EP0966737A4 - Protection contre la corrosion de l'aluminium et d'alliages d'aluminium au moyen de polyanilines emeraldine base - Google Patents
Protection contre la corrosion de l'aluminium et d'alliages d'aluminium au moyen de polyanilines emeraldine baseInfo
- Publication number
- EP0966737A4 EP0966737A4 EP98910331A EP98910331A EP0966737A4 EP 0966737 A4 EP0966737 A4 EP 0966737A4 EP 98910331 A EP98910331 A EP 98910331A EP 98910331 A EP98910331 A EP 98910331A EP 0966737 A4 EP0966737 A4 EP 0966737A4
- Authority
- EP
- European Patent Office
- Prior art keywords
- group
- coating
- substance
- metal piece
- aluminum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D179/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen, or carbon only, not provided for in groups C09D161/00 - C09D177/00
- C09D179/02—Polyamines
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/02—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using non-aqueous solutions
Definitions
- the present invention relates to the protection of aluminum and its alloys from corrosion.
- EB emeraldine base polyaniline
- containing film protects the aluminum surface it is coated on, but may also protect the
- the present invention includes a coating composition for
- the composition comprises
- oligomers may be trimers, tetramers,
- emeraldine base may range from about .3 to about .75 units.
- emeraldine base or oligomers thereof may also be provided with additional ring substituents for purposes such as providing polymer cross linking, improved or in
- substituents may be, for example, carbonate groups, alkyl groups, epoxy groups, and
- the coating composition also include a
- polymers/oligomers mentioned herein may also offer corrosion protection of
- corrosion protecting polymer/oligomer also is likely to be utilized in order to improve
- the present invention also includes a coated metal piece which may be of
- the coated metal piece also has on at least one such surface a coating
- the coating may also be provided with a
- coating sealant such as a lacquer or epoxy sealant.
- the present invention also includes, in broadest terms, a coating composition
- composition for protecting aluminum and alloys thereof from corrosion, the composition
- oligomers comprising at least one substance selected from the group consisting of sulfonated polyaniline and salts and oligomers thereof.
- oligomers may include trimers,
- the sulfonated polyaniline coatings may also be born by resin such as acrylic
- the sulfonated polyaniline coatings will have a degree of sulfonation
- sulfonated polyaniline may also be provided with additional ring substituents for
- substituents may be, for example, carbonate
- the present invention also includes a coated metal piece comprising a metal
- said metal piece selected from the group consisting of aluminum and alloys thereof, said metal piece
- oligomers may be trimers
- the coated metal piece may also have a coating sealant atop the coating, and
- sealants may be, for instance, lacquers and epoxy sealants.
- Figure 1 shows the schematic chemical structure of emeraldine base
- Figure 2 shows the schematic chemical structure of sulfonated (100%)
- polyaniline in the emeraldine base form.
- Figure 3 shows the XPS Al 2p core level depth profile of a polished A13003
- Figure 4 shows the XPS Al 2p core level spectra of (a) an A13O03 sample
- Figure 5 shows the XPS Al 2p core level spectra of (a) A13003 exposed to
- Figure 6 shows a graph of a potentiodynamic scan showing the results of a
- the surface was polished with 600 grit emery paper and degreased
- Figure 7 shows a graph of a potentiodynamic scan showing the results of a
- Figure 8 shows a graph of a potentiodynamic scan showing the results of a
- Figure 9 shows a graph of a potentiodynamic scan showing the results of a
- Example 1 EB films were coated onto A13003 alloys and were found to reduce the
- samples consisting of Al vapor deposited onto glass.
- the acid used was 0.1 M HCl. After the acid exposure, the samples were
- X-ray photoelectron spectroscopy was carried using a VG Scientific
- depth profiling was carried out both the A13003 side and the EB side.
- metallic Al being the dominating feature at depths of -10 nm giving an estimate of the
- the unprotected A13003 sample (a) has a
- top coats typically used in the paint industry to protect the primer layer An example
- the unprotected sample has a distinct shoulder at -78 eV
- thickness of the EB films were -20 micrometers, and -40 micrometers for the trimer
- the potentiostat used for the potentiodynamic experiments was a Gamry Instruments model PC3 potentiostat galvanostat equipped with the CMS 100 corrosion system
- the scanning speed for the experiments was 5 mV/s.
- Trimer top coated A12024-T3 coupons had open circuit potentials of - -0.75 V vs
- the aluminum alloy is ennobled in the presence of an EB or a trimer
- top coat i.e., some form of anodic protection is taking place.
- trimer films have throwing power, i.e., the ability to protect a metal against
- Fig. 8 are shown the potentiodynamic scans for scribed EB and epoxy, and the
- trimer samples was reduced by an order of magnitude compared to the epoxy- coated coupons.
- oligomers of EB and SPAN trimers, tetramers, octamers, hexdecamers, etc.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Paints Or Removers (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Laminated Bodies (AREA)
Abstract
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US3668597P | 1997-03-11 | 1997-03-11 | |
US36685P | 1997-03-11 | ||
PCT/US1998/004832 WO1998040881A1 (fr) | 1997-03-11 | 1998-03-11 | Protection contre la corrosion de l'aluminium et d'alliages d'aluminium au moyen de polyanilines emeraldine base |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0966737A1 EP0966737A1 (fr) | 1999-12-29 |
EP0966737A4 true EP0966737A4 (fr) | 2000-04-19 |
Family
ID=21890053
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP98910331A Withdrawn EP0966737A4 (fr) | 1997-03-11 | 1998-03-11 | Protection contre la corrosion de l'aluminium et d'alliages d'aluminium au moyen de polyanilines emeraldine base |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0966737A4 (fr) |
JP (1) | JP2000512344A (fr) |
AU (1) | AU6459598A (fr) |
CA (1) | CA2283926A1 (fr) |
WO (1) | WO1998040881A1 (fr) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6326441B1 (en) * | 2000-01-18 | 2001-12-04 | Council Of Scientific And Industrial Research | Compensated sulphonated polyaniline and a process for the preparation thereof |
CN100358964C (zh) * | 2004-12-08 | 2008-01-02 | 吉林正基科技开发有限责任公司 | 聚苯胺防腐密封胶 |
US8691028B2 (en) * | 2006-05-10 | 2014-04-08 | The Boeing Company | Article having a hexavalent-chromium-free, corrosion-inhibiting organic conversion coating thereon, and its preparation |
JP4640399B2 (ja) * | 2007-09-25 | 2011-03-02 | トヨタ自動車株式会社 | 防錆処理金属基材および金属基材表面の防錆法 |
CN101381578B (zh) * | 2008-10-17 | 2011-08-03 | 哈尔滨工程大学 | 一种超轻镁锂合金高效防腐蚀涂料 |
WO2013188496A2 (fr) * | 2012-06-12 | 2013-12-19 | Cbi Polymers, Inc. | Compositions d'additif résistant à la corrosion et compositions de revêtement les employant |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1993014166A1 (fr) * | 1992-01-21 | 1993-07-22 | Allied-Signal Inc. | Formulations de peinture a polymeres conjugues anti-corrosion pour surfaces metalliques |
US5441772A (en) * | 1993-09-29 | 1995-08-15 | Air Products And Chemicals, Inc. | Protecting carbon steel from corrosion with nonconducting poly(aniline) |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5208301A (en) * | 1988-05-13 | 1993-05-04 | Ohio State University Research Foundation | Sulfonated polyaniline compositions, ammonium salts thereof, process for their preparation and uses thereof |
US5137991A (en) * | 1988-05-13 | 1992-08-11 | The Ohio State University Research Foundation | Polyaniline compositions, processes for their preparation and uses thereof |
-
1998
- 1998-03-11 CA CA002283926A patent/CA2283926A1/fr not_active Abandoned
- 1998-03-11 WO PCT/US1998/004832 patent/WO1998040881A1/fr not_active Application Discontinuation
- 1998-03-11 AU AU64595/98A patent/AU6459598A/en not_active Abandoned
- 1998-03-11 EP EP98910331A patent/EP0966737A4/fr not_active Withdrawn
- 1998-03-11 JP JP10539791A patent/JP2000512344A/ja active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1993014166A1 (fr) * | 1992-01-21 | 1993-07-22 | Allied-Signal Inc. | Formulations de peinture a polymeres conjugues anti-corrosion pour surfaces metalliques |
US5441772A (en) * | 1993-09-29 | 1995-08-15 | Air Products And Chemicals, Inc. | Protecting carbon steel from corrosion with nonconducting poly(aniline) |
Non-Patent Citations (1)
Title |
---|
See also references of WO9840881A1 * |
Also Published As
Publication number | Publication date |
---|---|
JP2000512344A (ja) | 2000-09-19 |
WO1998040881A1 (fr) | 1998-09-17 |
CA2283926A1 (fr) | 1998-09-17 |
AU6459598A (en) | 1998-09-29 |
EP0966737A1 (fr) | 1999-12-29 |
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Legal Events
Date | Code | Title | Description |
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PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
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17P | Request for examination filed |
Effective date: 19990928 |
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RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: FAHLMAN, MATS, A. P. Inventor name: EPSTEIN, ARTHUR, J. |
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A4 | Supplementary search report drawn up and despatched |
Effective date: 20000303 |
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AK | Designated contracting states |
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STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION HAS BEEN WITHDRAWN |
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18W | Application withdrawn |
Withdrawal date: 20010607 |