EP0969078A2 - Procédé de traitement de surfaces métalliques embouties - Google Patents

Procédé de traitement de surfaces métalliques embouties Download PDF

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Publication number
EP0969078A2
EP0969078A2 EP99203252A EP99203252A EP0969078A2 EP 0969078 A2 EP0969078 A2 EP 0969078A2 EP 99203252 A EP99203252 A EP 99203252A EP 99203252 A EP99203252 A EP 99203252A EP 0969078 A2 EP0969078 A2 EP 0969078A2
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EP
European Patent Office
Prior art keywords
drying
cans
lubricant
castor oil
forming composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Application number
EP99203252A
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German (de)
English (en)
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EP0969078A3 (fr
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Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel Corp
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Henkel Corp
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Publication date
Application filed by Henkel Corp filed Critical Henkel Corp
Publication of EP0969078A2 publication Critical patent/EP0969078A2/fr
Publication of EP0969078A3 publication Critical patent/EP0969078A3/fr
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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
    • C—CHEMISTRY; METALLURGY
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    • C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
    • C10M107/20—Lubricating compositions characterised by the base-material being a macromolecular compound containing oxygen
    • C10M107/30—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M107/32—Condensation polymers of aldehydes or ketones; Polyesters; Polyethers
    • C10M107/34—Polyoxyalkylenes
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    • C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
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    • C10M125/00—Lubricating compositions characterised by the additive being an inorganic material
    • C10M125/18—Compounds containing halogen
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    • C10M129/04—Hydroxy compounds
    • C10M129/06—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
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    • C10M129/40—Carboxylic acids; Salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having 8 or more carbon atoms monocarboxylic
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    • C10M129/52—Carboxylic acids; Salts thereof having carboxyl groups bound to a carbon atom of a six-membered aromatic ring polycarboxylic
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/063—Complexes of boron halides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/065—Organic compounds derived from inorganic acids or metal salts derived from Ti or Zr
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/066—Organic compounds derived from inorganic acids or metal salts derived from Mo or W
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/30—Refrigerators lubricants or compressors lubricants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/32—Wires, ropes or cables lubricants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/34—Lubricating-sealants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/36—Release agents or mold release agents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/38—Conveyors or chain belts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/40—Generators or electric motors in oil or gas winning field
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/42—Flashing oils or marking oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/44—Super vacuum or supercritical use
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/50—Medical uses
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2050/00—Form in which the lubricant is applied to the material being lubricated
    • C10N2050/01—Emulsions, colloids, or micelles

Definitions

  • This invention relates to processes and compositions which accomplish at least one, and most preferably all, of the following related objectives when applied to formed metal surfaces, more particularly to the surfaces of cleaned aluminum and/or tin plated cans: (i) reducing the coefficient of static friction of the treated surfaces after drying of such surfaces, without adversely affecting the adhesion of paints or lacquers applied thereto; (ii) promoting the drainage of water from treated surfaces, without causing "water-breaks", i.e., promoting drainage that results in a thin, continuous film of water on the cans, instead of distinct water droplets separated by the relatively dry areas called "water-breaks" between the water droplets; and (iii) lowering the dryoff oven temperature required for drying said surfaces after they have been rinsed with water.
  • Aluminum cans are commonly used as containers for a wide variety of products. After their manufacture, the aluminum cans are typically washed with acidic cleaners to remove aluminum fines and other contaminants therefrom. Environmental considerations and the possibility that residues remaining on the cans following acidic cleaning could influence the flavor of beverages packaged in the cans has led to an interest in alkaline or acid cleaning to remove such fines and contaminants.
  • cleaning of aluminum cans generally results in differential rates of metal surface etch on the outside versus on the inside of the cans. For example, optimum conditions required to attain an aluminum fine-free surface on the inside of the cans usually leads to can mobility problems on conveyors because of the increased roughness on the outside can surface.
  • Aluminum cans that lack a low coefficient of static friction (hereinafter often abbreviated as "COF") on the outside surface usually do not move past each other and through the trackwork of a can plant smoothly. Clearing the jams resulting from failures of smooth flow is inconvenient to the persons operating the plant and costly because of lost production.
  • COF of the internal surface is also important when the cans are processed through most conventional can decorators. The operation of these machines requires cans to slide onto a rotating mandrel which is then used to transfer the can past rotating cylinders which transfer decorative inks to the exterior surface of the cans. A can that does not slide easily on or off the mandrel can not be decorated properly and results in a production fault called a "printer trip".
  • the current trend in the can manufacturing industry is directed toward using thinner gauges of aluminum metal stock.
  • the down-gauging of aluminum can metal stock has caused a production problem in that, after washing, the cans require a lower drying oven temperature in order to pass the column strength pressure quality control test.
  • lowering the drying oven temperature resulted in the cans not being dry enough when they reached the printing station, and caused label ink smears and a higher rate of can rejects.
  • One means of lowering the drying oven temperature would be to reduce the amount of water remaining on the surface of the cans after water rinsing.
  • it is advantageous to promote the drainage of rinse water from the treated can surfaces.
  • it is generally important to prevent the formation of surfaces with water-breaks as noted above.
  • Such water-breaks give rise to at least a perception, and increase the possibility in reality, of non-uniformity in practically important properties among various areas of the surfaces treated.
  • a process comprising the steps of cleaning an aluminum can with an aqueous acidic or alkaline cleaning solution, drying the cleaned can, and subsequently conveying the cleaned and dried can via automatic conveying equipment to a location where it is lacquered or decorated by printing or both, characterized by contacting at least one exterior surface of said aluminum can, prior to the last drying of said exterior surface before automatic conveying, with a lubricant and surface conditioner forming composition comprising ethoxylated, hydrogenated castor oil triglycerides, and drying the can without subsequent rinsing, thereby forming a film on the can surface to provide the surface of the can after drying with a coefficient of static friction that is not more than 1.5, preferably not more than 1.2, more preferably not more than 1.0, still more preferably not more than 0.80, and is less than the COF that would be obtained by an otherwise identical sequence of treatments except that the lubricant and surface conditioner forming composition is substituted with water only, characterized in that the lubricant and surface conditioner forming composition is
  • Preferred alkoxylated, especially ethoxylated, castor oil triglycerides that are commercially available include Trylox® 5900, Trylox® 5902, Trylox® 5904, Trylox® 5906, Trylox® 5907, Trylox® 5909, Trylox® 5918, and preferred hydrogenated castor oil derivatives include commercial materials such as Trylox® 5921 and Trylox® 5922, all available from Henkel Corporation. These materials are particularly useful as additives to final stage rinses, because they provide a dried lubricant and surface conditioner film on the treated surface that resists rise of the COF with heating beyond the minimum necessary to dry the surface.
  • Additional improvements can often be achieved, particularly for lubricant and surface condition treatments applied before the final contact of the treated surface with an aqueous composition, by using an inorganic material selected from metallic or ionic zirconium, titanium, cerium, aluminum, iron, vanadium, tantalum, niobium, molybdenum, tungsten, hafnium or tin to produce a film combining one or more of these metals with one or more of the above-described organic materials.
  • an inorganic material selected from metallic or ionic zirconium, titanium, cerium, aluminum, iron, vanadium, tantalum, niobium, molybdenum, tungsten, hafnium or tin to produce a film combining one or more of these metals with one or more of the above-described organic materials.
  • a thin film is produced having a coefficient of static friction that is not more than 1.5, preferably not more than 1.2, more preferably not more than 1.0, or still more preferably not more than 0.80, and is less than the coefficient without such film, thereby improving can mobility in high speed conveying without interfering with subsequent lacquering, other painting, printing, or other similar decorating of the containers.
  • Preferred surfactants include ethoxylated and non-ethoxylated sulfated or sulfonated fatty alcohols, such as lauryl and coco alcohols.
  • Suitable are a wide class of anionic, non-anionic, cationic, or amphoteric surfactants.
  • Alkyl polyglycosides such as C 8 - C 18 alkyl polyglycosides having average degrees of polymerization between 1.2 and 2.0 are also suitable.
  • surfactants suitable in combination are ethoxylated nonyl and octyl phenols containing from 1.5 to 100 moles of ethylene oxide, preferably a nonylphenol condensed with from 6 to 50 moles of ethylene oxide such as Igepal® CO-887 available from Rhone-Poulenc; alkyl/aryl polyethers, for example, Triton® DF-16; and phosphate esters of which Triton® H-66 and Triton® QS-44 are examples, all of the Triton® products being available from Union Carbide Co., and Ethox® 2684 and Ethfac® 136, both available from Ethox Chemicals Inc., are representative examples; polyethoxylated and/or polypropoxylated derivatives of linear and branched alcohols and derivatives thereof, as for example Trycol® 6720 (Henkel Corp.), Surfonic® LF-17 (Texaco) and Antarox® LF-330 (Rhone-Poulen
  • the lubricant and surface conditioner n accordance with this invention may comprise a phosphate acid ester or preferably an ethoxylated alkyl alcohol phosphate ester.
  • phosphate esters are commercially available under the trade name Gafac® PE 510 from GAF Corporation, Wayne, NJ, and as Ethfac® 136 and Ethfac® 161 from Ethox Chemicals, Inc., Greenville, SC.
  • the organic phosphate esters may comprise alkyl and aryl phosphate esters with and without ethoxylation.
  • the lubricant and surface conditioner for aluminum cans may be applied to the cans during their wash cycle, during one of their treatment cycles such as cleaning or conversion coating, during one of their water rinse cycles, or during their final water rinse cycle.
  • the lubricant and surface conditioner may be applied to the cans after their final water rinse cycle, i.e., prior to oven drying, or after oven drying, by fine mist application from water or another volatile non-inflammable solvent solution. It has been found that the lubricant and surface conditioner is capable of depositing on the surface to provide it with the desired characteristics.
  • the lubricant and surface conditioner may be applied by spraying and interacts with the surface through chemisorption or physiosorption to provide it with the desired dried lubricant and surface conditioner film.
  • the amount of lubricant and surface conditioner to be applied to the cans should be sufficient to reduce the coefficient of static friction on the outside surface of the cans to a value of about 1.5 or lower, and preferably to a value of about 1 or lower. Generally speaking, such amount should be on the order of from about 3 mg/m 2 to about 60 mg/m 2 of lubricant and surface conditioner on the outside surface of the cans.
  • Uncleaned aluminum cans from an industrial can manufacturer are washed clean in examples Type A with alkaline cleaner available from Parker+Amchem Division, Henkel Corporation, Madison Heights, Michigan, employing the Ridoline® 3060/306 process and in Examples Type B with an acidic cleaner, Ridoline® 125 CO from the same company.
  • a lubricant and surface conditioner composition comprising one of the following (i) about a 1 % by weight aqueous solution in deionized water of active organic material (I) as specified in Table 2 below; (ii) about 1 % of the active organic (I) in deionized water plus about 2 gm/l (0.2 %) of the inorganic constituent (II) as specified in Table 2; (iii) about 1% active organic (I) in deionized water plus about 0.5 % of surfactant (III) as specified in Table 2; (iv) about 1 % active organic (I), about 0.2% inorganic (II), and about 0.5% surfactant (III) as specified in Table 2.
  • compositions of the aqueous lubrication and surface conditioning treatment in this group the ones containing inorganic constituent (II) from Table 2 are applied in Stage 4 as defined above, while those not containing this ingredient are applied immediately before final drying.
  • the cans after drying are evaluated for their coefficient of static friction using a custom built slip time tester.
  • This apparatus consisted of three timing stations attached to a motor driven inclinable ramp. Two cans are placed horizontally in each station and a third placed on top of them in the opposite direction. This procedure insures that the burr on the cut edge of the cans does not interfere with the motion of the cans. The test begins as the ramp is raised toward the vertical. The elapsed time from the start of the ramps movement to the time when the third can slides is recorded as the "Slip Time".
  • COF (Static) Coefficient of Friction
  • the COF produced on the surface is less than 1.5.
  • Dome staining was evaluated by first removing the domes from the treated cans with a can opener. The domes were then placed in a water bath containing 0.2 g/L of borax at 65.6° C for 30 minutes, then rinsed in deionized water and dried in an oven. Staining resistance was evaluated visually by comparison with known satisfactory and unsatisfactory standards. Results are shown in Table 7. The last two conditions shown in the Table are highly satisfactory with respect to both COF and dome staining resistance during pasteurization.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Metallurgy (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Engineering & Computer Science (AREA)
  • Lubricants (AREA)
  • Detergent Compositions (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Chemically Coating (AREA)
  • Chemical Treatment Of Metals (AREA)
EP99203252A 1992-07-08 1993-07-08 Procédé de traitement de surfaces métalliques embouties Withdrawn EP0969078A3 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US910483 1986-09-23
US91048392A 1992-07-08 1992-07-08
EP93916982A EP0649458A4 (fr) 1992-07-08 1993-07-08 Conditionnement de surface et lubrification aqueuse pour surfaces metalliques travaillees.
PCT/US1993/006359 WO1994001517A1 (fr) 1992-07-08 1993-07-08 Conditionnement de surface et lubrification aqueuse pour surfaces metalliques travaillees

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JP (1) JPH07509261A (fr)
CN (1) CN1085244A (fr)
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BR (1) BR9306696A (fr)
CA (1) CA2135920A1 (fr)
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MX9606330A (es) * 1994-06-13 1997-03-29 Du Pont Composicion inhibidora de corrosion para acero.
DE4441710A1 (de) * 1994-11-23 1996-05-30 Henkel Kgaa Korrosionsschutz und Reibungsverminderung von Metalloberflächen
US5935348A (en) * 1995-11-14 1999-08-10 Henkel Kommanditgesellschaft Auf Aktien Composition and process for preventing corrosion and reducing friction on metallic surfaces
GB9625652D0 (en) * 1996-12-11 1997-01-29 Novamax Technologies Limited The treatment of aluminium surfaces
CN1065787C (zh) * 1998-03-11 2001-05-16 日石三菱株式会社 拉深展薄罐的生产方法
US6190738B1 (en) 1999-04-07 2001-02-20 Ppg Industries Ohio, Inc. Process for cleaning a metal container providing enhanced mobility
US6821633B2 (en) 2002-05-17 2004-11-23 Henkel Kommanditgesellschaft Auf Aktien (Henkel Kgaa) Non-chromate conversion coating compositions, process for conversion coating metals, and articles so coated
CN1309812C (zh) * 2004-07-06 2007-04-11 中国石油化工集团公司 一种润滑油组合物及其应用
US7741257B2 (en) 2005-03-15 2010-06-22 Ecolab Inc. Dry lubricant for conveying containers
US7745381B2 (en) 2005-03-15 2010-06-29 Ecolab Inc. Lubricant for conveying containers
EP2619296B1 (fr) 2010-09-24 2020-01-22 Ecolab USA Inc. Procede de lubrification d'un transporteur
EP2589647A1 (fr) * 2011-11-04 2013-05-08 Basf Se Polyétheramines quaternisées et leur utilisation en tant qu'additifs dans des carburants et des lubrifiants
JP5885578B2 (ja) * 2012-05-14 2016-03-15 株式会社クラレ 潤滑剤
CN105164032B (zh) 2013-03-11 2018-02-02 艺康美国股份有限公司 使用油或水包油乳液润滑转移板
US10435806B2 (en) 2015-10-12 2019-10-08 Prc-Desoto International, Inc. Methods for electrolytically depositing pretreatment compositions
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MD960241A (ro) 1998-04-30
CA2135920A1 (fr) 1994-01-20
AU4665493A (en) 1994-01-31
AU675800B2 (en) 1997-02-20
ZA934846B (en) 1994-02-03
BR9306696A (pt) 1998-12-08
JPH07509261A (ja) 1995-10-12
EP0649458A4 (fr) 1996-02-14
WO1994001517A1 (fr) 1994-01-20
CN1085244A (zh) 1994-04-13
EP0649458A1 (fr) 1995-04-26
MX9304090A (es) 1994-03-31

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