EP1157825B1 - Ordinateur à plaque par jet d'encre - Google Patents

Ordinateur à plaque par jet d'encre Download PDF

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Publication number
EP1157825B1
EP1157825B1 EP20000201858 EP00201858A EP1157825B1 EP 1157825 B1 EP1157825 B1 EP 1157825B1 EP 20000201858 EP20000201858 EP 20000201858 EP 00201858 A EP00201858 A EP 00201858A EP 1157825 B1 EP1157825 B1 EP 1157825B1
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Prior art keywords
substituted
unsubstituted
ink
printing
saturated
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EP20000201858
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German (de)
English (en)
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EP1157825A1 (fr
Inventor
Johan c/o Agfa-Gevaert N.V. Loccufier
Marc C/O Agfa-Gevaert N.V. Van Damme
Leo c/o Agfa-Gevaert N.V. Oelbrandt
Peter c/o Agfa-Gevaert N.V. Hendrickx
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Agfa Gevaert NV
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Agfa Gevaert NV
Agfa Gevaert AG
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Priority to EP20000201858 priority Critical patent/EP1157825B1/fr
Priority to DE2000610437 priority patent/DE60010437T2/de
Priority to US09/864,462 priority patent/US6523472B1/en
Priority to JP2001155417A priority patent/JP2002046248A/ja
Publication of EP1157825A1 publication Critical patent/EP1157825A1/fr
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Publication of EP1157825B1 publication Critical patent/EP1157825B1/fr
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41C—PROCESSES FOR THE MANUFACTURE OR REPRODUCTION OF PRINTING SURFACES
    • B41C1/00—Forme preparation
    • B41C1/10—Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme
    • B41C1/1066—Forme preparation for lithographic printing; Master sheets for transferring a lithographic image to the forme by spraying with powders, by using a nozzle, e.g. an ink jet system, by fusing a previously coated powder, e.g. with a laser

Definitions

  • the present invention relates to a method for the preparation of a lithographic printing plate by means of ink jet printing.
  • the image to be printed is present on a plate as a pattern of ink accepting (oleophilic) areas on an ink repellent (oleophobic or hydrophilic) background.
  • the required ink repellency is provided by an initial application of a dampening (or "fountain) solution prior to inking.
  • Conventional presensitized lithographic printing plates bear a UV sensitive coating based on photopolymer or diazonium chemistry.
  • the plates have to be UV-exposed through a mask carrying the image.
  • the mask is a graphic arts film prepared by photographic techniques based on silver halide chemistry and involving exposure by a camera or by an image-setter, and further involving wet processing.
  • the SETPRTINT material trade mark of Agfa-Gevaert N.V. is based on silver halide DTR chemistry and consists of a polyethylene terephthalate base carrying a photographic coating which after photo-mode exposure and processing produces complementary oleophilic and hydrophilic areas.
  • Another system based on photo-mode exposure but with a hydrophilic aluminum base is LITHOSTAR, trade mark of Agfa-Gevaert N.V..
  • a system based on heat mode exposure by means of an intense infra-red laser is called THERMOSTAR, also a trade mark of Agfa-Gevaert N.V..
  • ink jet printers have replaced laser printers as the most popular hard copy output printers for computers. Some of the competitive advantages of ink jet printers are low cost and reliability.
  • the ink jet printing system is a relatively rapid image output system and has a simple construction because it does not require any complex optical system.
  • an oleophilic liquid or fluid ink was printed by ink jet printing onto a hydrophilic aluminum surface of a lithographic printing plate. Titanate or silane coupling agents were present in the ink.
  • ink jet printing wherein the ink is a solid or phase change type ink instead of a liquid or fluid type ink is described in U.S. Pat. No. 4,833,486 to deposit a hot wax on a surface of an offset plate. Upon cooling of the wax, it solidifies, thereby providing a printing plate.
  • Solid ink jet printing has serious disadvantages for lithographic plates in that the wax or resin image has limited durability due to its thermoplastic, chemical, and adhesive properties and the amount and rounded shape of the solidified ink jet droplet on the media do not have the intrinsic image resolution properties found in liquid ink jet printing.
  • Japanese Kokai Publication 113456/1981 proposes methods for preparing printing plates whereby ink-repelling materials (e.g. curable silicones) are printed on a printing plate by ink jet printing.
  • the printing plate obtained by this method is an intaglio printing plate in which the ink-repelling material formed on the surface of the substrate serves as a non-image part.
  • the resolution of the printed images at shadow area or reversed lines is not so good.
  • a large amount of ink is needed in this method because the ink-repelling material must be deposited on the whole non-image part which occupies most of the surface of the printing plate, thereby delaying the printing process.
  • US-P- 5 511 477 discloses a method for the production of photopolymeric relief-type printing plates comprising: forming a positive or a negative image on a substrate by ink jet printing with a photopolymeric ink composition, optionally preheated to a temperature of about 30°-260°C, and subjecting the resulting printed substrate to UV radiation, thereby curing said ink composition forming said image.
  • This is an obnoxious method due to the sometimes high vapour pressure and toxicity of said inks.
  • US-P- 5 312 654 discloses a method for making lithographic printing plates comprising: forming an image on a substrate having an ink absorbing layer and a hydrophilized layer between the substrate and the absorbing layer by ink jet printing using a photopolymerizable ink composition, and exposing it to an actinic light in the wavelength region with which said ink composition is sensitized to cure the image.
  • the printing endurance of said printing plates is low.
  • Japanese Kokai Publication 69244/1992 discloses a method for making printing plates comprising the steps of forming a printed image on a recording material subjected to a hydrophilic treatment by ink jet printing using a hydrophobic ink containing photocurable components, and exposing the whole surface to actinic light.
  • the surface of the substrate to be used for the lithographic plate is usually subjected to various treatments such as a mechanical graining, an anodizing or a hydrophilic treatment to obtain good hydrophilic property and water retention property. Therefore, even the use of an ink composition having a very high surface tension results in a poor image on the surface of the substrate because of ink spreading and low printing endurance.
  • EP-A- 533 168 discloses a method for avoiding said ink spreading by coating the lithographic base with an ink absorbing layer which is removed after ink printing. This is an uneconomical and cumbersome method.
  • Research Disclosure 289118 of May 1988 discloses a method for making printing plates with the use of an ink jet wherein the ink is a hydrophobic polymer latex.
  • said printing plates have a bad ink acceptance and a low printing endurance.
  • EP-A- 003 789 discloses a process for the preparation of offset printing plates by means of an ink jet method with oleophilic inks. There is not indicated how said inks are made but from the examples it is clear that it concerns artificial latices, which are difficult to prepare.
  • EP-A-882 584 discloses a method for the preparation of a lithographic printing plate comprising the step of ink-jet printing an image on a surface of a printing plate support using a solution containing a salt of a hydrophobic organic acid.
  • JN- 57/038142 discloses a method of preparing a printing plate by forming an ink image on a blank printing plate, and also by fixing this image thermally by making toner to adhere to this image-formed area.
  • the composition of the ink is not mentioned, only the composition of the toners is disclosed.
  • JN- 07/108667 discloses a plate-making method forming an ink image containing a hydrophilic substance on a conductive support whose surface layer is made hydrophilic according to an electrostatic attraction type ink set system to dry or cure the same, by applying bias voltage to the conductive support at the time of ink jet writing. This is a cumbersome process.
  • US-P- 5,213,041 discloses a method for preparing a reusable printing plate for printing, projecting an imaging deposit on the plate surface by jet printing using an ejectable substance containing a heat fusible component.
  • the image forms an imaging deposit which is fused to the surface of the printing plate using a variable frequency and variable power induction heater.
  • a lithographic printing plate is manufactured by means of an ink jet fluid comprising reactive components selected from the group consisting of transition metal complexes and organic carbonyl compounds.
  • the reactive compound comprises one or more chromium complexes of an organic acid.
  • the present invention extends the teaching on the preparation of a lithographic printing plate whereby an oleophilizing fluid is directly applied onto a lithographic receiver by means of ink jet printing.
  • the above mentioned objects are realized by providing a method for the preparation of a lithographic printing plate, said method comprising dispensing information-wise by means of ink jet printing droplets of a fluid onto a surface of a lithographic receiver, characterized in that said fluid contains an oleophilizing agent having in its chemical structure a phosphorous containing group capable of reacting with said surface of said lithographic receiver.
  • the essence of the present invention is the presence in the ink jet fluid of an oleophilizing compound having in its molecule a phosphorous containing group capable of reacting with the surface of the lithographic receiver.
  • the oleophilizing agents containing a phosphorous containing functional group, capable of interacting with a metal oxide are selected from mono- or di-esters of phosphoric acids or salts thereof or the thio-analogues, phosphonic acid derivatives salts thereof or the thio-analogues, and phosphorylhydrazides or the thio-analogues.
  • Said mono- and di-esters of phosphoric acid are represented by general formula (I).
  • R12 and R13 each independently represent hydrogen or a counterion to compensate the negative charge of X 2 or X 3 , a substituted or unsubstituted, saturated or unsaturated aliphatic chain, a substituted or unsubstituted aryl or heteroaryl group; R12 and R13 may form a ring;
  • X 1 , X 2 , X 3 and X 4 are independently selected from oxygen or sulfur;
  • M is a proton or a counterion to compensate the negative charge of X 4 .
  • X 1 to X 4 are oxygen.
  • the phosphate hydrophobizing agent is a phoshate surfactant represented by the general formula (II) : wherein n is an integer different from 0 ; M and N are independently selected from a proton or a counterion to compensate the negative charge of the phosphate ; R represents a substituted or unsubstituted, saturated or unsaturated aliphatic chain, a substituted or unsubstituted aryl or hetero-aryl group.
  • the oleophilizing compounds are chosen from phosphonic acids and their thio-analogues.
  • Phosphonic acids and their thio-analogues are represented by general formula (III).
  • R14 represent a substituted or unsubstituted saturated or unsaturated aliphatic chain, or a substituted or unsubstituted aryl or hetero-aryl group
  • R15 represents a hydrogen or counterion to compensate the negative charge of X 6 , a substituted or unsubstituted, saturated or unsaturated aliphatic chain, or a substituted or unsubstituted aryl or hetero-aryl group
  • R14 and R15 may form a ring
  • X 5 , X 6 and X 7 are independently selected from oxygen or sulfur
  • M is a proton or a counterion to compensate the negative charge of X 7 .
  • X 5 to X 7 are oxygen.
  • Still a further preferred class of oleophilizing compounds according to the present invention are phosphorylhydrazides and hydroxamic acids.
  • R16 and R17 each independently represent a substituted or unsubstituted, saturated or unsaturated aliphatic group, a substituted or unsubstituted aryl or hetero-aryl group, OR 20 , NR 21 R 22 , SR 23 or N(YR18) (M); R 20 to R 23 independently represent a hydrogen or counterion to compensate the negative charge, a substituted or unsubstituted, saturated or unsaturated aliphatic group or a substituted or unsubstituted aryl or hetero-aryl group; all R groups may form rings; X represents oxygen or sulfur; Y represents oxygen or NR19; R18 and R19 are independently selected from a hydrogen, a substituted or unsubstituted, saturated or unsaturated aliphatic chain, a substituted or unsubstituted aryl or hetero-aryl group, or an acyl group; R18 and R19 may form a ring; M is
  • the oleophilizing agent may be present in the ink in an amount from 0.01 to 6, preferably from 0.02 to 3 % by weight.
  • the oleophilizing agent is in the form of a homogeneous solution or a stable colloidal dispersion, so that it can pass through the nozzles of the printer head.
  • the liquid carrier is water or an organic solvent or combinations thereof. Choice of the specific liquid carrier depends on the specific ink jet printer and its compatibility with the ink jet printing head and cartridge being used for the ink jet printing. Both aqueous based and solvent based fluids can be used in the present invention depending on the ink jet technology that is being used : piezo, thermal, bubble jet or continuous ink jet.
  • the aqueous composition may comprise one or more water miscible solvents e.g. a polyhydric alcohol such as ethylene glycol, diethylene glycol, triethylene glycol or trimethylol propane.
  • the amount of aqueous carrier medium in the aqueous composition may be in the range from 30 to 99.995, preferably from 50 to 95 % by weight.
  • organic solvents may be used as a carrier medium for the ink jet fluid, e.g. alcohols, ketones or acetates.
  • Ink jet fluids suitable for use with ink jet printing systems may have a surface tension in the range from 20 to 60, preferably from 30 to 50 mN/m (dyne/cm). Control of surface tensions in aqueous ink jet fluids may be accomplished by additions of small amounts of surfactants. The level of surfactants to be used can be determined through simple trial and error experiments. Several anionic and nonionic surfactants are known in the ink jet art.
  • the viscosity of the fluid is preferably not greater than 20 mPa.s, e.g. from 1 to 10, preferably from 1 to 5 mPa.s at room temperature.
  • the ink jet fluid may further comprise other ingredients.
  • a cosolvent may be included to help prevent the ink from drying out in the orifices of the print head.
  • a biocide may be added to prevent unwanted microbial growth which may occur in the ink over time. Additional additives that may be optionally present in the ink include thickeners, pH adjusters, buffers, conductivity enhancing agents, drying agents and defoamers.
  • dyes may be added.
  • Many dyes and pigments are known to be suited for the ink jet technology. Suitable dyes are further selected based on their compatibility in the carrier medium (i.e. aqueous based or solvent based) and on the compatibility with the oleophilizing agent, i.e. they should not lead to coagulation.
  • aqueous inks are anionic dyes such as acid black
  • the support may be any support suitable for printing plates.
  • Typical supports include metallic and polymeric sheets or foils.
  • a support having a metallic surface is used.
  • the metallic surface is oxidised.
  • a support having an anodised aluminium surface is employed.
  • the support for the lithographic printing plate is typically formed of aluminium which has been grained, for example by electrochemical graining, and then anodised, for example, by means of anodising techniques employing sulphuric acid and/or phosphoric acid. Methods of both graining and anodising are very well known in the art and need not be further described herein.
  • the printing plate After writing the image the printing plate can be inked with printing ink in the normal way, and the plate can be used on a printing press. Before inking the plate can be treated with an aqueous solution of natural gum, such as gum acacia, or of a synthetic gum such as carboxymethyl cellulose, as it is well known in the art of printing.
  • natural gum such as gum acacia
  • synthetic gum such as carboxymethyl cellulose
  • the lithographic base with a hydrophilic surface comprises a flexible support, such as e.g. paper or plastic film, provided with a cross-linked hydrophilic layer.
  • a particularly suitable cross-linked hydrophilic layer may be obtained from a hydrophilic binder cross-linked with a cross-linking agent such as formaldehyde, glyoxal, polyisocyanate, melamine type cross-linkers, ammonium zirconyl carbonate, titanate crosslinkers, or a hydrolysed tetraalkylorthosilicate. The latter is particularly preferred.
  • hydrophilic binder there may be used hydrophilic (co)polymers such as, for example, homopolymers and copolymers of vinyl alcohol, acrylamide, methylol acrylamide, methylol methacrylamide, acrylate acid, methacrylate acid, hydroxyethyl acrylate, hydroxyethyl methacrylate or maleic anhydride/vinylmethylether copolymers.
  • the hydrophilicity of the (co)polymer or (co)polymer mixture used is preferably the same as or higher than the hydrophilicity of polyvinyl acetate hydrolyzed to at least an extent of 60 percent by weight, preferably 80 percent by weight.
  • a cross-linked hydrophilic binder in the heat-sensitive layer used in accordance with the present embodiment also contains colloidal inorganic pigments that increase the mechanical strength and the porosity of the layer e.g. metal oxide particles which are particles of titanium dioxide or other metal oxides. It is believed that incorporation of these particles gives the surface of the cross-linked hydrophilic layer a uniform rough texture consisting of microscopic hills and valleys which serve as storage places for water in background areas.
  • these particles are oxides or hydroxydes of beryllium, magnesium, aluminium, silicon, gadolinium, germanium, arsenic, indium, tin, antimony, tellurium, lead, bismuth, titanium or a transition metal.
  • Particularly preferable inorganic particles are oxides or hydroxides of aluminum, silicon, zirconium or titanium, used in at most 75 % by weight of the hydrophilic layer.
  • the inorganic pigments may have have a particla size ranging from 0.005 ⁇ m to 10 ⁇ m.
  • the thickness of a cross-linked hydrophilic layer in a lithographic base in accordance with this embodiment may vary in the range of 0.2 to 25 pm and is preferably 1 to 10 ⁇ m.
  • plastic film e.g. subbed polyethylene terephthalate film, subbed polyethylene naphthalate film, cellulose acetate film, polystyrene film, polycarbonate film etc.
  • the plastic film support may be opaque or transparent.
  • ink jet printing tiny drops of ink fluid are projected directly onto an ink receptor surface without physical contact between the printing device and the receptor.
  • the printing device stores the printing data electronically and controls a mechanism for ejecting the drops image-wise. Printing is accomplished by moving the print head across the paper or vice versa.
  • Early patents on ink jet printers include US 3,739,393, US 3,805,273 and US 3,891,121.
  • the jetting of the ink droplets can be performed in several different ways.
  • a continuous droplet stream is created by applying a pressure wave pattern. This process is known as continuous ink jet printing.
  • the droplet stream is divided into droplets that are electrostatically charged, deflected and recollected, and into droplets that remain uncharged, continue their way undeflected, and form the image.
  • the charged deflected stream forms the image and the uncharged undeflected jet is recollected.
  • several jets are deflected to a different degree and thus record the image (multideflection system).
  • the ink droplets can be created “on demand” (“DOD” or “drop on demand” method) whereby the printing device ejects the droplets only when they are used in imaging on a receiver thereby avoiding the complexity of drop charging, deflection hardware, and ink recollection.
  • DOD on demand
  • the ink droplet can be formed by means of a pressure wave created by a mechanical motion of a piezoelectric transducer (so-called “piezo method”), or by means of discrete thermal pushes (so-called “bubble jet” method, or “thermal jet” method).
  • test pattern containing a text image was written onto a grained and anodised aluminium printing plate material which had been loaded into the printer. The plate was removed and gummed with OZASOL RC515.
  • the ink as described in example 1 was loaded into the ink cartridge of a Epson STYLUS COLOR 900 ink jet printer, the cartridge having previously been emptied and cleaned.
  • test pattern containing a text image was written onto a grained and anodised aluminium printing plate material which had been loaded into the printer. The plate was removed and gummed with OZASOL RC515.
  • Example 1 was repeated with the exception that before loading the ink was adjusted to pH 7 with 1 M NaOH. Again, after imaging, gumming and printing excellent copies were obtained.
  • Example 1 was repeated with the exception that the plate was not gummed after the imaging. Excellent copies were also obtained.
  • Example 1 was repeated with the exception that another oleophilizing agent comprising a phosphorous containing group, as described in following table 1 replaced EMPHOS PS810. All compounds are represented by general formula (II). The suppliers of which the compounds are trade marks are added to the table.
  • GAFAC RA600 Rhone-Poulenc (II-1) Excellent copies 6.
  • GAFAC KE870 Rhone Poulenc III-2) Excellent copies 7.
  • EMPHOS 141 WITCO (II-7) Excellent copies 11.
  • EMPHOS CS1361 WITCO (II-8) Excellent copies 12.
  • EMPHOS CS136 WITCO (II-9) Excellent copies
  • Example 1 was repeated with the exception that no oleophilizing agent was used in the ink solution. After imaging, gumming and printing no good copies could be obtained. The image did not show any tendency to accept the ink.

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  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Manufacture Or Reproduction Of Printing Formes (AREA)
  • Printing Plates And Materials Therefor (AREA)
  • Ink Jet (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Claims (12)

  1. Procédé pour la préparation d'un cliché d'impression lithographique, ledit procédé comprenant le fait de distribuer, en forme d'information, à l'aide d'un jet d'encre, des gouttelettes d'impression d'un fluide sur une surface hydrophile d'un récepteur lithographique, caractérisé en ce que ledit fluide contient un composé rendant oléophile possédant, dans sa structure chimique, un groupe comprenant un ou plusieurs atomes de phosphore, capable de réagir avec ladite surface dudit récepteur lithographique.
  2. Procédé selon la revendication 1, dans lequel ledit composé rendant oléophile répond à la formule générale (I) :
    Figure 00300001
    dans laquelle R12 et R13 représentent, chacun indépendamment l'un de l'autre, une chaíne aliphatique saturée ou insaturée, substituée ou non substituée, un groupe aryle ou un groupe hétéroaryle substitué ou non substitué ; R12 et R13 peuvent former un noyau ; X1, X2, X3 et X4 sont choisis, indépendamment l'un de l'autre, parmi le groupe comprenant un atome d'oxygène et un atome de soufre ; M représente un proton ou un ion antagoniste pour compenser la charge négative de X4.
  3. Procédé selon la revendication 1, dans lequel ledit composé rendant oléophile répond à la formule générale (II) :
    Figure 00300002
    dans laquelle n représente un entier différent de 0 ; M et N sont choisis, indépendamment l'un de l'autre parmi le groupe comprenant un proton ou un ion antagoniste pour compenser la charge négative du phosphate ; R représente une chaíne aliphatique saturée ou insaturée, substituée ou non substituée, un groupe aryle ou un groupe hétéroaryle substitué ou non substitué.
  4. Procédé selon la revendication 1, dans lequel ledit composé rendant oléophile répond à la formule générale (III) :
    Figure 00310001
    dans laquelle R14 représente une chaíne aliphatique saturée ou insaturée, substituée ou non substituée, ou bien un groupe aryle ou un groupe hétéroaryle substitué ou non substitué ; R15 représente un atome d'hydrogène ou un ion antagoniste pour compenser la charge négative de X6, une chaíne aliphatique saturée ou insaturée, substituée ou non substituée, ou bien un groupe aryle ou un groupe hétéroaryle substitué ou non substitué ; R14 et R15 peuvent former un noyau ; X5, X6 et X7 sont choisis, indépendamment l'un de l'autre, parmi le groupe comprenant un atome d'oxygène et un atome de soufre ; M représente un proton ou un ion antagoniste pour compenser la charge négative de X7.
  5. Procédé selon la revendication 1, dans lequel ledit composé rendant oléophile répond à la formule générale (IV) :
    Figure 00310002
    dans laquelle R16 et R17 représentent, chacun indépendamment l'un de l'autre, une chaíne aliphatique saturée ou insaturée, substituée ou non substituée, un groupe aryle ou un groupe hétéroaryle substitué ou non substitué, OR20, NR21R22, SR23 ou N(YR18) (M) ; R20 à R23 représentent, indépendamment l'un de l'autre, un atome d'hydrogène ou un ion antagoniste pour compenser la charge négative, une chaíne aliphatique saturée ou insaturée, substituée ou non substituée, ou bien un groupe aryle ou un groupe hétéroaryle substitué ou non substitué ; tous les groupes R peuvent former un noyau ; X représente un atome d'oxygène et un atome de soufre ; Y représente un atome d'oxygène ou NR19 ; R18 et R19 sont choisis, indépendamment l'un de l'autre, parmi le groupe comprenant un atome d'hydrogène, une chaíne aliphatique saturée ou insaturée, substituée ou non substituée, un groupe aryle ou un groupe hétéroaryle substitué ou non substitué, ou un groupe acyle ; R18 et R19 peuvent former un noyau ; M représente un atome d'hydrogène ou un ion antagoniste pour compenser la charge négative.
  6. Procédé selon l'une quelconque des revendications 1 à 5, dans lequel ledit composé rendant oléophile est présent dans ledit fluide en une quantité qui se situe dans la plage de 0,01 à 6 % en poids.
  7. Procédé selon l'une quelconque des revendications 1 à 6, dans lequel ledit fluide contient en outre un colorant.
  8. Procédé selon l'une quelconque des revendications 1 à 7, dans lequel ladite surface dudit récepteur lithographique est une surface métallique.
  9. Procédé selon la revendication 8, dans lequel ladite surface métallique est de l'aluminium grainé et anodisé.
  10. Procédé selon l'une quelconque des revendications 1 à 7, dans lequel ledit récepteur lithographique comprend un support et une couche hydrophile réticulée.
  11. Procédé selon la revendication 10, dans lequel ladite couche hydrophile comprend un pigment inorganique.
  12. Procédé selon la revendication 11, dans lequel ledit pigment inorganique est choisi parmi le groupe comprenant un oxyde ou un hydroxyde de béryllium, de magnésium, d'aluminium, de silicium, de gadolinium, d'arsenic, d'indium, d'étain, d'antimoine, de tellure, de plomb, de bismuth, de titane ou d'un métal de transition.
EP20000201858 2000-05-25 2000-05-25 Ordinateur à plaque par jet d'encre Expired - Lifetime EP1157825B1 (fr)

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Application Number Priority Date Filing Date Title
EP20000201858 EP1157825B1 (fr) 2000-05-25 2000-05-25 Ordinateur à plaque par jet d'encre
DE2000610437 DE60010437T2 (de) 2000-05-25 2000-05-25 "Computer-to-plate" durch Tintenstrahl
US09/864,462 US6523472B1 (en) 2000-05-25 2001-05-23 Computer-to-plate by ink jet
JP2001155417A JP2002046248A (ja) 2000-05-25 2001-05-24 インキジェットによるコンピュータツウプレート

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GB0217976D0 (en) * 2002-08-02 2002-09-11 Eastman Kodak Co Method for the preparation of a printing plate
GB0217979D0 (en) 2002-08-02 2002-09-11 Eastman Kodak Co Method and substrate for the preparation of a printing plate
EP1401190B1 (fr) 2002-09-17 2013-05-29 Agfa Graphics N.V. Modulation de la phase des sous-points pour les systèmes d'ordinateur à plaque par jet d'encre
US6814789B2 (en) * 2002-09-24 2004-11-09 Hewlett-Packard Development Company, L.P. Use of additives to reduce puddling in inkjet inks
US6742886B1 (en) 2003-01-21 2004-06-01 Kodak Polychrome Graphics Lle Ink jet compositions for lithographic printing
US7094503B2 (en) 2003-03-27 2006-08-22 Kodak Graphics Communications Canada Company Nanopastes for use as patterning compositions
US7081322B2 (en) 2003-03-27 2006-07-25 Kodak Graphics Communications Canada Company Nanopastes as ink-jet compositions for printing plates
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JP2002046248A (ja) 2002-02-12
DE60010437D1 (de) 2004-06-09
EP1157825A1 (fr) 2001-11-28

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