EP1043416B1 - Plaquette de carbure frittée - Google Patents
Plaquette de carbure frittée Download PDFInfo
- Publication number
- EP1043416B1 EP1043416B1 EP00106692A EP00106692A EP1043416B1 EP 1043416 B1 EP1043416 B1 EP 1043416B1 EP 00106692 A EP00106692 A EP 00106692A EP 00106692 A EP00106692 A EP 00106692A EP 1043416 B1 EP1043416 B1 EP 1043416B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- cemented carbide
- cutting tool
- tool insert
- binder phase
- insert according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C30/00—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process
- C23C30/005—Coating with metallic material characterised only by the composition of the metallic material, i.e. not characterised by the coating process on hard metal substrates
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/02—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
- C22C29/06—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
- C22C29/08—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on tungsten carbide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/24—After-treatment of workpieces or articles
- B22F2003/247—Removing material: carving, cleaning, grinding, hobbing, honing, lapping, polishing, milling, shaving, skiving, turning the surface
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F5/00—Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
- B22F2005/001—Cutting tools, earth boring or grinding tool other than table ware
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24942—Structurally defined web or sheet [e.g., overall dimension, etc.] including components having same physical characteristic in differing degree
- Y10T428/2495—Thickness [relative or absolute]
- Y10T428/24967—Absolute thicknesses specified
- Y10T428/24975—No layer or component greater than 5 mils thick
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/252—Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/263—Coating layer not in excess of 5 mils thick or equivalent
- Y10T428/264—Up to 3 mils
- Y10T428/265—1 mil or less
Definitions
- the present invention relates to a coated cemented carbide cutting tool insert particularly useful for turning operations in steels or stainless steels, especially suited for operations with high demands regarding toughness properties of the insert.
- the cemented carbide insert has surface zones with element compositions differing from the bulk composition giving simultaneously an excellent toughness performance and good resistance to plastic deformation.
- High performance cutting tools must nowadays possess high wear resistance, high toughness properties and good resistance to plastic deformation. Improved toughness behaviour of a cutting insert can be obtained by increasing the WC grain size and/or by raising the overall binder phase content, but such changes will simultaneously result in significant loss of the plastic deformation resistance.
- a coated cemented carbide insert with a 10-30 ⁇ m, thick essentially gamma phase free and binder phase enriched surface zone with an average binder phase content (by volume) in the range 1.2-2.0 times the bulk binder phase content.
- the gamma phase consists essentially of TaC and TiC and to some extent of WC dissolved into the gamma phase during sintering.
- the ratio Ta/Ti is 2.0-3.0.
- the binder phase is highly W-alloyed.
- the CW-ratio takes a value ⁇ 1 and the lower the CW-ratio is the higher is the W-content in the binder phase. It has now been found according to the invention that an improved cutting performance is achieved if the CW-ratio is in the range 0.80-0.85.
- the present invention is applicable to cemented carbides with a composition of 5-12, preferably 9-11, weight percent of Co binder phase, and 3-11, preferably 7-10, weight percent TaC + TiC and a balance WC.
- the Nb content should not exceed 0.1 weight percent.
- the weight ratio Ta/Ti should be 2.0-3.0.
- the WC has an average grain size of 1.0 to 4.0 ⁇ m.
- the cemented carbide body may contain small amounts, ⁇ 1 volume-%, of ⁇ -phase (M 6 C).
- Inserts according to the invention are further provided with a coating consisting of basically 3-12 ⁇ m columnar TiCN-layer followed by a 1-8 ⁇ m thick Al 2 O 3 -layer deposited e.g. according to any of the patents US 5,766,782, US 5,654,035, US 5,674,564, US 5,702,808 preferably with a ⁇ -Al 2 O 3 -layer and preferably with an outermost thin layer of TiN which preferably is removed in the edge line by brushing or by blasting.
- a cemented carbide insert produced according to the invention is provided with a coating consisting of: 6 ⁇ m TiCN, 5 ⁇ m Al 2 O 3 and 1 ⁇ m TiN. This coated insert is particularly suited for cutting operations in steel.
- a cemented carbide insert produced according to the invention is provided with a coating consisting of: 4 ⁇ m TiCN, 2 ⁇ m Al 2 O 3 and 1 ⁇ m TiN. This coating is particularly suited for cutting operations in stainless steels.
- Cutting inserts according to the invention comprising a cemented carbide substrate consisting of a binder phase of Co, WC and a gamma phase from the elements Ta and Ti with a binder phase enriched surface zone essentially free of gamma phase and a coatings are made in the following way.
- a powder mixture containing 5-12, preferably 9-11, weight percent of binder phase consisting of Co, and 3-11, preferably 7-10, weight percent TaC + TiC and a balance WC with an average grain size of 1,0-4,0 ⁇ m, preferably 1,5-3,0 ⁇ m is prepared.
- the Nb content should not exceed 0,1 weight percent.
- the weight ratio Ta/Ti should be 1,0-4,0, preferably 2,0-3,0.
- the raw materials are mixed with pressing agent and possibly W such that the desired CW-ratio is obtained and the mixture is milled and spray dried to obtain a powder material with the desired properties.
- the powder material is compacted purview of the skilled artisan to determine whether the requisite surface zone of the cemented carbide have been obtained and to modify the nitrogen addition and the sintering process in accordance with the present specification in order to obtain the desired result.
- the raw materials are mixed with pressing agent and possibly W such that the desired CW-ratio is obtained and the mixture is milled and spray dried to obtain a powder material with the desired properties.
- the powder material is compacted and sintered. Sintering is performed at a temperature of 1300-1500°C, in a controlled atmosphere of about 50 mbar followed by cooling. After conventional post sintering treatments including edge rounding a hard, wear resistant coating according to above is deposited by CVD- or MT-CVD-technique.
- Inserts from A, B and C were tested with respect to toughness in a longitudinal turning operation with interrupted cuts.
- the inserts from A and C were tested in a three turning operations with high toughness demands due to interrupted cuts.
- the inserts were run until breakage of the edge.
- the insert style SNMG120412-PR was used.
- Examples 2, 3 and 4 show that the inserts A according to the invention exhibit much better toughness in combination with somewhat better plastic deformation resistance in comparison to the inserts B and C according to prior art.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
- Powder Metallurgy (AREA)
- Chemical Vapour Deposition (AREA)
- Carbon And Carbon Compounds (AREA)
Claims (7)
- Plaquette d'outil de coupe pour l'usinage de l'acier, comprenant un corps en carbure cémenté et un revêtement, dans laquelle le corps comprend du WC ayant une taille moyenne de grain entre 1,0 et 4,0 µm, 5 à 12 % en poids de Co et 3 à 11 % en poids de carbures cubiques des métaux Ta, Ti et W, avec une quantité de Nb inférieure ou égale à 0,1 % en poids, et une teneur en azote comprise entre 0,6 et 2 % du poids des éléments Ti et Ta,
le rapport Ta/Ti est de 2,0 à 3,0, la phase de liant Co est fortement alliée avec W avec un rapport CW de 0,80 à 0,85 et
le corps de carbure cémenté comporte une zone de surface enrichie sensiblement exempte de phase gamma d'une épaisseur de 10 à 30 µm avec une teneur en phase de liant, en volume, de 1,2 à 2 fois la teneur en phase de liant de la masse. - Plaquette d'outil de coupe selon la revendication 1, caractérisée par le fait que la teneur en Co est dans la plage allant de 9 à 11% en poids.
- Plaquette d'outil de coupe selon l'une des revendications 1 et 2, caractérisée par le fait que la teneur en TiC et TaC est dans la plage allant de 7 à 10 % en poids.
- Plaquette d'outil de coupe selon l'une quelconque des revendications 1 à 3, caractérisée par le fait que le revêtement comprend une couche TiCN en colonne de 3 à 12 µm suivie par une couche Al2O3 de 1 à 8 µm d'épaisseur.
- Plaquette d'outil de coupe selon l'une quelconque des revendications précédentes, caractérisée par le fait que la couche Al2O3 est du Al2O3-κ.
- Plaquette d'outil de coupe selon l'une quelconque des revendications 4 et 5, caractérisée par le fait que la couche la plus externe est du TiN.
- Plaquette d'outil de coupe selon les revendications précédentes, caractérisée par le fait que la couche TiN dans la ligne d'arête est enlevée par brossage ou soufflage.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE9901243 | 1999-04-08 | ||
SE9901243A SE519828C2 (sv) | 1999-04-08 | 1999-04-08 | Skär av en hårdmetallkropp med en bindefasanrikad ytzon och en beläggning och sätt att framställa denna |
Publications (3)
Publication Number | Publication Date |
---|---|
EP1043416A2 EP1043416A2 (fr) | 2000-10-11 |
EP1043416A3 EP1043416A3 (fr) | 2002-08-14 |
EP1043416B1 true EP1043416B1 (fr) | 2004-09-15 |
Family
ID=20415138
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP00106692A Expired - Lifetime EP1043416B1 (fr) | 1999-04-08 | 2000-03-29 | Plaquette de carbure frittée |
Country Status (6)
Country | Link |
---|---|
US (1) | USRE39893E1 (fr) |
EP (1) | EP1043416B1 (fr) |
JP (1) | JP2000334608A (fr) |
AT (1) | ATE276379T1 (fr) |
DE (1) | DE60013675T2 (fr) |
SE (1) | SE519828C2 (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7939013B2 (en) | 2005-04-20 | 2011-05-10 | Sandvik Intellectual Property Ab | Coated cemented carbide with binder phase enriched surface zone |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE520253C2 (sv) | 2000-12-19 | 2003-06-17 | Sandvik Ab | Belagt hårdmetallskär |
SE0103970L (sv) | 2001-11-27 | 2003-05-28 | Seco Tools Ab | Hårdmetall med bindefasanrikad ytzon |
SE526604C2 (sv) | 2002-03-22 | 2005-10-18 | Seco Tools Ab | Belagt skärverktyg för svarvning i stål |
SE526603C3 (sv) * | 2003-01-24 | 2005-11-16 | Sandvik Intellectual Property | Belagt hårdmetallskär |
SE527348C2 (sv) | 2003-10-23 | 2006-02-14 | Sandvik Intellectual Property | Sätt att tillverka en hårdmetall |
EP1609883B1 (fr) | 2004-06-24 | 2017-09-20 | Sandvik Intellectual Property AB | Outil de coupé revêtu |
SE528108C2 (sv) * | 2004-07-13 | 2006-09-05 | Sandvik Intellectual Property | Belagt hårdmetallskär, speciellt för svarvning av stål, samt sätt att tillverka detsamma |
AT502703B1 (de) * | 2005-10-28 | 2008-06-15 | Boehlerit Gmbh & Co Kg | Hartmetall für schneidplatten von kurbelwellenfräsern |
SE531670C2 (sv) | 2007-02-01 | 2009-06-30 | Seco Tools Ab | Texturerat alfa-aluminiumoxidbelagt skär för metallbearbetning |
AT12293U1 (de) | 2009-10-05 | 2012-03-15 | Ceratizit Austria Gmbh | Schneidwerkzeug zur bearbeitung metallischer werkstoffe |
DE102016107958A1 (de) * | 2016-04-28 | 2017-11-02 | Herrmann Ultraschalltechnik Gmbh & Co. Kg | Stanz-Siegeleinheit und Ultraschallbearbeitungsvorrichtung mit einer solchen |
ES2912991T3 (es) * | 2019-07-10 | 2022-05-30 | Sandvik Mining And Construction Tools Ab | Cuerpo de carburo cementado con gradiente y método de fabricación del mismo |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5487719A (en) | 1977-12-23 | 1979-07-12 | Sumitomo Electric Industries | Super hard alloy and method of making same |
US4610931A (en) | 1981-03-27 | 1986-09-09 | Kennametal Inc. | Preferentially binder enriched cemented carbide bodies and method of manufacture |
US4497874A (en) | 1983-04-28 | 1985-02-05 | General Electric Company | Coated carbide cutting tool insert |
US4729823A (en) | 1986-08-08 | 1988-03-08 | Guevara-Kelley Scientific Products, Inc. | Apparatus and methods for electrophoresis |
SE9101953D0 (sv) | 1991-06-25 | 1991-06-25 | Sandvik Ab | A1203 coated sintered body |
SE9200530D0 (sv) | 1992-02-21 | 1992-02-21 | Sandvik Ab | Haardmetall med bindefasanrikad ytzon |
SE505425C2 (sv) | 1992-12-18 | 1997-08-25 | Sandvik Ab | Hårdmetall med bindefasanrikad ytzon |
SE501527C2 (sv) | 1992-12-18 | 1995-03-06 | Sandvik Ab | Sätt och alster vid beläggning av ett skärande verktyg med ett aluminiumoxidskikt |
SE9300376L (sv) | 1993-02-05 | 1994-08-06 | Sandvik Ab | Hårdmetall med bindefasanriktad ytzon och förbättrat eggseghetsuppförande |
SE502223C2 (sv) | 1994-01-14 | 1995-09-18 | Sandvik Ab | Sätt och alster vid beläggning av ett skärande verktyg med ett aluminiumoxidskikt |
IL110663A (en) * | 1994-08-15 | 1997-09-30 | Iscar Ltd | Tungsten-based cemented carbide powder mix and cemented carbide products made therefrom |
SE504968C2 (sv) | 1994-11-15 | 1997-06-02 | Sandvik Ab | Metod att belägga ett skärverktyg med ett skikt av alfa-Al2O3 |
SE514283C2 (sv) | 1995-04-12 | 2001-02-05 | Sandvik Ab | Belagt hårmetallskär med bindefasadanrikad ytzon samt sätt för dess tillverkning |
US5786069A (en) | 1995-09-01 | 1998-07-28 | Sandvik Ab | Coated turning insert |
SE509616C2 (sv) * | 1996-07-19 | 1999-02-15 | Sandvik Ab | Hårdmetallskär med smal kornstorleksfördelning av WC |
SE516017C2 (sv) * | 1999-02-05 | 2001-11-12 | Sandvik Ab | Hårdmetallskär belagt med slitstark beläggning |
-
1999
- 1999-04-08 SE SE9901243A patent/SE519828C2/sv not_active IP Right Cessation
-
2000
- 2000-03-29 EP EP00106692A patent/EP1043416B1/fr not_active Expired - Lifetime
- 2000-03-29 DE DE60013675T patent/DE60013675T2/de not_active Expired - Lifetime
- 2000-03-29 AT AT00106692T patent/ATE276379T1/de active
- 2000-04-10 JP JP2000113257A patent/JP2000334608A/ja active Pending
-
2006
- 2006-06-08 US US11/449,014 patent/USRE39893E1/en not_active Expired - Lifetime
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7939013B2 (en) | 2005-04-20 | 2011-05-10 | Sandvik Intellectual Property Ab | Coated cemented carbide with binder phase enriched surface zone |
Also Published As
Publication number | Publication date |
---|---|
ATE276379T1 (de) | 2004-10-15 |
SE9901243D0 (sv) | 1999-04-08 |
JP2000334608A (ja) | 2000-12-05 |
DE60013675D1 (de) | 2004-10-21 |
SE519828C2 (sv) | 2003-04-15 |
EP1043416A3 (fr) | 2002-08-14 |
EP1043416A2 (fr) | 2000-10-11 |
DE60013675T2 (de) | 2005-02-10 |
SE9901243L (sv) | 2000-10-09 |
USRE39893E1 (en) | 2007-10-23 |
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