EP1116815A1 - Textile coated with epichlorohydrin rubber and printed - Google Patents

Textile coated with epichlorohydrin rubber and printed Download PDF

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Publication number
EP1116815A1
EP1116815A1 EP01400070A EP01400070A EP1116815A1 EP 1116815 A1 EP1116815 A1 EP 1116815A1 EP 01400070 A EP01400070 A EP 01400070A EP 01400070 A EP01400070 A EP 01400070A EP 1116815 A1 EP1116815 A1 EP 1116815A1
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EP
European Patent Office
Prior art keywords
textile
parts
printed
coated
coating layer
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Granted
Application number
EP01400070A
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German (de)
French (fr)
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EP1116815B1 (en
Inventor
Guy Bauts
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Venilia Sas
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Pennel Industries SAS
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Priority to SI200130319T priority Critical patent/SI1116815T1/en
Publication of EP1116815A1 publication Critical patent/EP1116815A1/en
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Publication of EP1116815B1 publication Critical patent/EP1116815B1/en
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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins

Definitions

  • the present invention relates to coated textiles printed in which the coating layer is based on epichlorohydrin elastomer as well than a process for their preparation.
  • Printed coated fabrics currently available, for example for the production of tablecloths or other articles in the field of tableware, usually have a PVC (polyvinyl chloride) coating layer and / or halogenated polymers, in particular fluoropolymers.
  • PVC polyvinyl chloride
  • coated fabrics are however not very flexible and have a insufficient aging resistance by becoming stiff and brittle but also sticky to the touch. In particular, they have very poor resistance to bad weather and ultra-violet rays.
  • these fabrics have poor resistance to food stains that remain more and more marked over time and become more and more difficult to remove. At the same time, they may lose their colors or print patterns, especially as and when cleaning or the effect of light, or give rise to yellowing.
  • PVC coated fabrics also have poor resistance to heat so that they are damaged, for example by laying dishes hot.
  • the objective of the present invention is to provide coated textiles may have printed patterns or decorations, usable in particular in the field of tableware, and not having the drawbacks mentioned above.
  • Another object of the invention is to provide coated textiles particularly flexible and retaining their flexibility during use or during their storage, as well as during their successive cleaning.
  • Another objective of the invention is also to provide a coated textile having satisfactory "printability" characteristics allowing particularly the printing of patterns or decorations placed resistant to aging in particular over time, with regard to light rays, cleaning, heat, etc ...
  • Another object of the invention is also to provide a method for the production of such printed coated textiles which is simple and inexpensive.
  • the invention relates to a coated textile with printed patterns, characterized in that it comprises a textile underlay forming a support associated with a coating layer based on epichlorohydrin elastomer vulcanized, said coating layer having one or more pattern (s) imprint (s) on its surface not linked to the textile underlay.
  • coated textile printed according to the invention is described in more detail below.
  • printed means the application of patterns or decorations on the surface of the coating layer of the coated textile, so discontinuous and varied, generally using acrylic type inks and / or modified polyurethane? as opposed to homogeneous coloring in the mass leading to relatively uniformly colored materials.
  • the inventors have discovered quite surprisingly that applying a coating based on epichlorohydrin elastomer on a textile support, you could then print one or more motif (s) or decor (s) using transfer or rotogravure printing techniques, in particular using acrylic and / or polyurethane ink possibly modified.
  • the coating layer comprises, in addition to the epichlorohydrin component above, various additives known per se for modifying / improving the properties mechanical, resistance to light, heat, etc. such as plasticizers, fillers, UV or heat stabilizers, vulcanizing agent.
  • the textile layer forming a support may comprise or be made up a fabric, nonwoven or mesh, the fabric or nonwoven being favorite. It can be either natural, artificial or synthetic textile.
  • the aforementioned coating composition is applied to the textile support by calendering.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Laminated Bodies (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

Printed textile product comprises a textile substrate with a coating of vulcanized epichlorohydrin elastomer, the coating being printed on the side not bonded to the substrate. An Independent claim is also included for a process for producing the printed textile product, comprising coating the substrate with the elastomer, printing designs on the coating, vulcanizing the elastomer and optionally applying a protective varnish.

Description

La présente invention concerne des textiles enduits imprimés dans lesquels la couche d'enduction est à base d'élastomère d'épichlorhydrine ainsi qu'un procédé pour leur préparation.The present invention relates to coated textiles printed in which the coating layer is based on epichlorohydrin elastomer as well than a process for their preparation.

Les tissus enduits imprimés disponibles actuellement, par exemple pour la réalisation de nappes ou autres articles du domaine de l'art de la table, présentent généralement une couche d'enduction PVC (polychlorure de vinyle) et/ou de polymères halogénés en particulier de polymères fluorés.Printed coated fabrics currently available, for example for the production of tablecloths or other articles in the field of tableware, usually have a PVC (polyvinyl chloride) coating layer and / or halogenated polymers, in particular fluoropolymers.

Ces tissus enduits ne sont néanmoins pas très souples et présentent une résistance au vieillissement insuffisante en devenant raides et cassants mais aussi collants au toucher. Ils ont notamment une très mauvaise résistance aux intempéries et aux rayons ultra-violets.These coated fabrics are however not very flexible and have a insufficient aging resistance by becoming stiff and brittle but also sticky to the touch. In particular, they have very poor resistance to bad weather and ultra-violet rays.

Par ailleurs, ces tissus résistent mal aux taches alimentaires qui restent de plus en plus marquées au fil du temps et deviennent de plus en plus difficiles à retirer. Parallèlement, ils peuvent perdre leurs couleurs ou leurs motifs d'impression, notamment au fur et à mesure des nettoyages ou sous l'effet de la lumière, ou encore donner lieu à un jaunissement.Furthermore, these fabrics have poor resistance to food stains that remain more and more marked over time and become more and more difficult to remove. At the same time, they may lose their colors or print patterns, especially as and when cleaning or the effect of light, or give rise to yellowing.

Les tissus enduits PVC possèdent en outre une mauvaise résistance à la chaleur de sorte qu'ils se trouvent abímés, par exemple par la pose de plats chauds.PVC coated fabrics also have poor resistance to heat so that they are damaged, for example by laying dishes hot.

L'objectif de la présente invention est de fournir des textiles enduits pouvant présenter des motifs ou décors imprimés, utilisables notamment dans le domaine de l'art de la table, et ne présentant pas les inconvénients mentionnés ci-dessus.The objective of the present invention is to provide coated textiles may have printed patterns or decorations, usable in particular in the field of tableware, and not having the drawbacks mentioned above.

Un autre objectif de l'invention est de fournir des textiles enduits particulièrement souples et conservant leur souplesse lors de leur utilisation ou de leur stockage, ainsi que lors de leurs nettoyages successifs.Another object of the invention is to provide coated textiles particularly flexible and retaining their flexibility during use or during their storage, as well as during their successive cleaning.

Un autre objectif de l'invention est encore de fournir un textile enduit présentant des caractéristiques « d'imprimabilité » satisfaisantes permettant en particulier l'impression de motifs ou décors placés résistant au vieillissement en particulier dans le temps, vis-à-vis des rayons lumineux, des nettoyages, de la chaleur, etc...Another objective of the invention is also to provide a coated textile having satisfactory "printability" characteristics allowing particularly the printing of patterns or decorations placed resistant to aging in particular over time, with regard to light rays, cleaning, heat, etc ...

Un autre objectif de l'invention est aussi de fournir un procédé pour la production de tels textiles enduits imprimés qui soit simple et peu coûteux. Another object of the invention is also to provide a method for the production of such printed coated textiles which is simple and inexpensive.

A cette fin, l'invention a pour objet un textile enduit à motifs imprimés, caractérisé en ce qu'il comprend une sous-couche textile formant support associée à une couche d'enduction à base d'élastomère d'épichlorhydrine vulcanisé, ladite couche d'enduction présentant un ou plusieurs motif(s) imprimé(s) sur sa surface non liée à la sous-couche textile.To this end, the invention relates to a coated textile with printed patterns, characterized in that it comprises a textile underlay forming a support associated with a coating layer based on epichlorohydrin elastomer vulcanized, said coating layer having one or more pattern (s) imprint (s) on its surface not linked to the textile underlay.

L'invention fournit également un procédé pour la préparation du textile enduit imprimé ci-dessus, caractérisé en ce que :

  • on prend un textile formant support,
  • on dépose sur ledit textile support une couche d'enduction à base d'épichlorhydrine,
  • on imprime le ou les motif(s) ou décor(s) désiré(s),
  • on vulcanise l'ensemble résultant, et
  • on dépose éventuellement un vernis de protection.
The invention also provides a process for the preparation of the coated textile printed above, characterized in that:
  • we take a textile forming a support,
  • a coating layer based on epichlorohydrin is deposited on said textile support,
  • we print the desired motif (s) or decor (s),
  • we vulcanize the resulting assembly, and
  • a protective varnish may be deposited.

Le textile enduit imprimé selon l'invention est décrit plus en détail ci-après.The coated textile printed according to the invention is described in more detail below.

Selon l'invention, par « imprimé» on entend l'application de motifs ou décors à la surface de la couche d'enduction du textile enduit, de manière discontinue et variée, généralement à l'aide d'encres de type acrylique et/ou polyuréthane modifié ?, par opposition à une coloration homogène dans la masse conduisant à des matériaux colorés de façon relativement uniforme.According to the invention, by "printed" means the application of patterns or decorations on the surface of the coating layer of the coated textile, so discontinuous and varied, generally using acrylic type inks and / or modified polyurethane? as opposed to homogeneous coloring in the mass leading to relatively uniformly colored materials.

Les inventeurs ont découvert de manière tout à fait surprenante qu'en appliquant une enduction à base d'élastomère d'épichlorhydrine sur un textile support, on pouvait alors réaliser l'impression d'un ou plusieurs motif(s) ou décor(s) par les techniques d'impression par transfert ou par héliogravure, notamment à l'aide d'encre de type acrylique et/ou polyuréthane éventuellement modifié.The inventors have discovered quite surprisingly that applying a coating based on epichlorohydrin elastomer on a textile support, you could then print one or more motif (s) or decor (s) using transfer or rotogravure printing techniques, in particular using acrylic and / or polyurethane ink possibly modified.

La couche d'enduction comprend, outre le composant épichlorhydrine précité, divers additifs connus en soi pour modifier / améliorer les propriétés mécaniques, la résistance à la lumière, à la chaleur, etc. tels que des plastifiants, charges, stabilisants U.V. ou chaleur, agent de vulcanisation.The coating layer comprises, in addition to the epichlorohydrin component above, various additives known per se for modifying / improving the properties mechanical, resistance to light, heat, etc. such as plasticizers, fillers, UV or heat stabilizers, vulcanizing agent.

La composition de la couche d'enduction est typiquement telle que définie ci-dessous :

  • Epichlorhydrine   100 parties en poids
  • Copolymère Ethylène-Vinyl-Acétate (EVA)   5 à 30 parties en poids
  • Charges   30 à 80 parties en poids
  • Plastifiants   5 à 15 parties en poids
  • Stabilisants U.V. et chaleur   1 à 3 parties en poids
  • Agent de vulcanisation   1 à 6 parties en poids
  • Colorants   10 à 40 parties en poids
The composition of the coating layer is typically as defined below:
  • Epichlorohydrin 100 parts by weight
  • Ethylene-Vinyl-Acetate Copolymer (EVA) 5 to 30 parts by weight
  • Loads 30 to 80 parts by weight
  • Plasticizers 5 to 15 parts by weight
  • UV and heat stabilizers 1 to 3 parts by weight
  • Vulcanizing agent 1 to 6 parts by weight
  • Dyes 10 to 40 parts by weight

La couche textile formant support peut comprendre ou être constituée d'un tissu, d'un non-tissé ou d'une maille, le tissu ou le non-tissé étant préférés. Il peut s'agir indifféremment de textile naturel, artificiel ou synthétique.The textile layer forming a support may comprise or be made up a fabric, nonwoven or mesh, the fabric or nonwoven being favorite. It can be either natural, artificial or synthetic textile.

La composition d'enduction précitée est appliquée sur le support textile par calandrage.The aforementioned coating composition is applied to the textile support by calendering.

On réalise ensuite l'impression proprement dite d'un ou plusieurs motif(s) ou décor(s) souhaité(s) sur le textile enduit résultant.We then carry out the actual printing of one or more motif (s) or desired decor (s) on the resulting coated textile.

A cet effet, on peut mettre en oeuvre deux méthodes :

  • L'impression peut être effectuée par transfert. Dans ce cas, le ou les motif(s) sont préalablement réalisés sur un papier transfert par des techniques préparatoires connues en soi.
  • Le papier imprimé est alors assemblé au textile enduit sous pression et à chaud. La température est généralement de l'ordre de 100°C et la pression de l'ordre de 1 bar.
  • Le ou les motif(s) à imprimer sont mis en contact avec la couche d'enduction et le papier est enlevé après refroidissement de l'ensemble.
  • L'impression peut être également réalisée par héliogravure.
  • Dans ce cas, le textile enduit est imprimé par passage entre des rouleaux métalliques portant le ou les motif(s) gravé(s) en creux et encré(s).
  • Le textile enduit imprimé résultant de l'une ou l'autre de ces opérations est ensuite vulcanisé. Selon les cas, cette étape de vulcanisation peut être réalisée à chaud en continu ou en discontinu, éventuellement sous pression.
  • Le textile enduit imprimé final peut ensuite être protégé par un vernis, notamment de type acrylique. Selon l'effet désiré, le vernis de protection peut être incolore ou coloré mais translucide pour laisser apparaítre le ou les motif(s) imprimé(s). Il peut s'agir en particulier d'un vernis à propriétés anti-taches alimentaires.
  • Le textile enduit imprimé selon l'invention présente notamment une grande souplesse ainsi qu'une bonne résistance au vieillissement, aux intempéries, aux rayons U.V.
  • Il est facilement nettoyable et les impressions appliquées présentent une bonne adhérence au support textile et une bonne résistance dans le temps, notamment lors d'intempéries, des lavages successifs.
  • Il présente par ailleurs une bonne résistance à la chaleur et supporte ainsi le contact avec des plats chauds par exemple.
  • De plus, on n'observe pas d'apparition de toucher collant à mesure de son utilisation.
  • Le textile enduit imprimé conforme à l'invention présente de bonnes caractéristiques d'imperméabilité aux liquides.
  • L'invention concerne aussi des articles comprenant un textile enduit imprimé tel que défini ci-dessus et s'applique plus particulièrement à la fabrication de nappes enduites imprimées ou autres articles destinés à l'art de la table.
  • L'invention va maintenant être illustrée à l'aide d'un exemple qui ne doit pas être considéré comme limitatif.
    • Two methods can be used for this purpose:
  • Printing can be done by transfer. In this case, the pattern (s) are previously produced on transfer paper by preparatory techniques known per se.
  • The printed paper is then assembled to the textile coated under pressure and hot. The temperature is generally around 100 ° C and the pressure around 1 bar.
  • The pattern (s) to be printed are brought into contact with the coating layer and the paper is removed after the assembly has cooled.
  • Printing can also be done by gravure printing.
  • In this case, the coated textile is printed by passing between metal rollers carrying the pattern (s) etched (intaglio) and inked (s).
  • The printed coated textile resulting from one or other of these operations is then vulcanized. Depending on the case, this vulcanization step can be carried out hot continuously or discontinuously, possibly under pressure.
  • The final printed coated textile can then be protected by a varnish, in particular of acrylic type. Depending on the desired effect, the protective varnish can be colorless or colored but translucent to allow the printed pattern (s) to appear. It can in particular be a varnish with anti-food stain properties.
  • The coated textile printed according to the invention has in particular great flexibility as well as good resistance to aging, weathering, UV rays.
  • It is easy to clean and the applied prints have good adhesion to the textile support and good resistance over time, especially during bad weather, successive washings.
  • It also has good heat resistance and thus withstands contact with hot dishes for example.
  • In addition, no appearance of sticky feel is observed as it is used.
  • The coated printed textile according to the invention has good liquid impermeability characteristics.
  • The invention also relates to articles comprising a printed coated textile as defined above and applies more particularly to the manufacture of printed coated tablecloths or other articles intended for tableware.
  • The invention will now be illustrated by means of an example which should not be considered as limiting.

    • EXEMPLEEXAMPLE

    Les différentes phases de production d'une nappe enduite imprimée sont les suivantes :

  • 1) Utilisation d'un support coton-polyester 75/25 ; poids 75 g/m2.
  • 2) Calandrage sur le support d'un film d'élastomère de 180 g/m2 - température de calandrage 100°C.
    Composition d'enduction utilisée :
    • Epichlorhydrine   100 parties en poids
    • Ethylène Vinyl Acétate (EVA)   20 parties en poids
    • Oxyde zinc   10 parties en poids
    • Magnésie   10 parties en poids
    • Acide stéarique   5 parties en poids
    • Silice   20 parties en poids
    • Craie   20 parties en poids
    • Dioctyl Phtalate (DOP)   11 parties en poids
    • Oxyde titane   35 parties en poids
    • Anti UV   2 parties en poids
    • Agents de vulcanisation   5,7 parties en poids
    Poudrage de l'enduction à l'aide de stéarate de calcium.
  • 3) Impression Utilisation d'un papier transfert imprimé.Doublage à 100°C et sous pression du papier transfert avec le tissu calandré.L'impression est en contact avec l'élastomère.
  • 4) Vernissage Vernissage par héliogravure à l'aide d'un vernis à base de résines acryliques modifiées-polyuréthane pour rendre l'article anti-tache.Dépôt de 20 g/m2 humide d'une solution à 15% d'extrait sec.Séchage à environ 80°C.
  • 5) Vulcanisation Vulcanisation en continu dans un tunnel.Vitesse 5 mètres par minute.Température du tunnel 180°C.
    • The different production phases of a printed coated tablecloth are as follows:
  • 1) Use of a 75/25 cotton-polyester support; weight 75 g / m 2 .
  • 2) Calendering on the support of an elastomer film of 180 g / m 2 - calendering temperature 100 ° C.
    Coating composition used:
    • Epichlorohydrin 100 parts by weight
    • Ethylene Vinyl Acetate (EVA) 20 parts by weight
    • Zinc oxide 10 parts by weight
    • Magnesia 10 parts by weight
    • Stearic acid 5 parts by weight
    • Silica 20 parts by weight
    • Chalk 20 parts by weight
    • Dioctyl Phthalate (DOP) 11 parts by weight
    • Titanium oxide 35 parts by weight
    • Anti UV 2 parts by weight
    • Vulcanizing agents 5.7 parts by weight
    Powder coating with calcium stearate.
  • 3) Printing Use of a printed transfer paper. Doubling at 100 ° C and under pressure of the transfer paper with the calendered fabric. The printing is in contact with the elastomer.
  • 4) Varnishing Varnishing by rotogravure using a varnish based on modified polyurethane acrylic resins to make the article stain-resistant. Deposit of 20 g / m 2 wet with a 15% solution of dry extract Drying at around 80 ° C.
  • 5) Vulcanization Continuous vulcanization in a tunnel. Speed 5 meters per minute. Tunnel temperature 180 ° C.

    • Claims (12)

    Textile enduit à motifs imprimés, caractérisé en ce qu'il comprend une sous-couche textile formant support associée à une couche d'enduction à base d'élastomère d'épichlorhydrine vulcanisé, ladite couche d'enduction présentant un ou plusieurs motif(s) imprimé(s) sur sa surface non liée à la sous-couche textile.Textile coated with printed patterns, characterized in that it comprises a textile underlay forming a support associated with a base coating layer vulcanized epichlorohydrin elastomer, said coating layer having one or more pattern (s) printed on its surface not related to the underlay textile. Textile enduit à motifs imprimés selon la revendication 1, caractérisé en ce que la sous-couche textile comprend ou consiste en un tissu, un non-tissé ou une maille, de préférence un tissu ou un non-tissé.Textile coated with printed patterns according to claim 1, characterized in what the textile underlay includes or consists of a fabric, a nonwoven or a mesh, preferably a fabric or a nonwoven. Textile enduit à motifs imprimés selon la revendications 1 ou 2, caractérisé en ce qu'il est muni d'un vernis de protection appliqué sur la couche d'enduction imprimée, de préférence un vernis de protection à propriétés anti-taches.Textile coated with printed patterns according to claim 1 or 2, characterized in that it is provided with a protective varnish applied to the printed coating layer, preferably a protective varnish anti-stain properties. Procédé pour la préparation d'un textile enduit à motifs imprimés selon l'une quelconque des revendications 1 à 3, caractérisé en ce que : on prend un textile formant support, on dépose sur ledit textile support une couche d'enduction à base d'épichlorhydrine, on imprime le ou les motif(s) ou décor(s) désiré(s), on vulcanise l'ensemble résultant, et on dépose éventuellement un vernis de protection. Process for the preparation of a coated textile with printed patterns according to any one of Claims 1 to 3, characterized in that: we take a textile forming a support, a coating layer based on epichlorohydrin is deposited on said textile support, we print the desired motif (s) or decor (s), we vulcanize the resulting assembly, and a protective varnish may be deposited. Procédé selon la revendication 4, caractérisé en ce que le textile formant support comprend ou consiste en un tissu, un non-tissé ou une maille, de préférence un tissu ou un non-tissé.Method according to claim 4, characterized in that the textile forming a support comprises or consists of a fabric, a nonwoven or a mesh, preferably a fabric or a nonwoven. Procédé selon la revendication 4 ou 5, caractérisé en ce que la composition de la couche d'enduction est la suivante : Epichlorhydrine   100 parties Copolymère Ethylène-Vinyl-Acétate   5 à 30 parties Charges   30 à 80 parties Plastifiants   5 à 15 parties Stabilisants U.V. et chaleur   1 à 3 parties Agent de vulcanisation   1 à 6 parties Colorants   10 à 40 parties Method according to claim 4 or 5, characterized in that the composition of the coating layer is as follows: Epichlorohydrin 100 parts Ethylene-Vinyl-Acetate copolymer 5 to 30 parts Charges 30 to 80 parts Plasticizers 5 to 15 parts UV and heat stabilizers 1 to 3 parts Vulcanizing agent 1 to 6 parts Dyes 10 to 40 parts Procédé selon l'une quelconque des revendications 4 à 6, caractérisé en ce que la couche d'enduction est appliquée par calandrage sur le support textile.Method according to any of claims 4 to 6, characterized in that the coating layer is applied by calendering on the support textile. Procédé selon l'une quelconque des revendications 4 à 7, caractérisé en ce que l'impression du ou des motif(s) ou décor(s) est réalisée par transfert.Method according to any one of claims 4 to 7, characterized in that the printing of the motif (s) or decoration (s) is carried out by transfer. Procédé selon l'une quelconque des revendications 4 à 7, caractérisé en ce que l'impression du ou des motif(s) ou décor(s) est réalisée par héliogravure.Method according to any one of claims 4 to 7, characterized in that the printing of the motif (s) or decoration (s) is carried out by photogravure. Procédé selon la revendication 8 ou 9, caractérisé en ce que l'impression est réalisée à l'aide d'encres de type acrylique et/ou polyuréthane éventuellement modifié.Method according to claim 8 or 9, characterized in that printing is carried out using acrylic and / or polyurethane inks possibly modified. Articles comprenant un textile enduit à motifs imprimés selon l'une quelconque des revendications 1 à 10.Articles comprising a coated textile with printed patterns according to one any of claims 1 to 10. Articles selon la revendication 11, caractérisés en ce qu'ils consistent en des nappes.Articles according to claim 11, characterized in that they consist in tablecloths.
    EP01400070A 2000-01-12 2001-01-11 Textile coated with epichlorohydrin rubber and printed Expired - Lifetime EP1116815B1 (en)

    Priority Applications (1)

    Application Number Priority Date Filing Date Title
    SI200130319T SI1116815T1 (en) 2000-01-12 2001-01-11 Textile coated with epichlorohydrin rubber and printed

    Applications Claiming Priority (2)

    Application Number Priority Date Filing Date Title
    FR0000358A FR2803607B1 (en) 2000-01-12 2000-01-12 PRINTED COATED TEXTILE BASED ON EPICHLORHYDRIN ELASTOMER
    FR0000358 2000-01-12

    Publications (2)

    Publication Number Publication Date
    EP1116815A1 true EP1116815A1 (en) 2001-07-18
    EP1116815B1 EP1116815B1 (en) 2005-03-02

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    Application Number Title Priority Date Filing Date
    EP01400070A Expired - Lifetime EP1116815B1 (en) 2000-01-12 2001-01-11 Textile coated with epichlorohydrin rubber and printed

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    EP (1) EP1116815B1 (en)
    AT (1) ATE290118T1 (en)
    DE (1) DE60109070T2 (en)
    DK (1) DK1116815T3 (en)
    ES (1) ES2234784T3 (en)
    FR (1) FR2803607B1 (en)
    PT (1) PT1116815E (en)
    SI (1) SI1116815T1 (en)

    Citations (1)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    FR2702416A1 (en) * 1993-03-10 1994-09-16 Lecomte Roger PVC-based printed material and production process

    Patent Citations (1)

    * Cited by examiner, † Cited by third party
    Publication number Priority date Publication date Assignee Title
    FR2702416A1 (en) * 1993-03-10 1994-09-16 Lecomte Roger PVC-based printed material and production process

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    SI1116815T1 (en) 2005-06-30
    ES2234784T3 (en) 2005-07-01
    FR2803607A1 (en) 2001-07-13
    ATE290118T1 (en) 2005-03-15
    EP1116815B1 (en) 2005-03-02
    DK1116815T3 (en) 2005-05-17
    FR2803607B1 (en) 2002-04-05
    PT1116815E (en) 2005-05-31
    DE60109070T2 (en) 2005-07-21
    DE60109070D1 (en) 2005-04-07

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