EP1037726A1 - Dispositif pour surveiller un liquide de traitement - Google Patents
Dispositif pour surveiller un liquide de traitementInfo
- Publication number
- EP1037726A1 EP1037726A1 EP98966297A EP98966297A EP1037726A1 EP 1037726 A1 EP1037726 A1 EP 1037726A1 EP 98966297 A EP98966297 A EP 98966297A EP 98966297 A EP98966297 A EP 98966297A EP 1037726 A1 EP1037726 A1 EP 1037726A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- processing liquid
- monitoring
- processing
- sensor
- determination
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 238000012545 processing Methods 0.000 title claims abstract description 48
- 239000007788 liquid Substances 0.000 title claims abstract description 39
- 238000012544 monitoring process Methods 0.000 title claims abstract description 25
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 239000000839 emulsion Substances 0.000 claims description 29
- 239000012530 fluid Substances 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- 244000005700 microbiome Species 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- 230000036284 oxygen consumption Effects 0.000 claims description 8
- 244000052616 bacterial pathogen Species 0.000 claims description 5
- 230000005540 biological transmission Effects 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 3
- 238000011156 evaluation Methods 0.000 claims description 3
- 238000003754 machining Methods 0.000 description 13
- 238000005259 measurement Methods 0.000 description 8
- 239000005068 cooling lubricant Substances 0.000 description 7
- 239000007787 solid Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 4
- 230000001580 bacterial effect Effects 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 2
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 2
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 238000005097 cold rolling Methods 0.000 description 2
- 238000011109 contamination Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000003745 diagnosis Methods 0.000 description 2
- 239000012065 filter cake Substances 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 238000005491 wire drawing Methods 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 238000013528 artificial neural network Methods 0.000 description 1
- 238000009529 body temperature measurement Methods 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000011217 control strategy Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000011157 data evaluation Methods 0.000 description 1
- 238000001739 density measurement Methods 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000013505 freshwater Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000009740 moulding (composite fabrication) Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000004171 remote diagnosis Methods 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/18—Water
- G01N33/1826—Organic contamination in water
- G01N33/1833—Oil in water
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23Q—DETAILS, COMPONENTS, OR ACCESSORIES FOR MACHINE TOOLS, e.g. ARRANGEMENTS FOR COPYING OR CONTROLLING; MACHINE TOOLS IN GENERAL CHARACTERISED BY THE CONSTRUCTION OF PARTICULAR DETAILS OR COMPONENTS; COMBINATIONS OR ASSOCIATIONS OF METAL-WORKING MACHINES, NOT DIRECTED TO A PARTICULAR RESULT
- B23Q11/00—Accessories fitted to machine tools for keeping tools or parts of the machine in good working condition or for cooling work; Safety devices specially combined with or arranged in, or specially adapted for use in connection with, machine tools
- B23Q11/10—Arrangements for cooling or lubricating tools or work
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/26—Oils; Viscous liquids; Paints; Inks
- G01N33/28—Oils, i.e. hydrocarbon liquids
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/20—Controlling water pollution; Waste water treatment
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/12—Condition responsive control
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/20—Oxygen containing
- Y10T436/207497—Molecular oxygen
- Y10T436/209163—Dissolved or trace oxygen or oxygen content of a sealed environment
Definitions
- the invention relates to a device for monitoring a machining fluid.
- a method for monitoring a machining fluid is known from US Pat. No. 5,224,051. This method is used in particular on a metal processing system, a large number of metal processing machines being provided and a centrally stored reservoir which contains the amount of aqueous cooling lubricant liquid. The metal processing machines are supplied centrally from this reservoir.
- the cooling lubricant liquid consists of lubricant and water-containing components. These components are monitored and measurement signals are generated which are sent to an analysis device. Based on the analysis, the content of a component in the monitored liquid is modified.
- the method described in the cited patent shows a device with which the content of dissolved oxygen is determined as an indication of microorganisms.
- the conductivity, the pH value and the temperature are also determined.
- no information is given on the correlation between oxygen consumption and microorganism contamination.
- a disadvantage of this system is that the reliable assignment of the measurement data to the components of the processing fluid is not possible. It is therefore very difficult to add additional components or modify the processing fluid.
- a disadvantage of this known device is that certain parameters in the liquid are very difficult to detect. So z. B. the determination of the microorganisms contained in the liquid is often only possible indirectly. There is also a risk that due to solids and chemically dissolved substances in the processing liquid, the measurement signal is falsified or the functionality of the sensor is impaired.
- the invention has for its object to provide a device for monitoring a machining fluid that is suitable, even under difficult conditions, ie. H. Detect several components in the liquid, even with machining liquids that are contaminated with solids and chemically contaminated.
- the main advantage of the invention is that a device for maintaining the functionality of the sensor or sensors is initially provided. Meaningful measured values can only be determined if the sensor properties are continuously analyzed. The measured values arrive at a device for processing the monitoring signals in order to influence the composition of the processing liquid directly or indirectly from these processed signals.
- This device ensures optimum stabilization of the processing fluid and thus ensures a long service life for this fluid.
- a PT 100 sensor is suitable for temperature measurement.
- the concentration of the processing liquid can be determined from the combination of the refractive index with the density or the UV haze with the density.
- Foreign oil can also be determined using a combination of refractive index and density or turbidity and density.
- Aerobic germs can be determined using a corresponding O 2 sensor.
- the pH value is usually sensed with a PH electrode, the conductivity with a Conductivity sensor.
- the corrosiveness of the machining fluid can be determined with a redox electrode.
- composition of the processing fluid is influenced, for example, by predetermined control algorithms using an expert system or by means of neural networks. It is of course also conceivable to use fuzzy logic which carries out an optimization process with regard to the quality of the processing fluid.
- the processing liquid is expediently monitored in a treatment tank.
- This monitoring can, for. B. by a mobile service device, which is suitable for field use.
- a mobile service device which is suitable for field use.
- different device variants are conceivable, such as. B. a semi-mobile device that supplies the determined data to a remote diagnosis.
- the processing liquid is monitored in one or more processing containers. It is also possible to arrange containers in the bypass of a processing container in order to ensure particularly favorable environmental conditions there.
- sensors can be used which sense the loading of the processing liquid with solid particles. It is also expedient to measure the microorganisms, the pH or the corrosivity or other relevant variables such as germs, yeasts, bacteria, abrasiveness, nitrate, nitrite, water hardness, disruptive ions, dispersed air, foam, foreign oil, foreign substances, temperature, conductivity to determine in the machining fluid.
- a further development of the invention aims to carry out remote data transmission; Monitoring signals are sent to one or more devices for evaluation via these, for example via a corresponding modem; Integrated data evaluation is also possible.
- a filter system for mechanical cleaning is provided in an advantageous embodiment of the invention.
- This filter system consists, for example, of a belt filter system or a vacuum filter as well as other suitable systems / devices and peripheral devices. If the processing liquid has to be separated into certain components, for example for disposal, a system can be provided in a further embodiment of the invention, which performs, for example, an emulsion splitting.
- Such systems usually work on a membrane basis (ultrafiltrate), but also on a thermal or chemical basis.
- An important component in the device for monitoring machining fluid is the detection of an aerobic attack. This correlates with the oxygen consumption in the machining fluid.
- the oxygen consumption caused by aerobic germs is directly related to the bacterial count (microbiologically expressed in column-forming units per milliliter).
- the oxygen consumption is temperature-dependent. It is therefore useful to determine the correlation between oxygen consumption, bacterial count and temperature.
- the oxygen consumption can only be determined in a closed system. It is therefore necessary to supply the processing liquid separately to a sample container and to carry out the measurement of the oxygen consumption there.
- FIG. 1 shows a processing plant for processing liquid
- Figure 2 shows an integrated system concept for monitoring and processing the
- FIG. 3 shows the schematic representation of the sensors for recording the data of a processing liquid.
- the preparation system according to FIG. 1 shows several machine tools 10, 11, 12, 13 in a schematic representation. Machining liquid, in particular a cooling lubricant emulsion, is fed to these machine tools via line 14.
- Machining liquid in particular a cooling lubricant emulsion
- the cooling lubricant emulsion which is loaded with solids or dirt particles and other contaminants, reaches an emulsion preparation 16 via line 15 Filter system 19 the removal of very fine particles from the emulsion.
- the cleaned and prepared emulsion arrives in a collecting tank 20 and is again available for the processing process.
- the cooling lubricant emulsion is transported via feed pumps, not shown here.
- FIG. 2 shows a device for monitoring the processing liquid.
- the machine tools 10, 11, 12, 13 are to be supplied with prepared emulsion via the line 14.
- the contaminated emulsion is fed via line 15 to the emulsion preparation and emulsion care 16.
- the processed emulsion is available in a tank 20.
- measured variables are now determined using suitable sensors. This is one or the following of the following parameters: temperature, pH, concentration, conductivity, corrosiveness, corrosion protection, foreign oil, solid particles, foreign substances, microorganisms, germs, yeasts, bacteria, abrasiveness, nitrate, nitrite, water hardness, disturbing Ions, dispersed air, foam chloride.
- other measured variables can also be determined using suitable sensors.
- This diagnosis system has the task of analyzing the condition of the coolant medium by comparing the actual values with predefined target values, recognizing trends with regard to the course of the actual values and possibly possible Control strategies developed. Of course, an evaluation of the measured variables is also possible on site.
- interventions in the emulsion for emulsion preparation or for emulsion maintenance take place directly or via remote data transmission.
- the interventions can also be carried out manually, ie certain components of the emulsion are changed by visual monitoring of the data. So will for example, the emulsion is cleaned according to its degree of contamination by a filter system 21. 22 foreign oil is removed from the emulsion via a corresponding system. Another filter system 23 is able to remove very fine particles from the emulsion.
- a system 24 for reducing the microorganisms is also controlled via the diagnostic system 30. The pH value is adjusted or regulated via a system 25.
- the corrosivity can be changed via a system 26, the temperature via a suitable device 27 and the concentration of the emulsion, ie the ratio between water and oil is controlled via a system 28. Further process steps can also be carried out, the possibility with the block box 40 is indicated in FIG.
- the processing of the cooling lubricant emulsion is also independent of the type of machining process on the machine tools. It is irrelevant whether the machine tools carry out a uniform or different machining process, the emulsion is only monitored and optimized according to its properties. Also in machining processes such as wire drawing, cold rolling, forming manufacturing processes.
- the measurement variables can be diagnosed automatically.
- the entire device for monitoring the processing liquid can have a device 31 for filter cake dewatering or for grinding sludge oil removal as an additional system.
- the solid fraction from this device is fed to a chip washing system via a line 32 or a conveyor device.
- the de-oiled chips go to a corresponding collecting device or to a recycling plant.
- the liquid fraction from the filter cake dewatering or from the chip washing system passes via lines 33, 34 to a device 35 for emulsion splitting.
- the waste emulsion from the tank 20 can be fed to this device via the line 36.
- the emulsion cleavage carries out a separation between oil and water, the oil passes via a line 37 to a treatment plant, not shown here.
- the water can can be returned via line 38 to tank 20.
- Fresh water or emulsion concentrate can additionally be supplied to the tank via a line 39.
- Sensors arranged in the tank 30 are provided with one or more suitable devices which maintain the functionality of the sensors. This can be a washing device, a corresponding cleaning device or the like. The sensors are calibrated at regular intervals, ie the diagnostic system 30 checks and corrects the sensor-specific signals.
- a partial flow from a container 20 with processing liquid reaches the temperature sensor via a valve 50.
- a density measurement is then carried out with the sensor 52 and the conductivity is measured with the sensor 53.
- a sensor 54 is provided to determine the turbidity.
- the sensor 55 is a redox transmitter for determining the corrosion behavior.
- valves 59, 60, 61 there are three valves 59, 60, 61 in the circuit.
- the valves 59, 60 are closed and the valve 61 is open.
- valve 61 is closed and valves 59, 60 are opened.
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Pathology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Mechanical Engineering (AREA)
- Auxiliary Devices For Machine Tools (AREA)
- Lubricants (AREA)
- Apparatus Associated With Microorganisms And Enzymes (AREA)
Abstract
L'invention concerne un dispositif permettant de surveiller un liquide de traitement, qui comprend un détecteur pour produire au moins un signal de surveillance. Il est également prévu un dispositif servant à détecter, mémoriser et maintenir la fiabilité de fonctionnement du détecteur et un dispositif destiné à traiter le signal de surveillance et à produire un signal pour influer indirectement ou directement sur la composition du liquide de traitement, ainsi que des actionneurs pour convertir des critères et des valeurs théoriques prédéterminés.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19755477 | 1997-12-13 | ||
| DE19755477A DE19755477A1 (de) | 1997-12-13 | 1997-12-13 | Einrichtung zur Überwachung einer Bearbeitungsflüssigkeit |
| PCT/EP1998/008077 WO1999030869A1 (fr) | 1997-12-13 | 1998-12-11 | Dispositif pour surveiller un liquide de traitement |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| EP1037726A1 true EP1037726A1 (fr) | 2000-09-27 |
Family
ID=7851815
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP98966297A Withdrawn EP1037726A1 (fr) | 1997-12-13 | 1998-12-11 | Dispositif pour surveiller un liquide de traitement |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US6555379B1 (fr) |
| EP (1) | EP1037726A1 (fr) |
| DE (1) | DE19755477A1 (fr) |
| WO (1) | WO1999030869A1 (fr) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102007038603A1 (de) * | 2007-08-16 | 2009-02-19 | Volkswagen Ag | Vorrichtung und Verfahren zum Analysieren und Dosieren von Kühlschmierstoff-Emulsion |
| DE102010028319A1 (de) * | 2010-04-28 | 2011-11-03 | Zf Friedrichshafen Ag | Verfahren und Vorrichtung zur Steuerung der Konzentration wassergemischter Kühlschmierstoffe |
| DE102010035228A1 (de) * | 2010-08-24 | 2012-03-01 | Technotrans Ag | Kühlschmiermittelzuführeinrichtung |
| JP6309936B2 (ja) | 2015-11-17 | 2018-04-11 | ファナック株式会社 | クーラント監視機能を有する制御装置 |
| GB2547056B (en) * | 2016-04-04 | 2018-03-28 | Jemtech Uk Ltd | A system for determining the condition of a fluid in a tank, an apparatus including the system and a method for managing the condition of the fluid |
| JP7395105B2 (ja) * | 2018-03-28 | 2023-12-11 | 株式会社山本金属製作所 | 冷却液良否管理システム及び冷却液良否検出ユニット |
| CN109822392A (zh) * | 2019-02-22 | 2019-05-31 | 合肥齐泰光电科技有限公司 | 用于光机电一体机的流量分配系统 |
| FI131645B1 (fi) * | 2021-03-19 | 2025-08-19 | Spesnes Oy | Laite ja menetelmä prosessinesteen käsittelemiseksi |
| WO2023121511A1 (fr) * | 2021-12-21 | 2023-06-29 | Общество с ограниченной ответственностью "Центр эффективных производственных решений" | Station automatique de surveillance et de correction de paramètres de liquide de lubrification-refroidissement |
| US11951578B1 (en) * | 2022-12-02 | 2024-04-09 | National Kaohsiung University Of Science And Technology | Cutting fluid digital monitoring management system and method |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3565786A (en) * | 1968-11-08 | 1971-02-23 | Texaco Inc | Method and apparatus for controlling the composition of fluids |
| US3750847A (en) * | 1972-05-03 | 1973-08-07 | Master Chemical Corp | Method of supplying an aqueous cutting fluid to machine tools |
| US4053743A (en) * | 1976-02-18 | 1977-10-11 | Antti Johannes Niemi | Method for controlling the ph and other concentration variables |
| JPS5814836B2 (ja) * | 1978-03-27 | 1983-03-22 | 株式会社明電舎 | 活性汚泥の動力学的性質測定装置 |
| US5224051A (en) * | 1989-05-19 | 1993-06-29 | Cincinnati Milacron, Inc. | Fluid condition monitoring and controlling system for a metalworking fluid central system |
| US5506791A (en) * | 1989-12-22 | 1996-04-09 | American Sigma, Inc. | Multi-function flow monitoring apparatus with multiple flow sensor capability |
| DE4005627A1 (de) * | 1990-02-22 | 1991-08-29 | Henkel Kgaa | Aufbereitungssystem fuer kuehlschmierstoffe |
| GB9119382D0 (en) * | 1991-09-11 | 1991-10-23 | Knight Scient Ltd | Apparatus for monitoring liquids |
| CA2131318A1 (fr) * | 1992-03-11 | 1993-09-16 | Henricus Lambertus Franciscus Maria Spanjers | Methode d'etalonnage des sondes |
| DE4306184A1 (de) * | 1993-02-27 | 1994-09-01 | Joerg Doerpinghaus | Vorrichtung zum kontinuierlichen Erfassen physikalischer und/oder chemischer Parameter von Flüssigkeiten |
| US5518590A (en) * | 1994-06-21 | 1996-05-21 | Pennzoil Products Company | Electrochemical sensors for motor oils and other lubricants |
| GB2295232B (en) * | 1994-11-15 | 1999-05-05 | Boghos Awanes Manook | Continuous multi-parameter monitoring of liquids with a novel sensor cleaning and calibration system |
| JPH0985577A (ja) * | 1995-09-20 | 1997-03-31 | Exedy Corp | 水溶性切削油の自動管理装置 |
| WO1997043027A1 (fr) * | 1996-05-16 | 1997-11-20 | Baker Hughes Incorporated | Technique de commande pour epaississeurs, clarificateurs et decanteurs et appareil correspondant |
| US5832411A (en) * | 1997-02-06 | 1998-11-03 | Raytheon Company | Automated network of sensor units for real-time monitoring of compounds in a fluid over a distributed area |
-
1997
- 1997-12-13 DE DE19755477A patent/DE19755477A1/de not_active Withdrawn
-
1998
- 1998-12-11 EP EP98966297A patent/EP1037726A1/fr not_active Withdrawn
- 1998-12-11 US US09/581,421 patent/US6555379B1/en not_active Expired - Fee Related
- 1998-12-11 WO PCT/EP1998/008077 patent/WO1999030869A1/fr not_active Ceased
Non-Patent Citations (1)
| Title |
|---|
| See references of WO9930869A1 * |
Also Published As
| Publication number | Publication date |
|---|---|
| WO1999030869A1 (fr) | 1999-06-24 |
| DE19755477A1 (de) | 1999-06-17 |
| US6555379B1 (en) | 2003-04-29 |
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