EP1102836B1 - Wasser-in-öl-mikroemulsion zur erzielung kosmetischer eigenschaften in zusammensetzungen auf basis von wäscheweichmachern - Google Patents

Wasser-in-öl-mikroemulsion zur erzielung kosmetischer eigenschaften in zusammensetzungen auf basis von wäscheweichmachern Download PDF

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Publication number
EP1102836B1
EP1102836B1 EP99937670A EP99937670A EP1102836B1 EP 1102836 B1 EP1102836 B1 EP 1102836B1 EP 99937670 A EP99937670 A EP 99937670A EP 99937670 A EP99937670 A EP 99937670A EP 1102836 B1 EP1102836 B1 EP 1102836B1
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Prior art keywords
microemulsion
perfume
water
ether
composition
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EP99937670A
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French (fr)
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EP1102836A1 (de
Inventor
Eric Ewbank
Dominique Tummers
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Colgate Palmolive Co
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Colgate Palmolive Co
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0017—Multi-phase liquid compositions
    • C11D17/0021—Aqueous microemulsions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/62—Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/001—Softening compositions
    • C11D3/0015—Softening compositions liquid
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/43—Solvents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/50—Perfumes

Definitions

  • This invention relates to a composition and method for "post-adding" cosmetic attributes to a fabric softening base composition at the final stage of its manufacture. More particularly it relates to a water-in-oil microemulsion which is suitable for containing adjuvants such as perfume or colorant and which can be readily mixed with a fabric softening base composition with only a minimum amount of shear and without adversely affecting its physical stability.
  • perfumes and colorants are routinely introduced into liquid fabric softening compositions to provide appealing cosmetic attributes for the consumer.
  • the introduction of perfume, for example, to a liquid softening composition is meant to leave a pleasant and lasting fragrance on the treated fabrics.
  • the colorant is intended to provide a visually pleasing product as well as convey to the consumer an overall impression of softness and quality.
  • perfumes and colorants are attributes which allow the formulator a degree of flexibility to provide product variety for a given softening technology or for a fixed fabric softening base composition.
  • perfume on a weight basis, is invariably a very minor component of a commercial fabric softener composition
  • its introduction into the composition in an efficient manner is a subject of much concern in the formulation art. This is particularly true for concentrated fabric softeners containing more than about 10% by weight of active softening ingredients insofar as the aqueous softener base compositions tend to gel in the presence of water-immiscible perfume. This tendency of gel formation is particularly problematic when the water-immiscible perfume is poorly dispersed in the aqueous emulsion which constitutes the softening base composition.
  • Undesirable thickening or gelation of a softener base composition has significant drawbacks: it reduces the effective shelf life of the final product and adversely affects consumer acceptance for a softener product which upon use has thickened to an unexpectedly viscous mass instead of meeting the consumers expectation of being essentially free-flowing.
  • the prior art has addressed itself to overcoming the pervasive problems of gelation and the formation of high viscosity liquids which accompany the introduction of water-insoluble perfumes into aqueous fabric softener base compositions.
  • U.S. Patent 5,447,644 to International Flavors & Fragrances describes a method to avoid gelation of the softening composition resulting from the introduction of increased levels of perfume into a softener base composition.
  • this method there is first formed an aqueous microemulsion by mixing the perfume with a defined nonionic surfactant under conditions of high shear to uniformly disperse the perfume in the surfactant/water mixture.
  • the perfume-containing microemulsion is then mixed with a fabric softener base formulation to form the final fabric softener composition.
  • a high shear mixer is required for this mixing operation.
  • a perfume-containing water-in-oil microemulsion capable of being mixed with a perfume-free fabric softener base composition which is in the form of an aqueous emulsion so as to disperse perfume in said aqueous emulsion under conditions of low shear while avoiding any problem of gelation to thereby provide a physically stable perfume-containing liquid fabric softening composition
  • said water-in-oil microemulsion comprising:
  • the diester ammonium compounds (a)(i) are diester quaternary ammonium compounds.
  • microemulsion as 'a system of water, oil and amphiphile which is a single optically isotropic and thermo-dynamically stable liquid solution'. This definition of microemulsion is used herein in describing the present invention.
  • a microemulsion has the following characteristics/properties:
  • the present invention also provides a method for introducing a perfume into a perfume-free fabric softener base composition which is in the form of an aqueous emulsion under conditions of low shear and without adversely affecting its physical stability comprising the steps of:
  • the water-in-oil microemulsion compositions of the invention are predominantly comprised of the oily phase as defined above, namely, the cationic surfactant fabric softener, the organic solvent and the water-insoluble perfume.
  • the amount of water should generally be from 5% to 25%, by weight.
  • the preferred diester quaternary ammonium surfactants for use herein are the dioleyl diester "quats" represented by equation (1). Particularly preferred is methyl bis-[ethyl(oteyl)]-2-hydroxyethyl ammonium methyl sulfate, commonly referred to as "DODEQ”.
  • the present invention is predicated on the discovery that cosmetic attributes such as perfume and colorant can be readily "post-added” to an aqueous fabric softening base composition at the final stage of its manufacture by using a water-in-oil microemulsion as herein defined as the vehicle to be added to and mixed with the aqueous emulsion to form the finished product.
  • the water-in-oil microemulsion is incorporated into the softening base composition under conditions of gentle agitation or low shear, using a sufficient amount to provide the desired level of perfume to the finished product.
  • the microemulsion undergoes an inversion upon dilution in the aqueous emulsion which serves to efficiently disperse the perfume or colorant throughout the composition without concomitant problems of gelation or product instability.
  • the present invention provides important advantages from the standpoint of manufacturing a softening product composition as well as in insuring the integrity of the final product itself.
  • the essence of the present invention is an oil in water microemulsion which can be readily formed at room temperature with no need for high shear forces or elaborate mixing equipment. And with regard to the finished product, it is clear that the introduction of cosmetic attributes into a softening base composition is accomplished without adversely compromising the rheology or physical stability of the resulting product.
  • Diester quaternary ammonium surfactant fabric softeners represented by equation (1) are preferred for use herein and are commercially available from Stepan Co. as Stepantex® and from KAO Corp. as Tetranyl® but can also be synthesized by the reaction of two moles of a fatty acid with a trialkanolamine, preferably, triethanolamine followed by methylation with dimethyl sulfate or an alkyl halide such as, methyl iodide. In a preferred mode the fatty acid is oleic acid.
  • Soya fatty acids are a practical source for this purpose consisting of about 3% myristic acid, about 5% palmitic acid, about 5% palmitoleic acid, 1.5% stearic acid, 72.5% oleic acid and about 13% linoleic acid.
  • Other sources of useful fatty acids are those obtained from the saponification of beef tallow, butter, corn oil, cottonseed oil, lard, olive oil, palm oil, peanut oil, cod liver oil, and coconut oil.
  • a preferred diester quaternary ammonium surfactant fabric softener is methyl bis[ethyl(oleyl)]-2-hydroxyethyl ammonium methyl sulfate.
  • Other diesters useful in the practice of this invention include:
  • coconut and soft-tallow indicate mixtures of esters corresponding to the fatty acid source.
  • a certain amount of the triester homolog may be produced as an impurity.
  • perfume is used herein in its ordinary sense to refer to and include any non water-soluble fragrant substance or mixture of substances including natural (i.e., obtained by extraction of flower, herb, blossom or plant), artificial (i.e., a mixture of natural oils or oil constituents) and synthetic (i.e., a single or mixture of synthetically produced substance) odoriferous substances.
  • perfumes are complex mixtures of blends of various organic compounds, such as, esters, ketones, hydrocarbons, lactones, alcohols, aldehydes, ethers, aromatic compounds and varying amounts of essential oils (e.g., terpenes) such as from 0% to 80%, usually from 10% to 70% by weight, the essential oils themselves being volatile odoriferous compounds and also serving to dissolve the other components of the perfume.
  • essential oils e.g., terpenes
  • the precise composition of the perfume has no particular effect on fabric softening so long as it meets the criteria of water immiscibility and pleasant odor.
  • Organic solvents suitable for use in this invention include: aliphatic alcohols having 1 to 6 carbon atoms, such as, ethanol, propanol, isopropanol, n-butanol, isobutanol, t-butanol, n-pentanol, isopentanol, sec-pentanol, n-hexanol, isohexanol, and other isomers aliphatic polyalcohols, such as, ethylene glycol, propylene glycol, butylene glycol, diethylene glycol, dipropylene glycol, 1,4-butanediol, 2-methylpentanediol, hexane triol, tripropylene glycol, pentaerythritol, glycerol, and sorbitol; aliphatic ethers, such as, ethylene glycol monobutyl ether(EGMBE), diethylene glycol monobutyl ether(DEGM
  • DPM dipropylene glycol methyl ether
  • DnB dipropylene glycol monobutyl ether
  • EGMBE ethylene glycol monobutyl ether
  • the weight range of cationic surfactant is generally from 5% to 80%, and preferably from 10% to 60%, by weight;
  • the weight range of the organic solvent is generally from 2% to 50%, and preferably from 4% to 40%, by weight; and the weight range of the water-immiscible perfume is generally from 5% to 80%, and preferably from 10% to 70%, by weight.
  • the water content is generally from 0.5% to 25%, and preferably from 5% to 25%, by weight.
  • the weight ratio of the defined oily phase to water is generally from 3:1 to 200:1, preferably from 5:1 to 50:1, and most preferably from 5:1 to 20:1.
  • the microemulsions of the invention have a particle size between 10 and 100 nanometers. At particle sizes below about 50 nanometers, the microemulsions are generally clear.
  • the microemulsions are formed by simply combining the above-described components of the composition under gentle agitation or low shear. Conventional mixing equipment known to those skilled in the art is sufficient for this purpose. All of the components described herein, both required and optional, must be normally liquid, namely, liquid at ambient room temperatures. Accordingly, there is no need for heating during the preparation of the microemulsions.
  • Microemulsion compositions/area in a pseudo-ternary phase diagram were basically determined on a clear/turbid criteria basis by mixing three of the components and titrating with incremental amounts of the fourth component.
  • a mixture consisting of organic solvent (or mixture of), water-immiscible perfume and water were introduced in a suitable/fixed ratio, and then titrated with DODEQ (dioleyl diesterquat).
  • DODEQ dioleyl diesterquat
  • Samples were mixed at RT using a magnetic stirrer operating at 100-150 rpm after which they were allowed to stand for few minutes before visual examination for clarity/tubidity. Clear samples were further examined under a polarizing microscope to check that the liquids were isotropic.
  • estimated regions for microemulsion compositions were located on pseudo-ternary phase diagrams. Some compositions located inside these microemulsion areas were selected to illustrate the present invention.
  • the water-in-oil microemulsions contain dioleyl diester quat (DODEQ) as described hereinabove.
  • DODEQ dioleyl diester quat
  • the formula of DODEQ is as follows: wherein R 1 and R 2 are C 17 H 34 , unsaturated alkyl chains from oleic acid.
  • DODEQ is commercially available from KAO as Tetranyl® or from Stepan Co. as Stepantex®. It is synthesized by the reaction of two moles of oleic acid with triethanolamine followed by methylation with dimethyl sulfate.
  • oleic acid may be replaced by olive fatty acids in the synthesis of DODEQ, such olive fatty acids comprising 14% palmitic acid, 2% palmitoleic acid, 2% stearic acid, 64% oleic acid, 16% linoleic acid and 2% linolenic acid.
  • DODEQ olive fatty acids
  • Such material is available from KAO under the name Tetranyl AO-2®.
  • the water-soluble dyes used in the examples are marketed under the names Liquitint Royal Blue®, Liquitint Yellow LP® and Liquitint Nature Green®, by Miiliken Chemical company.
  • the fabric softening base compositions contain two principal softening compounds:
  • the dialkyl amidoamine compounds have the general structural formula as follows: wherein n is an integer of from 1 to 3; R is an alkylene radical having 2 to 4 carbon atoms; R' is an alkyl or alkenyl group having 8 to 22 carbon atoms; R 1 is a lower alkyl group having 1 to 4 carbon atoms or hydrogen; and X- is a softener compatible anion.
  • the softening ingredients are each melted, mixed together with stirring and maintained at 60 to 70°C.
  • the mixture of molten softening active compounds is added to heated (60-70°C) deionized water with stirring using a 4-pitched blade impeller.
  • the hot water mixture is stirred for 10 to 15 min at about 400 rpm in order to emulsify the molten actives.
  • the stirring speed is increased to 700-800 rpm as the viscosity of the emulsion increases.
  • hydrochloric acid is first introduced separately in the water prior to the addition of the molten softening ingredients.
  • the emulsion is allowed to cool down to 30°C while stirring it at 300-400 rpm.
  • the particle size distribution of the emulsion is further reduced, subjecting the product to high pressure homogenization. This step reduces the viscosity of the composition.
  • Calcium chloride, preservative, sequestering agent and other optional ingredients such as the thickener, are all introduced sequentially with stirring into the cooled product.
  • compositions 1 through 6 were prepared following the procedures described above, each composition having varying weight percentages of the four principal components: cationic surfactant; organic solvent; perfume; and water.
  • the ratio of perfume to organic solvent was kept constant at 60:40.
  • Table 1 The compositions are shown in Table 1 along with observations concerning the appearance of the resulting composition and whether it is within the invention, namely, it formed a water in oil microemulsion, or outside the invention, by forming an emulsion.
  • compositions 1-4 are w/o microemulsions within the invention; compositions 5 and 6 are emulsions.
  • compositions 7 through 9 were prepared containing a fixed level of perfume and a varying amount of colorant. The compositions are shown below in Table 2 along with observations concerning the physical appearance of the resulting composition. COMPONENT 7 8 9 DODEQ 25% 25% 15% Organic solvent (DPM) 26 26 32 Perfume 39 39 48 Water 9.95 9.5 4.9 Colorant 0.05 0.5 0.1 Appearance of composition clear clear clear Microemulsion (M)/Emulsion (E) M M M M M M M M M
  • compositions 5, 6, 10, 11 and 12 were prepared wherein the weight ratio of fragrance to organic solvent was varied.
  • the compositions are shown in Table 3 along with observations concerning the appearance of the resulting composition.
  • COMPONENT 5 10 11 6 12 DODEQ 15% 15% 15% 25% 25% Perfume + organic solvent (DPM) 59% 59% 59% 60%
  • DPM Perfume + organic solvent
  • Ratio of Perfume to organic solvent 60:40 60:50 32:68 60:40 50:50 Water 26% 26% 26% 15% 15% Appearance of composition Turbid Turbid Clear Turbid Clear Microemulsion (M)/Emulsion (E) E E E M E M E M
  • compositions 5 and 6 are two compositions from Example 1, which are outside of the invention but are included in Table 3 as comparative compositions.
  • Table 3 demonstrates that by changing the ratio of Perfume to organic solvent, it is possible to convert a turbid emulsion into a clear fragrance microemulsion suitable for the present invention.
  • composition 11 a clear w/o microemulsion
  • compositions 5 and 10 which are outside the invention underscores the criticality of the perfume to organic solvent ratio.
  • compositions 6 and 12 demonstrates that by properly adjusting the ratio of perfume to organic solvent, a composition which is outside the invention (composition 6), can be reformulated to provide a clear w/o microemulsion (composition 12).
  • compositions 13 through 18 were prepared to demonstrate the ability to prepare microemulsions in accordance with the invention using organic solvents from the following classes: ethers, esters, glycols and alkanols.
  • organic solvents from the following classes: ethers, esters, glycols and alkanols.
  • the compositions are shown in Table 4 below along with observations concerning the appearance of the resulting composition.
  • the dispersion properties of a perfume-containing microemulsion in accordance with the invention were demonstrated using two different softening base compositions and comparing same with dispersion into 100% water.
  • the perfume micromemulsion composition was comprised of the following: 39% perfume; 26% EGMBE organic solvent; 25% DODEQ; 0.48% Liquitint Royal Blue colorant (4% solution); and balance water.
  • a first softening base composition (“AA/EstQ” base) was comprised of the following: 2.74% amidoamine (Rewopal V3340); 1.64% Esterquat (Tetranyl AT1-75); 0.29% glyceryl monooleate; 0.3% hydrochloric acid (25% solution); 0.074% lactic acid (Purac SP80); and balance water.
  • the second softening base composition (“EstQ/FA” base) was comprised of the following: 3.9% Esterquat (Tetranyl AT1-75); 0.83% C 16-18 fatty alcohol; 0.2% alcohol ethoxylate (C 13-15 fatty alcohol 20EO); 0.1 % amino trimethyl phosphonic acid; 0.063% lactic/lactate buffer solution; 0.20% polyacrylate thickener; and balance water.
  • the perfume microemulsion was introduced into each of the above-described softening base compositions at a level of 1.28%, by weight, under very low shear conditions. Mixing was achieved with an Oscell-12 shaker operating for 12 seconds at 700 oscillations per minute. Particle size of the softening base compositions was measured before and after the addition of the perfume microemulsion. For purposes of comparison, dispersion "as is" was measured by post-adding pure perfume to each softening base.
  • microemulsion composition was comprised of the following:
  • the softening base composition was comprised of the following:

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  • Chemical & Material Sciences (AREA)
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  • Engineering & Computer Science (AREA)
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  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
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Claims (15)

  1. Parfüm-haltige Wasser-in-Öl-Mikroemulsion, die in der Lage ist, mit einer Parfüm-freien Textilweichmacherbasiszusammensetzung gemischt zu werden, die in Form einer wässrigen Emulsion vorliegt, um so Parfüm in der wässrigen Emulsion unter Bedingungen mit geringer Scherung unter Vermeidung irgendeines Gelierungsproblems zu dispergieren, um dadurch eine physikalisch stabile Parfüm-haltige flüssige textilweichmachende Zusammensetzung zu liefern, wobei die Wasser-in-Öl-Mikroemulsion umfasst:
    (a) 5 bis 80 Gew.-% Tensid-Textilweichmacher ausgewählt aus der Gruppe bestehend aus:
    (i) Diesterammoniumverbindungen mit den folgenden Strukturformein:
    Figure 00240001
       in der jedes
       A unabhängig C(O)O-R' oder -O(O)C-R' ist,
       R eine niedere Alkylgruppe mit 1 bis 4 Kohlenstoffatomen ist,
       R' eine Alkyl- oder Alkenylgruppe mit 8 bis 22 Kohlenstoffatomen ist,
       R" unabhängig ein niederer Alkylrest mit 1 bis 6 Kohlenstoffatomen oder eine Hydroxyalkylgruppe oder H ist,
       n eine Zahl mit einem Wert von 2 ist und
       X- ein Weichmacher verträgliches Anion ist, und
    Figure 00250001
       in der B unabhängig A oder (R)A ist und A, R, R" wie oben definiert sind, und
    Figure 00250002
       in der A, R und R" wie oben definiert sind, und/oder
    (ii) Diamidoammoniumverbindungen mit der Formel
    Figure 00250003
       in der X- und R' wie oben definiert sind, R1 ein niederer Alkylrest mit 1 bis 4 Kohlenstoffatomen oder Wasserstoff ist und R ein Alkylenrest mit 2 bis 4 Kohlenstoffatomen ist,
    (b) 2 bis 50 Gew.-% organisches Lösungsmittel,
    (c) 5 bis 80 Gew.-% nicht mit Wasser mischbares Parfüm, wobei die Komponenten (a), (b) und (c) die Ölphase der Mikroemulsion umfassen,
    (d) 0 bis 1 % Färbemittel und
    (e) 0,5 bis 25 Gew.-% Wasser, wobei die Mikroemulsion frei von anionischem Tensid ist und ein Gewichtsverhältnis der Ölphase zu Wasser von 3 : 1 bis 200 : 1 aufweist, wobei die Prozentsätze der Komponenten (a), (b) und (c) und der Wert des Gewichtsverhältnisses so gewählt sind, dass die resultierende Zusammensetzung eine Wasser-in-Öl-Mikroemulsion bildet.
  2. Mikroemulsion nach Anspruch 1, bei der das quartäre Ammoniumdiestertensid Methylbis[ethyl(oleyl)}-2-hydroxyethylammoniummethylsulfat ist.
  3. Mikroemulsion nach Anspruch 1, bei der das organische Lösungsmittel ein aliphatischer Alkohol mit 1 bis 6 Kohlenstoffatomen ist.
  4. Mikroemulsion nach Anspruch 3, bei der das organische Lösungsmittel n-Butanol ist.
  5. Mikroemulsion nach Anspruch 1, bei der das organische Lösungsmittel ein mehrwertiger aliphatischer Alkohol ist.
  6. Mikroemulsion nach Anspruch 5, bei der der mehrwertige Alkohol Hexylenglykol ist.
  7. Mikroemulsion nach Anspruch 1, bei der das organische Lösungsmittel ein aliphatischer Ether ist.
  8. Mikroemulsion nach Anspruch 7, bei der der Ether Dipropylenglykolmethylether ist.
  9. Mikroemulsion nach Anspruch 7, bei der der Ether Dipropylenglykol-nbutylether ist.
  10. Mikroemulsion nach Anspruch 7, bei der der Ether Ethylenglykolmonobutylether ist.
  11. Mikroemulsion nach Anspruch 1, bei der das organische Lösungsmittel ein aliphatischer Ester ist.
  12. Mikroemulsion nach Anspruch 11, bei der der Ester Methyllactat ist.
  13. Mikroemulsion nach Anspruch 1, bei der die Textilweichmacherbasiszusammensetzung einen quartären Ammoniumdiester-Weichmacher enthält.
  14. Verfahren zur Einführung eines Parfüms in eine Parfüm-freie Textilweichmacherbasiszusammensetzung, die in Form einer wässrigen Emulsion vorliegt, unter Bedingungen mit geringer Scherung und ohne nachteilige Beeinträchtigung ihrer physikalischen Stabilität, bei dem
    (a) eine Parfüm-haltige Wasser-in-Öl-Mikroemulsion gemäß Anspruch 1 bereitgestellt wird, und
    (b) eine Menge der Wasser-in-Öl-Mikroemulsion, die ausreicht, um die gewünschte Menge Parfüm zu enthalten, mit der Textilweichmacherbasiszusammensetzung unter Bedingungen mit geringer Scherung gemischt wird, wodurch die Umwandlung der Mikroemulsion und der Dispersion des Parfüms in der wässrigen Emulsion unter Bildung einer physikalisch stabilen Parfüm-haltigen flüssigen textilweichmachenden- Zusammensetzung bewirkt wird.
  15. Verfahren zur Vermittlung von Weichheit an Textilien begleitet von einem Parfümduft, bei dem die Textilien mit einer weichmachend wirkenden Menge der flüssigen textilweichmachenden Zusammensetzung, die gemäß Anspruch 14 gebildet worden ist, in Kontakt gebracht wird.
EP99937670A 1998-07-30 1999-07-29 Wasser-in-öl-mikroemulsion zur erzielung kosmetischer eigenschaften in zusammensetzungen auf basis von wäscheweichmachern Expired - Lifetime EP1102836B1 (de)

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DK99937670T DK1102836T3 (da) 1998-07-30 1999-07-29 Vand-i-olie-mikroemulsion til opnåelse af kosmetiske egenskaber for sammensætninger baseret på stofblödgörere

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US12630898A 1998-07-30 1998-07-30
US126308 1998-07-30
PCT/US1999/017319 WO2000006690A1 (en) 1998-07-30 1999-07-29 Water-in-oil microemulsion for providing cosmetic attributes to fabric softening base composition

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EP1102836A1 EP1102836A1 (de) 2001-05-30
EP1102836B1 true EP1102836B1 (de) 2004-09-22

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US6620437B2 (en) * 1998-07-30 2003-09-16 Colgate-Palmolive Co. Water-in-oil microemulsion for providing cosmetic attributes to fabric softening base composition
GB9910101D0 (en) 1999-04-30 1999-06-30 Unilever Plc Concentrated perfume compositions and manufacture of a fabric softening composition therefrom
GB9915964D0 (en) * 1999-07-07 1999-09-08 Unilever Plc Fabric conditioning composition
WO2001098450A2 (en) 2000-06-20 2001-12-27 The Procter & Gamble Company Multi-phase fabric care composition for delivering multiple fabric care benefits
GB0025442D0 (en) * 2000-10-17 2000-11-29 Unilever Plc Fabric conditioning compositions
US8470762B2 (en) 2007-05-31 2013-06-25 Colgate-Palmolive Company Fabric softening compositions comprising polymeric materials
CN101353862B (zh) * 2007-07-23 2012-12-12 五星化学工业株式会社 用于提高纤维的柔软性的纤维柔软剂的制造方法
WO2012072368A1 (en) 2010-12-03 2012-06-07 Unilever Plc Ifabric conditioners
US12093036B2 (en) 2011-01-21 2024-09-17 Teladoc Health, Inc. Telerobotic system with a dual application screen presentation
CN102277239A (zh) * 2011-07-20 2011-12-14 天津鎏虹科技发展有限公司 天然植物水性清洗剂及其制备方法
CA2843605C (en) 2011-08-02 2017-07-04 The Procter & Gamble Company Liquid-liquid extraction composition useful in processing water-soluble surfactants
RU2014101944A (ru) 2011-08-02 2015-09-10 Дзе Проктер Энд Гэмбл Компани Композиции водорастворимых поверхностно-активных веществ с улучшенным вкусом
JP2014521693A (ja) 2011-08-02 2014-08-28 ザ プロクター アンド ギャンブル カンパニー 界面活性剤の味及び／又は臭気改善のためのプロセス
US9072671B2 (en) 2012-08-02 2015-07-07 The Procter & Gamble Company Process for oral care material taste and/or odor improvement
MX360843B (es) * 2012-12-11 2018-11-20 Colgate Palmolive Co Composicion de esterquat que tiene un alto contenido de triesterquat.

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US5447644A (en) * 1994-05-12 1995-09-05 International Flavors & Fragrances Inc. Method of controlling viscosity of fabric softeners
US5525245A (en) * 1994-12-21 1996-06-11 Colgate-Palmolive Company Clear, concentrated liquid fabric softener compositions
US6129934A (en) * 1995-06-07 2000-10-10 Ony, Inc. Modification of animal lung surfactant for treating respiratory disease due to lung surfactant deficiency or dysfunction
DE19624051A1 (de) * 1996-06-17 1997-12-18 Henkel Kgaa Parfümölkonzentrate

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YU6201A (sh) 2003-01-31
ATE277165T1 (de) 2004-10-15
CN1168816C (zh) 2004-09-29
ZA200100581B (en) 2002-01-21
PL345700A1 (en) 2002-01-02
AU5245899A (en) 2000-02-21
IL140880A0 (en) 2002-02-10
EP1102836A1 (de) 2001-05-30
AU774872B2 (en) 2004-07-08
NO20010491L (no) 2001-01-29
BR9912573A (pt) 2001-05-02
WO2000006690A1 (en) 2000-02-10
DE69920480D1 (de) 2004-10-28
HUP0103066A3 (en) 2003-04-28
CN1311814A (zh) 2001-09-05
DK1102836T3 (da) 2005-01-31
DE69920480T2 (de) 2005-10-13
HUP0103066A2 (hu) 2002-02-28
NO20010491D0 (no) 2001-01-29
CA2338372A1 (en) 2000-02-10
TR200100233T2 (tr) 2001-05-21
RU2232185C2 (ru) 2004-07-10

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