Classifications

• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
  • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
  • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
  • A61L15/42—Use of materials characterised by their function or physical properties
  • A61L15/46—Deodorants or malodour counteractants, e.g. to inhibit the formation of ammonia or bacteria
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
  • A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
  • A01N33/02—Amines; Quaternary ammonium compounds
  • A01N33/12—Quaternary ammonium compounds
• • A—HUMAN NECESSITIES
  • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
  • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
  • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
  • A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
  • A01N47/42—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides containing —N=CX2 groups, e.g. isothiourea
  • A01N47/44—Guanidine; Derivatives thereof
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
  • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
  • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
  • A61L15/20—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing organic materials
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
  • A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
  • A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
  • A61L15/42—Use of materials characterised by their function or physical properties
  • A61L15/60—Liquid-swellable gel-forming materials, e.g. super-absorbents
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
  • A61L2300/00—Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices
  • A61L2300/20—Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices containing or releasing organic materials
  • A61L2300/204—Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices containing or releasing organic materials with nitrogen-containing functional groups, e.g. aminoxides, nitriles, guanidines
  • A61L2300/208—Quaternary ammonium compounds
• • A—HUMAN NECESSITIES
  • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
  • A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
  • A61L2300/00—Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices
  • A61L2300/40—Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices characterised by a specific therapeutic activity or mode of action
  • A61L2300/404—Biocides, antimicrobial agents, antiseptic agents

Definitions

• Disposable absorbent products of this type generally comprise a fluid-permeable topsheet material, an absorbent core, and a fluid-impermeable backsheet material.
• Various shapes, sizes and thicknesses of such articles have been explored in an attempt to make their use more comfortable and convenient.
• Such known absorbent polymers are capable of absorbing from about thirty to sixty grams of water per gram of polymer.
• Antimicrobial agents and bactericides are chemical compositions that are used to prevent microbiological contamination and deterioration of products, materials, and systems. Particular areas of application of antimicrobial agents and compositions are, for example, cosmetics, disinfectants, sanitizers, wood preservation, food, animal feed, cooling water, metalworking fluids, hospital and medical uses, plastics and resins, petroleum, pulp and paper, textiles, latex, adhesives, leather and hides, paint slurries, and disposable diapers.
• Japanese Patent 4-17058 discloses a disposable diaper which is said to prevent the occurrence of diaper rash caused by the growth of saprophytes such as the bacteria colibacillus and Candida.
• the disclosed disposable diaper consists of a water-permeable top sheet, a water-impermeable back sheet, and a water-absorbent layer sandwiched between these sheets.
• the water-absorbent layer is further disclosed as consisting of a) an ammonia- adsorbent, water-absorbent organic polymer selected from the group consisting of polyacrylate polymers, starch-acrylonitrile graft copolymer hydrolizates, starch- acrylic acid graft copolymers, polyvinyl alcohol-acrylate copolymers, polymers produced by further crosslinking of a crosslinked acrylate with a crosslinking agent, and modified carboxymethyl cellulose; and b) benzalkonium chloride and/or chlorhexidine gluconate, contained within the water-absorbent organic polymer.
• the reference further discloses forming the organic polymer / bactericide material by combining the starting materials of the organic polymer (e.g., microparticulate silicon dioxide, a copolymer such as crosslinked potassium polyacrylate, and a cross-linking agent such as ethylene glycol diglycidyl) and the bactericide.
• the starting materials of the organic polymer e.g., microparticulate silicon dioxide, a copolymer such as crosslinked potassium polyacrylate, and a cross-linking agent such as ethylene glycol diglycidyl
• a cross-linking agent such as ethylene glycol diglycidyl
• the bactericide because the bactericide is incorporated within the polymer, the bactericide does not begin acting until the polymer swells with the urine. In other words, the product does not provide immediate efficacy upon, e.g., urination.
• water-absorbent polymers tend to produce dust during manufacture.
• Such dust production has several disadvantages including, health risks to workers who inhale the dust, increased cleanings of the machinery to remove the dust, and loss of product in the form of unclaimed dust.
• A-HFAP antimicrobial hydrogei- forming absorbent polymer
• the present invention is directed to an antimicrobial hydrogel-forming absorbent polymer comprising a hydrogel-forming absorbent polymer, and an antimicrobial; wherein the hydrogel-forming absorbent polymer is coated with the antimicrobial.
• an antimicrobial hydrogel-forming absorbent polymer comprising a hydrogel-forming absorbent polymer, and an antimicrobial; wherein the hydrogel-forming absorbent polymer is coated with the antimicrobial.
• the present invention further relates to a process for making such an antimicrobial hydrogel-forming absorbent polymer, the process comprising coating a hydrogel-forming absorbent polymer with an antimicrobial.
• a process for making such an antimicrobial hydrogel-forming absorbent polymer the process comprising coating a hydrogel-forming absorbent polymer with an antimicrobial.
• the present invention further relates to a disposable absorbent article comprising an antimicrobial hydrogel-forming absorbent polymer.
• a disposable absorbent article comprising an antimicrobial hydrogel-forming absorbent polymer.
• Figure 1 is a plan view of a disposable diaper embodiment of the present invention, having portions cut away to reveal underlying structure, the inner surface of the diaper facing the viewer;
• Figure 2 is a cross-sectional view of one embodiment of the disposable diaper of Figure 1 , taken along transverse center line 110 of Figure 1 ;
• Figure 3 is an enlarged view of an alternative embodiment of the disposable diaper of Figure 1 , the view corresponding to a portion of Figure 2;
• Figure 4 shows the key elements of the finished product acquisition test.
• A-HFAP means antimicrobial hydrogel-forming absorbent polymer.
• Body fluids includes urine, menses and vaginal discharges.
• Disposable describes absorbent articles which are not intended to be laundered or otherwise restored or reused as an absorbent article (i.e., they are intended to be discarded after a single use and, preferably, to be recycled, composted or otherwise disposed of in an environmentally compatible manner).
• HFAP hydrogel-forming absorbent polymer.
• Unitary absorbent article refers to an absorbent article which is formed of separate parts united together to form a coordinated entity so that they do not require separate manipulative parts like a separate holder and liner.
• the present invention relates to an antimicrobial hydrogel-forming absorbent polymer comprising a HFAP, and an antimicrobial; wherein the HFAP is coated with the antimicrobial.
• the weight ratio of HFAP to antimicrobial is from about 100:0.01 to about 100:2, more preferably from about 100:0.02 to about 100:1 , more preferably still from about 100:0.05 to about 100:0.5.
• Hvdro ⁇ el-Forminq Absorbent Polymer The water-insoluble, water-swellable absorbent polymers useful in the present invention are commonly referred to as "hydrogel-forming absorbent polymers” (HFAPs), “hydrocolloids", or “superabsorbent” polymers and can include polysaccharides such as carboxymethyl starch, carboxymethyl cellulose, and hydroxypropyl cellulose; nonionic types such as polyvinyl alcohol, and polyvinyl ethers; cationic types such as polyvinyl pyridine, polyvinyl morpholinione, and N,N-dimethylaminoethyl or N,N-diethylaminopropyl acrylates and methacrylates, and the respective quaternary salts thereof.
• HFAPs hydrogel-forming absorbent polymers
• hydrocolloids hydrocolloids
• superabsorbent polymers can include polysaccharides such as carboxymethyl starch, carboxymethyl cellulose
• HFAPs useful in the present invention have a multiplicity of anionic, functional groups, such as sulfonic acid, and more typically carboxy, groups.
• polymers suitable for use herein include those which are prepared from polymerizable, unsaturated, acid-containing monomers.
• such monomers include the olefinically unsaturated acids and anhydrides that contain at least one carbon to carbon olefinic double bond. More specifically, these monomers can be selected from olefinically unsaturated carboxylic acids and acid anhydrides, olefinically unsaturated sulfonic acids, and mixtures thereof.
• non-acid monomers can also be included, usually in minor amounts, in preparing the HFAPs herein.
• Such non-acid monomers can include, for example, the water-soluble or water-dispersible esters of the acid-containing monomers, as well as monomers that contain no carboxylic or sulfonic acid groups at all.
• Optional non-acid monomers can thus include monomers containing the following types of functional groups: carboxylic acid or sulfonic acid esters, hydroxyi groups, amide-groups, amino groups, nitrile groups, quaternary ammonium salt groups, aryl groups (e.g., phenyl groups, such as those derived from styrene monomer).
• Olefinically unsaturated carboxylic acid and carboxylic acid anhydride monomers include the acrylic acids typified by acrylic acid itself, methacrylic acid, ethacrylic acid, 3-chloroacrylic acid, cyanoacrylic acid, methacrylic acid (crotonic acid), phenylacrylic acid, acryloloxypropionic acid, sorbic acid, chlorosorbic acid, angelic acid, cinnamic acid, p-chlorocinnamic acid, sterylacrylic acid, itaconic acid, citroconic acid, mesaconic acid, glutaconic acid, aconitic acid, maleic acid, fumaric acid, tricarboxyethylene and maleic acid anhydride.
• acrylic acids typified by acrylic acid itself, methacrylic acid, ethacrylic acid, 3-chloroacrylic acid, cyanoacrylic acid, methacrylic acid (crotonic acid), phenylacrylic acid, acryloloxypropi
• Olefinically unsaturated sulfonic acid monomers include aliphatic or aromatic vinyl sulfonic acids such as vinylsulfonic acid, allyl sulfonic acid, vinyl toluene sulfonic acid and styrene sulfonic acid; acrylic and methacrylic sulfonic acid such as sulfoethyl acrylate, sulfoethyl methacrylate, sulfopropyl acrylate, sulfopropyl methacrylate, 2-hydroxy-3-methacryloxypropyl sulfonic acid and 2- acrylamide-2-methylpropane sulfonic acid.
• Preferred HFAPs for use in the present invention contain carboxy groups.
• These polymers include hydrolyzed starch-acrylonitrile graft copolymers, partially neutralized hydrolyzed starch-acrylonitrile graft copolymers, starch-acrylic acid graft copolymers, partially neutralized starch-acrylic acid graft copolymers, saponified vinyl acetate-acrylic ester copolymers, hydrolyzed acrylonitrile or acrylamide copolymers, slightly network crosslinked polymers of any of the foregoing copolymers, partially neutralized polyacrylic acid, and slightly network crosslinked polymers of partially neutralized polyacrylic acid.
• polymers can be used either solely or in the form of a mixture of two or more different polymers. Examples of these polymer materials are disclosed in U.S. Patent 3,661 ,875, U.S. Patent 4,076,663, U.S. Patent 4,093,776, U.S. Patent 4,666,983, and U.S. Patent 4,734,478.
• More preferred polymer materials for use in making the HFAPs are slightly network crosslinked polymers of partially neutralized polyacrylic acids and starch derivatives thereof. More preferably, the HFAPs comprise from about 50 to about 95%, preferably about 75%, neutralized, slightly network crosslinked, polyacrylic acid (i.e., poly (sodium acrylate/acrylic acid) ). Network crosslinking renders the polymer substantially water-insoluble and, in part, determines the absorptive capacity and extractable polymer content characteristics of the HFAPs. Processes for network crosslinking these polymers and typical network crosslinking agents are described in greater detail in U.S. Patent 4,076,663.
• surface crosslinked HFAPs can be preferably used in the present invention. They have a higher level of crosslinking in the vicinity of the surface than in the interior.
• surface describes the outer-facing boundaries of the particle, fiber, etc.
• exposed internal boundaries can also be included.
• a higher level of crosslinking at the surface it is meant that the level of functional crosslinks for the HFAP in the vicinity of the surface is generally higher than the level of functional crosslinks for the polymer in the interior.
• the gradation in crosslinking from surface to interior can vary, both in depth and profile.
• the depth of surface crosslinking can be shallow, with a relatively sharp transition to a lower level of crosslinking.
• the depth of surface crosslinking can be a significant fraction of the dimensions of the HFAP, with a broader transition.
• the degree and gradient of surface crosslinking can vary within a given HFAP.
• surface crosslinking can vary with particle size, porosity, etc.
• Surface crosslinking is generally accomplished after the final boundaries of the HFAP are essentially established (e.g., by grinding, extruding, foaming, etc.) However, it is also possible to effect surface crosslinking concurrent with the creation of final boundaries. Furthermore, some additional changes in boundaries can occur even after surface crosslinks are introduced.
• a number of processes for introducing surface crosslinks are disclosed in the art. These include those where: (i) a di- or poly-functional reagent(s) (e.g., glycerol, 1 ,3-dioxolan-2-one, polyvalent metal ions, polyquaternary amines) capable of reacting with existing functional groups within the HFAP is applied to the surface of the HFAP; (ii) a di- or poly-functional reagent that is capable of reacting with other added reagents and possibly existing functional groups within the HFAP such as to increase the level of crosslinking at the surface is applied to the surface (e.g., the addition of monomer plus crosslinker and the initiation of a second polymerization reaction); (iii) no additional polyfunctional reagents are added, but additional reaction(s) is induced amongst existing components within the HFAP either during or after the primary polymerization process such as to generate a higher level of crosslinking at or near the surface (e.g
• Patent 4,734,478 (Tsubakimoto), issued March 29, 1988; U.S. Patent 5,164,459 (Kimura et. al.), issued November 17, 1992; published German patent application 4,020,780 (Dahmen), published August 29, 1991 ; and published European patent application 509,708 (Gartner), published October 21 , 1992.
• the HFAP is preferably of one type (i.e., homogeneous)
• mixtures of polymers can also be used in the present invention.
• mixtures of starch-acrylic acid graft copolymers and slightly network crosslinked polymers of partially neutralized polyacrylic acid can be used in the present invention.
• the HFAP particles used in the present invention can have a size, shape and/or morphology varying over a wide range.
• the HFAP particles do not have a large ratio of greatest dimension to smallest dimension (e.g., granules, flakes, pulverulents, interparticle aggregates, interparticle crosslinked aggregates, and the like) and can be in the form of fibers, foams, and the like.
• the HFAPs can also comprise mixtures with low levels of one or more additives, such as for example powdered silica, surfactants, glue, binders, and the like.
• the components in this mixture can be physically and/or chemically associated in a form such that the hydrogel-forming polymer component and the non-hydrogel- forming polymer additive are not readily physically separable.
• the HFAPs can be essentially non-porous or have substantial internal porosity.
• particle size is defined as the dimension determined by sieve size analysis.
• a particle that is retained on a U.S.A. Standard Testing Sieve with 710 micron openings e.g., No. 25 U.S. Series Alternate Sieve Designation
• a particle that passes through a sieve with 710 micron openings and is retained on a sieve with 500 micron openings e.g., No.
• 35 U.S, Series Alternate Sieve Designation is considered to have a particle size between 500 and 710 microns; and a particle that passes through a sieve with 500 micron openings is considered to have a size less than 500 microns.
• the mass median particle size of a given sample of hydrogel-forming absorbent polymer particles is defined as the particle size that divides the sample in half on a mass basis, i.e., one-half of the sample by weight will have a particle size less than the mass median size and one-half of the sample will have a particle size greater than the mass median size.
• a standard particle-size plotting method (wherein the cumulative weight percent of the particle sample retained on or passed through a given sieve size opening is plotted versus sieve size opening on probability paper) is typically used to determine mass median particle size when the 50% mass value does not correspond to the size opening of a U.S.A. Standard Testing Sieve.
• the particles will generally range in size from about 1 to about 2000 microns, more preferably from about 20 to about 1000 microns.
• the mass median particle size will generally be from about 20 to about 1500 microns, more preferably from about 50 microns to about 1000 microns, and even more preferably from about 100 to about 800 microns.
• a broader size cut wherein the particles generally have a size in the range of from about 150 microns to about 800 microns can be useful.
• the antimicrobial agent useful in the present invention may be any chemical capable of preventing the growth of or killing microorganisms, and is capable of binding to an HFAP; more preferably, capable of binding to the surface of an HFAP.
• Preferred antimicrobials are those that can prevent the growth of or kill microorganisms typically found in body fluids, more preferably those body fluids typically collected by a disposable absorbent article.
• Preferred antimicrobials include, but are not limited to, quaternary ammonium, phenolic, amide, acid, and nitro compounds, and mixtures thereof; more preferably quaternary ammonium, acid and phenolic; more preferably still quaternary ammonium compounds.
• Preferred quaternary ammonium compounds include, but are not limited to, 2-(3-anilinovinylul)3,4-dimethyl-oxazolinium iodide, alkylisoquinolium bromide, benzalkonium chloride, benzethonium chloride, cetylpyridium chloride, chlorhexidine gluconate, chlorhexidine hydrochloride, lauryl trimethyl ammonium, methylbenzethonium chloride, stearltrimethylammonium chloride, 2,4,5-trichloro phenoxide, and mixtures thereof; more preferably benzalkonium chloride and chlorhexidine gluconate; more preferably still benzalkonium chloride.
• Preferred phenolic compounds include, but are not limited to, benzyl alcohol, p-chlorophenol, chloreocresol, chloroxylenol, cresol, o-cymene-5-ol (BIOSOL), hexachlorophene, hinokitiol, isopropylmethylphenol, parabens (having methyl, ethyl, propyl, butyl, isobutyl, isopropyl, and/or sodium methyl substituents), phenethyl alcohol, phenol, phenoxyethanol, o-phynylphenol, resorcin, resorcin monoacetate, sodium parabens, sodium phenolsulfonate, thioxolone, 2,4,4 , -trichloro-2'-hydroxydiphenyl ether, zinc phenolsulfonate, and mixtures thereof; more preferably sodium parabens.
• Preferred amides include, but are not limited to, diazolidinyl urea, 2,4- imidazolidinedione (HYDATOIN), 3,4,4'-trichlorocarbanilide, 3-trifluoromethyl-4-4'- dichlorocarbanilide, undecylenic acid monoethanolamide, and mixtures thereof; more preferably diazolidinyl urea and 2,4-imidazolidinedione; more preferably still 2,4-imidazolidinedione.
• HYDATOIN 2,4- imidazolidinedione
• 3,4,4'-trichlorocarbanilide 3,4,4'-trichlorocarbanilide, 3-trifluoromethyl-4-4'- dichlorocarbanilide, undecylenic acid monoethanolamide, and mixtures thereof
• diazolidinyl urea and 2,4-imidazolidinedione more preferably still 2,4-imidazolidinedione.
• Preferred acids include, but are not limited to, benzoate, benzoic acid, citric acide, dehydroacetic acid, potassium sorbate, sodium citrate, sodium dehydroacetate, sodium salicylate, sodium salicylic acid, sorbic acid, undecylenic acid, zinc undecylenate, and mixtures thereof; more preferably benzoic acid, citric acid, salicylic acid and sorbic acid, more preferably still citric acid and sorbic acid.
• Preferred nitro compounds include, but are not limited to, 2-bromo-2-nitro- 2,3-propanediol (BRONOPOL), and methyldibromo glutaronitrile and propyulene glycol (MERGUARD), and mixtures thereof.
• the invention further relates to a process for making an antimicrobial hydrogel-forming absorbent polymer, the process comprising coating HFAP particles with an antimicrobial.
• coating means that the antimicrobial will be on at least a portion of the surface area of the HFAP.
• the antimicrobial is applied onto all of the surface of the HFAP.
• it is believed that the antimicrobial is bonded to the surface of the HFAP by Coulumb interaction.
• the A-HFAP is hydrated, most of the antimicrobial remains ionically attracted to the HFAP. However, some antimicrobial may diffuse to interparticulate space and fibers.
• the antimicrobial in the form of a small particle or powder, can be applied by any of various techniques and apparatus used for applying (e.g., coating) a material to another material.
• the antimicrobial in another case where the antimicrobial is in the form of a liquid, the antimicrobial can be applied (e.g., coated onto the HFAP) by any of various techniques and apparatus used for applying a liquid to a material.
• A-HFAPs of the present invention can be obtained as described above.
• an antimicrobial is dissolved into a solvent to make a solution.
• the antimicrobial can be dissolved in the solvent by any of various techniques and apparatus used for dissolving a material to a solvent known in the art.
• an inorganic solvent is used as the solvent; preferably water.
• the concentration of the antimicrobial in the solution by weight is from about 2% to 25%, more preferably, from about 5% to 15%.
• an antimicrobial which is insoluble in an organic solvent can be used.
• a polar organic solvent is used as the solvent.
• a mixture solvent of a hydrophilic organic solvent and water is used as the solvent for the antimicrobial.
• the preferred organic solvent includes: the low molecular weight alcohols such as methanol, ethanol, or propanol; acetone; dimethylformamide(DMF); dimethylsulfoxide(DMSO); hexylmethylphosphoric triamide(HMPT); and mixtures thereof.
• non-polar solvents such as hexane, toluene, xylene, and benzene can be used as one of the organic solvents.
• the solution is applied onto the HFAP thereby making an intermittent mixture. More specifically, an amount of the solution is applied onto the HFAP.
• the solution can be applied by any of various techniques and apparatus used for applying a solution to a material including coating, dumping, pouring, dropping, spraying, atomizing, condensing, or immersing the liquid mixture onto the absorbent gelling particles; to cause partial or complete coating of the HFAP with the antimicrobial.
• the solution will be on (e.g., coat) at least a portion of the surface area of the HFAP.
• the solution will be on all of the surface of the HFAP particles.
• the amount of the antimicrobial which is sufficient to effect an efficacious antimicrobial properties can vary based on a number of factors such as the chemical composition of the HFAP and the physical forms of the HFAP, e.g., particle size of the HFAP, and the chemical composition and molecular weight of the antimicrobial, as well as on the method of applying the antimicrobial.
• the solvent is removed from the intermittent mixture.
• at least about 80%, more preferably more than 95%, most preferably about 100% of the solvent is removed from the intermittent mixture.
• the removal of the solvent can be made by any of various techniques and apparatus used for separating or removing liquids from liquid-solid mixtures, including evaporation, filtration, washing, or a combination thereof.
• the antimicrobial is applied onto the HFAP after the treatment of the surface crosslinking of the HFAP particles.
• the antimicrobial is applied onto the HFAP before the treatment of the surface crosslinking of the HFAP.
• the application of the antimicrobial and the treatment of the cross linking can be carried out at the same time.
• the resultant A-HFAP can have a number of shapes and sizes.
• the absorbent materials can be typically in the form of particles, sheets, films, cylinders, blocks, fibers, filaments, or other shaped elements. More preferably, the absorbent material is particulate.
• the A-HFAPs according to the present invention can be used for many purposes in many fields of use.
• the A-HFAPs can be used for packing containers; drug delivery devices; wound cleaning devices; burn treatment devices; ion exchange column materials; construction materials; agricultural or horticultural materials such as seed sheets or water-retentive materials; and industrial uses such as sludge or oil dewatering agents, materials for the prevention of dew formation, desiccants, and humidity control materials.
• an absorbent article refers to articles which absorb and contain body fluids and more specifically refers to articles which are placed against or in proximity to the body of the wearer to absorb and contain the various fluids discharged from the body.
• an absorbent article comprises: (a) a liquid pervious topsheet which is located adjacent to the wearer's body; (b) a liquid impervious backsheet which is located distant from the wearer's body and adjacent to the wearer's clothing; and (c) an absorbent core positioned between the topsheet and the backsheet.
• the absorbent core comprises at least one of the above described A- HFAPs of the present invention.
• the absorbent core further comprises a substrate web wherein the absorbent material is attached to the substrate web.
• the absorbent core further comprises an envelope web encasing the absorbent material.
• the absorbent core further comprises two layered tissues wherein the absorbent material is distributed between the two layered tissues.
• the A-HFAP in the absorbent core has a basis weight of from about 60 g/m 2 to about 1500 g/m 2 , more preferably from about 100 g/m 2 to about 1000 g/m 2 , most preferably from about 150 g/m 2 to about 500 g/m 2 of the absorbent material.
• the absorbent core or absorbent member can further comprise fibers or fluff pulp (fibrous or fiber material), more specifically, non-absorbent-gelling fibers.
• fiber material can be used as reinforcing members in the absorbent core, improving fluid handling of the core, as well as a co-absorbent with the absorbent polymers.
• the absorbent core or member includes from about 40% to about 100% by weight of the A-HFAP and from about 60% to about 0% by weight of such non-absorbent- gelling fiber material distributed within the absorbent material.
• the A-HFAP is in a concentration of at least 40%, more preferably from about 60 to 100% by weight in at least one region of the core or absorbent member.
• the absorbent member comprises fibrous matrix wherein the A-HFAP is distributed in the fibrous matrix.
• any type of fiber material which is suitable for use in conventional absorbent products can be used in the absorbent core or absorbent member herein.
• fiber material include cellulose fibers, improved cellulose fibers, rayon, polypropylene, and polyester fibers such as polyethylene terephthalate (DACRON), hydrophilic nylon (HYDROFIL), and the like.
• other fiber materials for use in the present invention include hydrophilized hydrophobic fibers, such as surfactant-treated or silica-treated thermoplastic fibers derived, for example, from polyolefins such as polyethylene or polypropylene, polyacrylics, polyamides, polystyrenes, polyurethanes and the like.
• hydrophilized hydrophobic fibers which are in and of themselves not very absorbent and which, therefore, do not provide webs of sufficient absorbent capacity to be useful in conventional absorbent structures, are suitable for use in the absorbent core by virtue of their good wicking properties.
• the wicking propensity of the fibers is as important, if not more important, than the absorbent capacity of the fiber material itself due to the high rate of fluid uptake and lack of gel blocking properties of the absorbent core.
• Synthetic fibers are generally preferred for use herein as the fiber component of the absorbent core.
• Most preferred are polyolefin fibers, preferably polyethylene fibers.
• cellulosic fiber materials which can be useful in certain absorbent cores or absorbent members herein are chemically stiffened cellulosic fibers.
• Preferred chemically stiffened cellulosic fibers are the stiffened, twisted, curled cellulosic fibers which can be produced by internally crosslinking cellulose fibers with a crosslinking agent.
• Suitable stiffened, twisted, curled cellulose fibers useful as the hydrophilic fiber material herein are described in greater detail in U.S. Patent 4,888,093 (Dean et al), issued December 19, 1989; U.S. Patent 4,889,595 (Herron et al), issued December 26, 1989; U.S.
• Patent 4,889,596 Schott al
• U.S. Patent 4,889,597 (Bourbon et al), issued December 26, 1989
• U.S. Patent 4,898,647 (Moore et al), issued February 6, 1990.
• a preferred embodiment of the disposable absorbent article is a diaper.
• the term "diaper” refers to a garment generally worn by infants and incontinent persons that is worn about the lower torso of the wearer.
• a preferred diaper configuration for a diaper comprising an absorbent core is described generally in U.S. Patent 3,860,003 (Buell), issued January 14, 1975.
• Alternatively preferred configurations for disposable diapers herein are also disclosed in U.S. Patent 4,808,178 (Aziz et al), issued February 28, 1989; U.S. Patent 4,695,278 (Lawson), issued September 22, 1987; U.S. Patent 4,816,025 (Foreman), issued March 28, 1989; and U.S. Patent 5,151 ,092 (Buell et al.), issued September 29, 1992.
• FIG. 1 is a plan view of the diaper 20 of the present invention in its flat-out, uncontracted state (i.e., with elastic induced contraction pulled out) with portions of the structure being cut-away to more clearly show the construction of the diaper 20 and with the portion of the diaper 20 which faces the wearer, the inner surface 40, facing the viewer.
• the diaper 20 preferably comprises a containment assembly 22 comprising a liquid pervious topsheet 24; a liquid impervious backsheet 26 joined to the topsheet; and an absorbent core 28 positioned between the topsheet 24 and the backsheet 26.
• the absorbent core 28 has a pair of opposing longitudinal edges 60, an inner surface 62 and an outer surface 64.
• the diaper preferably further comprises side panels 30; elasticized leg cuffs 32; elasticized waistbands 34; and a fastening system 36 preferably comprising a pair of securement members 37 and a landing member 38.
• the diaper 20 is shown in Figure 1 to have an inner surface 40 (facing the viewer in Figure 1), an outer surface 42 opposed to the inner surface 40, a rear waist region 44, a front waist region 46 opposed to the rear waist region 44, a crotch region 48 positioned between the rear waist region 44 and the front waist region 46, and a periphery which is defined by the outer perimeter or edges of the diaper 20 in which the side edges are designated 50 and the end edges are designated 52.
• the inner surface 40 of the diaper 20 comprises that portion of the diaper 20 which is positioned adjacent to the wearer's body during use (i.e., the inner surface 40 generally is formed by at least a portion of the topsheet 24 and other components joined to the topsheet 24).
• the outer surface 42 comprises that portion of the diaper 20 which is positioned away from the wearer's body (i.e., the outer surface 42 is generally formed by at least a portion of the backsheet 26 and other components joined to the backsheet 26).
• the term "joined” encompasses configurations whereby an element is directly secured to the other element by affixing the element directly to the other element, and configurations whereby the element is indirectly secured to the other element by affixing the element to intermediate member(s) which in turn are affixed to the other element.
• the rear waist region 44 and the front waist region 46 extend from the end edges 52 of the periphery to the crotch region 48.
• the diaper 20 also has two centerlines, a longitudinal centerline 100 and a transverse centerline 110.
• the terms “transverse” and “lateral”, as used herein, are interchangeable and refer to a line, axis or direction which lies within the plane of the diaper that is generally perpendicular to the longitudinal direction (which divides the wearer into front and back body halves).
• the containment assembly 22 of the diaper 20 is shown in Figure 1 as comprising the main body (chassis) of the diaper 20.
• the containment assembly 22 preferably comprises a topsheet 24, a backsheet 26 and an absorbent core 28 having a pair of opposing longitudinal edges 60, an inner surface 62, an outer surface 64.
• the inner surface 62 generally faces the body of the wearer while the outer surface 64 generally faces away from the body of the wearer.
• the containment assembly 22 generally comprises the holder and the liner (i.e., the containment assembly 22 comprises one or more layers of material to define the holder while the liner comprises an absorbent composite such as a topsheet, a backsheet, and an absorbent core.)
• the containment assembly 22 preferably comprises the topsheet 24, the backsheet 26 and the absorbent core 28 of the diaper with other features added to form the composite diaper structure.
• Figure 1 shows a preferred embodiment of the containment assembly 22 in which the topsheet 24 and the backsheet 26 have length and width dimensions generally larger than those of the absorbent core 28.
• the topsheet 24 and the backsheet 26 extend beyond the edges of the absorbent core 28 to thereby form the periphery of the diaper 20.
• the topsheet 24, the backsheet 26, and the absorbent core 28 may be assembled in a variety of well known configurations, exemplary containment assembly configurations are described generally in U.S. Patent 3,860,003 entitled "Contractible Side Portions for Disposable Diaper" which issued to Kenneth B. Buell on January 14, 1975; and U.S.
• Patent 5,151 ,092 entitled “Absorbent Article With Dynamic Elastic Waist Feature Having A Predisposed Resilient Flexural Hinge” which issued to Kenneth B. Buell et al., on September 29, 1992; each of which is incorporated herein by reference.
• the absorbent core 28 may be any absorbent member which is generally compressible, conformable, non-irritating to the wearer's skin, and capable of absorbing and retaining liquids such as urine and other certain body exudates. As shown in Figure 1 , the absorbent core 28 has a garment-facing side, a body- facing side, a pair of side edges, and a pair of waist edges.
• the absorbent core 28 may be manufactured in a wide variety of sizes and shapes (e.g., rectangular, hourglass, "T"-shaped, asymmetric, etc.) and, in addition to including an A-HFAP of the present invention, may also include a wide variety of liquid-absorbent materials commonly used in disposable diapers and other absorbent articles such as comminuted wood pulp which is generally referred to as airfelt.
• suitable absorbent materials include creped cellulose wadding; meltblown polymers including coform; chemically stiffened, modified or cross-linked cellulosic fibers; tissue including tissue wraps and tissue laminates; absorbent foams; absorbent sponges; superabsorbent polymers; absorbent gelling materials; or any equivalent material or combinations of materials.
• the configuration and construction of the absorbent core 28 may vary (e.g., the absorbent core may have varying caliper zones, a hydrophilic gradient, a superabsorbent gradient, or lower average density and lower average basis weight acquisition zones; or may comprise one or more layers or structures). Further, the size and absorbent capacity of the absorbent core 28 may also be varied to accommodate wearers ranging from infants through adults. However, the total absorbent capacity of the absorbent core 28 should be compatible with the design loading and the intended use of the diaper 20.
• One embodiment of the diaper 20 has an asymmetric, modified T-shaped absorbent core 28 having ears in the front waist region but a generally rectangular shape in the rear waist region.
• Exemplary absorbent structures for use as the absorbent core 28 of the present invention that have achieved wide acceptance and commercial success are described in U.S. Patent 4,610,678 entitled “High-Density Absorbent Structures” issued to Weisman et al. on September 9, 1986; U.S. Patent 4,673,402 entitled “Absorbent Articles With Dual-Layered Cores” issued to Weisman et al. on June 16, 1987; U.S. Patent 4,888,231 entitled “Absorbent Core Having A Dusting Layer” issued to Angstadt on December 19, 1989; and U.S.
• Patent 4,834,735 entitled “High Density Absorbent Members Having Lower Density and Lower Basis Weight Acquisition Zones", issued to Alemany et al. on May 30, 1989.
• the absorbent core may further comprise the dual core system containing an acquisition/distribution core of chemically stiffened fibers positioned over an absorbent storage core as detailed in U.S. Patent 5,234,423, entitled “Absorbent Article With Elastic Waist Feature and Enhanced Absorbency” issued to Alemany et al., on August 10, 1993; and in U.S. Patent 5,147,345, entitled “High Efficiency Absorbent Articles For Incontinence Management” issued to Young, LaVon and Taylor on September 15, 1992.
• the topsheet 24 is preferably positioned adjacent the inner surface 62 of the absorbent core 28 and is preferably joined thereto and to the backsheet 26 by attachment means (not shown) such as those well known in the art. Suitable attachment means are described with respect to joining the backsheet 26 to the absorbent core 28.
• the topsheet 24 and the backsheet 26 are joined directly to each other in the diaper periphery and are indirectly joined together by directly joining them to the absorbent core 28 by any suitable attachment means.
• the topsheet 24 is preferably compliant, soft feeling, and non-irritating to the wearer's skin. Further, the topsheet 24 is preferably liquid pervious permitting liquids (e.g., urine) to readily penetrate through its thickness.
• a suitable topsheet 24 may be manufactured from a wide range of materials such as woven and nonwoven materials; polymeric materials such as apertured formed thermoplastic films, apertured plastic films, and hydroformed thermoplastic films; porous foams; reticulated foams; reticulated thermoplastic films; and thermoplastic scrims.
• Suitable woven and nonwoven materials can be comprised of natural fibers (e.g., wood or cotton fibers), synthetic fibers (e.g., polymeric fibers such as polyester, polypropylene, or polyethylene fibers) or from a combination of natural and synthetic fibers.
• the topsheet 24 is preferably made of a hydrophobic material to isolate the wearer's skin from liquids which have passed through the topsheet 24 and are contained in the absorbent core 28 (i.e.
• topsheet 24 is made of a hydrophobic material, at least the upper surface of the topsheet 24 is treated to be hydrophilic so that liquids will transfer through the topsheet more rapidly. This diminishes the likelihood that body exudates will flow off the topsheet 24 rather than being drawn through the topsheet 24 and being absorbed by the absorbent core 28.
• the topsheet 24 can be rendered hydrophilic by treating it with a surfactant. Suitable methods for treating the topsheet 24 with a surfactant include spraying the topsheet 24 material with the surfactant and immersing the material into the surfactant. A more detailed discussion of such a treatment and hydrophilicity is contained in U.S.
• An alternative preferred topsheet comprises an apertured formed film.
• Apertured formed films are preferred for the topsheet because they are pervious to body exudates and yet non-absorbent and have a reduced tendency to allow liquids to pass back through and rewet the wearer's skin. Thus, the surface of the formed film which is in contact with the body remains dry, thereby reducing body soiling and creating a more comfortable feel for the wearer.
• Suitable formed films are described in U.S. Patent 3,929,135, entitled “Absorptive Structures Having Tapered Capillaries", which issued to Thompson on December 30, 1975; U.S.
• Patent 4,324,246 entitled “Disposable Absorbent Article Having A Stain Resistant Topsheet", which issued to Mullane, et al. on April 13, 1982;
• U.S. Patent 4,342,314 entitled “Resilient Plastic Web Exhibiting Fiber-Like Properties", which issued to Radel. et al. on August 3, 1982;
• U.S. Patent 4,463,045 entitled “Macroscopically Expanded Three-Dimensional Plastic Web Exhibiting Non- Glossy Visible Surface and Cloth-Like Tactile Impression", which issued to Ahr et al. on July 31 , 1984; and
• U.S. 5,006,394 Multilayer Polymeric Film” issued to Baird on April 9, 1991.
• the backsheet 26 of the present invention is that portion of the diaper 20 which is generally positioned away from the wearer's skin and which prevents the exudates absorbed and contained in the absorbent core 28 from wetting articles which contact the diaper 20 such as bedsheets and undergarments.
• the backsheet 26 is preferably impervious to liquids (e.g., urine) and is preferably manufactured from a thin plastic film, although other flexible liquid impervious materials may also be used.
• the term "flexible” refers to materials which are compliant and will readily conform to the general shape and contours of the human body.
• the backsheet 26 permits vapors to escape from the diaper 20.
• a suitable material for the backsheet 26 is a thermoplastic film having a thickness of from about 0.012 mm (0.5 mil) to about 0.051 mm (2.0 mils), preferably comprising polyethylene or polypropylene.
• the backsheet 26 of the present invention may comprise a single member such as the film described above, or may comprise a number of materials joined together to form the backsheet 26.
• the backsheet may have a central region 74 comprising one film or other member and one or more outer regions 76 joined to the central region 74 comprising the same or different films or other materials.
• the backsheet 26 comprises a central region 76 comprising a liquid impervious, non-apertured film and two opposing outer regions 76 comprising an air pervious, apertured film.
• the means by which any portions of such a backsheet are joined my include any means known in the art such as adhesives, heat, pressure, heat and pressure and ultrasonic bonds.
• the backsheet 26 may comprise any number of layers of material joined together to form a laminate. If the backsheet 26 is a laminate, the layers need not be uniform throughout the backsheet. For example, the central region 74 of the backsheet 26 may comprise more layers or layers of different material than the outer regions 76.
• the backsheet 26 is preferably positioned adjacent the outer surface 64 of the absorbent core 28 and is preferably joined thereto by any suitable attachment means known in the art.
• the backsheet 26 may be secured to the absorbent core 28 by a uniform continuous layer of adhesive, a patterned layer of adhesive, or an array of separate lines, spirals, or spots of adhesive.
• Adhesives which have been found to be satisfactory are manufactured by H. B. Fuller Company of St. Paul, Minnesota and marketed as HL-1258.
• An example of a suitable attachment means comprising an open pattern network of filaments of adhesive is disclosed in U.S. Patent 4,573,986 entitled "Disposable Waste-Containment Garment", which issued to Minetola et al. on March 4, 1986.
• attachment means comprising several lines of adhesive filaments swirled into a spiral pattern is illustrated by the apparatus and methods shown in U.S. Patent 3,911 ,173 issued to Sprague, Jr. on October 7, 1975; U.S. Patent 4,785,996 issued to Ziecker, et al. on November 22, 1978; and U.S. Patent 4,842,666 issued to Werenicz on June 27, 1989.
• the attachment means may comprise heat bonds, pressure bonds, ultrasonic bonds, dynamic mechanical bonds, or any other suitable attachment means or combinations of these attachment means as are known in the art.
• Embodiments of the present invention are also contemplated wherein the absorbent core is not joined to the backsheet 26, and/or the topsheet 24 in order to provide greater extensibility in the front waist region 46 and the rear waist region 44.
• an additional member such as a liquid impervious barrier material(s) (not shown), is positioned between the outer surface 64 of the absorbent core 28 and the backsheet 28. Any such barrier member may or may not be joined to the absorbent core 28.
• the backsheet 26 may or may not be joined to any barrier material(s) that are positioned between the backsheet 26 and the absorbent core 28.
• Preferred catamenial products comprise a formed-film, apertured topsheet as disclosed in U.S. Patent 4,285,343 (McNair), issued August 25, 1981 ; U.S. Patent 4,608,047 (Mattingly), issued August 26, 1986; and U.S. Patent 4,687,478 (Van Tilburg), issued August 18, 1987.
• Preferred catamenial products can comprise wings, side flaps, and other structures and elements, as described in co-pending, commonly-assigned U.S. application serial No. 984,071 , to Yasuko Morita, entitled “Absorbent Article Having Elasticized Side Flaps", Attorney Docket No. JA-09RM, filed November 30, 1992.
• a particularly preferred disposable absorbent article comprising the A-HFAP has a reduced tendency for surface wetness. Such an article facilitates maintaining the antimicrobial away from the user's skin, even after wetting.
• a disposable absorbent article comprising a backsheet, a topsheet, an acquisition/distribution layer, and an absorbent core; the absorbent core comprising the A-HFAP of the present invention.
• Such an absorbent article preferably has a total finished product acquisition rate (test method discussed below) greater than or equal to about 1.9 ml/sec at first gush and greater than or equal to about 0.3 ml/sec at fourth gush.
• the folded stackheight of such an absorbent article is preferably less than about 9.9 mm per pad, more preferably less than about 6 mm.
• the topsheet of such a product retains no more than about 0.05 g to about 1 g of fluid as measured by the finished product wetness test (discussed below); more preferably no more than about 0.5 g of fluid; more preferably, no more than about 0.2 g of fluid; more preferably still, no more than about 0.15 g of fluid.
• FIG 2 is a cross-sectional view of such an embodiment of the disposable diaper of Figure 1 , taken along transverse center line 110 of Figure 1.
• This view shows fragmentary cross- sectional views of the backsheet 26, core cover 22, absorbent core 28, topsheet 24, and elasticized leg cuffs 32.
• This embodiment differs from that shown in Figure 1 , in that an additional element, acquisition/distribution layer 105 has been added.
• FIG 3 is an enlarged view of an alternative embodiment of the disposable diaper of Figure 1 , the view corresponding to a portion of Figure 2.
• topsheet 24 comprises first topsheet layer 115 and second topsheet layer 120.
• First topsheet layer 115 and second topsheet layer 120 are preferably heat bonded together.
• Acquisition/distribution layer 105 comprises a first acquisition/distribution layer 125 and a second acquisition/distribution layer 130.
• First acquisition/distribution layer 125 is preferably spiral glue bonded to second topsheet layer 120.
• Preferably first acquisition/distribution layer 125 and second acquisition/distribution layer 130 are not bonded together.
• Either embodiment set forth in Figure 2 or Figure 3 provides reduced tendency for surface wetness; and consequently facilitates maintaining the antimicrobial away from the user's skin, even after wetting. In other words, such an embodiment reduces the chance that liquid, e.g., urine having come in contact with the A-HFAP and now possibly containing antimicrobial, will flow back to the user's skin, bringing the antimicrobial in contact with the user's skin.
• liquid e.g., urine having come in contact with the A-HFAP and now possibly containing antimicrobial
• Preferred topsheet 24 and acquisition/distribution layer 105 materials for such a reduced surface wetness absorbent article include the following:
• Preferred topsheet 24 material is P-8 nonwoven available from Fiberweb North America, Inc. (Simpsonville, South Carolina, U.S.A.). It is a conventional thermobonded carded web of about 20 to 22 g/m2. made of polypropylene fibers of about 2.2 dtex and an easily removable surfactant (spin finish), i.e., at a first fluid insult, it is very hydrophilic, but at repeated wetting it is essentially as hydrophobic as the base polypropylene. More preferably, the topsheet 24 material is S-2355, available from Havix
• First topsheet layer 115 is preferably a polypropylene/polypropylene bicomponent fiber, e.g., a lower melting temperature polypropylene in sheath and a higher melting temperature polypropylene in the core of the fiber.
• Second topsheet layer 120 is preferably a polyethylene/polyethylene telephthalate bicomponent fiber, e.g., a lower melting temperature polyethylene in the sheath and a higher melting temperature and more resilient polyethylene telephthalate in the core of the fiber.
• the first topsheet layer 115 preferably has a weak hydrophilic surfactant and the second topsheet layer preferably has a normal hydrophilic surfactant.
• the total basis weight of a typical material is about 20 to 22 g/m 2 .
• the acquisition/distribution layer 105 comprises carded, resin bonded hiloft nonwoven materials such as, for example, FT-6860, available from Polymer Group, Inc., North America (Landisiville, New Jersey, U.S.A.). They are made of polyethylene telephthalate fibers of 6 dtex, and has a basis weight of about 43 g/m 2 .
• acquisition/distribution layer 105 comprises chemically treated stiffened cellulosic fiber material, available from Weyerhaeuser Co. (United States) under the trade designation of CMC.
• the acquisition/distribution layer 105 comprises conventional cellulosic fluff material, also known as wood pulp fiber, available from Weyerhaeuser Co. (United States) under the trade name FLINT RIVER.
• the specific synthetic urine used in the test methods is commonly known as JAYCO SYNURINE and is available from Jayco Pharmaceuticals Company of Camp Hill, Pennsylvania.
• the formula for the synthetic urine is: 20g/l of KCI, 2.0 g/l of Na2S04, 0.85 g/l of (NH 4 )H2P ⁇ 4; 0.15 g/l (NH ) 2 HP ⁇ 4, 0.19 g/l of CaCl2, and 0.23 g/l of MgCI 2 . All of the chemicals are of reagent grade.
• the pH of the synthetic urine is in the range of from about 6.0 to about 6.4. b. Finished Product Acquisition Test
• an absorbent structure 10 is loaded with a 75 ml gush of synthetic urine at a rate of 15 ml/s using a pump (Model 7520-00, supplied by Cole Parmer Instruments, Chicago, U.S.A.), from a height of 5 cm above the sample surface.
• the time to absorb the urine is recorded by a timer.
• the gush is repeated every 5 minutes at precisely 5 minute gush intervals until the article is sufficiently loaded.
• Current test data are generated by loading four forms.
• the test sample which comprises an absorbent core and includes a topsheet and a backsheet, is arranged to lie flat on a foam platform 11 within a perspex box (only base 12 of which is shown).
• a perspex plate 13 having a 5 cm diameter opening substantially in its middle is placed on top of the sample.
• Synthetic urine is introduced to the sample through a cylinder 14 fitted, and glued into the opening.
• Electrodes 15 are located on the lowest surface of the plate, in contact with the surface of the absorbent structure 10. The electrodes are connected to the timer. Loads 16 are placed on top of the plate to simulate, for example, a baby's weight. A pressure of 50 g/cm 2 is typically utilized for this test.
• test fluid As test fluid is introduced into the cylinder it typically builds up on top of the absorbent structure thereby completing an electrical circuit between the electrodes. This starts the timer. The timer is stopped when the absorbent structure has absorbed the gush of urine, and the electrical contact between the electrodes is broken.
• the acquisition rate is defined as the gush volume absorbed (ml) per unit time (seconds).
• the acquisition rate is calculated for each gush introduced into the sample.
• Of particular interest in view of the current invention are the first and the last of the four gushes. This test is primarily designed to evaluate products having an absorbent capacity of about 300 ml to about 400 ml. If products with significantly different capacities should be evaluated, the settings in particular of the fluid volume per gush should be adjusted appropriately to about 20% of the theoretical capacity, and the deviations should be recorded. c. Finished Product Wetness Test
• a disposable absorbent article is placed on the apparatus set forth in Figure 4, as discussed under the finished product acquisition test, above, with the following differences. 225 ml of synthetic urine is loaded into the absorbent article sample. The load occurs via 3 gushes, of 75 ml each, at 3 min. intervals. No additional pressure is applied, other than any negligible pressure that may come from the perspex plate.
• the perspex plate is removed.
• Two pieces of filter paper supplied by Hollingsworth & Vose, United Kingdom, of the type ERT FF3.W/S), having dimensions of 12 cm by 12 cm, are weighed, and then placed on the urine loaded diaper.
• a load of 2 kg over a 10 cm by 10 cm area is applied to the filter paper (i.e., 0.28 psi) for 2 minutes.
• the filter paper is removed and weighed a second time.
• the diaper rewet value is defined as the increase in weight (g) of the filter paper, d.
• Bag Stack Height Essentially, the in bag stack height is measured by measuring the height of a stack of absorbent products as it is packed into cartons or bags as supplied to the market, and dividing the height by the number of articles in this stack.
• a suitable device such as a stress-strain measurement device such as provided by INSTRON Instruments.
• Basis weights are often referred to for various materials. These can be generated by essentially dividing the weight of a specimen by the area of it. The size of the area as well as the number of rewired replicates depend on the homogeneity of the specimen. f. Hvdrophilicitv / Hvdrophobicitv
• Hydrophilicity and hence, wettability are typically defined in terms of contact angle and the surface tension of the fluids and solids involved. This is discussed in detail in, e.g., the American Chemical Society publication entitled
• materials can be categorized into three groups: Materials which are "highly hydrophilic” (abbreviated “h+”): These generally have a contact angle of less than about 80 degrees. Examples include cellulosic fibers and olefinic polymers when they are treated with an effective and strong surfactant (at least when exposed the first time to wetting).
• h- Materials which are "essentially hydrophobic”: These generally have a contact angle of more than about 100 degrees. Examples include pure olefines (polyethylene/polypropylene) without surfactants (neither at the surface, nor resin incorporated).
• Example 1 This example shows how to manufacture a HFAP for use in the present invention.
• an absorbent polymer B having the surface region thereof secondarily cross-linked is obtained.
• Example 2 This example shows how to manufacture an A-HFAP of the present invention.
• benzalkonium chloride available, e.g., from Wako Chemical (Osaka, Japan) is dissolved into 100 ml of distilled ionized water. After complete dissolution, the solution is introduced to an air tank which is connected to a spray nozzle and air pump. 500g of the absorbent polymer B from Example 1 is evenly placed on a stainless steel plate to form thin layers of ca. 3 mm thickness. 25 g of the benzalkonium chloride aqueous solution is sprayed onto the 500 g of absorbent polymer B particles at room temperature. The particles are then placed into a food mixer and agitated for 15 minutes.
• the benzalkonium chloride-coated absorbent polymer B particles are subsequently subjected to drying at 95°C in a dynamic oven for one hour, or through hot air drying for 10 minutes to reduce the moisture level to less than 1% of the absorbent polymer B particles.
• the dry particles are gently ground into granules of equal or less than 800 ⁇ m in size, resulting in nominal production of polymer dust.
• the resulting particles contain 0.5% benzalkonium chloride.
• Example 3 This example shows how to manufacture another embodiment of an A- HFAP of the present invention.
• Example 2 the same procedure as in Example 2 is followed, except that the absorbent polymer B is replaced with Aqualic CA-L76 (a cross-linked sodium polyacrylate; available from Nippon Shokubai Co. Ltd, Osaka, Japan).
• Aqualic CA-L76 a cross-linked sodium polyacrylate; available from Nippon Shokubai Co. Ltd, Osaka, Japan.
• the process results in nominal production of polymer dust, following coating with the benzalkonium chloride.
• Example 4 shows the an absorbent core comprising an A-HFAP of the present invention, for use in a disposable absorbent article.
• Wood pulp of Southern Pine is disintegrated and opened in an air flowing chamber. Fibers having an average length of about 3 mm are allowed to fall on a vacuum plate. During the fiber laydown procedure, the A-HFAP of Example 3 is sprinkled into the wood pulp fibers. A core containing 230 to 400 g/m 2 of wood pulp fibers and 160 to 360 g/m 2 of the A-HFAP is formed. The core is suitable for use in infant and/or adult incontinent diaper applications.
• a typical composition of an L-size infant diaper application is as follows:
• Wood pulp fiber 15 55 Hydrogel-forming absorbent polymer 12 44 Antimicrobial 0.024 0.09
• This example shows a disposable baby diaper comprising an A-HFAP of the present invention.
• Topsheet carded and thermally bonded staple-length polypropylene fibers (Hercules type 151 polypropylene); width at top and bottom 33 cm; notched inwardly on both sides to a width-at-center of 28.5 cm; length 50.2 cm.
• Absorbent core comprises 28.6 g of cellulose wood pulp and 4.9 g of the A-HFAP of Example 3; 8.4 mm thick, calendered; width at top and bottom 28.6 cm; notched inwardly at both sides to a width-at-center of 10.2 cm; length 44.5 cm.
• Elastic leg bands four individual rubber strips (2 per side); width 4.77 mm; length 370 mm; thickness 0.178 mm (all the foregoing dimensions being in the relaxed state).
• the diaper is prepared in standard fashion by positioning the core material covered with the topsheet on the backsheet and gluing.
• the elastic bands are stretched to ca. 50.2 cm and positioned between the topsheet/backsheet along each longitudinal side (2 bands per side) of the core.
• the inner bands along each side are positioned ca. 55 mm from the narrowest width of the core (measured from the inner edge of the elastic band), this provides a spacing element along each side of the diaper comprising the flexible topsheet/backsheet material between the inner elastic and the curved edge of the core.
• the inner bands are glued down along their length in the stretched state.
• the topsheet/backsheet assembly is flexible, and the glued-down bands contract to elasticize the sides of the diaper.
• the resulting diaper provides combined fluid adsorption and antimicrobial properties.
• Example 6 This example shows an adult incontinent product comprising an A-HFAP of the present invention.
• a heavy weight core is formed having 24 to 40 g of wood pulp fiber and 10 to 20 g of the A-HFAP.
• the core is subsequently interposed between a fluid-impermeable poly backsheet and a fluid-permeable topsheet to form an adult incontinent product.
• Example 7 This example shows a light weight pantiliner product comprising an A- HFAP of the present invention.
• a light weight pantiliner suitable for use between menstrual periods comprises a pad.
• the pad has a surface area 117 cm 2 ; and contains 3 g of wood pulp fiber and 1.5 g A-HFAP of Example 3.
• the pad is subsequently interposed between a porous formed-film topsheet according to U.S. Patent No. 4,463,045 and a fluid-impermeable backsheet is manufactured per U.S. Patent No. 4,687,478, to form a light weight pantiliner product.
• the resulting pantiliner provides combined fluid adsorption and antimicrobial properties.
• Example 8 This example shows a sanitary pad comprising an A-HFAP of the present invention.
• a catamenial product in the form of a sanitary napkin having two flaps extending outward from its absorbent core is prepared per the design of U.S. Patent No. 4,687,478, Van Tillburg, issued Aug. 18, 1987.
• the pad utilized has a surface are of 117 cm 2 ; and containing 6 to 12 g of wood pulp fiber and 1 to 3 g of the A-HFAP of Example 2.
• the fluid-permeable topsheet is manufactured per U.S. Patent No. 4,463,045.
• the fluid-impermeable backsheet is manufactured per U.S. Patent No. 4,687,478.
• the resulting sanitary pad provides combined fluid adsorption and antimicrobial properties.
• the aspects and embodiments of the present invention set forth in this document have many surprising advantages, including improved efficacy and improved processability.
• the antimicrobial will act immediately upon fluid entering the absorbent core.
• the antimicrobial were incorporated within the HFAP, its efficacy would be delayed until the HFAP began swelling with the fluid.
• the coating of HFAP with, e.g., the antimicrobial results in reducing the release of HFAP dust particles into the air. This reduction of HFAP dust particles produces a safer environment for workers, less downtime spent cleaning processing equipment, and prevention of loss of material.

Landscapes

• Health & Medical Sciences (AREA)
• Life Sciences & Earth Sciences (AREA)
• General Health & Medical Sciences (AREA)
• Engineering & Computer Science (AREA)
• Chemical & Material Sciences (AREA)
• Hematology (AREA)
• Materials Engineering (AREA)
• Epidemiology (AREA)
• Animal Behavior & Ethology (AREA)
• Public Health (AREA)
• Veterinary Medicine (AREA)
• Pest Control & Pesticides (AREA)
• Agronomy & Crop Science (AREA)
• Plant Pathology (AREA)
• Dentistry (AREA)
• Wood Science & Technology (AREA)
• Zoology (AREA)
• Environmental Sciences (AREA)
• Toxicology (AREA)
• Dispersion Chemistry (AREA)
• Absorbent Articles And Supports Therefor (AREA)
• Orthopedics, Nursing, And Contraception (AREA)
• Compositions Of Macromolecular Compounds (AREA)
• Processes Of Treating Macromolecular Substances (AREA)

Applications Claiming Priority (1)

Publications (1)

Family

ID=22256113

Family Applications (1)

Country Status (14)

Families Citing this family (30)

Family Cites Families (6)

• 1996
  • 1996-11-14 CA CA002271465A patent/CA2271465A1/en not_active Abandoned
  • 1996-11-14 KR KR19997004246A patent/KR100335554B1/ko not_active IP Right Cessation
  • 1996-11-14 EP EP96940374A patent/EP0946210A1/en not_active Withdrawn
  • 1996-11-14 AU AU77270/96A patent/AU7727096A/en not_active Abandoned
  • 1996-11-14 CN CN96180559A patent/CN1241947A/zh active Pending
  • 1996-11-14 BR BR9612826-7A patent/BR9612826A/pt not_active Application Discontinuation
  • 1996-11-14 MX MX9904534A patent/MXPA99004534A/es unknown
  • 1996-11-14 WO PCT/US1996/018079 patent/WO1998020916A1/en not_active Application Discontinuation
  • 1996-11-14 JP JP09536160A patent/JP3071471B2/ja not_active Expired - Lifetime
• 1997
  • 1997-10-31 ZA ZA9709836A patent/ZA979836B/xx unknown
  • 1997-11-13 ID IDP973676A patent/ID18871A/id unknown
  • 1997-11-13 AR ARP970105307A patent/AR010594A1/es unknown
  • 1997-11-14 PE PE1997001028A patent/PE8999A1/es not_active Application Discontinuation
  • 1997-11-20 TW TW086117375A patent/TW480181B/zh not_active IP Right Cessation

Non-Patent Citations (1)

Also Published As

Similar Documents

Legal Events