EP0964907A1 - Composition detergente contenant un adjuvant de zeolite particulaire et un agent lubrifiant - Google Patents
Composition detergente contenant un adjuvant de zeolite particulaire et un agent lubrifiantInfo
- Publication number
- EP0964907A1 EP0964907A1 EP96931608A EP96931608A EP0964907A1 EP 0964907 A1 EP0964907 A1 EP 0964907A1 EP 96931608 A EP96931608 A EP 96931608A EP 96931608 A EP96931608 A EP 96931608A EP 0964907 A1 EP0964907 A1 EP 0964907A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- zeolite
- detergent composition
- zeolite builder
- lubricant
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
Definitions
- the detergent composition according to the invention contains as an essential component a surfactant selected from anionics, nonionics, zwitterionics, ampholytics and cationics.
- the nonionic surfactant is preferably a hydrophobic nonionic surfactant, particularly an alkoxylated nonionic surfactant, having a hydrophilic lipophilic balance (hlb) value of ⁇ 9.5, more preferably ⁇ 10.5.
- hlb hydrophilic lipophilic balance
- hydrophobic alkoxylated nonionic surfactants include alkoxylated adducts of fatty alcohols containing an average of less than 5 alkylene oxide groups per molecule.
- the alkylene oxide residues may, for example, be ethylene oxide residues or mixtures thereof with propylene oxide residues.
- Preferred nonionic surfactants include primary Cj 1-C15 aliphatic alcohols condensed with an average of no more than five ethylene oxide groups per mole of alcohol, having an ethylene oxide content of less than 50% by weight, preferably from 25% to less than 50% by weight.
- the second essential component ofthe detergent compositions ofthe present invention is an aluminosilicate zeolite builder, optionally in conjunction with one or more cobuilders.
- aluminosilicate zeolite builders are generally water-insoluble.
- the zeolite builder is typically present at a level of from 1% to 80%, more preferably from 15% to 40% by weight ofthe compositions.
- WO 93/16159 describes particularly suitable fatty alcohol poly (ethylene glycol) ethers which contain from 4 to 7 glycol units.
- DE 4124247 A similarly describes suitable fatty alcohol poly (ethylene glycol) ethers.
- DE 3401861 A describes suitable alkylphenol polyglycol ethers.
- DE 344431 1 A describes suitable isotridecyl polyglycol ethers.
- the detergent composition according to the invention may contain other detergent components such as cobuilders, bleaches, fluorescers, antiredeposition agents, inorganic salts such as sodium sulphate, other enzymes, lather control agents, fabric softening agents, pigments, coloured speckles and perfumes.
- other detergent components such as cobuilders, bleaches, fluorescers, antiredeposition agents, inorganic salts such as sodium sulphate, other enzymes, lather control agents, fabric softening agents, pigments, coloured speckles and perfumes.
- the bleach system preferably comprises a peroxy bleach compound, preferably an inorganic persalt, optionally in conjunction with a peroxyacid bleach precursor.
- Suitable persalts include sodium perborate monohydrate and tetrahydrate and sodium percarbonate, with sodium percarbonate being most preferred.
- Preferred bleach precursors are peracetic acid precursors, such as tetraacetylethylene diamine (TAED); peroxybenzoic acid precursors.
- TAED tetraacetylethylene diamine
- the detergent composition according to the invention may be of any physical type, for example powders, liquids and gels. However, granular and liquid compositions are preferred.
- the detergent compositions ofthe invention may be prepared by any suitable method.
- the particulate detergent compositions are suitably prepared by any tower (spray-drying) or non-tower process.
- TAS Sodium alkyl sulfate surfactant containing predominantly C 16 - Cj 8 alkyl chains derived from tallow oil.
- Alcalase Proteolytic enzyme sold under the tradename Alcalase by Novo Industries A S (approx 1 % enzyme activity by weight)
- the detergent compositions A to E according to the invention which comprise a zeolite particle lubricant (i.e. PEG 1 or PEG 2), show good results in stain removal and lower printed cotton fabric damage as compared with a composition comprising no zeolite particle lubricant.
- a zeolite particle lubricant i.e. PEG 1 or PEG 2
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB9520024.2A GB9520024D0 (en) | 1995-09-30 | 1995-09-30 | Detergent composition |
GB9520024 | 1995-09-30 | ||
PCT/US1996/014858 WO1997012953A1 (fr) | 1995-09-30 | 1996-09-13 | Composition detergente contenant un adjuvant de zeolite particulaire et un agent lubrifiant |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0964907A1 true EP0964907A1 (fr) | 1999-12-22 |
EP0964907A4 EP0964907A4 (fr) | 2000-01-05 |
Family
ID=10781586
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96931608A Withdrawn EP0964907A4 (fr) | 1995-09-30 | 1996-09-13 | Composition detergente contenant un adjuvant de zeolite particulaire et un agent lubrifiant |
Country Status (5)
Country | Link |
---|---|
EP (1) | EP0964907A4 (fr) |
BR (1) | BR9610730A (fr) |
CA (1) | CA2233594A1 (fr) |
GB (1) | GB9520024D0 (fr) |
WO (1) | WO1997012953A1 (fr) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0552054A1 (fr) * | 1992-01-17 | 1993-07-21 | Unilever Plc | Compositions détergentes |
DE4320358A1 (de) * | 1993-06-21 | 1994-12-22 | Henkel Kgaa | Verfahren zur Herstellung wasch- oder reinigungsaktiver Extrudate |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB8825783D0 (en) * | 1988-11-03 | 1988-12-07 | Unilever Plc | Novel aluminosilicates & detergent compositions containing them |
DE4109501A1 (de) * | 1991-03-22 | 1992-09-24 | Degussa | Waessrige stabile suspension wasserunloeslicher, zum binden von calciumionen befaehigter silikate und deren verwendung zur herstellung von wasch- und reinigungsmitteln |
USH1468H (en) * | 1994-04-28 | 1995-08-01 | Costa Jill B | Detergent compositions containing cellulase enzyme and selected perfumes for improved odor and stability |
-
1995
- 1995-09-30 GB GBGB9520024.2A patent/GB9520024D0/en active Pending
-
1996
- 1996-09-13 WO PCT/US1996/014858 patent/WO1997012953A1/fr not_active Application Discontinuation
- 1996-09-13 CA CA 2233594 patent/CA2233594A1/fr not_active Abandoned
- 1996-09-13 BR BR9610730A patent/BR9610730A/pt not_active Application Discontinuation
- 1996-09-13 EP EP96931608A patent/EP0964907A4/fr not_active Withdrawn
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0552054A1 (fr) * | 1992-01-17 | 1993-07-21 | Unilever Plc | Compositions détergentes |
DE4320358A1 (de) * | 1993-06-21 | 1994-12-22 | Henkel Kgaa | Verfahren zur Herstellung wasch- oder reinigungsaktiver Extrudate |
Non-Patent Citations (1)
Title |
---|
See also references of WO9712953A1 * |
Also Published As
Publication number | Publication date |
---|---|
GB9520024D0 (en) | 1995-12-06 |
BR9610730A (pt) | 1999-07-13 |
EP0964907A4 (fr) | 2000-01-05 |
CA2233594A1 (fr) | 1997-04-10 |
WO1997012953A1 (fr) | 1997-04-10 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
17P | Request for examination filed |
Effective date: 19980311 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LI LU NL PT SE |
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A4 | Supplementary search report drawn up and despatched |
Effective date: 19991119 |
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AK | Designated contracting states |
Kind code of ref document: A4 Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LI LU NL PT SE |
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RIC1 | Information provided on ipc code assigned before grant |
Free format text: 7C 11D 3/12 A, 7C 11D 1/72 B, 7C 11D 7/20 B, 7C 11D 9/18 B |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
18D | Application deemed to be withdrawn |
Effective date: 20001002 |