of water soluble packages containing fluid substances subjects the formed packages to considerable impact forces. A particular problem is that when a number of such packages are loose packed in a larger container which is then transported, the impact forces suffered by the packages within the container can be severe. The difficulty is that in such a situation it only takes one package in the larger container to break for the whole product to be ruined as far as the consumer is concerned because the fluid contents of the broken package may leak over any unbroken packages. Consumer confidence in a product is likely to be badly damaged by such an occurrence.
The problem of minimising breakage to an acceptable level is particularly acute in the area of laundry detergents and other domestic consumer products and has not been solved until now..
It is an object of the invention to overcome at least some of the above disadvantages. It is a particular object of the invention to provide a water soluble package containing a fluid substance for release on dissolution of the package, which package has greater rupture resistance compared to known water-soluble packages.
STATEMENT OF INVENTION
According to the invention, there is provided a water soluble package containing a fluid substance for release on dissolution of the package, characterised in that the package has a body portion for containing the substance comprising a first sheet of a water soluble material thermoformed to form a body wall of the body portion, and a second sheet of water soluble material superposed on the first sheet and sealed thereto along a continuous region of the superposed sheets to form a base wall of the body portion, and in that the body portion of the package is generally dome shaped.
The applicants have surprisingly discovered that the above mentioned problems and disadvantages of prior art water soluble packages are substantially addressed by the packages according to the invention. In particular, the invention yields water soluble packages which are sufficiently robust to withstand (to a commercially acceptable level) the rigours of packaging and transport even when the fluid substance inside the package is a domestic consumer product such as a laundry detergent. The combination of thermoforming the packages of the invention and forming the packages into a dome shape confers surprising advantages on the packages of the invention. It is thought that thermoforming reduces stress on the film during forming compared to other forming techniques. As will be shown below, applicants have found that the dome is a shape which yields greater uniformity of film thickness over the package and greater impact resistance of the package.
In a preferred embodiment of the invention, the maximum height of the body wall above the base wall is preferably less than or equal to the maximum width of the base wall. The base wall is preferably generally circular but other dome shaped body portions according to the invention are envisaged. For example, dome shapes having rectangular, oval, square and triangular bases are envisaged.
Preferably, the base of the dome will be substantially flat. Alternatively, the base may be somewhat concave or convex. In any case the resulting package is aysmmetrical about the base wall, although of course there can be one or more planes of symmetry perpendicular to the base wall.
The water soluble film, at least of the body wall, is thermoformable and, in one embodiment of the invention, is polyvinyl alcohol, or a polyvinyl alcohol derivative. Preferably the water soluble film of the base wall is the same material as that used to make the body wall. It is important that the body wall be thermoformed rather than cold formed because applicants have discovered that cold forming stresses the film and weakens the end package as a result.
Preferably, the thermoformed body wall of a package according to the invention is of substantially uniform thickness. By "substantially uniform" it is meant that at any measured point the thickness of the thermoformed film is preferably less than about ±25%, even more preferably less than about ±20% and most preferably less than about ±15%, different from the original thickness of the film pre-thermoforming.
Preferably the film has a thickness of between 10 and 1000 microns. More preferably the film has a thickness of between 20 and 80 microns, most preferably between 40 and 60 microns.
In one embodiment of the invention, an exterior surface of the film is treated with BITREX™ to discourage ingestion of the package of the invention by children.
The substance contained within the package may be a liquid, a gel or a paste. If the substance is a liquid then preferably the liquid has a viscosity between 100 and 1000 centipoise, more preferably between 300 and 800 centipoise, even more preferably between 500 and 700 centipoise, and most preferably about 600 centipoise, when measured at 20°C at 105s-1. In a preferred embodiment of the invention the substance is present in an amount of between 10 and 500ml, preferably between 10 and 100ml, most preferably between 10 and 50ml. Suitably, the capsule contains between 20 and 30ml of a fluid composition. In a particularly preferred embodiment of the invention the fluid composition is a laundry treatment agent such as a laundry detergent, fabric conditioner or fabric care formulation. However, other compositions for domestic consumer use may be envisaged, such as disinfectants, personal care products, and the like. Preferably the composition is substantially non-aqueous, however the composition may comprise some water, for example between about 1 and about 5% water
The invention also relates to a process for producing a package according to the invention, the process comprising the steps of:
  • thermoforming a first sheet of a water soluble material to form a domed body wall of the body portion;
  • placing the fluid substance in the body portion;
  • superposing a second sheet of a water soluble material over the first sheet; and
  • heat sealing the first and second sheets along a continuous region of the superposed sheets surrounding the substance to form a base wall of the body portion.
In one preferred process the first sheet of water-soluble material is thermoformed by means of a heating plate. Preferably, the sheet of water-soluble material intimately contacts the heating plate, typically by applying a vacuum between the heating plate and the sheet of water-soluble material. Generally, the vacuum applied will be of less than 0.6 Bar. Alternatively the sheet may be blown into contact with the heating plate. The thermoforming sheet can be blown or sucked off the heating plate and into a suitable dome-shaped mould. In one aspect of the invention, the process includes an additional step of, prior to the addition of the fluid substance, applying a vacuum to the thermoformed body wall to maintain the shape of the body portion at least until after the heat sealing step.
The invention also relates to a process for the machine washing of laundry by employing a package according to the invention, wherein the fluid substance contained within the package comprises a laundry treatment agent, the process comprising the steps of:
  • placing at least one package into the machine along with the laundry to be washed; and
  • carrying out a washing operation.
Detailed Description of the Invention
The packages of the invention are illustrated with reference to the drawings in which:
  • Figures 1a, 1b, 1c and 1d show different views of a first package according to the invention in which the base wall of the body portion is circular.
  • Figures 2a, 2b, 2c and 2d show different views of a second package according to the invention in which the base wall of the body portion is square.
  • Figures 3a, 3b, 3c and 3d show different views of a third package according to the invention in which the base wall of the body portion is oval.
  • Figures 4a, 4b, 4c and 4d show different views of a fourth package according to the invention in which the base wall of the body portion is triangular.
  • Figures 5a, 5b, 5c and 5d show different views of a fifth package according to the invention in which the base wall of the body portion is rectangular.
  • EXAMPLE
    In this example a thermoforming process is described where a number of packages according to the invention are produced from two sheets of water soluble material. In this regard recesses are formed in the sheet using a forming die having a plurality of cavities with dimensions corresponding generally to the dimensions of the packages to be produced. Further, a single heating plate is used for thermoforming the film for all the cavities, and in the same way a single sealing plate is described.
    A first sheet of polyvinyl alcohol film is drawn over a forming die so that the film is placed over the plurality of forming cavities in the die. Each cavity is generally dome shape having a round edge, the edges of the cavities further being radiussed to remove any sharp edges which might damage the film during the forming or sealing steps of the process. Each cavity further includes a raised surrounding flange. In order to maximise package strength; the film is delivered to the forming die in a crease free form and with minimum tension. In the forming step, the film is heated to 100 to 120°C, preferably approximately 110°C, for up to 5 seconds, preferably approximately 700 micro seconds. A heating plate is used to heat the film, which plate is positioned to superpose the forming die. During this preheating step, a vacuum of 0.5 bar is pulled through the pre-heating plate to ensure intimate contact between the film and the pre-heating plate, this intimate contact ensuring that the film is heated evenly and uniformly (the extent of the vacuum is dependant of the thermoforming conditions and the type of film used, however in the present context a vacuum of less than 0.6 bar was found to be suitable) Non-uniform heating results in a formed package having weak spots. In addition to the vacuum, it is possible to blow air against the film to force it into intimate contact with the preheating plate.
    The thermoformed film is moulded into the cavities blowing the film off the heating plate and/or by sucking the film into the cavities thus forming a plurality of recesses in the film which, once formed, are retained in their thermoformed orientation by the application of a vacuum through the walls of the cavities. This vacuum is maintained at least until the packages are sealed. Once the recesses are formed and held in position by the vacuum, the composition, in this case a non-aqueous liquid detergent is added to each of the recesses. A second sheet of polyvinyl alcohol film is then superposed on the first sheet across the filled recesses and heat-sealed thereto using a sealing plate. In this case the heat sealing plate, which is generally flat, operates at a temperature of about 140 to 160°C, and contacts the films for 1 to 2 seconds and with a force of 8 to 30kg/cm2, preferably 10 to 20kg/cm2. The raised flanges surrounding each cavity ensure that the films are sealed together along the flange to form a continuous seal. The radiussed edge of each cavity is at least partly formed by a resiliently deformable material, such as for example silicone rubber. This results in reduced force being applied at the inner edge of the sealing flange to avoid heat/pressure damage to the film.
    Once sealed, the packages formed are separated from the web of sheet film using cutting means. At this stage it is possible to release the vacuum on the die, and eject the formed packages from the forming die. In this way the packages are formed, filled and sealed while nesting in the forming die. In addition they may be cut while in the forming die as well.
    During the forming, filling and sealing steps of the process, the relative humidity of the atmosphere is controlled to ca. 50% humidity. This is done to maintain the heat sealing characteristics of the film. When handling thinner films, it may be necessary to reduce the relative humidity to ensure that the films have a relatively low degree of plasticisation and are therefore stiffer and easier to handle.
    EXPERIMENTAL DETERMINATION OF OPTIMUM PACKAGE SHAPE i) Film Thinning During Thermoforming
    The objective of this experimental work was to create thermoformed packages different shapes from the same material under the same conditions with the same depth of draw and approximately the same volume.
    The formed packages were then tested for thickness at specific points using a micrometer. The results were then compared between shapes,
    The conditions used were:
    Film Polyvinyl alcohol (supplied By Chris Craft under Reference CC8534)
    Thickness 75µm
    Volume of cavity Approx. 30ml
    Atmospheric condition 17°C, 46% RH
    Micrometer sensitivity 5µm
    Measurement points
    Figure 00100001
    The rectangular shape shown is used only as an example to show the various points.
    For a dome shaped package only points A & E are the same. Points B, C and D are all equivalent in the dome shape and they were represented by Point F below.
    Figure 00110001
    The results were as follows:
    Measurement in microns
    Shape Sample Draw Depth A B C D E F
    Dome 1 20mm 60 70 65
    2 " 65 60 65
    3 " 65 60 60
    Triangle 1 " 50 50 45 30 65
    2 " 55 55 40 25 55
    3 " 55 55 40 25 60
    Dome 4 25mm 60 70 70
    5 " 65 70 70
    6 " 65 65 70
    Cube 1 " 55 40 20 15 35
    2 " 65 35 25 20 35
    3 " 60 40 25 20 40
    These results show that while thinning always takes place on thermoforming:
  • a) for the dome shape thinning is uniform over the test points; and
  • b) the dome has a lower level of thinning than the others over the test points.
  • ii) Impact Testing
    The objective of this test was to show any differences, which exist, between the impact resistance of the dome shape and other shapes.
    A falling dart impact test was used.
    The test specimen was placed on a hard surface immediately below the suspended dart. The dart was allowed to fall, striking the specimen centrally. The specimen was then examined and any rupture or leak recorded. If there was no rupture or leak, the specimen was subjected to successive impacts, each at a higher dart weight, until rupture did occur.
    Three shapes of package were used, all of the same material, fill and approximate weight and size. The test was repeated on both sides of the package (base side up and base side down) and several replicates were tested and a mean taken.
    Before testing all specimens were exposed to the conditions of the test site for 12 hours to reach equilibrium. Test details were:
    Dart smooth hemispherical impact surface of 38mm diameter
    Drop height 615mm
    Surface Smooth non-resilient plate
    Conditions 20°C, 70% RH
    Dome, triangle (ie triangular pyramid) and cube shapes were tested.
    Each package was formed from polyvinyl alcohol supplied by Chris Craft under reference CC8534. The film thickness was 75µm.
    Results were as follows:
    Sample Shape Orientation No. of Drops Dart Weight to Rupture Observations
    1 Dome Base Up 3 250g Small hole mid base
    2 Triangle " 2 150g 2 holes in edges
    3 Cube " 2 150g 3 or more holes in corners & edge
    4 Dome Base Down 4 350g hole in base
    The above results show that the impact resistance of dome is greater than the cube or triangle.
    iii) Secondary Packaging Test
    This experimental test was designed to establish any difference in impact survival between dome shaped packages and triangular packages of a liquid detergent product when multiple packages are contained in fibreboard box
    22 dome-shaped packages according to the invention, containing a liquid laundry detergent, were placed randomly in a fibreboard box. The box was made of "M-flute" material of dimensions 170 x 85 x 54 mm which had a total filled weight of 609g.
    The box was sealed closed and subjected to a vertical drop of 1.2 m on to a hard flat surface on the short dimensions.
    This test was repeated for triangular packages of the same weight and film.
    The results of the test were that 3 out of the 22 dome shaped packages were found to have a small amount of leakage but with the triangular packages, 7 of the 22 were leaking and in 5 cases leakage was very severe.

    Claims (14)

    1. A water soluble package containing a fluid substance for release on dissolution of the package, characterised in that the package has a body portion for containing the substance comprising a first sheet of a water soluble material thermoformed to form a body wall of the body portion, and a second sheet of water soluble material superposed on the first sheet and sealed thereto along a continuous region of the superposed sheets to form a base wall of the body portion, and in that the body portion of the package is generally dome shaped.
    2. A package according to claim 1, characterised in that the maximum height of the body wall above the base wall is less than or equal to the maximum width of the base wall.
    3. A package according to claim 1 or claim 2, characterised in that the base wall is generally circular.
    4. A package according to claim 1 or claim 2, characterised in that the base wall is generally oval.
    5. A package according to any one of claims 1 to 4, characterised in that the base wall is generally flat, or slightly concave or convex.
    6. A package according to any one of claims 1 to 5, characterised in that the first sheet of water-soluble material comprises polyvinyl alcohol or a polyvinyl alcohol derivative.
    7. A package according to any one of claims 1 to 6, characterised in that the second sheet of water soluble material comprises polyvinyl alcohol or a polyvinyl alcohol derivative.
    8. A package according to any one of claims 1 to 7, characterised in that the fluid substance is a liquid, paste or a gel.
    9. A package according to any one of claims 1 to 8, characterised in that the fluid substance is a domestic consumer product.
    10. A package according to claim 9, characterised in that the substance is a laundry detergent composition.
    11. A process for producing a water soluble package having a body portion containing a fluid substance for release on dissolution of the package, characterised in that the process comprises the steps of:
      thermoforming a first sheet of a water soluble material to form a domed body wall of the body portion;
      placing the fluid substance in the body portion;
      superposing a second sheet of a water soluble material over the first sheet; and
      heat sealing the first and second sheets along a continuous region of the superposed sheets surrounding the substance to form a base wall of the body portion.
    12. A process according to claim 11, characterised in that the first sheet of water-soluble material is thermoformed by means of a heating plate.
    13. A process according to claim 11 or claim 12, characterised in that prior to the addition of the substance a vacuum is applied to the thermoformed body wall to maintain the shape of the body portion at least until after the heat sealing step.
    14. A process for the machine washing of laundry by employing a package according to any of claims 1 to 10, characterised in that the fluid substance contained within the package comprises a laundry treatment agent, the process comprising the steps of:
      placing at least one package into the machine along with the laundry to be washed; and
      carrying out a washing operation.
    EP00912519A 1999-03-17 2000-02-29 Water soluble package Revoked EP1161382B1 (en)

    Priority Applications (2)

    Application Number Priority Date Filing Date Title
    EP03003920A EP1314654A3 (en) 1999-03-17 2000-02-29 Water soluble package
    EP03013108A EP1361172B1 (en) 1999-03-17 2000-02-29 Water soluble package

    Applications Claiming Priority (3)

    Application Number Priority Date Filing Date Title
    GB9906175 1999-03-17
    GBGB9906175.6A GB9906175D0 (en) 1999-03-17 1999-03-17 A water soluble package
    PCT/EP2000/001646 WO2000055068A1 (en) 1999-03-17 2000-02-29 Water soluble package

    Related Child Applications (2)

    Application Number Title Priority Date Filing Date
    EP03003920A Division EP1314654A3 (en) 1999-03-17 2000-02-29 Water soluble package
    EP03013108A Division EP1361172B1 (en) 1999-03-17 2000-02-29 Water soluble package

    Publications (2)

    Publication Number Publication Date
    EP1161382A1 EP1161382A1 (en) 2001-12-12
    EP1161382B1 true EP1161382B1 (en) 2003-09-03

    Family

    ID=10849830

    Family Applications (3)

    Application Number Title Priority Date Filing Date
    EP03003920A Withdrawn EP1314654A3 (en) 1999-03-17 2000-02-29 Water soluble package
    EP03013108A Revoked EP1361172B1 (en) 1999-03-17 2000-02-29 Water soluble package
    EP00912519A Revoked EP1161382B1 (en) 1999-03-17 2000-02-29 Water soluble package

    Family Applications Before (2)

    Application Number Title Priority Date Filing Date
    EP03003920A Withdrawn EP1314654A3 (en) 1999-03-17 2000-02-29 Water soluble package
    EP03013108A Revoked EP1361172B1 (en) 1999-03-17 2000-02-29 Water soluble package

    Country Status (16)

    Country Link
    US (1) US20020033004A1 (en)
    EP (3) EP1314654A3 (en)
    CN (1) CN1344214A (en)
    AR (1) AR022943A1 (en)
    AT (2) ATE445548T1 (en)
    AU (1) AU3425600A (en)
    BR (1) BR0009049A (en)
    CA (1) CA2360804A1 (en)
    DE (3) DE1161382T1 (en)
    ES (2) ES2186595T3 (en)
    GB (1) GB9906175D0 (en)
    ID (1) ID30482A (en)
    RO (1) RO118946B1 (en)
    TR (1) TR200102519T2 (en)
    WO (1) WO2000055068A1 (en)
    ZA (1) ZA200105052B (en)

    Cited By (8)

    * Cited by examiner, † Cited by third party
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    US7830263B2 (en) 2006-04-28 2010-11-09 Obrist Closures Switzerland Gmbh Closure with RFID device
    USD630093S1 (en) 2010-06-11 2011-01-04 Obrist Closures Switzerland Gmbh Closure
    US8413830B2 (en) 2008-04-04 2013-04-09 Obrist Closures Switzerland Gmbh Closure
    US8453856B2 (en) 2007-07-13 2013-06-04 Obrist Closures Switzerland Gmbh Tamper-evident closure
    US8490804B2 (en) 2007-10-31 2013-07-23 Obrist Closures Switzerland Gmbh Closure with movable tamper-evident member
    US8522991B2 (en) 2003-10-31 2013-09-03 Obrist Closures Switzerland Gmbh Tamper evident closure
    US9102448B2 (en) 2007-07-13 2015-08-11 Obrist Closures Switzerland Gmbh Tamper-evident closure

    Families Citing this family (77)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    AU2001262160A1 (en) * 2000-04-14 2001-10-30 Hewitt, Malcolm Water soluble package of liquid cleaning composition
    AU2001256248A1 (en) 2000-04-14 2001-10-30 Unilever Plc Water soluble package and liquid contents thereof
    AU2001263062A1 (en) 2000-05-11 2001-11-20 The Procter And Gamble Company Highly concentrated fabric softener compositions and articles containing such compositions
    AU2001270503B2 (en) 2000-05-15 2004-04-01 Unilever Plc Liquid detergent composition
    US20020142931A1 (en) * 2000-07-19 2002-10-03 The Procter & Gamble Company Gel form automatic dishwashing compositions, methods of preparation and use thereof
    DE10040724A1 (en) * 2000-08-17 2002-03-07 Henkel Kgaa Mechanically stable, liquid formulated detergent, detergent or cleaning agent portions
    AU2001284175B2 (en) * 2000-08-25 2006-07-13 Reckitt Benckiser (Uk) Limited Water-soluble thermoformed containers comprising aqueous compositions
    GB0020964D0 (en) 2000-08-25 2000-10-11 Reckitt & Colmann Prod Ltd Improvements in or relating to containers
    ATE305886T1 (en) 2000-10-18 2005-10-15 Reckitt Benckiser Nv DETERGENT PACKED WITH ETHOXYLATED POLYVINYL ALCOHOL
    GB2369083A (en) * 2000-11-17 2002-05-22 Procter & Gamble Process for preparing pouches
    IT1320095B1 (en) * 2000-11-23 2003-11-18 Packaging Imolese S P A PROCESS AND MACHINE FOR THE PRODUCTION OF PLASTIC BLISTERS FOR THE CONTAINMENT OF LIQUID PERFUMES TO BE USED AS DEODORANTS
    US8940676B2 (en) 2000-11-27 2015-01-27 The Procter & Gamble Company Detergent products, methods and manufacture
    WO2002042400A2 (en) 2000-11-27 2002-05-30 The Procter & Gamble Company Dishwashing method
    ATE340850T1 (en) * 2000-11-27 2006-10-15 Procter & Gamble DISHWASHING METHOD
    US7125828B2 (en) 2000-11-27 2006-10-24 The Procter & Gamble Company Detergent products, methods and manufacture
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    GB2371307B (en) 2001-01-19 2003-10-15 Reckitt Benckiser Nv Packaged detergent compositions
    GB2373235A (en) * 2001-03-16 2002-09-18 Reckitt Benckiser Composition packaged in film
    GB0107529D0 (en) * 2001-03-26 2001-05-16 Unilever Plc A process and device for washing laundry in a washing machine
    GB2374581B (en) * 2001-04-20 2004-01-28 Reckitt Benckiser Water soluble containers
    GB2374830A (en) * 2001-04-20 2002-10-30 Reckitt Benckiser Improvements in or relating to compositions/components including a thermoforming step
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    GB2380463B (en) 2001-10-03 2003-09-24 Reckitt Benckiser Nv A Process for Producing a Sealed Water-Soluble Package
    GB0126407D0 (en) * 2001-11-02 2002-01-02 Unilever Plc Water soluble capsules
    EP1440016A1 (en) * 2001-11-02 2004-07-28 Unilever Plc Water soluble capsules
    GB2387805A (en) * 2002-01-26 2003-10-29 Aquasol Ltd Improvements in or relating to Devices
    GB2385857B (en) 2002-02-27 2004-04-21 Reckitt Benckiser Nv Washing materials
    DE10215601B4 (en) * 2002-04-10 2005-08-04 Henkel Kgaa Water-soluble container and process for its preparation and use
    CA2494721A1 (en) * 2002-07-31 2004-02-05 Colgate-Palmolive Company Unit dose nonaqueous softener disposed in water soluble container
    ITMI20021865A1 (en) 2002-08-30 2004-02-29 Packaging Imolese S P A PROCESS FOR THERMOFORMING PRODUCTION OF
    GB2392450A (en) 2002-08-31 2004-03-03 Reckitt Benckiser Inc Liquid detergent compositions
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    DE10244802B4 (en) 2002-09-26 2011-12-22 Henkel Ag & Co. Kgaa Plump detergent tablets
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    DE102004021732A1 (en) 2004-04-30 2005-11-24 Henkel Kgaa Textilplegemittel with amine group-containing cellulose ether
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    EP3205601A1 (en) * 2016-02-11 2017-08-16 The Procter and Gamble Company Packaged product
    JOP20190032A1 (en) * 2017-06-14 2019-02-26 Grow Solutions Tech Llc Systems and methods for depositing seeds in a grow pod
    JOP20190030A1 (en) * 2017-06-14 2019-02-26 Grow Solutions Tech Llc Precision seeder heads and seeder components that include precision seeder heads
    CN108004070B (en) * 2017-11-24 2020-06-09 江苏金太阳纺织科技股份有限公司 Anti-contamination washing gel bead and preparation method thereof
    WO2019123343A1 (en) 2017-12-22 2019-06-27 Church & Dwight Co., Inc. Laundry detergent composition
    CN115535335B (en) * 2022-10-27 2024-06-14 重庆大学 Preparation device and method of giant electrorheological fluid variable-rigidity elastic ball group

    Family Cites Families (8)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    US2377118A (en) * 1940-11-30 1945-05-29 Mabe Corp Package
    GB8726096D0 (en) * 1987-11-06 1987-12-09 Koska & Watts Ltd Packages of sugar syrups &c
    FR2641551B2 (en) 1988-05-18 1991-11-22 Procter & Gamble METHOD AND DEVICE FOR WASHING LAUNDRY IN A MACHINE WITH A PARTICULATE PRODUCT
    FR2631639B1 (en) 1988-05-18 1991-06-21 Procter & Gamble METHOD FOR WASHING LAUNDRY IN A MACHINE WITH A PARTICULATE PRODUCT AND DEVICE FOR IMPLEMENTING SAME
    EP0366231A1 (en) * 1988-09-26 1990-05-02 Zimpro Environmental, Inc. Sealed PVA package with activated carbon and its use in waste water treatment
    US4973416A (en) * 1988-10-14 1990-11-27 The Procter & Gamble Company Liquid laundry detergent in water-soluble package
    IL101490A (en) 1991-04-05 1995-03-15 Rhone Poulenc Agriculture Package for agrochemicals
    JPH10510857A (en) * 1994-12-15 1998-10-20 アルベマール・コーポレーシヨン Liquid laundry detergent

    Cited By (8)

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    Publication number Priority date Publication date Assignee Title
    US7674761B2 (en) 2001-03-16 2010-03-09 Unilever Home & Personal Care, Division Of Conopco, Inc. Water soluble sachet with a dishwashing enhancing particle
    US8522991B2 (en) 2003-10-31 2013-09-03 Obrist Closures Switzerland Gmbh Tamper evident closure
    US7830263B2 (en) 2006-04-28 2010-11-09 Obrist Closures Switzerland Gmbh Closure with RFID device
    US8453856B2 (en) 2007-07-13 2013-06-04 Obrist Closures Switzerland Gmbh Tamper-evident closure
    US9102448B2 (en) 2007-07-13 2015-08-11 Obrist Closures Switzerland Gmbh Tamper-evident closure
    US8490804B2 (en) 2007-10-31 2013-07-23 Obrist Closures Switzerland Gmbh Closure with movable tamper-evident member
    US8413830B2 (en) 2008-04-04 2013-04-09 Obrist Closures Switzerland Gmbh Closure
    USD630093S1 (en) 2010-06-11 2011-01-04 Obrist Closures Switzerland Gmbh Closure

    Also Published As

    Publication number Publication date
    EP1161382A1 (en) 2001-12-12
    EP1314654A2 (en) 2003-05-28
    WO2000055068A1 (en) 2000-09-21
    ES2334436T3 (en) 2010-03-10
    BR0009049A (en) 2002-01-15
    GB9906175D0 (en) 1999-05-12
    ZA200105052B (en) 2002-09-20
    ES2186595T1 (en) 2003-05-16
    EP1361172A1 (en) 2003-11-12
    ES2186595T3 (en) 2004-05-01
    DE60004976D1 (en) 2003-10-09
    TR200102519T2 (en) 2001-12-21
    US20020033004A1 (en) 2002-03-21
    RO118946B1 (en) 2004-01-30
    AU3425600A (en) 2000-10-04
    EP1314654A3 (en) 2003-07-02
    ATE445548T1 (en) 2009-10-15
    DE60043162D1 (en) 2009-11-26
    ATE248758T1 (en) 2003-09-15
    DE1161382T1 (en) 2003-08-14
    DE60004976T2 (en) 2004-05-19
    ID30482A (en) 2001-12-13
    AR022943A1 (en) 2002-09-04
    CA2360804A1 (en) 2000-09-21
    EP1361172B1 (en) 2009-10-14
    CN1344214A (en) 2002-04-10

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