EP1116815B1 - Textile coated with epichlorohydrin rubber and printed - Google Patents

Textile coated with epichlorohydrin rubber and printed Download PDF

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Publication number
EP1116815B1
EP1116815B1 EP01400070A EP01400070A EP1116815B1 EP 1116815 B1 EP1116815 B1 EP 1116815B1 EP 01400070 A EP01400070 A EP 01400070A EP 01400070 A EP01400070 A EP 01400070A EP 1116815 B1 EP1116815 B1 EP 1116815B1
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EP
European Patent Office
Prior art keywords
textile
printed
parts
weight
coated
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
EP01400070A
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German (de)
French (fr)
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EP1116815A1 (en
Inventor
Guy Bauts
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Venilia Sas
Original Assignee
Venilia S A S
Venilia Sas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Venilia S A S, Venilia Sas filed Critical Venilia S A S
Priority to SI200130319T priority Critical patent/SI1116815T1/en
Publication of EP1116815A1 publication Critical patent/EP1116815A1/en
Application granted granted Critical
Publication of EP1116815B1 publication Critical patent/EP1116815B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins

Definitions

  • the present invention relates to coated textiles printed in which the coating layer is based on epichlorohydrin elastomer as well as as a process for their preparation.
  • the printed coated fabrics currently available for example for the production of tablecloths or other articles in the field of table art, generally have a coating layer PVC (polyvinyl chloride) and / or halogenated polymers, in particular fluoropolymers.
  • PVC polyvinyl chloride
  • halogenated polymers in particular fluoropolymers.
  • coated fabrics are nevertheless not very flexible and have a insufficient resistance to aging by becoming stiff and brittle but as sticky to the touch. In particular, they have very bad resistance to bad weather and ultraviolet rays.
  • these fabrics are poorly resistant to food stains that remain more and more marked over time and become more and more difficult to remove. At the same time, they may lose their colors or printing patterns, especially as and when cleaning or under the effect of light, or give rise to yellowing.
  • the object of the present invention is to provide coated textiles may have printed patterns or decorations, which may be used in particular in the field of the art of the table, and not presenting the disadvantages mentioned above.
  • Another object of the invention is to provide coated textiles particularly flexible and retain their flexibility during their use or their storage, as well as during their successive cleanings.
  • Another object of the invention is still to provide a coated textile satisfactory 'printability' characteristics allowing particular the impression of patterns or decorations placed resistant to aging in particularly in time, with regard to light rays, cleaning, heat, etc ...
  • the subject of the invention is a coated textile with printed patterns, characterized in that it comprises a textile sub-layer forming a support associated with a coating layer based on elastomeric epichlorohydrin vulcanized, said coating layer having one or more pattern (s) printed on its surface not bound to the textile underlayment.
  • printed is meant the application of patterns or decorations on the surface of the coating layer of the coated textile, so discontinuous and varied, usually using acrylic type inks and / or modified polyurethane, as opposed to homogeneous coloration in the mass leading to relatively uniformly colored materials.
  • the inventors have discovered quite surprisingly that applying an epichlorohydrin elastomer coating to a textile support, one could then realize the impression of one or more motive (s) or decor (s) by transfer printing or rotogravure printing techniques, especially using acrylic type ink and / or polyurethane possibly modified.
  • the coating layer comprises, in addition to the epichlorohydrin component mentioned various additives known per se for modifying / improving the properties mechanical resistance to light, heat, etc. such as plasticizers, fillers, U.V stabilizers or heat, vulcanizing agent.
  • the above-mentioned coating composition is applied to the textile support by calendering.
  • Printing can be done by transfer.
  • the pattern (s) are previously made on a transfer paper by techniques preparatory measures known per se.
  • the printed paper is then assembled to the pressure-coated textile and to hot.
  • the temperature is usually 100 ° C and the pressure of 1 bar.
  • the printing can also be done by gravure printing.
  • the coated textile is printed by passing between rollers metal with the pattern (s) engraved (s) and inked (s).
  • the printed coated textile according to the invention has in particular a flexibility and good resistance to aging, bad weather, U.V.
  • the printed coated textile according to the invention has good liquid impermeability characteristics.
  • the invention also relates to articles comprising a coated textile printed as defined above and applies more particularly to the manufacture of printed coated tablecloths or other articles for use in Table.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

Printed textile product comprises a textile substrate with a coating of vulcanized epichlorohydrin elastomer, the coating being printed on the side not bonded to the substrate. An Independent claim is also included for a process for producing the printed textile product, comprising coating the substrate with the elastomer, printing designs on the coating, vulcanizing the elastomer and optionally applying a protective varnish.

Description

La présente invention concerne des textiles enduits imprimés dans lesquels la couche d'enduction est à base d'élastomère d'épichlorhydrine ainsi qu'un procédé pour leur préparation.The present invention relates to coated textiles printed in which the coating layer is based on epichlorohydrin elastomer as well as as a process for their preparation.

Les tissus enduits imprimés disponibles actuellement, par exemple pour la réalisation de nappes ou autres articles du domaine de l'art de la table, présentent généralement une couche d'enduction PVC (polychlorure de vinyle) et/ou de polymères halogénés en particulier de polymères fluorés.The printed coated fabrics currently available, for example for the production of tablecloths or other articles in the field of table art, generally have a coating layer PVC (polyvinyl chloride) and / or halogenated polymers, in particular fluoropolymers.

Ces tissus enduits ne sont néanmoins pas très souples et présentent une résistance au vieillissement insuffisante en devenant raides et cassants mais aussi collants au toucher. Ils ont notamment une très mauvaise résistance aux intempéries et aux rayons ultra-violets.These coated fabrics are nevertheless not very flexible and have a insufficient resistance to aging by becoming stiff and brittle but as sticky to the touch. In particular, they have very bad resistance to bad weather and ultraviolet rays.

Par ailleurs, ces tissus résistent mal aux taches alimentaires qui restent de plus en plus marquées au fil du temps et deviennent de plus en plus difficiles à retirer. Parallèlement, ils peuvent perdre leurs couleurs ou leurs motifs d'impression, notamment au fur et à mesure des nettoyages ou sous l'effet de la lumière, ou encore donner lieu à un jaunissement.In addition, these fabrics are poorly resistant to food stains that remain more and more marked over time and become more and more difficult to remove. At the same time, they may lose their colors or printing patterns, especially as and when cleaning or under the effect of light, or give rise to yellowing.

Les tissus enduits PVC possèdent en outre une mauvaise résistance à la chaleur de sorte qu'ils se trouvent abímés, par exemple par la pose de plats chauds.PVC coated fabrics also have poor resistance to heat so that they are damaged, for example by the laying of dishes hot.

L'objectif de la présente invention est de fournir des textiles enduits pouvant présenter des motifs ou décors imprimés, utilisables notamment dans le domaine de l'art de la table, et ne présentant pas les inconvénients mentionnés ci-dessus.The object of the present invention is to provide coated textiles may have printed patterns or decorations, which may be used in particular in the field of the art of the table, and not presenting the disadvantages mentioned above.

Un autre objectif de l'invention est de fournir des textiles enduits particulièrement souples et conservant leur souplesse lors de leur utilisation ou de leur stockage, ainsi que lors de leurs nettoyages successifs.Another object of the invention is to provide coated textiles particularly flexible and retain their flexibility during their use or their storage, as well as during their successive cleanings.

Un autre objectif de l'invention est encore de fournir un textile enduit présentant des caractéristiques « d'imprimabilité » satisfaisantes permettant en particulier l'impression de motifs ou décors placés résistant au vieillissement en particulier dans le temps, vis-à-vis des rayons lumineux, des nettoyages, de la chaleur, etc...Another object of the invention is still to provide a coated textile satisfactory 'printability' characteristics allowing particular the impression of patterns or decorations placed resistant to aging in particularly in time, with regard to light rays, cleaning, heat, etc ...

Un autre objectif de l'invention est aussi de fournir un procédé pour la production de tels textiles enduits imprimés qui soit simple et peu coûteux. Another object of the invention is also to provide a method for production of such printed coated textiles which is simple and inexpensive.

A cette fin, l'invention a pour objet un textile enduit à motifs imprimés, caractérisé en ce qu'il comprend une sous-couche textile formant support associée à une couche d'enduction à base d'élastomère d'épichlorhydrine vulcanisé, ladite couche d'enduction présentant un ou plusieurs motif(s) imprimé(s) sur sa surface non liée à la sous-couche textile.For this purpose, the subject of the invention is a coated textile with printed patterns, characterized in that it comprises a textile sub-layer forming a support associated with a coating layer based on elastomeric epichlorohydrin vulcanized, said coating layer having one or more pattern (s) printed on its surface not bound to the textile underlayment.

L'invention fournit également un procédé pour la préparation du textile enduit imprimé ci-dessus, caractérisé en ce que :

  • on prend un textile formant support,
  • on dépose sur ledit textile support une couche d'enduction à base d'épichlorhydrine,
  • on imprime le ou les motif(s) ou décor(s) désiré(s),
  • on vulcanise l'ensemble résultant, et
  • on dépose éventuellement un vernis de protection.
The invention also provides a process for the preparation of the coated textile printed above, characterized in that:
  • we take a textile forming a support,
  • depositing on said support fabric a coating layer based on epichlorohydrin,
  • we print the desired pattern (s) or decor (s),
  • vulcanizing the resulting assembly, and
  • a protective varnish is optionally deposited.

Le textile enduit imprimé selon l'invention est décrit plus en détail ci-après.The printed coated textile according to the invention is described in more detail below.

Selon l'invention, par « imprimé » on entend l'application de motifs ou décors à la surface de la couche d'enduction du textile enduit, de manière discontinue et variée, généralement à l'aide d'encres de type acrylique et/ou polyuréthane modifié ?, par opposition à une coloration homogène dans la masse conduisant à des matériaux colorés de façon relativement uniforme.According to the invention, by "printed" is meant the application of patterns or decorations on the surface of the coating layer of the coated textile, so discontinuous and varied, usually using acrylic type inks and / or modified polyurethane, as opposed to homogeneous coloration in the mass leading to relatively uniformly colored materials.

Les inventeurs ont découvert de manière tout à fait surprenante qu'en appliquant une enduction à base d'élastomère d'épichlorhydrine sur un textile support, on pouvait alors réaliser l'impression d'un ou plusieurs motif(s) ou décor(s) par les techniques d'impression par transfert ou par héliogravure, notamment à l'aide d'encre de type acrylique et/ou polyuréthane éventuellement modifié.The inventors have discovered quite surprisingly that applying an epichlorohydrin elastomer coating to a textile support, one could then realize the impression of one or more motive (s) or decor (s) by transfer printing or rotogravure printing techniques, especially using acrylic type ink and / or polyurethane possibly modified.

La couche d'enduction comprend, outre le composant épichlorhydrine précité, divers additifs connus en soi pour modifier / améliorer les propriétés mécaniques, la résistance à la lumière, à la chaleur, etc. tels que des plastifiants, charges, stabilisants U.V. ou chaleur, agent de vulcanisation.The coating layer comprises, in addition to the epichlorohydrin component mentioned various additives known per se for modifying / improving the properties mechanical resistance to light, heat, etc. such as plasticizers, fillers, U.V stabilizers or heat, vulcanizing agent.

La composition de la couche d'enduction est typiquement telle que définie ci-dessous :

  • Epichlorhydrine   100 parties en poids
  • Copolymère Ethylène-Vinyl-Acétate (EVA)   5 à 30 parties en poids
  • Charges   30 à 80 parties en poids
  • Plastifiants   5 à 15 parties en poids
  • Stabilisants U.V. et chaleur   1 à 3 parties en poids
  • Agent de vulcanisation   1 à 6 parties en poids
  • Colorants   10 à 40 parties en poids
The composition of the coating layer is typically as defined below:
  • Epichlorohydrin 100 parts by weight
  • Ethylene-Vinyl-Acetate Copolymer (EVA) 5 to 30 parts by weight
  • Charges 30 to 80 parts by weight
  • Plasticizers 5 to 15 parts by weight
  • UV stabilizers and heat 1 to 3 parts by weight
  • Vulcanizing agent 1 to 6 parts by weight
  • Dyes 10 to 40 parts by weight

La couche textile formant support peut comprendre ou être constituée d'un tissu, d'un non-tissé ou d'une maille, le tissu ou le non-tissé étant préférés. Il peut s'agir indifféremment de textile naturel, artificiel ou synthétique.The textile layer forming a support may comprise or consist of of a fabric, a nonwoven or a mesh, the fabric or nonwoven being preferred. It can be indifferently natural textile, artificial or synthetic.

La composition d'enduction précitée est appliquée sur le support textile par calandrage.The above-mentioned coating composition is applied to the textile support by calendering.

On réalise ensuite l'impression proprement dite d'un ou plusieurs motif(s) ou décor(s) souhaité(s) sur le textile enduit résultant.The actual printing of one or more pattern (s) is then carried out or desired decoration (s) on the resulting coated textile.

A cet effet, on peut mettre en oeuvre deux méthodes :For this purpose, two methods can be implemented:

L'impression peut être effectuée par transfert. Dans ce cas, le ou les motif(s) sont préalablement réalisés sur un papier transfert par des techniques préparatoires connues en soi.Printing can be done by transfer. In this case, the pattern (s) are previously made on a transfer paper by techniques preparatory measures known per se.

Le papier imprimé est alors assemblé au textile enduit sous pression et à chaud. La température est généralement de 100°C et la pression de 1 bar.The printed paper is then assembled to the pressure-coated textile and to hot. The temperature is usually 100 ° C and the pressure of 1 bar.

Le ou les motif(s) à imprimer sont mis en contact avec la couche d'enduction et le papier est enlevé après refroidissement de l'ensemble.The pattern (s) to be printed are put in contact with the layer coating and the paper is removed after cooling the assembly.

L'impression peut être également réalisée par héliogravure.The printing can also be done by gravure printing.

Dans ce cas, le textile enduit est imprimé par passage entre des rouleaux métalliques portant le ou les motif(s) gravé(s) en creux et encré(s).In this case, the coated textile is printed by passing between rollers metal with the pattern (s) engraved (s) and inked (s).

Le textile enduit imprimé résultant de l'une ou l'autre de ces opérations est ensuite vulcanisé. Selon les cas, cette étape de vulcanisation peut être réalisée à chaud en continu ou en discontinu, éventuellement sous pression.The printed coated textile resulting from one or other of these operations is then vulcanized. Depending on the case, this vulcanization step can be carried out hot continuously or discontinuously, possibly under pressure.

Le textile enduit imprimé final peut ensuite être protégé par un vernis, notamment de type acrylique. Selon l'effet désiré, le vernis de protection peut être incolore ou coloré mais translucide pour laisser apparaítre le ou les motif(s) imprimé(s). Il peut s'agir en particulier d'un vernis à propriétés anti-taches alimentaires.The final printed coated textile can then be protected by a varnish, especially acrylic type. Depending on the desired effect, the protective varnish may be colorless or colored but translucent to reveal the pattern (s) printed. It may be in particular a varnish with anti-stain properties food.

Le textile enduit imprimé selon l'invention présente notamment une grande souplesse ainsi qu'une bonne résistance au vieillissement, aux intempéries, aux rayons U.V.The printed coated textile according to the invention has in particular a flexibility and good resistance to aging, bad weather, U.V.

Il est facilement nettoyable et les impressions appliquées présentent une bonne adhérence au support textile et une bonne résistance dans le temps, notamment lors d'intempéries, des lavages successifs.It is easy to clean and the applied prints are good adhesion to textile support and good resistance over time, especially during bad weather, successive washings.

Il présente par ailleurs une bonne résistance à la chaleur et supporte ainsi le contact avec des plats chauds par exemple.It also has good resistance to heat and thus supports contact with hot dishes for example.

De plus, on n'observe pas d'apparition de toucher collant à mesure de son utilisation.In addition, there is no appearance of sticky touch as its use.

Le textile enduit imprimé conforme à l'invention présente de bonnes caractéristiques d'imperméabilité aux liquides.The printed coated textile according to the invention has good liquid impermeability characteristics.

L'invention concerne aussi des articles comprenant un textile enduit imprimé tel que défini ci-dessus et s'applique plus particulièrement à la fabrication de nappes enduites imprimées ou autres articles destinés à l'art de la table.The invention also relates to articles comprising a coated textile printed as defined above and applies more particularly to the manufacture of printed coated tablecloths or other articles for use in Table.

L'invention va maintenant être illustrée à l'aide d'un exemple qui ne doit pas être considéré comme limitatif.The invention will now be illustrated with the aid of an example which not be considered as limiting.

EXEMPLEEXAMPLE

Les différentes phases de production d'une nappe enduite imprimée sont les suivantes :

  • 1) Utilisation d'un support coton-polyester 75/25 ; poids 75 g/m2.
  • 2) Calandrage sur le support d'un film d'élastomère de 180 g/m2 - température de calandrage 100°C. Composition d'enduction utilisée :
    • Epichlorhydrine   100 parties en poids
    • Ethylène Vinyl Acétate (EVA)   20 parties en poids
    • Oxyde zinc   10 parties en poids
    • Magnésie   10 parties en poids
    • Acide stéarique   5 parties en poids
    • Silice   20 parties en poids
    • Craie   20 parties en poids
    • Dioctyl Phtalate (DOP)   11 parties en poids
    • Oxyde titane   35 parties en poids
    • Anti UV   2 parties en poids
    • Agents de vulcanisation   5,7 parties en poids
    Poudrage de l'enduction à l'aide de stéarate de calcium.
  • 3) Impression Utilisation d'un papier transfert imprimé.Doublage à 100°C et sous pression du papier transfert avec le tissu calandré.L'impression est en contact avec l'élastomère.
  • 4) Vernissage Vernissage par héliogravure à l'aide d'un vernis à base de résines acryliques modifiées-polyuréthane pour rendre l'article anti-tache.Dépôt de 20 g/m2 humide d'une solution à 15% d'extrait sec.Séchage à environ 80°C.
  • 5) Vulcanisation Vulcanisation en continu dans un tunnel.Vitesse 5 mètres par minute.Température du tunnel 180°C.
    • The different production phases of a printed coated sheet are the following:
  • 1) Use of a 75/25 cotton-polyester support; weight 75 g / m 2 .
  • 2) Calendering on the support of an elastomer film of 180 g / m 2 - calender temperature 100 ° C. Coating composition used:
    • Epichlorohydrin 100 parts by weight
    • Ethylene Vinyl Acetate (EVA) 20 parts by weight
    • Zinc oxide 10 parts by weight
    • Magnesia 10 parts by weight
    • Stearic acid 5 parts by weight
    • Silica 20 parts by weight
    • Chalk 20 parts by weight
    • Dioctyl Phthalate (DOP) 11 parts by weight
    • Titanium oxide 35 parts by weight
    • UV protection 2 parts by weight
    • Vulcanizing agents 5.7 parts by weight
    Powder coating with calcium stearate.
  • 3) Printing Using a printed transfer paper. Blotting at 100 ° C and pressurizing the transfer paper with the calendered fabric. The printing is in contact with the elastomer.
  • 4) Varnishing Rotogravure painting using a varnish based on modified acrylic-polyurethane resins to make the anti-stain article. 20 g / m 2 wet deposit of a 15% solids solution Drying at about 80 ° C.
  • 5) Vulcanization Continuous vulcanization in a tunnel. Speed 5 meters per minute. Tunnel temperature 180 ° C.

    • Claims (12)

    1. Coated textile having printed patterns, characterized in that it comprises a textile sub-layer forming a support associated with a layer of coating based on vulcanised epichlorhydrin elastomer, the said coating layer having one or more printed patterns on its surface not bound to the textile sub-layer.
    2. Coated textile having printed patterns according to claim 1, characterized in that textile sub-layer comprises or consists of a woven textile, a non-woven textile or a mesh, preferably a woven textile or a non-woven textile.
    3. Coated textile having printed patterns according to claims 1 or 2, characterized in that it is provided with a protective varnish applied over the printed coating layer, preferably a protective varnish with stain-resistant properties.
    4. Method for preparing a coated textile having printed patterns according to any one of claims 1 to 3, characterized in that:
      a textile is taken forming a support,
      a coating layer based on epichlorhydrin is deposited on the said textile support,
      the desired pattern(s) or design(s) is/are printed,
      the resulting assembly is vulcanised, and
      a protective varnish is applied as required.
    5. Method according to claim 4, characterized in that the textile forming a support comprises or consists of a woven textile, a non-woven textile or a mesh, preferably a woven textile or a non-woven textile.
    6. Method according to claim 4 or 5, characterized in that the composition of the coating layer is as following :
      Epichlorhydrin   100 parts by weight
      Ethylene-vinyl acetate copolymer   5 to 30 parts by weight
      Fillers   30 to 80 parts by weight
      Plasticisers   5 to 15 parts by weight
      UV and heat stabilisers   1 to 3 parts by weight
      Vulcanising agent   1 to 6 parts by weight
      Colouring agents   10 to 40 parts by weight
    7. Method according to any one of claims 4 to 6, characterized in that the coating layer is applied by calendering onto the textile support.
    8. Method according to any one of claims 4 to 7, characterized in that the pattern(s) or design(s) is/are transfer-printed.
    9. Method according to any one of claims 4 to 7, characterized in that the pattern(s) or design(s) is/are printed by photogravure.
    10. Method according to claim 8 or 9, characterized in that printing is carried out with the aid of inks of the acrylic and/or polyurethane type, modified as required.
    11. Articles comprising a coated textile having printed patterns according to any one of claims 1 to 10.
    12. Articles according to claim 11, characterized in that they consist of cloths.
    EP01400070A 2000-01-12 2001-01-11 Textile coated with epichlorohydrin rubber and printed Expired - Lifetime EP1116815B1 (en)

    Priority Applications (1)

    Application Number Priority Date Filing Date Title
    SI200130319T SI1116815T1 (en) 2000-01-12 2001-01-11 Textile coated with epichlorohydrin rubber and printed

    Applications Claiming Priority (2)

    Application Number Priority Date Filing Date Title
    FR0000358 2000-01-12
    FR0000358A FR2803607B1 (en) 2000-01-12 2000-01-12 PRINTED COATED TEXTILE BASED ON EPICHLORHYDRIN ELASTOMER

    Publications (2)

    Publication Number Publication Date
    EP1116815A1 EP1116815A1 (en) 2001-07-18
    EP1116815B1 true EP1116815B1 (en) 2005-03-02

    Family

    ID=8845843

    Family Applications (1)

    Application Number Title Priority Date Filing Date
    EP01400070A Expired - Lifetime EP1116815B1 (en) 2000-01-12 2001-01-11 Textile coated with epichlorohydrin rubber and printed

    Country Status (8)

    Country Link
    EP (1) EP1116815B1 (en)
    AT (1) ATE290118T1 (en)
    DE (1) DE60109070T2 (en)
    DK (1) DK1116815T3 (en)
    ES (1) ES2234784T3 (en)
    FR (1) FR2803607B1 (en)
    PT (1) PT1116815E (en)
    SI (1) SI1116815T1 (en)

    Family Cites Families (1)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    FR2702416B1 (en) * 1993-03-10 1995-06-09 Lecomte Roger PRINTED MATERIAL BASED ON PVC AND MANUFACTURING METHOD THEREOF.

    Also Published As

    Publication number Publication date
    DE60109070D1 (en) 2005-04-07
    SI1116815T1 (en) 2005-06-30
    FR2803607A1 (en) 2001-07-13
    EP1116815A1 (en) 2001-07-18
    DE60109070T2 (en) 2005-07-21
    ATE290118T1 (en) 2005-03-15
    PT1116815E (en) 2005-05-31
    ES2234784T3 (en) 2005-07-01
    FR2803607B1 (en) 2002-04-05
    DK1116815T3 (en) 2005-05-17

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