CN1085244A - 成型金属表面的水性润滑兼表面调节处理 - Google Patents

成型金属表面的水性润滑兼表面调节处理 Download PDF

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CN1085244A
CN1085244A CN93109893A CN93109893A CN1085244A CN 1085244 A CN1085244 A CN 1085244A CN 93109893 A CN93109893 A CN 93109893A CN 93109893 A CN93109893 A CN 93109893A CN 1085244 A CN1085244 A CN 1085244A
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Prior art keywords
jar
alkoxylate
described method
acid
lubricant
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S·B·阿瓦德
T·L·凯利
G·L·罗克福特
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Henkel Corp
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Henkel Corp
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    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/34Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
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Abstract

一种用于成型金属表面,特别是饮料容器表面的 润滑剂兼表面调理剂,其降低所述金属表面的静摩擦 系数并能够使所述金属表面在较低的温度下干燥。 该调理剂包括选自如下的水溶性有机物:磷酸酯,醇 类,一元、二元、三元及多元脂肪酸,诸如盐类的脂肪 酸衍生物,羟基酸、酰胺、酯类、醚类及其衍生物;以及 它们的混合物。

Description

本发明涉及一些方法和组合物,当将其应用于成形金属表面,更具体是,当应用于洁净铝罐和/或镀锡罐表面时,可达到至少一个且最佳为所有下述目的:(ⅰ)在处理过的表面干燥后,降低这类表面的静磨擦系数,而不会对施于其上的油漆或清漆的粘附力有不利影响;(ⅱ)促进水从已处理处理表面上排流而不形成“破水膜”,即促成罐面上所形成的薄而连续水膜,而不是滴液流间被称为“破水膜”的较干区域所分开的间断滴液流的排流;及(ⅲ)降低用于烘干以水清洗过的所述表面所需的温度。
以下的讨论主要针对铝罐,因其代表了本发明的最大应用范围。然而,应当理解,加以显而易见的必要改进后,上述讨论也适用于镀锡钢罐及其它类型的成形金属表面,因为本发明预定的上述各目的中的任何一个目的都具有实际意义。
铝罐普遍用作许多种产品的容器。铝罐制成后,一般用酸性清洁剂洗涤,以去除铝屑及其表面上的其它污染物。由于环境因素以及酸性清洗后留在罐上的残留物会影响罐内所装饮料味道的可能性,使人们对去除这类碎屑及污染物的碱性或酸性清洗产生了兴趣。然而,铝罐的这种清洗处理,其外部与内部比较,通常产生不同的金属表面侵蚀速率。例如,使罐内获得无碎铝屑的表面所要求的最佳条件,通常由于提高了罐筒外表面粗糙度而带来罐筒在传送机上移动的问题。
外表面静磨擦系数(下文中常缩写为“COF”)不够低的铝罐,通常不能平滑地相互移过和平滑地移动通过制罐车间的导轨装置。清除因移动不畅所致的阻塞,给车间操作人员带来不便,且由于产量的损失而提高了成本。当罐筒的加工通过最为惯用的罐筒美饰器进行时,内表面的COF也很重要。这些机器的操作要求罐筒滑移到一旋转芯棒上,然后用该芯棒传送罐筒通过多个滚筒,这些滚筒将美饰印剂转印到罐筒外表面上。不能容易地滑上或滑脱芯棒的罐筒便不能正确地加以美饰,造成称做“印机脱节”的生产缺陷。除直接产生这类印机脱节的误载罐外,作为印制机和传送系统机构失配的后果,该误载罐前、后的三到四个罐筒通常要失去美饰的机会。由于近年来线速度已提高至现已通用的约1200-1500个罐筒/分钟的水平,阻塞和印机脱节现象便成为越来越棘手的难题。因此,在罐筒加工,特别是铝罐筒加工工业中,需要通过改变罐筒内、外表面的COF来改善其移动性。
改变罐筒表面性能时所考虑的重要方面,是担心待美饰罐筒送往印刷或印标签工位时,这些改变会对罐筒的性能有碍或有相反作用。例如,清洗罐筒后,在其外表面上印制标签,并在其内表面上喷漆。在这一情况下,油漆和喷漆的粘附力就特别重要。因而,本发明的一个目的就是在对油漆、美饰印剂、喷漆或类似物料不产生不良作用的前提下来改进移动性。
另外,当前罐筒加工工业的发展方向是趋向使用更薄规格的铝金属原料。洗涤之后,为通过罐筒强度压力质量控制试验,罐筒仅要求较低的烘干炉温度,而使用薄规格铝罐金属原料便由此产生一个生产上的问题。然而,降低烘干炉温度使得罐筒抵达印饰工位时仍不能充分干燥,还造成标签印剂模糊及罐筒较高的报废率。
降低烘干炉温的一个措施即是用水漂洗后减少保留在罐筒表面的水量。因此,促进漂洗水自所处理的罐筒表面排除,是有益的。然而,为能如此,一般来说重要的是防止形成如前所述的带有破水膜的表面。这样的破水膜位于所处理表面的不同部位上,至少使人觉察到一些重要性能根本不一致,且事实上也增加了这种不一致的可能性。
因此,理想的是,提供一种改善铝罐通过各别过滤器和印刷机迁移性的方法,以提高产量、减少在线阻塞、极大地缩短生产时间、降低罐筒废品率、改善或至少不有害地影响印剂的附着性并能够降低罐筒洗后烘干的烘箱温度。
在现行的最为广泛应用的工业实践中,至少就大规模生产操作而言,铝罐一般要经历六道顺序的清洗和漂洗工序,如下面表1所述。
表1
阶段序号 各阶段对表面的作用
1 用含酸水液预清洗
2 用含酸水液和表面活性剂清洗
3 用自来水漂洗
4 用弱酸二次后续清洗、转化覆层或用自来水漂洗
5 用自来水漂洗
6 用去离子(“DI”)水漂洗
通过抑或在上述阶段4抑或阶段6使用适宜的表面活性剂,通常有可能使生产的罐筒满意地移动且使随后施于其上的印剂和/或喷漆具有足够的附着力。用于阶段6中的优选处理剂在美国专利4,944,889和4,859,351中已有记述,且其中的一些可以商品名ME-40
Figure 931098939_IMG1
从Parker+Amchem Divisiion of Henkel Corporation(后文中常简写为“P+A”)购得。然而,已发现有许多生产厂家不愿在阶段6中使用诸如ME-40
Figure 931098939_IMG2
之类的化学品。在某些情况下,这种不情愿是由于DI水(通常在阶段6)体系存在有碳过滤器,过滤器吸附了诸如ME-40
Figure 931098939_IMG3
中的那些润滑剂及表面调理添加剂,使之不能再起作用;在其它情况下,是由于人们不愿实行为使用ME-40
Figure 931098939_IMG4
所必需的工艺改变。
为满足那些不喜欢在最终漂洗阶段加入任何润滑剂及表面调理剂而仍希望获得由这类添加作用可达到的好处的制造商的要求,研究出了用于如上所述阶段4的另外的处理剂,并公开在美国专利5,030,323和5,064,500中。其中某些物质可以商品名FIXODINE
Figure 931098939_IMG5
500从P+A购得。
然而,若使处理的罐筒在完成了上述六阶段操作后经受异常加热,则由现有技术中的处理剂抑或在阶段4抑或在阶段6获得的摩擦系数的降低,实际上常常处在不合要求的水平。高速生产线只要一停顿几分钟就会在烘箱中发生这类罐的超常受热,这种情况在实际中绝非少见。从实际看,COF测值的上升相应于移动性的降低,因而使向洗罐配剂中引入提高移动性的表面活性剂的作用失效。因此,本发明的一个目的和/或优于现有技术所述方法的上述其它目的之一,在于改进铝罐的移动性,并特别涉及在充分低于干燥所处理表面所需最低温度下加热所获的稳定的有益效果。
应当理解,除操作实例或另有说明之处,本说明书所用的所有表达各成分量或反应条件的数值在任何情况下均以“约”字修饰,以表述本发明的最宽范围。但通常优选在给定的数字范围内实施。
除另有明确的相反说明之外,以下对适于或优选用于本发明特殊配剂的化学物组的描述还意味,各组中两种或多种物质的混合物与独自使用该物组的单一物质具有等同的适宜性或优选性。另外,在以离子态说明化学物质时,应当理解为包含有一些抗衡离子,以满足整个组合物电中性的需要。通常,应当首先从规定为本发明组成部分的离子型物质中选择允许范围的这类抗衡离子;一般可自由选择任意所需的保留抗衡离子,只是应避免采用那些不利于达到本发明目的的抗衡离子。
根据本发明可以看出,当润滑剂兼表面调理剂组合物包含至少一种下列有机物时,用该润滑剂兼表面调理剂所处理表面的摩擦系数不太轻易因受热而改变,这些有机物为:烷氧基化或未烷氧基化蓖麻油甘油三酯和氢化蓖麻油衍生物;烷氧基化或未烷氧基化的脂肪酸(包括一元、二元、三元、和多元酸)的胺盐;烷氧基化或未烷氧基化氨基脂肪酸;烷氧基化和未烷氧基化脂肪族N-氧化胺;烷氧基化和未烷氧基化季铵盐;及水溶性烷氧基化或未烷氧基化聚合物。此外,至少当润滑剂兼表面调理剂不随与表面相接触的最终含水组合物之后施用到罐筒表面,尔后最终干燥表面并进行自动传输时,该含有机物的组合物还应含有呈金属或离子形态的选自下面物组的一种金属元素:锆、钛、铈、铝、铁、锡、钒、钽、铌、钼、钨、和铪,且表面上所形成的作为部分干态润滑剂兼表面调理剂的膜,除有机物之外还应含有一些这种金属元素。
市场可购的较佳烷氧基化,尤其是乙氧基化的蓖麻油甘油三酯,包括Trylox
Figure 931098939_IMG6
5900、Trylox 5902、Trylox
Figure 931098939_IMG8
5904、Trylox
Figure 931098939_IMG9
5906、Trylox
Figure 931098939_IMG10
5907、Trylox
Figure 931098939_IMG11
5909、Trylox
Figure 931098939_IMG12
5918,而较佳的氢化蓖麻油衍生物,包括诸如Trylox 5921和Trylox 5922之类的市售产品,它们均可由Henkel Corporation购得。这些物质用作最终漂洗阶段的添加剂特别有效,因其在所处理的表面上形成润滑剂兼表面调理剂的干膜,当加热超过干燥该表面所需最低温度时,该膜阻止了COF升高。
另一较佳的有机物组,包括水溶性烷氧基化,较佳为乙氧基化、丙氧基化、或混合的乙氧基化和丙氧基化物质,而最佳为乙氧基化和未乙氧基化的物质,它们选自包括一元、二元、三元和多元酸的脂肪酸胺盐、氨基脂肪酸、脂族N一氧化胺和季铵盐以及水溶性聚合物。
较佳的脂肪酸胺盐,包括在阳离子或/和阴离子型物质中含有至多50mol烯化氧的脂肪酸的铵、季铵、鏻及碱金属的盐,以及它们的衍生物。具体的实例包括,可由Exxon Chemical Co.购得的Amphoteric N和Amphoteric 400亚氨二丙酸钠盐;可由Henkel Corp.购得的Deriphat
Figure 931098939_IMG15
154(N-牛脂-β-亚氨二丙酸二钠)和Deriphat
Figure 931098939_IMG16
160(N-月桂基-β-亚氨二丙酸二钠)。
较佳的氨基酸包括α和β-氨基酸及二酸和它们的盐,其中包括烷基和烷氧基亚氨二丙酸及其盐,以及肌氨酸衍生物及其盐。具体的实例包括可由Akzo Chemicals Inc.购得的Armeen
Figure 931098939_IMG17
Z(N-coco-β-氨基丁酸;Exxon Chemical Co.的Amphoteric N、Amphoteric 400;肌氨酸(N-甲基甘氨酸);羟乙基甘氨酸;均可由W.R.Grace & Co.购得的Hamposyl
Figure 931098939_IMG18
TL-40月桂酰肌氨酸三乙醇胺、Hamposyl O油酰肌氨酸盐、Hamposyl
Figure 931098939_IMG20
AL-30月桂酰肌氨酸铵、Hamposyl
Figure 931098939_IMG21
L月桂酸肌氨酸盐和Hamposyl C cocoyl肌氨酸盐。
较佳的N-氧化胺包括其中至少有一个烷基取代基含有至少3个,至多20个碳的氧化铵。具体实例包括均可从Akzo Chemicals Inc.购得的Aromox
Figure 931098939_IMG23
C/12双-(2-羟乙基)coco烷基胺化氧、Aromox
Figure 931098939_IMG24
T/12双-(2-羟乙基)牛脂烷基胺化氧、Aromox DMC二甲基coco烷基胺化氧、Aromox
Figure 931098939_IMG26
DMHT氢化二甲基牛脂烷基胺化氧、Aromox DM-16二甲基十六烷基胺化氧;以及可从Exxon Chemical Co.购得的Tomah AO-14-2和Tomah
Figure 931098939_IMG29
AO-728。
优选的季盐包括脂肪胺的季铵衍生物,其中含有至少一个含12-20个碳原子和0-50mol氧化乙烯和/或0-15mol氧化丙烯的取代基,其中的抗衡离子由卤离子、硫酸根、硝酸根、羧酸根、烷基硫酸根或芳基硫酸根、烷基磺酸根或芳基磺酸根或其衍生物组成。具体的实例包括均可由Akzo Chemicals Inc.购得的Arquad
Figure 931098939_IMG30
12-37W氯化十二烷基三甲基铵、Arquad
Figure 931098939_IMG31
18-50氯化十八烷基三甲基铵、Arquad
Figure 931098939_IMG32
210-50氯化二癸基二甲基铵、Arquad
Figure 931098939_IMG33
218-100氯化二(十八烷基)二甲基铵、Arquad 316(W)氯化三(十六烷基)甲基铵、Arquad B-100氯化苄基二甲基(C12-18)烷基铵、Ethoquad
Figure 931098939_IMG36
C/12氯化coco甲基[POE(2)]铵、Ethoquad C/25氯化coco甲基[POE(15)]铵、Ethoquad C/12硝酸盐、Ethoquad
Figure 931098939_IMG39
T/13 Acetate乙酸三(2-羟乙基)牛脂烷基铵、Duoqaud
Figure 931098939_IMG40
T-50二氯化N,N,N′,N′,N′-五甲基-N-牛脂-1,3-二铵、Propoquad
Figure 931098939_IMG41
2HT/11氯化二(氢化牛脂烷基)(2-羟基-2-甲基乙基)甲基铵、Propoquad
Figure 931098939_IMG42
T/12甲基硫酸牛脂烷基甲基-双-(2-羟基-2-甲基乙基)铵;可从Mona Industries Inc.购得的Monoquat
Figure 931098939_IMG43
P-TS硬脂酰氨基PG-二铵氯化物磷酸盐;可从Chemax Inc.购得的Chemquat
Figure 931098939_IMG44
12-33氯化月桂基三甲基铵、Chemquat
Figure 931098939_IMG45
16-50氯化鲸蜡基三甲基铵;以及壬酸、月桂酸、肉豆蔻酸、油酸、硬脂酸或异硬脂酸的四乙铵盐。
优选的水溶性聚合物,包括氧化乙烯、氧化丙烯、氧化丁烯、丙烯酸及其衍生物、马来酸及其衍生物、乙烯基苯酚及其衍生物、和乙烯基醇的均聚物或杂聚物。具体实例包括:均可从Union Carbide Corp.购得的Carbowax
Figure 931098939_IMG46
200、Carbowax 600、Carbowax
Figure 931098939_IMG48
900、Carbowax
Figure 931098939_IMG49
1450、Carbowax
Figure 931098939_IMG50
3350、Carbowax
Figure 931098939_IMG51
8000、和Compound 20M;均可从BASF Wyandotte Corp.购得的Pluronic L61、Pluronic L81、Pluronic
Figure 931098939_IMG54
31R1、Pluronic 25R2、Tetronic
Figure 931098939_IMG56
304、Tetronic
Figure 931098939_IMG57
701、Tetronic
Figure 931098939_IMG58
908、Tetronic 90R4、及Tetronic
Figure 931098939_IMG60
150R1、均可从Rohm & Haas Company购买的Acusol
Figure 931098939_IMG61
410N聚丙烯酸钠盐、Acusol
Figure 931098939_IMG62
445、聚丙烯酸、Acusol 460ND马来酸/油酸共聚物的钠盐、及Acusol 479N丙烯酸/马来酸共聚物的钠盐;以及聚乙烯苯酚的N-甲基葡糖胺加合物和聚乙烯苯酚的N-甲基乙醇胺加合物。
通过用选自金属态或离子态的锆、钛、铈、铝、铁、钒、钽、铌、钼、钨、铪或锡,使一种或多种这些金属与一种或多种上述有机物结合生成薄膜,常可获得附加的改进效果,对于在所处理表面与一种含水组合物接触前施用的润滑剂兼表面调理剂来说更是如此。所生成薄膜的静磨擦系数不高于1.5且低于没有此膜时的相应系数,从而改进了罐筒在高速传送时的移动性,同时不会影响随后对该容器所进行的喷涂、其它种漆涂、印饰或其它类似美饰处理。
与此类无机物质结合使用的技术,公开在美国专利5,030,323(1991年7月9日)和5,064,500(1991年11月12日)中,其中特别详细论及含锆物质,上述专利全文中不与本文所声明的任何论点相违背的所有内容均在此引入本说明书资作参考。以其它金属物质取代上述任一专利中明确说明的那些金属是本领域普通技术人员能够做到的。
在本发明方法的另一优选实施方案中,为了获得改善的水溶性(尤其对本文所述的未乙氧基化有机物质而言)并在罐筒表面形成适宜的薄膜而使干燥后罐筒表面的静摩擦系数不高于1.5,在最后干燥和传送之前,除这类未乙氧基化有机物外还使用一种或多种较佳为烷氧基化且最佳为乙氧基化的表面活性剂的混合物,使之与经清洗的罐筒表面接触。优选的表面活性剂包括乙氧基化和未乙氧基化的硫酸化或磺化脂肪醇,诸如月桂醇及椰醇(coco alcohols)。多类阴离子型、非离子型、阳离子型或两性型的表面活性剂均适用。诸如平均聚合度在1.2与2.0间的C8-C18烷基聚苷之类烷基聚苷也是适宜的。其它类适宜结合使用的表面活性剂为:含1.5-100mol氧化乙烯的乙氧基化壬基酚和辛基酚,较佳为与6-50mol氧化乙烯缩合的壬基酚,诸如可由Rhone-Poulenc购得的Igepal
Figure 931098939_IMG65
CO-887;烷基/芳基聚醚,例如Triton
Figure 931098939_IMG66
DF-16;以及实例为Triton H-66和Triton
Figure 931098939_IMG68
QS-44(Triton
Figure 931098939_IMG69
产品均可从Union Carbide Co.购得)的磷酸酯,还有代表性实例为Ethox
Figure 931098939_IMG70
2684和Ethfac
Figure 931098939_IMG71
136(均可从Ethox Chemicals Inc.购得);直链醇与支链醇及其衍生物的聚乙氧基化和/或聚丙氧基化衍生物,例如Trycol
Figure 931098939_IMG72
6720(Henkel Corp.)、Surfonic
Figure 931098939_IMG73
LF-17(Texaco)和Antarox
Figure 931098939_IMG74
LF-330(Rhone-Poulenc);直链或支链脂族醇的磺化衍生物,例如:Neodol
Figure 931098939_IMG75
25-3S(Shell Chemicl Co.);磺化芳基衍生物,例如Dyasulf
Figure 931098939_IMG76
9268-A、Dyasulf
Figure 931098939_IMG77
C-70、Lomar
Figure 931098939_IMG78
D(均可由Henkel Corp.购得)和Dowfax 2A1(可从Dow Chemical Co.购得);以及氧化乙烯与氧化丙烯的共聚物,例如Pluronic L-61、Pluronic 81、Pluronic 31R1、Tetronic
Figure 931098939_IMG83
L-701、Tetronic
Figure 931098939_IMG84
90R4及Tetronic
Figure 931098939_IMG85
150R1(均可从BASF Corp.购得)。
此外,本发明的润滑剂兼表面调理剂,还可包含一种酸式磷酸酯盐(phosphate acid ester)或较佳为一种乙氧基化烷基醇磷酸酯。这类磷酸酯可以Gafac
Figure 931098939_IMG86
PE 510的商品名从GAF Corporation(Wayne,NJ)购得,还可以Ethfac 136及Ethfac 161的商品名从Ethox Chemicals,Inc.(Creenville,SC)购得。通常,该有机磷酸酯可包括乙氧基化或未乙氧基化的烷基及芳基磷酸酯。
对铝罐而言,可在其洗涤周期,在其诸如清洗或转化涂覆的一个处理周期、在其诸水漂洗周期中的某个水漂洗周期、或在其最终水漂洗周期内,将润滑剂兼表面调理剂施涂到铝罐上。此外,可在罐筒的最终水漂洗周期之后,即在入烘箱干燥之前或之后,以细雾喷施的方式将润滑剂兼表面调理剂随与水或另外一不易燃的挥发性溶剂组成的溶液施用到该罐筒。已发现,该润滑剂兼表面调理剂能够沉积在表面上而使该表面获得所期望的性能。可喷雾施用该润滑剂兼表面调理剂,且通过化学吸附或物理吸附作用使之与该表面相互作用,以使该表面获得理想的润滑剂兼表面调理剂的干性膜。
施用于罐筒的润滑剂兼表面调理剂的量,应当足以使罐筒外表面的静摩擦系数降至约1.5或更低的数值,且最好降至约1或更低的数值。一般来讲,在罐筒的外表面上,该量应相当于约3mg/m2至约60mg/m2的润滑剂兼表面调理剂。
为了更全面地理解本发明,还应参考下面实施例。这些实施例仅用来描述和示意说明本发明,而不用来限定本发明范围。
实施例
在类型A的实施例中,采用Ridoline
Figure 931098939_IMG89
3600/306法,将来自工业制罐厂的未清洗铝罐用可得自Parker+Amchem Division,Henkel Corporation(Madison Heights,Michigan)的碱性清洗剂洗涤干净,而在类型B的实施例中,则用得自同一公司的Ridoline
Figure 931098939_IMG90
125酸目性清洗剂。在初次漂洗之后和最后干燥之前,用含下面溶液之一的润滑剂兼表面调理剂组合物处理已清洗过的罐筒:(ⅰ)下面表1中说明的活性有机物(Ⅰ)溶于去离子水所成的约1%(重量)水溶液;(ⅱ)该活性有机物(Ⅰ)溶于去离子水所成的约1%溶液加上约2g/l(0.2%)表1中说明的无机成分(Ⅱ);(ⅲ)活性有机物(Ⅰ)溶于去离子水所成约1%的溶液加上约0.5%的表1中说明的表面活性剂(Ⅲ);(ⅳ)含约1%活性有机物(Ⅰ)、约0.2%无机物(Ⅱ)及约0.5%表面活性剂(Ⅲ)((Ⅰ)、(Ⅱ)、(Ⅲ)如表1中说明)的溶液。
在这组含水的润滑兼表面调节处理组合物中,含有表1中无机成分(Ⅱ)的组合物施用于前面所限定的阶段4,而不含这一成分的那些组合物,则施用于紧接最终干燥工序之前的阶段6。
另外,罐筒干燥后要用实验室静摩擦测试仪评定其静摩擦系数。这一装置测量与铝罐表面特性有关的静摩擦。此试验用一斜面(ramp)来进行,用一衡速电动机使该斜面向上转过90℃弧度,一线轴和线缆接在该板面的自由摆动端。一托架接在该斜面的底部用来搁放罐筒,两个罐筒圆顶朝向该斜面的固定端以约0.5吋的间距水平放置。第三个罐平放在那两个罐上,其圆顶朝向该斜面的自由摆动端,且找平三个罐的边而使它们彼此对齐。
当该斜面随其弧度的变化而开始移动时,计时器自动启动。当该斜面达到使第三个罐可从下面两个罐上自由滑下的角度时,一光电开关即关掉该计时器。以秒计的这一时间通常称为“滑脱时间”。静摩擦系数等于在该罐开始移动时刻该斜面扫过角度的正切值。
在这组实施例中任意情况下,后续用漆的粘合性令人满意且在表面上产生的COF低于1.5。
表1
实施例类型 活性有机物(Ⅰ) 无机物(II) 表面活性剂(III) pH
商品名 化学名称
A Emery 657 辛酸 Al2(SO4)3 IGEPAL CO-887 2.2
B Emery 659 癸酸 H2ZrF6 TRITON X-101 2.2
A Emery 651 月桂酸 FeF3 NEODOL 25-5-3 2.3
B Emery 655 肉豆蔻酸 SnCl4 TERGITOLTMN-6 2.3
A Emersol143 棕榈酸91% Ce(NO3)4 TRITON DF-16 2.6
B Emersol153NF 硬脂酸92% H2TiF6 TRYCOL 6720 2.6
A Emersol871 异硬脂酸 H2HfF6 ANTAROX LF-330 2.6
B Emersol6313NF 油酸75% (NH4)2ZrF6 TRITON H-55 2.6
A Empol1014 二聚酸95% Fe2(SO4)3 TRITON H-66 2.6
B Emery1110 壬二酸 Al(NO3)3 TRITON QS -44 2.6
B Ethox MI5 乙氧基化异硬脂酸 TiCl4 TRYCOL6720 3.0
A EmulphorVN430 聚氧乙基化油酸 Cel3 SURFONIC LF-17 3.0
B EthoxMO5 聚氧乙基化油酸 FeF3 LOMARD 3.0
A Monamide150 LW 月桂链烷醇酰胺 FeCl3 DOWFAX2Al 2.0
B Monamide150MW 肉豆蔻链烷醇酰胺 FeBr3 DYASULF 9268-A 3.0
A Monamide150IS 异硬脂链烷醇酰胺 H2ZrF6 DYASULF C-70 4.0
表1(续)
实施例类型 活性有机物(Ⅰ) 无机物(II) 表面活性剂(III) pH
商品名 化学名称
B Momanide718 硬脂链烷醇酰胺 H2TiF6 IGEPAL CO -887 5.0
A Gafac BH650 脂族磷酸酯,酸式 Fe(NO3)3 POLYTERGENTSLF-18 2.0
B EthoxPP16 芳族磷酸酯 (NH4)2ZrF6 PLURONIC L-61 3.0
A Gafac BL750 脂族磷酸酯,酸式 TaF5 TETRONIC701 6.0
B GafacPE510 芳族磷酸酯,酸式 NbF5 PLURONIC 31R1 5.0
A Ethfac142W 脂族磷酸酯 H2ZrF6 PLURONIC150R1 4.0
B Gafac RA600 脂族磷酸酯,酸式 (NH4)2MoO4 APG300 6.0
A Armeen Z N-Coco-B-氨基丁酸 H2TiF6 TRITON CF-21 6.0
B HamposylL 月桂酰肌氨酸 VF4 TRITON DF-18 5.0
A HamposylC Cocoyl肌氨酸 FeF3 TRITON GR-7M 4.0
B HamposylO 油酰肌氨酸 SnCl4 TRITON H-55 3.0
A HamposylS 硬脂酰肌氨酸 Al2(SO4)3 TRITON X-100 2.0
B Acusol410N 聚丙烯酸,钠盐 H2ZrF6 TRITON X-120 4.0
表1(续)
实施例类型 活性有机物(Ⅰ) 无机物(II) 表面活性剂(III) pH
商品名 化学名称
B Triton GR-5M 二辛基硫代琥珀酸盐 Al(NO3)3 TRYCOL 5882 6.0
A Avanel S70 烷基醚磺酸钠 VOSO4 TRYCOL 5887 5.0
B IgeponTC-42 N-椰子和N-甲基牛磺酸钠 VF5 TRYCOL 5964 4.0
A IgeponTK-32 N-甲基-N-浮油酸牛磺酸钠 VF3 IGEPAL CO-887 3.0
B Neodol 25-3A 磺化直链醇,铵盐 (NH4)2WO4 IGEPAL CO-630 3.0
A AromoxC/12 双(2-羟乙基)α-绰昔柯碱氧化物 (NH4)2ZrF6 NEODOL25-3 3.0
B AromoxDMC 二甲基α-绰昔古柯碱氧化物 FeF3 NEODOL 25-35 3.0
A Ethoquad0/25 油烯基[POE(15)]铵化氯 Fe2(SO4)3 NEODOL 25-9 2.0
B EthoquadC/12 Coco甲基[POE(2)]铵化氯 Al2(SO4)3 NEODOL 91-25 3.0
A Ethoquad18/5 十八烷基[POE(15)]铵化氯 Sn(SO4) TRITON Q5-15 3.0
表1(续)
实施例类型 活性有机物(I) 无机物(II) 表面活性剂(III) pH
商品名 化学名称
B PorpoquadT/12 牛脂烷基甲基-双-(2-羟基-2-甲基乙基)铵甲基硫酸盐 Ce2(SO4)3 TRITON DF-12 2.0
A Ethfac 136 磷酸酯 H2ZrF6 IGEPAL 10-887 2.3
B Ethox2684 磷酸酯 H2ZrF6 IGEPAL CO-887 2.7
A Trylox5922 乙氧基化氢化蓖麻油 H2ZrF6 IGEPAL CO-887 2.3
B Trylox5921 H2TiF6 IGEPAL CO-887 2.7
A Trylox5925 H2ZrF6 TRITON H-66 2.7

Claims (20)

1、一种包括以酸性或碱性清洗水溶液清洗金属罐,干燥所清洗的罐,并随后使所清洗和干燥的罐经自动传送装置送往对其涂漆或印刷美饰或者既涂漆又印刷美饰的工位在内诸步骤的方法,其特征在于,在金属罐外表面最终干燥和自动传送之前,使至少一个所述金属罐的外表面与一种润滑剂兼表面调理剂组合物相接触,从而在该罐表面形成薄膜,使该罐表面干燥后形成静摩擦系数不高于1.5且低于无此种膜层的同类罐表面静摩擦系数的表面,所述反应性润滑剂兼表面调理剂组合物为一种水溶液,其中包含选自下面一组物质的水溶性有机材料:烷氧基化或未烷氧基化蓖麻油甘油三酯,氢化蓖麻油衍生物,包括一元、二元、三元及多元酸在内的烷氧基化或未烷氧基化脂肪酸胺盐,烷氧基化或未烷氧基化氨基脂肪酸,烷氧基化或未烷氧基化脂肪族N-氧化胺,烷氧基化和未烷氧基化季铵盐,水溶性烷氧基化和未烷氧基化聚合物及它们的混合物,该组合物还包含至少一种呈金属或离子形态、选自锆、钛、铈、铬、铁、锡、钒、钽、铌、钼、钨和铪的元素,而且罐表面上形成的膜层除所述有机材料之外,还至少含有一部分所述的无机材料。
2、权利要求1所述的方法,其中所述水溶液包含选自下面这组物质中的至少一种物质:包括一元、二元、三元及多元酸在内的烷氧基化脂肪酸胺盐,烷氧基化氨基脂肪酸,烷氧基化脂族N-氧化胺、烷氧基化季铵盐,以及水溶性烷氧基化聚合物。
3、权利要求2所述的方法,其中所述水溶液包含至少一种选自下面这组的物质:包括一元、二元、三元及多元酸在内的乙氧基化脂肪酸胺盐;乙氧基化氨基脂肪酸,乙氧基化脂族N-氧化胺,乙氧基化季铵盐,及水溶性乙氧基化聚合物。
4、权利要求1所述的方法,其中所述水溶液包含一种脂肪酸胺盐。
5、权利要求1所述的方法,其中所述水溶液包含一种氨基脂肪酸。
6、权利要求1所述的方法,其中所述水溶液包含一种脂族N-氧化胺。
7、权利要求1所述的方法,其中所述水溶液包含一种季盐。
8、权利要求1所述的方法,其中所述水溶液包含一种水溶性聚合物。
9、权利要求1所述的方法,其中所述水溶液包含一种烷氧基化或未烷氧基化蓖麻油甘油三酯或一种氢化蓖麻油衍生物。
10、权利要求1所述的方法,其中所述无机物包括锆。
11、权利要求1所述的方法,其中所述无机物包括钛。
12、权利要求1所述的方法,其中所述水溶液还包含一种非离子型、阴离子型、阳离子型或两性型的表面活性剂。
13、权利要求12所述的方法,其中所述表面活性剂是乙氧基化的。
14、权利要求14所述的方法,其中所述表面活性剂为一阴离子型表面活性剂。
15、权利要求1所述的方法,其中所述润滑剂兼表面调理剂。在罐筒清洗后施用。
16、权利要求1-15中任何一项所述的方法,其中的罐为铝罐。
17、一种权利要求16所述的方法,其中所述润滑剂兼表面调理剂随最终的组合物水溶液施用,罐筒与其相接触后进行最后干燥,接着被自动传送。
18、一种如权利要求16所述的方法,其中施用该润滑剂兼表面调理剂,且在施用了这类润滑剂兼表面调理剂之后,将所处理的罐与组合物水溶液至少接触两次。
19、一种步骤包括用酸性或碱性清洗水溶液清洗铝罐、干燥清洗过的罐筒,并随后使所清洗的干燥罐筒通过自动传送装置送往对其喷漆或美饰或喷漆并美饰的印制工位的方法,其特征在于在铝罐外表面最终干燥和自动传送之前,使至少一个所述铝罐的外表面与一润滑剂兼表面调理剂的组合物相接触,从而在该罐表面上形成膜层而使该罐表面干燥后获得的静摩擦系数不高于1.5,且低于同类罐表面在没形成这类膜层时可获得的相应系数,所述的为水溶液的润滑剂兼表面调理剂组合物,包括烷氧基化或未烷氧基化蓖麻油甘油三酯或氢化蓖麻油衍生物。
20、一种如权利要求19所述的方法,其中的润滑剂兼表面调理剂组合物包括乙氧基化、氢化蓖麻油甘油三酯。
CN93109893A 1992-07-08 1993-07-08 成型金属表面的水性润滑兼表面调节处理 Pending CN1085244A (zh)

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