EP1043416B1

EP1043416B1 - Cemented carbide insert

Info

Publication number: EP1043416B1
Application number: EP00106692A
Authority: EP
Inventors: Anders Lenander; Mikael Lindholm
Original assignee: Sandvik AB
Current assignee: Sandvik AB
Priority date: 1999-04-08
Filing date: 2000-03-29
Publication date: 2004-09-15
Anticipated expiration: 2020-03-29
Also published as: ATE276379T1; SE9901243D0; JP2000334608A; DE60013675D1; SE519828C2; EP1043416A3; EP1043416A2; DE60013675T2; SE9901243L; USRE39893E1

Abstract

The present invention relates to a cutting tool insert for machining of steel comprising a cemented carbide body and a coating. The cemented carbide body comprises WC, 5-12 wt-% Co and 3-11 wt-% of cubic carbides of metals Ta, Ti and W. The amount of Nb is below 0.1 wt-% and the ratio Ta/Ti is 1,0-4,0. The Co-binder phase is highly alloyed with W with a CW-ratio of 0,75-0,95 and, finally, the cemented carbide body has a binder phase enriched and essentially gamma phase free surface zone of a thickness of 5-50 mu m. <IMAGE>

Description

The present invention relates to a coated cemented carbide cutting tool insert particularly useful for turning operations in steels or stainless steels, especially suited for operations with high demands regarding toughness properties of the insert. The cemented carbide insert has surface zones with element compositions differing from the bulk composition giving simultaneously an excellent toughness performance and good resistance to plastic deformation.
High performance cutting tools must nowadays possess high wear resistance, high toughness properties and good resistance to plastic deformation. Improved toughness behaviour of a cutting insert can be obtained by increasing the WC grain size and/or by raising the overall binder phase content, but such changes will simultaneously result in significant loss of the plastic deformation resistance.
Methods to improve the toughness behaviour by introducing an essentially gamma phase free and binder phase enriched surface zone with a thickness of about 20-40 µm on the inserts by a so called gradient sintering techniques have been known for some time e.g. US 4,277,283, US 4,497,874, US 4,548,786, US 4,640,931, US 5,484,468, US 5,549,980, US 5,649,279, US 5,729,823. The characteristics of these patents are that the surface zone is depleted of gamma phase and binder phase enriched.
It has now surprisingly been found that by using an optimised composition of the gamma phase i.e. a gamma phase consisting essentially of only TaC and TiC in addition to WC, by keeping the ratio between the elements Ta and Ti within specific limits and a highly W-alloyed binder phase, the toughness properties of the gradient sintered cutting inserts can be significantly improved without any loss of plastic deformation resistance.
Figure 1 is a plot showing the level of Co enrichment near the surface of an insert according to the invention.
According to the present invention there is now provided a coated cemented carbide insert with a 10-30 µm, thick essentially gamma phase free and binder phase enriched surface zone with an average binder phase content (by volume) in the range 1.2-2.0 times the bulk binder phase content. The gamma phase consists essentially of TaC and TiC and to some extent of WC dissolved into the gamma phase during sintering. The ratio Ta/Ti is 2.0-3.0.
The binder phase is highly W-alloyed. The content of W in the binder phase can be expressed as a CW-ratio = MS /(wt-% Co · 0.0161) where M_S is the measured saturation magnetisation of the cemented carbide body in kA/m and wt-% Co is the weight percentage of Co in the cemented carbide. The CW-ratio takes a value ≤1 and the lower the CW-ratio is the higher is the W-content in the binder phase. It has now been found according to the invention that an improved cutting performance is achieved if the CW-ratio is in the range 0.80-0.85.
The present invention is applicable to cemented carbides with a composition of 5-12, preferably 9-11, weight percent of Co binder phase, and 3-11, preferably 7-10, weight percent TaC + TiC and a balance WC. The Nb content should not exceed 0.1 weight percent. The weight ratio Ta/Ti should be 2.0-3.0. The WC has an average grain size of 1.0 to 4.0 µm. The cemented carbide body may contain small amounts, <1 volume-%, of η-phase (M₆C).
Inserts according to the invention are further provided with a coating consisting of basically 3-12 µm columnar TiCN-layer followed by a 1-8 µm thick Al₂O₃-layer deposited e.g. according to any of the patents US 5,766,782, US 5,654,035, US 5,674,564, US 5,702,808 preferably with a κ-Al₂O₃-layer and preferably with an outermost thin layer of TiN which preferably is removed in the edge line by brushing or by blasting.
By applying coatings with different thickness on the cemented carbide body according to the invention, the property of the coated insert can be optimised to suit specific cutting conditions. In one embodiment, a cemented carbide insert produced according to the invention is provided with a coating consisting of: 6 µm TiCN, 5 µm Al₂O₃ and 1 µm TiN. This coated insert is particularly suited for cutting operations in steel. In another embodiment, a cemented carbide insert produced according to the invention is provided with a coating consisting of: 4 µm TiCN, 2 µm Al₂O₃ and 1 µm TiN. This coating is particularly suited for cutting operations in stainless steels.
Cutting inserts according to the invention comprising a cemented carbide substrate consisting of a binder phase of Co, WC and a gamma phase from the elements Ta and Ti with a binder phase enriched surface zone essentially free of gamma phase and a coatings are made in the following way. A powder mixture containing 5-12, preferably 9-11, weight percent of binder phase consisting of Co, and 3-11, preferably 7-10, weight percent TaC + TiC and a balance WC with an average grain size of 1,0-4,0 µm, preferably 1,5-3,0 µm is prepared. The Nb content should not exceed 0,1 weight percent. The weight ratio Ta/Ti should be 1,0-4,0, preferably 2,0-3,0. Well-controlled amounts of nitrogen have to be added either through the powder as carbonitrides or/and added during the sintering process via the sintering gas atmosphere. The amount of added nitrogen will determine the rate of dissolution of the cubic phases during the sintering process and hence determine the overall distribution of the elements in the cemented carbide after solidification. The optimum amount of nitrogen to be added depends on the composition of the cemented carbide and in particular on the amount of cubic phases and varies between 0,6 and 2,0% of the weight of the elements Ti and Ta. The exact conditions depend to a certain extent on the design of the sintering equipment being used. It is within the purview of the skilled artisan to determine whether the requisite surface zone of the cemented carbide have been obtained and to modify the nitrogen addition and the sintering process in accordance with the present specification in order to obtain the desired result.
The raw materials are mixed with pressing agent and possibly W such that the desired CW-ratio is obtained and the mixture is milled and spray dried to obtain a powder material with the desired properties. Next, the powder material is compacted purview of the skilled artisan to determine whether the requisite surface zone of the cemented carbide have been obtained and to modify the nitrogen addition and the sintering process in accordance with the present specification in order to obtain the desired result.
The raw materials are mixed with pressing agent and possibly W such that the desired CW-ratio is obtained and the mixture is milled and spray dried to obtain a powder material with the desired properties. Next, the powder material is compacted and sintered. Sintering is performed at a temperature of 1300-1500°C, in a controlled atmosphere of about 50 mbar followed by cooling. After conventional post sintering treatments including edge rounding a hard, wear resistant coating according to above is deposited by CVD- or MT-CVD-technique.

Example 1

A.) Cemented carbide turning inserts of the style CNMG 120408-PM and SNMG120412-PR with the composition 9,9 wt% Co, 6,0 wt% TaC, 2,5 wt% TiC and 0,3 wt% TiN and balance WC with an average grain size of 2,0 µm were produced according to the invention. The nitrogen was added to the carbide powder as TiCN. Sintering was done at 1450 °C in an atmosphere consisting of Ar at a total pressure of about 50 mbar. Metallographic investigation showed that the produced inserts had a gamma phase free zone of 15 µm. Fig. 1 shows a plot of the Co enrichment near the surface measured by image analysis technique. The Co was enriched to a peak level of 1,3 times the bulk content. Magnetic saturation values were recorded and used for calculating CW-values. An average CW-value of 0.81 was obtained.After conventional pre coating treatment like edge honing, cleaning etc. the inserts were coated in a CVD-process comprising a first coated with a thin layer <1 µm of TiN followed by 6 µm thick layer of TiCN with columnar grains by using MTCVD-techniques (process temperature 850 °C and CH₃CN as the carbon/nitrogen source). In a subsequent process step during the same coating cycle, a 5 µm thick κ-Al₂O₃ layer was deposited according to patent US 5,674,564. On top of the κ-Al₂O₃ layer a 1.0 µm TiN layer was deposited. The coated inserts were brushed in order to smoothly remove the TiN coating from the edge line.
B.) Cemented carbide turning inserts of the style CNMG 120408-PM and SNMG120412-PR with the composition 10,0 wt% Co, 2,9 wt% TaC, 3,4 wt% TiC, 0,5 wt% NbC and 0.2 wt% TiN and balance WC with an average grain size of 2.1 µm were produced. The inserts were sintered in the same process as A. Metallographic investigation showed that the produced inserts had a gamma phase free zone of 15 µm. Magnetic saturation values were recorded and used for calculating CW-values. An average CW-value of 0.81 was obtained. The inserts were subject to the same pre-coating treatment as A, coated in the same coating process and also brushed in the same way as A.
C.) Cemented carbide turning inserts of the style CNMG 120408-PM and SNMG120412-PR with the composition 10,0 wt% Co, 3,0 wt% TaC, 6,3 wt% ZrC and balance WC with an average grain size of 2.5 µm were produced. Metallographic investigation showed that the produced inserts had a gamma phase free zone of 12 µm. Magnetic saturation values were recorded and used for calculating CW-values. An average CW-value of 0.79 was obtained. The inserts were subject to the same pre-coating treatment as A, coated in the same coating process and also brushed in the same way as A

Example 2

Inserts from A, B and C were tested with respect to toughness in a longitudinal turning operation with interrupted cuts.
Material: Carbon steel SS1312
Cutting data:
Cutting speed = 130 m/min
Depth of cut = 1,5 mm
Feed = Starting with 0,15 mm and gradually increased by 0,10 mm/min until breakage of the edge
Eight edges of each variant were tested
Inserts style: CNMG120408-PM

	Mean feed at breakage
Inserts A	0,31 mm/rev
Inserts B
	0,22 mm/rev
Inserts C
	0,22 mm/rev

Example 3

Inserts from A, B and C were tested with respect to resistance to plastic deformation in longitudinal turning of alloyed steel (AISI 4340).
Insert style: CNMG 120408-PM
Cutting data:
Cutting speed= 100 m/min
Feed= 0,7 mm/rev.
Depth of cut= 2 mm
Time in cut= 0,50 min
The plastic deformation was measured as the edge depression at the nose of the inserts.

Edge depression, µm

Insert A 49

Insert B 63

Insert C 62

Example 4

Tests performed at an end user producing rear shaft for lorries. The inserts from A and C were tested in a three turning operations with high toughness demands due to interrupted cuts. The inserts were run until breakage of the edge. The insert style SNMG120412-PR was used.

Results:

	Number of machined components
Operation
	1	2	3
Variant A	172	219	119
Variant C	20	11	50

Examples 2, 3 and 4 show that the inserts A according to the invention exhibit much better toughness in combination with somewhat better plastic deformation resistance in comparison to the inserts B and C according to prior art.

Claims

A cutting tool insert for machining of steel comprising a cemented carbide body and a coating wherein said body comprises WC with an average WC-grain size of within 1,0-4,0 µm, 5-12 wt-% Co and 3-11 wt-% of cubic carbides of metals Ta, Ti and W, with an amount of Nb of less than or equal to 0,1 weight percent, and a nitrogen content of between 0,6 and 2 % of the weight of the elements Ti and Ta,
the ratio Ta/Ti is 2,0-3,0, the Co-binder phase is highly alloyed with W with a CW-ratio of 0.80-0.85 and
the cemented carbide body has a binder phase enriched essentially gamma phase free surface zone of a thickness of 10-30 µm with a binder phase content, by volume, of 1.2-2 times the bulk binder phase content.
A cutting tool insert according to claim 1 characterised in that the Co content is within 9-11 weight percent.
A cutting tool insert according to claims 1 or 2 characterised in that the content of TiC and TaC is within 7-10 weight percent.
A cutting tool insert according to any of claims 1-3 characterised in that said coating comprises a 3-12 µm columnar TiCN-layer followed by a 1-8 µm thick Al₂O₃-layer.
A cutting tool insert according to the previous claim characterised in that the said Al₂O₃-layer is κ-Al₂O₃.
A cutting tool insert according to any of claims 4-5 characterised in an outermost layer of TiN.
A cutting tool insert according to the previous claim characterised in that the TiN layer in the edge line is removed by brushing or by blasting.